ASSESSMENT OF PCBs, SELECTED ORGANIC PESTICIDES AND MERCURY IN
FISHES FROM NEW JERSEY: 1998-1999 MONITORING PROGRAM
Report No. 00-20D
Jeffrey Ashley
Richard J. Horwitz
Patrick Center for Environmental Research
The Academy of Natural Sciences
1900 Benjamin Franklin Parkway
Philadelphia, PA 19103
12 December 2000
EXECUTIVE SUMMARY
Prior to this study, the most recent monitoring for organic contaminants and mercury in fish from
New Jersey’s coastal waters was in 1991. To assess the possible temporal and spatial changes in
contamination since that time, and to provide more up-to-date and extensive monitoring data
regarding contaminant levels in New Jersey fishes, this study was implemented in 1998. Over
300 samples were analyzed for polychlorinated biphenyls, organochlorine pesticides (e.g., DDT
and its metabolites, and chlordanes) and mercury from locations extending from Raritan Bay to
the Delaware River and its tributaries. Using the US Food and Drug’s Action Limits (as well as
state-promulgated guidelines), a cursory assessment of risk based on exceedances of these limits
was made. Based on the number, species and locations of the exceedances of US FDA action
limits for PCBs and chlordanes, the following regions of concern were designated: 1) the
Camden area (Newton Lake, Strawbridge Ponds, Pennsauken River and Cooper River Lake),
based largely on chlordane concentrations within common carp, 2) sections of the Delaware
River and its tributaries (e.g., Raccoon Creek) based on PCB concentrations, mainly in American
eel, and 3) Raritan Bay, based on higher than average concentration of PCBs in American eels
(and white perch). Comparisons with historical data sets were made. For most species and
regions, concentrations of PCBs and chlordanes have decreased markedly compared to
evaluations made a decade ago. Changes in DDX are more equivocal, with some groups showing
decreases, but with little evidence of change for other comparisons. The observed decreases
could be due to environmental cleanup, pollution prevention programs, degradation, or changes
in the bioavailability of contaminants.
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TABLE OF CONTENTS
Page
EXECUTIVE SUMMARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
LIST OF TABLES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iii
LIST OF FIGURES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v
INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
METHODS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Collections . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Sample Handling and Preparation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Chemical Analyses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Data Reporting . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
RESULTS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Overview of Data Set . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Ranges and Means . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Risk Assessment Based on Exceedances of FDA Action Levels . . . . . . . . . . . . . . . . . . 32
Organochlorine Pesticides of Concern Having No Action Limits . . . . . . . . . . . . . . . . . . 36
DISCUSSION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
Regions and Species of Concern . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
Temporal Changes in Contaminant Concentrations in NJ Fish . . . . . . . . . . . . . . . . . . . . 38
Gaining Information by Comparing PCB Congener-Specific Patterns . . . . . . . . . . . . . . 46
Comparison of Metabolite Ratios . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
Using TEqs for Risk Assessment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
CONCLUSIONS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52
APPENDIX I: Quality Assurance/Quality Control Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
APPENDIX II: Raw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 71
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LIST OF TABLES
Page
Table 1.
Study design for the 1998-1999 NJ Monitoring study. . . . . . . . . . . . . . . . . . . . . . . . . 3
Table 2.
List of target organic analytes for the 1998-1999 NJ Monitoring study. . . . . . . . . . . . 7
Table 3.
Groupings of stations used to summarize spatial patterns in contaminants. . . . . . . . 10
Table 4.
Number of species collected for PCBs, OCPs and Hg or all three combined. . . . . . 12
Table 5.
Mean Hg concentrations (ng/g wet weight) for each species, by region. . . . . . . . . . . 14
Table 6.
Mean total PCB (mid) (ng/g wet weight) for each species, by region. . . . . . . . . . . . 19
Table 7.
Total number of individual samples of each species analyzed and the number
of those above analytical detection limits for organochlorine pesticides. . . . . . . . . . 26
Table 8.
Mean heptachlor concentrations (ng/g wet weight) for each species, by region . . . . 27
Table 9.
Mean heptachlor epoxide concentrations (ng/g wet weight) for each species, by
region. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
Table 10. Mean dieldrin concentrations (ng/g wet weight) for each species, by region. . . . . . . 28
Table11. Mean total chlordane concentrations, including cis and trans nonachlor and
oxychlordane (ng/g wet weight), for each species, by region. . . . . . . . . . . . . . . . . . . 28
Table 12. Mean total chlordane (cis and trans chlordane only - min values)
(ng/g wet weight) for each species, by region. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 29
Table 13. Mean DDX (max) concentrations (ng/g wet weight) for each species, by region . . . 31
Table 14. Mean total BHC (mid) concentrations (ng/g wet weight) for each species,
by region. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
Table 15. Summary of U.S. FDA’s Action Limits for mercury, PCBs and pesticides. . . . . . . . 32
Table 16. Mercury exceedances based on various consumption guidelines and action limits . 33
Table 17. Species exceeding (numbers in bold) US FDA’s action limits (PCBs,
total heptachlor, chlordanes, and dieldrin + aldrin, and DDXs). . . . . . . . . . . . . . . . . 35
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Table 18. Comparison of PCB concentrations evaluated in this study with data compiled from
1981-82, 1986-87, and 1988-91. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39
Table 19. Comparison of previous data (from Kennish and Ruppel 1997) with current data. Data
are sums of the cis- and trans-chlordane components as )g/kg wet weight. For the
1998-1999 data, nondetect values are set to 0, and values below detection limit are set
to ½ the detection limit. Standard deviations (sd) are calculated on raw
(untransformed) data, which may be non-normal. . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
Table 20. Comparison of DDX concentrations evaluated in this study with data compiled
from 1986-87.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 43
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LIST OF FIGURES
Page
Figure 1. Sampling locations for the NJ Monitoring Study. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Figure 2. Relationship between Hg concentration ()g/g wet weight) and length (cm) for
American eels. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Figure 3. Relationship between Hg concentration ()g/g wet weight), lipid content (%wet
weight), and length (cm) for American eels. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Figure 4. Relationship between Hg concentration ()g/g wet weight) and length (cm) for
bluefish. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
Figure 5. Relationship between Hg concentration ()g/g wet weight) and length (cm)
for striped bass. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Figure 6. Relationship between PCB (mid) concentration (ng/g wet weight), lipid content
(%wet weight), and length (cm) in the American eel. . . . . . . . . . . . . . . . . . . . . . . . . 20
Figure 7. Relationship between total PCB concentration (ng/g wet weight), lipid content (%)
and total length (cm) in striped bass. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Figure 8. Relationship between total lipid normalized PCB (mid) concentration (ng/g wet
weight) and total length (cm) in the American eel. . . . . . . . . . . . . . . . . . . . . . . . . . . 22
Figure 9. Relationship between total lipid normalized PCB (mid) concentration (ng/g wet
weight) and total length (cm) in striped bass. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
Figure 10. Relationship between total PCB (mid) concentration (ng/g wet weight),
lipid content (%), and total length (cm) in bluefish. . . . . . . . . . . . . . . . . . . . . . . . . . 24
Figure 11. Relationship between sum of all chlordanes, including nonachlors
(ng/g wet weight) and lipid content (%) in all species, by location. . . . . . . . . . . . . . 30
Figure 12. Relationship between total PCB concentrations and length for American eel
from the Delaware Bay and River sites from 1986-87 and 1998-99. . . . . . . . . . . . . 40
Figure 13. Relationship between chlordane concentrations and length for American eel from
Northeastern sites from 1986087 and 1998-99. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42
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Figure 14. Relationship between DDX concentrations and length for American eel from
Delaware Bay and River sites from 1986-86 and 1998-99. . . . . . . . . . . . . . . . . . . . . 44
Figure 15. Relationship between DDX concentrations and length for American eel from
Northeastern sites from 1986-87 and 1998-99. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 45
Figure 16. Relationship between lipid normalized DDX concentrations and length for American
eel from Northeastern sites from 1986-87 and 1998-99. . . . . . . . . . . . . . . . . . . . . . . 47
Figure 17. Normalized PCB congeneric patterns for striped bass collected from the Atlantic
Ocean. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48
Figure 18. Normalized PCB congeneric patterns for American eel collected from various
locations including Toms River. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50
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INTRODUCTION
Since 1975, the State of New Jersey (Department of Environmental Protection; NJ DEP) has
conducted a fish tissue monitoring program for mercury and chlorinated hydrocarbons, including
polychlorinated biphenyls (PCBs) and various pesticides (e.g., chlordanes, DDTs). The main
objectives of this program are to determine ambient levels of contaminants in selected species, to
evaluate any geographic variations, and to determine potential human health impacts. The
monitoring has concentrated on contamination of finfish and shellfish of recreational or
commercial importance (NJ DEP 1990; Kennish and Ruppel 1996; Hauge 1993; Horwitz et al.
1995).
Health advisories have been issued and are in effect, based upon this comprehensive monitoring
program (Ruppel et al. 1994; NJ Fish and Wildlife Digest 2000). Different advisories are
specified for high risk individuals (including children and women of reproductive age) and the
general population. For example, based on organic contaminants, there are statewide advisories
for American eel (Anguilla rostrata) and bluefish (Pomatomus saltatrix) over six pounds. The
advisories recommend no consumption by high risk individuals and limited consumption (no
more than once per week) for the general population. There are also local advisories based on
contamination in individual drainages or waterbodies. For example, based on chlordane
contamination, no consumption of fish or crustaceans from the Camden area is recommended.
Other advisories include the restricted consumption of:
& striped bass (Morone saxatilis) in the Newark Bay area, the Raritan Bay area, the
Hudson River, Northern coastal waters, and the Delaware River, Estuary and Bay;
& blue crab (Callinectes sapidus) from the Hudson River and Raritan Bay;
& white perch (Morone americana) and white catfish (Ameiurus catus) from Newark Bay
area and parts of the Delaware River, Estuary and Bay;
& all finfish from the Delaware River between the Delaware/Pennsylvania border and the
C and D Canal.
Restricted consumption of some predatory fish (mainly largemouth bass Micropterus salmoides
and chain pickerel Esox niger) is recommended in fresh waters of the state based on mercury
contamination. Consumption advisories are also in place for adjacent states in some adjoining
waterways (e.g., the State of Delaware for the Delaware River), based on organic contaminants.
The most recent monitoring for organic contaminants (e.g., PCBs, DDT and its metabolites, and
chlordanes) throughout the state and for mercury in coastal fish was in 1991. Significant changes
in fish body burdens could have occurred due to environmental cleanup, pollution prevention
programs, chemical degradation of contaminants, or changes in the bioavailability of
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contaminants. To provide current information on concentrations of contaminants, a new study
was implemented to analyze concentrations of PCBs, selected pesticides and mercury in fish
species from areas under the current advisory and from selected areas with little or no current
information. Fish were collected in 1998-1999 for this study. These data will be used to
determine geographic and temporal variation of these compounds and to assess the human health
risk and suitability for human consumption. The individual data from this study were reported to
the State of New Jersey in July 2000. This report provides a summary of the current data with
respect to spatial trends and differences among species, comparisons with results of previous
New Jersey monitoring studies, and documentation of methods and quality assurance/quality
control procedures.
The study design for the 1998-1999 monitoring is shown in Table 1, and sampling locations are
shown in Figure 1. Analyses are based on individual fillet samples. Analyses focused on:
• striped bass and bluefish; bioaccumulation of some contaminants may be important for
these large, predatory fish because of their longevity and trophic position;
• eels; bioaccumulation of contaminants can be important for eels, because of their high
lipid content and diet, which includes benthic prey items;
• a range of freshwater fish species from the Camden area, which has been identified as
an area of chlordane bioaccumulation in previous studies; species analyzed included
benthic species (carp and bullheads), top predators (largemouth bass), important
recreational species (sunfishes), and species with high lipid content (carp);
• a range of freshwater fish species from the Raritan-Passaic drainage, which has been
identified as an area of concern for several contaminants in previous studies; analyses
included a variety of freshwater fish from the river and several coastal species from the
estuary;
• several specimens of snapping turtles were analyzed from different parts of the state.
Bioaccumulation of mercury or other contaminants was identified as a potential issue in
previous studies (ANSP 1994; Horwitz et al. 1995), and snapping turtles have been
used for contaminant monitoring in other states (Bryan et al. 1987; Bonin et al. 1995).
Snapping turtles are harvested for human consumption, so monitoring for possible
human health risks is important.
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Table 1. Study design for the 1998-1999 NJ Monitoring study.
Region Station
Short
AOC
AON
AOS
Cam
Cam
Cam
Cam
Cam
Cam
Cam
DB
DBtr
DBtr
DBtr
DR
DR
DR
DR
NCtr
NCtr
NCtr
PBtr
PBtr
PBtr
Rar
Rar
Rar
Rar
Rar
Rar
TOTAL
AOC
AON
AOS
CRE
CRE*
CRL
NEW
PNR
PNR
STB
STB
STL
DBL
CHR
MAS
MRR
DRD
DRTA
DRTB
RC
NVR
SBR
SKR
CBB
MLR
TR
POMP
PRE
PRP
RBM
RBU
RRL
Waterbody
Atlantic Ocean
Atlantic Ocean
Atlantic Ocean
Cooper River
Cooper River
Cooper River
Newton Lake
Pennsauken River
Pennsauken River
Strawbridge Ponds
Strawbridge Ponds
Stewart Lake
Delaware Bay
Cohansey River
Maskells Mill Lake
Maurice River
Delaware River
Delaware River
Delaware River
Raccoon Creek
Navesink River
Shrewsbury River
Shark River
Cranberry bog
Mullica River
Toms River
Pompton Lake
Passaic River
Passaic River
Raritan Bay
Raritan Bay
Raritan Bay
THE ACADEMY OF NATURAL SCIENCES
Location
Asbury park to Atlantic City
North of Asbury Park
Atlantic City to Cape May
at and just below Evans Pond
"Hopkins Pond"
Cooper River Lake
Forked Landing
Forked Landing
Salem to Cape May
Greenwich and mouth
Amer. Striped Blue- White Catfish Catfish Com- Largeeel
bass
fish perch
species mon mouth
carp
bass
7
9
10
9
6
8
3
Amneb 5
2
Amneb
3
Amneb 5
3
3
Amneb 5
3
1
1
Amneb 5
3
4
Amcat
4
Amneb 5
3
1
Icpun
3
Amneb 5
3
10
5
5
Sunfish Sunfish Black
species crappie
Snapping
turtle
2
Lemac
3
3
1
2
2
Lemac
Lemac
Lemac
Legib
Lemac
1
1
2
Lemac
1
1
1
1
Mauricetown, Port Norris
National Park to Deepwater
Above Trenton
Trenton to just above National Park
5
6
6
5
8
3
7
6
2
4
7
1
Estuary
Estuary
Estuary
near Vincentown
Below dam at Batsto to Green Bank 6
Toms River
6
1
1
Elmwood Park
Pompton
At Rt. 1
Raritan Bay upper
Raritan River lower
4
4
5
72
52
4
6
41
3
3
Amneb
5
1
Amnat
3
8
28
0
6
4
3
3
3
3
Leaur
Leaur
40
21
21
0
2
6
TOTAL
16
19
14
10
2
14
14
12
6
16
1
15
15
5
1
5
8
10
12
9
3
7
6
1
6
6
1
19
10
10
9
9
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Sampling Regions
41
Lower Hudson
River (HR)
Raritan-Passaic (Rar)
40.5
North Coast
Tribs (NCtr)
Delaware River
and Tribs (DR)
Atlantic Ocean
North (AON)
Camden Area (Cam)
40
Pine Barrens
Tributaries (PBtr)
Atlantic Ocean
Central (AOC)
39.5
Delaware Bay
Tributaries (DBtr)
Atlantic Ocean
South (AOS)
Delaware
Bay (DB)
39
-75.5
-75
-74.5
-74
Figure 1. Sampling locations for the NJ Monitoring Study.
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METHODS
Collections
Fish were collected by a variety of methods, as appropriate for the species and sampling
locations. Boat electro-shocking was done in most of the freshwater sampling sites, including
the Delaware River (for striped bass) and small lakes, ponds, impoundments and streams (for a
variety of species, such as carp, bass, bullheads and eels). Baited traps and eel pots were used in
a number of sites to collect eels and/or bullheads. Angling was done at the Atlantic Ocean sites
to collect striped bass and bluefish, and in a few other sites. Gill nets were used in some
freshwater ponds (e.g., Strawbridge Lakes) to collect a variety of species. In addition, some
striped bass and bluefish were obtained from gill net catches of commercial fishermen and the
New Jersey Department of Fish and Game. Snapping turtles were collected in hoop nets or by
hand. Most specimens were obtained by staff of the Academy of Natural Sciences and/or New
Jersey Department of Fish and Game. Some specimens were obtained from other researchers,
commercial fishermen or anglers, where adequate sample handling (fish not gutted or filleted,
held on ice, etc.) and documentation (place of capture) was assured.
Sample Handling and Preparation
Specimens were placed on ice as soon after capture as practical. Specimens were held in metal
containers (typically stainless steel) until processing. Within 24 h of capture (usually less),
specimens were wrapped in muffled aluminum foil sealed with freezer tape, and placed in
freezers. Specimens were labeled with both internal and external tags. Specimens were held
frozen until thawed for sample preparation. Samples were maintained with complete sample
documentation (chain-of-custody forms, etc.) consistent with the QA/QC Plan.
Specimens were thawed prior to sample preparation. After thawing, specimens were examined
to confirm identification, sample number and to check for anomalies, parasites, etc. Specimens
were weighed (g) and measured (total length, cm). Fillet samples were taken with the skin
removed. For snapping turtles, leg meat was dissected. The entire sample (fillet, pair of fillets, or
turtle leg meat ) was homogenized and the homogenate was split for the required analyses.
Utensils and plates on which samples were processed were cleaned prior to use and between
preparation of separate samples.
Chemical Analyses
Mercury
Strong acid digestions were performed using 10 ml nitric acid on approximately 1 g
homogenized wet fish material in a CEM MDS 2100 microwave digestion system. Mercury
analysis was subsequently accomplished on a Perkin Elmer Fimms 400 Cold Vapor AA.
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Calibration blanks, inter-calibration verification samples, and instrument duplicates were
analyzed to ensure instrument performance and accuracy. Quality assurance/quality control
results are presented in Appendix I.
Polychlorinated Biphenyls and Organochlorine Pesticides
Homogenized fish samples were stored frozen until extraction. Samples were thawed and 2 g of
the homogenate was subsampled using a stainless steel spatula. An additional 2- to 5-g
subsample was taken for moisture analysis. Approximately 30 g of Na2SO4 (previously extracted
with hexane using a Soxhlet extractor and dried) was added to the sub-sample to eliminate water.
The dried sample was placed in a glass thimble and extracted using a Soxhlet extractor with
approximately 200 ml dichloromethane (DCM) for a minimum of 18 hours. The extracts were
sub-sampled for gravimetric lipid determination. For this, a known volume of extract was
transferred to a pre-weighed aluminum pan. The solvent was evaporated at 110(C for at least
24 h. The residue remaining (lipid) was weighed and percent lipid was calculated.
Lipids were removed from sample extracts by gel permeation chromatography (GPC) using
DCM as the mobile phase. The collected fraction containing analytes was concentrated by rotoevaporation and a N2 stream. Solid-liquid chromatography using florisil was done as an
additional clean-up step. Using this technique, PCBs (as well as heptachlor, nonachlors, and
DDEs) were eluted from the chromatographic column containing Florisil using petroleum ether
(F1 fraction). The remaining organochlorine pesticides were eluted using 50:50 petroleum ether
and dichloromethane (F2 fraction).
Congener-specific PCBs and organochlorine pesticides (Table 2) were analyzed using a Hewlett
Packard 5890 gas chromatograph equipped with a 63Ni electron capture detector and a 5%
phenylmethyl silicon capillary column. The identification and quantification of PCB congeners
followed the ‘610 Method’ (Mullin, 1985) in which the identities and concentrations of each
congener in a mixed Aroclor standard (25:18:18 mixture of Aroclors 1232, 1248 and 1262) were
determined by calibration with individual PCB congener standards. Congener identities in the
sample extracts were based on their chromatographic retention times relative to the internal
standards added. In cases where two or more congeners could not be chromatographically
resolved, the combined concentrations were reported (Table 2). Organochlorine pesticides
(OCPs) were identified and quantified based on comparisons (retention times and peak areas)
with a known calibration standard prepared from individual compounds. A detailed description
of the quality assurance/control procedures and results appears in Appendix I.
Data Reporting
Data are reported as quantified concentrations (typically ng/g wet weight) of single compounds
or as groups of compounds. Unquantifiable data require decisions on data handling. There were
three classes of non-quantifiable data:
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 2. List of target organic analytes for the 1998-1999 NJ Monitoring study.
Organochlorine Pesticides
Polychlorinated Biphenyls*
BHC (alpha, beta, gamma, delta)
1
40
137,176
Heptachlor
3
100
163,138
4,10
63
158
7
74
129,178
6
70,76
187,182
8,5
66,95
183
14
91
128
19
56,60
185
12,13
101
174
Aldrin
18
99
177
Endosulfan I and II
17
83
202,171
Endrin
24,27
97
172,197
Oxychlordane
16,32
81,87
180
29
85
193
26
136
191
25
77,110
199
31,28
82
170,190
33,21,53
151
198
22
134,144
201
45
107
203,196
46
149
189
52
118
208,195
49
134
207
48,47
131
194
44
146
205
37,42
132,153,105
206
41,71
141
209
Heptachlor Epoxide
Chlordanes (gamma and alpha)
#
Nonachlors (cis and trans)
Dieldrin
DDDs (o,p and p,p)
+
DDEs (o,p and p,p)
DDTs (o,p and p,p)
64
*
PCB congeners appearing as pairs or triplets were coeluted and reported as sum.
+ o,p-DDE coelutes with PCB congeners 92,85
#
Evidence for PCB coelution with cis-nonachlor
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
1) Non-detect (ND), i.e., there was no evidence of the substance being present.
2) Below detection limit (BDL), i.e., a signal for the substance was detected, but the
concentration was below the detection limit, which is defined to provide a high level of
confidence that the signal reflects actual presence.
3) Unquantifiable (UQ); for a few data, the signal indicated interference, etc. Thus, while a
signal was detected, it is not considered to represent presence of the contaminant.
There are several ways of handling these data in calculating totals for groups of contaminants
(e.g., total PCBs from the sum of congeners; sum of BHC components). For this report, four
methods have been used for handling these non-quantifiable data:
1) Min. All three classes (ND, BDL and UQ) are set to 0.
2) Mid. ND and UQ are set to 0, and BDL is set to one-half the detection limit.
3) Max. ND and BDL are set equal to the detection limit. UQ is treated as 0 concentration.
4) Reg. FDA action levels (see below) typically specify how low concentrations are to be
handled. Exceedances are based on the specified methods.
Methods 1) and 3) are expected to underestimate and overestimate total concentrations,
respectively. They are used here to bracket estimates. Method 2) (mid) may either underestimate
or overestimate concentrations depending on the distribution of concentrations, but this bias will
only be important for very low concentrations of contaminants. In general, the patterns of
concentrations among species, sites, etc. are very similar for the three methods. While precise
values may vary among the methods, these differences only vary by a few per cent at the most.
Detection limits are low relative to action levels, so that conclusions about exceedances of
regulatory thresholds are not sensitive to the method used. Similarly, conclusions about spatial
patterns of groups of contaminants (e.g., chlordanes, PCBs, DDT and metabolites) are not
affected by the method used, since individual components (individual congeners, etc.) were well
above detection limits for virtually all specimens. Therefore, if not specifically stated, the “mid”
method is most frequently used to report concentrations in this report.
Six compounds comprise DDT and its metabolites (o,p’ DDT and p,p’ DDT, o,p’ DDE, p,p’
DDE, o,p’ DDD and p,p’ DDD). The sum of the concentrations of these six compounds (termed
total DDX) was used as an indicator of DDX contamination. However, there was coelution of
other contaminants (probably some PCBs) with both o,p’ DDT and o,p’ DDE. Consequently, the
concentrations of these two analytes were overestimated. Moreover, the sum of all quantified
forms (“total DDX” concentrations) should also be considered to be overestimated. To provide a
more reliable value of DDX, this report includes the sum of the remaining DDX conformations
which did not undergo analytical coelution with other matrix components. Only the min estimate
of this sum (called pos min DDX) is presented. For risk assessment, total DDX may be more
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appropriate, while pos min DDX may be more appropriate when detecting spatial patterns in
DDX occurrences unaffected by other contaminants.
Two measures of chlordanes were used in this report. The sum of cis- and trans- chlordanes
(called cis/trans chlordane) was used for temporal comparisons because these were used in
previous studies (e.g., Kennish and Ruppel 1997). For regulatory assessment, concentrations of
cis- and trans-nonachlor, and oxychlordane were included as well (this sum is termed “total
chlordanes”). Note that chlordenes were not quantified in this study and subsequently cannot be
included in this total. Chlordenes are expected to be a relatively small component of total
chlordanes.
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RESULTS
Overview of Data Set
The resulting contaminant concentrations for each sample (expressed in wet weight), in addition
to the other acquired data such as lipid content, weight, length, etc., appear in Appendix II.
Because of the enormous amount of information contained in this data set, an attempt to reduce
its complexity was made.
Samples were first sorted by station and assigned an abbreviation and code (Table 3), facilitating
an easier description of the results. Samples were then sorted according to species within each of
these collection stations. Throughout the entire monitoring effort, a total of 15 different species
were collected from a total of ten stations. The total number of individuals caught at each station
are summarized in Table 4.
Table 3.
Groupings of stations used to summarize spatial patterns in contaminants.
Region
Atlantic Ocean
Central
Abbrev Code Station
Station Name
AOC C
AOC Atlantic Ocean, Asbury Park to
Atlantic City
Specific Locations
Island Beach State Park
Atlantic Ocean
north
AON
N
AON
Atlantic Ocean, North of Asbury
Park
Near Sandy Hook
Near Belmar
Atlantic Ocean
south
AOS
S
AOS
Atlantic Ocean, Atlantic City to
Cape May
At and near Cape May rips
Out of Wildwood Crest
Delaware Bay
tributaries
DBtr
M
MRR
CHR
MAS
Camden area
Cam
Maurice River
Cohansey River
Maskells Mill Lake
Mauricetown, Port Norris
Near Greenwich
E
CRE
Cooper River at and just below
Evans Pond
CRE* Cooper River: Hopkins Pond
CRL Cooper River Lake
NEW Newton Lake
PNR Pennsauken River
STL
Stewart Lake
STB
Strawbridge Ponds
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Forked Landing
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 3 (continued). Groupings of stations used to summarize spatial patterns in contaminants.
Region
Delaware Bay
Abbrev Code Station
Station Name
DB
B
DBL Delaware Bay, Salem to Cape
May
Specific Locations
Reeds Beach
Bowers Beach
Below Reedy Island
Below Dennis Creek
Delaware River
and tribs
DR
R
DRTB Delaware River, Trenton to
National Park
Trenton
At Crosswick Creek
At Philadelphia/Camden
At Paulsboro
DRTA Delaware River, Above Trenton
Near Easton
Near Raubsville
RC
DRD
Hudson River
HR
U
North coast
tributaries
NCtr
H
Pine Barrens
tributaries
Raritan-Passaic
area
PBtr
Rar
Raccoon Creek
Delaware River, Deepwater to
National Park
HR
Hudson River, Lower
Near Fort Mifflin
Below National Park
Pennsville
No samples in 1998-1999 program
SBR
NVR
SKR
Shrewsbury River
Navesink River
Shark River
Estuary
Estuary, At Red Bank
Estuary
TR
MLR
Toms River
Mullica River
Toms River
below dam at Batsto, Green Bank,
New Gretna
CBB
Cranberry Bog near Vincentown
PRP
PRE
POMP
RBU
RBM
RBL
RRL
Passaic River at Pompton
Passaic River at Elmwood Park
Pompton Lake
Raritan Bay
Raritan Bay
Raritan Bay
Raritan River lower
P
A
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At Perth Amboy
At Route 1
At Union Beach
At Route 35
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 4.
Number of species collected for PCBs, OCPs and Hg or all three combined.
Location: AOC
Analytes: ALL
Common Name
American eel
black crappie
bluefish
bluegill
brown bullhead
channel catfish
common carp
common snapping turtle
largemouth bass
pumpkinseed
redbreast sunfish
striped bass
white catfish
white perch
yellow bullhead
8
7
AON
ALL
9
9a
AOS
ALL
Cam
PCBs
and
OCPs
DB
ALL
Hg
1
2
1
1
13
19
1
30
3
15
2
3
3
0
10
3
6
3
8
DBtr DR NCtr PBtr Rar
ALL ALL ALL ALL ALL TOTAL TOTAL TOTAL
10
25
16c
11d
5
6b
10
3
1
10
4
8
1
14
10
2
6
6
5
4
8
1e
71
2
40
13
19
1
30
7
21
2
6
51
8
8
1
71
40
13
19
1
30
7
21
2
6
50
8
8
1
69
1
40
3
6
0
20
7
12
3
6
52
4
8
0
a
9 specimens for PCBs and OCPs; 10 specimens for Hg.
6 specimens for PCBs and Hg; 5 specimens for OCPs.
c
16 specimens for PCBs and OCPs; 15 specimens for Hg.
d
11 specimens for PCBs and OCPs; 10 specimens for Hg.
e
1 specimen for PCBs and OCPs; 0 specimens for Hg.
b
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Ranges and Means
To further facilitate easy recognition of regions and species of concern, means of contaminant
concentrations were calculated for each species in each of the designated collection areas of
Table 3. The following sub-sections summarize these observations according to analyte.
Mercury
For American eels, striped bass and bluefish, mean mercury concentrations ranged from 0.15
)g/g (eels from North coastal tributaries) to 0.72 )g/g (striped bass from the Atlantic Ocean in
the southern part of the state) (Table 5). Mercury concentrations in American eels were not well
related to length (Figure 2). Moreover, lipid content was not well correlated to mercury
concentrations (Figure 3). Highest mercury concentrations were in eels from the Pine Barrens
tributaries of the Mullica and Tom’s River. Length was well related to mercury concentration for
bluefish, with a number of exceptions from fish caught in Raritan and Delaware Bays that had
higher concentrations than expected based on length (Figure 4). For striped bass, concentrations
showed more scatter when compared to length, though a relationship was discernable (Fig. 5).
For the remaining fish species, mean mercury concentrations ranged from 0.02 (Camden brown
bullheads) to 0.44 (Raritan largemouth bass) (Table 5).
PCBs
Mean PCB concentrations in fish tissue ranged from 26 ng/g (Raritan yellow bullheads) to 1006
ng/g (Raritan American eels) (Table 6). Common carp from Raritan Bay and American eels
from Delaware Bay also had high mean concentrations (978 and 921 ng/g, respectively).
Snapping turtles from four sites had the lowest mean PCB concentrations (< 35 ng/g). For
American eels and striped bass, PCB concentrations increased with increasing length and lipid
(Figs. 6 and 7). In general, American eels from the Delaware River and its tributaries, and from
Raritan Bay, had higher concentrations than those collected elsewhere. Upon lipid normalization
of PCB concentrations, a substantial number of eels from Raritan Bay had elevated levels of
PCBs which could not be explained by their lipid content or length (Fig. 8). This suggests that
these eels may be utilizing habitats that contain elevated levels of PCBs. In these more
contaminated areas, proximity to contamination (or habitat use) may play a larger role in
determining PCB body burdens as opposed to such factors as lipid content and length.
Highest PCB concentrations in striped bass were observed in fish from the north and south coasts
of New Jersey and Delaware Bay/River. Upon lipid normalization of t-PCB concentrations (Fig.
9), striped bass from Raritan Bay still had levels of PCBs that were higher than expected based
on lipid content and length. For bluefish, PCB concentrations increased with lipid content (Fig.
10), however, the trend was not as pronounced as with other species because bluefish lipid
content varied less widely. There was no discernable difference in concentrations among stations
for bluefish. Furthermore, concentration was not clearly related to length, and differences in
concentration may reflect annual variations in habitat use. Skinny, large fish were probably postspawners and depuration of PCBs may take place during spawning.
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Table 5. Mean Hg concentrations (ng/g wet weight) for each species, by region.
Common Name
striped bass
bluefish
American eel
black crappie
bluegill
brown bullhead
chain pickerel
common carp
common snapping turtle
largemouth bass
pumpkinseed
redbreast sunfish
white catfish
white perch
AOC
0.37
0.43
THE ACADEMY OF NATURAL SCIENCES
AON
0.33
0.46
AOS
0.72
0.57
Cam
DB
0.35
0.42
0.30
0.10
0.03
0.02
DBtr
DR
0.33
NCtr
0.20
0.17
0.15
NW
PBtr
0.45
Rar
0.21
0.20
0.21
0.08
0.31
0.03
0.10
0.17
0.16
0.37
0.22
0.21
0.43
0.44
0.25
0.04
0.2
14
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
American Eel
1.0
0.9
0.8
MLR
0.7
MLR
Tot Hg (ug/g)
0.6
TR
DRTA
MLR
0.5
TR
MLR
SKR
DRD
0.4
TR
0.3
PNR
MLR
TR
0.2
MRR
MRR
DRD
0.1
RBM
NVR
NVR
RC
SKR RCRC
SBR
DRTA
MLR
SKR
CHR
MRR
CHR
DRD
PRE
CHR
SKR
CHR
PRE
DRTA
SKR
DRTB
RC
DRTB
NVR
SBR
DRD
DRTA
MRR
DRD
RC
RCSBR
CHR
SBR
SBR SBR
DRTB
RC
RBM
MRR
RBM
PRE
PRE
DRD
DRTA
SKR
RBM
RC
DRTA
DRTB
DRTB
0.0
20
30
40
50
60
70
80
90
Total Length (cm)
Figure 2. Relationship between Hg concentration ()g/g wet weight) and length (cm) for American eels.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
American Eel
1.0
0.8
Tot Hg (ug/g)
0.6
0.4
0.2
90
40
20
15
%L
10
ipid
tal
50
25
To
30
len
g th
60
(cm
70
)
80
0.0
30
5
0
20
M (Maurice and Cohansey)
R (Delaware River and tribs)
P (Mullica and Toms)
A (Raritan and Passaic)
H (North Coast tribs)
Figure 3. Relationship between Hg concentration ()g/g wet weight), lipid content (%wet weight), and
length (cm) for American eels.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Bluefish
1.0
S
0.8
N S
S
Tot Hg (ug/g)
B
S
C
0.6
B
N
A
S
0.4
N
N
N
N
C
B
B
A
A
A
0.2
C
N
CS
CN
S
C
C
C
C
N
A
A
B
S
AA
AA
0.0
20
30
40
50
60
70
80
90
100
Total Length (cm)
Figure 4. Relationship between Hg concentration ()g/g wet weight) and length (cm) for bluefish.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Striped Bass
1.0
S
0.8
S
R
C
S
B
S
Tot Hg (ug/g)
N
0.6
B
S
R
R
R
N
B
0.4
B
R
C
C
B
N
N
C
C
N
N
R
N
R
R
R
R
0.2
R
R
A
A
R
C
B
N BA
B B
A
N
A
C N
R
B
0.0
40
60
80
100
120
140
Total Length (cm)
Figure 5. Relationship between Hg concentration ()g/g wet weight) and length (cm) for striped bass.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 6. Mean total PCB (mid) (ng/g wet weight) for each species, by region.
Common Name
striped bass
bluefish
American eel
black crappie
bluegill
brown bullhead
channel catfish
common carp
common snapping turtle
largemouth bass
pumpkinseed
redbreast sunfish
white catfish
white perch
yellow bullhead
THE ACADEMY OF NATURAL SCIENCES
AOC
307
646
AON
463
562
AOS
483
657
Cam
DB
DBtr
DR
629
680
703
369
37
62
45
302
674
34
361
143
114
921
NCtr
321
PBtr
141
Rar
431
366
1006
112
13
15
978
15
123
60
146
893
26
19
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
American Eel
4000
Tot PCB mid (ng/g)
3000
2000
1000
90
40
20
15
%L
10
30
5
ipid
tal
50
25
To
30
len
gth
60
(c m
70
)
80
0
0
20
M (Cohansey and Maurice)
R (Delaware and tribs)
P (Toms and Mullica)
A (Raritan)
H (north coast tribs)
Figure 6. Relationship between PCB (mid) concentration (ng/g wet weight), lipid content (%wet weight),
and length (cm) in the American eel.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Striped Bass by Station
R
1600
1400
SS
S
0
)
120
100
80
ta
8
140
m
200
(c
400
h
N
600
gt
800
N
R
RB
CA
S
B
RR
BN
B
B
S RN N
N
B
A
CB
NC
B
R NA
BC
R
R
C BNCN S
R R
R
C
en
R
lL
1000
6
% Lip
60
4
2
id
0
To
Tot PCB mid (ng/g)
1200
40
Figure 7. Relationship between total PCB concentration (ng/g wet weight), lipid content (%) and total
length (cm) in striped bass.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
American Eel
600x103
R
500x103
Tot PCBmid/Lipid
400x103
300x103
200x103
R
100x103
P
R
P
R
R
AP
0
20
30
R
R
A
R
R
RH
A
R A A AH R R R
H
R
M
RP
HM
RRMHM
MR
M P H RP PAM
MA
P HH H R M HMH
R
40
50
HP
H
60
R
H
P RP
70
R
RH
80
90
Total Length (cm)
Figure 8. Relationship between total lipid normalized PCB (mid) concentration (ng/g wet weight) and
total length (cm) in the American eel.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Striped Bass
200x103
180x103
R
160x103
Tot PCB mid/Lipid
140x103
120x103
R
100x103
80x103
R
A
60x103
40x103
A
R
20x103
R A
R
0
40
60
N
R R
R
R
R
B
C
A
RC
B
B
R S
S
C
N
N NR
AC C BBB
N
NB
N
80
S
N
S
N
C SB
B
100
S
120
140
Total Length (cm)
Figure 9. Relationship between total lipid normalized PCB (mid) concentration (ng/g wet weight) and
total length (cm) in striped bass.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Bluefish
1400
1200
)
TotPCB mid (ng/g
N
C
S
C
1000
CC
800
C
C
S
SS
B
B
N
B
N
SS
C
A CC
A
N
A
N
S N
NN
SA
100
N
BA
90
A
80
)
A
A
m
70
(c
th
B
60
ng
600
A
400
200
0
25
20
15
% 10
Lip
id
50
40
5
0
30
To
Le
l
ta
20
Figure 10. Relationship between total PCB (mid) concentration (ng/g wet weight), lipid content (%), and
total length (cm) in bluefish.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Organochlorine Pesticides
The concentrations of most pesticides of concern (aldrin, dieldrin, chlordanes, nonachlor, DDXs,
heptachlor and heptachlor epoxide), that is, those having associated action limits for fish
consumption, were above detectable limits (Table 7). The exception was aldrin (and to a lesser
degree lindane), which was rarely detected above detection limits.
In general, concentrations of heptachlor and heptachlor epoxide were low. Mean heptachlor and
heptachlor epoxide concentrations in fish species ranged from 0.02 ng/g (eels from the Delaware
Bay at Trenton) to 3.62 ng/g (white perch from the Raritan region) and 0.27 ng/g (Raritan yellow
bullheads) to 10.72 ng/g (Raritan eels), respectively (Tables 8 and 9). Mean dieldrin
concentrations ranged from 1.27 ng/g (north Atlantic Ocean striped bass) to 59.62 ng/g (Camden
common carp) (Table 10). Snapping turtles had very low concentrations of these contaminants.
Mean chlordane values were calculated based on the FDA method which includes other forms of
the pesticide (cis- and trans-nonachlor, oxychlodane) (Table 11) and a method which only reports
the sum of the cis- and trans- forms of chlordane (Table 12). Mean values for ‘chlordane’ varied
widely depending on the method of calculation (2 to 10 times larger for FDA method vs. simpler
reporting method). Because the FDA method is helpful in evaluating exceedances of
consumption guidelines, a discussion using this method follows. Mean total chlordane
concentrations ranged from 3.66 ng/g (Raritan yellow bullheads) to 223.03 ng/g (Camden
common carp) (Table 11). Chlordane concentrations were somewhat positively related to lipid
(Fig. 11). In general, higher concentrations were found in common carp and in some American
eels, striped bass, and white perch. Higher concentrations were predominantly from Camden
stream and ponds; moderate values were from Raritan and Delaware rivers.
The mean concentration of DDXs (the sum of all quantifiable DDTs, DDEs and DDDs) in fish
species ranged from 12 ng/g (Raritan yellow bullheads) to 785 ng/g (Camden common carp)
(Table 13) using the ‘max’ method whereby NDs and BDLs (see Data Reporting section) are set
equal to the detection limit. Of all analyzed species, common carp from the Camden area had the
highest mean concentrations of those organochlorine pesticides of concern. There was a weak
relationship between DDX concentrations and length/lipid. Higher concentrations were found in
common carp, American eels and white perch and in Camden, Raritan and Delaware fish.
Mean “mid” BHC concentrations (the sum of alpha, beta, gamma BHCs, and lindane) ranged
from 0.43 ng/g (Delaware Bay tributaries snapping turtles) to 32.49 ng/g (Camden common carp)
(Table 14). There was a weak positive relationship with lipid content. In general, BHC
concentrations were higher in common carp, American eels and white perch, and in those fish
from Camden ponds, Raritan Bay and Delaware Bay.
Concentrations of endosulfan I, endosulfan II and endrin were very low in most fish, often only
an order of magnitude above the detection limits. For the entire data set, mean concentrations of
the three contaminants were 2.5, 2.8 and 1.0 ng/g (Appendix II).
THE ACADEMY OF NATURAL SCIENCES
25
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 7.
Region
Short
AOC
AOC
AON
AON
AOS
AOS
Cam
Cam
Cam
Cam
Cam
Cam
Cam
Cam
Cam
Cam
DB
DB
DBtr
DBtr
DR
DR
NCtr
PBtr
PBtr
Rar
Rar
Rar
Rar
Rar
Rar
Rar
Rar
Rar
Rar
Total number of individual samples of each species analyzed and the number of those above
analytical detection limits for organochlorine pesticides.
Common Name
bluefish
striped bass
bluefish
striped bass
bluefish
striped bass
American eel
black crappie
bluegill
brown bullhead
channel catfish
common carp
common snapping
turtle
largemouth bass
pumpkinseed
white catfish
bluefish
striped bass
American eel
common snapping
turtle
American eel
striped bass
American eel
American eel
common snapping
turtle
American eel
bluefish
brown bullhead
common carp
common snapping
turtle
largemouth bass
redbreast sunfish
striped bass
white perch
yellow bullhead
Total
Anal.
BHC
Aldrin
Dieldrin Chlordane
Nona- DDxAll DDXchlor
pos
Hepta- Heptachlor
chlor
epoxide
7
8
6
7
8
7
9
9
8
7
5
4
1
1
2
1
12
5
19
17
1
1
30
30
3
3
8
7
9
9
8
6
1
2
13
19
1
30
3
8
6
8
9
8
5
1
0
9
15
1
30
2
1
0
1
1
1
0
0
0
0
1
0
0
0
8
6
9
9
8
5
1
2
12
19
1
30
3
8
7
9
9
8
5
1
2
12
19
1
30
0
8
7
9
9
8
5
1
2
13
19
1
30
3
8
7
9
9
8
5
1
2
12
19
1
30
3
8
7
9
9
8
5
1
2
12
19
1
30
2
15
2
4
5
10
10
1
15
2
4
5
10
8
0
1
0
0
0
0
0
0
15
2
4
5
10
10
1
15
2
4
5
10
10
0
15
2
4
5
10
9
0
15
2
4
5
10
10
0
15
2
4
5
10
10
0
15
2
4
5
10
10
0
12
2
3
4
10
1
0
25
14
16
11
1
22
13
16
8
1
2
0
0
0
1
25
14
16
11
1
25
14
16
10
0
25
14
15
11
0
25
14
16
11
1
25
14
16
11
1
25
14
16
11
0
22
14
13
6
1
8
10
3
10
2
8
10
2
10
2
7
2
0
3
0
8
10
3
10
2
8
10
3
10
2
8
10
3
10
2
8
10
3
10
2
8
10
3
10
2
8
10
3
10
2
8
10
1
10
0
6
6
5
8
1
6
5
5
8
1
0
0
0
2
0
6
6
5
8
1
6
6
5
8
1
6
6
5
8
1
6
6
5
8
1
6
6
5
8
1
6
6
5
8
1
5
4
5
8
0
THE ACADEMY OF NATURAL SCIENCES
26
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 8. Mean heptachlor concentrations (ng/g wet weight) for each species, by region.
Common Name
striped bass
bluefish
American eel
black crappie
bluegill
brown bullhead
channel catfish
common carp
common snapping
turtle
largemouth bass
pumpkinseed
redbreast sunfish
white catfish
white perch
yellow bullhead
AOC
0.41
0.56
AON
0.79
0.35
AOS
0.71
0.57
Cam
DB
1.09
0.49
0.21
0.26
0.13
0.33
1.37
2.49
0.41
DBtr
DR
1.70
NCtr
PBtr
0.02
0.51
0.37
0.22
Rar
1.08
0.60
1.46
0.18
0.00
0.42
0.75
0.23
2.49
0.00
0.28
0.07
0.29
3.62
0.04
Table 9. Mean heptachlor epoxide concentrations (ng/g wet weight) for each species, by region.
Common Name
striped bass
bluefish
American eel
black crappie
bluegill
brown bullhead
channel catfish
common carp
common snapping
turtle
largemouth bass
pumpkinseed
redbreast sunfish
white catfish
white perch
yellow bullhead
AOC
0.53
0.92
AON
0.94
0.49
THE ACADEMY OF NATURAL SCIENCES
AOS
0.85
0.90
Cam
3.96
0.37
0.61
1.16
2.89
6.97
1.81
1.95
1.02
DB
0.95
0.51
DBtr
DR
2.21
NCtr
PBtr
1.35
3.35
5.03
4.21
Rar
2.56
0.57
10.72
1.52
0.06
0.06
6.25
0.11
1.14
0.84
1.25
3.43
0.27
27
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 10. Mean dieldrin concentrations (ng/g wet weight) for each species, by region.
Common Name
AOC AON
AOS
Cam
striped bass
1.27
7.69
5.08
bluefish
11.37
6.33 12.05
American eel
23.90
black crappie
2.54
bluegill
4.75
brown bullhead
5.92
channel catfish
14.28
common carp
59.62
common snapping turtle
2.93
largemouth bass
20.50
pumpkinseed
7.38
redbreast sunfish
white catfish
7.84
white perch
yellow bullhead
DB
DBtr
5.99
2.61
7.58
DR
NCtr
18.14
32.11
10.27
PBtr
15.19
Rar
11.00
4.28
45.73
4.33
0.18
0.20
17.39
1.20
3.11
1.66
14.91
1.98
Table11. Mean total chlordane concentrations, including cis and trans nonachlor and oxychlordane
(ng/g wet weight), for each species, by region.
Common Name
AOC AON
AOS
Cam
American eel
62.54
black crappie
7.90
bluefish
48.20 38.34 44.56
bluegill
20.86
brown bullhead
27.14
channel catfish
70.43
common carp
223.03
common snapping turtle
4.59
largemouth bass
54.52
pumpkinseed
17.58
redbreast sunfish
striped bass
21.53 26.54 33.30
white catfish
22.35
white perch
yellow bullhead
THE ACADEMY OF NATURAL SCIENCES
28
DB
DBtr
10.11
DR
NCtr PBtr
Rar
84.24 52.66 40.73 131.63
51.14
24.27
32.48
0.00
48.74
0.00
50.14
168.20
3.60
18.62
11.60
26.18
77.06
3.66
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 12. Mean total chlordane (cis and trans chlordane only - min values) (ng/g wet weight) for each
species, by region.
Common Name
AOC AON
AOS
Cam
American eel
14.69
black crappie
1.89
bluefish
13.45
6.58 10.10
bluegill
2.18
brown bullhead
14.49
channel catfish
26.61
common carp
110.66
common snapping turtle
0.00
largemouth bass
19.19
pumpkinseed
5.27
redbreast sunfish
striped bass
1.97
8.41
9.34
white catfish
10.56
white perch
yellow bullhead
THE ACADEMY OF NATURAL SCIENCES
29
DB
DBtr
3.54
DR
NCtr PBtr
18.47 16.53 20.59
5.56
Rar
63.09
8.05
15.22
0.00
8.26
0.00
15.62
55.49
0.68
6.42
2.60
13.70
43.81
1.45
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
All Species: C=carp; E=American eel; R=striped bass; B=bluefish; L=largemouth bass;
S=pumpkinseed; R=redbreast sunfish; P=white perch; W=white catfish; X=black crappie)
700
C
Total Chlordanes, including Nonachlor (ng/g)
600
500
C
C
C
400
C
E
E
C
300
C
C
CC
E
C
C
C
200
R
E
C
E
C
CC
C
C
C
P
CE
C C
C
S L
E
C
C
C
C
RC BRE
R
E
C
R
P
H
E
C
LC
PECCP
B
P B R
RC
P R
E
P
P
L EH
R
RE R
R
R
E
H
LBL CR
P
B E B
H
W
LR C
R
H
BB EEB RR
E R
LL
LEH
B
S B
LH
RW
R
H
LB
E
RL
H
BRR R
E RB R EEB R B
L
H
H
B
SRR
BB
E
R
B
R
L
S
R
BB
C
E
BE
B
H
R
R
BE
B
SH
E
W
RHS
R
SR
E
S
LE
BH ERREE R
LLS
H
EE
R
E
H
SS
H
W
S
B
E
L
R
H
H
H
E
S
S
S
EC
E
S
E
S
R
TXTE
E
S
S
TT
C
E
E
L
100
0
0
5
E
E
E
C
EB
E
E
E
EB
B
E
B
E
EB
B
R
E
E
X
E
E
B B
E
B
E
E
E
B
E S
EE
10
B
E
E
B
15
20
25
30
% Lipid
Figure 11. Relationship between sum of all chlordanes, including nonachlors (ng/g wet weight) and lipid
content (%) in all species, by location.
THE ACADEMY OF NATURAL SCIENCES
30
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 13. Mean DDX (max) concentrations (ng/g wet weight) for each species, by region.
Common Name
American eel
black crappie
bluefish
bluegill
brown bullhead
channel catfish
common carp
common snapping
turtle
largemouth bass
pumpkinseed
redbreast sunfish
striped bass
white catfish
white perch
yellow bullhead
AOC
AON
156
111
AOS
Cam
402
21
147
DB
DBtr
72
DR
NCtr
PBtr
598
160
104
101
75
42
344
785
4
92
30
3
3
198
84
51
130
162
Rar
481
249
17
26
202
18
106
339
97
386
12
Table 14. Mean total BHC (mid) concentrations (ng/g wet weight) for each species, by region.
Common Name
striped bass
bluefish
American eel
black crappie
bluegill
brown bullhead
channel catfish
common carp
common snapping turtle
largemouth bass
pumpkinseed
redbreast sunfish
white catfish
white perch
yellow bullhead
AOC AON AOS
Cam
2.17 11.99
7.41
8.94
4.47
4.64
6.70
0.82
3.52
5.58
6.01
32.49
4.53
10.36
6.90
THE ACADEMY OF NATURAL SCIENCES
DB
DBtr
7.04
2.55
2.63
DR
NCtr
7.87
9.59
16.63
PBtr
8.59
Rar
3.81
3.98
20.08
2.58
0.43
2.06
31.68
0.68
5.60
3.08
10.26
32.21
4.9
31
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Risk Assessment Based on Exceedances of FDA Action Levels
The FDA promulgates guidelines for the consumption of fish and fishery products by issuing
action limits (Table 15). The primary purpose of these limits is to represent the point at or above
which the administration will take legal action to remove products from the market. However,
they are often used as a benchmark for the minimum concentration above which ingestion is not
recommended.
Table 15. Summary of U.S. FDA’s Action Limits for mercury, PCBs and pesticides.
Compound or Class
Action Level (ppm or ng/g wet)
Caveats
Mercury
1,000
Many states have adopted lower values
(often 0.5 ppm)
Polychlorinated Biphenyls
2,000
“Tolerance Value”
Aldrin and Dieldrin
300
Chlordane
300
DDT, DDD and DDE
5,000
Heptachlor and
Heptachlor Epoxide
300
Cis- and trans-chlordane, cis- and transnonachlor, oxychlordane, alpha-, beta-,
and gamma-chlordene, and chlordene.
Levels of individual components must
be quantitated at 0.02 ppm or above and
confirmed in order to be added into the
“chlordane” total value
Individually or in combination. In
adding amounts of DDT, DDE and
DDD, do not count any of the three
found below 0.2 ppm
Individually or in combination. Do not
count heptachlor or its metabolite if
found at a level below 0.1 ppm.
Mercury
The action limit for total mercury in fish tissue is 1,000 ng/g. None of the fish or turtles analyzed
from this study exceeded this limit. The State of New Jersey has developed separate
concentration thresholds for high risk individuals and the general population. Different
advisories (do not eat, eat no more than once a week, eat no more than once a month) are set for
different concentrations. State action levels for high risk individuals vary from 0.08 mg/kg (eat
no more than once a week) to 0.54 mg/kg (do not eat). State action levels for the general
population vary from 0.34 mg/kg (eat no more than once a week) to 2.81 mg/kg (do not eat)
(Ruppel et al. 1994).
The exceedances of mercury based on these various action and consumption guidelines are
shown in Table 16.
THE ACADEMY OF NATURAL SCIENCES
32
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 16. Mercury exceedances based on various consumption guidelines and action limits.
Station
AOC
AOC
AON
AON
AOS
AOS
CHR
MAS
MRR
PNR
PNR
PNR
PNR
PNR
PNR
PNR
STB
STL
STL
STL
STL
STL
STL
DBL
DBL
DRTA
DRTA
RC
RC
NVR
SBR
SKR
MLR
TR
POMP
PRE
PRE
PRE
PRE
PRE
PRP
Common Name
bluefish
striped bass
bluefish
striped bass
bluefish
striped bass
American eel
common snapping
turtle
American eel
American eel
bluegill
common carp
common snapping
turtle
largemouth bass
pumpkinseed
white catfish
common snapping
turtle
black crappie
bluegill
brown bullhead
common carp
common snapping
turtle
largemouth bass
bluefish
striped bass
American eel
striped bass
American eel
striped bass
American eel
American eel
American eel
American eel
American eel
common snapping
turtle
American eel
brown bullhead
common carp
largemouth bass
redbreast sunfish
common carp
High Risk Population
Total
General Population
No
<1/week <1/month Do not Number
No
<1/week <1/month Do not
restr.
eat
of
restr.
eat
0.07 0.07-0.18 0.19-0.54 >0.54 Specimens 0.34 0.35-0.93 0.94-2.81 >2.81
0
0
7
2
2
7
0
0
9
0
1
5
1
4
3
0
0
7
0
0
6
3
1
8
0
0
9
0
2
7
1
5
5
0
0
10
0
1
2
5
1
7
0
0
8
0
0
0
5
0
5
0
0
5
0
1
4
0
5
0
0
0
5
0
0
1
0
0
1
0
0
1
0
0
1
5
0
3
0
0
0
0
2
1
0
0
1
0
0
0
0
0
5
1
1
5
1
5
1
1
5
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
2
4
1
1
0
0
0
1
1
0
0
0
0
0
0
3
3
4
1
3
2
4
1
0
1
0
0
0
0
0
0
0
0
0
0
0
2
3
4
1
1
0
0
1
0
0
0
0
0
0
0
0
0
0
0
1
2
3
5
1
1
2
3
5
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
1
0
1
1
0
1
0
0
1
0
1
2
1
6
0
2
5
2
0
0
0
2
3
7
2
2
1
1
0
0
4
3
3
1
0
2
2
1
1
0
0
0
0
0
2
1
0
3
5
10
6
4
8
1
3
6
6
6
4
1
3
3
5
5
1
8
1
3
6
5
2
1
0
0
2
5
1
3
0
0
0
0
1
4
3
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
2
1
0
0
0
0
1
4
0
2
0
4
0
1
1
1
4
0
0
0
2
0
0
4
3
6
3
3
4
4
3
6
1
3
3
0
0
0
2
0
1
0
0
0
0
0
0
0
0
0
0
0
0
THE ACADEMY OF NATURAL SCIENCES
33
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 16 (continued). Mercury exceedances based on various consumption guidelines and action limits.
Station
PRP
PRP
RBM
RBM
RBU
RBU
RRL
RRL
Common Name
largemouth bass
redbreast sunfish
American eel
white perch
bluefish
striped bass
bluefish
white perch
No
restr.
0.07
0
0
1
0
4
0
0
0
High Risk Population
Total
General Population
<1/week <1/month Do not Number
No
<1/week <1/month Do not
eat
of
restr.
eat
0.07-0.18 0.19-0.54 >0.54 Specimens 0.34 0.35-0.93 0.94-2.81 >2.81
0
3
0
0
3
0
0
3
0
3
0
2
1
0
0
3
0
3
0
4
0
0
0
4
4
1
0
5
0
0
0
5
0
0
0
4
0
0
0
4
1
4
0
5
0
0
0
5
0
6
0
5
1
0
0
6
1
2
0
3
0
0
0
3
PCBs
Polychlorinated biphenyls (PCBs), globally ubiquitous despite their production ban in the mid
1970s, are of particular concern due to their bioaccumulative nature. Of all the individual fish
analyzed for total PCBs, only seven exceeded the FDA limit of 2,000 ng/g (Table 17). These
individuals included several American eels and common carp from the Delaware River, its
tributaries (Racoon Creek, Pennsauken and Passaic Rivers) and Raritan Bay. A largemouth bass
from Cooper River Lake and a white perch Raritan River also exceeded the threshold.
Dieldrin and Aldrin
Aldrin and dieldrin, both chlorinated cyclodiene insecticides, were popular pesticides for
agricultural crops such as corn and cotton in the 1950s-1970. Aldrin breaks down into dieldrin in
the environment. The Environmental Protection Agency banned all uses of dieldrin and aldrin in
1974 with the exception of termite control. In 1987, the agency banned all uses. Because
dieldrin and aldrin are so closely related both in structure and toxicity, they are regulated
together. The US FDA’s action limit for aldrin and dieldrin in fish is 300 ng/g. Based on the
concentrations determined in this monitoring study, none of the collected fish or turtles exceeded
the action limit for dieldrin and aldrin (Table 17).
Chordane
In the U.S., chlordane was used as a pesticide on crops such as corn and citrus and on home
lawns and gardens from 1948 to 1988. Chlordane is comprised of pure chlordane (cis and trans
isomers) as well as many related chemicals (cis- and trans-nonachlor, oxychlordane, alpha-,
beta- and gamma-chlordene, and chlordene). The US FDA has set an action limit of 300ng/g for
chlordane in fish. Total clordane values were calculated based on the US FDA guidelines with
the exception that no chlordenes were included in the sum. Of the 10 individual fish that
exceeded the action limit for chlordane, 8 were common carp (from Cooper River, Strawbridge
THE ACADEMY OF NATURAL SCIENCES
34
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 17. Species exceeding (numbers in bold) US FDA’s action limits (PCBs, total heptachlor, chlordanes, and dieldrin + aldrin, and DDXs).
Sample
ID
F-2973
F-3084
F-3173
F-3197
F-3032
F-3225
F-2859
F-3178
F-3202
F-3049
F-2937
F-2841
F-3220
F-3221
F-2939
Serial Number Analytical
Number
NJ98-DRDEP2 F-2973
NJ98-RCEP9
F-3084
NJ98-PNRBS1
F-3173
NJ98-CRLBS1
F-3197
NJ98-RRUB4
F-3032
NJ98-PREBS1
F-3225
NJ98-RRLCRT1 F-2859
NJ98-PNRBS1
F-3178
NJ98-CRLBS1
F-3202
NJ98-CREBS1
F-3049
NJ98-STBGN5 F-2937
NJ98-PREBS1
F-2841
NJ98-NEWBS1 F-3220
NJ98-NEWBS1 F-3221
NJ98-STBGN4 F-2939
THE ACADEMY OF NATURAL SCIENCES
Common Name
American eel
American eel
common carp
largemouth bass
American eel
common carp
white perch
common carp
common carp
common carp
common carp
American eel
common carp
common carp
common carp
Water Body
Delaware River
Raccoon Creek
Pennsauken River
Cooper River Lake
Raritan Bay
Passaic River
Raritan River
Pennsauken River
Cooper River Lake
Cooper River
Strawbridge Ponds
Passaic River
Newton Lake
Newton Lake
Strawbridge Ponds
35
LTL cm TotPCB Adlrin Chlordane DDX Hept Lipid%
max
Dieldrin
Exc
Exc
Exc
3451
365
76.2
182
2572
27
18.19
2844
41.3
19
199
406
1
0.54
2777
631
62.7
202
3814
40
19.56
2682
38.6
71
140
158
2
1.05
2311
28.8
71
181
1692
30
19.57
2238
51.7
17
205
221
12
4.36
2010
27.1
28
166
901
10
6.54
393
57.6
1296
172
2016
32
11.79
481
48
1273
158
1258
30
7.84
461
52.3
1053
42
1052
16
6.06
359
64.5
866
116
1060
34
14.12
308
45.4
734
91
492
43
8.92
305
61.3
616
94
956
18
3.52
432
63
525
178
629
27
9.21
322
55.5
489
122
1522
30
0.11
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Ponds, Newton Lake, and Pennsauken River) and the remaining were American eels from the
Passaic River (Lake Dundee) and the Delaware River (near Ft. Mifflin) (Table 17).
Heptachlor and Heptachlor Epoxide
Heptachlor was used as an insecticide in the US from 1953 to 1974. The pesticide was
commonly used to control termites as well as kill insects in seed grains and on crops but nearly
all registered uses of pesticide were cancelled by 1974. Heptachlor epoxide is an oxidation
product of heptachlor formed by many organisms including humans. Based on their toxicity,
both heptachlor and heptachlor epoxide action limits in food were set by the US FDA. For fish,
the two compounds, either individually or in combination, should not exceed 300 ng/g. For this
study, concentrations for all collected species fell well below the action limit (Table 17).
DDXs
DDT (1,1,1-trichloro-2,2-bis-(p-chlorophenyl)ethane) was widely used to control insect pests on
agricultural crops and those carrying infectious diseases. Technical DDT is primarily a mixture
of three forms (p,p'-DDT, o,p'-DDT, and o,o'-DDT). In addition, DDE (1,1-dichloro-2,2-bis(pchlorophenyl)ethylene), and DDD (1,1-dichloro-2, 2-bis(p-chlorophenyl) ethane), are found in
small amounts as contaminants in technical DDT. DDD was also used to kill pests. DDT and
DDD can no longer be used as a pesticide in the United States except in cases of public health
emergency. However, its use continues in other countries. Because of its bioaccumulative
nature and toxicity, the US FDA has set an action limit for DDXs (sum of DDTs, DDEs, and
DDDs) at 5000 mg/g. Using the previously-described method of reporting DDXs (see Data
Reporting section), none of the fish evaluated in this study exceeded the action limit (Table 17).
The common carp from Pennsauken River that exceeded PCB and chlordane limits, had the
highest concentrations of DDX (3,800 ng/g) of all fish sampled.
Organochlorine Pesticides of Concern Having No Action Limits
The are no federal action limits or consumption guidelines for foods containing benzene
hexachlorides (alpha, beta, and delta BHC). Concentrations of BHCs were low except in a few
instances (Appendix II).
Lindane, another compound having no FDA fish actions limits, is used as a insecticide and
fumigant on a wide variety of crops and seeds and as a means to control insect-borne diseases.
Technical lindane is primarily comprised of the gamma isomer of hexachlorocyclohexane (HCH). Based on this study, lindane concentrations were low for most of those fish collected
(Appendix II).
Endrin has been used as a pesticide to control insects and rodents. It is no longer produced or
sold for general use in the US. To date, there are no federal action limits or consumption
THE ACADEMY OF NATURAL SCIENCES
36
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
guidelines for foods containing endrin. The concentrations of this contaminant were very low for
all samples analyzed (Appendix II).
Alpha and beta forms of endosulfan (or I and II) make up the technical form of the insecticide
endosulfan. The majority of applications of endosulfan were made to tobacco and cotton, though
it was also used to control insects on grains, tea, fruit, and vegetables. Though the pesticide has
not been produced in the US since 1982, it is still currently used on crops and is used to produce
other chemicals. In this country, there are no federal action limits or consumption guidelines for
foods containing endosulfan. The concentrations of the two forms of endosulfan were very low
in all samples analyzed (Appendix II).
THE ACADEMY OF NATURAL SCIENCES
37
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
DISCUSSION
Regions and Species of Concern
One of the main objectives of this program was to determine potential human health impacts
based on contaminant data encompassing a wide range of fish species and locations. Based on
the number, species and locations of the exceedances of US FDA action limits for PCBs and
chlordanes, the following regions of concern are designated.
1) The Camden area (Newton Lake, Strawbridge Ponds, Pennsuaken River and Cooper
River Lake) based largely on chlordane concentrations within common carp;
2) Sections of the Delaware River and its tributaries (e.g., Raccoon Creek) based on
PCB concentrations in primarily American eel;
3) Raritan Bay based on higher than average concentration of PCBs in American eels
(and white perch).
Temporal Changes in Contaminant Concentrations in NJ Fish
Previous evaluations of concentration of organic contaminants (e.g., PCBs, DDT and its
metabolites, and chlordanes) in coastal finfish were conducted in several periods between 1981
and 1991. These studies (Kennish et al. 1992; Kennish and Ruppel 1996, 1997) provide an
historical benchmark to which the data of this monitoring study may be compared.
PCBs
Mean concentrations in species from different regions from different sampling periods (1981-82,
1986-87, and 1988-91) were compared to PCB concentrations evaluated in this study (Table 18).
In all instances except one (eels from Delaware River/Bay in the late 1980s compared to this
study), mean concentrations of PCBs decreased in all evaluated species in all NJ regions.
Moreover, the number of individuals of each species exceeding the FDA limit of 2,000 ng/g
(2 ppm) dropped significantly over the time period represented by these four data sets.
Though historical comparisons based on means are helpful in evaluating the temporal trends of
contamination, several points should be kept in mind. Factors such as length, age, and exact
location may vary between collection years or decades. For example, concentrations of PCBs in
American eel in the Delaware Bay and River seemed to change only slightly between the 198687 collections compared to those made in this monitoring effort (Fig. 12). However, the earlier
collections were comprised, on average, of smaller eels. The recent collections contained eels
that were significantly larger but with similar concentrations, suggesting that concentrations in
these fishes have in fact declined due to less contaminated habitats. Despite the larger sizes of
THE ACADEMY OF NATURAL SCIENCES
38
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 18.
Comparison of PCB concentrations evaluated in this study with data compiled from 1981-82,
1986-87, and 1988-91.
Scientific Name
Ameiurus
nebulosus
Ameiurus
nebulosus
Anguilla rostrata
Anguilla rostrata
NJDEP
Region
Camden
Region
Camden
1981-82
1988-1991
1998-99
Mean N Mean N>2 N Mean N>2 N Mean N>2 N
600
0 8 1110
0 2
45
0 19
Northeast Raritan-Passaic
Camden Camden
Delaware Delaware River and
tribs
Anguilla rostrata Northeast Raritan-Passaic 3209 20
Cyprinus carpio Camden Camden
Cyprinus carpio Northeast Raritan-Passaic
Camden Camden
Micropterus
salmoides
Northeast Raritan-Passaic
Micropterus
salmoides
Northeast Raritan-Passaic 2594 15
Morone
americana
Atlantic Ocean
Morone saxatilis North
Coast
north
Morone saxatilis Northeast Raritan-Passaic 3332 45
Atlantic Ocean
Morone saxatilis South
Coast
south
North
Atlantic Ocean
Pomatomus
Coast
north
saltatrix
Northeast Raritan-Passaic
Pomatomus
saltatrix
South
Atlantic Ocean
Pomatomus
Coast
south
saltatrix
THE ACADEMY OF NATURAL SCIENCES
1986-87
39
1180
1
2
2320
990
4
1
7
9
1110
600
0
0
1710
1470
3200
560
3 10
3 13
3 4
0 5
2030
4
112
0
3
2
4
369
921
0
2
1
25
7
1006
674
978
361
1
1
1
1
8
30
10
15
123
0
6
200
0
1
2060
1
6
1280
0
3
893
1
8
2330
7 10
1640
6 18
463
0
9
2140
1350
6 16
1 5
1800
1130
5 14
3 17
431
483
0
0
5
6
930
0 24
950
1
6
562
0
9
820
1 11
1480
2
6
366
0
10
830
1 29
910
1
8
657
0
8
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Total PCBs (mg/kg wet weight)
PCBs in American eel
in Delaware Bay and River sites
3.8
3.6
3.4
3.2
3.0
2.8
2.6
2.4
2.2
2.0
1.8
1.6
1.4
1.2
1.0
0.8
0.6
0.4
0.2
0.0
20
30
1986-1987
1998-1999
40
50
60
70
80
Total length (cm)
Figure 12. Relationship between total PCB concentrations and length for American eel from the
Delaware Bay and River sites from 1986-87 and 1998-99.
THE ACADEMY OF NATURAL SCIENCES
40
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
eels in the recent study, 9 of the 25 specimens collected from the Delaware Bay and River in
1998-99 had concentrations below 0.42 ng/g, the minimum noted in 1986-87. The relatively
large sample size in the recent survey increases assurance that observed differences are real.
Chlordane
Data from 1986-7 and 1988-91 were compared to chlordane (sum of cis and trans chlordane
only) concentrations evaluated in this study (Table 19). At all sites, mean chlordane
concentrations of species from each region decreased, usually markedly, over the past decade.
Though mean chlordane concentrations in eels from the Northeastern sites were slightly lower in
the more recent survey, a dramatic decline over the decade was not apparent. There was much
overlap in concentrations between the two surveys, and there was no obvious relationship
between concentrations and length for this location (Fig. 13).
Table 19.
Comparison of previous data (from Kennish and Ruppel 1997) with current data. Data are
sums of the cis- and trans-chlordane components as )g/kg wet weight. For the 1998-1999
data, nondetect values are set to 0, and values below detection limit are set to ½ the
detection limit. Standard deviations (sd) are calculated on raw (untransformed) data, which
may be non-normal.
1986-7
Scientific
Ameiurus nebulosus
Ameiurus nebulosus
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Cyprinus carpio
Cyprinus carpio
Micropterus salmoides
Micropterus salmoides
Morone americana
Morone saxatilis
Morone saxatilis
Morone saxatilis
Pomatomus saltatrix
Pomatomus saltatrix
Pomatomus saltatrix
KRRegion Mean
Camden
Northeast
Camden
Delaware
Northeast
Camden
Northeast
Camden
Northeast
Northeast
North Coast
Northeast
South Coast
North Coast
Northeast
South Coast
THE ACADEMY OF NATURAL SCIENCES
124
73
630
62
73
260
334
21
13
64
61
50
64
37
30
33
1988-1991
#
Mean
8
2
7
9
10
13
4
5
1
6
10
16
5
24
11
29
102
53
275
149
48
41
1998-9
#
Mean
8
1
1
1
2
15
15
15
18
63
111
55
19
6
44
8
14
9
7
8
10
SD
12
18
18
44
80
32
21
5
13
4
15
8
4
5
9
#
38
6
1
25
8
60
20
30
6
8
9
5
5
9
10
8
198687
Prop>
300
0.13
0
0.57
0
0
0.31
0
0
0
0
0
0
0
0
0
0
199899
Prop>
300
0
0
0
0
0
0.017
0
0
0
0
0
0
0
0
0
0
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Chlordane (cis- and trans-) ng/kg wet weight
Chlordane in American eel
in Northeastern sites
175
150
125
100
75
50
25
0
25
30
35
1986-1987
1998-1999
40
45
50
55
60
65
Total length (cm)
Figure 13. Relationship between chlordane concentrations and length for American eel from
Northeastern sites from 1986087 and 1998-99.
THE ACADEMY OF NATURAL SCIENCES
42
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
DDXs
Data from 1986-87 were compared to DDX concentrations evaluated in this study (Table 20).
For some groups, such as brown bullhead (Ameiurus nebulosus) and striped bass (Morone
saxatilis), concentrations were lower in the recent survey. However, for most comparisons,
concentrations remained similar to those evaluated a decade before. In some instances,
concentrations were higher or lower at some sites; these differences may be due to small sample
sizes or differences in fish length, age or lipid content.
Table 20.
Comparison of DDX concentrations evaluated in this study with data compiled from 1986-87.
Scientific
Ameiurus nebulosus
Ameiurus nebulosus
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Cyprinus carpio
Cyprinus carpio
Micropterus salmoides
Micropterus salmoides
Morone americana
Morone saxatilis
Morone saxatilis
Morone saxatilis
Pomatomus saltatrix
Pomatomus saltatrix
Pomatomus saltatrix
KRRegion
Camden
Northeast
Camden
Delaware
Northeast
Camden
Northeast
Camden
Northeast
Northeast
North Coast
Northeast
South Coast
North Coast
Northeast
South Coast
Region
Camden
Raritan-Passaic
Camden
Delaware River and tribs
Raritan-Passaic
Camden
Raritan-Passaic
Camden
Raritan-Passaic
Raritan-Passaic
Atlantic Ocean north
Raritan-Passaic
Atlantic Ocean south
Atlantic Ocean north
Raritan-Passaic
Atlantic Ocean south
1987-7
Mean
#
177
8
193
2
1300
7
412
9
261
10
540
13
425
4
74
5
30
1
193
6
194
10
189
16
193
5
104
24
102
11
96
29
1998-9
Mean
#
33
19
19
3
373
1
554
25
361
8
666
30
179
10
163
15
17
6
263
8
100
9
72
5
135
6
91
9
76
10
118
8
DDX concentrations in eels from Delaware Bay and River from 1986-87 were compared to
concentrations determined in this study (Fig. 14). There was no relationship between
concentration and length for these locations. Collections made for the recent study did capture
eels that were longer, and presumably older. The highest DDX concentration was in a very large
(76 cm) eel from the Delaware River at Deepwater. Because of the difference in lengths between
the two collection efforts, it is difficult to definitively say that DDX concentrations in the
environment have remained constant over time. For eels from Northeastern sites (Fig. 15),
higher mean DDX concentrations were observed in the more recent monitoring. These eels were
longer than those sampled in the earlier survey. However, there is much variability in the
concentrations among fish from the recent survey, and relationships between length and DDX
concentration are not clear. By normalizing to lipid content, concentrations were relatively
THE ACADEMY OF NATURAL SCIENCES
43
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
DDx in American eel
in Delaware Bay and River sites
DDx (p and p') ng/kg wet weight
2600
2400
2200
2000
1800
1600
1400
1200
1000
800
600
400
200
0
20
30
1986-1987
1998-1999
40
50
60
70
80
Total length (cm)
Figure 14. Relationship between DDX concentrations and length for American eel from Delaware Bay
and River sites from 1986-86 and 1998-99.
THE ACADEMY OF NATURAL SCIENCES
44
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
DDx in American eel
in Northeastern sites
DDx (p and p') ng/kg wet weight
1600
1400
1200
1000
800
600
400
200
0
25
30
1986-1987
1998-1999
35
40
45
50
55
60
65
Total length (cm)
Figure 15. Relationship between DDX concentrations and length for American eel from Northeastern
sites from 1986-87 and 1998-99.
THE ACADEMY OF NATURAL SCIENCES
45
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
invariant with respect to length and not clearly different between surveys (Fig. 16), with the
exception of one eel from the 1986-87 survey having an extremely elevated DDX concentration.
Gaining Information by Comparing PCB Congener-Specific Patterns
Differences in Congener Patterns Among Species
The analysis of PCBs on a congener basis facilitates comparison of accumulation patterns of
those fish of the same species but collected from different locations. For this comparison, fish of
the same species were grouped according to the region in which they were collected. The
average normalized congeneric patterns for striped bass collected from various regions showed
remarkable similarity. However, a striking pattern shift was observed in those striped bass
collected from oceanic waters (Fig. 17). As the collection region shifted from south waters
(Cape May) to those in the north (Raritan Bay at Perth Amboy), congeneric patterns also shifted
to a pattern that was dominated by more lighter chlorinated congeners. Most evident in this
pattern shift were the decreasing dominance of coeluting congener groups 153+132+105 and
163+138 in the congener patterns with increasingly northward collections.
Ashley et al. (2000) found a similar gradient in striped bass patterns within the Hudson River
estuary. Using otolith chemistry, lifetime migration behaviors were estimated. Congeneric
patterns with higher proportions of di-, tri-, and tetrachlorbiphenyls were found in those striped
bass residing in the upper reaches of the estuary while the converse was true for those fish
spending more time in saline water or those undergoing annual migrations throughout the salinity
gradient. Their research suggests that the historic PCB loading and resulting contamination in the
upper reaches of the Hudson River imparts a unique signature to those fish using that habitat for
most of their life.
The shift seen from in this data set may represent a congeneric pattern shift in striped bass to a
pattern more characteristic of the Hudson River. Fish collected in the Raritan Bay region are
likely to have migrated through the salinity gradient of the Hudson River. However, those
striped bass caught further south most likely include fish that used the Delaware Bay (and
possibly the Chesapeake Bay) during their annual migrations, with some Hudson River fish
possibly present. Fish caught near Sandy Hook in early June could include Delaware and
Chesapeake Bay fish moving north as well as Hudson River fish.
Though comparisons of congeneric patterns from striped bass caught in different locations may
be interesting, teasing definitive information from it is marred by the fact that these fishes are
migratory. Without the use of otolith analysis or telemetry, no knowledge of the habitat use may
be gained. That is, though caught in one specific area, that congener pattern may represent the
pattern of contamination characteristic of a region other than it capture zone.
It has been suggested that the American eel may be a sentinel species for local contamination due
to its suspected limited home range, omnivorous diets, and high lipid content. In this is true,
THE ACADEMY OF NATURAL SCIENCES
46
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
DDx(p and p')/proportion lipid ng/kg wet weight
DDx in American eel
in Northeastern sites
60000
50000
40000
30000
20000
10000
0
25
30
1986-1987
1998-1999
35
40
45
50
55
60
65
Total length (cm)
Figure 16. Relationship between lipid normalized DDX concentrations and length for American eel from
Northeastern sites from 1986-87 and 1998-99.
THE ACADEMY OF NATURAL SCIENCES
47
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
N o r m a liz e d C o n c e n t r a t io n ( % )
P C B C o n g e n e r P a tte r n s in S trip e d B a s s
R a r ita n B a y @ P e r th A m b o y
m e a n t - P C B s 4 3 0 + /- 2 4 7 n g /g
(n = 5 )
15
10
5
A t la n t ic O c e a n , N o r t h o f S a n d y H o o k
m e a n t-P C B s 4 6 1 + /- 1 8 6 n g /g
(n = 1 0 )
15
10
5
A t la n t ic O c e a n , Is la n d B e a c h S t a t e P a r k
m e a n t - P C B s 3 0 5 + /- 2 4 3 n g /g
(n = 7 )
15
10
5
15
A t la n t ic O c e a n , C a p e M a y R ip s
m e a n t - P C B s 4 8 1 + /- 3 2 2 n g /g
(n = 6 )
10
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
33+53+21
22
45
46
52
49
47+48
44
37+42
41+71
64
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
81+87
85
136
77+110
82
151
135+144
107
149
118
134
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
198
201
203+196
189
208+195
207
194
205
206
209
5
PC B C ongener
Figure 17. Normalized PCB congeneric patterns for striped bass collected from the Atlantic Ocean.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
congeneric pattern differences between eels caught from different locations may be more useful
than compared to those of striped bass when assessing the degree and extent (and possible
source) of PCB contamination. Congeneric patterns in American eels collected from various
locations were again remarkably similar (Fig. 18). However, those eels collected from Toms
River had a distinctly different pattern from the other locales. The pattern was dominated by
more lighter chlorinated congeners. Without further assessing the patterns in the sediment and
prey items, information regarding the source of this accumulated pattern is difficult to assess.
Differences in Congener Patterns Between Species
The analysis of PCBs on a congener basis also facilitates comparison of accumulation patterns
between species. Again PCB congeneric patterns were very similar between species. Three
exceptions were observed. Patterns for brown bullhead, red breast sunfish, and white perch were
visible different from other species and may be reflective of a diet based on items of lower
trophic levels compared to other species like striped bass and American eel.
Comparison of Metabolite Ratios
Dearth and Hites (1991) calculated ratios of chlordane (sum of cis and trans chlordane and cis
and trans nonachlor) to its primary metabolite, oxychlordane. They found an average ratio of 10
(though a large spread was observed) for fish while for humans, the ratio was much lower (~1).
For this data set, the mean ratio was 6 (with an equally large spread of values being observed).
There was no clear pattern of higher or lower ratios in certain species. The relatively high ratio
indicates the inability of fish to metabolize the parent compounds of chlordane.
Using TEqs for Risk Assessment
For risk assessment, the use of TEqs (Toxic Equivalents) is often useful, although TEqs have not
been incorporated into consumption advisories to date. This involves ‘normalizing’ the effects of
certain PCB congeners to that of a benchmark contaminant, 2,3,7,8-tetrachlorodibenzo-p-dioxin
(TCDD), which by definition is given a TEq value of 1. The concentrations of non-ortho-PCBs
(congeners 77, 81, 126 and 169) and mono-ortho-PCBs (105, 114, 118, 123, 156, 157, 167 and
189) are multiplied by their corresponding TEqs and a final “equivalents of TCDD” may be
reported by summing all products.
Of the 12 non-ortho and mono-ortho-PCB congeners listed above, four were evaluated in this
study (congeners 77, 105, 118 and 189). Congener 105, a mono-ortho-PCB, coeluted with
congeners 153 and 132. Similarly, the non-ortho-substituted congener 77 coeluted with congener
110. Mono-ortho substituted congeners 118 and 189 were well-resolved using the clean-up
procedures employed in this study. Though limiting, it would be imaginable to use these two
congeners for risk assessment based on calculation of TEqs.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
N o r m a liz e d C o n c e n t r a t io n ( % )
15
M u llic a R iv e r
m e a n t-P C B s 1 2 8 + /- 6 3 n g /g
(n = 6 )
10
5
15
D e la w a r e R iv e r - V a r io u s L o c a tio n s
m e a n t-P C B s 6 0 0 + /- 4 7 1 n g /g
(n = 6 )
10
5
15
T o m s R iv e r
m e a n t -P C B s 2 9 3 + /- 1 4 6 n g /g
(n = 7 )
10
206
209
194
205
201
208+195
207
203+196
189
191
199
170+190
198
180
193
157+200
172+197
174
177
202+171
128
185
158
187+182
183
129+178
137+176
163+138
134
131
PCB Congener
146
153+132+105
141
149
118
82
151
135+144
107
136
77+110
97
81+87
85
99
83
56+60
101
66+95
91
70+76
40
100
63
74
41+71
64
45
46
52
49
47+48
44
37+42
25
31+28
33+53+21
22
12+13
18
17
24+27
16+32
29
26
7
6
8+5
19
1
3
4+10
5
Figure 18. Normalized PCB congeneric patterns for American eel collected from various locations
including Toms River.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
CONCLUSIONS
From the evaluation of this extensive monitoring effort, and comparisons with historical data, the
following conclusions may be stated:
1) Many of the common carp caught in the Camden area (Newton Lake, Strawbridge
Ponds, Pennsauken River and Cooper River Lake) exceeded FDA action limits for
consumption based on chlordane concentrations. This fact, in addition to the observed
PCB action limit exceedances for Raritan Bay eels (and sections of the Delaware
River), consumption guidelines should not be relaxed for fishes in these areas.
2) For most species and regions, concentrations of PCBs and chlordanes have markedly
decreased compared to evaluations made a decade ago.
3) Changes in DDX are more equivocal, with some groups showing decreases, but with
little evidence of change for other comparisons.
4) The observed decreases could be due to environmental cleanup, pollution prevention
programs, degradation, or changes in the bioavailability of contaminants.
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REFERENCES
Academy of Natural Sciences of Philadelphia (ANSP). 1994. Preliminary assessment of total
mercury concentrations in fishes from rivers, lakes and reservoirs of New Jersey. Rept.
No. 93-15F. Acad. Nat. Sci. Phila. 92 pp.
Ashley, J.T.F., D.H. Secor, E. Zlokovitz, S.Q. Wales, and J.E. Baker. 2000. Linking habitat use
of Hudson River striped bass to accumulation of PCBs. Environ. Sci. Technol. 34:10231029.
Bonin, J., J.-L DesGranges, C.A. Bishop, J. Ridrigue, A. Gendron, and J.E. Elliott. 1995.
Comparative study of contaminants in the mudpuppy (Amphibia) and the common
snapping turtle (Reptilia), St. Lawrence River, Canada. Arch. Environ. Contam. Toxicol.
28(2):184-194.
Bryan, A.M., P.G. Olafsson and W.B. Stone. 1987. Disposition of low and high environmental
concentrations of PCBs in snapping turtle tissues. Bull. Environ. Contam. Toxicol.
38(6)1000-1005.
Dearth, M.A. and R.A. Hites. 1991. Chlordane accumulation in people. Environ. Sci. Technol.
25:1279-1285.
Hauge, C. 1993. Polychlorinated Biphenyls (PCBs), Chlordane, and DDTs in Selected Fish and
Shellfish from New Jersey Waters, 1988-1991: Results from New Jersey’s Toxics in
Biota Monitoring Program. New Jersey Dept. Env. Protection and Energy, Div. Sci. and
Res. July 1993. 95 pp.
Horwitz, R.J., B. Ruppel, S. Wisniewski, P. Kiry, M. Hermanson and C. Gilmour. 1995.
Mercury concentrations in freshwater fishes in New Jersey. Wat., Air and Soil Poll.
80:885-888.
Kennish, M.J., T.J. Belton, P. Hauge, K. Lockwood and B.E. Ruppel. 1992. Polychlorinated
biphenyls in estuarine and coastal marine waters of New Jersey: A review of
contamination problems. Reviews in Aquatic Sciences. 6:275-293.
Kennish, M.J. and B.E. Ruppel. 1996. DDT contamination in selected estuarine and coastal
marine finfish and shellfish of New Jersey. Arch. Environ. Contam. Toxicol. 31:256-262.
Kennish, M.J., and B.E. Ruppel. 1997. Chlordane contamination in selected freshwater finfish in
New Jersey. Bull. Environ. Contam. Toxicol. 58:142-149.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Mullin, M.D. 1985. Workshop, U.S. Environmental Protection Agency Large Lakes Research
Station. U.S. EPA, Grosse Ile, MI.
New Jersey Department of Environmental Protection (NJDEP). 1990. Polychlorinated
biphenyls (PCBs), Chlordane, and DDTs in Selected Fish and Shellfish From New Jersey
Waters, 1986-1987: Results from New Jersey’s Toxics in Biota Monitoring Program.
_________. 2000. New Jersey Fish and Wildlife Digest. A summary of rules and management
information. New Jersey Dept. of Environ. Protection, Div. Of Fish, Game and Wildlife
13(2), January 2000.
Ruppel, B., A. Stern and M. Sheil. 1994. Mercury contamination in New Jersey freshwater fish.
Report of the Toxics in Biota Committee, New Jersey Dept. of Environ. Protection, New
Jersey Dept. of Health, and New Jersey Dept. of Agric. Trenton, NJ. 88 pp.
THE ACADEMY OF NATURAL SCIENCES
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I
Quality Assurance/Quality Control Summary
THE ACADEMY OF NATURAL SCIENCES
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
NJ Fish Tissue Analysis for the Evaluation of Spatial Trends
and Human Health Impacts
Quality Assurance/Quality Control Summary
Environmental Geochemistry Section
Patrick Center for Environmental Research
Academy of Natural Sciences
Philadelphia, PA 19103
This report summarizes the results of the chemical analyses (both mercury and organic analyses)
performed to date with particular emphasis on the results of the quality assurance and control
measures that were followed. This report will constitute a more detailed final summary report to be
submitted by ANS after internal QA/QC review and completion of further analyses of additional
fishes.
I. Mercury
a) Extractions and Analyses:
Strong acid digestions were performed using 10 ml nitric acid on approximately 1g homogenized
wet fish material in a CEM MDS 2100 microwave digestion system. Mercury analysis was
subsequently accomplished on a Perkin Elmer Fimms 400 Cold Vapor AA. Calibration blanks,
intercalibration verification samples, and instrument duplicates were analyzed to ensure instrument
performance and accuracy.
b) Analytical Quality Assurance:
Sample blanks, duplicates, spikes, and a National Research Counsel of Canada (NRC) Standard
Reference Material (DORM-2, dogfish muscle) were digested with the samples to ensure adequate
recoveries. Recoveries for NRC Dorm-2 were compared to the certified NRC values and were
within 83-111% of the actual concentration for all samples digested. Inter-calibration verification
samples were all 90-110% of the actual concentration. The relative percent differences (RPD) for
instrument duplicates were below 6%, while RPDs for sample duplicates ranged from 0.1 to13%.
Finally, sample spikes were analyzed and were typically within 80-120% of added concentrations.
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II. Polychlorinated Biphenyls and Organochlorine Pesticides:
a) Extractions and Analyses:
Homogenized fish samples were stored frozen until extraction. Samples were thawed and 2 g of the
homogenate was sub-sampled using a stainless steel spatula. An additional 2-5 g sub-sample was
taken for moisture analysis. Approximately 30 g of Na2SO4 (previously extracted with hexane using
a Soxhlet extractor and dried) was added to the sub-sample to eliminate water. The dried sample
was placed in a glass thimble and extracted using a Soxhlet extractor with ca. 200 ml
dichloromethane (DCM) for a minimum of 18 h. The extracts were sub-sampled for gravimetric
lipid determination. For this, a known volume of extract was transferred to a pre-weighed aluminum
pan. The solvent was evaporated at 110(C for at least 24 h. The residue remaining (lipid) was
weighed and percent lipid was calculated.
Lipids were removed from sample extracts by gel permeation chromatography (GPC) using DCM
as the mobile phase. The collected fraction containing analytes was concentrated by rotoevaporation and a N2 stream. Solid-liquid chromatography using florisil was done as an additional
clean-up step. Using this technique, PCBs (as well as heptachlor, nonachlors, and DDEs) were
eluted from the chromatographic column containing Florisil using petroleum ether (F1 fraction). The
remaining organochlorine pesticides were eluted using 50:50 petroleum ether and dichloromethane
(F2 fraction).
Congener-specific PCBs and organochlorine pesticides (Table 1) were analyzed using a Hewlett
Packard 5890 gas chromatograph equipped with a 63Ni electron capture detector and a 5%
phenylmethyl silicon capillary column. The identification and quantification of PCB congeners
followed the ‘610 Method’ (Mullin 1985) in which the identities and concentrations of each
congener in a mixed Aroclor standard (25:18:18 mixture of Aroclors 1232, 1248 and 1262) were
determined by calibration with individual PCB congener standards. Congener identities in the
sample extracts were based on their chromatographic retention times relative to the internal standards
added. In cases where two or more congeners could not be chromatographically resolved, the
combined concentrations were reported (Table 1). Organochlorine pesticides (OCPs) were identified
and quantified based on comparisons (retention times and peak areas) with a known calibration
standard prepared from individual compounds.
b) Analytical Quality Assurance:
Surrogate Recoveries: Analyte loss through analytical manipulations was assessed by the addition
of surrogate PCB congeners 14, 65 and 166 prior to extraction by Soxhlet apparatus. These
surrogates were not industrially prepared and therefore are not present in the environment. Average
recoveries of congeners 14, 65 and 166 were 96 ± 27%, 77 ± 18% and 86 ± 18%. Due to the
relatively high surrogate recoveries and the low standard deviations, all reported values for PCB and
OCP concentration in this study were not corrected for analyte loss.
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 1.
List of target organic analytes.
Organochlorine Pesticides
Polychlorinated Biphenyls*
BHC (alpha, beta, gamma, delta)
1
40
137,176
Heptachlor
3
100
163,138
4,10
63
158
7
74
129,178
6
70,76
187,182
Dieldrin
8,5
6695
183
DDDs (o,p and p,p)
14
91
128
DDEs (o,p+ and p,p)
19
56,60
185
DDTs (o,p and p,p)
12,13
101
174
Aldrin
18
99
177
Endosulfan I and II
17
83
202,171
Endrin
2427
97
172,197
Oxychlordane
16,32
81,87
180
29
85
193
26
136
191
25
77,110
199
31,28
82
170,190
33,21,53
151
198
22
134144
201
45
107
203,196
46
149
189
52
118
208,195
49
134
207
48,47
131
194
44
146
205
37,42
132,153,105
206
41,71
141
209
Heptachlor Epoxide
Chlordanes (gamma and alpha)
#
Nonachlors (cis and trans)
64
* PCB congeners appearing as pairs or triplets were coeluted and reported as sum.
+
o,p-DDE coelutes with PCB congeners 92,85
#
Evidence for PCB coelution with cis-nonachlor
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Detection Limits: Matrix blanks (~40) were generated to monitor possible laboratory contamination
and to calculate the detection limits for PCBs and OCPs. Each matrix blank, consisting of
approximately 30 g of clean Na2SO4, was analyzed using the same procedures as the samples.
Average surrogate recoveries for these blanks were 81%, 73% and 80% for PCBs 14, 65 and 166,
respectively. Chromatograms of most blanks were void of significant peaks suggesting that little
contamination through laboratory exposure occurred.
The detection limit was estimated as three times the peak area of the signal produced in the matrix
blank. The method detection may be reported on a mass per sample basis or, if extraction weights
of sub-sampled fish remained relatively invariant as in this study (~2 g), a ‘wet weight normalized’
concentration may be reported. The matrix blank-based detection limits for PCBs and OCPs ranged
from to 0.06 to 1.11 and 0.11 to 2.16 ng/g wet weight, respectively (Tables 2 and 3). Based on 31
matrix blanks, the detection limit for total PCBs (t-PCBs) was 24.2 ng/g wet weight.
Analytical Accuracy: A National Institute for Standards and Technology (NIST) standard reference
material (SRM #1974a; Organics in Mussel Tissue) was used to periodically evaluate extraction
efficiency and analytical accuracy (July 28, 1999 and January 27, 2000). The majority of determined
concentrations fell below those values reported by NIST (Tables 4 and 5), denoting the partial loss
of these semi-volatile analytes through analytical manipulations. For PCBs, recoveries ranged from
49 to 117% with most values falling short of those reported by NIST. Considering the average
surrogate recovery for all three surrogates (14, 65 and 166) was 75% and that some discrepancies
exist between which congeners are reported (e.g., coeluting versus non-coeluting), PCB recoveries
suggest a relatively high degree of accuracy in the ANS’ ability to quantify PCBs.
NIST reports the concentrations of only five OCPs in their SRM 1974a as opposed to the 17 OCPs
quantified in this study. Recoveries for p,p-DDE and trans-nonachlor from two separate analyses
(January 27, 1999 and July 28, 2000) averaged 77 and 112%. Average recoveries for o,p-DDE and
cis-nonachlor were very large (>400%). Values this high usually indicate one of two things: a
problem with the concentration value assigned for that analyte in the calibration standard or a
problem with the ability to resolve that analyte without interference (from PCB congeners or other
unidentifiable compounds) using the analytical instrumentation.
To investigate the first issue, prepared standards were compared to a previously prepared and
actively used mixed standard from a colleague’s laboratory (Dr. Greg Foster, George Mason
University, VA). By using our mixed pesticide standard as an unknown, concentrations were
assigned using the ‘Foster mixed standard’ as the true calibration standard. Calculated
concentrations of OCPs in our standard mixture compared very well to our originally assigned
concentrations, providing confidence that the standards were indeed prepared accurately. The
question then remained as to the resolving power of gas chromatography (with electron capture
detector) to clearly and accurately differentiate closely coeluting compounds. To investigate this
issue in more depth and to provide additional quality assurance, our laboratory was involved in
NIST’s Inter-laboratory Comparison exercise, a blind evaluation of NIST-issued fish tissue for PCBs
and OCPs.
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Table 2. Detection Limits for PCBs.
Congener
Det. Limit
(ng/sample)
Det. Limit
(ng/g wet)
1
3
4+10
7
6
8+5
14
19
30
12+13
18
17
24+27
16+32
29
26
25
31+28
33+53+21
heptachlor
22
45
46
52
49
47+48
65
44
37+42
41+71
64
40
100
63
74
70+76
66+95
91
56+60
o,p DDE
101
99
trans-nonachlor
83
97
81+87
p,p DDE
0.76
1.68
0.48
0.14
0.29
0.56
0.38
0.84
0.24
0.07
0.15
0.28
0.49
0.25
0.90
0.68
0.52
0.24
0.74
0.36
0.50
1.73
2.20
1.12
0.16
1.54
0.33
0.47
0.67
0.48
2.11
0.45
0.34
0.26
0.12
0.37
0.18
0.25
0.86
1.10
0.56
0.08
0.77
0.17
0.23
0.33
0.24
1.06
0.51
0.16
0.22
0.32
0.19
0.27
0.23
0.53
0.53
1.25
0.26
0.55
0.56
0.45
0.47
1.07
0.23
0.15
0.57
2.23
0.25
0.08
0.11
0.16
0.09
0.13
0.12
0.27
0.27
0.62
0.13
0.27
0.28
0.22
0.24
0.54
0.12
0.08
0.29
1.11
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 2 (continued). Detection Limits for PCBs.
Congener
Det. Limit
(ng/sample)
Det. Limit
(ng/g wet)
85
136
77+110
82
151
135+144
107
149
118
134
cis-nonachlor
131
146
153+132+105
141
137+176
163+138
158
129+178
166
187+182
183
128
185
174
177
202+171
157+200
204
172+197
180
193
191
199
170+190
198
201
203+196
189
208+195
207
194
205
206
209
0.20
0.12
0.61
0.14
0.18
0.16
0.13
0.53
0.47
0.24
2.00
0.14
0.56
2.30
0.24
0.73
1.36
0.46
0.38
0.1
0.06
0.31
0.07
0.09
0.08
0.07
0.26
0.23
0.12
1.00
0.07
0.28
1.15
0.12
0.36
0.68
0.23
0.19
0.73
0.31
0.34
0.15
0.18
0.24
0.23
0.19
0.36
0.16
0.17
0.08
0.09
0.12
0.12
0.09
0.15
0.76
0.56
0.18
0.14
0.46
0.15
0.34
0.46
0.22
0.28
0.18
0.54
0.25
0.36
0.16
0.07
0.38
0.28
0.09
0.07
0.23
0.08
0.17
0.23
0.11
0.14
0.09
0.27
0.12
0.18
0.08
sum PCBs
48.38
24.19
Average Surr Rec
81
73
80
% Recovery
14
65
166
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 3. Detection limits for organochlorine pesticides.
COMPOUND
Det. Limit
(ng/sample)
Det. Limit
(ng/g wet)
0.53
4.31
0.45
1.20
3.15
0.21
0.49
0.38
0.55
0.27
0.32
0.47
0.46
0.97
0.55
1.21
0.26
2.16
0.23
0.60
1.58
0.11
0.25
0.19
0.28
0.14
0.16
0.23
0.23
0.49
0.27
0.60
alpha BHC
beta BHC
lindane
delta BHC
aldrin
heptachlor epoxide
gamma chlordane
endosulfan I
alpha chlordane
dieldrin
o,p DDD
endrin
endosulfan II
p,p DDD
o,p DDT
p,p DDT
Table 4. Comparison of PCB and pesticide concentrations reported by the Academy of Natural Sciences
and those from the NIST (Mussel Tissue SRM 1974a) - January 27, 2000.
COMPOUND
PCB 18
PCB 28/31
PCB 52
PCB 44
PCB 66/95
o,p DDE
PCB 101
trans-nonachlor
p,p DDE
PCB 118
cis-nonachlor
PCB 153+132+105
PCB 138/163
PCB 159/182/187
PCB 128
PCB 180
PCB 170/190
ANS -PCER
Mean (n=4)
3.35
20.50
8.70
8.18
22.71
3.40
8.61
2.30
4.61
7.29
3.80
16.82
11.76
3.13
1.71
1.36
0.63
THE ACADEMY OF NATURAL SCIENCES
NIST SRM
Std
1.12
6.55
1.84
1.84
13.98
0.80
2.02
0.78
1.50
1.82
1.30
4.39
2.76
0.97
0.61
0.44
0.23
Mean
3.70
17.60
13.10
8.28
21.04
0.70
14.60
2.05
5.84
14.90
0.78
22.49
15.20
3.87
2.50
1.95
0.63
61
Recovery
Std
1.20
4.10
1.30
0.84
2.40
0.15
1.10
0.41
0.63
0.40
0.10
1.10
0.27
0.39
0.43
0.12
90%
116%
66%
99%
108%
486%
59%
112%
79%
49%
487%
75%
77%
81%
68%
70%
99%
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 5. Comparison of PCB and pesticide concentrations reported by the Academy of Natural Sciences
and those from the NIST (Mussel Tissue SRM 1974a) - July 28, 1999.
COMPOUND
PCB 52
PCB 49
PCB 44
PCB 66/95
PCB 101/90
PCB 99
trans-nonachlor
p,p DDE
o,p DDE
PCB 77+110
PCB 151
PCB 149
PCB 118
cis-nonachlor
PCB 153/132/105
PCB 163/138
PCB 187/182
PCB 183
PCB 128
PCB 180
ANS -PCER
Mean (n=6)
8.28
8.66
7.07
22.66
7.97
4.45
2.27
4.41
2.72
10.71
1.90
6.52
7.44
3.40
18.56
13.33
3.07
2.13
1.96
1.39
NIST SRM
Std
1.09
1.50
0.86
5.13
0.71
0.49
0.39
0.49
0.31
1.21
0.21
0.67
0.77
0.34
1.89
1.44
0.36
0.32
0.28
0.14
Mean
13.10
10.12
8.28
21.04
14.60
8.08
2.05
5.84
0.70
14.50
2.91
9.98
14.90
0.78
22.59
15.20
3.87
1.82
2.50
1.95
Std
1.30
0.59
0.84
2.40
1.10
0.46
0.41
0.63
0.15
1.00
0.40
0.27
0.40
0.10
1.25
1.10
0.27
0.27
0.39
0.43
Recovery
63%
86%
85%
108%
55%
55%
111%
75%
388%
74%
65%
65%
50%
436%
82%
88%
79%
117%
79%
71%
The NIST Interlaboratory Comparison exercise is also helpful when assessing a laboratory’s ability
to accurately quantify OCPs. Often, the concentrations of only a few (or no) OCPs contained in an
issued SRM are reported. For example, Environment Canada’s carp tissue SRM reports no OCPs.
For the NIST Inter-laboratory Comparison, over 30 labs submitted concentrations for OCPs in fish
tissue. All but one of these labs used the same analytical technique (gas chromatography with an
electron capture detector) as the one used in this investigation. Though the pooled concentrations
for each OCP (or PCB congener) may not be considered a ‘NIST certified’ SRM value (and thus,
recoveries were not calculated), they are helpful in indicating the closeness of one obtained
concentration value (from one laboratory) to the average value (obtained from all laboratories).
The results of the NIST Inter-laboratory Comparison for PCBs (Table 6) once again reiterated ANS’s
ability to precisely and accurately quantify these chemicals. For those congeners in which ANS’s
values were significantly different than the pooled average of all the labs (e.g., congeners 8, 28,
101/90, and 195) , quantification differences often can explain the discrepancies. For example, NIST
reports congeners 101/90 whereas ANS reports only congener 101. When NIST assigns a value of
38.1±10.7 ng/g wet wgt to these coeluting congeners and ANS reports a value of 17.39±1.09 ng/g
wet wgt, one must take note that the same congeners were not being evaluated. Other quantification
differences were present and are explained in Table 6. Though both NIST and ANS report congener
THE ACADEMY OF NATURAL SCIENCES
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 6. Comparison of polychlorinated biphenyl concentrations reported by the Academy of Natural
Sciences and those from the NIST Interlaboratory Comparison effort (unknown fish) - April, 2000.
COMPOUND
PCB 8 *
PCB 18
PCB 28 *
PCB 52
PCB 44
PCB 66/95
PCB 101/90 *
PCB 118
PCB 153 *
PCB 105 *
PCB 138/163/164 *
PCB 187/182
PCB 128
PCB 180
PCB 170/190
PCB 195 *
PCB 206
PCB 209
Total Reported PCBs
ANS -PCER
NIST INTERLAB
Mean (n=9)
13.21
0.58
5.00
4.96
5.59
26.78
17.39
20.60
121.36
Std
1.92
0.17
1.96
0.49
0.60
1.88
1.09
0.71
3.78
94.62
26.57
65.00
44.76
30.17
9.09
5.04
0.48
5.05
0.85
6.70
1.62
1.07
0.08
0.09
0.06
491.20
Mean
<2
<2
2.24
7.1
5.54
17.8
38.1
50.9
157
21.7
136
54.2
26.9
75
29.1
5.19
5.06
1.33
Std
0.89
1.85
3.23
5.9
10.7
13.4
34
6.7
23
10
13.6
16.8
9
1.51
1.15
0.5
633.16
*Congener 8 reported as 8+5
Congener 28 reported as 28+31
Congeners 101/90 reported as 101 only
Congener 153 reported as 132+105+153
Congeners138/163/164 reported as 138+163
Congener 195 reported as 195+208
128 as a non-coeluting peak, ANS’s assigned concentration (65.0 ± 6.7 ng/g wet wgt) was 2.5 times
larger than NIST’s. Though this congener usually produces a single distinct peak, it is likely that a
coeluting interference is responsible for this inflated concentration. By summing all the quantified
congeners, a final comparison using t-PCBs may be made. NIST reports a t-PCB value of 632 ng/g
wet wgt; ANS assigns 491 ng/g wet wgt. Differences on this scale are considered average and
represent a good degree of accuracy.
The results of the NIST Inter-laboratory Comparison for OCPs (Table 7) also revealed that the ANS
is on par with other labs in the ability to quantify this class of chemicals. For most of the OCPs,
reported values were close to those values by NIST (based on a averaging values from over 30 labs).
However, a large discrepancy between ANS and NIST o,p-DDE concentrations did exist. As with
ANS’s results from the NIST SRM evaluations (Tables 4 and 5), the reported o,p-DDE concentration
was once again well above the range of expected values. This OCP elutes in the first fraction (F1)
THE ACADEMY OF NATURAL SCIENCES
63
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 7. Comparison of organochlorine pesticide concentrations reported by the Academy of Natural
Sciences and those from the NIST Interlaboratory Comparison (unknown fish) - April, 2000.
COMPOUND
ANS - PCER
Mean (n=9)
alpha-HCH (a-BHC)
hexachlorobenzene
gamma-HCH (g-BHC,lindane)
heptachlor
aldrin
heptachlor epoxide
oxychlordane
gamma-chlordane (trans-chlordane
2,4'-DDE
endosulfan I
cis-chlordane (alpha-chlordane)
trans-nonachlor
dieldrin
4,4'-DDE
2,4'-DDD
endrin
endosulfan II
4,4'-DDD
2,4'-DDT
cis-nonachlor
4,4'-DDT
mirex
Std
5.5
2.0
not analyzed
1.0
0.3
2.3
1.0
2.4
0.5
5.8
0.3
not analyzed
5.6
0.2
9.6
1.3
0.2
3.2
10.6
3.2
74.8
4.3
9.3
0.2
473.3
31.7
2.0
0.8
5.8
0.9
5.3
0.9
12.6
3.6
75.1
24.2
148.6
50.4
24.0
8.7
not analyzed
NIST INTERLAB
Mean
5.2
6.6
1.2
<1
<1
5.1
17.4
8.0
1.0
<2
30.7
89.5
31.4
332.0
2.6
5.4
<5
16.9
23.0
59.9
41.1
6.1
Std
1.1
1.6
0.6
1.2
3.8
2.5
0.4
11.1
18.3
8.4
68.0
1.5
1.9
8.0
11.2
14.5
16.7
1.9
of the florisil clean-up along with the PCBs. Coelution with PCBs (specifically congeners 92/84)
takes place and is the likely cause of inflated concentrations of o,p-DDE compared to NIST
published values. Thus, this OCP should be reported as “o,p-DDE + Congener 92/85". The value
reported for cis-nonachlor was also well above that assigned by NIST (just as previously found with
the NIST SRM evaluations). An interfering species may be coeluting with this OCP and caution
should be taken when using reported values for cis-nonachlor. True values are likely half of reported
values.
As part of the NIST Inter-laboratory Comparison exercises, an additional SRM was analyzed.
Homogenized carp, supplied by Environment Canada, was analyzed (n=4). Only eight PCB
congener (or coeluting congeners) concentrations are reported for this SRM (Table 8). Percent
recoveries ranged from 37% (for congener 101/90) to 122% (for congeners 170/190). Recoveries
increased with increasing degree of chlorination in agreement with the fact that the lighter molecular
weight congeners (those that are more volatile) are more easily lost in the analytical procedure. Once
again, recoveries in this range are considered to be normal and reflect our capability in accurately
quantitating PCBs. As stated previously, no OCP concentrations are certified for this SRM.
THE ACADEMY OF NATURAL SCIENCES
64
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 8. Comparison of polychlorinated biphenyl concentrations reported by the Academy of Natural
Sciences and those from the Environment Canada (Carp) - April, 2000.
COMPOUND
PCB 52
PCB 101/90
PCB 118
PCB 153/105/132
PCB 138/163/164
PCB 187/182
PCB 180
PCB 170/190
ANS -PCER
Mean (n=4)
55.04
45.50
58.82
83.68
80.37
21.62
36.30
26.76
Environment Canada
Std
4.67
3.70
4.29
6.25
5.79
1.60
2.17
1.78
Mean
124
124
132
137
102
36
46
22
Std
32
37
60
63
23
16
14
8
Recovery
44%
37%
45%
61%
79%
60%
79%
122%
Analytical Precision: To assess precision of the organic contaminant analyses, sample duplicates
of randomly selected samples were performed at a frequency of 10%. The mean RPD for t-PCBs
was 27 ± 24% (Table 9). The mean RPD for F2 duplicates (most of the OCPs) was 50 ± 32%. In
most cases, duplicate analyses revealed good precision. For select duplicate analyses (e.g., F-3170
and F3171), RPD values were higher than expected. This is most likely a result of sub-sampling
error. For example, for those samples that were homogenized with skins retained, the homogenate
often contained small chunks of skin mixed with tissue from the fillet. If, when sub-sampling, a
piece of skin was taken for one duplicate and not the other, this could affect the final concentration
values (as well as lipid) and cause higher than expected RPD values between duplicates.
Additional Quality Assurance: Additions of known volumes of calibration standards to matrix
blanks, or ‘spiked samples’, were used to further evaluate quality assurance of the analytical
procedure. Analytes were quantified and resulting masses were compared to the masses initially
spiked into the matrix prior to extraction. For most PCB congeners, recoveries ranged from 44 %
(congener 47/48) to 123 % (congener 83) (Table 10). Several congeners had recoveries that
exceeded 160% (congeners 12/13, 24/27, 29, 25, 63, 137/176, 129/178, 128, 189, and 209). The sum
of these congeners represent <5% of the total mass in most fish tissues. Recoveries that are above
160% reflect the difficulty in quantifying congeners whose masses in spiked standards (and in actual
samples) are so low.
The recoveries of the OCPs eluting in F1 were not as surprising (Table 11). Cis-nonachlor and o,pDDE had recoveries exceeding 160% (315% and 192%, respectively). O,p-DDE was found to
coelute with PCB congeners 92/85; recoveries exceeding 100% are therefore expected. An
unidentifiable coeluting substance is responsible for exceedingly high recovery for cis-nonachlor.
Once again, care should be taken when using reported concentrations for these two OCPs. Cisnonachlor concentrations are likely 2-2.5 times lower than actual concentrations while o,p-DDE
should be reported as o,p-DDE + PCB congeners 92/85.
THE ACADEMY OF NATURAL SCIENCES
65
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 9. Duplicate RPDs for t-PCBs.
Fish ID t-PCBs t-PCBs
t-PCBs
RPD
Original Duplicate Triplicate
0
F-2851
F-2855
F-2938
F-2951
F-2955
F-2956
F-2960
F-2967
F-2972
F-2979
F-2989
F-3003
F-3020
F-3034
F-3036
F-3046
F-3051
F-3053
F-3059
F3065
F-3066
F-3071
F-3078
F-3098
F-3101
F-3107
F-3110
F-3112
F-3113
F-3115
F-3117
F-3118
F-3170
F-3171
F-3197
F-3203
F-3207
F-3224
548.93
42.39
695.20
554.16
101.53
1011.19
409.75
150.46
351.19
1189.73
159.69
361.79
176.57
49.57
1938.10
115.33
202.12
420.58
806.70
1077.87
171.12
973.22
356.68
250.80
1267.68
153.06
30.39
389.93
75.18
200.23
691.55
258.12
36.69
151.01
54.51
4235.77
512.51
46.46
72.95
Mean of RPDs
27
Std. Dev. of Mean RPDs
THE ACADEMY OF NATURAL SCIENCES
415.02
20.48
859.43
543.99
114.45
727.05
326.73
116.61
375.96
2353.34
176.99
354.36
332.58
48.55
1907.20
123.54
233.75
316.89
1249.15
1152.44
234.52
1102.86
446.47
327.67
1784.42
128.45
64.42
408.66
45.04
329.59
635.47
210.72
56.89
363.04
131.49
3460.19
498.30
45.22
66.55
28
70
21
2
78.82
33
23
25
7
66
10
2
61
2
2
7
15
28
43
7
31
12
22
27
34
17
72
5
50
49
8
20
54.47
82
83
20
3
3
9
24
66
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 10. Spike recoveries for F1 fraction.
Congener Ave. Spk STD
RSD % Mullins Mass in
Mass
Spike
Conc,
Spike,
(n=5) ng (n=5) ng
ng/L
ng
1
3
4+10
7
6
8+5
14
19
12+13
18
17
24+27
16+32
29
26
25
31+28
33+53+21
heptachlor
22
45
46
52
49
47+48
65
44
37+42
41+71
64
40
100
63
74
70+76
66+95
91
56+60
o,p DDE
101
99
transnonachlor
83
THE ACADEMY OF NATURAL SCIENCES
2.86
2.10
0.29
0.22
0.33
4.95
14.88
0.05
0.16
1.10
0.48
0.16
1.01
0.05
0.28
0.15
0.02
0.02
0.04
0.36
0.95
0.02
0.19
0.08
0.10
0.07
0.12
0.01
10%
7%
7%
8%
11%
7%
6%
39%
123%
7%
20%
44%
12%
22%
0.66
1.88
1.07
5.24
1.17
0.13
0.13
1.08
0.83
0.40
12.12
1.18
0.46
0.61
0.62
0.07
0.05
0.12
0.87
1.94
2.69
0.14
1.60
5.64
0.60
0.26
5.06
0.56
0.11
0.10
0.61
0.30
0.08
0.02
0.07
0.09
0.19
1.02
0.10
0.12
0.10
0.06
0.01
0.02
0.03
0.06
0.17
0.39
0.02
0.05
0.23
0.03
0.03
0.56
85%
6%
9%
12%
26%
58%
18%
7%
10%
49%
8%
8%
26%
17%
9%
21%
43%
23%
7%
9%
14%
13%
3%
4%
4%
12%
11%
0.04
0.01
16%
67
43
26
2.8
2.2
4.2
50
200
1
0.92
13
7.4
0.87
13.1
0.18
2.3
1
38
16.7
11
2.7
1.4
12
9
9
200
15
8.8
9.4
6.9
3.3
0.5
0.74
8.1
21
27.2
1.4
18
4.8
2.3
0.36
4.3
2.6
0.28
0.22
0.42
5
20
0.1
0.092
1.3
0.74
0.087
1.31
0.018
0.23
0.1
3.8
1.67
9.8
1.1
0.27
0.14
1.2
0.9
0.9
20
1.5
0.88
0.94
0.69
0.33
0.05
0.074
0.81
2.1
2.72
0.14
1.8
2.94
0.48
0.23
10.89
0.036
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 10 (continued). Spike recoveries for F1 fraction.
Congener Ave. Spk STD RSD % Mullins Mass in
Mass
Spike
Conc,
Spike,
(n=5) ng (n=5) ng
ng/L
ng
97
81+87
p,p DDE
85
136
77+110
82
151
135+144
107
149
118
134
cis-nonachlor
153+132+105
141
137+176
163+138
158
129+178
166
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
198
201
203+196
189
208+195
207
194
205
206
209
THE ACADEMY OF NATURAL SCIENCES
0.18
0.31
5.19
0.17
0.14
0.68
0.09
0.53
0.23
0.02
1.13
0.34
0.03
31.63
2.44
0.50
0.28
0.91
0.69
0.25
13.02
1.28
0.64
0.13
0.20
1.00
0.39
0.20
0.15
0.20
1.88
0.28
0.04
0.10
0.87
0.06
1.01
1.33
0.04
0.69
0.04
0.45
0.04
0.30
0.02
0.02
0.04
1.41
0.07
0.01
0.05
0.01
0.02
0.02
0.00
0.03
0.05
0.01
4.53
0.11
0.02
0.04
0.06
0.01
0.03
0.75
0.08
0.02
0.04
0.03
0.10
0.06
0.02
0.02
0.05
0.10
0.10
0.01
0.01
0.15
0.02
0.50
0.09
0.02
0.07
0.01
0.03
0.01
0.02
0.01
68
13%
13%
27%
43%
5%
7%
14%
3%
8%
0%
2%
14%
39%
14%
4%
5%
14%
6%
2%
12%
6%
6%
3%
32%
13%
10%
15%
13%
13%
26%
5%
36%
31%
13%
17%
39%
50%
7%
49%
10%
41%
6%
35%
8%
25%
1.9
3.32
2.1
1.4
7.1
1.3
5.7
2.2
0.33
11
3.5
0.45
21.6
5.2
1.388
9.8
1.2
3.7
200
15
7.7
0.47
2.2
11
5.7
3.69
2.07
2.14
24
2.4
0.45
1
12.1
0.67
15
17
0.18
8.0776
0.48
6.9
0.4
4.2
0.095
0.19
0.332
6.34
0.21
0.14
0.71
0.13
0.57
0.22
0.033
1.1
0.35
0.045
10.03
2.16
0.52
0.1388
0.98
0.12
0.37
20
1.5
0.77
0.047
0.22
1.1
0.57
0.369
0.207
0.214
2.4
0.24
0.045
0.1
1.21
0.067
1.5
1.7
0.018
0.80776
0.048
0.69
0.04
0.42
0.0095
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 11. Spike recoveries (ng) for F2 fractions.
Compound Mass
spk 1
alpha BHC
beta BHC
lindane
delta BHC
aldrin
heptachlor
epoxide
gamma chlordane
endosulfan I
alpha chlordane
dieldrin
o,p DDD
endrin
endosulfan II
p,p DDD
o,p DDT
p,p DDT
Mass
spk 2
Mass
spk 3
Mass
spk 4
Mass
spk 5
Ave.
Mass
STD
Mass
Mass in Recovery
Spike
(%)
9.12
46.84
7.36
6.30
1.41
11.93
9.66
44.59
7.71
8.16
0.86
11.05
9.29
42.81
7.41
8.00
0.85
11.76
8.77
31.62
6.89
7.14
0.95
11.53
8.50
30.15
6.35
6.90
0.60
8.89
9.07
39.20
7.15
7.30
0.93
11.03
0.45
7.74
0.53
0.78
0.30
1.24
9.57
33.20
7.13
8.77
9.59
9.22
95%
118%
100%
83%
10%
120%
7.68
9.85
8.61
8.84
9.21
27.38
4.99
27.84
12.52
6.92
8.04
10.27
8.87
10.74
9.14
28.37
5.48
29.11
10.34
6.81
7.15
9.88
8.42
10.38
8.92
27.27
4.65
28.24
10.19
7.22
6.50
9.00
8.25
9.95
8.20
24.72
5.20
25.87
8.89
7.68
6.26
8.61
7.38
8.33
7.69
22.15
4.43
24.46
7.98
6.03
7.13
9.52
8.31
9.65
8.63
25.98
4.95
27.10
9.98
6.93
0.76
0.69
0.57
1.02
0.66
2.53
0.42
1.90
1.72
0.61
7.14
9.60
8.45
10.15
8.53
26.31
8.00
29.40
26.04
6.89
100%
99%
98%
95%
101%
99%
62%
92%
38%
101%
Average Recovery 88%
With the exception of two compounds, the remaining OCPs (those that did not elute in F1) had
recoveries ranging from 62 to 120 % (Table 11). The recovery of o,p-DDT was low (40%) but still
is in the range of acceptable recoveries (40-120 %). It is not known why aldrin had such a low
recovery. For the NIST Interlaboratory Comparison exercise, ANS’s assigned concentration of
aldrin was 2.39 ng/g wet wgt while the NIST assigned value was <1 ng/g wet wgt. NIST considered
this within its acceptable range.
Comparison of Methods (Congener specific versus Aroclor Method): The majority of the t-PCB
concentrations reported in studies associated with consumption guidelines were derived from a
quantitation procedure that involves matching Aroclor patterns rather than summing individual
congeners (as was done in this study). During the acquisition of data in this study, the question arose
as to the comparability of concentrations determined by these two methods. To address this, five
extracted and analyzed samples were subsequently sent to US EPA’s Environmental Science Center
for analysis according to EPA’s SOP R3-QA207.1, a consolidated method derived from EPA
methods NPDES 608, RCRA 8081 and 8082, and the Superfund CLP Statement of Work. The
concentrations determined by the two methods were similar (Table 12) and had relative percent
differences ranging from 2 to 26%. From this limited data set, it is likely that the two analytical
methods used to determine t-PCBs are very similar with respect to the concentrations they supply,
suggesting that past data sets that were reliant on the ‘Aroclor method’ may be directly compared
to those generated in this investigation. The issue of how different extraction and clean up
procedures would determine final t-PCB values was not addressed. However, it is likely that small
differences in analytical ‘work-up’ procedures would not have a significant impact on the final
concentration.
THE ACADEMY OF NATURAL SCIENCES
69
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 12.
A comparison of two quantitation methods: The Aroclor method (samples sent to US EPA)
versus congener-specific determination (this study).
Common Name
Location
t-PCBs by
Cong-Spec
(PCER)
ng/g wet wgt
t-PCB by
‘Aroclor’
(US EPA)
ng/g wet wgt
RPD
%
American Eel
Mullica River
151
126
18
Striped Bass
Delaware Bay
1267
1021
22
Bluefish
Atlantic Ocean, Central
1193
1332
11
Large Mouth Bass
Pennsauken Creek
561
907
47
Carp
Copper River Lake
1052
980
7
THE ACADEMY OF NATURAL SCIENCES
70
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix II
Raw Data
THE ACADEMY OF NATURAL SCIENCES
71
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Concentrations in ng/g wet wgt)
ONGENER:
Sample ID
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
33+53+21
22
45
46
52
49
47+48
44
Detection Limits
0.38
0.84
0.24
0.07
0.15
0.28
0.25
0.45
0.34
0.26
0.12
0.37
0.18
0.25
0.86
1.10
0.56
0.77
0.17
0.23
0.33
0.24
1.06
0.25
F-2836
F-2837
F-2838
F-2840
F-2841
F-2842
F-2843
F2844
F-2845
F-2846
F-2847
F-2848
F2849
F2850
F-2851
F-2853
F-2854
F-2855
F-2856
F-2857
F-2858
F-2859
F-2860
F-2861
F-2862
F-2863
F-2864
F-2865
F-2866
F-2936
F-2937
F-2938
F-2939
F-2940
F-2945
F-2946
F-2947
F-2948
F-2949
F-2950
F-2951
F-2952
F-2953
F-2954
F-2955
F-2956
F-2957
F-2958
F-2959
F-2960
F-2961
F-2962
F-2963
F-2964
F-2965
F-2966
F-2967
BDL
ND
ND
0.70
0.45
0.41
1.08
BDL
0.56
BDL
0.86
0.39
ND
0.70
BDL
0.41
ND
BDL
0.56
0.94
0.53
ND
ND
ND
BDL
ND
ND
ND
ND
ND
ND
0.64
0.48
BDL
BDL
BDL
0.48
1.78
3.01
8.00
BDL
4.75
0.89
1.00
0.73
BDL
0.43
0.51
0.53
BDL
ND
BDL
0.48
0.99
0.48
0.51
0.52
1.00
BDL
BDL
1.09
2.13
3.46
BDL
2.17
BDL
2.22
BDL
1.68
ND
ND
BDL
BDL
ND
0.93
BDL
1.02
BDL
11.79
8.54
1.49
BDL
ND
ND
ND
1.47
ND
5.40
2.51
BDL
ND
2.13
2.90
BDL
BDL
3.01
1.56
1.21
2.95
4.68
1.00
BDL
BDL
BDL
BDL
BDL
ND
ND
BDL
0.86
1.22
1.35
BDL
BDL
0.26
0.25
0.29
BDL
BDL
BDL
BDL
0.35
0.35
0.31
ND
BDL
ND
ND
BDL
BDL
BDL
BDL
BDL
ND
BDL
0.50
0.48
0.34
0.33
0.34
BDL
BDL
BDL
0.93
0.71
2.22
BDL
BDL
BDL
0.25
0.48
BDL
3.01
BDL
BDL
0.25
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.96
BDL
0.38
1.01
BDL
0.31
0.28
0.21
0.18
0.27
BDL
BDL
BDL
BDL
BDL
BDL
0.26
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.10
0.13
BDL
BDL
1.51
0.70
0.72
0.11
0.15
BDL
BDL
0.17
ND
0.08
0.12
BDL
0.07
BDL
ND
0.48
0.51
3.01
BDL
BDL
2.95
0.10
BDL
BDL
BDL
BDL
0.51
BDL
BDL
0.08
0.07
BDL
0.08
BDL
BDL
0.52
5.09
3.83
5.79
ND
ND
BDL
BDL
0.18
0.16
0.59
BDL
BDL
BDL
BDL
BDL
0.75
1.25
1.60
1.59
0.44
0.18
64.00
21.75
11.43
BDL
1.62
0.25
0.34
2.29
1.87
0.26
BDL
0.16
0.61
0.51
0.49
0.48
BDL
0.41
1.28
0.20
0.65
0.20
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
6.81
5.75
7.35
2.17
4.64
1.10
ND
1.72
2.47
6.15
1.28
0.72
BDL
BDL
BDL
0.93
BDL
2.55
2.06
0.58
0.42
49.99
23.72
13.05
2.95
1.81
0.35
1.16
2.72
BDL
5.11
3.14
1.62
1.33
1.89
2.47
0.48
0.51
1.33
1.18
0.79
2.92
1.34
0.95
0.35
0.67
0.40
0.46
0.76
0.36
1.02
0.90
0.80
0.99
0.62
2.09
2.14
BDL
0.35
0.58
BDL
BDL
ND
BDL
BDL
0.55
0.67
BDL
ND
BDL
BDL
ND
BDL
BDL
0.47
0.44
BDL
BDL
1.00
1.24
0.47
ND
0.28
BDL
BDL
BDL
BDL
0.38
0.32
BDL
BDL
BDL
BDL
0.48
0.51
3.01
1.10
0.36
1.44
BDL
BDL
0.25
0.43
BDL
0.51
0.53
BDL
ND
ND
0.48
BDL
0.48
0.51
0.52
0.66
BDL
BDL
BDL
0.45
BDL
BDL
BDL
BDL
BDL
BDL
ND
0.68
0.70
BDL
BDL
BDL
BDL
BDL
0.81
BDL
0.74
BDL
BDL
BDL
BDL
BDL
0.59
BDL
BDL
0.54
BDL
BDL
BDL
0.49
BDL
0.48
BDL
0.53
0.55
0.46
1.36
0.79
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
2.35
2.75
6.31
BDL
BDL
BDL
BDL
1.58
4.50
3.15
0.81
BDL
BDL
BDL
BDL
0.81
0.47
0.66
0.94
0.73
0.71
14.44
8.96
5.99
0.41
2.64
0.56
0.74
1.47
BDL
3.71
0.56
1.56
1.42
1.25
1.30
0.48
BDL
BDL
2.14
0.44
3.09
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.54
BDL
BDL
1.33
1.62
3.83
BDL
0.27
BDL
ND
0.79
2.48
1.65
0.34
0.30
BDL
BDL
0.31
0.32
BDL
0.34
0.54
BDL
0.46
8.04
4.76
3.51
BDL
1.68
BDL
0.55
0.94
BDL
1.73
BDL
0.83
0.57
0.63
0.67
0.48
0.51
0.36
BDL
0.28
1.20
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.32
0.65
0.31
0.95
BDL
BDL
0.33
BDL
0.25
0.65
0.64
0.15
0.52
1.45
1.36
1.31
1.60
ND
0.45
1.71
1.05
0.96
2.31
2.72
1.00
ND
0.85
0.34
0.71
0.57
ND
1.22
0.19
0.44
0.43
0.21
0.20
0.48
0.72
1.15
3.37
0.26
7.57
0.30
0.14
BDL
0.43
0.15
0.51
0.13
0.64
ND
BDL
0.13
ND
0.48
0.51
0.52
2.34
2.22
5.41
BDL
0.43
0.56
BDL
1.85
4.70
4.58
0.67
ND
0.68
BDL
BDL
1.32
0.78
0.87
1.74
0.73
1.21
13.34
8.05
5.34
BDL
3.43
0.46
1.04
1.97
0.44
5.56
0.46
1.82
1.93
1.71
1.69
0.48
BDL
1.03
0.38
BDL
0.84
0.74
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.21
BDL
BDL
BDL
BDL
BDL
0.18
BDL
BDL
0.41
0.27
BDL
BDL
0.19
BDL
BDL
BDL
ND
ND
BDL
BDL
BDL
BDL
BDL
0.48
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.52
1.76
1.46
3.17
0.45
0.53
1.20
BDL
1.39
1.81
1.61
BDL
0.28
0.30
0.30
BDL
0.57
0.71
0.67
0.34
0.49
0.49
5.72
5.83
2.59
0.77
1.89
0.48
0.47
1.77
0.34
4.56
0.37
0.97
2.32
0.40
0.79
0.37
BDL
1.34
0.76
BDL
1.46
1.29
0.27
0.31
BDL
0.32
BDL
BDL
BDL
0.41
ND
BDL
0.30
0.37
BDL
BDL
1.65
1.58
2.12
BDL
BDL
BDL
BDL
1.18
0.98
1.30
BDL
0.99
1.24
1.20
BDL
0.98
BDL
1.04
1.21
0.94
BDL
3.21
4.64
2.27
BDL
2.90
1.61
2.20
2.03
ND
2.04
BDL
BDL
1.08
BDL
BDL
BDL
BDL
BDL
ND
BDL
1.40
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
15.65
17.45
43.85
1.35
1.50
13.42
BDL
14.87
30.06
6.26
4.36
2.64
2.44
1.98
1.54
3.86
4.93
5.70
4.13
4.48
4.61
70.32
65.31
20.42
9.30
16.10
2.33
3.54
11.71
6.12
30.07
18.16
10.61
10.61
5.01
7.20
BDL
2.77
2.59
2.42
2.21
5.50
BDL
1.33
1.12
BDL
BDL
BDL
1.67
3.22
5.87
1.83
2.78
5.89
8.36
9.04
BDL
3.83
4.35
7.34
0.62
BDL
2.83
BDL
2.42
3.16
5.89
1.01
BDL
BDL
1.64
BDL
1.04
1.13
2.01
0.94
1.00
1.13
12.25
12.05
7.89
1.18
4.14
1.45
BDL
2.77
0.88
3.06
BDL
2.80
1.23
1.63
2.95
BDL
BDL
1.29
1.54
BDL
0.73
0.99
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1.18
BDL
BDL
BDL
1.78
2.26
7.09
1.41
4.80
1.99
BDL
3.92
5.11
5.67
1.66
BDL
0.84
BDL
BDL
1.02
0.87
1.33
0.98
BDL
0.78
13.28
9.26
4.60
2.08
3.65
1.19
1.01
1.99
2.14
13.69
4.62
3.59
2.74
2.38
5.78
1.32
1.26
6.18
1.56
1.77
4.17
2.38
3.06
BDL
1.67
0.97
0.86
1.67
0.79
0.93
BDL
BDL
1.95
1.19
BDL
3.20
2.43
2.44
1.58
ND
ND
4.87
ND
2.64
5.08
2.12
ND
0.79
0.65
0.65
0.25
1.24
0.32
1.81
1.95
0.79
0.90
9.17
3.35
2.50
1.44
1.54
0.54
0.56
1.99
1.86
19.87
1.89
7.34
5.89
8.33
10.33
0.72
0.79
2.65
0.58
0.93
3.04
1.92
2.74
0.78
0.99
0.58
1.37
BDL
0.73
0.62
0.27
BDL
0.73
2.75
0.72
11.16
0.67
0.52
0.94
0.45
1.33
1.44
BDL
0.95
0.56
1.72
0.40
0.36
0.61
0.46
0.24
0.56
0.26
1.62
0.64
0.54
0.45
3.38
2.21
1.21
0.30
1.13
0.65
0.96
0.82
0.67
1.83
0.32
0.52
0.58
0.28
0.78
0.48
BDL
0.31
BDL
0.28
0.44
BDL
BDL
BDL
BDL
BDL
BDL
0.27
BDL
ND
BDL
BDL
ND
0.30
BDL
0.26
14.04
21.52
18.62
8.14
14.80
12.56
2.47
8.82
18.26
20.44
5.89
1.89
1.88
BDL
BDL
6.83
5.48
8.56
5.82
5.11
4.19
58.91
29.68
21.59
9.92
9.69
2.10
4.29
10.66
7.11
15.61
9.31
6.72
8.02
5.14
7.86
0.41
0.55
1.52
0.69
1.62
3.00
BDL
BDL
3.75
2.96
BDL
0.46
0.38
1.98
5.49
3.03
1.50
3.61
9.81
7.03
2.86
12.52
14.32
16.72
1.15
2.05
2.20
0.58
6.76
15.17
14.85
4.65
0.55
0.34
BDL
BDL
5.48
3.81
5.88
3.59
4.60
4.07
52.24
24.83
19.51
2.43
8.32
1.74
3.63
9.11
3.22
14.83
1.57
5.45
7.02
4.08
7.40
0.43
0.51
1.63
0.32
1.09
2.95
1.89
1.34
0.65
0.56
0.42
0.96
1.38
BDL
2.26
0.39
BDL
0.85
1.89
1.16
0.39
24.08
22.82
29.50
11.75
14.93
9.79
2.88
5.00
ND
12.72
1.92
4.01
5.29
1.73
1.79
11.10
8.96
12.06
8.13
10.20
8.34
63.15
ND
22.67
23.02
9.65
ND
6.08
9.42
5.62
11.65
BDL
4.47
6.72
2.68
6.62
BDL
1.27
1.59
9.53
BDL
7.24
BDL
BDL
8.16
2.99
BDL
BDL
BDL
3.02
10.12
4.27
4.94
8.82
10.77
8.13
2.82
10.92
7.21
7.63
1.89
4.26
2.70
0.93
8.63
6.60
18.10
4.62
0.50
0.27
ND
6.28
3.86
3.68
6.04
3.38
2.63
2.78
55.54
25.70
19.60
8.27
8.01
1.45
2.67
8.05
3.43
13.44
2.37
5.65
6.34
4.12
6.12
BDL
0.29
1.30
0.41
1.19
1.37
0.86
0.68
1.12
0.90
0.33
0.44
0.59
BDL
2.96
0.51
0.28
0.96
1.82
1.60
0.43
Concentrations in ng/g wet wgt)
ONGENER:
Sample ID
F-2968
F-2969
F-2970
F-2971
F-2972
F-2973
F-2974
F-2975
F-2976
F-2977
F-2978
F-2979
F-2980
F-2981
F-2982
F-2983
F-2984
F-2985
F-2986
F-2987
F-2988
F-2989
F-2990
F-2991
F-2992
F-2993
F-2994
F-2995
F-2996
F-2998
F-2999
F-3000
F-3001
F-3002
F-3003
F-3004
F-3005
F-3006
F-3007
F-3008
F-3009
F-3010
F-3011
F-3012
F-3013
F-3014
F-3015
F-3016
F-3017
F-3018
F-3019
F-3020
F-3021
F-3022
F-3025
F-3026
F-3027
F-3028
F-3029
F-3030
1
0.51
ND
0.50
0.53
1.34
0.49
1.36
ND
ND
0.48
0.55
0.82
0.50
0.52
0.60
0.45
0.52
ND
ND
ND
BDL
ND
0.59
ND
ND
BDL
ND
ND
ND
1.32
BDL
BDL
BDL
0.54
0.50
0.50
0.55
0.48
0.50
0.51
BDL
ND
BDL
0.97
ND
ND
BDL
ND
BDL
7.58
1.64
2.06
1.97
1.77
BDL
ND
ND
BDL
ND
0.43
3
BDL
ND
BDL
BDL
ND
BDL
1.22
ND
ND
BDL
BDL
ND
BDL
BDL
BDL
BDL
ND
1.45
2.08
2.31
ND
2.18
0.93
ND
BDL
BDL
ND
BDL
BDL
1.43
1.00
1.01
BDL
1.17
0.88
BDL
BDL
BDL
1.18
BDL
BDL
BDL
BDL
BDL
ND
ND
ND
ND
ND
2.98
2.19
ND
ND
ND
BDL
BDL
1.67
0.89
ND
ND
4+10
BDL
ND
0.37
BDL
BDL
0.35
ND
0.80
BDL
BDL
0.39
0.47
BDL
BDL
0.62
0.60
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.36
BDL
BDL
BDL
0.29
BDL
0.30
BDL
0.29
BDL
BDL
0.74
0.33
BDL
0.50
0.87
BDL
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
1.97
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
7
BDL
ND
BDL
0.53
BDL
0.19
ND
0.07
ND
BDL
BDL
BDL
BDL
BDL
0.20
0.45
BDL
0.09
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.08
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.48
BDL
0.07
BDL
BDL
BDL
0.11
BDL
ND
BDL
BDL
BDL
0.15
0.13
BDL
BDL
BDL
BDL
0.23
0.17
0.28
0.08
BDL
6
BDL
ND
0.23
0.15
0.56
BDL
BDL
0.27
0.26
0.25
BDL
0.46
0.20
BDL
BDL
BDL
BDL
0.35
0.24
0.35
0.32
0.40
0.45
0.36
BDL
BDL
0.47
0.27
0.45
0.29
BDL
BDL
BDL
BDL
BDL
0.68
0.33
0.26
BDL
1.04
0.70
0.34
0.32
0.48
0.66
0.45
0.31
BDL
0.27
ND
0.21
0.36
BDL
0.31
0.17
7.70
4.08
0.34
0.32
BDL
8+5
0.55
ND
0.37
0.53
0.68
2.38
0.92
0.77
0.29
0.67
1.18
0.80
0.50
0.60
1.10
0.55
0.65
1.37
2.04
1.81
0.46
1.43
0.50
0.48
0.94
0.29
1.27
0.60
0.62
0.54
0.87
0.35
1.76
1.05
BDL
1.50
1.12
1.21
BDL
2.61
ND
0.40
0.44
1.06
ND
ND
ND
0.57
0.39
1.69
1.62
0.90
0.62
1.96
0.36
10.72
5.22
3.36
1.47
1.04
19
0.51
ND
0.50
0.53
BDL
BDL
BDL
BDL
BDL
0.48
BDL
BDL
BDL
0.52
BDL
0.45
BDL
0.46
0.72
BDL
BDL
BDL
BDL
BDL
0.36
ND
BDL
BDL
ND
BDL
0.49
0.50
BDL
0.54
0.50
BDL
BDL
BDL
0.50
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
ND
ND
ND
BDL
ND
0.40
0.34
BDL
0.25
BDL
12+13
BDL
ND
BDL
BDL
BDL
BDL
BDL
0.53
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.54
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
ND
BDL
0.72
0.58
BDL
BDL
0.51
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
18
BDL
ND
BDL
BDL
0.42
0.53
BDL
0.84
0.63
BDL
0.55
BDL
0.78
1.86
0.86
BDL
0.86
1.11
1.60
0.81
0.61
1.06
0.75
1.06
2.29
0.34
1.24
1.16
1.19
BDL
0.49
BDL
BDL
BDL
BDL
2.21
0.61
1.46
BDL
2.20
0.41
BDL
0.67
0.57
BDL
0.53
BDL
BDL
BDL
0.40
BDL
BDL
BDL
0.40
0.53
3.06
3.39
0.55
2.21
0.41
17
BDL
ND
BDL
BDL
BDL
0.53
BDL
BDL
0.34
BDL
0.54
BDL
0.98
1.93
0.85
0.35
0.84
0.60
1.06
0.76
0.38
0.78
0.54
0.84
1.58
BDL
0.91
0.91
0.75
BDL
BDL
BDL
BDL
BDL
BDL
1.76
0.46
1.24
BDL
2.12
BDL
BDL
0.64
0.38
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.26
0.39
1.75
1.99
0.28
1.56
0.47
24+27
0.51
ND
0.50
0.53
ND
BDL
ND
ND
0.37
0.48
BDL
ND
0.50
1.54
0.18
0.45
0.37
0.75
1.42
0.27
0.37
0.40
1.02
0.35
1.04
0.15
0.45
0.18
0.17
0.54
BDL
0.50
0.50
BDL
BDL
0.72
0.55
0.72
0.50
0.61
0.35
0.14
ND
1.06
ND
BDL
ND
0.54
1.17
0.69
0.73
0.79
1.16
0.98
ND
0.58
0.59
BDL
0.30
0.55
16+32
BDL
ND
BDL
BDL
0.59
0.52
0.41
1.04
0.54
BDL
1.10
BDL
1.20
2.96
1.43
0.63
1.02
1.97
3.29
1.25
0.86
1.88
1.35
1.35
2.55
0.49
2.17
1.45
1.17
BDL
BDL
BDL
BDL
BDL
0.40
2.77
0.89
2.26
BDL
3.17
0.48
0.42
0.98
0.80
0.45
0.74
BDL
BDL
0.43
1.02
0.38
0.58
BDL
0.86
0.86
2.46
2.94
0.43
2.33
0.68
29
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
26
BDL
ND
BDL
0.78
ND
2.16
ND
ND
0.40
BDL
0.61
0.31
0.49
1.82
0.35
0.34
1.48
0.59
1.35
1.23
0.86
0.56
0.67
0.72
0.74
0.52
0.81
0.77
0.66
BDL
BDL
BDL
0.39
BDL
BDL
0.87
BDL
0.94
BDL
1.40
0.31
ND
ND
0.60
BDL
0.59
BDL
0.76
0.82
0.74
0.33
0.43
0.48
0.36
1.41
1.37
1.58
1.41
1.08
2.56
25
BDL
ND
BDL
BDL
BDL
BDL
1.20
BDL
BDL
BDL
BDL
BDL
BDL
1.14
1.70
BDL
1.24
1.04
1.07
0.97
1.01
1.08
0.99
BDL
BDL
BDL
BDL
BDL
0.87
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1.70
BDL
1.08
0.94
0.91
BDL
BDL
BDL
BDL
BDL
BDL
1.04
1.04
BDL
0.97
1.09
0.89
BDL
BDL
1.24
BDL
BDL
1.06
31+28
3.40
ND
2.86
7.38
3.91
7.24
6.70
3.07
2.01
2.13
6.81
2.07
3.19
6.72
6.74
BDL
8.54
6.29
9.84
3.48
2.70
3.06
3.08
5.72
3.63
3.97
10.63
9.31
5.83
18.48
7.19
3.39
4.46
BDL
3.00
16.76
3.85
8.56
BDL
15.21
2.35
2.10
2.82
2.69
1.25
4.05
1.76
2.37
2.71
12.90
3.18
2.42
2.16
3.82
7.88
20.60
16.88
22.01
11.90
7.61
33+53+21
BDL
ND
BDL
BDL
1.35
1.05
1.43
0.71
BDL
BDL
2.76
BDL
1.48
3.98
2.40
1.28
BDL
2.88
4.72
1.54
1.58
1.76
0.95
1.57
1.74
BDL
1.68
2.31
1.44
BDL
BDL
BDL
BDL
BDL
BDL
3.08
BDL
4.77
BDL
4.05
BDL
BDL
BDL
0.59
BDL
1.22
BDL
BDL
1.13
2.35
0.80
BDL
2.11
2.32
2.14
0.66
0.78
1.67
1.27
0.77
22
BDL
ND
BDL
BDL
1.41
10.21
1.66
1.19
BDL
BDL
4.64
0.84
BDL
1.90
3.54
0.83
1.18
0.81
2.14
BDL
BDL
0.79
0.86
1.18
BDL
BDL
1.33
1.09
1.02
BDL
1.02
BDL
1.57
BDL
BDL
2.11
0.80
2.44
BDL
2.03
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.98
3.83
1.05
1.01
1.32
2.38
0.90
1.93
2.00
2.33
2.45
2.89
45
1.49
ND
1.17
2.19
2.83
5.47
2.98
1.23
1.07
0.76
5.40
0.73
1.34
1.76
1.45
0.80
0.84
0.92
1.22
1.12
1.11
0.90
0.93
0.94
0.84
BDL
1.04
0.75
0.67
0.72
0.90
0.47
2.06
0.29
0.34
1.78
0.76
2.80
BDL
2.12
0.41
0.32
0.36
0.62
0.46
0.89
0.30
0.96
0.64
3.96
2.22
0.29
0.31
3.23
0.58
0.77
2.13
2.38
1.62
0.87
46
BDL
ND
0.41
0.47
0.32
0.81
ND
0.48
0.39
BDL
1.01
BDL
0.60
0.64
1.84
0.30
0.50
0.75
1.06
0.59
0.51
0.60
0.42
0.47
0.33
0.29
0.42
0.34
0.28
BDL
BDL
BDL
0.41
BDL
BDL
0.44
0.52
0.93
BDL
0.91
0.26
BDL
0.29
0.26
BDL
0.23
BDL
0.51
0.40
1.14
0.65
0.51
0.45
0.68
BDL
0.52
0.61
0.67
0.53
1.90
52
4.32
ND
4.99
5.12
14.32
28.37
12.87
1.85
4.08
3.55
5.60
1.50
4.61
8.43
9.17
2.99
10.50
8.84
11.43
7.10
5.69
3.99
3.27
5.30
4.33
6.30
9.15
8.18
5.32
4.45
3.17
0.59
3.68
0.47
2.39
10.68
4.93
15.62
0.66
17.56
4.47
3.15
2.96
3.75
2.69
5.41
2.80
1.48
3.65
19.09
4.45
0.48
0.43
2.18
14.76
11.88
11.04
20.06
4.96
19.53
49
1.02
ND
1.03
1.74
3.24
4.96
2.11
1.52
3.84
3.30
4.68
1.40
3.64
8.80
10.21
2.73
10.91
7.77
10.10
6.87
4.78
3.58
2.99
4.89
4.29
4.90
7.99
7.16
4.85
1.26
0.48
BDL
0.87
BDL
2.25
9.71
4.34
14.53
0.56
17.82
3.21
2.65
2.55
3.17
2.07
4.95
2.49
0.81
0.96
7.12
0.96
2.58
1.66
2.44
15.72
10.43
9.56
3.46
7.37
2.72
47+48
6.01
ND
4.26
18.50
19.18
38.48
19.87
1.83
4.99
3.64
7.54
1.85
3.91
10.00
1.68
3.30
18.31
17.81
21.67
15.37
11.17
9.61
6.60
9.56
4.49
11.97
16.09
17.54
10.18
BDL
6.92
3.03
6.89
BDL
3.97
10.30
5.96
19.09
BDL
19.44
ND
6.55
5.93
6.94
5.52
ND
6.15
6.87
8.09
53.21
5.00
3.23
3.51
7.58
24.89
18.38
ND
42.32
13.98
21.43
44
0.63
ND
1.41
2.04
4.28
8.73
3.54
1.34
2.59
2.16
4.18
1.10
2.96
5.33
8.00
1.98
4.97
6.41
8.89
4.24
3.79
2.89
2.31
3.76
2.56
ND
6.85
7.34
7.98
1.38
1.19
BDL
1.07
BDL
1.38
8.19
3.09
10.76
0.26
11.44
8.63
ND
7.93
2.24
1.52
2.83
ND
1.04
1.39
10.44
1.21
0.75
0.56
0.94
8.10
3.50
4.22
7.90
8.27
4.52
Concentrations in ng/g wet wgt)
ONGENER:
Sample ID
F-3031
F-3032
F-3033
F-3034
F3035
F-3036
F-3037
F-3038
F-3039
F-3040
F-3041
F-3042
F-3043
F-3044
F-3045
F-3046
F-3047
F-3048
F-3049
F-3050
F-3051
F-3052
F-3053
F-3054
F-3055
F-3058
F-3059
F-3060
F-3061
F-3062
F-3063
F-3064
F-3065
F-3066
F-3067
F-3068
F-3069
F3070
F-3071
F-3072
F-3073
F-3074
F-3075
F-3076
F-3077
F-3078
F-3079
F-3080
F-3081
F-3082
F-3083
F-3084
F-3085
F-3086
F-3087
F-3088
F-3089
F-3090
F-3091
F-3092
1
1.10
0.47
ND
0.46
1.09
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.93
0.93
2.16
ND
4.13
2.26
1.24
1.50
3.59
2.60
1.34
ND
ND
ND
2.34
ND
ND
1.96
ND
1.37
2.19
0.49
2.06
ND
ND
1.58
0.54
0.54
2.84
0.55
0.53
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
3
4.89
BDL
ND
BDL
BDL
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
18.36
2.18
3.42
ND
4.72
ND
ND
ND
7.32
5.57
ND
ND
ND
ND
5.49
ND
ND
2.90
ND
2.06
2.08
2.58
1.95
ND
ND
ND
BDL
BDL
1.61
BDL
BDL
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
4+10
BDL
0.54
BDL
0.56
0.33
ND
ND
BDL
0.28
1.07
ND
BDL
ND
BDL
BDL
0.27
BDL
BDL
0.59
0.34
0.33
0.57
0.39
BDL
BDL
0.30
BDL
0.36
0.55
ND
ND
ND
0.37
1.39
0.57
ND
2.17
BDL
0.48
BDL
0.97
0.26
0.69
BDL
BDL
BDL
1.01
BDL
0.53
BDL
ND
BDL
BDL
ND
BDL
BDL
ND
BDL
ND
ND
7
BDL
0.99
BDL
0.25
ND
ND
ND
BDL
ND
0.86
ND
ND
ND
ND
ND
BDL
ND
BDL
0.08
BDL
BDL
0.12
0.09
ND
ND
BDL
0.17
ND
0.12
0.18
0.11
0.15
0.54
0.15
0.16
0.28
0.55
0.08
0.37
BDL
0.12
BDL
0.54
0.15
0.54
0.54
BDL
0.55
0.53
ND
ND
BDL
ND
ND
ND
ND
ND
ND
ND
ND
6
0.25
0.53
0.49
0.21
0.28
0.27
ND
0.18
1.54
0.86
ND
ND
BDL
BDL
ND
0.22
BDL
BDL
0.88
0.75
0.84
1.29
0.75
0.17
0.30
1.85
0.63
1.15
1.42
ND
0.75
0.86
0.59
0.66
0.70
1.04
1.98
2.18
2.05
0.47
0.38
1.34
0.72
0.66
0.54
0.38
BDL
BDL
0.43
ND
ND
ND
0.17
ND
0.86
ND
ND
BDL
ND
ND
8+5
1.54
12.62
0.70
4.16
1.28
0.56
0.34
0.69
1.31
2.85
BDL
0.30
0.94
2.04
0.74
2.94
0.90
0.94
13.94
6.09
1.49
1.17
2.58
0.44
ND
0.32
0.90
1.53
4.03
3.81
2.34
4.70
1.79
3.89
1.75
ND
6.29
0.36
1.33
2.17
1.03
0.50
0.54
1.08
BDL
0.42
1.83
0.56
0.39
ND
ND
BDL
ND
BDL
0.40
0.42
2.19
ND
ND
ND
19
BDL
BDL
BDL
0.25
ND
BDL
ND
BDL
BDL
0.42
ND
ND
ND
ND
ND
BDL
ND
BDL
0.28
BDL
0.36
0.84
BDL
BDL
ND
BDL
BDL
BDL
BDL
BDL
ND
0.27
BDL
0.29
0.53
0.37
0.55
BDL
0.26
BDL
0.33
0.26
0.54
ND
0.54
0.32
0.38
BDL
0.53
ND
ND
BDL
ND
ND
ND
ND
ND
ND
ND
ND
12+13
BDL
BDL
BDL
BDL
ND
ND
ND
BDL
1.27
BDL
ND
BDL
ND
BDL
ND
BDL
ND
BDL
0.47
BDL
0.52
ND
BDL
ND
ND
ND
BDL
BDL
BDL
ND
ND
BDL
BDL
0.54
0.53
0.55
0.55
ND
BDL
ND
ND
BDL
0.54
0.54
0.54
BDL
ND
BDL
0.53
ND
ND
BDL
ND
ND
ND
ND
ND
ND
ND
ND
18
0.55
1.46
1.12
0.66
BDL
0.64
0.35
1.17
2.68
4.35
BDL
BDL
BDL
BDL
ND
1.51
0.75
0.57
3.95
2.06
1.67
1.17
2.24
0.53
0.36
0.65
0.72
0.53
2.27
3.11
1.49
2.28
0.43
3.82
0.36
0.66
1.46
0.40
0.49
1.53
0.45
0.93
0.46
0.38
BDL
0.69
3.23
1.26
BDL
ND
BDL
BDL
BDL
ND
BDL
BDL
ND
ND
ND
ND
17
0.52
0.52
0.76
0.38
0.33
0.43
BDL
0.87
0.40
2.58
BDL
BDL
ND
BDL
ND
0.95
0.58
0.32
1.60
1.10
0.75
1.04
1.13
ND
ND
0.44
0.52
0.32
1.38
1.97
0.82
1.47
BDL
2.19
BDL
0.58
0.28
0.31
0.28
0.99
0.33
0.68
0.35
BDL
BDL
0.55
2.83
1.30
BDL
ND
BDL
BDL
BDL
ND
BDL
BDL
ND
ND
ND
ND
24+27
0.25
ND
0.14
BDL
ND
ND
ND
0.22
3.30
0.67
BDL
ND
ND
BDL
ND
0.16
ND
BDL
0.38
0.38
0.56
0.31
0.49
0.24
0.22
0.15
ND
BDL
0.37
0.38
ND
0.40
0.35
0.41
0.53
ND
0.55
BDL
0.31
0.24
0.34
BDL
0.54
0.48
BDL
0.41
0.41
0.40
0.53
ND
ND
BDL
BDL
ND
ND
ND
ND
ND
ND
ND
16+32
1.24
0.59
1.23
BDL
0.73
0.78
0.44
1.32
1.08
7.58
BDL
BDL
BDL
0.39
BDL
2.17
0.75
0.83
3.24
2.44
2.20
2.54
2.19
BDL
BDL
1.26
0.56
0.69
2.60
2.59
1.58
2.45
BDL
4.04
0.57
0.89
0.84
BDL
0.69
1.96
0.54
1.12
0.62
1.17
BDL
0.95
3.94
2.12
BDL
ND
BDL
BDL
BDL
0.69
BDL
BDL
ND
ND
ND
BDL
29
0.20
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.56
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
ND
ND
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
ND
ND
BDL
BDL
26
1.25
4.99
0.59
1.29
0.32
BDL
BDL
0.86
0.50
0.54
BDL
BDL
BDL
BDL
ND
1.18
0.48
0.32
1.71
1.36
1.13
1.32
0.91
0.41
BDL
0.66
2.20
0.33
0.89
1.41
0.46
1.11
0.45
3.25
0.40
1.73
0.28
BDL
0.38
0.37
0.28
0.78
0.41
ND
BDL
0.54
1.38
0.63
BDL
ND
BDL
0.31
0.60
0.56
1.15
BDL
ND
ND
ND
0.53
25
1.60
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.96
2.53
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1.07
BDL
BDL
BDL
BDL
BDL
BDL
1.16
BDL
BDL
BDL
BDL
BDL
BDL
ND
0.88
BDL
BDL
BDL
BDL
1.01
BDL
BDL
ND
BDL
BDL
BDL
ND
ND
ND
ND
ND
ND
BDL
31+28
2.96
48.86
5.45
22.67
4.58
2.85
BDL
2.31
1.38
28.46
BDL
BDL
BDL
1.76
ND
5.96
2.30
BDL
13.27
10.59
6.85
7.46
12.79
1.43
BDL
8.55
11.42
6.62
13.38
5.14
1.97
10.01
2.03
25.96
3.13
7.63
3.55
2.04
4.66
8.76
4.76
7.74
2.61
2.19
1.12
2.79
13.27
1.80
BDL
ND
BDL
BDL
ND
BDL
ND
1.68
ND
ND
ND
BDL
33+53+21
BDL
2.47
BDL
1.39
2.36
1.01
ND
1.68
0.74
7.68
BDL
BDL
ND
1.00
ND
1.39
0.96
0.67
2.42
1.83
3.05
2.13
1.87
BDL
BDL
1.58
ND
1.32
2.62
ND
ND
2.74
BDL
5.45
BDL
0.96
1.52
0.65
0.84
2.19
1.03
1.39
BDL
1.93
BDL
0.75
4.48
1.84
BDL
ND
ND
0.76
BDL
ND
BDL
BDL
ND
ND
ND
ND
22
1.13
5.08
0.77
3.36
2.33
1.06
BDL
1.70
1.76
10.29
BDL
BDL
BDL
0.83
ND
3.63
0.98
1.24
11.58
11.09
1.23
1.04
3.35
0.78
BDL
0.78
0.87
3.07
2.98
2.29
1.89
2.41
1.30
3.70
BDL
0.85
1.71
BDL
BDL
0.93
1.90
0.81
BDL
0.81
BDL
BDL
1.82
BDL
BDL
ND
BDL
BDL
BDL
ND
ND
BDL
ND
ND
ND
ND
45
1.59
4.20
0.65
2.49
3.37
ND
ND
1.22
1.29
0.54
0.18
0.37
1.12
3.07
0.63
ND
ND
3.75
ND
18.27
0.77
1.36
1.17
0.37
0.38
0.35
0.91
0.31
1.58
1.63
0.94
1.47
0.35
2.17
0.27
1.56
1.07
0.56
0.59
1.17
0.32
0.86
0.22
0.87
BDL
0.33
1.57
0.63
BDL
ND
0.61
0.28
0.25
ND
1.41
0.45
ND
ND
ND
BDL
46
0.82
0.83
0.28
0.36
BDL
0.26
ND
0.30
BDL
1.49
BDL
BDL
BDL
BDL
ND
0.26
BDL
BDL
1.75
1.01
0.46
0.90
1.18
BDL
BDL
0.88
ND
0.47
0.69
0.30
0.39
0.49
BDL
0.86
BDL
ND
0.33
BDL
0.23
0.81
0.45
0.30
BDL
0.52
BDL
BDL
0.71
0.31
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
ND
ND
ND
BDL
52
6.82
55.06
5.58
19.69
24.03
2.11
2.03
5.27
3.10
24.06
BDL
0.47
0.34
1.17
BDL
5.48
3.36
2.39
15.88
8.80
6.86
11.69
12.54
2.04
2.26
11.91
15.83
6.56
9.95
12.62
6.81
10.00
1.37
26.42
5.88
8.43
6.68
4.38
5.39
10.26
5.27
9.77
4.04
1.52
1.71
3.84
13.47
7.08
1.64
2.09
2.05
5.39
7.20
10.74
14.46
7.17
1.05
0.42
BDL
BDL
49
1.13
18.69
4.91
4.02
3.34
2.23
1.67
4.47
2.63
22.41
BDL
0.36
0.80
2.95
0.59
4.78
3.01
1.86
11.14
7.85
5.57
11.78
11.84
1.58
1.56
9.80
15.18
6.21
8.60
10.78
5.83
8.68
1.29
23.21
5.16
6.76
6.58
2.84
4.41
8.43
4.83
8.74
3.33
1.22
1.48
3.58
12.82
6.63
1.17
BDL
0.87
4.72
1.13
3.06
3.06
0.88
0.33
BDL
BDL
BDL
47+48
7.36
66.25
5.71
24.84
5.63
2.43
ND
5.06
10.89
21.14
BDL
BDL
BDL
BDL
ND
2.22
1.53
BDL
2.18
1.26
3.71
11.74
7.70
2.42
BDL
1.87
13.22
ND
8.91
ND
ND
9.29
1.25
23.75
5.50
8.30
7.61
BDL
2.21
10.17
2.43
BDL
3.41
3.24
2.16
2.61
4.25
7.67
1.74
ND
2.91
16.41
9.94
ND
12.98
8.34
BDL
ND
ND
BDL
44
1.64
8.81
7.63
8.05
8.79
2.32
1.31
3.56
2.46
22.38
BDL
0.26
0.37
1.04
BDL
4.47
2.22
1.89
12.49
7.30
3.92
5.51
8.08
1.11
1.14
6.02
5.26
3.71
8.48
10.10
5.30
8.31
0.82
17.16
3.49
3.10
3.44
2.38
2.93
7.02
3.29
5.24
2.10
0.66
1.10
2.24
7.96
3.75
0.90
0.30
0.54
1.82
1.47
4.72
4.36
1.67
0.37
BDL
BDL
BDL
Concentrations in ng/g wet wgt)
ONGENER:
Sample ID
F-3093
F-3094
F-3095
F-3096
F-3097
F-3098
F-3099
F-3100
F-3101
F-3102
F-3103
1
ND
ND
ND
ND
2.33
1.25
1.97
ND
ND
ND
ND
3
ND
ND
ND
ND
BDL
2.28
1.88
ND
ND
ND
ND
4+10
ND
ND
ND
BDL
0.54
0.97
0.56
0.99
ND
ND
0.53
7
ND
ND
ND
ND
0.09
0.11
BDL
BDL
ND
BDL
ND
6
ND
ND
ND
0.45
1.49
0.49
0.73
ND
ND
BDL
0.94
8+5
BDL
ND
BDL
0.41
3.64
2.96
1.36
1.06
ND
BDL
0.98
19
BDL
ND
ND
ND
0.39
0.25
BDL
ND
ND
ND
BDL
12+13
ND
ND
ND
BDL
BDL
BDL
BDL
BDL
ND
BDL
ND
18
BDL
ND
ND
BDL
0.54
2.38
0.93
BDL
BDL
BDL
2.07
17
BDL
ND
ND
BDL
2.92
2.19
0.46
BDL
BDL
BDL
2.93
24+27
ND
ND
ND
ND
0.91
0.76
0.17
ND
ND
0.24
0.20
16+32
BDL
BDL
BDL
0.47
4.94
3.56
1.32
BDL
ND
ND
2.31
29
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
26
BDL
BDL
ND
BDL
2.11
1.41
1.22
BDL
ND
BDL
3.66
25
ND
ND
BDL
BDL
BDL
BDL
BDL
BDL
ND
BDL
2.05
31+28
BDL
ND
ND
ND
23.55
18.68
11.31
BDL
BDL
ND
18.61
33+53+21
BDL
ND
ND
BDL
4.88
4.41
1.62
BDL
ND
BDL
3.32
22
BDL
ND
ND
BDL
2.88
3.38
2.41
BDL
ND
BDL
3.17
45
ND
ND
BDL
0.32
1.80
1.64
0.53
0.81
BDL
0.27
1.26
46
BDL
ND
ND
ND
0.73
1.29
0.93
BDL
ND
ND
0.80
52
0.93
1.21
0.56
1.22
24.14
14.93
13.15
1.56
BDL
BDL
18.89
49
0.25
0.32
BDL
BDL
23.29
15.40
8.16
0.50
ND
BDL
20.18
47+48
BDL
ND
BDL
BDL
30.46
3.75
2.42
1.15
BDL
BDL
17.36
44
0.27
0.33
BDL
BDL
14.09
9.65
7.00
0.34
BDL
BDL
10.43
F-3104
F-3105
F-3106
F-3107
F-3108
F-3109
F-3110
F-3111
F-3112
F-3113
F-3114
F-3115
F-3116
F-3117
F-3118
F-3119
F-3120
F-3121
F-3122
F-3123
F-3124
F-3125
F-3126
F-3127
F-3128
F-3129
F-3130
F-3131
F-3132
F-3133
F-3134
F-3135
F-3165
F-3166
F-3167
F-3168
F-3169
F-3170
F-3171
F-3172
F-3173
F-3174
F-3175
F-3176
F-3177
F-3178
F-3179
F-3180
0.53
ND
ND
1.05
ND
ND
ND
ND
0.61
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.54
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.97
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
BDL
ND
ND
2.79
ND
ND
ND
ND
1.77
ND
ND
ND
4.92
ND
ND
ND
ND
ND
ND
ND
ND
BDL
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.53
0.40
ND
BDL
2.03
0.50
ND
ND
BDL
BDL
0.36
1.08
3.67
5.29
BDL
BDL
ND
0.56
0.38
ND
ND
0.48
0.80
0.27
ND
BDL
BDL
ND
ND
ND
ND
ND
0.26
BDL
ND
ND
0.37
BDL
BDL
1.56
1.66
BDL
0.37
3.06
1.89
3.07
0.56
ND
0.53
ND
ND
BDL
0.11
0.53
ND
ND
0.10
BDL
0.55
ND
0.67
0.09
ND
BDL
ND
BDL
0.07
ND
ND
0.54
ND
0.55
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.10
BDL
0.10
ND
ND
ND
ND
0.09
ND
0.12
0.08
0.29
ND
ND
0.32
2.16
0.84
0.17
0.36
0.28
0.62
0.50
ND
1.07
0.75
BDL
BDL
0.49
2.52
0.24
1.09
ND
0.22
0.82
0.27
ND
BDL
BDL
ND
ND
BDL
ND
0.93
ND
ND
ND
ND
1.10
0.39
BDL
0.24
1.25
ND
5.18
ND
1.62
1.45
0.56
0.46
0.44
0.62
ND
0.42
2.10
0.53
0.34
ND
BDL
0.54
0.55
1.18
9.18
1.08
0.37
0.42
BDL
0.81
0.51
0.76
0.50
0.54
0.38
1.04
ND
BDL
BDL
0.30
BDL
ND
ND
0.36
0.43
0.47
BDL
0.38
4.54
0.51
0.63
6.28
7.23
0.33
1.14
1.50
5.52
10.27
1.58
1.93
BDL
ND
BDL
BDL
BDL
0.53
ND
ND
BDL
BDL
0.55
BDL
BDL
BDL
ND
BDL
ND
ND
BDL
BDL
BDL
0.54
0.49
BDL
ND
BDL
BDL
BDL
BDL
BDL
ND
ND
ND
ND
ND
ND
ND
BDL
ND
0.35
ND
BDL
BDL
BDL
0.56
0.65
BDL
ND
BDL
ND
ND
ND
BDL
0.53
ND
BDL
ND
0.54
0.55
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
ND
ND
0.54
ND
0.55
ND
ND
ND
BDL
BDL
BDL
ND
BDL
ND
ND
ND
ND
ND
BDL
ND
BDL
0.48
ND
ND
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.38
BDL
BDL
BDL
BDL
0.75
BDL
0.49
1.01
BDL
BDL
0.43
BDL
BDL
BDL
1.18
0.54
0.38
1.14
1.29
ND
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
0.37
BDL
BDL
BDL
0.45
BDL
4.08
6.13
BDL
2.02
BDL
4.71
10.58
1.57
0.69
BDL
BDL
BDL
BDL
0.98
BDL
BDL
ND
BDL
0.60
0.55
BDL
0.28
0.47
0.27
0.47
BDL
BDL
BDL
1.18
0.62
0.35
0.98
0.87
BDL
BDL
BDL
BDL
0.85
ND
ND
BDL
BDL
0.36
BDL
ND
ND
BDL
BDL
2.51
2.97
BDL
0.68
0.40
2.93
5.73
0.80
0.29
0.53
ND
ND
0.14
BDL
0.53
ND
0.40
BDL
0.16
0.55
ND
BDL
ND
0.14
BDL
ND
ND
ND
0.30
0.13
0.54
0.39
0.15
ND
ND
ND
ND
ND
0.50
ND
ND
ND
ND
ND
ND
ND
0.20
0.25
0.51
0.76
ND
0.98
0.18
0.92
1.47
0.18
BDL
0.47
BDL
BDL
BDL
1.38
0.42
BDL
BDL
BDL
1.40
0.72
0.38
BDL
ND
0.38
0.61
BDL
ND
BDL
2.18
1.04
0.49
1.97
2.10
ND
BDL
BDL
BDL
BDL
BDL
ND
BDL
0.39
0.78
BDL
ND
0.49
0.53
BDL
6.39
7.28
BDL
0.92
0.57
8.32
13.04
2.04
0.75
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.58
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
0.25
ND
0.37
1.06
0.29
BDL
BDL
0.33
0.48
0.55
BDL
BDL
0.40
BDL
BDL
BDL
BDL
BDL
1.11
0.72
BDL
0.65
0.99
ND
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
ND
ND
0.97
0.48
BDL
2.18
6.21
BDL
0.45
0.69
2.97
6.52
0.71
0.27
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
ND
BDL
ND
ND
BDL
BDL
ND
ND
BDL
ND
ND
ND
BDL
BDL
BDL
1.50
2.96
BDL
ND
BDL
2.12
3.38
BDL
BDL
1.53
1.55
ND
2.30
6.78
3.61
2.51
ND
1.65
2.11
1.75
3.82
BDL
2.14
2.07
BDL
1.51
2.10
BDL
7.02
3.73
1.54
4.33
8.86
BDL
BDL
BDL
2.83
1.66
ND
ND
BDL
BDL
ND
BDL
ND
BDL
4.40
BDL
20.26
41.97
BDL
5.44
5.81
24.67
32.34
8.41
BDL
BDL
BDL
BDL
ND
2.27
0.88
ND
BDL
BDL
0.76
BDL
0.58
ND
BDL
BDL
BDL
BDL
ND
BDL
2.81
1.60
BDL
1.56
3.13
ND
BDL
BDL
0.81
BDL
1.24
ND
ND
BDL
ND
ND
ND
ND
0.79
BDL
5.29
9.22
BDL
2.16
0.98
10.09
18.06
2.83
BDL
BDL
BDL
BDL
BDL
1.19
BDL
BDL
ND
BDL
BDL
BDL
0.81
BDL
BDL
BDL
0.98
BDL
BDL
BDL
1.15
BDL
BDL
BDL
1.78
BDL
BDL
BDL
1.23
BDL
0.82
ND
BDL
BDL
1.20
BDL
BDL
1.22
1.28
BDL
8.24
13.07
BDL
2.11
3.63
7.36
17.09
2.90
1.90
0.36
0.51
BDL
ND
1.42
0.48
0.32
BDL
BDL
0.32
0.27
1.85
0.29
0.58
0.44
0.75
0.27
0.58
1.34
1.57
0.70
0.20
0.73
1.52
BDL
0.26
ND
2.50
0.64
1.02
ND
2.83
0.35
0.72
BDL
ND
1.82
1.22
0.52
13.88
18.59
0.47
1.80
ND
10.61
16.14
ND
3.55
BDL
BDL
ND
BDL
0.74
0.24
0.26
ND
BDL
BDL
BDL
1.78
BDL
BDL
BDL
BDL
BDL
0.53
0.73
0.84
0.39
BDL
0.34
0.66
BDL
BDL
BDL
0.57
BDL
0.29
ND
0.65
BDL
0.26
BDL
ND
0.56
0.38
0.23
2.85
2.27
BDL
0.82
0.63
2.00
1.93
0.73
0.27
3.44
3.58
0.48
0.37
11.21
8.91
4.85
1.05
0.68
3.53
4.10
13.48
0.60
3.53
1.65
2.16
1.48
3.13
2.19
11.88
6.65
2.52
5.28
14.24
BDL
1.48
0.40
3.36
0.56
BDL
BDL
4.63
0.83
3.23
0.69
0.63
2.66
3.16
1.48
13.75
40.01
1.14
5.09
5.12
18.13
26.13
9.10
2.98
3.21
0.34
BDL
BDL
11.49
8.80
4.83
BDL
BDL
2.64
3.31
1.62
0.24
0.62
1.54
2.02
1.31
0.89
BDL
11.50
6.67
2.11
4.76
11.20
ND
1.13
BDL
1.24
BDL
BDL
BDL
1.21
0.96
3.02
0.69
0.60
3.37
3.03
1.35
12.18
35.83
0.97
4.86
4.08
17.42
23.29
8.65
2.38
4.19
3.18
BDL
BDL
11.38
10.01
4.74
1.17
BDL
3.10
4.16
3.66
BDL
3.62
BDL
1.70
1.26
2.75
BDL
13.52
7.77
2.38
4.82
14.31
ND
1.29
BDL
2.96
1.59
BDL
ND
2.81
1.21
2.72
BDL
ND
ND
2.13
2.17
10.97
24.05
1.08
5.38
3.23
22.08
22.52
11.53
2.11
2.07
0.49
BDL
BDL
6.84
4.42
2.92
BDL
BDL
2.06
2.26
4.04
0.33
0.59
0.71
1.12
0.50
1.44
BDL
7.96
3.81
1.52
3.16
9.60
BDL
0.92
BDL
1.10
BDL
BDL
BDL
1.34
0.61
1.30
0.25
0.41
1.67
1.47
0.76
11.95
37.04
0.70
3.55
3.94
15.43
24.07
7.42
2.15
Concentrations in ng/g wet wgt)
ONGENER:
Sample ID
F-3181
F-3182
F-3183
F-3184
F-3185
F-3186
F-3187
F-3188
F-3189
F-3190
F-3191
F-3192
F-3193
F-3194
F-3195
F-3196
F-3197
F-3198
F-3199
F-3200
F-3201
F-3202
F-3203
F-3204
F-3205
F-3206
F-3207
F-3208
F-3209
F-3210
F-3211
F-3212
F-3213
F-3214
F-3215
F-3216
F-3217
F-3218
F-3219
F-3220
F-3221
F-3222
F-3223
F-3224
F-3225
F-3226
F-3227
F-3228
F-3229
F-3230
F-3231
F-3232
F-3233
F-3234
1
ND
ND
ND
ND
9.19
ND
2.00
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.74
0.55
0.53
0.53
0.54
0.55
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.55
ND
ND
ND
ND
ND
ND
ND
ND
2.49
ND
ND
ND
ND
9.76
ND
ND
ND
ND
3
ND
ND
ND
ND
2.17
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
BDL
BDL
BDL
BDL
BDL
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
BDL
ND
ND
ND
2.32
ND
ND
ND
ND
8.54
ND
ND
ND
ND
4.45
ND
ND
ND
ND
4+10
0.25
ND
BDL
ND
BDL
ND
0.32
0.53
ND
ND
ND
ND
ND
BDL
BDL
BDL
BDL
0.55
1.58
1.63
1.51
2.16
0.37
BDL
ND
BDL
BDL
BDL
BDL
BDL
ND
BDL
ND
BDL
ND
0.55
BDL
0.34
ND
BDL
0.82
ND
ND
ND
0.95
1.01
1.97
ND
ND
0.53
1.24
ND
BDL
ND
7
ND
ND
BDL
ND
BDL
ND
BDL
ND
ND
ND
ND
ND
ND
BDL
ND
BDL
BDL
0.55
0.53
0.53
0.54
0.55
0.09
ND
ND
ND
ND
BDL
BDL
BDL
ND
0.54
ND
BDL
ND
0.55
0.07
0.09
ND
BDL
ND
ND
ND
ND
0.31
0.35
0.24
BDL
BDL
0.53
0.36
ND
BDL
ND
6
ND
BDL
ND
BDL
BDL
ND
0.31
ND
ND
ND
ND
ND
0.21
BDL
BDL
ND
BDL
0.45
1.50
0.80
0.54
1.27
0.28
ND
BDL
ND
ND
ND
BDL
BDL
BDL
0.54
0.39
0.24
0.74
0.55
0.18
0.32
1.48
0.15
0.67
ND
ND
BDL
0.82
0.27
0.45
ND
ND
2.25
0.85
0.22
BDL
ND
8+5
1.75
0.43
ND
0.33
0.77
ND
2.86
2.02
0.41
ND
ND
BDL
ND
0.75
0.38
0.90
0.62
1.07
2.58
3.16
2.83
3.27
1.84
0.49
0.35
0.53
0.41
BDL
1.03
2.79
0.74
2.33
0.66
1.03
2.40
0.55
1.04
1.07
1.76
5.69
2.66
ND
0.69
0.42
11.00
2.20
8.62
0.70
1.14
3.36
5.34
0.36
0.56
0.58
19
ND
ND
ND
ND
ND
ND
BDL
BDL
ND
ND
ND
ND
ND
ND
ND
ND
BDL
BDL
0.53
0.53
0.54
BDL
BDL
ND
ND
ND
ND
ND
BDL
ND
ND
0.54
ND
ND
0.33
0.55
ND
ND
ND
BDL
BDL
ND
ND
BDL
BDL
0.51
0.93
ND
ND
1.65
0.96
BDL
BDL
ND
12+13
ND
BDL
ND
ND
ND
ND
BDL
BDL
ND
ND
ND
ND
ND
BDL
ND
0.50
0.57
BDL
0.59
BDL
0.54
1.07
BDL
BDL
ND
ND
ND
ND
ND
BDL
ND
0.54
BDL
BDL
0.99
0.55
BDL
BDL
ND
BDL
1.09
ND
ND
ND
0.54
BDL
ND
ND
ND
0.49
0.62
ND
BDL
ND
18
0.75
BDL
0.35
BDL
0.89
ND
1.06
1.00
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.40
0.56
2.67
3.02
0.94
3.63
1.43
BDL
BDL
BDL
BDL
BDL
0.59
0.88
BDL
0.52
BDL
BDL
2.01
BDL
0.37
0.86
0.53
0.69
2.09
BDL
0.52
BDL
12.19
3.92
6.28
0.36
1.36
4.96
5.99
0.37
BDL
0.47
17
ND
BDL
BDL
ND
ND
ND
0.74
0.71
BDL
BDL
BDL
BDL
BDL
0.36
ND
BDL
0.49
0.38
1.24
1.57
0.37
1.94
0.87
0.37
ND
BDL
BDL
BDL
0.40
0.28
BDL
0.39
BDL
0.27
0.31
BDL
0.33
0.47
0.41
BDL
0.98
BDL
0.32
BDL
5.78
1.93
3.82
BDL
0.78
3.90
3.99
0.54
BDL
0.37
24+27
ND
0.38
BDL
0.30
0.61
ND
0.21
ND
ND
ND
0.16
BDL
BDL
0.20
BDL
0.13
ND
BDL
0.29
0.41
0.54
0.57
BDL
ND
ND
ND
ND
BDL
BDL
BDL
0.24
0.54
BDL
0.39
1.99
BDL
ND
BDL
ND
BDL
0.13
ND
BDL
0.16
1.37
0.51
1.22
0.58
0.15
1.46
0.95
BDL
0.18
ND
16+32
0.82
BDL
BDL
BDL
BDL
BDL
1.31
1.27
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.48
0.58
0.88
2.70
3.47
1.19
4.33
1.65
BDL
BDL
BDL
BDL
BDL
0.44
0.70
BDL
0.49
BDL
0.42
0.77
0.47
0.46
2.17
0.88
0.74
2.14
BDL
0.49
BDL
12.15
5.04
8.35
ND
1.73
10.02
9.24
0.46
BDL
0.41
29
ND
BDL
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
ND
ND
ND
ND
BDL
BDL
BDL
BDL
BDL
BDL
ND
0.53
BDL
BDL
BDL
BDL
26
ND
BDL
BDL
ND
0.54
ND
0.41
0.28
BDL
BDL
BDL
BDL
ND
BDL
BDL
0.26
1.02
0.39
0.94
2.10
0.38
2.24
0.77
BDL
BDL
BDL
BDL
BDL
BDL
0.56
BDL
0.29
BDL
BDL
0.60
BDL
0.30
0.69
0.66
0.77
1.18
ND
BDL
BDL
5.61
2.14
2.82
0.67
0.59
3.19
3.78
BDL
ND
BDL
25
ND
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
ND
BDL
ND
BDL
ND
BDL
BDL
BDL
BDL
1.07
BDL
1.22
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1.06
BDL
BDL
BDL
BDL
BDL
BDL
ND
ND
BDL
2.78
1.15
1.22
ND
BDL
2.99
2.70
ND
BDL
BDL
31+28
BDL
BDL
BDL
ND
BDL
ND
5.64
3.79
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
5.41
3.86
11.31
15.69
4.02
17.69
3.11
BDL
BDL
BDL
BDL
1.64
1.19
3.69
ND
3.34
BDL
2.21
1.26
1.23
3.35
3.33
1.78
ND
13.86
BDL
2.01
BDL
41.21
12.71
34.92
1.63
11.55
27.42
32.57
1.59
1.67
BDL
33+53+21
1.23
BDL
BDL
BDL
0.83
ND
0.75
0.72
BDL
BDL
ND
BDL
BDL
BDL
ND
BDL
0.70
0.87
2.54
1.69
1.48
2.86
1.66
BDL
BDL
BDL
BDL
BDL
BDL
0.66
BDL
BDL
BDL
BDL
0.85
BDL
BDL
BDL
0.93
1.29
1.58
ND
BDL
BDL
16.67
5.56
4.59
BDL
0.95
8.29
4.18
BDL
0.58
BDL
22
1.96
0.96
1.45
BDL
0.90
BDL
2.67
2.27
BDL
BDL
BDL
BDL
BDL
1.48
BDL
0.97
2.65
1.61
5.64
6.64
2.03
11.22
4.36
0.81
0.82
BDL
BDL
BDL
0.80
1.19
1.21
1.06
BDL
1.09
1.67
BDL
1.70
2.09
2.67
1.83
4.83
BDL
0.82
BDL
18.79
6.35
10.48
0.87
3.96
11.26
11.18
BDL
BDL
BDL
45
4.60
0.53
0.93
0.36
ND
0.51
0.40
8.04
ND
ND
ND
ND
BDL
1.50
ND
1.18
2.36
0.55
7.19
9.14
3.09
18.64
4.42
1.21
ND
0.21
0.40
BDL
ND
1.09
1.84
0.54
0.45
0.84
0.86
BDL
0.40
ND
4.57
2.00
BDL
0.31
ND
0.53
0.54
5.91
10.37
ND
ND
0.53
11.18
ND
0.25
ND
46
BDL
BDL
BDL
BDL
BDL
0.51
0.38
0.54
BDL
BDL
BDL
BDL
ND
BDL
BDL
0.31
ND
BDL
0.33
0.79
0.24
0.55
0.82
BDL
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
0.27
BDL
0.24
BDL
BDL
0.36
0.69
0.44
0.73
BDL
BDL
BDL
0.52
0.82
1.87
BDL
0.92
2.38
2.30
BDL
BDL
BDL
52
4.28
1.04
1.63
BDL
BDL
0.43
3.90
3.83
0.81
0.68
BDL
0.36
BDL
0.38
BDL
1.82
2.04
7.52
10.24
14.07
3.51
20.50
7.63
BDL
0.57
BDL
0.66
0.44
0.45
1.00
BDL
1.00
1.11
1.50
2.90
1.75
0.99
4.39
4.51
6.53
9.25
1.38
1.50
1.71
57.16
12.97
21.87
0.86
3.81
21.19
25.32
1.37
3.92
0.57
49
3.35
0.64
1.21
BDL
0.26
0.30
2.78
3.24
0.68
0.43
BDL
0.33
BDL
1.08
0.54
1.70
3.24
6.63
9.88
12.81
3.65
15.65
6.06
0.88
0.65
0.28
0.58
0.49
0.54
1.25
0.63
1.48
0.79
1.14
2.49
1.63
0.90
3.74
ND
4.49
8.15
1.10
1.28
1.42
33.79
10.82
18.58
1.10
6.17
18.91
22.29
1.06
1.91
0.67
47+48
3.07
ND
1.55
1.25
7.16
ND
2.18
2.36
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
4.51
9.54
15.43
16.78
5.05
16.53
4.25
BDL
BDL
BDL
BDL
BDL
BDL
1.37
BDL
1.22
BDL
BDL
6.10
2.34
1.12
3.54
2.76
4.42
7.33
ND
1.09
1.76
14.38
10.68
18.21
BDL
7.07
17.75
18.91
1.07
BDL
BDL
44
2.93
0.67
1.02
BDL
BDL
BDL
2.63
2.97
0.56
0.50
BDL
0.39
BDL
0.72
BDL
1.27
1.68
5.24
12.44
11.81
3.48
22.56
5.33
0.68
BDL
BDL
0.39
BDL
0.36
1.13
0.34
1.27
0.58
1.03
1.65
0.98
0.60
3.15
5.23
4.54
7.69
0.50
0.65
0.57
48.04
11.84
21.43
0.85
5.59
19.66
24.35
1.00
1.85
0.63
Concentrations in ng/g wet wgt)
Sample ID
37+42
41+71
64
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
81+87
85
136
77+110
82
151
135+144
107
149
Detection Limits
0.08
0.11
0.16
0.09
0.13
0.12
0.27
0.27
0.62
0.13
0.27
0.22
0.24
0.12
0.08
0.29
0.10
0.06
0.31
0.07
0.09
0.08
0.07
0.26
F-2836
F-2837
F-2838
F-2840
F-2841
F-2842
F-2843
F2844
F-2845
F-2846
F-2847
F-2848
F2849
F2850
F-2851
F-2853
F-2854
F-2855
F-2856
F-2857
F-2858
F-2859
F-2860
F-2861
F-2862
F-2863
F-2864
F-2865
F-2866
F-2936
F-2937
F-2938
F-2939
F-2940
F-2945
F-2946
F-2947
F-2948
F-2949
F-2950
F-2951
F-2952
F-2953
F-2954
F-2955
F-2956
F-2957
F-2958
F-2959
F-2960
F-2961
F-2962
F-2963
F-2964
F-2965
F-2966
F-2967
7.81
15.05
17.34
2.74
ND
4.15
ND
4.86
17.32
9.69
0.97
0.62
0.43
0.11
BDL
3.04
2.56
4.13
2.64
2.24
2.05
32.50
12.13
11.25
3.58
5.36
1.15
1.98
5.55
3.29
10.65
2.34
4.02
4.39
2.80
4.34
0.48
0.59
0.73
0.21
0.76
1.68
0.59
1.09
0.56
0.93
0.43
0.28
0.36
0.34
2.58
0.46
0.25
0.85
2.70
1.74
4.28
8.86
8.84
13.67
ND
ND
ND
ND
1.72
14.53
9.07
8.24
ND
ND
ND
BDL
2.09
2.22
3.28
1.68
1.77
2.20
88.79
18.06
31.13
1.67
6.58
1.51
2.46
6.89
ND
8.09
0.51
2.89
4.04
2.09
2.64
0.48
0.17
0.35
0.17
0.42
0.66
0.34
1.00
0.29
0.43
0.51
0.17
0.23
ND
ND
ND
0.48
ND
0.48
0.51
0.52
4.73
10.02
15.22
5.27
8.71
5.89
1.44
2.51
11.55
8.07
ND
0.79
0.68
BDL
BDL
1.74
1.32
2.78
1.68
1.41
1.34
ND
10.21
ND
ND
3.36
0.78
1.54
3.71
2.45
6.69
3.82
2.43
2.81
2.02
3.29
BDL
0.26
0.31
BDL
0.61
0.79
0.38
0.38
1.08
1.17
BDL
0.22
0.37
0.67
2.22
0.84
0.67
1.69
4.16
2.64
1.24
2.13
6.04
8.00
0.39
0.99
0.41
ND
1.79
9.54
2.54
0.43
BDL
ND
0.10
BDL
1.32
1.45
2.10
1.16
1.05
1.28
8.15
3.53
2.40
5.75
1.60
0.24
0.43
1.36
0.49
5.01
0.59
0.68
1.23
0.25
1.99
0.48
BDL
3.01
BDL
0.11
0.35
0.24
0.26
0.19
0.15
0.14
BDL
0.10
BDL
0.34
BDL
BDL
0.29
BDL
0.22
0.39
1.60
1.76
2.37
0.63
ND
0.76
ND
0.60
1.93
0.63
BDL
0.26
0.31
BDL
ND
1.47
0.69
1.69
0.23
0.83
1.27
5.21
1.40
1.77
0.40
0.84
0.45
0.66
0.90
ND
13.16
0.65
0.48
1.10
0.49
5.48
0.62
0.51
3.01
BDL
1.00
2.95
1.06
2.17
1.56
1.94
0.67
0.51
0.31
0.32
0.74
0.29
0.19
0.74
0.54
0.51
0.52
1.07
1.38
2.32
0.82
1.36
0.91
0.33
1.08
0.67
1.65
0.60
0.12
BDL
BDL
BDL
0.84
0.89
1.15
ND
0.65
0.46
5.23
1.41
1.83
2.99
0.45
0.15
0.30
0.53
0.73
1.52
0.43
0.66
0.76
0.54
1.25
0.97
BDL
0.35
0.59
BDL
0.51
0.13
0.12
1.01
0.42
BDL
BDL
BDL
0.15
0.26
0.23
0.12
0.24
0.80
0.54
0.83
11.80
0.92
1.10
3.90
6.61
6.86
1.45
4.06
1.52
11.87
3.99
1.34
1.19
0.44
BDL
6.18
0.85
5.66
7.01
4.95
3.02
46.99
21.01
14.63
0.88
5.91
1.60
3.68
8.06
3.63
11.68
11.64
3.46
4.02
3.68
6.83
1.16
1.02
10.42
0.58
0.95
2.91
2.18
4.02
3.26
4.66
1.41
0.33
0.55
2.03
6.84
2.95
3.45
6.16
9.75
8.01
2.12
21.65
10.93
10.20
0.99
1.41
2.47
0.34
7.57
13.16
21.80
4.79
0.37
BDL
BDL
BDL
7.57
4.62
9.70
5.53
5.29
5.68
86.95
40.12
26.61
8.78
10.31
1.95
4.57
11.64
3.54
17.31
1.14
6.63
8.10
5.73
7.66
0.37
0.61
1.80
0.80
1.63
2.22
BDL
BDL
0.32
BDL
BDL
BDL
0.28
0.29
1.23
0.71
0.29
0.61
1.64
2.00
1.03
24.00
26.91
26.30
11.26
22.00
19.55
4.00
18.62
17.79
67.43
16.02
3.18
3.27
0.71
BDL
33.65
8.17
27.88
22.62
24.01
16.90
177.31
85.80
64.83
1.19
28.95
6.89
16.67
32.87
7.76
50.32
32.82
21.89
25.54
16.52
31.15
1.12
1.96
7.48
8.65
5.63
9.26
1.83
2.37
10.23
6.32
1.24
1.91
2.25
4.20
19.59
6.84
7.60
14.37
33.71
21.02
4.85
4.97
66.19
54.49
1.06
2.75
2.44
0.55
10.56
61.93
6.21
1.17
0.22
0.20
BDL
0.28
4.32
22.71
21.67
2.12
3.14
1.90
2.37
4.86
5.52
25.42
2.32
0.59
2.20
2.76
1.75
3.88
1.68
2.11
2.07
1.39
2.87
0.19
BDL
0.99
0.26
0.62
0.81
0.23
0.27
1.29
0.65
0.15
0.15
0.60
BDL
0.62
0.23
0.17
0.55
2.28
1.05
1.26
21.71
5.78
3.65
3.08
5.59
5.21
1.24
4.85
4.31
17.02
4.26
0.78
0.64
BDL
BDL
6.81
1.97
9.25
7.75
3.58
4.75
73.66
35.10
26.64
1.47
12.84
2.14
6.89
17.69
4.06
34.62
12.81
25.10
21.91
26.50
37.60
2.25
3.08
11.84
3.17
18.03
15.74
3.32
2.59
6.32
4.79
1.32
3.12
3.51
0.93
4.61
1.73
2.15
4.35
9.98
1.01
2.20
22.59
10.91
8.10
4.80
15.96
9.55
1.84
8.60
10.07
31.06
7.86
2.01
1.08
BDL
BDL
19.20
1.39
14.72
14.46
13.99
8.73
52.09
23.48
22.24
5.72
11.01
3.87
8.81
13.12
6.43
20.47
7.95
11.85
12.95
12.03
20.87
0.77
1.34
8.79
1.88
2.63
6.43
0.48
0.54
7.63
3.98
0.35
0.87
0.72
1.02
3.63
2.37
1.56
3.16
14.73
5.95
3.63
16.53
30.48
16.00
14.81
23.33
14.88
3.74
7.73
20.02
22.67
4.24
4.33
2.98
0.51
BDL
19.34
15.51
22.26
14.69
15.20
9.26
44.28
20.20
16.04
9.24
8.08
3.08
6.83
10.15
6.88
ND
22.34
7.60
7.94
8.00
9.52
2.05
1.77
10.48
1.79
2.16
6.35
5.54
8.58
14.04
6.07
2.86
0.77
2.19
4.01
10.68
7.00
7.75
12.54
22.21
13.28
26.11
2.10
19.79
18.94
0.55
0.87
0.74
0.19
9.64
70.10
2.27
0.46
0.16
0.21
BDL
0.72
1.40
4.69
12.44
1.67
1.02
0.70
5.73
2.39
2.00
57.11
0.86
0.24
0.51
0.90
0.79
4.34
1.10
1.61
1.58
1.52
3.67
0.31
0.20
1.54
0.19
0.38
0.64
0.69
1.03
2.01
1.38
0.39
BDL
BDL
BDL
0.34
0.22
0.18
0.58
1.06
0.94
0.68
6.17
2.26
1.63
0.94
1.91
1.60
0.38
2.18
1.52
10.90
2.20
0.23
0.11
BDL
ND
4.89
0.73
4.44
3.36
3.63
2.04
16.07
7.14
6.65
0.92
3.27
1.00
2.42
4.08
1.68
5.66
1.46
3.45
3.62
3.58
6.13
0.20
0.27
1.65
0.45
0.67
1.53
0.28
0.27
1.09
0.48
0.17
0.29
0.34
0.12
0.94
0.46
0.13
0.54
1.31
1.15
0.53
10.28
10.26
5.19
4.43
6.04
4.49
1.45
3.98
6.52
17.04
3.31
0.78
0.71
BDL
BDL
5.79
3.72
6.85
4.79
3.81
2.78
21.76
9.38
8.72
1.10
3.55
1.14
2.68
4.54
2.16
10.35
3.30
5.69
5.24
5.91
9.93
0.42
0.57
3.18
0.71
1.44
2.58
0.68
0.77
3.61
1.50
0.34
0.57
0.83
0.50
1.57
1.26
0.38
1.32
5.22
2.65
1.46
9.05
65.26
74.15
7.72
8.54
6.47
ND
17.50
178.23
10.52
ND
1.61
1.05
BDL
0.13
5.90
ND
1.56
5.01
4.26
1.69
ND
9.12
ND
ND
3.58
1.18
2.92
4.84
2.48
ND
6.22
2.60
ND
2.77
ND
0.97
0.49
5.39
0.55
0.75
3.21
0.73
0.72
4.89
2.01
0.22
1.02
0.22
1.11
3.41
2.43
2.61
3.09
7.31
5.06
1.95
2.30
13.29
5.91
0.35
0.85
0.55
0.15
1.24
7.94
2.24
0.63
0.12
ND
BDL
2.00
1.90
5.10
5.04
1.40
1.13
1.16
3.69
2.19
1.81
7.59
1.16
0.31
0.80
1.19
0.68
2.36
0.82
1.16
1.49
0.61
1.98
0.97
0.07
0.39
0.15
0.21
0.24
0.09
0.12
0.68
0.28
BDL
0.12
0.17
BDL
0.25
0.10
0.11
0.36
1.05
0.57
0.65
33.50
2.26
1.48
25.17
38.18
22.83
5.97
9.53
2.35
53.57
8.49
4.82
3.10
BDL
BDL
24.25
1.33
18.30
15.33
16.76
10.15
68.75
34.81
31.88
0.79
15.25
4.33
10.09
18.09
10.06
36.80
22.37
18.58
18.50
18.33
29.78
1.22
1.25
5.76
2.37
3.82
6.39
1.66
1.88
21.36
10.78
1.13
1.78
2.17
2.77
6.89
5.56
4.01
7.35
30.83
16.30
10.83
1.80
54.84
27.17
0.83
ND
0.91
0.25
6.68
33.55
4.92
0.43
0.08
ND
ND
0.08
1.20
15.60
15.72
0.89
0.56
0.46
5.86
2.96
2.24
26.84
1.46
0.38
0.55
1.88
0.68
3.64
0.50
1.40
1.41
0.82
2.25
0.97
BDL
0.27
0.17
0.24
0.51
0.20
2.01
0.84
0.29
0.08
0.11
0.14
BDL
0.28
0.17
0.10
0.19
0.29
0.68
1.03
10.37
3.04
1.78
1.30
3.71
1.32
0.27
3.16
2.65
5.91
3.14
0.30
0.21
0.10
BDL
9.56
0.72
6.58
6.59
4.96
4.95
18.14
8.23
6.99
0.38
4.53
1.69
3.94
4.76
1.75
8.13
2.67
4.11
4.70
1.85
7.38
0.15
0.42
2.74
0.46
0.66
1.10
0.26
0.34
3.69
0.99
0.19
0.25
0.37
0.19
0.63
0.35
0.32
1.32
6.84
1.93
1.11
7.17
7.84
5.90
0.93
1.83
1.06
0.25
3.19
7.50
5.35
1.73
0.33
0.36
BDL
BDL
5.19
6.15
7.85
3.71
3.17
2.50
13.94
7.23
6.28
1.17
3.02
0.81
1.93
2.78
1.50
5.10
2.34
2.86
3.08
2.08
5.07
0.10
0.22
1.05
0.31
0.50
0.78
0.20
0.24
2.72
0.95
0.12
0.18
0.26
0.20
0.61
0.42
0.36
0.87
3.95
1.86
0.87
3.22
7.32
5.22
1.54
ND
1.92
0.25
1.61
5.32
2.66
0.70
0.39
0.42
ND
BDL
4.74
3.49
5.24
3.93
3.67
2.05
6.82
3.63
2.50
1.59
1.54
0.60
1.34
1.72
1.36
1.89
0.85
1.31
1.31
1.18
2.92
0.97
0.17
1.22
0.21
0.22
0.67
0.29
0.23
0.13
0.52
0.07
0.09
0.12
0.37
0.68
0.58
0.14
0.91
1.32
1.81
3.31
25.68
7.12
3.97
10.76
20.87
12.48
3.18
8.79
4.69
23.14
8.62
2.56
3.08
BDL
BDL
23.22
6.08
18.41
17.23
15.92
11.70
36.00
19.75
18.40
3.94
10.87
4.11
9.60
11.58
8.00
23.92
13.80
14.95
14.91
11.30
27.54
0.58
0.99
5.27
1.80
2.64
4.45
0.88
1.32
18.37
7.73
0.53
1.02
1.13
1.34
3.40
2.57
2.14
5.11
32.13
10.75
7.73
Concentrations in ng/g wet wgt)
Sample ID
F-2968
F-2969
F-2970
F-2971
F-2972
F-2973
F-2974
F-2975
F-2976
F-2977
F-2978
F-2979
F-2980
F-2981
F-2982
F-2983
F-2984
F-2985
F-2986
F-2987
F-2988
F-2989
F-2990
F-2991
F-2992
F-2993
F-2994
F-2995
F-2996
F-2998
F-2999
F-3000
F-3001
F-3002
F-3003
F-3004
F-3005
F-3006
F-3007
F-3008
F-3009
F-3010
F-3011
F-3012
F-3013
F-3014
F-3015
F-3016
F-3017
F-3018
F-3019
F-3020
F-3021
F-3022
F-3025
F-3026
F-3027
F-3028
F-3029
F-3030
37+42
1.42
ND
0.45
2.18
1.54
4.46
1.96
0.95
1.97
1.85
3.81
0.82
2.28
4.19
5.20
1.38
4.46
4.80
6.50
3.65
3.13
2.23
2.02
3.31
1.81
0.74
5.21
5.98
2.54
1.12
0.88
0.25
1.47
0.15
0.96
5.65
2.49
7.53
0.23
9.36
2.24
0.15
1.72
1.89
1.36
2.49
1.35
0.92
1.38
5.63
1.46
1.16
1.08
1.37
6.41
10.31
9.21
5.71
6.75
2.81
41+71
0.51
ND
0.50
0.53
ND
0.49
ND
ND
ND
1.33
2.44
ND
3.07
6.74
6.63
1.56
3.98
6.58
9.07
4.74
3.87
3.32
2.03
3.72
3.45
0.46
5.11
5.09
3.17
0.24
0.49
BDL
0.50
0.54
1.38
7.92
2.71
11.07
0.50
13.88
2.05
BDL
1.57
1.16
0.92
1.52
0.92
ND
ND
ND
ND
0.32
0.52
0.35
5.77
7.49
6.86
3.28
5.00
ND
64
1.75
ND
2.02
2.80
6.11
17.77
4.86
0.25
0.81
1.02
2.36
0.22
1.50
2.98
4.84
0.98
2.70
3.33
4.59
2.69
2.19
1.62
1.13
1.80
1.45
1.07
2.71
6.72
3.49
2.77
1.29
0.46
2.56
0.25
0.87
3.84
1.83
6.73
0.21
6.75
1.26
ND
1.02
1.14
0.90
1.61
0.88
0.70
1.31
12.24
1.92
0.31
0.38
1.21
5.98
7.06
7.67
ND
4.94
10.41
40
0.51
ND
0.10
BDL
0.29
1.90
0.32
ND
ND
0.43
0.99
ND
0.79
1.61
2.69
0.56
1.97
2.39
2.96
1.92
1.50
1.31
0.94
1.50
0.50
BDL
1.79
2.86
1.79
0.19
0.14
0.11
0.34
BDL
0.42
2.88
1.15
4.12
0.11
4.16
1.41
ND
0.84
1.06
0.43
1.33
0.52
0.18
0.31
1.35
0.41
BDL
BDL
0.54
4.40
4.42
3.73
8.42
3.26
0.77
100
0.48
ND
0.41
3.48
4.20
5.85
4.32
0.25
1.70
1.12
2.99
0.53
0.95
1.66
2.52
0.54
1.35
2.13
1.83
1.83
1.23
1.23
0.64
0.70
0.65
0.42
0.70
0.97
1.20
0.31
0.38
0.24
2.99
BDL
0.30
1.00
0.78
4.39
BDL
0.51
1.02
0.62
0.33
0.69
0.43
0.92
0.37
0.47
1.34
3.94
0.46
BDL
BDL
ND
2.18
1.21
1.24
0.54
1.02
2.19
63
0.32
ND
0.44
1.82
1.76
10.13
1.47
0.14
0.48
0.96
0.68
0.17
0.43
0.88
1.15
0.24
0.97
1.19
1.26
0.82
0.77
0.53
0.44
0.60
0.46
0.64
0.80
1.04
0.78
0.92
0.20
BDL
0.90
BDL
0.23
0.73
0.54
1.67
BDL
1.22
0.95
0.70
0.56
0.57
0.37
0.69
0.31
0.30
0.52
5.40
1.39
BDL
BDL
0.69
2.28
1.24
0.92
1.62
0.52
2.46
74
4.35
ND
3.07
6.71
4.41
22.43
5.16
1.01
2.10
3.81
4.58
1.22
3.46
5.55
10.75
1.89
8.92
5.16
5.47
3.94
2.91
1.92
3.03
4.41
3.57
0.32
7.40
0.62
0.47
14.01
6.97
3.61
7.54
0.75
3.10
7.18
5.13
8.90
0.62
11.98
0.70
BDL
0.34
3.84
2.16
5.46
2.75
1.31
1.12
11.76
4.37
0.52
0.46
3.08
1.37
0.77
0.74
1.07
0.61
10.84
70+76
BDL
ND
0.94
0.52
0.55
0.99
0.85
2.05
4.10
2.76
5.69
1.58
4.53
6.96
19.55
3.17
7.83
9.54
11.87
7.64
5.18
3.92
3.71
5.53
3.67
3.26
7.05
5.43
3.26
2.76
0.81
BDL
0.39
BDL
2.93
12.87
5.29
18.86
0.79
16.14
3.48
1.38
2.15
5.37
3.57
6.25
3.86
0.33
BDL
2.60
1.18
0.42
BDL
0.81
10.98
7.27
6.05
12.62
5.04
2.37
66+95
15.78
ND
10.16
23.19
20.59
21.97
20.76
ND
ND
15.90
24.23
ND
16.73
27.55
56.21
11.26
41.13
39.06
41.72
28.78
20.56
14.29
14.42
22.78
7.32
4.62
30.29
8.27
5.71
22.35
14.14
3.79
10.46
1.40
14.04
39.26
23.00
64.12
3.43
26.21
5.60
2.23
4.05
18.57
11.47
29.61
13.00
4.14
5.44
27.12
11.18
2.02
1.77
9.70
11.42
16.58
14.12
2.27
2.84
38.26
91
1.03
ND
1.30
1.32
1.29
7.22
1.24
0.48
1.93
1.50
2.96
0.47
1.01
3.68
7.14
1.60
5.08
4.64
4.92
5.16
3.17
2.42
1.88
3.23
1.46
14.62
3.12
13.60
19.50
0.69
0.29
BDL
0.93
BDL
1.11
3.53
2.13
7.76
0.35
6.58
21.19
9.29
11.90
2.60
1.23
3.25
1.42
0.22
0.75
5.98
1.29
0.20
0.20
0.84
68.22
39.20
34.34
50.11
23.15
3.38
56+60
4.79
ND
4.14
20.13
10.80
22.49
13.08
2.47
9.41
8.26
28.81
3.21
7.45
12.12
26.15
5.58
6.12
15.86
17.02
13.18
8.58
6.06
4.27
5.53
4.28
1.16
8.47
3.18
2.61
10.77
4.35
1.47
8.57
1.11
3.01
11.29
7.41
33.18
0.83
18.10
1.86
0.76
1.04
5.71
3.74
5.79
4.44
2.23
2.21
23.24
3.88
0.98
0.79
8.93
8.04
2.62
2.39
2.86
1.34
13.43
101
7.48
ND
8.08
7.44
15.41
35.61
8.45
3.59
12.11
7.67
11.35
3.43
9.51
17.06
35.11
6.95
22.70
18.44
18.76
17.46
12.77
7.87
8.31
11.07
10.11
BDL
11.89
4.06
4.12
3.60
3.52
0.56
4.41
0.86
6.53
15.78
13.55
32.23
2.36
25.97
2.08
ND
1.36
10.56
7.47
20.00
8.85
1.67
3.07
30.41
6.49
0.46
0.49
4.86
6.00
6.61
5.71
5.59
3.97
17.75
99
11.43
ND
7.90
19.10
21.38
38.83
19.12
3.04
7.48
6.14
11.58
3.55
7.63
14.62
33.90
5.53
23.59
12.69
12.35
13.40
7.94
5.04
7.34
9.31
8.49
8.97
9.25
12.72
10.45
9.06
12.01
4.89
15.51
2.68
7.43
12.86
13.63
23.85
1.80
22.04
13.73
11.19
7.12
9.93
7.24
19.95
8.44
4.22
4.30
34.40
9.89
0.83
1.48
10.61
34.83
11.17
10.78
15.52
6.34
28.54
83
0.58
ND
0.70
1.55
2.46
11.46
1.41
0.24
1.23
0.59
1.24
0.34
0.67
1.37
3.60
0.80
1.25
2.48
2.71
1.78
1.32
1.05
0.58
0.94
0.46
1.67
1.08
7.84
11.27
0.39
0.24
0.13
0.99
BDL
0.42
1.22
0.74
3.73
BDL
2.32
13.30
1.93
5.33
0.96
0.69
1.18
0.61
0.23
0.50
3.62
0.75
BDL
BDL
0.36
11.19
14.79
12.93
80.81
11.85
2.86
97
0.81
ND
0.86
1.39
3.32
4.79
1.28
0.91
3.25
2.29
2.86
0.89
2.82
4.52
10.30
1.87
6.31
4.61
5.17
4.80
3.41
1.93
2.15
3.04
2.87
0.23
3.25
1.10
0.73
0.65
0.36
BDL
0.38
BDL
1.49
4.69
3.48
8.98
0.55
7.58
0.94
0.23
0.53
2.68
1.78
4.96
2.04
0.30
0.72
6.03
0.92
0.21
0.23
0.63
2.72
1.21
1.07
2.13
0.73
3.36
81+87
2.45
ND
3.26
4.11
8.48
19.47
4.42
1.17
4.02
2.58
4.76
1.17
3.36
5.58
17.77
2.41
6.41
7.16
7.77
6.41
4.73
2.88
2.88
3.59
3.17
1.60
4.35
4.16
2.90
2.11
2.05
BDL
1.75
0.41
1.93
5.69
4.95
13.49
0.79
10.28
3.56
1.32
1.79
3.14
2.28
5.46
2.50
0.77
1.58
14.20
3.19
0.59
0.68
1.84
11.84
3.47
3.28
2.41
2.54
8.80
85
1.03
ND
3.69
1.06
191.21
0.99
514.24
20.54
120.10
2.48
1.09
25.00
3.18
5.18
10.23
1.59
6.56
2.53
3.12
2.76
1.27
2.12
2.77
2.99
3.63
7.74
3.77
46.13
65.32
3.95
4.08
1.21
3.08
0.56
2.19
4.95
5.11
0.96
1.00
8.38
ND
ND
ND
3.09
2.08
5.97
0.99
1.98
2.00
6.73
3.80
0.14
0.19
3.32
ND
ND
ND
ND
32.45
ND
136
0.51
ND
0.63
1.42
2.14
4.28
1.24
0.31
1.71
0.68
1.75
0.36
0.91
1.81
4.18
0.94
1.34
3.43
3.19
2.38
1.71
1.28
0.80
1.12
0.72
1.83
1.02
4.37
3.58
0.32
0.18
BDL
0.41
0.08
0.52
1.41
1.17
4.31
0.21
2.75
4.34
1.72
2.10
1.06
0.62
1.83
0.86
0.24
0.68
5.14
0.73
0.09
0.08
0.45
12.44
4.29
3.81
13.48
3.44
2.37
77+110
15.51
ND
18.34
24.17
46.79
111.86
22.56
4.93
15.77
9.95
16.17
4.67
11.20
19.77
60.71
9.26
21.51
29.22
30.22
28.05
19.52
11.71
9.68
14.05
9.29
0.52
15.55
1.43
1.12
9.56
8.95
2.71
10.15
2.67
8.47
20.70
15.35
49.66
2.59
36.22
1.29
0.65
0.69
12.27
6.87
19.94
7.46
3.22
7.90
85.94
19.36
1.25
1.45
4.90
3.04
1.14
1.14
1.41
0.73
66.07
82
0.25
ND
1.89
1.06
0.84
3.64
0.68
0.53
1.15
0.66
2.33
0.39
1.84
2.31
2.81
1.24
0.88
2.00
2.06
1.69
0.96
0.90
0.70
0.77
0.69
1.17
0.98
17.96
13.86
0.38
0.16
BDL
0.89
0.07
0.55
1.62
2.18
5.10
0.25
3.75
13.72
0.55
7.46
0.55
0.66
0.96
0.39
0.13
0.29
2.49
2.32
0.10
0.11
0.28
53.29
17.03
16.06
43.64
13.59
3.33
151
3.34
ND
2.34
2.56
3.64
10.90
2.21
1.69
8.33
3.44
7.27
1.82
4.48
9.05
21.86
4.36
5.99
11.64
10.73
9.09
7.21
4.77
4.46
5.31
4.67
ND
4.84
0.98
0.81
0.72
0.30
BDL
0.74
0.25
2.99
6.81
6.65
18.70
1.28
12.46
0.84
ND
0.24
5.30
3.76
8.79
4.51
0.22
0.96
9.98
1.62
0.28
0.29
2.02
2.09
1.04
1.01
0.71
1.02
5.66
135+144
1.51
ND
1.40
2.89
4.79
9.90
2.23
0.87
3.98
1.79
3.61
0.86
2.42
4.54
12.04
2.17
3.71
6.26
5.96
4.33
3.02
2.25
2.12
2.98
2.13
3.69
2.54
5.24
5.55
0.74
0.50
0.19
0.76
0.33
1.60
4.31
3.12
9.49
0.56
6.74
6.38
6.00
3.70
2.90
2.12
4.77
2.22
0.20
0.67
7.66
1.42
0.17
0.17
0.75
9.91
4.01
3.82
2.65
2.86
4.85
107
1.03
ND
1.12
2.77
3.32
0.99
1.47
0.52
1.61
1.19
1.53
0.48
1.62
3.21
6.15
0.99
5.27
2.79
2.76
2.94
1.72
1.15
1.89
2.26
1.73
1.98
1.99
3.18
2.78
1.25
1.03
0.37
1.00
0.49
1.34
2.49
2.62
4.51
0.41
3.65
3.71
3.45
1.93
2.49
1.76
4.80
2.06
0.35
0.78
5.75
1.40
0.14
0.14
1.26
7.66
3.11
3.07
2.99
2.22
3.78
149
14.23
ND
13.21
24.79
37.80
77.62
16.88
4.53
19.19
8.46
17.21
4.18
11.37
20.83
55.44
10.30
19.20
29.17
26.91
20.13
16.30
11.54
10.51
14.11
9.85
1.94
11.68
3.63
3.79
5.11
3.76
1.21
8.61
2.77
7.97
19.21
15.28
44.02
3.30
30.10
5.74
2.82
2.61
13.89
10.32
23.74
11.36
2.61
7.04
50.24
10.60
0.81
0.90
3.44
16.91
2.80
2.45
5.61
2.11
28.81
Concentrations in ng/g wet wgt)
Sample ID
F-3031
F-3032
F-3033
F-3034
F3035
F-3036
F-3037
F-3038
F-3039
F-3040
F-3041
F-3042
F-3043
F-3044
F-3045
F-3046
F-3047
F-3048
F-3049
F-3050
F-3051
F-3052
F-3053
F-3054
F-3055
F-3058
F-3059
F-3060
F-3061
F-3062
F-3063
F-3064
F-3065
F-3066
F-3067
F-3068
F-3069
F3070
F-3071
F-3072
F-3073
F-3074
F-3075
F-3076
F-3077
F-3078
F-3079
F-3080
F-3081
F-3082
F-3083
F-3084
F-3085
F-3086
F-3087
F-3088
F-3089
F-3090
F-3091
F-3092
37+42
1.82
30.95
3.64
6.27
9.06
1.47
0.87
2.50
1.31
16.63
BDL
0.29
0.17
0.54
ND
2.85
1.32
1.14
ND
4.82
1.94
4.70
4.95
0.66
0.75
4.89
3.44
3.08
4.37
5.81
2.76
4.12
0.58
8.99
1.88
2.05
2.71
1.55
1.64
3.53
1.91
3.32
1.26
0.58
0.74
1.54
4.32
2.34
0.43
0.27
0.44
2.42
1.00
2.63
2.79
0.78
0.31
0.13
BDL
BDL
41+71
ND
14.25
2.95
3.28
4.82
1.44
0.74
2.90
1.83
14.00
ND
0.13
ND
0.53
ND
2.25
1.17
0.86
3.64
3.68
1.40
5.88
4.18
0.30
0.38
3.89
ND
2.26
6.24
6.81
3.80
5.98
0.59
12.12
2.09
ND
1.75
1.31
1.33
4.96
2.00
3.52
1.45
ND
0.89
2.64
9.05
4.80
0.64
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
64
2.90
ND
3.84
ND
ND
1.27
0.71
BDL
BDL
12.93
BDL
BDL
BDL
0.44
BDL
2.48
1.02
0.27
6.13
4.21
2.02
ND
4.72
0.48
0.57
4.05
0.80
2.18
3.81
3.65
2.37
3.63
0.45
8.29
1.67
0.43
1.91
1.30
1.45
3.26
1.62
2.61
1.15
BDL
0.59
1.25
4.12
1.98
0.48
0.75
0.67
4.81
2.97
5.57
5.44
3.66
0.41
0.18
BDL
BDL
40
0.17
22.88
1.65
11.36
5.13
0.35
ND
0.40
0.45
5.88
BDL
BDL
ND
0.10
ND
1.55
0.22
0.32
5.01
5.26
0.94
2.53
2.66
0.31
0.35
1.87
ND
1.40
1.86
ND
1.14
0.56
0.63
4.58
0.90
ND
1.58
0.55
0.70
1.95
0.90
1.11
0.41
ND
0.38
0.71
2.71
1.26
0.35
BDL
ND
BDL
0.11
BDL
0.16
BDL
ND
ND
ND
ND
100
1.18
2.17
0.60
0.65
0.62
0.19
BDL
0.49
0.34
0.54
ND
ND
ND
ND
ND
ND
0.36
0.17
0.45
0.14
0.52
2.09
1.62
0.29
0.31
2.66
2.67
1.55
0.58
0.65
0.42
0.43
0.32
2.00
0.54
1.58
3.70
0.56
0.40
1.01
0.56
1.23
0.32
0.38
BDL
0.51
1.48
0.47
0.17
0.22
ND
2.01
1.31
0.76
0.66
0.78
ND
BDL
ND
ND
63
0.99
1.60
0.60
4.14
2.41
0.29
0.17
0.55
0.29
3.61
BDL
BDL
0.12
0.34
BDL
0.78
0.48
0.33
2.52
1.62
0.84
1.78
1.44
0.35
0.43
2.75
1.04
1.30
0.88
1.16
0.61
0.90
0.22
2.70
0.91
0.93
1.21
1.60
0.98
1.33
0.95
1.28
0.68
0.30
0.21
0.37
1.49
0.56
0.27
0.43
0.26
1.21
1.98
2.33
2.12
1.58
1.51
BDL
BDL
BDL
74
3.52
2.19
0.41
1.48
0.93
1.99
1.40
4.24
3.80
25.10
BDL
0.84
0.33
0.60
BDL
3.31
1.51
1.33
25.61
11.13
4.74
10.70
11.01
1.83
1.89
12.16
12.58
6.68
6.23
8.40
4.38
6.99
1.22
18.33
5.97
6.37
7.87
3.65
4.11
7.87
5.36
7.27
3.08
1.23
1.67
2.85
13.44
3.97
1.55
1.33
0.98
7.02
3.32
7.01
9.96
2.41
2.53
0.58
0.27
BDL
70+76
0.57
21.08
3.58
16.90
6.47
2.98
1.68
5.35
3.09
24.01
BDL
0.33
BDL
0.54
ND
6.50
3.23
2.43
17.38
8.76
5.92
9.25
13.34
2.41
2.63
14.00
16.61
6.76
9.80
13.19
5.92
9.95
1.89
20.33
6.56
9.42
6.99
5.34
6.47
8.30
7.01
8.75
3.78
1.85
1.43
2.96
12.18
4.72
1.94
BDL
0.76
0.77
ND
0.59
1.95
0.44
1.17
BDL
BDL
ND
66+95
12.29
11.77
6.25
2.95
8.14
4.01
5.08
15.16
10.18
75.05
BDL
1.25
1.69
3.54
0.90
15.88
9.40
6.96
58.51
30.10
21.72
50.51
28.00
9.53
9.86
57.84
ND
35.12
26.72
36.23
18.89
28.71
7.04
36.76
11.59
ND
12.20
19.90
21.60
16.92
27.10
37.09
15.68
ND
7.56
12.58
25.57
17.62
7.23
4.04
3.44
30.17
13.78
27.26
29.98
9.70
2.59
1.86
0.64
BDL
91
1.04
105.76
21.09
50.02
49.39
0.87
0.40
1.56
0.71
8.94
BDL
0.26
0.22
0.33
BDL
1.94
ND
0.85
5.58
3.32
1.91
7.18
5.06
0.87
1.01
5.76
5.29
3.53
2.13
2.73
1.53
2.10
1.06
8.21
2.38
2.59
4.05
2.01
2.01
2.95
2.42
3.75
1.66
0.70
0.75
1.34
4.34
2.30
0.79
ND
0.41
9.43
1.79
2.67
2.32
1.13
0.19
BDL
BDL
BDL
56+60
12.53
8.38
2.07
2.86
3.56
3.70
1.89
6.02
3.22
25.08
BDL
0.74
0.51
1.80
0.44
8.60
5.18
3.85
29.53
15.69
5.09
14.09
12.79
2.19
3.30
16.12
3.80
10.99
10.39
10.88
5.95
9.15
2.71
16.57
6.16
0.84
9.58
6.07
6.20
10.42
5.88
7.67
3.00
0.70
1.60
3.87
12.59
4.12
2.10
1.51
0.96
7.73
9.08
9.12
17.29
3.45
1.65
1.01
0.47
BDL
101
5.61
19.96
3.11
8.81
13.59
3.67
2.15
7.21
3.75
31.70
0.33
1.15
0.50
1.68
BDL
7.89
6.11
4.34
31.48
15.73
10.65
ND
25.61
6.45
7.30
38.20
37.59
24.42
9.59
12.48
7.11
10.19
5.03
33.42
13.17
20.15
23.87
12.97
13.02
16.11
15.04
20.23
9.19
3.88
4.51
7.59
24.10
11.23
5.06
1.92
1.70
111.68
14.02
9.03
12.91
4.90
1.55
0.40
0.47
0.27
99
11.98
39.91
9.27
13.53
14.54
2.85
1.51
4.99
2.64
1.09
0.33
0.98
0.64
1.37
0.38
3.83
3.95
2.46
117.03
74.22
10.72
35.61
28.76
6.17
6.64
36.34
28.79
22.80
6.98
8.37
5.34
7.53
5.27
32.47
14.18
18.45
28.03
12.07
12.78
14.55
15.35
15.74
8.88
3.74
4.79
7.46
25.64
10.08
5.04
3.54
1.91
109.08
14.33
13.24
17.37
9.82
2.07
2.21
1.06
0.81
83
0.85
85.26
6.62
101.17
63.42
0.22
BDL
0.30
0.38
5.02
BDL
BDL
BDL
0.25
ND
0.82
0.59
0.37
2.63
1.53
0.91
2.25
2.00
0.46
0.40
2.72
1.65
1.39
1.02
1.30
0.67
1.12
0.41
3.29
1.46
1.31
2.87
1.30
1.13
2.01
1.15
1.42
0.75
0.19
0.25
0.36
2.10
0.66
0.35
0.37
0.19
2.80
1.36
1.58
1.34
1.09
0.19
BDL
BDL
BDL
97
1.41
5.58
0.75
2.20
2.55
1.27
0.58
2.14
1.30
12.38
0.09
0.29
0.26
0.64
0.14
2.51
1.82
1.31
10.04
4.98
2.90
9.00
6.65
1.59
1.67
10.40
9.53
6.49
2.93
3.43
2.01
3.20
1.13
9.59
3.90
5.23
6.94
3.19
3.56
4.52
4.46
5.85
2.75
0.79
1.10
2.04
6.70
3.23
1.33
0.32
0.30
41.98
1.90
2.96
1.95
0.83
0.29
BDL
BDL
BDL
81+87
2.66
9.09
2.70
2.02
5.13
1.98
0.99
3.26
1.96
20.35
BDL
0.56
0.46
1.13
0.36
4.33
2.85
2.08
19.33
9.17
3.37
10.64
8.50
1.80
2.08
12.53
10.58
7.29
3.64
4.17
2.44
4.06
1.29
12.69
4.75
5.29
7.99
3.41
3.95
5.46
4.40
6.00
2.63
0.86
1.28
2.18
6.74
3.49
1.52
1.14
0.84
29.59
4.35
4.85
5.76
3.20
0.48
ND
ND
BDL
85
ND
395.12
37.40
355.87
123.70
1.26
0.82
2.54
1.38
13.13
0.14
0.43
0.25
ND
ND
2.40
ND
1.00
9.67
4.03
2.91
7.70
9.07
1.75
1.86
13.17
68.28
6.68
3.06
3.90
2.28
3.54
0.54
10.24
4.27
56.70
8.33
3.52
3.73
5.35
4.45
5.22
2.65
13.03
1.43
2.45
7.65
3.30
1.49
1.88
ND
99.74
7.42
7.62
ND
ND
ND
ND
ND
ND
136
0.82
21.43
2.97
16.13
10.77
0.20
0.06
0.35
0.21
3.22
BDL
BDL
0.07
0.20
0.08
0.80
0.49
0.37
2.35
1.34
0.88
3.78
2.49
0.64
0.65
3.25
4.02
2.22
0.95
1.30
0.64
1.02
0.56
3.42
1.27
1.77
3.17
1.06
1.12
1.59
1.32
1.80
0.79
0.34
0.40
0.65
1.81
1.09
0.46
0.11
0.16
2.09
0.99
1.16
0.96
0.81
ND
BDL
BDL
BDL
77+110
20.55
4.16
1.00
1.46
1.48
5.67
2.60
9.15
5.84
49.60
0.39
1.42
1.30
3.31
0.91
12.26
8.22
5.73
56.30
26.07
11.56
39.31
15.00
5.83
6.72
48.28
22.04
24.34
12.31
12.72
8.75
12.50
4.63
36.91
13.76
13.93
21.10
11.82
13.07
16.97
17.70
21.04
9.58
2.89
4.47
7.73
32.03
10.97
4.66
7.49
3.02
142.46
19.17
27.11
22.42
20.98
3.34
0.78
0.77
0.93
82
1.15
96.92
12.44
53.00
57.16
0.73
BDL
0.88
0.87
5.58
ND
BDL
ND
0.21
ND
1.27
0.50
0.54
4.68
2.77
1.45
4.34
2.76
0.53
0.52
2.60
0.18
1.39
1.25
0.24
0.82
0.71
0.32
2.74
1.14
ND
1.61
0.48
0.69
2.07
1.46
1.02
0.60
ND
0.25
0.56
2.02
0.87
0.33
ND
0.08
0.97
0.75
0.21
ND
0.12
ND
ND
ND
BDL
151
1.56
3.47
0.63
0.64
1.85
1.01
0.47
2.78
1.36
7.39
BDL
0.24
0.33
0.55
0.14
2.18
1.45
1.45
7.69
4.56
5.11
23.73
15.04
2.92
3.22
13.84
18.86
11.65
3.19
4.33
2.50
3.48
2.56
13.00
5.47
10.22
13.19
6.60
4.84
7.33
6.35
7.82
3.38
3.19
2.11
3.98
10.92
4.70
2.58
0.88
0.70
2.71
6.58
2.97
1.90
0.99
0.28
BDL
BDL
BDL
135+144
1.34
10.49
4.55
1.95
3.75
0.71
ND
1.23
0.67
7.26
BDL
0.13
0.19
0.41
0.10
1.73
1.23
0.82
6.66
3.32
2.77
10.10
7.40
1.68
2.03
9.05
10.85
6.45
2.22
2.93
1.53
2.41
1.42
8.32
3.25
5.60
6.53
3.80
3.22
4.11
4.17
4.57
2.14
1.17
1.02
1.77
5.37
2.59
1.36
0.70
0.40
9.48
2.95
2.36
1.76
1.64
0.37
BDL
BDL
0.11
107
1.56
9.31
2.70
3.10
2.79
0.44
0.19
0.99
0.57
5.20
BDL
0.10
0.18
0.29
0.07
0.82
0.75
0.45
0.86
1.09
1.82
7.43
4.05
0.96
1.13
1.13
5.31
ND
1.17
1.25
0.75
1.56
0.92
7.39
2.90
3.65
6.60
2.33
2.41
2.89
0.74
2.73
2.13
0.62
1.00
1.66
1.12
1.90
1.00
0.61
0.35
7.48
1.68
ND
2.48
1.74
0.40
0.16
ND
0.15
149
11.63
9.97
3.09
8.77
3.39
3.74
1.91
6.79
3.55
25.73
BDL
0.81
1.14
2.01
0.46
7.27
5.97
4.18
31.56
15.61
12.31
43.81
31.30
7.80
9.41
42.25
47.37
31.63
7.73
10.27
5.66
8.23
8.10
32.00
13.74
25.12
29.39
17.46
14.72
16.58
17.87
20.93
9.95
0.91
5.17
9.07
26.84
12.15
6.74
5.70
3.20
88.38
18.94
15.70
13.57
10.39
2.25
0.59
0.58
0.93
Concentrations in ng/g wet wgt)
Sample ID
F-3093
F-3094
F-3095
F-3096
F-3097
F-3098
F-3099
F-3100
F-3101
F-3102
F-3103
37+42
0.25
0.35
0.09
0.15
8.96
7.73
3.74
0.47
ND
BDL
6.72
41+71
ND
ND
ND
0.45
30.72
10.58
4.10
0.45
ND
BDL
11.16
64
0.30
0.44
0.22
ND
0.41
6.11
4.43
BDL
BDL
ND
7.39
40
ND
BDL
ND
BDL
4.64
3.72
1.97
BDL
ND
ND
3.24
100
ND
0.27
BDL
ND
1.85
1.89
0.95
ND
ND
BDL
3.13
63
0.30
0.15
BDL
0.32
2.75
2.36
1.83
0.28
0.14
BDL
1.83
74
0.75
1.06
0.53
1.51
21.43
20.02
12.69
2.50
BDL
BDL
12.67
70+76
0.66
0.48
ND
0.31
20.02
17.10
10.76
0.51
ND
BDL
14.56
66+95
2.80
5.53
1.55
2.35
72.46
71.72
20.34
4.26
BDL
BDL
49.73
91
0.14
0.36
BDL
0.17
1.33
6.64
3.49
0.51
BDL
BDL
7.45
56+60
0.70
1.60
1.12
1.01
23.45
19.58
13.66
1.37
0.42
BDL
14.86
101
1.12
1.74
0.63
1.03
33.98
35.08
19.59
2.57
0.46
BDL
26.03
99
1.39
3.94
2.04
3.48
30.84
39.72
6.70
7.07
1.35
0.27
24.88
83
BDL
0.18
BDL
0.28
2.92
2.92
1.93
0.41
BDL
ND
2.22
97
0.25
0.24
BDL
0.18
10.11
10.55
5.48
0.41
BDL
ND
8.51
81+87
0.31
0.32
BDL
0.56
13.72
10.61
7.61
0.78
ND
BDL
8.77
85
0.52
ND
ND
ND
1.08
12.34
6.60
ND
ND
BDL
8.12
136
0.10
0.17
0.09
0.09
3.17
3.08
1.43
0.23
BDL
BDL
2.43
77+110
1.86
2.50
1.54
3.50
40.74
48.25
28.33
4.09
1.45
BDL
33.95
82
BDL
ND
BDL
0.09
15.28
4.31
3.13
0.14
ND
BDL
2.87
151
0.30
0.27
BDL
0.57
0.35
19.94
5.56
0.78
BDL
BDL
11.49
135+144
0.23
0.43
0.17
0.42
8.52
9.49
4.09
0.55
0.16
BDL
5.33
107
0.21
ND
0.26
0.59
1.08
1.08
0.62
0.82
0.30
BDL
5.14
149
1.34
2.81
1.29
2.76
59.12
44.34
19.53
4.27
2.24
BDL
24.93
F-3104
F-3105
F-3106
F-3107
F-3108
F-3109
F-3110
F-3111
F-3112
F-3113
F-3114
F-3115
F-3116
F-3117
F-3118
F-3119
F-3120
F-3121
F-3122
F-3123
F-3124
F-3125
F-3126
F-3127
F-3128
F-3129
F-3130
F-3131
F-3132
F-3133
F-3134
F-3135
F-3165
F-3166
F-3167
F-3168
F-3169
F-3170
F-3171
F-3172
F-3173
F-3174
F-3175
F-3176
F-3177
F-3178
F-3179
F-3180
1.56
0.59
0.13
BDL
5.29
3.63
2.26
0.19
0.11
1.31
1.72
1.52
0.22
0.59
0.64
0.99
0.50
1.00
0.58
5.68
2.77
1.03
2.08
5.73
ND
0.54
0.22
1.92
0.40
0.12
ND
2.22
0.47
1.58
0.30
0.28
1.27
1.10
0.47
9.44
13.23
0.46
2.60
2.59
10.27
17.02
4.80
1.68
2.03
ND
ND
ND
6.73
3.18
1.89
ND
ND
1.95
1.60
ND
ND
3.03
0.55
0.81
ND
ND
ND
8.34
4.91
1.07
3.32
9.42
ND
0.46
ND
ND
ND
0.15
ND
ND
0.50
1.10
ND
ND
1.81
0.89
0.68
8.70
14.47
0.43
3.06
0.76
13.33
16.65
4.57
1.23
1.20
1.50
0.26
0.25
3.92
3.18
1.74
0.41
0.26
0.98
1.50
3.27
0.22
ND
0.60
0.77
0.47
1.35
0.51
5.22
2.39
0.83
1.82
5.46
BDL
0.47
BDL
1.31
0.21
ND
BDL
1.44
0.31
1.24
0.36
0.33
ND
1.33
BDL
7.23
20.51
0.43
2.46
2.14
8.61
13.57
4.39
0.40
0.69
BDL
BDL
ND
3.18
2.05
1.11
BDL
BDL
BDL
0.50
0.20
BDL
0.17
BDL
0.11
BDL
BDL
BDL
2.80
1.39
0.35
1.00
3.35
ND
0.29
BDL
0.21
BDL
ND
ND
0.24
0.15
0.37
BDL
ND
0.51
0.17
0.14
6.28
11.22
0.15
1.20
1.42
6.79
7.85
2.61
1.13
0.50
0.40
BDL
BDL
1.29
1.56
0.76
BDL
ND
0.19
0.66
ND
ND
1.03
0.21
0.15
0.22
ND
0.33
2.33
1.06
0.27
0.88
3.66
ND
0.31
BDL
ND
ND
0.50
ND
ND
ND
ND
0.21
ND
ND
0.57
BDL
10.35
10.91
0.16
1.29
ND
9.58
2.76
0.82
3.13
0.43
1.64
BDL
BDL
0.93
1.49
0.61
0.17
BDL
0.47
0.70
1.27
0.13
1.42
0.14
0.21
0.14
0.97
0.24
1.61
0.79
0.35
0.78
1.90
BDL
0.22
BDL
0.47
BDL
BDL
BDL
0.56
0.17
0.38
0.13
0.12
0.63
1.28
0.21
2.46
8.08
0.12
1.14
0.78
4.75
4.17
2.19
0.31
3.17
1.81
0.43
0.38
8.84
9.23
3.97
0.83
0.55
2.04
3.81
7.44
1.34
8.89
1.07
1.43
1.31
3.35
2.00
6.40
4.42
2.14
4.02
9.91
BDL
1.15
0.72
2.64
1.48
ND
0.28
2.61
0.71
1.49
0.40
0.37
1.78
1.87
1.02
10.86
30.18
0.57
5.15
3.97
13.79
18.86
7.90
3.95
3.32
0.46
BDL
BDL
10.98
9.92
6.14
0.57
0.34
3.00
4.12
6.96
0.33
3.90
1.54
2.09
1.61
2.48
0.67
13.38
6.04
2.71
5.63
15.24
ND
1.73
BDL
0.95
ND
BDL
BDL
1.05
1.13
4.01
0.99
ND
0.93
0.60
BDL
15.91
39.57
0.90
6.42
5.67
21.36
30.65
9.59
3.73
7.04
6.53
1.24
0.84
37.45
18.43
22.86
2.34
0.96
9.87
7.52
31.83
1.27
14.00
3.93
5.41
4.18
11.90
3.31
38.80
21.17
9.85
7.93
54.22
BDL
5.78
1.96
9.10
3.56
ND
BDL
9.70
2.86
10.11
2.49
ND
8.78
10.31
4.69
43.24
141.25
3.77
20.12
17.17
58.62
81.48
34.11
10.32
1.60
0.62
BDL
BDL
5.25
5.56
2.76
0.23
BDL
0.99
1.97
3.04
0.13
0.41
0.28
0.39
0.25
0.91
0.39
5.50
2.49
1.20
2.32
7.31
BDL
0.53
0.13
1.03
0.25
ND
BDL
1.34
0.31
1.19
0.34
0.20
0.88
0.86
0.44
4.64
14.30
0.36
2.39
2.08
6.64
8.38
4.25
1.39
5.30
2.47
0.52
0.58
12.31
11.50
6.04
1.00
0.64
3.10
6.36
15.31
0.69
8.49
1.55
2.31
1.97
4.14
5.16
20.78
7.30
2.65
6.93
23.98
BDL
2.75
1.02
3.73
2.15
BDL
BDL
4.23
2.68
9.62
1.29
0.92
5.08
5.68
2.94
25.97
111.95
3.34
19.53
17.81
41.02
76.37
25.64
12.15
10.27
3.71
0.81
0.62
23.46
28.07
12.78
1.57
0.75
5.79
11.83
17.61
0.65
3.43
1.82
2.34
2.20
4.37
1.91
23.89
13.29
7.08
11.20
31.70
BDL
4.01
0.41
3.77
0.53
BDL
BDL
4.65
1.82
6.80
2.34
1.42
5.01
6.42
2.56
18.84
66.56
2.36
12.43
9.18
24.04
32.42
20.11
6.71
8.59
7.16
1.39
0.84
25.40
29.00
10.72
2.96
1.46
5.61
12.24
17.07
1.61
8.25
1.32
1.90
1.69
6.86
4.54
15.29
11.75
7.00
11.10
28.72
BDL
3.93
2.37
7.32
3.67
BDL
0.44
6.35
1.62
3.93
1.25
0.73
2.58
3.66
1.81
6.95
34.60
1.38
7.85
4.02
10.24
15.26
10.65
3.36
0.51
0.63
BDL
BDL
2.98
2.20
0.97
0.22
0.12
0.62
0.95
3.01
0.22
0.57
BDL
BDL
BDL
0.77
0.74
3.07
1.22
0.39
0.84
3.39
ND
0.36
BDL
0.59
BDL
ND
BDL
0.60
0.27
0.44
BDL
BDL
0.43
0.37
0.28
2.69
20.87
0.22
2.13
3.32
9.66
9.59
5.63
1.81
2.98
0.38
0.14
0.09
6.59
8.07
4.00
0.19
0.16
1.57
3.15
4.26
0.10
0.50
0.47
0.61
0.55
1.60
1.13
6.93
3.67
1.95
2.94
9.36
BDL
0.95
BDL
0.59
0.08
BDL
BDL
0.76
0.40
1.40
0.46
0.21
0.87
0.65
0.34
5.47
22.78
0.45
3.22
2.54
6.38
10.58
5.86
1.99
3.22
1.55
0.42
BDL
7.67
9.86
4.02
0.63
0.43
1.75
3.86
10.64
0.50
2.45
0.88
1.01
0.88
2.95
1.43
8.96
4.41
2.27
3.25
10.96
BDL
1.20
BDL
1.57
0.33
BDL
BDL
2.29
0.56
2.24
0.76
0.51
1.88
1.83
0.97
9.38
36.25
0.88
5.09
3.72
10.58
16.58
8.58
3.06
3.21
ND
0.56
0.40
7.67
9.92
4.04
0.72
0.47
1.75
3.97
ND
1.07
4.07
0.71
0.96
0.93
3.09
0.95
6.94
4.42
2.21
3.49
9.50
BDL
1.20
0.74
2.31
ND
0.14
BDL
ND
ND
1.87
0.61
ND
ND
1.87
0.61
5.48
ND
ND
ND
2.45
6.72
10.18
ND
2.08
0.81
0.42
BDL
BDL
2.77
3.33
1.74
0.16
BDL
0.47
1.13
1.76
0.08
0.15
BDL
0.08
BDL
0.46
0.10
3.51
1.63
0.58
1.02
4.70
BDL
0.41
0.08
0.45
0.11
BDL
BDL
0.56
0.21
0.54
0.14
0.09
0.46
0.34
0.16
2.96
11.37
0.22
1.47
1.04
5.26
4.98
3.33
0.71
9.74
9.53
2.05
1.20
25.64
29.64
14.36
3.86
2.19
5.58
12.14
43.33
1.53
8.56
1.85
2.21
1.77
13.57
11.00
31.29
14.60
6.74
11.74
39.07
BDL
3.66
1.11
7.48
1.47
BDL
BDL
10.67
1.63
8.92
2.80
1.80
6.45
7.26
3.10
34.18
125.47
2.92
17.80
18.03
47.96
64.36
32.93
10.61
0.77
0.40
BDL
BDL
2.65
2.05
1.22
0.11
0.07
0.40
0.85
ND
0.08
0.24
0.18
0.39
BDL
2.08
2.27
4.12
1.63
0.50
1.07
3.53
BDL
0.39
ND
0.17
BDL
ND
BDL
0.09
0.18
0.67
0.23
0.13
0.85
0.39
0.29
4.24
13.07
0.27
2.90
2.15
5.71
6.47
1.97
0.99
4.84
0.96
BDL
BDL
14.22
13.86
5.98
0.40
BDL
2.53
5.67
3.82
0.11
1.03
0.49
0.46
0.31
1.70
0.65
17.03
9.16
3.35
5.60
17.43
BDL
2.81
BDL
1.07
BDL
BDL
BDL
1.16
0.78
3.49
1.38
0.45
2.60
3.39
1.37
10.61
43.68
1.27
9.37
4.61
20.02
15.77
12.10
2.74
2.22
1.28
0.18
0.11
6.54
7.69
3.85
0.42
0.16
1.43
3.00
3.80
0.13
0.22
0.24
0.31
0.26
1.55
0.52
6.48
3.63
1.77
2.74
10.01
BDL
1.07
0.08
0.85
0.10
ND
BDL
0.93
0.37
1.13
0.44
0.32
1.42
2.07
0.66
5.24
22.46
0.43
3.57
2.30
8.77
8.73
6.04
1.43
1.80
1.58
0.25
0.09
4.66
7.65
3.02
0.57
0.15
1.35
2.84
3.33
0.09
1.04
0.17
0.22
0.20
1.49
0.46
3.83
2.55
1.53
2.72
7.39
BDL
0.92
0.25
0.93
0.32
BDL
BDL
0.83
0.26
0.50
0.26
0.13
0.58
0.58
0.32
2.28
9.73
0.24
1.89
0.91
3.31
3.66
2.71
0.90
10.80
7.88
1.30
0.79
28.28
31.17
15.55
3.14
1.07
6.88
14.48
20.25
1.00
3.56
1.47
1.64
1.38
8.86
3.55
28.03
15.33
8.84
12.82
40.25
BDL
5.26
0.83
5.26
0.75
BDL
BDL
7.15
1.65
8.21
3.35
2.04
6.85
9.02
3.08
23.83
92.00
2.92
17.92
11.22
37.29
36.13
27.49
6.87
Concentrations in ng/g wet wgt)
Sample ID
F-3181
F-3182
F-3183
F-3184
F-3185
F-3186
F-3187
F-3188
F-3189
F-3190
F-3191
F-3192
F-3193
F-3194
F-3195
F-3196
F-3197
F-3198
F-3199
F-3200
F-3201
F-3202
F-3203
F-3204
F-3205
F-3206
F-3207
F-3208
F-3209
F-3210
F-3211
F-3212
F-3213
F-3214
F-3215
F-3216
F-3217
F-3218
F-3219
F-3220
F-3221
F-3222
F-3223
F-3224
F-3225
F-3226
F-3227
F-3228
F-3229
F-3230
F-3231
F-3232
F-3233
F-3234
37+42
1.80
0.44
0.81
0.16
ND
0.17
2.01
2.30
0.34
0.27
0.10
0.19
0.09
0.44
ND
0.85
1.16
2.88
7.66
7.60
1.55
12.79
3.85
0.39
0.35
0.13
0.29
0.16
0.22
0.53
0.44
0.75
0.35
0.71
1.24
0.69
0.68
2.61
3.04
1.92
6.24
0.44
0.76
0.64
12.54
7.53
13.09
0.65
3.35
14.96
15.08
0.68
0.58
0.39
41+71
1.29
0.38
0.68
0.12
BDL
ND
1.24
1.50
0.28
0.21
BDL
0.17
BDL
0.46
ND
0.77
ND
2.10
7.51
8.28
1.60
8.98
3.26
0.38
0.17
0.12
0.23
0.22
0.22
0.73
0.28
0.52
0.42
0.64
1.37
1.11
0.53
1.52
3.26
1.96
3.16
ND
0.52
0.53
74.67
7.15
5.04
0.47
2.71
38.38
22.95
0.59
0.96
0.28
64
1.69
BDL
0.18
BDL
BDL
0.16
1.60
1.91
0.34
0.27
BDL
0.24
BDL
0.19
BDL
BDL
0.32
2.58
6.11
6.43
1.74
8.69
0.57
BDL
0.29
BDL
0.28
BDL
0.25
BDL
BDL
0.62
BDL
BDL
0.18
0.56
BDL
2.10
0.75
2.53
3.80
0.44
0.61
0.68
0.54
6.05
12.12
0.53
3.88
0.53
ND
0.55
0.78
0.34
40
0.93
0.23
0.30
0.14
ND
ND
1.19
0.82
0.24
0.10
0.10
0.15
BDL
0.17
BDL
0.26
ND
1.66
6.00
5.04
1.64
7.09
1.14
0.16
0.10
BDL
BDL
BDL
BDL
0.11
0.11
0.13
0.12
0.26
0.35
0.34
0.19
1.09
1.03
0.71
1.01
ND
BDL
BDL
8.61
2.58
4.50
0.17
0.93
5.84
5.55
0.16
0.14
0.10
100
ND
ND
0.43
BDL
ND
ND
0.60
ND
ND
ND
ND
ND
BDL
BDL
ND
0.33
1.45
1.93
4.69
7.55
2.88
15.40
1.61
BDL
BDL
BDL
BDL
0.25
0.15
0.14
ND
0.17
1.03
0.36
0.97
0.18
1.08
ND
ND
0.45
0.74
ND
BDL
ND
0.54
3.23
7.99
ND
ND
0.59
8.80
ND
0.17
ND
63
0.44
BDL
0.24
BDL
BDL
BDL
0.53
0.55
BDL
BDL
BDL
BDL
BDL
0.18
BDL
0.27
0.42
1.34
5.06
2.76
0.93
3.41
1.22
0.21
0.12
BDL
BDL
0.12
BDL
0.16
BDL
0.17
0.12
0.19
0.34
0.16
0.20
1.44
1.49
1.16
1.70
0.16
BDL
0.17
3.12
1.48
3.36
BDL
1.01
2.95
2.83
0.13
0.16
BDL
74
3.65
1.23
2.26
0.28
1.56
BDL
4.80
2.63
0.86
0.58
BDL
0.58
BDL
0.82
0.27
1.16
2.80
6.81
11.87
13.06
5.71
18.27
4.78
0.58
0.48
BDL
0.57
0.66
0.34
1.05
0.29
0.81
0.66
0.89
2.34
1.23
1.42
3.82
3.85
7.00
6.43
1.17
1.08
1.47
36.92
12.11
26.78
0.98
7.81
24.57
22.44
1.02
2.04
0.56
70+76
4.90
1.26
2.36
BDL
0.55
0.55
3.39
3.72
1.04
0.79
BDL
0.31
BDL
0.42
BDL
2.05
3.36
5.65
11.77
13.48
3.33
16.35
8.73
0.27
0.68
0.30
0.58
0.88
0.66
0.52
BDL
0.63
0.87
1.56
3.22
1.29
1.39
5.07
5.07
6.33
11.28
1.98
1.99
2.03
67.17
9.58
20.80
0.69
1.91
27.43
30.50
1.17
3.56
0.40
66+95
17.53
4.02
6.58
1.06
1.57
ND
16.05
13.11
2.73
2.61
0.90
1.90
0.70
2.53
1.03
5.66
BDL
29.62
38.99
47.48
12.54
57.00
23.85
2.36
1.75
0.86
1.91
1.66
0.93
2.80
0.89
3.29
2.47
4.10
9.67
5.64
2.68
15.53
15.36
12.52
29.22
3.63
3.67
4.65
162.01
39.87
63.14
2.85
22.60
68.33
74.30
3.72
11.54
1.95
91
2.15
0.45
0.73
BDL
BDL
0.13
1.52
1.65
0.28
0.26
BDL
0.15
BDL
0.25
0.13
0.72
0.37
4.14
5.24
6.74
1.86
8.59
3.59
0.17
0.17
0.15
0.18
0.13
BDL
0.21
BDL
0.23
0.23
0.64
0.95
0.63
0.21
1.83
1.77
2.53
3.57
0.33
0.30
0.41
19.54
4.86
6.81
BDL
1.45
2.26
7.83
0.34
0.86
0.14
56+60
13.96
3.09
5.82
0.85
1.37
1.09
9.34
13.37
2.45
2.22
0.72
1.31
0.94
2.68
0.94
4.27
2.39
10.42
22.12
30.00
8.66
33.18
16.79
1.90
1.34
0.83
1.26
0.71
0.62
3.01
0.74
1.68
3.39
2.03
3.97
1.32
3.54
7.58
7.92
15.06
17.91
1.32
1.65
1.98
38.13
11.97
28.66
1.29
10.37
24.37
30.56
2.19
2.26
0.89
101
12.79
2.57
4.19
0.51
1.09
1.17
12.09
7.02
1.37
1.71
0.31
0.75
0.54
0.78
0.30
3.64
8.87
20.01
20.78
29.71
9.89
29.05
14.03
0.65
1.08
0.95
1.20
1.53
0.74
1.23
0.30
1.30
1.86
2.69
7.38
3.45
2.05
10.40
10.49
20.01
15.99
2.51
1.71
2.39
86.25
16.13
25.60
1.02
5.16
29.53
29.80
1.73
6.09
0.67
99
8.01
1.49
2.66
0.25
1.18
0.79
7.04
3.81
2.23
1.04
0.89
0.53
0.31
0.76
0.83
2.49
69.91
15.08
33.77
43.75
11.90
95.24
10.36
0.91
0.88
0.78
0.72
0.87
ND
0.87
ND
1.03
1.18
2.00
5.20
3.43
1.40
7.97
6.86
13.81
16.20
2.17
1.53
2.56
23.88
8.48
BDL
0.76
5.33
60.14
17.68
1.27
3.29
0.66
83
1.33
0.20
0.61
0.15
ND
BDL
1.44
1.11
0.26
0.19
BDL
0.15
BDL
BDL
BDL
0.32
6.35
2.56
4.95
4.98
1.87
7.48
1.64
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
0.14
BDL
0.16
0.41
1.10
BDL
0.95
1.31
1.08
1.49
BDL
BDL
BDL
7.87
2.30
2.83
BDL
0.73
5.25
4.10
0.14
0.30
BDL
97
3.66
0.72
1.09
0.18
0.26
0.25
3.46
2.30
0.38
0.46
0.14
0.31
0.13
0.36
0.18
0.87
25.05
6.02
6.45
9.24
2.96
10.00
3.79
0.31
0.26
0.19
0.29
0.27
0.19
0.45
0.12
0.57
0.47
0.69
2.11
0.91
0.48
3.31
3.31
5.50
4.66
0.51
0.45
0.65
35.45
5.61
7.66
0.40
2.71
10.81
10.11
0.52
1.99
0.29
81+87
5.17
1.09
1.62
0.40
0.50
0.45
4.61
3.66
0.70
0.67
0.31
0.55
BDL
0.71
0.39
1.44
32.51
9.22
9.50
15.08
4.36
17.43
5.93
0.58
0.57
BDL
0.58
0.51
0.43
0.79
0.36
0.95
0.77
1.08
2.75
0.94
0.73
4.55
4.87
7.79
7.54
0.84
0.81
1.10
59.49
9.17
13.59
0.80
4.59
18.14
17.56
0.87
3.27
0.62
85
3.90
0.73
1.35
0.20
0.39
0.32
2.99
2.26
ND
0.50
ND
0.37
0.16
ND
0.13
1.04
ND
5.39
6.79
8.51
1.09
7.31
3.96
ND
0.32
0.26
ND
0.47
0.29
0.45
0.17
0.61
0.55
0.73
2.63
1.12
0.64
3.34
2.85
3.79
5.65
0.96
0.65
0.95
25.34
5.86
9.36
0.48
3.66
1.06
11.84
0.62
2.12
0.36
136
1.31
0.18
0.29
0.08
BDL
BDL
0.73
0.79
0.12
0.10
BDL
0.14
BDL
0.18
0.06
0.33
6.10
3.65
4.87
5.39
1.58
5.55
1.64
0.18
BDL
BDL
0.18
BDL
BDL
0.13
BDL
0.17
BDL
0.12
0.31
0.30
BDL
0.88
0.70
1.16
1.67
BDL
BDL
0.08
7.25
1.97
2.86
0.07
0.48
3.38
2.21
0.07
0.24
BDL
77+110
17.19
3.70
5.08
1.19
0.92
1.51
15.79
11.14
2.09
2.37
0.86
1.91
0.79
1.96
0.98
4.30
71.85
28.31
30.50
41.92
11.70
51.50
18.32
1.78
1.47
0.50
1.60
0.74
0.81
2.25
0.71
2.55
2.08
3.34
8.60
3.27
1.46
12.23
13.25
25.39
20.23
2.33
2.16
2.72
145.08
27.10
39.35
2.02
13.12
50.43
49.27
2.34
9.47
1.48
82
1.18
0.26
0.61
0.07
BDL
0.09
1.19
1.12
0.15
0.16
0.08
0.15
BDL
0.19
0.08
0.37
ND
1.39
2.96
3.97
0.91
3.60
1.59
0.17
0.12
BDL
0.15
0.09
0.10
0.17
0.10
0.16
0.19
0.28
0.72
0.19
0.11
1.00
1.02
1.22
1.57
0.25
0.27
0.48
18.50
2.66
6.21
0.34
2.30
5.09
7.71
0.28
0.73
0.20
151
4.76
1.08
1.99
0.28
0.32
0.34
3.25
2.66
0.47
0.65
0.17
0.52
0.20
0.90
0.31
1.85
46.33
9.59
12.95
14.30
4.15
11.23
8.08
0.80
0.51
0.62
0.83
0.28
0.19
0.43
0.13
0.49
0.55
0.92
3.12
1.76
0.69
3.65
3.37
5.05
6.00
0.63
0.41
0.54
18.67
6.07
13.12
0.34
1.89
7.70
8.42
0.43
0.87
0.18
135+144
2.80
0.52
0.82
0.16
0.15
ND
2.36
1.58
0.27
0.32
0.10
0.26
0.11
0.35
0.19
0.72
ND
6.68
7.92
9.65
2.53
7.88
3.46
0.32
0.24
0.17
0.22
0.14
0.08
0.24
0.09
0.35
0.22
0.39
1.10
0.78
0.26
2.08
2.13
3.58
3.23
0.31
0.21
0.31
20.46
4.21
7.05
0.21
1.33
7.04
6.19
0.27
1.00
0.14
107
1.51
0.31
0.57
0.07
0.13
0.10
0.30
0.79
0.12
0.16
BDL
0.11
BDL
0.26
0.11
0.56
11.76
3.22
3.98
4.97
1.77
4.80
2.53
0.20
0.20
0.19
0.18
0.20
0.10
0.17
BDL
0.26
0.21
0.28
1.06
0.84
0.27
1.48
1.59
2.72
2.54
0.24
0.18
0.30
10.15
2.38
3.79
0.16
1.37
3.81
3.42
0.17
0.45
0.13
149
15.50
2.76
4.09
0.69
0.83
0.93
12.42
7.63
1.28
1.75
0.44
1.23
0.63
1.55
0.83
4.16
ND
29.57
30.16
41.20
12.88
34.26
16.15
1.35
1.25
0.87
1.49
0.72
0.50
1.06
0.40
1.53
1.45
2.26
6.76
4.09
1.24
10.29
10.45
18.89
14.64
1.72
1.32
1.80
68.67
20.40
32.23
1.00
6.21
25.55
23.07
1.50
4.43
0.56
Concentrations in ng/g wet wgt)
Sample ID
118
134
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
Detection Limits
0.23
0.12
0.07
0.28
1.15
0.12
0.36
0.68
0.23
0.19
0.36
0.16
0.17
0.08
0.09
0.12
0.12
0.09
0.07
0.38
0.28
0.09
0.07
0.23
F-2836
F-2837
F-2838
F-2840
F-2841
F-2842
F-2843
F2844
F-2845
F-2846
F-2847
F-2848
F2849
F2850
F-2851
F-2853
F-2854
F-2855
F-2856
F-2857
F-2858
F-2859
F-2860
F-2861
F-2862
F-2863
F-2864
F-2865
F-2866
F-2936
F-2937
F-2938
F-2939
F-2940
F-2945
F-2946
F-2947
F-2948
F-2949
F-2950
F-2951
F-2952
F-2953
F-2954
F-2955
F-2956
F-2957
F-2958
F-2959
F-2960
F-2961
F-2962
F-2963
F-2964
F-2965
F-2966
F-2967
25.84
24.15
15.63
39.59
31.21
28.36
6.18
12.01
24.79
36.97
7.98
7.71
4.77
0.64
BDL
26.86
16.45
28.92
20.75
21.36
11.16
71.37
32.38
25.09
13.32
11.67
4.36
10.44
14.69
7.84
21.21
27.35
15.02
12.63
16.82
26.63
0.67
1.53
11.24
2.41
2.86
9.75
1.23
1.36
22.04
10.26
0.84
1.23
1.63
9.16
16.74
10.98
12.71
14.03
35.75
20.08
11.36
2.53
42.63
17.88
1.48
1.73
0.93
0.26
5.04
24.16
2.60
0.63
0.18
0.38
ND
0.31
2.99
25.36
14.97
2.34
1.93
1.11
3.70
1.60
1.75
32.82
0.78
0.20
0.69
0.71
0.94
16.16
1.80
1.24
1.35
0.81
3.63
0.96
0.15
6.78
0.17
0.24
0.30
3.22
5.73
9.60
13.32
1.78
BDL
0.33
0.15
0.38
0.21
0.40
0.84
2.10
1.74
0.55
1.24
ND
ND
ND
ND
0.11
ND
3.38
12.26
ND
ND
BDL
0.10
0.10
0.19
0.68
9.93
7.26
0.43
0.38
0.25
ND
0.91
ND
18.26
0.14
BDL
ND
0.17
0.12
0.47
0.11
0.20
0.15
0.20
0.39
0.97
BDL
0.14
BDL
0.08
0.16
0.12
0.07
0.50
BDL
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
0.10
0.08
0.14
14.14
BDL
BDL
12.87
14.58
11.12
3.70
3.15
BDL
7.93
3.37
4.31
3.64
BDL
BDL
19.72
BDL
10.67
14.92
13.35
10.38
24.11
12.03
8.86
BDL
5.92
3.18
6.85
6.81
4.98
9.16
12.21
6.96
6.01
5.64
13.74
0.29
0.66
4.32
1.06
1.04
4.38
0.60
0.76
20.85
8.92
0.49
0.48
0.61
4.04
6.04
4.25
5.07
6.56
29.74
10.57
9.49
103.75
9.86
7.20
108.10
100.63
80.86
28.80
28.23
7.99
70.40
36.23
30.54
25.25
3.82
BDL
115.17
14.73
70.19
91.08
79.64
64.87
161.65
80.38
68.89
16.25
40.68
20.11
43.32
47.07
31.18
66.34
100.86
50.69
47.08
52.83
102.92
2.25
5.47
37.27
8.90
9.05
37.91
1.71
1.99
155.68
61.31
1.21
3.43
2.45
32.11
50.76
37.16
39.59
54.87
225.67
75.60
64.86
3.56
77.15
56.11
0.98
1.37
0.71
BDL
18.09
76.08
1.62
1.47
0.20
0.23
BDL
2.21
3.89
100.62
54.84
2.56
1.79
2.58
5.30
2.48
2.59
127.86
2.12
0.69
1.57
1.99
1.01
2.90
1.86
1.77
1.70
0.56
2.79
0.97
BDL
0.39
BDL
0.21
0.20
BDL
BDL
2.07
0.56
BDL
BDL
BDL
0.24
0.41
0.21
0.20
0.81
2.54
1.35
0.38
1.01
2.49
1.99
4.18
3.20
2.94
0.99
1.72
3.77
3.12
1.32
0.71
0.42
BDL
BDL
2.09
2.49
4.55
1.52
1.17
0.95
5.93
2.80
2.25
1.37
1.70
0.72
1.71
1.59
1.30
2.94
2.13
2.00
1.88
1.65
3.96
BDL
BDL
0.85
BDL
0.47
0.79
BDL
BDL
3.13
1.61
BDL
BDL
BDL
0.65
ND
0.80
0.84
ND
4.87
2.10
1.72
77.74
1.64
1.05
118.62
104.75
79.74
25.47
21.57
1.57
74.64
27.29
17.57
16.12
2.18
BDL
79.57
1.39
47.93
66.18
53.23
40.63
134.33
61.64
55.52
1.41
27.80
12.44
27.58
32.99
19.64
56.34
61.41
42.94
36.82
42.61
86.95
1.71
4.01
28.88
6.90
6.73
26.95
3.26
3.68
107.45
44.24
2.26
3.04
3.67
15.89
24.96
19.60
22.86
31.01
152.01
50.61
42.92
12.62
77.94
43.40
16.37
12.92
ND
3.55
16.36
63.09
9.54
3.49
1.77
2.02
0.28
0.57
8.14
64.96
42.91
6.05
5.83
4.08
14.27
7.98
5.50
91.55
2.58
1.10
2.75
3.76
1.91
7.59
6.86
5.78
4.99
6.49
12.53
0.27
0.59
4.33
1.44
0.97
4.26
0.57
0.49
16.28
5.70
0.38
0.43
0.59
1.73
2.61
1.85
2.05
2.98
18.89
5.40
4.69
5.92
14.11
6.63
4.02
4.97
4.88
1.68
3.41
10.08
1.55
1.81
1.64
1.68
0.29
BDL
7.27
5.97
7.68
5.55
4.01
5.65
7.45
3.91
2.92
16.49
2.68
1.97
2.71
2.83
2.29
3.08
5.10
2.33
2.17
1.01
2.34
0.97
0.34
1.48
0.19
0.37
0.56
BDL
BDL
11.36
4.00
BDL
0.20
1.05
1.55
2.30
1.33
1.73
2.58
16.13
4.40
4.18
25.88
8.89
8.67
20.30
33.67
21.81
8.97
13.97
8.10
12.04
11.21
6.34
6.94
0.37
3.58
22.79
6.11
16.86
17.76
12.37
15.49
31.72
16.79
13.29
10.07
10.35
6.12
10.24
11.25
7.31
18.52
18.39
15.63
12.64
6.70
31.41
0.49
1.16
8.01
1.84
1.61
7.22
1.34
1.55
40.15
16.45
0.97
0.95
1.20
5.63
8.56
6.13
6.96
10.19
68.79
16.42
17.30
17.96
13.31
12.90
11.55
12.96
11.11
4.59
10.81
20.58
5.27
6.70
2.67
3.73
0.38
0.23
11.03
15.88
16.66
8.47
5.88
8.40
18.89
9.52
7.66
35.66
4.96
3.58
5.11
6.15
3.38
9.38
10.10
7.82
6.60
4.89
15.87
0.20
0.59
3.73
0.18
0.99
4.59
0.84
0.56
27.51
8.92
0.37
0.44
0.59
2.55
4.04
2.95
2.50
4.36
44.87
9.52
9.00
9.28
7.77
8.02
19.64
14.37
11.37
3.28
5.53
13.84
11.57
2.88
2.47
2.41
0.36
0.25
12.55
8.53
15.61
16.49
8.35
5.52
15.70
7.25
6.23
20.94
3.60
2.28
2.86
4.48
2.92
7.96
8.32
5.10
4.88
5.15
11.86
0.17
0.56
4.06
1.03
0.97
3.77
0.75
0.54
11.93
5.17
0.33
0.37
0.61
2.34
3.88
2.98
3.52
3.73
14.59
6.51
4.24
2.17
6.20
2.30
0.29
0.59
0.48
0.08
1.47
3.44
0.82
1.13
0.10
BDL
ND
0.08
0.92
4.02
4.07
1.21
0.34
0.76
1.83
0.75
0.78
5.25
0.44
0.35
0.58
0.57
0.19
1.71
0.15
0.92
1.27
0.48
2.42
0.97
BDL
0.42
0.09
0.12
0.20
0.09
BDL
0.62
0.16
BDL
BDL
0.09
BDL
ND
BDL
BDL
BDL
1.24
1.01
0.14
6.44
1.02
1.22
3.58
4.86
3.62
0.93
3.86
2.34
4.01
4.13
0.50
0.42
BDL
ND
4.19
0.59
3.22
2.94
2.33
4.18
8.70
5.31
4.72
0.54
2.90
0.98
2.75
2.92
1.76
7.83
2.54
5.32
5.18
2.86
10.38
0.13
0.25
1.23
0.31
0.63
0.93
0.18
0.23
8.22
2.52
0.20
0.20
0.23
0.29
0.71
0.48
0.31
1.13
13.97
1.00
1.91
3.33
4.92
5.19
8.45
10.01
8.43
2.92
5.50
12.05
4.34
4.20
1.98
2.79
BDL
BDL
8.11
3.09
7.07
5.74
4.31
5.55
7.60
5.09
3.60
4.40
3.90
1.62
3.67
3.68
2.52
6.73
7.04
5.14
5.26
2.12
11.69
0.12
0.21
1.77
0.22
0.47
0.36
0.30
0.30
13.96
5.43
0.25
0.44
0.40
1.43
1.91
1.62
2.03
3.52
30.91
5.88
6.00
8.98
3.20
3.44
11.94
5.44
5.34
2.75
4.32
9.53
6.77
3.80
1.81
2.84
BDL
BDL
11.65
5.14
11.16
5.98
3.98
10.48
8.66
5.68
3.37
13.30
4.28
2.34
5.54
6.41
3.37
6.45
8.43
4.56
4.50
1.81
8.75
0.12
0.25
1.97
0.42
0.49
1.22
4.26
0.42
13.17
5.48
0.18
0.21
0.18
1.34
2.36
1.36
1.90
2.67
27.42
6.91
5.81
3.62
ND
3.50
4.03
3.44
3.13
0.98
2.25
6.12
ND
1.38
0.81
0.82
ND
BDL
3.88
4.09
7.40
3.13
2.54
4.50
ND
2.76
2.18
7.56
1.79
0.81
1.99
2.11
1.16
2.39
2.21
1.85
2.18
1.40
3.78
0.97
0.13
0.79
0.26
0.21
0.88
0.26
0.15
3.37
1.67
0.11
BDL
0.14
0.70
1.22
0.86
0.86
1.06
6.21
2.05
1.43
5.37
9.99
9.87
3.92
4.39
3.68
1.77
6.71
9.74
1.69
2.23
0.63
0.51
ND
9.72
2.72
10.20
6.17
2.09
1.61
2.62
5.24
2.81
2.25
10.06
1.28
0.74
1.56
1.62
0.87
3.11
1.72
2.63
2.37
1.71
5.73
0.97
0.21
1.42
0.38
0.32
1.23
0.49
0.26
7.66
2.48
0.21
0.16
0.21
0.55
0.78
0.61
0.55
1.01
11.25
0.98
1.89
59.83
2.20
2.44
43.98
46.03
38.10
14.39
17.48
3.97
17.39
24.01
6.83
5.36
1.27
1.07
24.10
2.15
14.74
18.36
13.30
22.94
61.70
28.32
27.36
5.59
13.02
5.34
13.20
16.23
7.54
32.80
25.51
29.85
21.71
18.71
59.82
0.65
1.67
10.97
3.68
2.98
15.73
1.56
1.63
86.02
27.22
1.52
1.22
1.78
6.59
10.11
6.68
7.35
12.31
124.04
14.62
22.48
6.54
22.49
29.66
4.76
ND
5.20
2.28
22.18
45.12
ND
1.60
1.24
1.04
0.37
1.40
2.85
21.32
34.74
18.92
7.33
10.44
1.94
14.64
0.74
60.77
ND
0.34
0.78
1.02
ND
69.72
5.68
3.49
18.03
4.45
40.93
0.51
1.49
8.33
BDL
0.68
7.33
1.22
1.11
21.62
11.62
0.77
BDL
BDL
1.33
3.87
0.73
1.44
2.97
21.25
9.73
4.33
1.44
0.88
1.19
1.07
1.17
0.71
0.38
9.98
36.23
0.49
0.54
0.11
0.15
ND
0.20
0.73
11.34
9.69
0.53
0.32
0.51
1.46
0.46
0.40
6.21
0.25
0.12
0.70
0.30
0.16
0.80
0.92
0.76
0.50
0.61
1.40
0.97
BDL
0.34
0.11
0.10
0.41
4.26
BDL
2.57
0.79
BDL
BDL
1.05
0.15
0.23
0.15
0.19
0.29
4.97
0.49
0.79
BDL
0.91
1.26
0.09
0.14
0.08
BDL
0.58
2.06
0.27
0.31
ND
ND
ND
0.07
0.21
0.61
0.68
0.15
0.11
0.32
0.15
0.10
BDL
2.12
0.14
BDL
0.86
0.14
BDL
0.45
BDL
0.39
0.32
0.17
0.70
0.97
BDL
6.02
BDL
BDL
0.08
0.11
BDL
0.10
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
0.22
BDL
BDL
40.69
BDL
BDL
31.68
33.16
28.14
10.13
11.41
0.73
13.66
15.58
4.12
3.55
1.00
0.35
16.59
BDL
9.71
13.01
9.73
14.55
35.82
17.05
14.96
BDL
8.13
3.45
6.77
10.15
4.15
22.70
13.78
21.26
14.37
13.44
42.15
0.48
1.23
8.02
2.45
1.96
10.42
1.30
1.02
58.88
16.82
0.98
0.93
1.22
3.46
5.01
3.10
3.74
7.44
83.56
8.66
15.46
Concentrations in ng/g wet wgt)
Sample ID
F-2968
F-2969
F-2970
F-2971
F-2972
F-2973
F-2974
F-2975
F-2976
F-2977
F-2978
F-2979
F-2980
F-2981
F-2982
F-2983
F-2984
F-2985
F-2986
F-2987
F-2988
F-2989
F-2990
F-2991
F-2992
F-2993
F-2994
F-2995
F-2996
F-2998
F-2999
F-3000
F-3001
F-3002
F-3003
F-3004
F-3005
F-3006
F-3007
F-3008
F-3009
F-3010
F-3011
F-3012
F-3013
F-3014
F-3015
F-3016
F-3017
F-3018
F-3019
F-3020
F-3021
F-3022
F-3025
F-3026
F-3027
F-3028
F-3029
F-3030
118
18.49
ND
17.11
41.37
44.45
87.74
36.26
4.05
10.76
9.17
1.09
3.88
12.76
23.15
55.02
0.90
32.79
16.18
16.53
16.71
10.12
6.26
11.21
12.91
12.09
8.51
13.83
13.78
12.60
13.79
19.12
6.18
15.85
5.77
10.44
18.63
23.07
33.08
2.91
28.71
16.92
15.46
8.53
13.40
9.39
26.70
10.48
6.07
7.35
66.71
19.82
1.10
1.21
11.62
38.64
9.78
10.18
22.87
7.36
51.22
134
0.93
ND
1.15
2.64
4.35
57.24
1.81
0.35
1.03
0.77
1.10
0.76
0.91
1.32
8.62
0.89
2.42
2.50
2.68
1.53
0.69
0.65
0.97
1.46
0.67
7.75
1.29
14.24
12.91
0.49
0.45
0.35
3.67
0.68
0.73
1.52
1.11
3.14
0.19
2.83
20.02
8.60
9.99
1.43
1.00
2.31
0.96
0.20
0.79
8.71
2.28
BDL
BDL
0.37
58.48
13.36
10.66
53.89
9.67
3.13
131
1.03
ND
BDL
1.06
BDL
0.16
ND
BDL
0.13
BDL
0.25
BDL
0.09
0.15
0.52
0.09
0.56
0.89
1.01
1.00
0.50
0.36
0.34
0.38
ND
ND
0.47
ND
ND
BDL
BDL
BDL
BDL
1.08
BDL
0.21
0.12
0.56
BDL
0.29
ND
ND
5.55
0.33
0.14
0.54
0.18
0.09
0.09
0.75
0.17
0.10
0.10
0.28
19.77
6.16
5.71
25.11
4.02
0.18
146
14.01
ND
10.76
37.11
43.09
94.10
28.79
3.29
11.81
6.00
10.50
2.98
7.81
15.45
33.44
6.52
14.89
14.61
12.59
14.21
9.21
6.95
8.49
9.48
7.06
BDL
7.91
BDL
BDL
5.29
6.05
2.89
13.17
5.60
7.55
11.38
12.30
23.36
2.23
16.54
BDL
ND
BDL
12.47
8.54
22.20
11.56
4.67
9.97
52.26
7.74
0.49
0.50
5.83
BDL
BDL
BDL
BDL
BDL
30.93
153+132+105 141
103.88
1.48
ND
ND
79.50
1.00
270.04
1.71
281.63
15.54
521.35
6.69
205.37
1.20
21.31
0.61
74.52
3.16
34.92
1.25
81.06
2.36
20.17
0.74
49.77
1.51
93.81
2.77
221.48
8.20
40.78
1.64
92.10
1.75
93.49
4.48
80.46
4.50
83.17
2.89
57.50
2.00
45.84
1.63
52.38
1.67
54.36
2.20
50.13
1.59
5.50
37.96
48.06
1.84
7.77
51.31
9.91
63.04
38.21
0.32
54.22
BDL
25.29
BDL
91.63
0.31
38.18
0.18
45.61
1.02
69.91
2.96
88.68
2.27
144.74
5.84
14.62
0.45
104.62
4.34
14.29
95.51
14.58
94.87
7.57
51.10
69.21
2.37
54.41
1.73
125.14
3.66
64.74
2.12
33.22
0.13
63.31
0.70
304.16
6.22
58.40
0.65
2.18
BDL
2.33
0.12
48.87
0.23
25.94
172.57
4.83
34.91
4.02
31.23
23.38
182.46
3.73
23.70
183.00
3.58
137+176
2.42
ND
2.71
5.29
4.06
20.88
ND
ND
ND
1.23
2.05
ND
1.73
3.06
7.49
1.58
1.40
1.66
1.85
1.47
0.93
0.67
0.87
0.95
1.78
1.21
0.79
2.24
2.32
1.23
1.02
0.43
1.17
0.90
1.25
2.65
2.81
6.38
0.49
4.31
2.83
2.94
1.71
1.19
0.91
1.85
0.95
BDL
0.75
5.08
0.74
BDL
BDL
BDL
2.91
1.46
1.47
2.35
1.29
6.55
163+138
66.98
ND
59.59
185.18
214.21
414.20
138.87
13.45
50.90
25.11
53.09
12.51
35.25
65.78
173.41
26.22
68.35
64.72
60.94
58.46
41.65
29.68
35.06
38.27
35.00
BDL
33.41
0.98
1.06
25.27
35.36
13.51
54.98
26.02
26.13
50.58
61.66
109.03
9.22
77.19
1.46
0.93
0.72
45.52
34.04
80.85
40.88
18.65
42.61
245.49
48.64
3.01
3.18
32.83
2.77
BDL
BDL
1.97
BDL
137.75
158
7.82
ND
7.77
31.78
35.58
74.80
26.24
1.31
6.23
2.16
6.89
1.39
2.98
6.29
22.34
2.91
8.90
10.27
8.90
9.57
6.32
4.49
4.38
4.16
2.56
18.22
4.56
36.27
39.38
2.93
5.34
1.69
7.15
2.66
2.05
4.02
1.09
13.88
0.81
7.60
61.27
32.40
31.83
4.09
2.83
8.28
3.14
3.44
7.38
48.88
8.60
0.53
0.51
6.21
127.41
26.96
23.74
137.57
22.63
21.82
129+178
7.67
ND
5.38
18.93
22.97
49.14
12.57
1.40
5.51
2.71
4.87
1.42
2.86
5.74
11.76
2.89
3.95
7.04
4.85
5.06
3.54
2.53
3.41
3.81
2.86
1.94
3.14
4.26
3.36
1.65
1.59
1.11
4.41
2.38
2.60
4.46
4.54
7.42
0.81
6.82
5.28
3.01
3.06
4.87
3.35
7.33
4.47
1.81
4.72
24.33
3.62
0.31
0.34
1.64
14.09
4.05
3.43
23.43
3.56
12.75
187+182
29.18
ND
22.93
66.69
83.01
160.22
47.73
5.30
22.18
8.68
17.66
4.93
10.11
19.97
57.77
12.13
10.93
24.14
19.70
19.02
14.28
11.74
12.63
12.43
11.14
3.22
10.63
9.39
8.88
8.23
7.01
4.65
22.77
10.67
10.53
16.41
16.75
34.59
3.21
24.61
9.89
2.44
9.70
16.49
11.90
24.81
16.72
7.52
18.51
81.40
14.67
1.50
1.30
9.11
9.61
4.51
4.65
10.50
9.18
42.35
183
17.72
ND
10.64
49.82
51.99
106.30
33.84
2.31
14.09
3.74
11.29
2.42
4.77
10.37
35.77
6.91
5.51
15.66
12.92
12.98
9.46
7.54
6.64
5.99
5.70
8.59
5.57
12.34
16.82
3.68
4.64
2.30
13.18
5.47
4.05
7.47
9.33
22.96
1.49
13.15
19.89
20.44
11.89
7.12
5.32
11.70
6.81
4.43
11.61
52.82
6.77
0.68
0.63
6.17
19.62
7.46
7.22
45.21
6.89
26.85
128
6.76
ND
7.94
20.97
25.35
62.48
16.18
1.74
5.76
3.09
6.20
1.62
4.48
8.87
27.30
3.11
12.38
8.20
8.10
8.16
5.19
3.92
5.27
5.33
4.25
4.02
4.75
6.07
7.76
3.72
7.04
2.05
7.93
3.77
3.46
6.69
9.66
16.60
1.17
11.74
9.64
9.74
5.38
6.95
5.55
12.45
5.51
2.48
5.15
35.03
7.80
0.60
0.62
5.59
10.31
4.40
3.67
28.95
3.25
21.73
185
0.40
ND
0.65
0.69
1.56
3.36
0.33
0.10
2.20
0.28
1.54
0.25
0.41
1.11
4.81
0.85
0.40
2.58
2.32
2.10
1.63
1.18
0.48
0.49
0.47
0.11
0.43
1.98
2.36
0.12
BDL
BDL
0.08
BDL
0.22
0.58
0.67
3.62
0.14
1.46
4.22
0.10
1.62
0.57
0.34
0.67
0.44
BDL
0.19
2.33
0.39
0.13
0.09
0.58
11.43
1.43
1.25
8.66
1.40
1.17
174
4.50
ND
3.87
11.84
14.71
26.71
5.81
1.12
7.03
1.71
5.32
1.01
2.06
5.07
20.37
3.17
2.42
9.54
9.15
4.86
4.29
3.37
2.40
3.24
2.11
0.30
2.11
0.48
0.64
1.21
0.54
0.22
1.74
0.88
1.45
3.92
3.16
13.33
0.83
7.58
0.68
0.61
0.36
2.91
2.31
4.04
2.50
0.65
2.17
15.46
2.69
0.37
0.40
1.85
0.48
0.68
0.53
0.84
0.60
11.44
177
10.77
ND
7.85
23.69
32.83
69.98
12.33
1.70
6.37
3.06
4.69
1.44
3.46
5.31
22.95
3.23
4.27
7.61
8.07
4.75
3.84
2.69
4.21
4.86
3.38
1.62
3.62
2.35
3.24
2.79
1.41
1.12
4.53
3.78
3.08
6.49
5.75
12.95
1.23
9.19
3.46
3.63
1.87
5.54
4.14
8.33
5.15
1.69
5.95
34.80
5.82
0.34
0.34
0.38
4.09
2.97
2.83
7.75
3.03
18.83
202+171
10.26
ND
7.79
32.76
18.90
49.86
ND
2.63
11.74
2.80
6.45
2.30
3.88
6.24
30.80
5.92
3.64
15.28
14.10
13.02
8.60
6.59
7.11
7.23
3.38
1.51
6.15
4.22
4.98
2.69
2.05
1.29
11.31
4.06
4.39
7.03
6.99
24.81
1.44
11.54
6.16
2.40
3.38
8.25
4.60
8.22
6.38
2.83
9.06
29.51
5.83
0.24
0.30
3.17
6.96
2.27
2.14
16.86
2.66
16.71
157+200
2.65
ND
2.56
6.83
5.45
0.99
5.38
0.96
4.05
1.28
2.61
0.86
1.61
3.05
10.68
2.32
2.91
4.44
3.97
4.47
2.82
2.13
2.37
2.37
1.71
2.52
1.76
3.78
7.46
0.88
1.35
0.54
3.10
0.79
1.41
2.60
3.00
6.80
0.47
4.05
5.83
5.66
4.47
3.14
2.16
4.20
3.18
1.05
2.21
10.07
2.07
0.17
0.26
1.53
5.71
1.96
1.75
11.31
1.50
7.12
172+197
3.71
ND
2.53
13.58
17.13
37.72
8.82
0.68
4.22
0.94
2.58
0.64
1.14
2.59
11.66
1.92
1.59
4.36
3.82
3.55
2.55
2.08
1.67
1.52
1.36
9.83
1.27
10.18
10.48
0.84
0.97
0.72
3.23
1.78
1.05
1.75
2.24
7.17
0.41
3.64
10.87
10.48
10.84
1.97
1.49
2.74
1.89
1.34
3.57
15.36
2.23
0.29
0.20
2.10
10.45
10.23
10.80
10.91
10.37
7.58
180
47.10
ND
27.61
138.72
151.98
312.24
92.94
5.62
40.35
9.16
30.11
6.13
10.97
26.32
108.37
19.10
12.83
42.94
37.05
33.44
24.34
20.18
16.18
13.29
12.52
0.86
13.15
1.09
1.96
9.62
12.23
5.66
37.74
15.00
10.57
17.92
22.40
66.18
3.53
35.59
2.10
2.30
1.30
16.95
ND
25.28
16.53
12.78
34.10
134.97
17.66
1.24
1.95
21.62
2.60
1.11
1.00
8.22
1.10
73.93
193
6.67
ND
65.99
76.98
12.17
37.81
16.99
12.63
22.62
6.17
49.91
6.51
29.95
36.30
4.78
1.18
7.77
80.01
69.92
2.34
23.75
1.10
1.07
0.93
1.04
9.28
0.79
12.46
19.11
0.53
2.46
0.88
37.88
2.45
0.63
0.72
0.82
2.04
3.80
1.02
20.30
21.69
12.18
1.15
0.65
1.33
ND
1.74
4.96
11.25
7.58
BDL
0.35
2.07
22.34
11.96
10.70
91.26
12.69
11.49
191
1.63
ND
0.90
5.75
4.10
13.69
2.36
0.18
1.07
0.18
0.87
0.13
0.38
0.81
3.42
0.57
0.36
1.50
0.96
1.42
0.66
0.55
0.48
0.32
0.25
0.87
0.34
7.46
13.84
0.29
0.40
0.20
1.03
0.52
0.32
0.39
0.88
2.06
0.11
0.98
12.92
2.32
4.21
0.48
0.29
0.53
0.29
0.31
0.87
5.10
0.57
BDL
BDL
0.46
2.98
6.03
4.58
9.43
3.51
1.43
199
0.09
ND
0.09
0.16
0.27
0.68
0.08
BDL
0.34
0.08
0.19
BDL
0.09
0.15
0.97
0.17
0.08
0.39
0.42
0.28
0.16
0.14
0.19
0.13
0.10
0.28
0.08
0.36
0.60
1.07
0.98
0.99
1.01
BDL
BDL
0.11
0.15
0.62
BDL
0.32
0.84
0.58
0.33
0.21
0.09
0.22
0.13
BDL
BDL
0.71
BDL
BDL
BDL
BDL
0.89
0.42
0.51
3.59
0.37
0.21
170+190
29.17
ND
19.73
109.27
98.09
217.21
64.04
3.95
27.08
5.99
16.85
3.95
7.67
16.28
85.46
12.86
10.73
29.87
26.55
23.31
17.65
13.81
10.15
9.26
7.76
BDL
8.01
BDL
BDL
5.58
6.77
2.95
21.80
10.23
6.43
11.51
14.63
40.76
2.42
24.75
BDL
BDL
BDL
11.13
8.49
16.95
10.98
7.74
22.03
86.52
14.37
1.26
1.30
15.15
BDL
BDL
BDL
BDL
BDL
51.13
Concentrations in ng/g wet wgt)
Sample ID
F-3031
F-3032
F-3033
F-3034
F3035
F-3036
F-3037
F-3038
F-3039
F-3040
F-3041
F-3042
F-3043
F-3044
F-3045
F-3046
F-3047
F-3048
F-3049
F-3050
F-3051
F-3052
F-3053
F-3054
F-3055
F-3058
F-3059
F-3060
F-3061
F-3062
F-3063
F-3064
F-3065
F-3066
F-3067
F-3068
F-3069
F3070
F-3071
F-3072
F-3073
F-3074
F-3075
F-3076
F-3077
F-3078
F-3079
F-3080
F-3081
F-3082
F-3083
F-3084
F-3085
F-3086
F-3087
F-3088
F-3089
F-3090
F-3091
F-3092
118
25.47
49.09
10.32
19.75
15.29
4.33
2.30
8.42
4.69
36.76
0.55
1.75
1.16
2.29
0.73
7.27
6.38
4.29
36.92
17.01
13.02
38.75
31.55
8.44
8.67
60.33
40.32
36.03
8.41
11.22
6.66
9.70
4.22
38.11
15.12
27.64
29.16
17.68
17.21
17.51
18.36
24.11
11.09
5.79
5.47
9.45
32.51
10.74
5.61
7.78
3.27
251.70
25.55
23.48
27.88
18.37
2.50
2.64
1.41
1.48
134
0.71
63.66
11.98
65.89
31.11
0.29
BDL
0.30
0.88
19.25
BDL
0.19
BDL
0.21
BDL
1.20
0.58
0.31
14.68
5.88
2.04
6.50
4.04
0.79
0.91
4.41
2.11
2.68
0.94
0.76
0.47
0.99
1.16
7.34
4.98
1.46
9.30
1.31
1.57
3.41
2.27
2.16
1.40
1.59
0.48
0.63
5.05
1.73
0.82
0.48
0.45
13.79
1.60
1.46
1.25
2.18
0.18
BDL
BDL
BDL
131
ND
65.29
5.92
36.94
11.62
0.09
BDL
0.11
0.10
1.47
BDL
BDL
BDL
BDL
BDL
0.35
0.12
0.14
0.83
0.38
0.10
0.54
0.18
BDL
BDL
0.19
0.27
0.09
0.11
0.10
BDL
0.14
0.56
0.54
0.17
0.15
0.34
BDL
0.10
0.24
BDL
0.13
0.09
0.23
BDL
BDL
0.12
0.12
BDL
BDL
ND
1.48
ND
BDL
0.11
ND
ND
ND
ND
ND
146
18.70
BDL
BDL
BDL
BDL
1.52
0.75
3.29
1.62
11.73
BDL
0.51
0.56
0.80
0.32
2.54
2.45
1.73
12.05
6.16
9.10
36.94
26.97
6.50
7.72
32.26
29.20
27.34
3.76
5.02
3.03
4.56
5.50
24.63
11.06
20.18
30.83
15.00
11.41
11.57
12.83
15.01
7.56
5.75
5.20
8.83
21.93
8.73
5.23
5.32
2.15
69.61
21.00
17.00
12.34
18.08
2.38
2.08
1.40
1.75
153+132+105 141
130.26
1.20
26.65
200.82
6.81
42.28
33.27
243.89
6.48
60.80
12.74
0.26
5.79
BDL
26.57
0.36
13.15
0.20
79.66
2.00
1.53
BDL
4.99
BDL
1.67
BDL
4.70
0.17
BDL
BDL
18.40
0.73
19.84
0.45
12.85
0.35
95.92
2.13
47.70
1.59
60.60
1.67
210.47
8.16
158.37
6.61
44.94
1.32
52.33
1.70
214.32
5.65
176.87
7.35
172.21
5.37
26.65
1.35
34.80
1.68
21.22
0.91
30.26
1.35
31.84
1.10
135.28
4.70
63.82
1.99
123.33
4.40
158.95
5.63
96.65
2.84
71.92
1.85
67.68
2.69
82.27
2.71
94.80
2.74
45.44
1.16
37.20
1.09
26.56
0.74
48.72
1.58
129.19
4.23
50.20
1.84
32.02
1.06
41.99
0.55
14.10
0.33
520.13
1.40
140.95
2.78
99.97
1.50
78.83
0.85
101.65
0.85
13.53
0.22
16.52
BDL
9.43
BDL
12.83
BDL
137+176
2.69
8.90
1.84
2.17
2.48
0.62
BDL
1.00
0.57
5.13
BDL
BDL
BDL
BDL
BDL
0.90
0.82
0.57
4.39
2.08
2.12
10.68
7.72
1.34
1.67
8.92
ND
6.47
1.35
1.51
0.96
1.29
1.29
5.82
2.40
ND
8.83
2.88
2.16
3.51
2.58
3.85
1.91
ND
0.96
1.81
4.32
2.06
1.28
1.12
0.46
31.98
2.86
3.59
2.45
4.18
0.41
ND
BDL
0.42
163+138
94.01
2.91
0.76
3.45
0.84
10.00
4.72
21.13
10.43
71.54
1.23
4.01
2.59
4.96
1.71
16.12
15.16
10.45
87.96
44.77
39.11
132.73
100.13
27.62
32.05
160.09
107.04
119.65
18.20
23.95
14.18
20.71
18.22
94.57
42.35
78.15
104.04
62.41
47.79
47.15
54.67
65.93
29.33
17.86
15.59
28.93
84.97
31.76
19.59
29.37
9.90
523.95
97.56
75.72
59.48
71.37
8.10
7.04
4.88
7.26
158
13.83
166.98
29.82
181.28
47.81
1.64
0.57
3.35
1.71
14.44
BDL
0.60
0.40
0.87
0.27
2.55
2.47
1.62
11.86
6.27
2.61
12.39
8.05
1.89
2.48
14.07
11.56
8.71
2.04
2.25
1.23
2.60
1.50
10.64
4.18
7.53
9.62
4.65
3.90
4.56
3.68
5.30
2.53
1.49
1.42
2.35
6.71
3.13
1.96
3.29
1.14
126.93
16.45
9.85
10.96
13.23
0.95
0.69
0.43
0.90
129+178
7.55
19.47
3.10
34.37
8.98
0.56
0.33
1.14
0.46
2.76
BDL
0.23
0.22
0.45
ND
1.15
0.74
0.47
3.74
1.98
3.90
18.79
14.16
2.94
3.90
11.53
12.13
11.52
2.09
2.57
1.39
2.22
2.66
9.24
4.27
7.41
12.15
6.82
4.14
5.72
5.32
6.53
2.44
3.10
1.91
3.63
9.67
3.18
2.37
2.73
1.18
11.05
11.09
7.60
4.91
9.45
1.59
0.80
0.67
0.95
187+182
31.08
10.86
9.01
11.34
9.81
2.83
1.50
7.45
3.10
13.23
BDL
0.84
1.20
1.70
0.66
4.08
3.69
3.34
25.97
12.95
13.12
56.02
43.44
9.85
13.03
37.64
39.92
38.56
5.68
7.27
4.30
6.22
8.85
29.00
12.57
24.95
38.03
22.72
12.78
16.34
16.93
18.30
7.92
8.86
6.82
13.05
32.47
11.45
8.41
11.28
6.49
42.39
38.11
29.02
18.04
30.22
4.42
3.55
2.55
4.16
183
20.74
48.66
11.22
73.33
16.44
1.71
0.52
3.85
1.63
7.55
BDL
0.43
0.26
1.01
0.28
2.70
2.52
1.37
11.80
5.14
5.39
27.86
20.41
4.09
5.72
18.76
20.63
16.84
3.18
4.10
2.36
3.58
3.23
14.47
6.26
12.53
17.04
9.09
5.72
7.86
7.39
7.66
3.36
4.18
2.70
5.60
13.56
5.47
3.74
6.54
1.40
37.78
25.68
18.01
10.52
19.47
2.00
1.95
1.29
2.16
128
13.38
28.69
5.05
42.11
9.53
1.74
0.47
2.55
1.55
15.78
0.19
0.68
BDL
0.67
0.25
2.86
2.14
1.53
13.48
6.51
6.33
21.73
13.40
3.29
5.39
33.31
3.99
17.03
2.73
1.73
1.99
2.73
2.35
17.97
8.26
3.68
20.93
8.25
7.30
7.55
6.96
6.92
5.21
0.84
1.87
3.25
10.20
4.28
3.72
3.84
0.82
84.66
16.42
7.29
5.60
8.16
1.05
0.92
0.68
0.98
185
0.26
11.67
1.46
11.33
3.10
0.25
0.09
0.47
0.24
1.31
BDL
BDL
BDL
0.10
BDL
0.34
0.33
0.23
1.97
0.92
0.49
2.34
1.80
0.28
0.43
1.47
1.98
1.46
0.27
0.46
0.20
0.31
0.33
1.24
0.53
0.77
1.60
0.60
0.42
0.69
0.59
0.73
0.18
0.55
0.14
0.40
0.96
0.48
0.33
0.26
0.09
1.78
1.88
0.86
0.75
0.16
ND
1.08
ND
ND
174
5.84
2.38
0.49
0.68
0.82
1.10
0.35
1.96
0.96
5.97
BDL
0.14
0.29
0.34
0.14
1.69
1.41
1.04
8.59
3.74
2.38
11.53
9.31
1.58
2.12
7.61
11.28
6.71
1.82
2.81
1.19
1.91
1.89
6.06
2.67
4.88
5.92
3.71
2.37
3.99
3.35
3.66
1.51
1.96
1.07
2.13
5.33
2.37
1.61
2.74
0.95
6.07
9.46
7.16
3.68
4.12
1.05
0.10
0.19
0.30
177
9.62
19.47
2.46
7.55
4.64
1.00
0.30
1.84
0.84
6.04
BDL
0.20
0.26
0.54
0.18
1.64
1.37
1.06
7.05
4.18
4.16
18.71
14.21
2.96
3.67
13.03
11.93
11.96
2.20
2.76
1.59
2.29
2.65
10.26
4.43
7.10
12.20
6.71
4.16
5.96
6.02
6.38
2.88
2.39
1.90
3.89
8.10
3.83
2.58
4.00
1.17
23.07
6.95
9.26
5.16
12.27
1.58
0.49
0.74
1.26
202+171
18.47
24.85
3.80
26.37
4.51
0.78
ND
1.57
0.82
1.09
ND
ND
ND
ND
ND
1.13
ND
0.59
5.09
2.53
4.45
22.84
15.59
2.79
4.97
13.59
16.85
11.07
2.10
1.94
1.51
1.90
3.47
9.49
4.39
6.44
11.56
7.66
3.51
5.78
5.07
4.75
2.21
4.04
1.92
3.44
8.74
3.53
2.99
2.97
1.07
ND
11.01
9.17
ND
14.81
1.60
1.13
0.95
1.30
157+200
4.76
13.65
3.42
15.29
2.99
0.47
0.16
1.00
0.43
4.01
BDL
0.12
0.10
0.25
BDL
0.59
0.64
0.43
1.07
1.70
2.05
11.94
8.29
1.56
2.37
7.28
7.11
6.50
1.05
1.27
0.71
1.10
1.63
6.19
2.45
3.53
7.21
3.49
2.19
3.23
2.69
2.28
1.32
ND
1.05
1.89
4.76
1.74
1.54
1.23
0.42
34.21
6.24
4.91
3.52
4.52
1.01
0.72
0.52
0.29
172+197
6.51
10.61
10.49
10.15
10.46
0.62
0.24
1.29
0.61
2.33
ND
0.20
0.17
0.32
0.22
0.69
1.27
0.58
3.11
1.46
1.31
7.03
5.29
0.97
1.36
3.76
5.77
3.50
0.78
1.12
0.62
0.88
0.93
3.22
1.40
3.06
3.70
1.92
1.39
2.23
1.40
1.41
0.79
1.66
0.71
1.34
2.69
1.20
1.04
1.79
0.97
10.78
7.50
5.95
3.21
6.03
0.71
0.48
0.44
0.74
180
68.72
10.16
1.12
11.60
1.19
5.14
1.70
12.05
5.34
22.18
0.43
1.45
0.93
2.13
1.29
5.91
6.90
4.96
41.64
19.33
12.52
63.71
54.10
9.50
13.88
43.57
51.99
41.38
7.59
10.85
5.76
9.60
8.29
33.43
13.74
28.71
37.48
22.57
12.33
17.75
16.61
18.19
7.38
10.15
6.17
13.94
32.80
12.41
9.31
18.44
3.31
94.83
73.28
52.81
30.36
47.08
4.70
4.52
3.33
5.76
193
8.38
106.27
12.00
132.25
23.49
0.42
0.30
8.94
0.40
2.70
BDL
0.74
BDL
BDL
0.32
ND
ND
2.75
1.88
1.35
6.02
51.33
13.63
0.68
2.58
2.33
7.18
1.41
0.29
1.70
ND
ND
0.77
1.74
0.95
4.16
1.47
1.35
0.71
0.59
1.02
0.60
0.31
2.41
BDL
0.90
1.84
1.09
1.59
ND
ND
14.18
8.81
8.18
4.66
7.49
0.90
0.69
0.53
1.38
191
1.48
8.79
9.27
13.44
1.89
0.15
BDL
0.28
0.10
1.13
BDL
BDL
BDL
BDL
BDL
0.12
0.16
BDL
0.83
0.43
0.26
1.67
1.60
0.27
0.42
1.04
1.22
1.07
0.19
0.29
0.15
ND
0.20
1.03
0.38
0.60
1.32
0.64
0.35
0.51
0.46
0.64
0.19
2.07
0.14
0.35
0.88
0.24
0.20
0.69
0.27
4.58
2.37
1.82
1.08
1.74
ND
0.12
BDL
0.17
199
0.18
3.16
0.23
5.17
0.75
BDL
ND
BDL
BDL
0.36
ND
BDL
BDL
BDL
ND
0.12
0.10
BDL
0.63
0.32
0.13
0.83
0.70
0.10
0.16
0.43
0.62
0.59
0.08
0.11
BDL
0.08
0.11
0.41
0.13
0.20
0.40
0.19
0.62
0.19
0.17
0.21
BDL
0.92
BDL
0.11
0.34
0.13
0.08
ND
0.12
0.20
0.19
0.18
0.17
0.12
ND
BDL
BDL
ND
170+190
48.83
0.60
BDL
BDL
BDL
3.13
1.17
8.78
3.94
18.29
0.31
0.96
0.67
1.53
0.81
4.30
4.66
3.37
28.98
14.11
8.31
41.33
34.32
6.15
8.62
33.20
31.85
30.30
3.90
7.03
2.91
4.36
5.63
19.04
7.78
17.86
27.85
14.61
8.78
9.92
11.03
10.53
5.37
ND
3.95
8.78
20.43
6.49
5.91
10.22
1.63
80.80
47.45
30.69
21.27
33.87
2.63
2.19
1.81
3.21
Concentrations in ng/g wet wgt)
Sample ID
F-3093
F-3094
F-3095
F-3096
F-3097
F-3098
F-3099
F-3100
F-3101
F-3102
F-3103
118
1.88
4.19
2.77
5.44
1.08
45.28
25.23
5.58
3.28
0.83
28.18
134
BDL
BDL
0.14
0.78
5.36
9.66
5.20
2.47
0.17
ND
3.54
131
ND
ND
ND
ND
0.47
0.19
0.11
ND
ND
ND
0.36
146
1.15
3.72
2.70
4.40
23.39
33.26
12.08
5.28
4.29
BDL
16.19
153+132+105
8.92
20.81
19.46
31.59
131.85
190.57
81.74
35.05
31.33
6.57
99.74
141
0.15
0.27
BDL
0.37
5.50
7.18
2.18
0.30
BDL
ND
3.04
137+176
BDL
0.40
BDL
0.70
7.02
7.37
2.80
0.71
0.77
BDL
4.54
163+138
4.68
9.68
8.90
19.17
93.40
130.80
61.97
21.90
19.43
3.24
67.52
158
0.44
0.61
1.06
1.69
11.29
9.59
5.86
2.20
2.38
0.29
7.10
129+178
0.49
1.66
1.28
2.25
9.51
14.65
5.50
2.30
2.53
0.20
6.51
187+182
1.77
6.03
5.19
7.60
31.13
48.43
18.30
10.59
10.40
0.52
19.92
183
0.87
2.07
2.49
3.91
15.37
20.79
7.90
4.78
5.88
0.83
10.22
128
0.65
1.24
1.38
2.84
4.89
14.98
8.59
4.15
2.39
0.36
10.89
185
BDL
BDL
ND
BDL
1.27
1.97
0.92
0.10
BDL
ND
0.93
174
0.27
0.48
0.34
0.97
5.93
10.55
3.75
0.97
0.68
BDL
4.36
177
0.46
1.55
1.14
2.17
11.11
16.29
6.46
2.85
3.41
BDL
6.75
202+171
0.72
2.47
2.10
2.62
17.67
13.97
6.72
3.04
3.24
0.19
7.04
157+200
0.23
0.88
0.90
0.95
5.68
7.07
2.42
1.14
0.84
BDL
4.46
172+197
0.22
0.50
0.63
1.29
2.78
5.06
1.55
1.39
1.93
0.15
2.42
180
1.80
4.22
5.70
9.89
30.55
55.19
19.85
11.71
15.97
2.54
23.47
193
ND
0.81
ND
4.18
1.96
2.56
2.25
5.14
2.39
0.49
1.24
191
BDL
0.10
0.12
0.24
0.60
1.30
0.56
0.31
0.45
0.09
0.89
199
BDL
BDL
ND
BDL
0.21
0.61
0.23
BDL
ND
ND
0.27
170+190
1.08
2.49
2.86
5.85
21.22
36.41
13.83
7.87
10.94
1.65
16.48
F-3104
F-3105
F-3106
F-3107
F-3108
F-3109
F-3110
F-3111
F-3112
F-3113
F-3114
F-3115
F-3116
F-3117
F-3118
F-3119
F-3120
F-3121
F-3122
F-3123
F-3124
F-3125
F-3126
F-3127
F-3128
F-3129
F-3130
F-3131
F-3132
F-3133
F-3134
F-3135
F-3165
F-3166
F-3167
F-3168
F-3169
F-3170
F-3171
F-3172
F-3173
F-3174
F-3175
F-3176
F-3177
F-3178
F-3179
F-3180
11.47
8.35
3.06
1.33
26.19
33.14
12.34
4.34
2.43
6.71
14.98
35.87
1.92
12.08
1.86
2.69
2.73
11.98
8.37
19.24
15.24
9.32
14.09
30.01
0.24
4.79
3.58
9.21
4.76
BDL
0.81
8.92
1.69
5.40
2.11
1.35
4.44
5.18
2.47
17.94
66.91
2.12
13.00
8.35
20.09
31.43
20.64
6.85
0.77
1.12
BDL
BDL
8.97
4.67
1.76
0.31
BDL
0.80
2.54
6.63
1.39
2.76
BDL
0.13
ND
1.26
12.83
1.94
1.37
0.70
1.24
5.29
ND
0.54
BDL
0.70
BDL
ND
BDL
0.85
0.22
0.37
0.13
0.19
0.44
BDL
0.60
21.93
68.19
0.14
3.98
20.35
46.74
50.48
20.25
8.39
0.12
BDL
ND
BDL
0.38
0.58
0.11
ND
BDL
BDL
0.16
0.17
BDL
BDL
BDL
BDL
BDL
ND
ND
0.62
0.24
0.07
0.14
0.81
ND
BDL
BDL
0.11
ND
BDL
ND
0.11
BDL
BDL
BDL
ND
ND
BDL
BDL
0.71
3.11
BDL
0.33
0.30
0.35
0.67
0.62
0.21
8.83
11.54
2.00
1.14
22.16
29.17
10.35
4.02
1.48
5.34
13.34
12.55
0.76
3.72
0.60
0.79
0.75
5.69
3.82
15.20
12.75
7.82
10.15
28.76
BDL
4.89
1.51
4.05
1.67
BDL
BDL
3.59
1.02
3.56
1.73
1.02
2.93
4.51
1.60
9.87
38.84
1.35
10.09
4.29
12.85
13.47
11.77
3.39
51.20
61.00
13.87
7.66
129.22
150.74
56.25
24.95
10.15
32.85
75.71
90.70
5.50
28.54
4.39
6.37
6.40
40.76
29.44
95.58
72.33
47.26
62.80
153.75
2.10
30.51
12.98
32.04
17.15
1.77
3.46
30.68
7.66
24.34
12.91
9.12
24.35
38.16
13.20
66.71
248.78
10.59
72.62
32.00
89.80
90.82
84.77
25.09
1.57
0.92
BDL
BDL
5.28
5.48
2.84
0.38
BDL
0.86
2.25
1.35
BDL
0.30
BDL
BDL
BDL
0.71
0.21
3.96
2.65
1.30
1.74
6.36
BDL
1.08
BDL
0.73
BDL
BDL
BDL
0.68
0.19
0.75
0.35
0.21
0.90
1.46
0.41
3.15
12.50
0.15
1.68
1.10
6.51
4.70
3.74
0.71
1.97
1.88
0.52
BDL
6.89
7.43
2.69
0.83
0.37
1.20
2.80
ND
BDL
1.33
BDL
BDL
BDL
4.36
ND
4.61
3.00
2.03
2.48
7.51
ND
1.14
BDL
1.06
BDL
BDL
BDL
0.93
BDL
0.76
BDL
ND
0.93
1.15
0.41
3.60
14.23
0.41
2.47
1.37
5.06
6.42
4.16
1.15
33.27
33.59
8.48
4.03
87.48
98.87
34.92
14.70
6.10
19.94
49.92
82.61
4.15
21.49
3.89
5.29
5.33
31.80
23.75
67.09
47.87
29.29
39.25
99.97
1.08
17.67
7.25
19.83
8.25
ND
2.25
20.38
5.22
20.03
9.43
5.20
15.42
24.83
8.30
52.89
217.66
7.06
51.47
24.14
70.79
81.11
66.73
19.43
3.29
4.34
1.16
0.49
8.25
9.52
3.14
1.48
0.76
1.71
5.39
14.55
0.38
2.99
0.60
0.82
0.85
4.57
3.66
10.11
4.94
3.01
3.93
11.68
BDL
1.50
1.06
3.39
1.31
ND
0.27
3.41
0.56
1.53
0.94
0.60
2.25
3.26
1.22
7.62
33.26
0.99
7.71
3.50
10.13
12.80
9.75
2.95
3.15
6.00
1.13
0.63
11.05
11.38
5.19
1.93
0.84
1.82
5.31
4.09
0.29
2.13
0.23
0.38
0.41
2.04
1.98
5.51
5.68
2.99
4.27
11.17
BDL
2.83
0.54
2.20
0.66
BDL
BDL
2.05
0.48
1.64
0.79
0.39
1.44
2.47
0.74
3.90
16.55
0.64
5.43
1.67
9.14
5.76
5.33
1.15
11.99
20.29
4.59
2.30
32.18
33.82
15.94
7.02
2.87
6.81
18.52
17.51
1.44
6.59
1.21
1.32
1.17
9.31
5.92
24.54
17.91
10.91
13.13
37.41
0.52
8.88
2.28
7.27
2.46
BDL
0.37
7.37
2.17
9.69
4.49
2.48
6.11
10.00
3.26
20.65
81.84
2.51
20.88
7.38
29.97
24.66
25.23
6.28
5.03
9.46
1.77
1.04
16.14
16.56
7.14
3.05
1.17
2.81
9.07
10.09
0.37
4.18
0.34
0.55
0.52
4.66
3.39
16.38
8.82
5.11
5.98
20.40
0.31
4.06
1.19
4.40
1.70
BDL
0.33
4.13
0.95
2.45
1.67
1.47
3.91
6.36
1.90
11.16
44.99
1.43
13.03
5.37
16.49
13.76
14.52
3.19
3.96
4.82
1.45
0.61
17.39
19.06
5.15
1.89
1.05
5.26
9.73
17.22
1.01
3.78
0.50
0.91
0.50
4.83
4.26
9.12
7.88
3.96
5.97
17.45
BDL
2.21
1.18
2.47
1.04
BDL
0.39
2.23
0.67
2.34
0.94
0.54
1.98
2.25
0.94
7.54
39.05
1.05
7.92
4.38
9.00
15.62
11.62
2.87
0.43
0.33
BDL
BDL
1.76
1.20
0.52
0.52
ND
0.24
0.64
0.58
BDL
0.43
BDL
BDL
BDL
0.29
1.23
3.10
0.87
0.36
0.41
2.12
BDL
0.32
ND
0.12
ND
BDL
ND
0.25
0.13
0.56
0.27
0.19
0.69
1.06
0.29
2.29
8.91
0.14
2.02
1.04
3.88
3.10
2.63
0.62
1.93
3.57
0.41
0.27
6.96
6.84
3.71
0.81
0.36
1.25
3.45
5.80
0.21
1.12
0.29
0.40
0.30
2.34
1.32
8.05
4.09
1.91
2.72
11.09
BDL
1.75
0.12
1.42
0.10
BDL
BDL
1.83
0.53
2.44
1.06
1.04
3.49
5.45
1.42
9.65
38.42
0.85
6.74
4.39
17.01
13.15
11.74
1.81
3.48
6.89
1.35
0.72
10.88
11.38
5.71
2.01
0.95
2.22
6.17
7.95
0.33
1.72
0.24
0.37
0.29
3.46
ND
7.06
5.65
3.36
4.47
13.07
BDL
2.83
0.50
2.18
0.29
BDL
BDL
2.73
0.65
1.70
0.96
0.69
2.44
3.57
1.05
7.69
31.59
0.67
6.30
3.09
12.70
10.37
9.63
2.07
3.59
6.49
1.09
0.81
10.55
11.28
5.11
2.63
0.92
2.27
6.17
7.53
0.40
2.77
0.22
0.38
ND
2.52
4.53
13.03
5.48
3.45
4.18
13.08
0.22
2.97
0.50
1.15
0.57
BDL
0.12
1.45
0.53
1.49
0.93
ND
1.74
3.04
0.79
5.67
20.79
0.65
6.51
2.94
8.86
7.75
7.30
1.61
1.60
3.60
0.64
0.35
7.53
7.28
3.09
1.11
0.46
1.09
3.53
4.12
BDL
1.10
0.10
0.18
0.15
1.42
1.18
5.20
3.04
1.97
2.87
6.59
BDL
1.72
0.32
1.02
0.37
BDL
BDL
0.89
0.18
0.54
0.29
0.20
0.75
0.95
0.32
3.26
11.61
0.26
2.83
1.26
4.11
4.83
4.01
0.90
1.16
3.03
0.61
0.34
4.18
3.82
1.94
0.87
0.42
0.76
2.13
3.63
0.18
1.34
0.21
0.24
0.20
1.51
1.45
4.10
2.35
1.31
1.62
4.64
0.31
1.15
0.29
0.87
0.38
ND
0.17
0.74
0.37
0.99
0.60
0.47
1.15
1.71
0.64
3.39
14.11
0.44
4.10
1.55
4.67
4.48
4.62
1.07
11.36
25.93
5.08
2.20
36.27
39.09
14.91
6.53
3.09
6.84
20.75
30.51
1.06
11.13
1.15
1.75
1.80
13.10
10.81
42.85
22.36
12.37
14.24
49.55
0.96
10.26
2.61
10.24
3.82
1.04
0.98
10.01
2.95
8.97
5.14
4.41
11.19
19.49
5.69
35.86
141.55
3.97
40.53
15.00
48.96
41.46
46.48
9.47
1.31
ND
0.71
BDL
32.43
2.32
10.36
3.18
BDL
0.57
1.12
2.29
ND
5.11
BDL
ND
ND
ND
65.69
3.76
21.38
1.26
0.66
7.19
BDL
0.46
BDL
1.16
0.91
ND
ND
1.57
3.17
8.18
4.02
ND
ND
3.91
0.31
1.83
137.23
ND
1.55
0.86
4.90
1.92
4.44
0.35
0.26
0.69
0.10
BDL
1.00
1.48
0.48
0.19
BDL
0.15
0.65
0.98
ND
0.36
BDL
BDL
BDL
0.34
0.37
1.42
0.50
0.33
0.54
1.96
BDL
0.25
BDL
0.24
BDL
BDL
BDL
0.19
BDL
0.14
0.14
0.10
0.35
0.47
0.12
1.39
4.05
0.09
1.21
0.34
1.93
1.26
1.31
0.21
BDL
0.11
BDL
BDL
0.64
0.59
0.26
BDL
BDL
BDL
0.16
0.11
ND
0.07
BDL
BDL
BDL
BDL
ND
0.41
0.16
BDL
0.22
0.53
ND
0.10
ND
ND
ND
ND
BDL
BDL
BDL
0.10
BDL
BDL
0.14
0.16
BDL
0.56
2.30
BDL
0.22
0.15
0.88
0.72
0.70
0.16
6.36
12.99
2.73
1.21
20.29
27.02
9.87
4.01
1.79
4.35
12.00
25.26
0.91
7.41
0.85
1.15
1.30
9.73
7.72
24.86
12.41
8.46
8.14
28.86
0.66
5.39
1.24
5.85
1.93
0.65
0.62
5.95
2.00
5.12
3.07
2.21
6.23
13.38
3.76
26.17
89.16
2.76
23.09
8.85
31.34
32.86
27.34
6.62
Concentrations in ng/g wet wgt)
Sample ID
F-3181
F-3182
F-3183
F-3184
F-3185
F-3186
F-3187
F-3188
F-3189
F-3190
F-3191
F-3192
F-3193
F-3194
F-3195
F-3196
F-3197
F-3198
F-3199
F-3200
F-3201
F-3202
F-3203
F-3204
F-3205
F-3206
F-3207
F-3208
F-3209
F-3210
F-3211
F-3212
F-3213
F-3214
F-3215
F-3216
F-3217
F-3218
F-3219
F-3220
F-3221
F-3222
F-3223
F-3224
F-3225
F-3226
F-3227
F-3228
F-3229
F-3230
F-3231
F-3232
F-3233
F-3234
118
13.80
2.59
4.55
0.61
1.27
1.06
13.74
7.19
1.29
1.70
0.50
1.22
0.52
1.74
0.76
3.53
113.84
19.60
18.48
27.57
10.82
28.57
14.01
1.29
1.19
1.18
1.21
1.89
0.75
1.27
0.56
1.70
1.75
2.43
7.61
4.02
1.98
12.67
12.47
27.39
16.98
3.10
1.93
2.91
93.74
16.85
28.93
1.66
11.46
31.77
31.43
1.97
6.01
1.27
134
1.42
1.14
1.44
0.41
0.53
BDL
4.44
1.28
0.86
0.37
0.21
0.42
BDL
BDL
BDL
0.28
3.70
14.03
12.54
15.02
11.01
75.41
1.01
0.21
0.14
BDL
0.19
BDL
ND
BDL
BDL
0.17
BDL
0.17
0.27
0.27
BDL
0.95
0.75
1.55
1.55
BDL
BDL
0.13
20.84
11.55
8.19
0.16
0.89
1.06
9.28
0.14
0.44
BDL
131
0.23
BDL
0.08
BDL
ND
ND
0.14
0.33
BDL
BDL
ND
ND
ND
BDL
BDL
0.11
ND
0.44
0.93
0.53
0.26
1.63
0.45
BDL
BDL
BDL
ND
BDL
ND
BDL
BDL
BDL
BDL
BDL
0.08
BDL
BDL
0.19
0.26
ND
0.48
BDL
BDL
BDL
2.23
0.74
1.10
BDL
0.21
1.33
1.26
BDL
ND
BDL
146
8.35
1.27
2.35
0.32
0.66
0.54
8.08
3.12
0.54
0.85
BDL
0.59
0.30
0.99
0.50
1.89
69.25
13.34
14.29
18.78
7.88
14.91
8.28
0.74
0.65
0.78
0.68
0.87
0.37
0.63
BDL
1.08
0.88
1.14
4.70
4.11
0.88
6.39
6.12
10.33
7.86
1.08
0.57
0.83
25.30
8.04
12.63
0.56
3.36
11.41
9.58
0.68
1.18
0.36
153+132+105
62.54
10.39
18.83
1.88
5.30
4.44
71.87
23.69
4.47
7.10
1.17
3.60
2.48
3.63
1.53
16.22
551.36
103.53
91.12
138.42
65.15
106.25
61.71
3.56
5.16
6.67
5.67
6.52
2.78
3.17
BDL
3.78
6.23
8.28
30.73
21.83
6.59
50.56
47.94
91.31
57.07
9.51
4.82
7.77
182.01
60.79
103.87
3.37
16.40
76.33
63.52
5.39
9.67
1.98
141
1.84
0.18
0.31
BDL
BDL
BDL
1.15
0.73
0.12
BDL
BDL
0.16
BDL
0.29
0.16
0.30
45.57
4.16
5.22
6.89
1.60
4.99
1.53
0.28
0.16
BDL
0.18
BDL
BDL
0.13
BDL
0.17
BDL
BDL
0.26
0.68
BDL
1.00
0.90
1.78
1.40
BDL
BDL
BDL
6.09
2.34
4.82
BDL
0.50
2.05
2.24
BDL
BDL
BDL
137+176
2.82
0.48
0.77
BDL
BDL
ND
2.31
1.23
BDL
BDL
BDL
BDL
BDL
0.54
BDL
0.65
10.47
4.79
5.65
7.85
2.63
5.46
1.84
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.38
1.04
0.83
0.51
2.09
2.04
3.09
2.48
BDL
BDL
0.42
12.30
3.20
5.34
BDL
1.23
5.20
4.10
0.38
0.59
BDL
163+138
48.69
7.56
13.30
1.89
4.00
3.19
51.01
19.90
3.45
5.08
1.43
3.53
1.80
5.19
2.43
11.44
368.25
75.35
65.85
106.16
42.61
86.80
46.13
3.95
3.62
4.54
3.97
4.01
2.04
3.41
1.48
4.86
4.76
6.48
24.15
12.33
5.03
36.69
35.19
75.01
44.78
7.88
4.09
6.28
178.65
49.24
85.49
3.65
21.92
65.44
59.16
4.26
10.44
2.46
158
5.77
1.09
1.95
0.26
0.56
0.34
7.14
3.08
0.47
0.72
BDL
0.49
0.26
0.72
0.38
1.62
57.38
13.64
11.76
20.88
7.30
17.15
7.27
0.52
0.53
0.61
0.56
0.51
0.30
0.52
0.26
0.74
0.72
0.97
3.72
1.11
0.76
5.94
5.82
8.52
7.09
0.96
0.66
1.01
39.06
8.97
12.62
0.58
3.76
12.14
9.83
0.66
1.53
0.41
129+178
2.74
0.41
0.79
BDL
0.25
0.24
2.57
1.01
0.30
0.26
BDL
0.24
BDL
0.61
0.25
0.97
7.08
5.98
8.45
10.12
2.99
6.90
3.11
0.42
0.39
0.38
0.41
BDL
BDL
0.34
BDL
0.44
0.28
0.39
1.13
1.56
0.36
2.12
1.77
2.77
2.73
0.62
0.22
0.41
7.30
3.41
69.07
0.22
0.98
2.90
5.33
0.34
0.74
BDL
187+182
23.44
2.17
4.08
0.59
1.12
0.85
14.56
5.52
0.97
1.46
0.46
1.00
0.60
2.12
1.12
3.82
130.70
25.80
26.21
39.85
16.54
27.00
15.75
1.62
1.44
1.62
1.36
0.87
0.56
0.93
0.56
1.90
1.31
1.76
7.45
5.88
1.29
11.20
8.80
18.03
13.41
2.34
1.27
1.76
33.72
18.65
36.03
1.19
6.02
15.32
12.26
1.08
0.76
0.62
183
9.97
1.23
2.35
0.30
0.49
0.43
9.03
2.86
0.44
0.81
BDL
0.49
0.26
1.20
0.71
2.36
83.28
19.15
16.35
27.63
10.94
16.99
10.26
0.82
0.79
0.90
0.75
0.69
0.30
0.46
0.22
0.76
0.76
1.04
4.04
2.50
0.72
7.31
6.64
12.30
7.47
1.08
0.51
0.82
23.56
10.34
20.96
0.46
2.35
7.12
5.78
0.50
0.46
0.31
128
7.66
1.15
1.89
0.26
0.52
0.48
6.06
3.64
0.59
0.85
0.24
0.67
0.26
0.67
0.33
1.37
18.65
8.78
8.57
14.86
4.50
14.25
5.85
0.51
0.45
0.53
0.50
0.60
0.27
0.45
0.29
0.68
0.73
0.99
3.59
1.41
0.70
6.77
5.55
10.88
6.32
1.46
0.56
1.06
34.30
8.78
12.65
0.62
4.22
11.07
12.40
0.75
2.17
0.38
185
1.83
0.18
0.33
BDL
BDL
BDL
1.35
0.52
BDL
0.10
BDL
BDL
BDL
0.18
0.11
0.31
10.09
3.24
3.84
6.36
1.63
3.73
1.62
0.12
0.13
0.10
0.13
0.09
BDL
BDL
BDL
0.14
0.08
0.11
0.58
0.19
0.11
1.46
1.08
1.79
1.31
ND
BDL
0.10
4.02
1.80
3.41
0.09
0.44
1.32
0.97
BDL
BDL
BDL
174
5.65
0.76
1.19
0.28
0.19
0.19
3.97
2.47
0.32
0.41
0.14
0.54
0.14
0.98
0.41
1.32
39.24
14.82
13.84
20.40
5.67
12.96
5.34
0.79
0.47
0.27
0.42
0.21
0.12
0.31
0.16
0.73
0.28
0.56
1.64
0.92
0.32
4.03
3.81
6.07
4.83
0.45
0.31
0.44
21.04
8.62
15.96
0.35
2.22
5.57
4.44
0.30
0.62
0.22
177
6.13
0.59
1.22
0.21
0.27
0.25
4.32
2.02
0.36
0.35
0.15
0.39
0.16
0.90
0.44
1.02
24.01
12.12
12.37
20.23
6.58
13.12
3.85
0.60
0.46
0.45
0.42
0.26
0.16
0.35
0.19
0.60
0.26
0.45
1.35
1.72
0.43
4.55
3.44
5.59
5.05
0.41
0.28
0.51
16.77
6.89
13.50
0.38
2.17
5.92
5.03
0.30
0.32
0.25
202+171
4.34
0.70
1.39
0.28
0.31
0.40
3.70
1.33
0.44
0.43
0.16
0.33
BDL
0.84
0.37
1.80
ND
10.00
13.61
23.68
5.34
19.14
5.30
0.70
0.44
0.75
0.76
0.59
0.25
0.44
0.18
0.40
0.36
0.50
1.85
1.53
0.66
3.07
2.52
4.66
3.51
0.55
0.30
0.52
31.30
4.65
15.28
0.30
1.34
4.28
3.41
0.29
ND
0.12
157+200
2.76
0.33
0.59
0.11
0.13
0.11
2.02
0.98
0.13
0.14
BDL
0.17
BDL
0.26
0.13
0.51
8.33
4.70
4.97
10.43
1.52
8.91
2.84
0.25
0.14
0.18
0.17
0.15
BDL
0.16
BDL
0.20
0.11
0.19
0.94
0.82
0.16
2.24
1.67
2.92
2.69
0.32
0.13
0.20
1.09
3.07
5.75
0.13
ND
1.06
3.36
0.15
0.31
BDL
172+197
3.44
0.48
0.81
0.21
0.20
0.29
2.63
1.03
0.27
0.36
0.18
0.25
0.18
0.45
0.30
0.79
23.61
5.30
4.83
9.36
3.03
5.71
3.19
0.37
0.29
0.35
0.30
0.41
0.18
0.21
0.14
0.37
0.27
0.36
1.24
0.68
0.26
2.58
2.16
4.18
2.21
ND
0.31
0.31
7.08
3.11
6.81
0.26
1.02
2.04
1.81
0.28
0.13
0.19
180
34.25
3.78
7.05
0.98
1.48
1.30
31.77
9.18
1.38
2.45
0.60
1.69
0.86
3.77
2.05
7.11
266.59
61.71
49.89
92.80
37.36
52.57
32.84
2.35
2.46
2.62
2.28
2.88
0.83
1.50
0.84
3.01
2.13
2.83
12.09
6.03
1.92
24.73
21.70
40.74
22.90
3.50
1.55
2.54
74.18
34.35
69.69
1.79
8.91
20.94
14.59
1.63
1.48
1.01
193
3.76
1.85
0.49
0.32
BDL
ND
1.31
1.15
ND
BDL
BDL
BDL
0.30
1.51
BDL
3.21
25.65
5.92
3.65
8.12
3.10
5.78
1.60
1.47
BDL
1.21
1.88
0.75
ND
BDL
0.74
0.31
1.42
1.95
7.11
0.66
1.66
1.96
9.96
3.79
1.65
ND
ND
ND
2.61
1.80
87.38
BDL
0.72
2.34
70.95
BDL
1.20
BDL
191
1.02
BDL
0.15
BDL
0.11
ND
1.06
0.20
ND
BDL
BDL
BDL
BDL
0.09
BDL
0.18
6.15
1.94
1.71
3.19
0.95
1.94
0.81
BDL
BDL
0.10
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.27
0.13
BDL
0.62
0.55
1.04
0.69
0.10
BDL
BDL
2.72
1.42
2.63
BDL
0.34
0.93
0.39
BDL
BDL
BDL
199
0.54
BDL
BDL
BDL
BDL
ND
0.31
0.13
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.79
0.85
0.70
1.51
0.36
0.80
0.17
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
0.29
0.22
0.40
0.28
BDL
BDL
BDL
1.19
0.58
1.07
BDL
0.08
0.38
0.28
BDL
ND
BDL
170+190
21.59
2.50
4.91
0.70
1.10
0.87
20.08
5.48
0.98
1.59
0.42
1.17
0.54
2.57
1.35
4.88
173.29
44.08
37.39
57.76
19.57
39.27
19.10
1.73
1.63
1.86
1.50
1.66
0.57
0.99
0.52
1.94
1.41
1.93
6.99
3.88
1.44
12.67
14.26
27.05
15.80
2.09
1.21
1.75
63.77
25.18
49.75
1.31
5.54
16.51
12.04
1.09
1.40
0.76
Concentrations in ng/g wet wgt)
Organochlorine Pesticides
Sample ID
198
201
203+196
189
208+195
207
194
205
206
209
Total PCBs
Detection Limits
0.08
0.17
0.23
0.11
0.14
0.09
0.27
0.12
0.18
0.08
24.19
F-2836
F-2837
F-2838
F-2840
F-2841
F-2842
F-2843
F2844
F-2845
F-2846
F-2847
F-2848
F2849
F2850
F-2851
F-2853
F-2854
F-2855
F-2856
F-2857
F-2858
F-2859
F-2860
F-2861
F-2862
F-2863
F-2864
F-2865
F-2866
F-2936
F-2937
F-2938
F-2939
F-2940
F-2945
F-2946
F-2947
F-2948
F-2949
F-2950
F-2951
F-2952
F-2953
F-2954
F-2955
F-2956
F-2957
F-2958
F-2959
F-2960
F-2961
F-2962
F-2963
F-2964
F-2965
F-2966
F-2967
0.56
17.63
18.10
0.67
0.80
0.69
0.29
7.19
32.12
0.28
0.42
0.08
ND
ND
0.83
0.41
13.69
7.83
0.33
0.21
0.78
0.58
0.35
0.29
28.44
0.31
0.10
2.56
0.29
ND
0.52
0.19
0.53
0.39
0.21
0.94
0.97
BDL
0.31
BDL
BDL
0.15
4.26
BDL
1.01
0.50
BDL
BDL
BDL
BDL
0.12
BDL
BDL
0.12
1.00
0.17
0.62
13.17
0.21
0.40
13.17
15.93
12.31
5.96
5.88
0.81
6.65
7.96
2.35
1.82
0.44
0.29
8.70
0.30
5.42
6.38
5.40
15.06
11.40
7.06
6.11
0.84
5.73
2.34
6.79
6.26
3.79
9.76
5.91
10.53
8.61
4.36
19.28
0.21
0.49
3.83
1.03
0.83
4.26
0.62
0.61
20.99
9.29
0.58
0.40
0.68
2.04
3.08
2.05
2.42
3.08
31.31
3.34
5.93
22.64
5.13
7.10
15.27
16.85
14.38
6.95
10.79
15.13
8.02
10.60
2.60
2.57
0.53
0.37
8.67
5.92
10.16
7.04
5.31
16.39
16.12
8.10
7.40
15.44
6.26
2.61
7.37
7.49
3.97
13.25
6.84
13.54
10.71
6.24
24.48
0.27
0.64
4.47
1.65
1.14
8.44
0.82
0.66
29.94
11.44
0.70
0.50
0.84
2.52
3.46
2.28
2.35
3.65
45.31
5.23
7.55
1.33
7.01
10.97
0.69
0.70
0.22
0.29
4.57
18.64
0.53
0.39
BDL
0.29
BDL
0.32
2.03
6.97
5.01
2.07
0.86
1.37
1.27
0.22
0.58
20.70
0.27
BDL
1.04
0.34
0.31
0.59
0.20
0.77
0.41
0.42
0.99
0.97
BDL
0.33
BDL
BDL
0.47
BDL
BDL
1.27
0.48
BDL
BDL
BDL
BDL
0.14
BDL
BDL
0.14
0.93
0.77
0.35
10.51
0.24
0.32
9.09
10.33
8.30
4.06
3.90
0.35
4.82
6.12
1.71
1.47
0.63
BDL
6.19
0.42
5.13
4.48
3.92
23.20
4.96
2.26
2.56
0.34
5.14
2.29
5.80
5.69
4.14
8.08
3.14
8.48
9.00
3.00
15.24
0.97
0.29
2.32
0.71
0.54
3.02
0.37
0.33
16.89
5.52
0.38
0.29
0.48
1.17
1.66
0.98
0.63
1.86
20.62
2.64
4.38
0.74
4.07
6.26
0.48
0.49
0.31
0.20
2.70
10.88
0.31
0.30
0.14
0.14
BDL
0.42
0.67
4.32
4.60
0.56
0.49
3.48
0.47
0.19
0.26
8.79
0.25
0.12
0.66
0.28
0.42
0.53
0.14
0.67
0.97
0.23
1.12
0.97
BDL
0.31
BDL
BDL
0.32
BDL
BDL
0.94
0.67
BDL
BDL
BDL
0.11
0.15
BDL
BDL
0.10
1.13
0.21
0.30
10.01
BDL
BDL
6.48
7.10
6.05
3.12
3.42
0.28
3.17
4.86
1.07
0.91
BDL
BDL
3.47
0.38
2.66
2.48
2.12
5.90
5.66
3.23
3.01
0.35
2.60
0.93
25.87
2.93
1.37
5.67
2.44
6.67
3.93
2.80
10.78
BDL
BDL
1.81
0.55
0.41
2.95
0.30
0.27
12.25
4.52
0.29
BDL
0.31
0.80
1.18
0.54
0.74
1.40
19.26
1.78
3.30
0.48
2.79
5.13
0.42
0.52
0.35
0.21
2.19
8.44
0.25
0.29
BDL
BDL
BDL
0.24
0.33
3.21
2.22
0.37
0.15
0.50
0.34
0.15
0.22
7.07
0.19
0.14
2.67
0.15
0.21
0.36
0.14
0.32
0.21
BDL
0.61
0.97
BDL
0.22
BDL
BDL
0.35
BDL
BDL
0.52
0.20
BDL
1.02
BDL
BDL
BDL
0.20
BDL
BDL
0.76
0.19
BDL
7.14
BDL
0.32
6.27
6.82
5.27
2.74
2.54
0.31
4.08
3.75
1.58
1.21
0.60
BDL
4.61
0.18
4.76
3.80
3.31
25.77
4.37
2.99
3.34
0.20
4.32
1.77
6.15
4.36
3.59
6.72
1.20
7.57
8.93
2.42
13.03
0.97
0.23
1.66
0.58
0.33
4.09
0.33
0.34
12.23
7.28
0.31
0.18
0.36
0.91
1.28
0.67
0.78
0.93
6.28
1.96
1.83
0.43
2.70
5.22
0.83
1.14
0.56
0.33
1.82
5.99
0.63
0.54
0.22
0.09
BDL
0.17
0.33
4.46
4.70
0.35
0.25
3.46
0.83
0.45
0.63
3.95
0.65
0.30
1.12
0.67
0.71
2.32
0.14
1.14
4.37
0.20
4.62
0.97
BDL
0.28
BDL
BDL
0.24
0.09
BDL
1.33
1.11
BDL
BDL
BDL
0.35
0.43
0.10
0.10
0.32
0.67
0.25
0.27
878.01
873.23
792.87
660.32
730.33
585.57
183.46
481.51
1098.56
774.54
309.44
145.02
130.59
25.93
37.78
662.38
519.40
783.62
540.48
451.33
475.07
2009.06
995.85
765.83
818.96
403.54
139.14
338.62
451.59
231.83
865.45
547.78
486.42
473.75
387.89
891.82
51.25
50.12
296.57
99.40
95.98
297.95
75.11
68.90
866.57
365.72
31.05
36.50
45.80
131.08
261.44
159.90
171.60
271.72
1303.87
406.04
361.16
SURROGATE RECOVERIES
14
65
166
105
109
115
93
115
121
90
112
118
111
93
120
97
92
88
100
90
123
106
130
82
115
124
95
117
109
94
89
94
105
172
127
63
125
105
124
84
6
90
241
103
110
90
84
77
90
87
85
99
87
88
80
55
94
120
83
98
82
80
86
91
95
93
86
92
75
96
88
97
81
73
76
84
40
87
82
90
70
99
91
87
91
82
85
66
80
95
120
87
40
83
74
98
74
77
72
65
75
73
73
73
65
70
78
64
82
87
81
66
48
84
85
66
85
98
99
98
95
92
105
88
96
92
97
90
103
82
70
78
94
66
102
90
101
78
101
100
89
111
89
103
92
89
85
93
90
44
89
80
97
76
82
75
176
80
86
77
74
88
79
80
71
84
88
76
68
51
78
119
76
81
alpha BHC beta BHC
lindane
delta BHC
aldrin
0.26
2.16
0.23
0.60
1.58
dieldrin mma chlorda
0.14
0.25
3.51
0.69
1.00
4.97
8.96
0.50
1.44
BDL
0.65
5.46
2.17
BDL
0.35
BDL
BDL
2.53
0.99
2.33
5.11
0.99
1.41
9.57
1.43
5.32
0.84
0.37
BDL
BDL
0.55
2.02
0.84
3.97
6.01
0.67
7.71
0.64
BDL
0.94
BDL
1.27
2.37
0.43
BDL
0.59
0.31
0.41
BDL
0.37
1.79
BDL
0.75
0.37
1.16
0.50
6.08
2.75
6.14
12.85
5.58
7.50
ND
73.54
5.66
15.05
2.33
7.23
38.86
16.15
2.93
2.35
7.18
3.38
11.12
5.62
3.95
13.46
4.73
8.11
134.00
ND
48.87
6.54
ND
2.45
BDL
BDL
13.24
18.13
32.20
43.35
11.54
57.38
8.91
BDL
6.84
BDL
7.30
15.01
3.79
BDL
2.98
2.49
5.64
2.31
4.08
13.09
BDL
2.36
BDL
8.54
3.41
44.50
15.23
29.72
BDL
0.31
0.64
0.93
2.44
1.01
0.54
0.46
0.98
1.55
0.64
BDL
BDL
BDL
BDL
0.30
BDL
0.66
0.67
BDL
BDL
1.51
0.69
0.35
0.74
BDL
BDL
BDL
BDL
0.43
1.70
0.60
1.19
0.64
1.17
0.83
ND
0.36
BDL
BDL
0.32
BDL
BDL
0.29
0.43
0.35
BDL
BDL
BDL
BDL
0.59
7.75
0.26
0.24
0.64
0.74
0.85
BDL
0.99
1.21
ND
0.76
BDL
BDL
0.74
BDL
1.65
2.34
0.78
0.68
BDL
0.62
0.92
0.95
1.23
1.24
0.77
BDL
0.89
1.33
BDL
0.74
1.09
1.03
0.99
0.81
BDL
0.80
1.51
1.02
1.17
1.04
0.84
ND
0.96
ND
1.03
0.87
0.86
ND
ND
BDL
BDL
BDL
BDL
BDL
0.76
0.96
5.54
BDL
0.86
BDL
0.79
BDL
BDL
BDL
BDL
5.25
5.92
1.91
5.14
BDL
1.59
5.11
5.51
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
4.88
BDL
5.45
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
7.72
11.74
15.61
19.43
85.50
28.32
7.14
4.40
20.78
17.12
5.30
1.16
1.17
3.65
4.09
6.34
0.69
8.92
8.75
2.33
6.53
22.66
17.52
10.94
44.82
4.73
1.11
2.12
2.23
40.19
114.91
21.50
120.69
34.66
37.19
42.77
3.83
11.99
4.63
6.81
33.67
6.63
2.54
10.04
15.27
23.90
4.62
5.26
9.15
2.57
9.71
2.61
6.23
8.01
35.26
10.75
23.62
6.30
8.80
10.72
9.92
21.38
8.66
3.27
7.14
42.93
30.72
8.80
1.20
0.59
BDL
BDL
2.76
0.33
3.25
4.38
1.13
1.58
16.07
10.94
9.72
10.40
3.22
0.66
1.01
1.98
11.26
73.84
9.20
84.82
27.71
43.14
49.32
0.75
1.13
0.30
2.59
10.95
2.11
1.09
2.22
2.64
4.27
0.55
6.65
14.28
0.63
2.82
0.92
1.61
3.40
13.87
4.96
14.42
Concentrations in ng/g wet wgt)
Organochlorine Pesticides
Sample ID
F-2968
F-2969
F-2970
F-2971
F-2972
F-2973
F-2974
F-2975
F-2976
F-2977
F-2978
F-2979
F-2980
F-2981
F-2982
F-2983
F-2984
F-2985
F-2986
F-2987
F-2988
F-2989
F-2990
F-2991
F-2992
F-2993
F-2994
F-2995
F-2996
F-2998
F-2999
F-3000
F-3001
F-3002
F-3003
F-3004
F-3005
F-3006
F-3007
F-3008
F-3009
F-3010
F-3011
F-3012
F-3013
F-3014
F-3015
F-3016
F-3017
F-3018
F-3019
F-3020
F-3021
F-3022
F-3025
F-3026
F-3027
F-3028
F-3029
F-3030
198
0.45
ND
0.52
2.30
3.02
6.83
1.67
0.13
1.03
0.18
0.58
0.23
0.17
0.46
1.76
0.48
0.15
0.98
0.91
0.92
0.64
0.42
0.32
0.28
0.15
4.04
0.23
7.47
11.46
0.13
0.12
BDL
0.85
0.25
0.18
0.32
0.29
1.71
0.09
0.68
13.05
7.42
7.60
0.40
0.24
0.37
0.40
0.35
0.80
2.85
0.44
BDL
BDL
0.40
19.36
7.61
6.99
47.69
8.06
1.99
201
11.29
ND
13.28
34.44
55.15
102.49
26.71
3.01
19.42
4.25
9.66
3.21
4.12
9.46
46.29
9.78
4.38
17.88
16.82
17.89
11.25
8.12
7.13
6.16
4.30
BDL
4.80
0.20
0.45
3.42
3.38
1.81
18.14
5.45
4.98
7.92
7.45
29.93
1.52
13.52
0.35
0.38
0.21
8.28
5.54
10.04
8.79
6.29
13.33
46.43
9.31
0.86
0.75
6.26
0.45
BDL
BDL
1.58
ND
34.75
203+196
15.34
ND
13.34
49.56
65.71
128.24
35.40
3.10
22.58
4.32
12.33
3.63
4.18
10.81
57.08
11.42
4.52
21.52
19.75
20.58
13.40
10.49
7.58
6.07
4.67
2.98
5.61
4.84
9.93
3.75
4.33
2.25
20.11
6.08
4.95
8.07
8.47
34.65
1.62
15.63
7.97
9.43
5.09
8.16
5.75
10.16
8.82
6.73
15.71
56.48
10.10
1.03
0.95
8.75
12.79
3.12
2.88
26.11
3.41
36.77
189
0.69
ND
0.45
2.26
1.85
6.24
1.10
0.21
0.62
0.67
0.67
0.27
0.73
1.16
2.23
0.86
0.65
1.15
1.17
1.09
0.63
0.47
1.02
0.99
0.34
3.29
0.83
5.66
10.34
BDL
0.13
BDL
0.32
0.16
0.22
0.98
0.95
1.16
BDL
1.31
7.89
9.39
5.25
1.76
0.95
1.63
1.31
0.21
0.54
2.20
0.44
BDL
0.14
0.43
11.75
3.95
3.77
33.78
4.34
0.36
208+195
7.24
ND
8.55
28.93
38.20
45.83
27.44
3.59
27.34
3.48
11.94
4.78
3.04
8.73
0.39
13.63
3.49
23.55
24.61
30.40
17.96
11.11
7.28
5.47
3.06
BDL
4.77
0.38
0.57
2.12
2.00
0.58
26.51
3.33
3.48
7.97
6.26
47.38
1.39
13.90
0.57
BDL
0.33
8.77
4.79
6.71
9.76
8.51
14.46
44.45
4.60
0.70
0.73
2.17
0.36
BDL
BDL
0.61
BDL
41.07
207
0.45
ND
0.60
1.60
3.83
6.68
2.06
0.35
2.94
0.34
1.07
0.59
0.27
0.94
4.54
1.57
0.45
2.97
2.96
4.33
2.44
1.69
0.88
0.58
0.20
2.11
0.50
4.03
11.35
0.16
0.16
BDL
2.79
0.28
0.33
0.68
1.09
4.90
0.12
1.24
5.22
6.69
4.30
1.15
0.66
0.83
1.30
0.97
1.44
3.54
0.37
0.10
BDL
0.52
9.81
1.16
1.07
17.77
1.94
2.81
194
6.46
ND
4.33
20.81
24.53
57.09
11.48
0.95
7.12
1.68
4.16
1.12
1.54
3.97
22.04
4.15
1.40
6.62
7.37
5.82
3.84
3.02
2.86
2.11
1.51
BDL
1.79
BDL
0.91
1.22
1.36
0.74
5.29
2.41
1.93
3.10
3.46
11.98
0.62
5.92
0.38
0.56
0.32
3.32
2.13
3.90
3.37
1.66
4.91
18.12
2.94
0.41
0.40
3.35
0.90
ND
BDL
0.70
ND
9.22
205
0.15
ND
0.24
0.84
0.45
2.24
0.27
ND
0.42
BDL
0.19
BDL
BDL
0.20
1.61
0.17
0.14
0.34
0.45
0.31
0.47
0.15
0.19
0.17
BDL
1.16
BDL
2.19
3.65
BDL
BDL
BDL
0.26
0.15
BDL
0.21
0.22
0.75
BDL
0.37
2.75
3.47
2.12
0.39
0.18
0.28
0.35
BDL
0.30
1.01
0.29
BDL
BDL
0.25
3.41
1.38
1.37
14.04
1.87
0.34
206
2.72
ND
4.79
18.20
51.59
97.23
26.74
3.42
35.80
2.89
11.62
5.38
2.47
9.33
50.51
15.30
3.51
29.27
31.95
42.04
23.44
13.82
7.04
4.58
1.93
BDL
4.33
BDL
BDL
1.60
1.28
0.78
28.51
2.13
2.84
6.69
4.38
58.41
1.23
13.10
0.19
BDL
BDL
8.69
4.32
5.51
9.14
10.58
15.63
45.52
4.01
0.58
0.46
5.31
BDL
BDL
BDL
0.43
BDL
52.80
209
0.34
ND
0.60
2.00
15.40
10.88
9.03
1.57
14.66
0.41
2.13
3.23
0.35
1.44
7.81
2.87
0.31
2.92
3.63
5.12
3.10
1.57
0.74
0.47
0.27
1.70
0.45
3.63
11.05
0.21
0.15
0.12
4.46
0.23
0.42
0.99
0.50
9.96
0.23
1.97
3.83
5.65
3.59
0.92
0.43
0.37
0.98
0.92
1.19
3.08
0.15
BDL
BDL
0.40
10.81
1.43
1.49
10.99
1.99
6.25
Total PCBs
550.50
0.00
518.30
1511.78
1890.69
3447.78
1606.29
169.02
709.30
253.45
583.73
166.18
343.61
650.69
1631.49
313.78
594.42
858.92
845.87
695.89
500.03
357.22
342.58
385.45
303.81
227.25
404.64
457.37
516.99
267.51
275.00
112.33
576.18
182.77
251.66
559.53
496.51
1280.38
85.64
863.89
500.46
360.12
302.68
417.26
277.51
643.26
356.15
192.66
395.87
1993.81
390.45
47.06
48.70
301.14
1017.37
441.31
382.47
1256.05
354.38
1261.79
SURROGATE RECOVERIES
14
65
166
6
77
92
0
0
0
94
77
91
93
66
106
100
71
123
140
91
154
114
72
103
64
67
70
84
73
92
70
61
72
83
65
73
93
81
81
64
59
66
72
65
78
83
80
112
72
62
71
90
80
85
127
89
105
122
82
95
95
79
92
99
87
103
99
78
83
99
91
93
94
91
95
88
74
83
24
0
36
58
54
59
98
80
103
101
85
94
97
80
90
112
84
90
79
74
79
116
91
99
102
79
87
82
72
80
103
81
96
88
79
86
111
84
106
73
62
66
113
88
99
104
88
101
11
0
26
102
81
99
101
82
88
111
90
96
104
89
105
93
81
88
91
79
81
116
88
99
167
91
123
116
87
93
133
84
90
113
86
84
114
91
97
95
86
102
57
38
49
63
43
48
109
80
107
111
89
98
116
85
113
alpha BHC beta BHC
2.42
15.14
1.17
8.29
2.51
14.76
2.81
20.77
0.42
2.18
1.60
9.97
0.48
2.31
BDL
BDL
BDL
BDL
BDL
BDL
1.59
12.28
BDL
BDL
0.52
4.19
1.07
8.06
2.07
18.18
0.33
3.99
0.54
BDL
1.66
11.65
2.32
13.11
1.32
10.26
0.95
6.65
0.56
3.80
0.88
4.95
1.28
11.85
0.61
ND
0.67
BDL
1.65
9.00
0.66
4.21
0.47
3.89
1.32
14.56
1.17
17.35
0.84
8.97
2.36
13.01
0.35
BDL
0.52
3.08
2.26
25.50
0.99
16.88
3.81
21.31
0.29
BDL
1.60
23.41
0.47
BDL
0.37
2.57
0.93
BDL
1.69
8.89
0.82
5.95
1.42
7.96
1.36
7.47
BDL
BDL
0.57
2.86
4.64
42.51
1.87
18.66
0.45
5.73
0.45
3.28
0.28
4.31
BDL
BDL
0.59
5.92
1.21
8.59
1.42
4.73
0.35
3.77
0.70
6.91
lindane
0.52
BDL
1.35
1.57
1.33
3.11
1.89
BDL
BDL
BDL
0.46
BDL
0.33
0.58
BDL
BDL
BDL
0.67
1.14
0.45
0.23
0.33
BDL
0.28
BDL
BDL
0.44
0.49
0.36
0.32
0.24
BDL
0.97
BDL
BDL
0.62
0.29
0.58
BDL
0.43
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.27
3.32
2.90
BDL
0.30
0.43
BDL
0.31
0.59
0.91
0.23
1.43
delta BHC
1.75
BDL
1.10
1.88
0.72
0.91
0.69
0.87
0.82
0.61
BDL
0.77
0.94
0.99
BDL
1.02
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.92
0.89
BDL
BDL
BDL
1.29
BDL
BDL
BDL
BDL
1.66
BDL
BDL
1.00
BDL
0.69
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.68
0.84
1.11
0.98
0.80
BDL
1.21
0.72
0.76
1.23
aldrin
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
4.12
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
4.20
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
2.34
BDL
BDL
dieldrin mma chlorda
11.84
8.18
3.02
2.75
16.75
5.87
50.95
8.55
53.92
7.03
180.07
18.51
88.36
6.65
3.28
0.99
4.55
1.40
0.79
1.39
142.79
17.58
2.18
0.58
3.33
1.38
4.33
2.36
19.70
6.65
2.59
1.07
1.97
0.48
13.80
5.03
21.87
6.75
7.73
2.35
5.70
1.74
6.32
2.06
3.76
0.88
4.13
1.67
2.13
0.67
29.62
1.27
5.60
2.04
3.62
1.78
4.81
1.81
10.47
3.64
10.40
2.52
5.96
1.19
48.01
2.89
2.19
0.45
2.19
0.63
8.99
3.68
3.89
1.52
19.92
5.90
BDL
BDL
8.22
3.65
2.82
1.15
35.20
1.11
1.77
1.21
3.90
1.40
2.39
0.74
2.41
1.74
3.28
1.24
2.65
0.51
7.30
1.49
88.00
17.51
32.15
8.41
17.67
9.57
15.07
7.80
14.28
8.96
0.39
0.41
13.76
8.25
19.35
12.65
58.26
16.47
6.77
10.63
54.48
6.84
Concentrations in ng/g wet wgt)
Organochlorine Pesticides
Sample ID
F-3031
F-3032
F-3033
F-3034
F3035
F-3036
F-3037
F-3038
F-3039
F-3040
F-3041
F-3042
F-3043
F-3044
F-3045
F-3046
F-3047
F-3048
F-3049
F-3050
F-3051
F-3052
F-3053
F-3054
F-3055
F-3058
F-3059
F-3060
F-3061
F-3062
F-3063
F-3064
F-3065
F-3066
F-3067
F-3068
F-3069
F3070
F-3071
F-3072
F-3073
F-3074
F-3075
F-3076
F-3077
F-3078
F-3079
F-3080
F-3081
F-3082
F-3083
F-3084
F-3085
F-3086
F-3087
F-3088
F-3089
F-3090
F-3091
F-3092
198
1.67
75.50
7.30
68.25
10.48
0.09
BDL
0.16
BDL
0.52
BDL
BDL
BDL
BDL
BDL
0.11
0.10
BDL
0.61
0.31
0.24
1.48
1.31
0.17
0.33
0.73
1.10
0.90
ND
0.16
BDL
0.13
0.27
0.67
0.26
0.36
0.79
0.54
0.15
0.39
0.31
0.30
0.12
6.40
0.11
0.24
0.58
0.15
0.20
0.34
ND
1.24
1.78
1.76
0.85
1.71
0.21
0.12
0.12
BDL
201
30.17
2.38
0.18
1.78
0.42
1.91
0.55
4.22
1.93
8.75
0.18
0.40
0.38
0.84
0.50
2.04
2.23
1.62
13.08
6.69
5.54
31.80
27.02
4.42
7.26
14.62
24.04
17.45
2.75
3.32
1.84
2.70
5.64
14.19
5.30
9.37
16.68
9.79
4.58
9.07
7.28
6.60
2.70
11.59
3.64
6.69
17.24
4.74
5.20
6.77
3.37
20.70
29.98
30.05
14.28
28.46
4.94
2.87
3.15
2.16
203+196
33.78
41.25
4.55
31.27
8.87
2.43
0.67
5.38
2.41
10.30
0.25
0.57
0.38
0.96
0.66
2.55
2.76
2.01
16.13
8.01
5.58
33.36
28.82
4.32
7.62
15.70
25.49
17.92
3.20
4.08
2.22
3.23
5.10
15.21
5.59
10.29
16.78
9.89
4.64
9.14
6.98
6.59
2.67
2.91
3.38
6.65
16.33
5.09
5.45
8.84
2.42
29.46
35.72
31.64
15.06
29.77
4.53
3.30
3.00
2.55
189
0.36
40.18
4.70
43.87
11.39
0.14
ND
0.20
BDL
1.48
BDL
BDL
BDL
BDL
BDL
0.20
0.18
0.11
1.92
1.08
0.72
3.11
1.20
1.68
1.27
0.82
0.74
1.01
0.49
0.39
0.46
0.41
0.59
3.80
2.10
0.45
6.02
2.64
1.44
1.48
0.37
5.19
1.41
2.55
0.41
0.70
1.65
1.55
0.99
0.40
1.00
3.72
1.21
1.30
0.66
0.99
ND
BDL
BDL
0.16
208+195
38.77
0.78
0.45
0.68
BDL
1.51
ND
3.17
1.43
5.80
ND
0.30
ND
0.60
0.35
1.64
1.57
1.30
9.85
5.11
2.64
28.85
13.80
0.99
2.13
3.72
24.72
3.92
ND
1.30
ND
ND
3.77
7.25
1.59
6.02
16.00
2.51
2.03
ND
2.14
1.84
0.52
ND
2.63
1.79
4.97
1.36
6.00
2.86
8.50
ND
ND
ND
ND
ND
ND
ND
ND
1.39
207
2.76
26.94
3.66
17.86
4.04
0.14
BDL
0.23
BDL
0.37
BDL
BDL
ND
BDL
BDL
0.12
0.12
BDL
0.62
0.29
0.48
2.76
2.09
0.40
1.01
1.07
2.72
1.73
0.20
0.16
0.11
0.16
0.83
0.79
0.38
0.59
1.74
0.85
0.68
1.11
0.50
0.61
0.20
2.64
0.29
0.35
0.89
0.25
0.69
0.39
3.41
2.04
3.31
4.16
1.74
3.59
1.45
0.66
0.79
0.13
194
10.90
1.54
BDL
0.68
BDL
1.00
BDL
2.31
1.00
3.86
BDL
BDL
BDL
0.38
0.27
1.02
1.18
0.90
7.23
3.58
1.96
13.75
12.03
1.78
2.97
5.76
8.74
6.39
1.20
1.71
0.84
1.29
1.70
5.81
2.16
3.55
6.31
3.70
1.83
2.92
2.67
16.44
1.05
ND
1.19
2.70
6.22
1.87
2.00
2.96
14.48
11.20
11.33
9.66
4.64
7.40
0.81
0.74
0.57
ND
205
0.50
21.23
1.57
15.07
3.22
BDL
ND
0.15
BDL
0.32
ND
1.07
ND
ND
ND
ND
BDL
BDL
0.50
0.25
0.27
1.10
1.01
0.19
0.49
1.43
0.58
1.21
BDL
0.19
0.14
0.15
0.16
0.91
0.32
0.32
1.26
0.55
0.27
0.34
0.41
2.55
0.34
ND
BDL
0.19
0.35
0.21
0.13
0.28
2.00
1.17
0.75
0.81
0.27
0.39
ND
ND
BDL
BDL
206
55.76
0.85
BDL
0.24
0.45
1.18
0.29
2.27
1.12
4.71
BDL
0.30
BDL
0.48
0.38
0.99
1.08
0.81
6.20
3.32
3.99
24.07
20.65
3.00
8.53
10.15
25.60
16.44
1.76
1.74
1.12
1.59
7.97
9.27
3.49
5.04
14.86
7.28
2.31
9.67
4.08
4.50
1.39
ND
2.06
3.42
8.42
2.20
6.42
4.81
1.39
25.45
42.08
59.62
22.82
43.45
5.87
4.26
4.00
0.85
209
7.79
29.37
2.22
8.47
2.35
0.16
BDL
0.28
0.16
0.57
0.10
0.16
BDL
BDL
0.08
0.14
0.17
0.13
0.63
0.34
0.69
4.50
3.00
0.47
1.63
1.31
12.46
2.45
0.29
0.35
0.25
0.25
1.43
0.83
0.43
1.69
2.14
1.06
0.20
1.43
0.40
0.60
0.18
7.28
0.21
0.38
0.97
0.19
0.75
0.85
0.41
10.14
15.93
12.47
4.17
5.09
2.26
1.39
1.85
0.11
Total PCBs
850.06
2308.25
377.41
1933.41
769.70
119.20
53.16
248.74
149.11
946.12
6.24
32.54
23.14
61.34
15.37
218.01
159.19
119.26
1052.05
576.25
385.52
1329.98
1033.36
228.82
281.94
1192.71
1117.05
910.79
307.88
353.17
199.27
317.83
205.51
1037.97
391.35
666.55
899.28
496.03
400.16
504.76
472.76
581.60
261.75
203.87
154.57
287.71
824.55
333.30
198.16
220.70
116.42
2836.17
867.85
743.42
565.33
651.27
97.10
69.37
48.98
58.35
SURROGATE RECOVERIES
14
65
166
91
73
92
147
92
114
95
81
95
136
88
124
192
93
104
98
88
94
67
48
63
98
72
85
UQ
80
112
94
126
97
77
74
78
92
77
82
124
42
83
111
78
90
112
79
93
120
87
89
115
86
93
102
77
81
135
89
82
99
70
68
88
79
85
94
91
109
101
75
90
81
62
66
68
55
62
68
58
76
72
UQ
63
72
62
77
86
73
79
74
43
72
79
64
68
92
73
87
90
74
80
109
94
107
90
90
98
100
UQ
61
95
106
118
74
46
65
82
69
78
102
82
92
80
57
70
68
46
64
100
94
101
75
UQ
58
89
88
92
73
71
78
102
71
90
87
84
92
67
72
76
63
65
75
98
48
85
80
54
167
86
78
108
78
56
91
109
68
99
88
58
87
66
47
63
52
46
55
65
42
63
89
80
85
alpha BHC beta BHC
0.50
2.88
1.93
8.76
0.38
11.98
1.16
6.65
1.19
8.74
0.45
3.48
BDL
BDL
0.95
7.71
0.36
5.47
BDL
2.77
BDL
ND
0.31
ND
BDL
2.90
ND
5.23
BDL
BDL
4.63
42.49
1.94
17.28
2.17
15.39
0.45
5.73
0.67
9.70
0.54
BDL
0.40
BDL
0.51
2.45
0.35
BDL
BDL
BDL
2.71
2.66
1.33
BDL
1.53
BDL
0.80
7.64
0.87
BDL
0.28
BDL
0.36
BDL
0.54
BDL
0.85
BDL
0.44
2.86
2.43
BDL
0.40
BDL
3.16
2.83
2.09
2.65
0.78
6.37
BDL
BDL
0.79
BDL
BDL
BDL
0.51
BDL
BDL
BDL
BDL
BDL
0.31
BDL
BDL
BDL
0.40
BDL
BDL
BDL
BDL
2.26
0.55
BDL
1.47
2.34
0.69
2.85
1.17
4.56
BDL
BDL
0.95
3.55
0.40
BDL
BDL
ND
BDL
4.01
lindane
0.26
1.81
0.43
1.14
0.35
0.37
0.55
0.59
0.71
1.70
ND
BDL
BDL
BDL
BDL
0.33
BDL
ND
0.39
0.24
0.29
0.53
0.34
0.54
BDL
0.49
0.49
0.33
0.25
0.43
0.46
BDL
0.32
0.55
BDL
0.40
0.51
0.85
1.23
0.41
0.39
0.36
0.73
0.38
BDL
0.34
0.43
0.35
BDL
BDL
1.51
BDL
0.40
1.34
1.99
2.27
0.82
0.36
BDL
BDL
delta BHC
BDL
0.97
0.96
BDL
0.76
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1.28
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
5.48
BDL
BDL
0.62
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.69
BDL
BDL
0.67
BDL
BDL
BDL
BDL
BDL
BDL
0.61
BDL
BDL
BDL
0.77
BDL
BDL
BDL
BDL
BDL
aldrin
2.65
2.28
BDL
2.15
1.65
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1.81
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
2.54
BDL
BDL
1.87
BDL
BDL
BDL
BDL
BDL
3.74
BDL
BDL
BDL
BDL
ND
BDL
BDL
3.23
BDL
BDL
BDL
BDL
BDL
BDL
2.27
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
dieldrin mma chlorda
8.42
1.33
68.84
47.99
2.91
1.65
95.48
19.20
56.60
43.12
3.27
2.39
1.73
1.23
6.35
3.70
3.24
1.16
19.27
20.33
0.71
0.34
8.70
0.57
7.92
4.15
6.07
12.77
1.85
2.40
33.63
58.82
17.18
20.01
10.48
15.69
40.04
70.33
23.89
52.25
1.96
0.47
6.05
2.07
5.36
3.67
0.40
0.37
0.36
0.51
6.09
2.81
62.59
5.07
6.40
1.82
4.18
4.34
8.41
6.33
2.62
3.07
4.98
5.07
3.43
0.99
7.61
5.17
2.71
1.01
47.78
2.87
7.44
0.99
6.74
1.59
9.63
1.08
4.90
2.71
1.93
1.43
3.17
2.14
1.15
BDL
9.14
0.95
0.60
0.30
0.71
0.51
2.36
0.45
1.24
0.40
1.68
0.31
3.52
0.89
23.65
3.96
17.39
0.56
5.16
0.56
20.88
2.90
31.39
7.76
13.74
1.72
15.67
0.44
4.79
0.49
1.60
0.29
0.65
0.31
Concentrations in ng/g wet wgt)
Organochlorine Pesticides
Sample ID
F-3093
F-3094
F-3095
F-3096
F-3097
F-3098
F-3099
F-3100
F-3101
F-3102
F-3103
198
BDL
0.15
0.15
0.11
0.35
0.95
0.35
0.16
0.23
BDL
0.53
201
0.71
3.18
3.85
3.42
9.94
24.32
7.82
4.73
5.22
0.52
10.76
203+196
0.83
3.32
4.05
3.88
11.25
24.31
8.29
5.08
6.62
0.87
11.45
189
BDL
0.16
BDL
0.21
0.73
3.31
0.47
0.32
0.32
BDL
1.47
208+195
ND
ND
ND
2.67
3.22
6.70
2.97
3.82
3.54
0.55
ND
207
0.10
0.68
0.70
0.36
0.39
1.05
0.48
0.36
0.24
BDL
1.11
194
0.32
0.72
0.82
1.63
1.66
9.91
2.99
2.04
2.78
0.31
4.30
205
ND
BDL
BDL
0.17
1.08
0.55
0.63
BDL
0.20
0.16
0.33
206
0.66
6.07
4.53
2.06
3.89
9.97
4.75
2.97
2.00
0.32
11.19
209
0.14
1.94
2.49
0.43
0.28
1.01
0.60
0.56
0.56
BDL
2.24
Total PCBs
43.51
105.11
85.83
146.55
1026.67
1266.74
572.05
188.82
150.96
21.45
796.51
F-3104
F-3105
F-3106
F-3107
F-3108
F-3109
F-3110
F-3111
F-3112
F-3113
F-3114
F-3115
F-3116
F-3117
F-3118
F-3119
F-3120
F-3121
F-3122
F-3123
F-3124
F-3125
F-3126
F-3127
F-3128
F-3129
F-3130
F-3131
F-3132
F-3133
F-3134
F-3135
F-3165
F-3166
F-3167
F-3168
F-3169
F-3170
F-3171
F-3172
F-3173
F-3174
F-3175
F-3176
F-3177
F-3178
F-3179
F-3180
0.17
0.86
0.14
BDL
0.93
0.95
0.40
0.24
0.09
1.08
0.45
0.67
BDL
0.28
BDL
BDL
BDL
0.22
0.20
1.00
0.40
0.17
0.29
1.00
BDL
0.23
BDL
ND
BDL
ND
ND
0.15
BDL
0.12
BDL
BDL
0.18
0.30
0.09
0.68
2.83
BDL
0.75
ND
0.85
0.91
0.93
0.23
4.56
17.43
3.09
1.87
17.68
20.03
9.44
4.41
2.42
2.86
10.78
12.51
0.63
4.50
0.51
0.63
0.62
5.52
4.69
19.93
8.81
5.25
6.95
19.40
0.52
5.30
0.84
3.33
1.06
BDL
0.26
3.16
1.06
4.04
1.86
1.55
3.40
5.35
2.02
11.71
49.33
1.28
12.88
4.95
16.05
15.18
16.25
4.41
4.58
16.96
3.22
1.99
18.68
20.68
9.03
4.58
2.36
2.89
11.07
14.99
0.71
5.47
0.47
0.75
0.74
6.65
5.72
24.27
9.47
5.70
6.85
21.42
0.60
5.71
1.10
4.86
1.48
0.70
0.40
4.77
1.15
3.32
1.94
2.01
4.48
6.82
2.44
15.67
61.94
1.46
16.81
6.58
20.51
18.90
20.69
4.95
1.92
0.55
BDL
BDL
4.07
3.20
0.63
0.14
BDL
1.06
1.82
1.07
BDL
0.25
BDL
BDL
BDL
0.48
0.31
1.29
1.48
1.27
0.73
4.61
BDL
0.47
BDL
0.19
0.13
BDL
ND
0.12
BDL
0.32
ND
0.12
ND
0.55
BDL
0.94
4.74
BDL
1.34
0.51
1.03
1.79
1.94
0.21
3.25
25.70
ND
0.52
20.16
15.64
8.04
6.05
0.85
1.17
9.78
7.45
0.17
2.75
0.22
0.38
0.40
3.71
2.87
32.83
8.55
4.27
7.83
16.36
ND
6.13
0.27
2.36
0.85
0.24
ND
2.54
0.73
2.33
1.39
0.68
1.72
4.12
0.88
ND
27.97
0.95
10.17
4.10
13.09
13.47
8.17
4.54
0.34
2.48
0.31
0.40
2.35
1.69
0.80
0.78
0.45
0.30
1.05
0.62
BDL
0.29
BDL
BDL
BDL
0.32
0.17
3.39
0.74
0.41
0.78
1.52
0.13
0.68
BDL
0.17
0.09
BDL
ND
0.15
BDL
ND
BDL
BDL
ND
0.19
0.10
0.57
3.06
BDL
0.70
0.28
0.61
0.81
0.95
0.35
1.62
4.97
1.02
0.39
6.77
8.30
3.70
1.24
0.60
1.36
4.30
5.41
BDL
2.02
BDL
BDL
0.31
2.50
2.18
7.78
3.49
2.29
2.70
8.21
BDL
2.25
0.37
1.56
0.51
0.29
BDL
1.58
0.43
1.34
0.73
0.74
1.67
3.00
0.94
6.72
26.72
0.54
7.29
2.84
8.46
7.58
8.44
1.81
0.27
0.26
BDL
1.04
0.85
1.13
0.24
0.13
BDL
1.08
0.40
0.53
ND
0.14
BDL
ND
ND
0.19
0.22
0.55
0.22
0.21
0.20
0.64
BDL
0.16
ND
ND
ND
BDL
ND
ND
BDL
BDL
BDL
BDL
ND
0.23
BDL
0.49
1.72
BDL
0.53
0.21
0.64
0.54
0.56
0.14
2.70
30.67
2.32
1.62
17.63
16.35
6.98
6.06
1.83
1.63
10.81
6.23
0.39
1.90
0.22
0.28
0.35
3.31
2.71
39.40
7.05
3.38
6.80
17.08
0.99
4.70
0.43
1.32
0.54
0.34
BDL
1.28
0.54
1.80
0.94
0.92
1.78
2.67
1.16
6.93
34.10
0.53
10.49
3.19
7.68
9.80
11.59
4.78
0.19
5.44
1.13
0.75
1.94
1.97
1.07
1.42
0.97
0.23
1.68
0.42
BDL
0.22
BDL
0.11
0.14
0.33
0.21
9.84
0.82
0.33
1.65
2.47
0.17
1.38
BDL
0.14
0.08
0.26
0.10
0.35
0.12
0.43
0.22
0.20
0.28
0.37
0.23
1.29
3.32
BDL
0.74
0.28
1.32
1.02
1.22
0.99
292.43
394.66
72.14
47.65
913.36
916.96
407.37
135.49
60.07
198.74
446.41
666.53
55.96
236.02
45.79
63.32
52.86
270.63
259.12
864.29
496.88
263.88
379.86
1091.54
8.80
179.80
50.50
196.28
72.83
10.08
11.23
199.21
59.44
202.47
81.20
50.17
177.20
260.44
90.79
772.74
2774.86
72.00
561.34
330.30
1086.52
1293.77
768.05
231.46
SURROGATE RECOVERIES
14
65
166
46
46
48
63
53
67
59
56
64
56
72
76
105
95
108
91
69
90
88
71
83
83
90
93
82
67
82
80
73
76
99
84
91
82
100
79
78
106
95
92
65
84
80
100
89
106
79
77
93
78
114
73
108
63
91
99
79
85
79
99
138
101
44
68
124
88
74
69
80
101
72
109
135
139
63
144
109
98
138
104
85
80
72
70
63
89
85
79
70
68
73
90
90
68
89
60
78
56
84
72
89
62
87
79
76
83
72
81
80
73
3
63
84
83
76
69
79
87
61
84
132
121
57
74
81
114
114
89
95
90
82
78
68
101
106
95
79
76
81
100
103
69
96
68
86
79
98
79
104
72
94
83
94
89
77
89
88
92
33
68
93
85
78
78
82
89
69
88
96
128
64
95
85
102
100
92
95
alpha BHC beta BHC
0.29
ND
0.84
3.08
0.55
BDL
BDL
BDL
0.74
2.61
BDL
BDL
0.38
BDL
BDL
BDL
BDL
ND
BDL
BDL
0.36
BDL
lindane
ND
0.60
0.29
BDL
0.69
0.36
0.28
BDL
BDL
BDL
0.93
delta BHC
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
aldrin
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
dieldrin mma chlorda
0.90
1.76
19.99
1.84
5.35
0.48
5.20
0.86
8.63
1.59
3.90
BDL
4.00
0.75
8.25
1.03
0.33
BDL
1.06
BDL
8.16
1.31
BDL
0.71
0.27
BDL
0.28
BDL
0.33
BDL
BDL
0.66
0.54
1.01
BDL
0.46
BDL
0.42
0.34
0.56
BDL
BDL
0.47
BDL
3.26
ND
BDL
BDL
BDL
4.08
BDL
BDL
BDL
BDL
3.80
BDL
BDL
BDL
2.22
BDL
8.29
BDL
BDL
BDL
BDL
0.69
BDL
0.23
0.42
0.28
BDL
0.40
BDL
0.34
0.40
0.40
0.32
0.71
0.30
0.34
BDL
0.31
BDL
0.61
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.68
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
2.32
15.48
1.82
2.42
6.44
3.81
1.61
6.06
2.66
2.76
5.43
15.17
1.57
7.26
1.16
2.78
0.84
14.37
2.34
12.94
0.73
0.59
4.14
0.46
0.45
0.92
1.41
1.73
0.75
0.66
0.44
0.87
2.03
0.29
0.82
0.35
0.86
0.29
2.43
0.47
4.00
0.62
1.24
1.11
BDL
0.58
0.58
3.08
1.33
BDL
BDL
3.42
0.66
0.71
0.36
ND
1.00
1.28
0.41
5.36
11.10
0.38
0.75
0.50
1.50
5.34
0.79
0.98
6.73
11.50
ND
2.40
3.62
23.91
10.37
BDL
ND
19.35
5.80
7.77
3.34
4.49
14.15
7.28
8.18
47.92
106.69
3.05
7.22
7.63
19.50
52.42
12.99
10.42
0.30
ND
ND
0.38
BDL
0.32
BDL
BDL
0.25
0.35
0.91
0.65
0.38
0.59
0.92
0.92
0.62
3.23
2.55
0.33
0.46
0.63
1.99
2.35
1.01
0.36
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.74
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
1.42
1.31
BDL
0.70
BDL
1.06
1.24
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
2.31
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
4.30
11.29
0.18
2.55
4.15
36.08
14.84
0.20
1.20
54.31
7.69
12.52
2.24
2.53
17.08
7.57
4.19
169.25
199.93
5.30
19.81
41.88
97.79
170.14
18.64
10.68
1.06
4.17
BDL
1.29
1.21
19.60
3.32
BDL
BDL
38.51
1.19
2.03
0.52
1.42
7.50
4.80
2.29
58.56
111.39
1.75
5.42
10.46
47.56
82.46
13.13
9.13
Concentrations in ng/g wet wgt)
Organochlorine Pesticides
Sample ID
F-3181
F-3182
F-3183
F-3184
F-3185
F-3186
F-3187
F-3188
F-3189
F-3190
F-3191
F-3192
F-3193
F-3194
F-3195
F-3196
F-3197
F-3198
F-3199
F-3200
F-3201
F-3202
F-3203
F-3204
F-3205
F-3206
F-3207
F-3208
F-3209
F-3210
F-3211
F-3212
F-3213
F-3214
F-3215
F-3216
F-3217
F-3218
F-3219
F-3220
F-3221
F-3222
F-3223
F-3224
F-3225
F-3226
F-3227
F-3228
F-3229
F-3230
F-3231
F-3232
F-3233
F-3234
198
0.87
BDL
0.12
BDL
BDL
ND
0.64
0.16
BDL
BDL
ND
BDL
BDL
BDL
BDL
0.12
2.80
0.91
0.74
1.62
0.44
0.74
0.57
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
BDL
0.14
0.09
BDL
0.39
0.34
0.60
0.41
ND
BDL
BDL
1.34
0.71
1.52
BDL
0.17
0.48
0.31
BDL
ND
BDL
201
17.73
1.57
2.84
0.57
0.70
0.53
11.64
3.48
0.61
1.01
0.29
0.87
0.41
1.24
0.75
2.01
70.69
19.17
15.01
30.38
10.49
16.80
9.37
0.84
0.96
0.75
0.65
0.45
0.25
0.67
0.39
1.32
0.64
0.98
4.00
3.01
0.68
8.83
6.74
12.15
8.41
1.11
0.53
0.83
25.40
12.83
28.08
0.74
3.25
8.92
6.01
0.62
0.29
0.42
203+196
22.17
1.94
3.55
0.65
0.73
0.64
15.31
3.95
0.72
1.24
0.32
0.98
0.43
1.56
0.97
2.73
98.36
26.48
19.66
42.78
15.23
22.05
13.57
1.08
1.19
0.97
0.85
0.98
0.35
0.89
0.47
1.62
0.89
1.41
5.43
3.00
0.85
11.96
9.36
16.62
10.30
1.32
0.63
1.02
32.20
16.28
35.31
0.88
3.78
10.89
7.21
0.76
0.42
0.51
189
0.96
0.12
0.15
BDL
BDL
BDL
1.10
0.31
BDL
0.13
BDL
BDL
ND
BDL
BDL
0.18
2.86
1.91
1.89
3.66
1.32
2.44
0.71
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.19
0.41
BDL
0.86
0.44
0.51
0.53
0.14
BDL
BDL
2.94
0.92
1.79
BDL
0.26
1.06
0.57
BDL
BDL
BDL
208+195
18.45
1.46
0.98
0.85
BDL
ND
2.73
1.80
0.20
0.40
BDL
0.37
BDL
1.09
ND
1.55
49.13
16.28
13.35
25.38
8.52
13.87
8.03
0.85
0.70
0.68
0.49
0.45
0.21
0.72
0.41
0.42
0.47
0.79
3.15
2.10
0.52
4.02
6.06
5.45
7.44
0.80
0.39
0.63
17.68
9.26
22.45
0.56
2.33
5.87
4.13
0.40
0.24
0.39
207
1.70
0.19
0.22
BDL
BDL
BDL
1.19
0.26
BDL
0.12
BDL
0.17
BDL
BDL
BDL
0.12
3.98
0.97
0.74
1.32
0.48
0.81
0.50
BDL
BDL
BDL
BDL
BDL
BDL
BDL
ND
0.14
0.14
BDL
0.35
0.21
BDL
0.64
0.48
0.71
0.54
BDL
BDL
BDL
0.77
0.52
1.08
BDL
0.14
0.38
0.27
BDL
ND
BDL
194
8.56
0.68
1.29
BDL
BDL
BDL
6.04
1.57
BDL
0.41
BDL
0.32
BDL
0.63
0.37
1.15
36.38
10.93
7.63
18.56
6.46
8.95
5.59
0.38
0.44
0.56
0.34
0.56
BDL
0.42
BDL
0.69
0.31
0.41
1.98
1.20
0.41
4.85
3.66
6.35
3.91
0.50
BDL
0.41
14.57
7.62
16.14
0.35
1.69
4.00
2.59
BDL
BDL
BDL
205
0.61
BDL
BDL
BDL
BDL
ND
0.39
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
BDL
3.41
0.64
0.45
1.16
0.30
0.55
0.36
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
0.28
ND
0.34
0.29
BDL
ND
BDL
0.90
0.61
1.48
BDL
BDL
0.31
0.23
BDL
ND
ND
206
22.61
1.66
2.75
0.73
0.86
0.55
16.81
3.52
0.64
1.03
0.39
1.29
0.38
0.83
0.58
1.24
42.18
11.62
10.16
16.02
6.43
10.01
6.04
0.62
0.53
0.54
0.50
0.42
BDL
0.69
0.35
1.26
0.35
0.74
3.23
1.51
0.46
7.25
4.92
8.88
6.93
0.54
0.22
0.39
9.95
7.03
14.25
0.44
1.61
4.98
3.35
0.33
BDL
0.30
209
5.54
0.33
0.45
0.22
0.16
0.16
2.73
0.44
0.14
0.12
BDL
0.21
BDL
0.15
0.09
0.18
11.40
0.85
0.91
1.03
0.38
0.72
0.70
0.08
BDL
0.11
BDL
BDL
BDL
0.24
0.09
0.26
BDL
0.16
0.55
0.13
0.11
0.86
1.04
1.36
1.50
0.13
BDL
0.18
0.57
0.92
2.02
BDL
0.20
0.34
0.61
BDL
BDL
BDL
Total PCBs
526.21
80.14
136.68
21.73
55.10
26.67
463.67
234.56
40.19
48.51
11.95
34.25
14.68
57.34
23.78
122.93
2677.51
814.08
896.07
1319.59
466.45
1271.26
505.11
44.28
39.09
36.67
41.34
38.99
22.94
53.00
17.98
65.44
50.00
73.87
237.83
132.30
61.85
373.35
363.29
612.21
522.45
65.25
50.15
66.28
2237.64
666.52
1331.28
42.88
260.18
957.26
969.25
51.11
108.60
26.01
SURROGATE RECOVERIES
14
65
166
89
83
93
95
87
91
113
91
93
128
99
103
109
59
67
57
54
56
96
67
75
119
85
85
88
87
89
71
65
68
105
76
82
95
78
83
96
72
80
119
88
95
107
87
91
113
85
101
79
UQ
UQ
83
81
93
106
117
110
106
101
112
85
100
100
154
158
111
132
83
91
99
84
90
118
79
87
89
88
92
104
81
85
51
UQ
26
106
76
84
93
66
76
112
76
80
99
64
84
82
75
74
121
92
100
167
58
83
44
42
45
89
77
79
99
66
64
88
66
69
130
83
92
198
99
90
72
74
78
91
74
82
97
74
82
124
114
118
151
102
101
124
101
102
116
79
86
125
83
89
92
121
99
93
114
101
90
78
86
83
64
66
86
80
85
alpha BHC beta BHC
3.14
16.90
0.39
4.63
0.75
ND
BDL
4.07
BDL
BDL
0.37
2.65
0.56
5.18
1.60
21.32
0.43
5.22
0.51
2.76
0.37
3.14
BDL
2.77
BDL
ND
BDL
BDL
0.41
3.53
0.90
11.91
0.89
12.87
0.48
7.96
1.47
18.26
2.16
25.78
1.41
15.91
2.87
35.38
4.32
30.42
BDL
BDL
0.47
5.24
0.29
2.69
0.31
3.16
BDL
BDL
0.27
3.57
BDL
4.31
1.52
10.55
1.23
14.70
0.51
6.67
0.59
5.81
1.08
9.60
0.37
2.29
0.34
ND
3.18
26.57
1.72
16.41
14.19
102.58
10.10
59.45
BDL
3.12
BDL
ND
0.32
6.26
2.56
20.52
1.89
24.37
4.50
66.21
0.34
2.89
BDL
BDL
2.02
41.98
4.41
51.44
0.45
7.22
0.29
BDL
BDL
BDL
lindane
0.90
ND
BDL
ND
ND
ND
0.25
0.37
0.36
ND
ND
ND
ND
BDL
0.38
0.30
BDL
ND
0.31
0.54
0.56
0.54
0.61
BDL
ND
0.23
ND
BDL
0.32
BDL
ND
0.28
ND
ND
0.45
ND
1.18
0.39
0.32
0.31
0.42
0.44
BDL
BDL
1.25
1.38
2.01
0.58
0.49
1.52
2.72
0.47
0.40
BDL
delta BHC
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.74
BDL
0.75
0.60
BDL
0.64
1.02
BDL
BDL
BDL
BDL
2.14
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
aldrin
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
3.01
BDL
BDL
BDL
ND
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
dieldrin mma chlorda
14.50
28.16
5.43
1.48
7.81
2.86
0.78
0.95
2.21
0.32
3.31
0.44
10.78
9.76
36.26
60.49
3.87
3.54
5.05
2.50
1.97
1.79
2.36
2.96
1.25
0.74
6.31
4.91
6.98
4.10
15.10
4.91
67.94
5.29
8.51
7.64
35.32
27.13
28.50
51.26
9.96
10.70
156.34
69.94
75.96
14.07
4.13
3.68
5.13
0.77
3.09
0.68
4.39
0.63
ND
BDL
1.98
BDL
1.36
1.77
3.72
10.70
4.71
6.38
1.76
0.94
9.44
3.08
4.87
2.85
0.64
0.32
7.85
1.35
42.39
65.95
31.05
28.25
92.56
62.87
176.18
105.11
1.95
0.47
1.41
0.27
1.80
0.56
15.04
18.18
13.65
14.01
22.74
23.38
2.29
1.44
9.73
14.50
23.07
13.69
32.55
33.60
2.85
1.59
1.22
0.74
0.97
1.43
Concentrations in ng/g wet wgt)
Total
Sample ID
Chlordanes
pha chlorda (cis +trans)endosulfan eIndosulfan I o,p DDD
Detection Limits
0.28
F-2836
F-2837
F-2838
F-2840
F-2841
F-2842
F-2843
F2844
F-2845
F-2846
F-2847
F-2848
F2849
F2850
F-2851
F-2853
F-2854
F-2855
F-2856
F-2857
F-2858
F-2859
F-2860
F-2861
F-2862
F-2863
F-2864
F-2865
F-2866
F-2936
F-2937
F-2938
F-2939
F-2940
F-2945
F-2946
F-2947
F-2948
F-2949
F-2950
F-2951
F-2952
F-2953
F-2954
F-2955
F-2956
F-2957
F-2958
F-2959
F-2960
F-2961
F-2962
F-2963
F-2964
F-2965
F-2966
F-2967
22.78
33.63
37.53
40.16
90.73
36.07
10.03
11.86
84.49
54.70
19.27
2.98
1.12
BDL
BDL
10.43
2.88
17.32
16.75
3.93
6.76
52.59
30.76
25.27
29.57
8.12
1.92
4.53
7.09
23.91
90.09
21.63
141.36
50.20
66.42
64.46
1.26
2.95
0.61
6.69
27.96
4.71
1.01
3.23
9.06
10.42
BDL
10.18
27.69
2.15
6.24
2.27
5.49
8.22
46.92
10.90
42.98
29.08
42.43
48.25
50.09
112.11
44.73
13.30
19.00
127.42
85.42
28.07
4.18
1.71
0.00
0.00
13.19
3.22
20.57
21.13
5.07
8.34
68.66
41.70
34.99
39.97
11.34
2.58
5.54
9.07
35.17
163.94
30.84
226.18
77.91
109.56
113.78
2.01
4.08
0.91
9.28
38.91
6.83
2.10
5.46
11.70
14.69
0.55
16.83
41.98
2.78
9.06
3.20
7.10
11.62
60.79
15.86
57.39
p,p DDD
o,p DDT*
p,p DDT
o,p DDE*
p,p DDE
endrin
0.19
0.23
0.16
0.49
0.27
0.60
0.28
1.11
0.23
tachlor epoxheptachlorans-nonachlcis-nonachlor* oxychlor
0.11
0.08
0.54
1.00
0.30
1.89
2.23
3.25
0.93
1.59
0.52
BDL
0.91
4.32
15.17
1.27
BDL
BDL
BDL
BDL
0.39
ND
0.65
3.52
0.48
1.61
11.37
6.22
4.91
0.57
1.30
0.40
0.59
0.58
1.51
18.78
0.61
12.51
3.05
1.37
1.17
BDL
0.40
BDL
BDL
0.54
BDL
BDL
0.66
0.39
0.45
0.20
0.25
0.35
BDL
0.31
1.07
BDL
BDL
BDL
0.49
0.54
1.19
1.25
1.80
13.22
36.08
11.22
4.58
0.52
3.08
1.59
0.69
0.99
0.75
0.62
BDL
0.95
0.67
1.59
0.90
0.45
0.78
3.94
2.57
1.14
9.61
0.43
BDL
BDL
0.41
4.39
ND
12.65
4.98
1.37
3.06
2.93
0.48
1.24
0.34
0.67
1.50
0.43
0.34
1.00
3.01
4.02
0.39
1.01
2.64
1.34
4.14
1.13
4.66
5.88
17.55
3.99
57.91
43.58
29.05
32.79
ND
3.55
1.70
0.73
1.58
10.53
19.31
3.02
0.31
0.16
BDL
BDL
2.69
2.20
2.58
0.85
1.54
2.92
146.03
67.62
84.54
3.47
10.17
1.64
3.92
9.66
2.29
39.93
5.48
130.68
27.16
20.09
19.38
0.48
0.38
BDL
1.82
4.39
1.25
0.21
0.87
1.96
2.26
0.22
1.14
1.36
0.19
1.15
2.09
0.56
0.56
10.47
2.23
1.87
124.37
78.34
106.21
42.09
80.78
32.35
10.90
15.14
57.33
68.13
16.23
4.57
4.49
0.54
BDL
12.59
0.78
29.38
16.03
5.44
15.33
511.12
279.71
245.79
109.68
27.96
4.67
7.40
27.31
37.88
305.85
71.31
853.45
220.16
234.24
320.32
2.70
12.27
3.48
12.10
33.48
9.51
2.67
7.54
116.97
98.33
1.54
14.49
21.76
4.59
17.64
3.29
14.54
21.70
109.22
31.82
29.47
25.49
39.86
40.52
55.69
110.89
79.70
23.95
18.02
100.50
36.55
14.37
11.10
5.49
2.25
1.31
16.78
18.01
45.19
22.20
6.50
11.32
47.12
40.73
21.32
77.46
12.51
4.30
10.62
14.30
17.12
94.29
50.89
113.30
54.82
62.70
110.31
1.93
11.94
5.40
14.57
22.62
9.59
1.10
4.67
23.47
23.51
0.44
9.89
10.77
11.63
24.73
7.69
17.20
29.78
86.53
24.79
253.07
14.03
12.20
13.34
4.41
8.25
7.01
2.18
0.84
3.18
BDL
BDL
1.36
BDL
BDL
BDL
5.66
2.35
18.91
8.63
2.85
2.12
15.02
11.52
12.29
9.79
1.64
1.09
1.87
1.82
2.60
1.30
2.01
3.06
2.18
2.72
1.65
BDL
BDL
BDL
1.28
1.21
BDL
BDL
1.88
3.36
1.44
BDL
0.67
7.60
0.88
1.06
5.25
1.37
1.14
4.77
1.43
7.68
9.21
14.79
22.36
8.18
43.00
3.05
3.44
4.71
18.80
52.59
6.64
0.57
0.32
0.31
BDL
4.06
4.18
9.35
2.43
2.21
3.19
116.53
15.88
39.37
8.18
5.45
1.10
1.77
5.33
3.22
52.14
7.18
11.15
11.29
4.50
24.42
1.30
1.92
5.08
1.23
2.75
4.08
2.98
5.38
3.91
3.77
1.51
0.92
1.59
0.41
2.06
1.96
0.95
3.17
2.89
3.22
5.08
147.39
15.09
6.30
137.24
245.16
126.36
89.06
33.97
9.14
500.71
52.08
29.41
10.54
1.23
1.80
108.00
3.62
133.22
161.88
39.71
126.78
64.79
216.85
26.28
3.86
45.19
11.95
42.69
62.46
48.77
566.04
284.41
410.40
446.35
702.28
1149.29
25.32
64.98
534.89
116.72
176.02
345.69
50.72
93.09
578.06
272.90
27.49
44.48
107.45
22.07
71.91
28.44
49.85
112.98
282.54
61.03
100.84
BDL
0.28
0.72
ND
0.81
1.14
BDL
0.33
1.29
0.28
BDL
0.26
BDL
BDL
BDL
0.41
1.31
3.06
BDL
0.28
0.27
1.39
2.19
0.59
0.24
0.35
ND
0.25
BDL
BDL
ND
0.34
0.44
0.38
BDL
0.69
ND
0.59
0.37
BDL
0.65
0.26
BDL
1.78
BDL
BDL
ND
BDL
1.15
BDL
BDL
2.48
BDL
BDL
0.34
0.46
1.49
1.94
2.78
3.60
6.58
21.41
9.33
3.13
2.07
6.45
7.46
2.18
0.46
0.18
0.94
2.84
0.93
BDL
1.34
1.79
0.44
1.32
5.15
3.61
2.93
9.85
1.39
0.46
0.63
0.49
10.97
17.01
7.63
15.20
5.37
7.36
6.75
0.55
1.28
0.66
1.07
4.34
0.99
0.49
2.03
2.04
3.96
1.28
1.80
3.90
0.80
2.86
0.76
2.26
2.78
9.48
2.92
34.64
1.81
2.42
3.30
1.15
2.87
0.84
0.51
0.88
2.71
4.01
0.39
ND
0.77
0.64
0.43
0.75
0.36
0.78
0.69
0.46
0.76
9.47
4.11
4.19
0.85
1.83
0.74
0.77
1.20
0.73
5.80
0.51
1.42
2.17
1.31
2.18
0.48
0.51
0.62
3.31
0.34
2.95
0.32
0.41
0.19
0.21
0.15
0.23
0.50
0.30
0.41
ND
0.16
0.65
0.51
0.17
1.43
28.53
20.20
10.77
63.51
174.89
99.13
34.64
14.51
16.87
48.28
12.26
6.10
4.28
2.47
0.96
18.57
13.24
27.54
26.46
7.93
10.20
45.05
21.65
16.57
17.43
7.33
2.85
5.49
10.07
17.20
82.05
31.49
28.22
23.97
32.73
81.73
4.10
11.58
66.46
10.98
17.48
33.36
9.06
11.83
30.45
25.58
3.57
3.85
9.82
4.95
12.58
5.33
12.10
17.63
48.46
19.02
222.55
16.33
2.32
1.54
16.56
21.22
10.10
4.75
3.25
2.04
17.94
2.85
3.13
1.92
BDL
BDL
13.62
1.16
11.60
11.32
7.90
7.40
51.98
19.79
15.27
1.66
5.55
2.16
2.93
6.95
6.57
56.27
12.22
5.67
5.62
6.69
31.52
4.68
2.21
68.92
1.47
1.44
4.59
10.94
14.37
26.17
22.28
5.98
BDL
1.49
3.24
6.03
6.53
4.65
9.79
18.81
15.32
7.51
11.45
41.27
36.44
47.08
114.13
193.10
31.50
18.13
107.67
20.97
6.07
15.45
15.70
7.11
12.12
6.95
2.60
32.75
9.10
3.51
5.29
44.89
71.56
14.72
80.50
8.80
3.65
6.08
12.95
24.02
71.29
89.85
77.57
26.36
46.46
64.30
2.83
18.35
4.79
12.17
24.01
3.32
1.26
4.61
22.55
36.02
4.76
5.29
96.20
16.99
43.68
18.25
21.48
40.67
82.40
31.28
NQ
Concentrations in ng/g wet wgt)
Total
Sample ID
F-2968
F-2969
F-2970
F-2971
F-2972
F-2973
F-2974
F-2975
F-2976
F-2977
F-2978
F-2979
F-2980
F-2981
F-2982
F-2983
F-2984
F-2985
F-2986
F-2987
F-2988
F-2989
F-2990
F-2991
F-2992
F-2993
F-2994
F-2995
F-2996
F-2998
F-2999
F-3000
F-3001
F-3002
F-3003
F-3004
F-3005
F-3006
F-3007
F-3008
F-3009
F-3010
F-3011
F-3012
F-3013
F-3014
F-3015
F-3016
F-3017
F-3018
F-3019
F-3020
F-3021
F-3022
F-3025
F-3026
F-3027
F-3028
F-3029
F-3030
Chlordanes
pha chlorda (cis +trans)endosulfan eIndosulfan I o,p DDD
16.93
25.11
0.21
6.33
1.99
7.61
10.36
BDL
2.66
1.03
18.62
24.49
2.90
4.26
3.51
22.52
31.07
2.05
6.03
11.23
27.21
34.23
1.25
6.35
7.09
53.03
71.54
3.18
18.76
13.45
19.96
26.61
1.83
9.10
6.27
3.08
4.07
1.35
0.30
2.65
6.01
7.41
1.59
0.33
7.74
4.87
6.26
0.29
0.33
1.60
45.71
63.29
7.87
4.50
16.36
1.23
1.82
0.57
BDL
1.15
5.47
6.86
0.53
0.61
3.75
8.72
11.08
2.01
0.51
11.68
24.12
30.77
14.33
2.67
31.65
3.04
4.10
1.83
0.33
4.49
2.29
2.77
0.27
BDL
4.46
15.44
20.48
5.58
1.00
24.33
20.62
27.37
11.03
0.92
28.53
10.12
12.47
3.47
0.86
16.84
7.04
8.78
1.54
0.34
12.29
5.45
7.51
2.47
0.24
10.91
4.62
5.50
0.97
0.41
3.00
6.87
8.54
2.16
0.46
5.38
3.08
3.75
0.68
BDL
1.45
5.10
6.37
BDL
0.36
20.98
8.76
10.81
1.49
0.91
7.60
6.39
8.17
0.81
0.59
5.38
5.82
7.63
1.15
0.57
4.25
9.08
12.72
0.88
3.64
1.44
5.59
8.11
0.22
7.59
0.27
2.51
3.69
BDL
3.58
0.19
10.85
13.74
1.09
10.38
4.72
1.82
2.27
BDL
1.28
0.28
2.68
3.31
0.54
0.43
1.75
11.50
15.17
3.33
1.37
16.47
4.76
6.28
0.89
3.01
5.42
23.42
29.32
3.98
1.97
44.90
1.14
1.14
BDL
BDL
3.73
10.64
14.29
2.39
1.45
21.14
6.11
7.26
BDL
0.68
0.70
5.38
6.50
BDL
3.90
22.10
4.02
5.23
0.23
0.48
0.96
6.66
8.06
0.77
0.73
2.18
4.42
5.16
0.20
0.63
0.73
8.24
9.98
0.29
0.79
1.19
5.34
6.58
0.55
0.75
1.26
0.87
1.38
BDL
0.69
0.69
4.62
6.12
0.48
1.33
1.78
43.36
60.87
3.62
11.62
10.34
24.14
32.55
4.05
6.08
3.41
16.40
25.97
0.80
1.28
0.48
14.91
22.71
0.99
1.33
0.21
17.65
26.61
0.44
1.56
1.68
2.03
2.43
BDL
0.30
1.41
25.23
33.47
2.28
1.38
21.96
39.28
51.93
3.04
1.76
32.62
45.21
61.68
1.06
15.92
7.55
15.81
26.45
1.13
1.08
5.10
20.66
27.49
0.59
6.97
5.57
p,p DDD
33.52
7.90
50.40
292.49
166.76
541.02
217.51
7.42
25.60
1.59
56.12
6.17
5.56
29.36
166.93
16.63
8.83
86.04
110.21
77.14
35.69
30.37
12.00
15.25
8.57
20.38
30.90
15.07
18.15
17.65
18.30
9.46
146.95
18.77
6.66
38.97
27.52
207.57
2.55
76.37
6.68
8.36
5.95
13.78
6.59
9.03
10.73
15.96
21.77
177.02
30.48
3.73
3.61
44.53
1.57
66.58
108.01
286.45
33.17
249.64
o,p DDT*
41.00
12.23
34.12
58.37
55.40
112.77
62.55
7.71
13.52
4.00
44.83
2.94
8.70
16.42
67.06
7.19
4.26
20.12
20.92
19.36
11.03
6.62
9.21
10.64
7.52
14.28
14.57
15.75
17.52
19.02
26.19
14.87
26.84
5.69
5.76
18.20
19.61
37.85
2.96
24.93
17.89
16.56
10.69
13.22
9.70
16.23
10.85
3.44
7.03
57.54
29.97
11.15
12.16
50.49
6.81
26.16
41.43
119.74
18.68
52.36
p,p DDT
3.22
0.91
16.03
11.76
9.41
7.44
9.77
3.05
5.24
BDL
3.55
0.88
1.61
3.63
43.38
0.87
1.14
4.12
4.56
4.58
4.82
1.38
2.92
2.62
3.75
4.19
2.35
4.43
3.99
4.95
2.62
1.75
8.97
3.54
1.37
3.95
2.78
6.29
1.39
3.71
8.97
12.32
4.71
4.45
2.13
5.83
3.43
2.86
1.79
8.65
35.44
BDL
BDL
3.47
1.44
6.11
11.73
43.70
3.07
10.23
o,p DDE*
1.03
ND
1.52
2.83
4.03
24.74
3.43
1.47
9.53
2.31
11.69
2.04
2.60
8.75
26.59
4.80
3.25
20.81
28.74
14.58
11.18
10.14
2.29
3.52
6.10
ND
4.45
8.23
5.60
1.46
2.50
1.07
5.99
BDL
1.98
6.26
3.32
35.39
0.37
13.21
4.83
ND
2.67
2.86
1.34
3.01
2.11
0.55
1.33
12.18
2.45
0.91
1.72
4.62
5.75
17.20
10.99
16.85
8.98
5.91
p,p DDE
133.12
ND
218.65
1086.63
681.95
1872.94
ND
ND
ND
43.39
294.18
ND
42.94
179.83
778.43
99.95
30.71
385.54
394.21
350.24
242.13
154.07
66.07
63.58
68.81
1.52
77.72
3.58
2.63
78.51
99.05
60.31
361.50
140.55
32.12
105.93
101.91
612.71
8.84
223.02
3.11
BDL
1.69
107.10
53.04
105.08
94.78
122.44
209.93
1456.14
195.12
8.75
8.81
239.33
8.25
4.39
3.76
6.20
3.07
839.83
endrin
BDL
BDL
1.08
BDL
0.26
1.21
BDL
BDL
ND
BDL
0.86
BDL
0.69
0.41
0.51
0.30
BDL
BDL
BDL
BDL
ND
BDL
0.26
BDL
BDL
2.12
0.28
1.27
0.78
BDL
0.48
BDL
0.78
BDL
0.40
0.68
2.13
BDL
BDL
0.37
ND
1.76
ND
0.43
0.51
0.39
BDL
BDL
BDL
0.69
1.64
ND
BDL
BDL
ND
0.75
0.54
1.61
BDL
0.47
tachlor epoxheptachlorans-nonachlcis-nonachlor* oxychlor
4.97
0.25
24.65
8.95
33.83
1.63
ND
ND
ND
30.94
3.03
0.30
25.51
10.00
34.14
5.03
0.36
36.82
29.23
132.47
3.90
1.13
34.71
33.73
41.32
13.56
1.78
127.34
165.94
89.42
5.03
1.27
31.00
23.73
107.36
0.80
1.04
3.64
3.59
5.25
0.51
1.29
6.92
8.27
4.29
0.46
BDL
4.81
4.60
4.38
17.38
1.99
33.01
8.69
68.72
0.59
0.45
3.57
5.28
2.48
1.03
0.48
9.08
5.89
6.35
0.96
1.60
13.63
11.17
7.59
1.76
1.43
63.56
112.65
18.72
0.64
0.57
6.83
6.81
4.23
0.40
0.81
7.53
8.71
1.92
1.50
2.80
20.47
10.25
7.83
2.55
4.60
19.91
10.33
3.45
0.89
1.79
16.85
9.55
5.35
0.45
1.68
7.86
5.12
2.63
1.01
1.99
5.80
3.38
1.96
1.07
0.69
9.00
5.24
3.92
1.15
0.95
9.13
6.00
4.29
0.47
0.49
5.43
10.09
2.73
0.39
0.61
7.05
BDL
8.46
1.12
0.87
8.72
5.50
7.95
0.69
1.07
9.91
1.11
9.66
0.88
0.75
9.17
1.00
7.74
3.11
0.16
15.16
5.41
18.90
3.72
0.30
22.72
8.15
58.62
2.32
0.22
13.11
6.24
18.50
5.25
0.41
39.02
22.71
42.06
0.44
BDL
7.58
5.56
3.95
0.31
0.11
5.76
7.36
7.30
1.53
0.67
11.69
8.93
6.87
0.92
0.22
16.23
11.51
4.90
1.78
3.35
33.53
20.74
9.08
BDL
0.50
1.67
1.27
1.35
1.32
1.63
23.00
18.63
8.73
0.55
0.57
12.99
1.55
11.13
0.24
0.82
10.08
BDL
12.82
0.36
0.51
6.15
BDL
45.86
0.83
0.45
12.21
7.64
4.89
0.40
0.08
9.70
5.05
3.88
0.67
ND
18.01
12.02
5.44
0.88
BDL
8.75
6.50
3.72
0.41
0.52
3.46
3.26
4.85
1.13
0.74
7.46
5.88
4.72
8.90
2.30
65.61
36.09
32.79
6.63
0.78
35.02
15.60
31.71
2.36
1.12
7.73
BDL
15.26
1.99
1.14
10.75
BDL
11.32
2.89
1.37
37.85
5.97
8.82
0.12
1.06
36.51
4.86
3.36
2.89
1.70
8.65
BDL
55.89
4.55
1.98
7.32
BDL
44.12
12.89
1.41
28.39
2.95
NQ
1.71
0.91
5.46
BDL
15.80
3.67
0.85
37.17
30.54
52.34
Concentrations in ng/g wet wgt)
Total
Sample ID
F-3031
F-3032
F-3033
F-3034
F3035
F-3036
F-3037
F-3038
F-3039
F-3040
F-3041
F-3042
F-3043
F-3044
F-3045
F-3046
F-3047
F-3048
F-3049
F-3050
F-3051
F-3052
F-3053
F-3054
F-3055
F-3058
F-3059
F-3060
F-3061
F-3062
F-3063
F-3064
F-3065
F-3066
F-3067
F-3068
F-3069
F3070
F-3071
F-3072
F-3073
F-3074
F-3075
F-3076
F-3077
F-3078
F-3079
F-3080
F-3081
F-3082
F-3083
F-3084
F-3085
F-3086
F-3087
F-3088
F-3089
F-3090
F-3091
F-3092
Chlordanes
pha chlorda (cis +trans)endosulfan eIndosulfan I o,p DDD
4.88
6.21
0.22
1.57
0.81
84.45
132.44
1.74
12.44
89.58
4.76
6.41
0.87
0.29
4.14
64.81
84.01
1.53
19.16
9.62
81.64
124.77
ND
13.87
8.10
5.40
7.80
1.48
0.84
1.42
3.62
4.85
3.24
0.30
1.41
11.41
15.11
2.63
1.31
3.44
2.06
3.22
1.24
0.72
0.69
25.94
46.27
9.99
2.12
7.28
0.65
0.99
ND
BDL
ND
2.69
3.25
0.21
1.27
ND
10.64
14.79
BDL
0.83
ND
24.44
37.21
ND
1.24
1.38
4.69
7.09
0.55
0.33
0.27
78.42
137.25
1.13
2.50
12.99
34.44
54.46
0.78
0.97
4.71
28.15
43.84
0.31
1.49
5.24
90.32
160.65
1.11
3.25
17.42
78.88
131.14
0.76
2.49
13.01
3.28
3.75
0.31
0.60
0.22
8.83
10.90
0.93
1.97
1.58
7.69
11.37
0.82
1.86
0.83
1.57
1.94
BDL
0.25
0.64
1.87
2.38
BDL
0.37
BDL
15.15
17.96
0.33
1.53
1.54
24.04
29.11
1.13
3.51
42.40
8.24
10.05
1.13
1.01
1.38
5.61
9.95
0.99
0.66
3.90
11.37
17.69
1.48
0.61
14.95
5.07
8.14
0.59
0.41
2.66
8.09
13.16
0.79
0.34
5.13
1.74
2.73
0.29
0.45
0.25
10.56
15.73
0.93
1.65
2.36
3.02
4.03
BDL
0.61
0.41
15.81
18.67
0.36
1.18
26.81
2.33
3.32
0.84
0.92
0.66
8.21
9.80
1.05
0.83
1.66
7.74
8.82
0.34
2.10
1.98
5.02
7.73
2.04
0.72
2.37
2.83
4.26
0.81
0.95
BDL
6.65
8.78
0.94
0.60
3.90
2.11
2.11
0.45
0.33
0.57
2.64
3.59
0.23
0.42
3.72
0.82
1.12
0.20
BDL
0.53
1.19
1.70
0.25
0.31
0.74
1.89
2.35
0.88
0.95
1.05
1.84
2.23
BDL
0.35
1.00
1.62
1.93
BDL
0.26
0.70
3.78
4.67
0.27
0.85
1.12
9.46
13.42
2.39
2.59
ND
3.30
3.86
0.26
1.41
167.01
6.86
7.42
0.44
1.34
1.47
11.92
14.82
0.36
2.87
11.01
27.68
35.44
2.82
13.77
5.34
6.99
8.71
0.19
2.19
1.07
2.96
3.40
BDL
0.61
4.59
1.41
1.90
BDL
0.74
0.55
0.92
1.22
BDL
0.47
0.41
0.45
0.75
BDL
BDL
ND
p,p DDD
47.64
1308.12
12.21
282.25
187.39
4.85
3.29
10.19
4.09
40.42
0.70
4.64
5.82
11.31
2.31
67.23
28.36
23.78
210.48
103.32
6.44
25.85
27.25
1.49
3.64
21.45
49.85
16.33
41.98
80.30
33.14
39.96
4.14
41.32
6.99
24.99
8.60
10.67
7.82
20.66
6.74
12.21
4.68
3.45
2.42
3.25
7.17
6.68
4.72
14.67
18.38
41.49
75.14
169.23
89.02
80.95
24.15
15.91
7.70
1.54
o,p DDT*
12.21
129.82
12.09
167.32
102.76
6.04
4.72
14.86
3.86
27.82
1.13
4.34
4.68
10.77
2.89
44.45
19.52
16.86
80.02
62.00
6.35
26.89
19.66
2.08
5.91
29.11
54.42
20.59
6.71
10.09
6.62
7.40
4.73
22.10
6.22
37.76
10.91
14.80
15.43
8.95
6.87
12.27
5.72
8.89
2.96
5.41
7.32
7.58
5.87
10.33
9.83
13.09
15.86
20.69
60.88
15.33
3.05
5.78
2.07
1.01
p,p DDT
1.47
104.37
2.70
30.54
22.83
1.14
0.87
1.48
BDL
0.64
ND
BDL
1.21
BDL
BDL
0.86
BDL
1.15
0.84
BDL
1.81
5.86
1.68
1.71
1.47
16.44
12.46
5.51
0.88
4.67
1.71
1.78
0.66
3.31
1.01
17.49
1.11
9.86
7.03
1.07
2.34
1.01
0.98
2.66
BDL
BDL
BDL
1.38
0.91
6.87
15.80
5.34
6.99
5.81
10.05
4.59
1.88
1.12
1.09
0.65
o,p DDE*
1.66
44.97
5.37
16.94
7.31
1.59
BDL
1.43
2.65
24.13
BDL
0.95
BDL
1.06
BDL
11.07
2.15
2.93
72.66
45.39
3.33
7.43
9.49
1.49
1.42
5.28
1.49
5.18
7.15
6.35
4.65
6.43
2.06
11.37
3.59
0.69
6.68
1.58
2.53
6.55
4.33
3.50
1.74
0.39
0.96
1.39
7.66
2.83
1.19
BDL
BDL
1.62
0.90
1.68
1.51
1.01
ND
BDL
BDL
BDL
p,p DDE
407.55
15.03
2.63
7.71
9.12
9.73
7.84
21.60
11.20
175.22
2.62
8.77
7.92
19.34
6.78
88.27
78.68
43.70
670.64
265.55
44.35
241.69
156.40
25.26
49.10
264.50
ND
229.88
41.81
59.25
27.48
46.01
35.26
111.33
54.33
ND
177.61
134.90
65.17
100.59
70.09
82.75
23.60
ND
13.91
19.84
119.88
31.77
28.84
91.04
38.46
177.59
443.32
328.77
224.55
312.90
52.84
41.88
24.68
12.41
endrin
BDL
1.31
0.41
0.55
2.31
BDL
ND
BDL
0.63
BDL
ND
ND
ND
BDL
ND
0.24
ND
BDL
0.42
BDL
0.24
0.45
BDL
0.29
BDL
BDL
3.61
0.87
0.41
2.08
0.63
BDL
BDL
0.32
0.24
5.15
BDL
0.24
1.56
BDL
BDL
ND
0.46
0.92
1.48
0.93
BDL
1.31
0.70
0.39
0.31
ND
ND
0.91
ND
0.26
0.56
BDL
BDL
ND
tachlor epoxheptachlorans-nonachlcis-nonachlor* oxychlor
0.72
0.77
11.60
14.75
7.67
15.18
2.49
40.89
7.76
108.34
0.69
0.79
7.24
BDL
6.28
16.54
1.60
32.82
3.43
NQ
14.47
1.80
18.07
2.26
135.01
1.31
0.24
8.09
2.80
6.56
0.74
0.12
1.40
1.55
6.20
2.13
0.46
16.70
4.23
17.09
1.22
0.79
13.50
11.79
5.29
6.65
3.23
79.26
83.27
25.45
0.33
ND
1.33
BDL
0.83
1.29
0.08
7.29
2.62
8.41
1.61
0.11
0.60
BDL
8.14
1.60
0.59
9.87
1.24
17.84
0.58
ND
2.78
BDL
1.97
6.64
2.54
45.74
11.39
19.49
2.72
0.86
16.04
3.38
8.96
1.89
0.79
19.24
2.44
7.68
8.08
3.40
202.42
97.54
41.87
4.45
2.69
103.39
53.00
20.98
0.53
0.29
11.13
16.76
5.52
0.64
0.58
37.35
61.27
7.07
1.23
0.76
26.80
32.36
8.33
BDL
ND
6.58
7.20
2.00
0.12
0.08
8.86
8.14
2.72
0.99
0.34
41.52
24.09
16.51
1.47
0.88
9.19
19.89
19.65
1.05
0.35
25.38
ND
6.58
0.58
0.79
5.87
5.60
4.13
1.23
0.80
2.64
7.04
9.80
0.51
0.42
4.45
4.10
4.56
0.81
0.71
4.53
6.58
8.71
0.64
0.38
6.82
9.12
1.66
0.92
1.38
26.44
40.50
22.98
0.43
0.14
13.58
25.45
2.91
1.03
1.30
8.01
14.33
19.19
1.04
0.55
32.59
64.50
3.16
1.14
0.20
11.56
9.96
8.29
0.82
0.15
13.63
13.89
7.22
0.67
0.54
13.17
20.88
5.13
0.29
0.31
13.68
15.56
2.68
0.44
0.45
9.96
13.18
5.19
0.20
0.15
6.13
8.13
2.37
0.50
1.35
1.82
3.13
3.96
0.82
0.09
3.28
5.52
1.81
0.89
0.23
5.47
6.75
2.18
0.56
1.15
22.49
37.83
4.33
0.85
0.64
10.47
14.53
2.12
0.26
0.14
7.02
7.47
35.37
0.37
ND
6.06
ND
4.45
3.67
0.13
3.62
3.36
1.42
0.39
0.13
19.54
175.82
7.20
0.36
0.09
15.56
25.72
5.30
1.85
ND
6.31
ND
10.54
9.37
0.31
12.23
18.06
NQ
1.22
0.11
6.07
22.62
11.83
4.27
ND
0.62
2.74
7.87
1.18
ND
1.56
2.53
9.00
0.28
ND
BDL
ND
2.40
0.42
ND
1.97
1.89
1.07
Concentrations in ng/g wet wgt)
Total
Sample ID
F-3093
F-3094
F-3095
F-3096
F-3097
F-3098
F-3099
F-3100
F-3101
F-3102
F-3103
F-3104
F-3105
F-3106
F-3107
F-3108
F-3109
F-3110
F-3111
F-3112
F-3113
F-3114
F-3115
F-3116
F-3117
F-3118
F-3119
F-3120
F-3121
F-3122
F-3123
F-3124
F-3125
F-3126
F-3127
F-3128
F-3129
F-3130
F-3131
F-3132
F-3133
F-3134
F-3135
F-3165
F-3166
F-3167
F-3168
F-3169
F-3170
F-3171
F-3172
F-3173
F-3174
F-3175
F-3176
F-3177
F-3178
F-3179
F-3180
Chlordanes
pha chlorda (cis +trans)endosulfan eIndosulfan I o,p DDD
1.31
3.07
ND
0.27
0.82
4.93
6.77
0.39
1.25
1.90
1.56
2.04
BDL
0.70
0.94
1.62
2.48
BDL
0.99
0.18
7.03
8.62
2.81
1.85
5.50
1.30
1.30
1.95
0.80
1.36
1.87
2.62
0.29
0.84
0.85
1.10
2.13
0.34
1.84
0.33
BDL
0.00
BDL
0.33
BDL
BDL
0.00
BDL
BDL
BDL
5.01
6.32
2.04
1.03
4.15
p,p DDD
3.96
22.83
17.59
9.52
30.93
5.90
6.58
8.42
BDL
BDL
26.37
o,p DDT*
3.29
7.61
5.63
6.53
28.53
7.05
6.09
7.02
0.97
1.09
15.44
p,p DDT
BDL
1.50
1.12
1.27
2.30
BDL
0.65
0.81
ND
BDL
2.91
o,p DDE*
BDL
0.31
BDL
0.72
11.14
11.25
8.91
1.85
BDL
BDL
7.60
p,p DDE
7.74
72.11
56.70
45.68
17.65
151.54
95.57
55.59
37.60
BDL
125.83
endrin
ND
BDL
ND
BDL
3.03
BDL
0.55
BDL
ND
BDL
BDL
tachlor epoxheptachlorans-nonachlcis-nonachlor* oxychlor
0.83
ND
1.16
1.22
2.54
2.68
BDL
3.30
ND
9.12
0.78
ND
2.94
3.26
6.35
0.98
ND
7.07
7.51
7.13
1.22
1.66
32.95
43.90
17.23
0.74
1.26
31.82
67.03
12.86
0.86
0.41
24.92
34.06
3.50
1.20
0.17
24.45
25.70
4.11
0.80
ND
2.19
3.82
2.37
1.66
0.15
0.65
BDL
4.12
1.20
1.46
21.90
29.35
6.37
1.67
8.06
1.23
0.82
2.79
5.33
6.91
2.19
1.27
3.32
4.60
7.70
BDL
3.49
1.41
5.03
1.42
6.93
1.12
17.98
3.74
2.25
12.21
1.69
1.27
3.71
6.74
8.65
2.94
1.92
3.76
5.48
9.72
0.29
4.31
1.76
5.89
1.71
9.36
1.59
21.97
4.36
0.60
0.53
0.25
BDL
0.97
0.71
0.23
BDL
BDL
BDL
0.32
0.36
0.19
0.82
2.35
7.74
2.37
0.66
BDL
3.73
BDL
BDL
2.19
0.49
0.31
0.59
1.00
0.50
0.85
0.27
0.29
0.83
3.75
0.29
3.71
0.47
1.19
0.41
1.36
0.75
0.93
0.32
1.89
0.99
0.22
0.32
0.92
0.71
1.33
0.37
0.51
1.01
2.90
12.25
0.18
0.55
0.48
0.96
1.24
2.48
2.86
23.18
3.91
4.69
59.73
4.99
2.95
8.73
10.59
6.48
11.04
3.49
6.99
19.01
181.31
3.77
109.36
2.33
3.95
1.37
25.77
104.61
154.76
20.58
6.20
15.14
2.95
1.32
7.82
16.82
10.21
6.15
1.54
8.85
13.34
25.94
0.90
14.96
3.81
8.03
3.79
11.34
6.67
33.16
16.37
0.87
2.06
0.95
BDL
1.67
1.94
1.24
1.15
0.92
2.76
3.48
164.48
BDL
1.38
0.71
1.93
BDL
33.38
17.97
6.96
2.59
2.28
1.61
BDL
BDL
8.76
5.31
3.04
0.31
BDL
1.15
2.75
6.79
0.87
1.86
BDL
0.33
BDL
1.54
1.04
23.25
5.12
37.36
133.73
16.01
15.54
163.83
135.49
40.53
35.95
19.45
29.77
83.22
384.84
26.19
197.18
4.54
10.03
9.29
98.00
110.49
356.30
105.94
BDL
BDL
ND
BDL
BDL
BDL
0.33
BDL
BDL
0.52
0.69
0.67
BDL
BDL
0.61
BDL
ND
1.19
BDL
BDL
BDL
0.67
2.11
0.28
0.49
1.23
0.57
0.17
0.92
0.49
0.50
0.84
2.60
0.51
2.11
0.70
1.76
0.34
1.63
0.42
0.94
0.13
0.21
0.12
ND
ND
0.88
0.33
0.15
ND
ND
0.26
0.14
0.17
0.09
0.23
0.09
0.14
ND
ND
0.11
2.55
0.78
6.77
15.10
2.07
1.26
30.06
31.90
9.71
3.81
1.32
7.79
14.46
32.28
3.13
18.94
3.72
8.19
1.39
12.31
9.33
25.28
12.99
8.78
15.33
2.53
1.47
60.88
33.49
11.06
4.20
1.71
5.48
17.90
104.61
3.74
13.33
1.15
1.38
1.41
23.15
205.87
18.96
15.04
1.70
15.44
NQ
2.53
2.99
5.29
2.97
4.14
2.60
3.59
6.54
24.08
0.73
12.01
7.74
11.79
4.65
8.06
4.02
7.90
5.33
5.37
19.27
ND
2.82
3.66
42.46
8.11
BDL
0.68
63.72
2.44
7.06
0.93
2.48
10.17
9.66
3.93
68.37
151.53
4.36
10.96
14.01
43.15
117.10
15.21
8.26
6.44
23.44
0.00
4.10
4.88
62.07
11.43
0.00
0.68
102.24
3.62
9.10
1.45
3.89
17.67
14.46
6.22
126.94
262.92
6.11
16.38
24.46
90.71
199.55
28.34
17.39
0.78
1.47
ND
0.36
BDL
0.47
0.38
BDL
BDL
0.70
3.70
4.26
0.57
0.75
13.44
3.13
1.01
43.70
16.48
1.68
7.57
16.54
19.65
22.42
3.42
0.44
0.55
2.48
ND
0.64
2.04
9.11
4.17
BDL
0.35
13.79
1.45
3.05
0.77
1.31
1.94
1.51
1.07
4.64
1.62
0.49
2.12
1.76
3.66
6.00
0.95
0.70
2.99
15.91
ND
2.09
0.56
2.16
0.81
BDL
0.64
4.81
1.52
5.13
1.36
1.78
3.48
3.93
1.79
52.83
194.93
4.58
12.27
28.72
72.14
148.36
17.44
5.77
11.91
55.66
ND
10.77
10.25
68.65
20.07
BDL
7.58
120.51
16.42
34.85
5.80
6.38
29.26
31.01
14.09
303.76
1417.85
16.61
99.04
195.87
361.18
983.16
141.30
43.48
11.20
35.78
BDL
5.68
9.86
39.93
18.36
0.35
3.66
57.12
8.62
15.72
3.58
3.13
10.07
9.19
3.75
53.18
136.84
7.37
30.19
19.77
37.72
96.13
22.90
12.53
3.06
5.83
ND
2.01
1.34
4.94
1.50
0.84
3.52
8.10
2.81
3.13
1.91
1.67
0.64
2.01
1.10
2.23
1.65
1.56
3.89
5.12
4.38
7.06
0.73
BDL
2.91
14.38
BDL
1.60
BDL
2.14
0.29
BDL
BDL
1.04
2.03
3.04
0.37
0.87
4.16
3.11
1.70
43.00
143.19
1.29
10.88
14.72
55.58
58.69
24.55
8.79
65.59
204.06
BDL
41.31
26.11
90.91
50.05
BDL
BDL
110.68
105.60
92.20
ND
16.44
78.67
122.59
38.59
363.77
1919.23
40.39
275.06
163.31
522.17
723.07
567.37
90.46
0.48
0.50
ND
0.45
ND
BDL
ND
ND
ND
1.13
0.56
0.69
0.39
ND
ND
ND
BDL
0.55
BDL
0.35
0.49
BDL
0.51
0.70
0.26
ND
0.86
1.50
BDL
0.42
1.06
10.28
3.69
BDL
0.11
15.65
1.10
1.69
0.35
0.54
2.82
1.08
0.55
18.82
19.85
0.52
1.83
3.94
9.27
16.24
2.54
2.06
0.47
1.51
ND
BDL
0.08
0.59
0.16
0.42
ND
0.70
ND
0.35
0.11
ND
0.64
0.31
0.23
5.58
5.12
0.20
1.16
ND
9.35
6.60
1.93
0.94
11.17
38.12
BDL
4.91
10.29
37.92
11.90
ND
1.82
31.96
11.42
15.75
2.41
2.62
13.13
9.08
5.41
72.41
202.61
3.77
37.42
22.91
53.91
99.25
42.07
31.84
12.62
33.92
BDL
6.74
1.79
5.55
2.53
BDL
1.11
5.73
3.19
3.85
2.59
2.31
5.95
5.27
3.38
69.38
165.17
1.65
27.18
27.65
64.27
93.78
48.89
35.95
8.65
14.38
0.43
2.99
14.33
1.82
NQ
1.89
1.82
36.75
7.52
21.49
3.74
1.67
6.22
4.38
2.67
22.17
35.86
3.63
37.97
7.95
12.59
37.49
8.07
4.91
Concentrations in ng/g wet wgt)
Total
Sample ID
F-3181
F-3182
F-3183
F-3184
F-3185
F-3186
F-3187
F-3188
F-3189
F-3190
F-3191
F-3192
F-3193
F-3194
F-3195
F-3196
F-3197
F-3198
F-3199
F-3200
F-3201
F-3202
F-3203
F-3204
F-3205
F-3206
F-3207
F-3208
F-3209
F-3210
F-3211
F-3212
F-3213
F-3214
F-3215
F-3216
F-3217
F-3218
F-3219
F-3220
F-3221
F-3222
F-3223
F-3224
F-3225
F-3226
F-3227
F-3228
F-3229
F-3230
F-3231
F-3232
F-3233
F-3234
Chlordanes
pha chlorda (cis +trans)endosulfan eIndosulfan I o,p DDD
33.36
61.52
1.01
1.00
15.94
3.03
4.51
BDL
0.52
0.93
6.07
8.93
0.26
2.37
2.17
1.18
2.14
BDL
BDL
0.17
0.47
0.79
ND
1.09
0.21
1.45
1.89
0.54
1.11
0.69
10.27
20.02
0.81
1.38
3.18
74.76
135.24
1.53
2.48
18.31
3.75
7.29
0.39
0.87
2.45
4.90
7.40
0.55
1.40
1.90
2.08
3.87
0.40
0.90
0.67
4.68
7.63
0.61
1.16
0.97
1.02
1.76
0.29
0.51
1.12
9.57
14.48
0.50
1.10
0.59
6.22
10.32
0.32
1.37
1.01
15.98
20.90
1.21
2.15
4.61
23.57
28.87
0.61
2.89
13.04
9.87
17.51
0.59
ND
3.82
35.65
62.78
1.54
3.18
23.95
59.86
111.12
2.63
2.79
26.12
8.24
18.94
1.72
31.71
4.00
85.00
154.94
2.60
5.18
36.69
74.18
88.25
1.85
6.03
17.13
8.12
11.81
0.40
0.57
0.50
3.14
3.90
0.64
1.37
0.65
1.53
2.21
0.47
0.86
0.54
1.62
2.25
0.43
1.11
0.56
BDL
BDL
BDL
BDL
BDL
1.45
1.45
0.31
1.34
0.23
4.96
6.73
0.26
0.68
0.57
15.92
26.62
0.58
0.99
0.63
10.72
17.09
7.19
1.65
4.06
3.21
4.16
0.39
0.67
0.90
9.52
12.61
0.51
1.68
1.40
7.37
10.22
0.58
4.62
1.12
0.97
1.29
0.48
0.56
0.97
1.66
3.01
0.69
2.20
0.17
110.54
176.48
0.94
3.47
6.80
42.18
70.43
0.83
2.26
4.75
163.52
226.39
1.54
5.30
9.31
206.07
311.18
1.77
5.97
16.04
1.60
2.08
0.62
0.66
0.50
1.60
1.87
0.58
0.60
0.25
1.76
2.32
0.81
0.92
ND
23.33
41.52
9.33
1.81
9.52
21.95
35.96
4.32
2.29
5.71
41.48
64.86
12.01
2.46
8.19
1.47
2.91
1.10
0.83
BDL
24.42
38.93
3.68
3.28
1.07
17.37
31.06
17.93
2.00
6.40
41.72
75.32
25.60
3.35
13.55
3.61
5.20
3.31
0.67
1.52
1.61
2.35
2.48
BDL
0.88
2.39
3.83
0.57
0.25
0.21
p,p DDD
126.23
8.72
20.82
2.24
2.51
5.30
24.94
186.68
11.08
12.23
3.12
7.04
1.66
10.60
10.24
25.26
59.49
51.34
217.60
335.57
ND
442.52
167.23
6.76
4.40
2.95
4.90
BDL
1.22
1.20
3.16
7.17
1.02
5.53
5.76
1.92
5.34
39.97
30.21
67.25
112.26
2.28
2.09
2.54
36.15
26.88
38.28
3.78
14.02
24.80
54.47
4.43
1.81
1.14
o,p DDT*
53.19
5.86
1.93
1.05
2.80
5.95
18.61
56.80
5.26
10.06
2.10
5.27
1.68
7.60
4.55
22.19
74.09
23.76
40.86
104.12
ND
90.83
94.16
4.88
4.68
4.69
4.16
BDL
4.30
4.20
7.72
9.72
3.56
17.01
32.67
2.97
9.02
89.31
49.89
112.87
166.81
7.61
3.98
8.65
23.66
20.60
53.38
2.67
20.01
20.80
41.38
5.42
3.29
1.73
p,p DDT
0.77
BDL
2.51
ND
0.91
1.99
1.11
1.53
1.53
2.14
1.31
0.63
0.81
0.72
1.84
6.21
11.11
0.85
1.55
1.46
80.48
3.45
21.13
BDL
1.16
1.23
BDL
BDL
1.61
ND
1.58
2.02
2.65
2.39
5.25
7.38
0.71
3.22
1.22
1.99
2.89
1.94
BDL
0.82
1.63
1.96
ND
1.27
1.57
2.48
3.47
2.18
1.17
BDL
o,p DDE*
8.96
2.38
3.81
0.60
0.87
ND
9.24
9.41
1.76
1.30
0.55
0.92
BDL
1.50
0.64
1.62
0.50
9.99
28.64
30.47
8.47
49.64
8.15
0.87
0.60
BDL
0.77
BDL
BDL
0.55
1.16
0.72
0.66
1.29
1.70
0.53
2.12
5.91
8.91
13.11
10.19
ND
0.42
0.60
42.41
14.97
30.49
1.22
5.80
31.41
30.37
0.87
4.01
0.41
p,p DDE
226.13
25.21
55.12
4.82
9.01
9.02
187.54
112.89
13.64
17.11
4.05
9.52
4.05
32.52
12.26
67.79
ND
305.21
363.73
513.23
227.66
634.81
314.50
19.76
13.73
18.58
17.12
ND
4.56
6.78
6.10
13.12
15.87
19.59
74.45
8.15
15.68
156.83
152.05
751.18
320.85
7.26
5.19
8.08
107.43
92.56
229.34
4.28
28.02
16.03
176.21
9.27
3.94
1.90
endrin
1.14
ND
ND
ND
ND
BDL
ND
0.42
BDL
0.58
0.73
ND
BDL
ND
ND
0.62
BDL
ND
0.50
0.28
23.06
3.44
0.65
ND
BDL
BDL
0.35
BDL
ND
ND
0.27
0.87
0.48
BDL
2.72
1.00
0.25
0.48
0.29
BDL
0.46
BDL
0.27
ND
0.29
0.32
0.25
BDL
ND
BDL
0.43
BDL
BDL
BDL
tachlor epoxheptachlorans-nonachlcis-nonachlor* oxychlor
1.87
0.86
50.78
15.71
8.72
0.37
0.27
11.06
11.27
2.90
3.92
0.21
20.77
15.34
8.26
0.11
0.19
1.71
2.78
0.34
0.37
0.09
4.67
4.75
1.56
0.32
ND
3.46
4.65
7.07
1.06
0.65
29.59
29.40
4.72
4.83
1.77
47.23
12.98
18.57
0.44
0.23
4.81
4.81
3.98
0.48
BDL
7.09
4.52
5.29
0.23
ND
1.75
1.85
0.52
0.41
0.15
3.66
4.19
3.45
0.19
BDL
0.99
BDL
0.92
0.80
0.21
7.16
2.25
8.55
1.03
0.18
3.60
1.04
2.90
1.71
0.36
9.46
2.80
21.42
2.13
ND
62.18
48.69
37.04
1.04
0.85
33.99
53.92
6.28
4.66
1.91
41.58
44.83
22.76
3.64
3.19
90.13
85.38
22.78
1.57
0.75
22.02
35.82
NQ
14.96
3.39
148.02
177.64
26.14
6.47
1.30
56.75
14.34
54.36
0.70
0.15
4.05
1.45
6.69
0.76
BDL
3.17
1.25
7.28
0.36
BDL
2.94
BDL
4.30
0.59
BDL
2.92
2.39
4.88
ND
BDL
BDL
1.51
0.61
0.27
BDL
2.21
BDL
4.08
0.24
0.24
1.07
BDL
5.50
0.46
0.40
9.80
BDL
6.36
0.47
0.18
3.17
1.31
8.56
0.28
0.19
4.17
1.51
5.19
0.66
0.26
9.69
1.68
14.27
0.56
0.61
17.57
5.35
12.25
0.18
0.14
2.43
3.27
1.44
0.56
0.15
9.96
5.44
11.45
4.78
1.79
57.96
7.81
26.94
3.19
0.94
42.90
12.05
23.90
9.04
1.33
60.54
18.38
36.48
13.54
4.12
108.69
11.86
78.08
1.05
ND
9.14
1.64
11.65
0.53
0.08
6.49
1.22
14.17
0.68
0.12
16.03
2.24
13.37
6.15
1.53
65.35
97.64
14.92
5.05
2.14
57.27
47.70
12.73
8.33
2.91
140.73
87.82
46.52
0.71
BDL
4.19
2.41
3.34
3.38
0.47
34.10
8.82
32.29
7.29
3.71
89.85
107.61
11.39
10.83
3.37
86.84
65.79
29.63
0.96
0.09
4.81
2.68
4.26
0.48
ND
2.46
3.17
2.93
0.48
BDL
2.25
BDL
3.40
Total PCBs for individual specimens, as estimated by different methods of handling estimates of congener concentrations below the detection limit for eac
Total PCB
Location
Scientific Name
Common Name
"Hopkins Pond"
brown bullhead
Ameiurus nebulosus
Sex
Total
Length cm
Total Wet
Weight g
Sample ID
Lipid%
Mid
Min
Max
M
21
110.2
F-3021
0.71
51
49
54
U
F
M
M
M
F
68.7
69.2
71.5
75.4
80.8
88.2
3400
3400
3300
4700
5300
6500
F-3078
F-3077
F-3007
F-3079
F-3080
F-3081
0.80
0.86
2.55
1.47
3.80
290
158
90
825
335
201
288
155
86
825
333
198
291
161
93
825
337
204
M
M
M
F
M
M
F
M
66.2
66.22
68.2
76.8
82
82.6
83.6
84.9
2874.2
2700
2809.6
4100
4950
5500
6200
5800
F-3071
F-2853
F-3067
F-3068
F-2855
F-2854
F-2856
F-3058
13.67
10.39
5.50
13.19
17.27
25.82
22.30
14.27
401
663
393
667
784
521
541
1193
400
662
391
667
784
519
540
1193
402
664
395
670
785
524
542
1195
M
F
F
F
F
F
81.4
89.6
91.3
94.4
100.5
125.77
6300
7100
8200
7700
8800
22500
F-3124
F-3125
F-3126
F-3127
F-3129
F-2858
1.44
2.37
6.83
4.02
0.91
5.49
498
266
381
1092
183
477
497
264
380
1092
180
475
501
268
383
1094
188
478
M
F
M
M
F
45.1
63
86.1
87.5
88.7
907.1
2364.9
5800
5900
6800
F-3065
F-3066
F-3012
F-3059
F-3060
7.48
10.53
6.38
10.98
14.85
207
1038
419
1118
912
206
1038
417
1117
911
209
1039
421
1120
914
Atlantic Ocean, Asbury Park to Atlantic City
striped bass
Morone saxatilis
Pomatomus saltatrix
Cape May
Morone saxatilis
Pomatomus saltatrix
bluefish
striped bass
bluefish
Total PCB
Location
Scientific Name
Park
Morone saxatilis
Pomatomus saltatrix
Cohansey River
Anguilla rostrata
Evans Pond
Ameiurus nebulosus
Cyprinus carpio
Common Name
Sex
M
F
Total
Total Wet
Length cm Weight g Sample ID
88.7
6300 F-3069
90.9
6400 F-3015
Lipid%
13.69
5.07
Mid
Min
Max
900
359
899
356
902
363
striped bass
F
F
F
M
F
F
M
F
73
73.3
73.6
73.7
76.4
77.9
89.6
91.5
4150
3800
4450
3700
4450
4700
7500
7850
F-2991
F-2993
F-3004
F-2992
F-2995
F-3005
F-2996
F-3008
4.41
1.24
9.28
0.56
3.68
4.63
4.62
4.43
386
231
561
306
459
498
518
865
385
227
560
304
457
497
517
864
389
235
562
308
462
500
520
866
F
M
F
F
F
F
F
F
67.1
67.2
73.7
73.8
76.5
83.2
86.3
86.7
2400
2350
3500
2950
3400
4100
4500
4900
F-3009
F-3014
F-3051
F-3013
F-3054
F-3053
F-3055
F-3052
3.45
3.40
4.30
2.32
1.71
2.45
0.75
4.29
503
645
386
280
230
1034
285
1331
500
643
386
278
229
1033
282
1330
506
649
387
284
233
1035
290
1333
51.1
53.5
58
59.1
60.6
275.8
323
224.7
416.1
407.9
F-3094
F-3090
F-3091
F-3089
F-3095
15.86
6.89
0.96
13.12
3.96
106
71
51
98
88
105
69
49
97
86
115
82
62
107
98
M
F
M
26.1
26.4
28.4
232.7
264.3
279.6
F-3044
F-3043
F-3045
1.37
1.11
0.58
64
27
18
61
23
15
69
35
29
F
F
43.2
47
1170.1
1536.6
F-3046
F-3047
6.13
1.96
219
160
218
159
222
164
bluefish
American eel
brown bullhead
common carp
Total PCB
Location
Scientific Name
Lepomis macrochirus
Cooper River Lake
Ameiurus nebulosus
Cyprinus carpio
Lepomis macrochirus
Micropterus salmoides
May
Morone saxatilis
Pomatomus saltatrix
Common Name
Sex
F
F
M
Total
Total Wet
Length cm Weight g Sample ID
47.2
1526.5 F-3048
51.2
2271.3 F-3050
52.3
2175.4 F-3049
Lipid%
1.89
4.96
6.06
Mid
Min
Max
122
577
1052
119
576
1052
126
578
1053
bluegill
M
F
15.3
15.4
65.2
57.9
F-3042
F-3041
0.42
0.32
37
13
33
6
43
23
M
F
M
23.8
25.2
28.9
153.2
205.4
341.1
F-3204
F-3194
F-3195
1.03
1.44
1.50
48
60
28
44
57
24
54
66
36
U
U
U
F
U
48
49.1
52.5
56.4
56.5
1704.2
1662.5
2127.7
2448.1
2384.3
F-3202
F-3198
F-3199
F-3201
F-3200
7.84
2.13
7.26
4.46
4.55
1272
816
897
467
1320
1271
814
896
466
1320
1273
817
898
468
1321
F
U
M
15.6
15.9
16.2
92.5
100.7
95.9
F-3207
F-3205
F-3206
0.75
1.18
0.85
45
43
41
41
39
37
51
49
48
F
M
F
33.6
38.6
44.5
670.5
1074.3
1497.7
F-3196
F-3197
F-3203
0.12
1.05
2.48
125
2679
506
123
2678
505
130
2682
508
M
F
F
F
M
F
F
73.9
74
74.3
75.6
80.8
92.7
97.2
4800
4500
4600
4500
6100
8400
11000
F-3098
F-3006
F-2994
F-3099
F-3097
F-3113
F-3114
4.49
4.34
3.59
4.59
4.80
4.92
1267
1281
406
573
1028
200
448
1267
1280
405
572
1027
199
446
1268
1282
408
574
1029
203
451
F
48
889.7
F-3110
0.23
409
407
413
brown bullhead
common carp
bluegill
largemouth bass
striped bass
bluefish
Total PCB
Location
Scientific Name
Common Name
Sex
F
M
M
Total
Total Wet
Length cm Weight g Sample ID
53.5
1023.7 F-3025
76.7
3300 F-3109
87.1
5700 F-3108
Lipid%
0.33
3.85
10.16
Mid
1019
918
914
Min
1017
917
913
Max
1022
921
916
Delaware River, Above Trenton
American eel
Anguilla rostrata
National Park
Anguilla rostrata
Morone saxatilis
Anguilla rostrata
Maskells Mill Lake
Chelydra serpentina
F
41.8
49.8
58.3
58.7
70
77.1
185.4
232.1
331
418.6
683.9
569.7
F-3019
F-3121
F-3115
F-3116
F-3122
F-3117
15.36
14.81
17.25
13.28
4.19
22.07
392
272
668
60
263
238
390
271
667
56
259
236
393
277
671
65
268
241
F
M
F
37.9
43.1
57.7
115.3
161.5
359.1
F-3018
F-3017
F-3001
9.19
0.72
10.96
1994
397
579
1994
396
576
1995
399
581
M
F
73.7
78.8
3800
5900
F-3104
F-3103
0.87
6.42
295
797
292
797
297
799
F
F
52
57.9
283.9
399.6
F-3082
F-3083
1.22
9.79
221
119
221
116
231
125
4600
F-3128
0.19
13
9
26
36.8
37.1
45.8
54.8
56.9
98.6
85
182.5
331.9
326
F-3105
F-3106
F-3107
F-3112
F-3111
17.10
3.48
3.40
2.76
4.66
396
76
52
64
137
395
72
48
60
135
401
84
57
68
144
29.7
39.5
149.6
127.1
F-3002
F-3101
2.48
0.15
187
154
183
151
191
164
American eel
striped bass
American eel
turtle
U
Maurice River
Anguilla rostrata
Mullica River
Anguilla rostrata
American eel
American eel
M
Total PCB
Location
Scientific Name
Navesink River
Anguilla rostrata
Newton Lake
Ameiurus nebulosus
Cyprinus carpio
Lepomis macrochirus
Micropterus salmoides
Common Name
Sex
Total
Total Wet
Length cm Weight g Sample ID
42.5
157.3 F-3093
45.7
173.5 F-3100
46.3
199.1 F-3092
69
633.3 F-3096
Lipid%
1.92
13.56
0.08
6.11
Mid
Min
Max
47
192
62
149
44
189
58
147
54
197
72
156
American eel
M
F
M
35.6
40.4
47.1
92.4
131.1
185.4
F-2998
F-3000
F-2999
6.15
2.01
3.98
271
116
277
268
112
275
274
120
279
U
F
F
23.7
30.1
30.3
165.8
338
331
F-3210
F-3212
F-3211
1.22
2.23
1.13
55
67
22
53
65
18
59
70
30
M
F
M
F
F
52.7
54.2
54.5
61.3
63
1965.7
2632.8
2233.6
3600
3600
F-3219
F-3216
F-3218
F-3220
F-3221
4.60
7.31
0.81
3.52
9.21
364
135
374
613
523
363
132
373
612
522
367
137
377
616
525
M
F
F
15.4
16.8
16.9
76.8
110.1
116.4
F-3217
F-3208
F-3209
2.25
2.13
1.50
64
43
26
62
39
23
67
49
32
F
M
35.7
37.8
42.9
616
866.2
1404.2
F-3213
F-3214
F-3215
0.39
0.17
0.81
54
76
238
50
74
238
60
80
240
U
M
F
17.5
28.3
29.4
57
339.3
349.4
F-3234
F-3228
F-3229
2.54
1.80
2.25
30
45
261
26
43
260
36
51
264
M
48.7
51.7
1642
2084.6
F-2845
F-3225
4.86
4.36
1099
2238
1099
2238
1101
2238
brown bullhead
common carp
bluegill
largemouth bass
Passaic River at Elmwood Park
brown bullhead
Ameiurus nebulosus
Cyprinus carpio
common carp
Total PCB
Location
Scientific Name
Lepomis auritus
Micropterus salmoides
Passaic River at Pompton
Cyprinus carpio
Lepomis auritus
Micropterus salmoides
Pennsauken River at Forked
Ameiurus catus
Common Name
Sex
M
F
F
F
Total
Total Wet
Length cm Weight g Sample ID
53.7
1838.2 F-2847
54.1
2150 F-2844
54.3
2595.9 F-3226
57.6
2915.8 F-3227
Lipid%
1.13
1.89
3.83
7.91
Mid
Min
Max
311
482
667
1331
309
482
667
1331
313
483
668
1333
redbreast sunfish
F
F
F
15.1
15.7
16
72.3
79.1
91.1
F-3222
F-3223
F-3224
0.28
16.52
0.52
67
52
69
65
50
66
76
57
75
F
F
F
34
39.3
44
679.9
1079.9
1384.5
F-3036
F-3038
F-3039
0.66
1.10
0.73
120
250
150
119
249
149
123
252
152
F
M
F
F
49.6
50.3
51.2
51.3
1844
2023.7
2142.5
2396.7
F-2846
F-3040
F-3231
F-3230
5.60
7.43
5.61
8.74
775
946
969
957
775
946
969
957
776
948
971
957
U
U
U
14.2
14.3
16.7
62.8
65.9
100.2
F-3118
F-3119
F-3120
0.43
0.92
0.24
49
66
56
46
63
53
55
71
61
M
F
F
27.9
29.8
34.6
352.9
401.3
699.5
F-3233
F-3232
F-3037
0.36
0.56
0.68
112
53
56
109
51
53
117
58
63
F
U
U
M
30.6
36
37.8
42.2
335.8
655.9
632.6
930.7
F-3168
F-3169
F-3170
F-3171
0.66
0.16
1.96
0.25
51
178
262
94
50
177
260
91
61
185
264
99
4200
F-3102
0.73
27
21
37
1986.2
F-3179
4.45
769
768
771
largemouth bass
common carp
redbreast sunfish
largemouth bass
white catfish
Chelydra serpentina
turtle
Cyprinus carpio
common carp
M
50.6
Total PCB
Location
Scientific Name
Lepomis gibbosus
Common Name
bluegill
Micropterus salmoides
largemouth bass
Raccoon Creek
Anguilla rostrata
Morone saxatilis
Raritan Bay at Rt. 1
Anguilla rostrata
Morone americana
Total
Total Wet
Length cm Weight g Sample ID
55.1
2608 F-3177
56.7
2712.8 F-3172
57.6
2930.6 F-3178
62.7
3750 F-3173
Lipid%
11.53
14.89
11.79
19.56
Mid
1087
773
1294
2775
Min
1087
773
1294
2775
Max
1088
775
1296
2777
pumpkinseed
Lepomis macrochirus
Pompton lake-Delta
Chelydra serpentina
Sex
F
M
U
M
M
F
15
18.6
67.7
163.5
F-3167
F-3166
0.35
2.37
84
203
81
202
91
208
M
17.4
110.6
F-3165
1.66
62
59
67
M
M
M
17.4
30.2
30.6
110.6
442.8
431.4
F-3165
F-3176
F-3174
1.66
2.18
0.65
62
331
75
59
330
72
67
334
80
16000
16000
F-3134
F-3134
0.38
0.38
15
15
11
11
28
28
turtle
American eel
U
41.3
47.4
55.5
60.8
69.5
165.9
217
346.5
501.5
824.1
F-3084
F-3085
F-3086
F-3087
F-3088
0.54
0.72
4.47
8.29
4.06
2839
870
744
566
653
2836
868
743
565
651
2844
876
752
573
658
M
67
3119.5
F-3123
1.68
865
864
868
F
M
45.1
47.6
187.6
221.3
F-3034
F-3028
13.73
9.13
1935
1258
1933
1256
1937
1259
M
F
M
M
F
16.1
18.1
18.6
19.2
22
56
82.2
90.5
93
162.7
F-3027
F-2838
F-3026
F-2837
F-2836
3.94
2.97
4.48
1.95
1.57
384
794
443
874
878
382
793
441
873
878
387
796
446
876
879
striped bass
American eel
white perch
Total PCB
Location
Scientific Name
Common Name
Raritan Bay upper
bluefish
Pomatomus saltatrix
Raritan River lower
Pomatomus saltatrix
Stewart Lake
Ameiurus nebulosus
Total
Length cm
Total Wet
Weight g
Sample ID
Lipid%
Mid
Min
Max
U
U
U
U
23.7
25
25.2
25.6
132.3
164.8
184.9
183.8
F-3063
F-3061
F-3064
F-3062
2.03
2.14
1.90
3.07
200
309
319
354
199
308
318
353
205
311
321
358
F
F
M
M
M
M
M
M
M
M
M
M
55.2
55.2
57.9
57.9
63.6
63.6
63.6
63.6
66.7
66.7
67.8
67.8
1762
1762
1836.2
1836.2
2191.5
2191.5
2329
2329
2750
2750
2455.6
2455.6
F-3072
F-3072
F-3076
F-3076
F-3075
F-3075
F-3074
F-3074
F-2857
F-2857
F-3073
F-3073
7.12
7.12
2.36
2.36
2.80
2.80
4.99
4.99
2.41
2.41
3.13
3.13
506
506
205
205
263
263
583
583
452
452
473
473
505
505
204
204
262
262
582
582
451
451
473
473
507
507
209
209
266
266
585
585
453
453
474
474
F
F
U
25.4
27.3
31.1
182.65
250.4
409.5
F-3184
F-3191
F-3192
0.08
1.19
3.09
25
17
38
22
12
34
32
26
45
3500
F-2850
0.29
30
26
36
bluefish
brown bullhead
Chelydra serpentina
turtle
Cyprinus carpio
common carp
Lepomis macrochirus
Sex
F
M
M
M
F
43.8
49.3
54.5
59.8
65.8
1133.6
1681.1
2135
2808.2
3850
F-3189
F-3188
F-3187
F-3181
F-3180
1.73
6.26
2.38
5.04
0.28
44
235
465
527
233
40
235
464
526
231
51
238
466
531
236
U
U
15.9
16.4
79.7
90.4
F-3185
F-3186
0.54
0.80
58
28
55
27
63
39
bluegill
Total PCB
Location
Scientific Name
Common Name
largemouth bass
Micropterus salmoides
Pomoxis nigromaculatus
Strawbridge Ponds
Chelydra serpentina
Total
Length cm
Total Wet
Weight g
Sample ID
Lipid%
Mid
Min
Max
M
M
F
35.9
38.9
43.5
632.5
934.9
1492.3
F-3190
F-3182
F-3183
0.48
0.18
0.16
52
83
139
49
80
137
59
89
143
F
18.3
74.1
F-3193
0.46
20
15
28
4700
F-2851
0.17
45
38
52
black crappie
turtle
Cyprinus carpio
common carp
Ictalurus punctatus
channel catfish
Toms River
Anguilla rostrata
Sex
M
59
3061.8
F-2946
7.26
893
892
894
F
44.5
1082.3
F-3022
2.31
302
301
304
39.4
44.9
56.6
70.3
116.7
165.8
628
803.4
F-3130
F-3135
F-3131
F-3132
1.97
9.50
13.44
5.99
55
201
197
76
50
199
196
73
63
207
202
82
American eel