Final Report:
Routine Monitoring Program
for Toxics in Fish
Contract SR02-064
Report No. 04-06
Submitted to: NJ Department of Environmental Protection
Division of Science Research and Technology
P. O. Box 409
401 East State Street
Trenton, NJ 08625
by
Richard Horwitz, Jeffrey Ashley, Paul Overbeck and David Velinsky
Patrick Center for Environmental Research
Academy of Natural Sciences
1900 Benjamin Franklin Parkway
Philadelphia, PA 19103-1105
May 16, 2005
EXECUTIVE SUMMARY
Currently, a number of freshwater lakes, rivers and reservoirs in the state of New Jersey are
listed as impaired in the 303d Water Quality Assessment Report (DEP 2004) due to
contaminants in fish. The 303d list drives the development of Total Maximum Daily Limits
(TMDL) and other contaminant control strategies. Consumption advisories for fish are also
based on contaminant information. By developing better monitoring tools, the accuracy of
placing waterbodies on the 303d list and the specification of consumption advisories can be
improved. In 2002, the state of New Jersey initiated a routine monitoring program in which
samples are taken in one of 5 different regions each year, so that regions are resampled every
five years. This report summarizes the results from the first routine monitoring study, conducted
in 2002 in the Passaic Region. The results of this program will be used to amend existing
advisories or, if necessary, develop new advisories, and to assist the NJDEP in evaluating trends
in contaminant concentrations.
For this study, 448 analyses were done on 382 fish samples collected from 28 freshwater lakes,
reservoirs and rivers within the Passaic River region of the State of New Jersey. Among sites
previously sampled, sites and taxa which showed relatively high levels of contaminants in
previous studies were chosen. Other taxa were analyzed which may be expected to have similar
or higher contaminant concentrations based on species characteristics (trophic level, lipid
content, benthic habitat, long life, etc.). New sites were chosen which may have the potential for
contamination, based on potential sources of contamination, presence of species with high
bioaccumulation potential, etc. Individual tissue samples were analyzed for one or more of three
groups of contaminants: 1) chlorinated organic contaminants, including congener-specific PCBs,
chlordanes (i.e., " and ( chlordane, heptachlor, heptachlor expoxide, cis- and trans- nonachlor)
and o,p and p,p forms of DDE, DDT, and DDD (total DDTs); 2) total mercury; and /or 3) dioxins
and furans. Information on size, lipid content and sex of fish were also taken.
Concentrations of mercury and PCBs were compared to NJ risk-based thresholds for
consumption advisories. Concentrations of other contaminants were compared to available FDA
action limits and USEPA screening values for recreational fishermen. For mercury, some
advisories to high risk groups would be applicable to most species at most sites sampled. For low
risk groups, advisories would be applicable to some fish (mostly larger predatory fish, carp and
yellow bullhead) from a number of sites, especially some of the larger lakes. In addition to these
relatively general recommendations, some sites of particular concern were noted such as: 1)
Branch Brook Park; carp from this site showed relatively high concentrations of DDX, possibly
indicating a local source. Consumption advisories based on mercury would also apply to some
fish from this site; 2). Overpeck Creek; fish with relatively high levels of PCBs, DDX,
chlordane, dieldrin and/or heptachlor epoxide were found at this site; 3). the Ramapo Lake,
Ramapo River, Pompton Lake and Pompton River; some fish from these sites showed relatively
high levels of mercury and/or PCBs. Some fish from Pompton Lake and Pompton River also
showed relatively high concentrations of chlordane, dieldrin and/or heptachlor epoxide relative
to SV; 4) Passaic River; fish from some sites showed relatively high concentrations of PCBs,
DDX, chlordane, dieldrin, heptachlor epoxide and/or mercury based on risk-based criteria; fish
from the Rockaway River at Powerville showed relatively high concentrations for the species
analyzed; 5) Boonton Reservoir, Canistear Reservoir, Clinton Reservoir, Echo Lake, Monksville
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Reservoir, Oak Ridge Reservoir, Sheppard Pond, Wanaque Reservoir and Wawayanda Lake,
which had some fish for which do not eat advisories for high risk groups would be applicable for
mercury. Other lakes, such as Greenwood Lake, Weequahic Lake, Lake Tappan, Split Rock
Reservoir, Lake Oradell, Speedwell Lake, showed some fish with an advisory of eat less than 1
meal per month for high risk groups. A few largemouth bass from Boonton Reservoir showed
relatively high concentrations of DDX and/or dieldrin relative to SV.
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Table of Contents
Page
EXECUTIVE SUMMARY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
LIST OF TABLES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iv
LIST OF FIGURES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v
INTRODUCTION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Background . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Monitoring Program . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
METHODS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Specimen Collection . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Specimen Handling . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Chemical Analyses . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
RESULTS AND DISCUSSION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Temporal and Spatial Changes in Contaminant Concentrations . . . . . . . . . . . . . . . . . . . . 9
Risk Assessment based on Exceedances of FDA Action Levels . . . . . . . . . . . . . . . . . . . 12
Regions and Species of Concern . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
APPENDIX I. Mercury Concentrations in Individual Fish Specimens . . . . . . . . . . . . . . . . . . . .53
APPENDIX II. Individual Sample Data Organic Contaminants . . . . . . . . . . . . . . . . . . . . . . . . . 71
i.
Key to Summary of PCP and OCP Concentrations . . . . . . . . . . . . . . . . . . . . . . .72
ii.
Summary of PCB and OCP Concentrations . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
iii.
Furans . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .107
iv.
Dioxins. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
APPENDIX III. Hg Quality Assurance Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 112
APPENDIX IV. Proposed Risk-based Consumption Advisories . . . . . . . . . . . . . . . . . . . . . . . .115
APPENDIX V. Quality Assurance/Quality Control Summary . . . . . . . . . . . . . . . . . . . . . . . . . 117
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LIST OF TABLES
Table 1.
Year- 1 Passaic River Region: Routine Monitoring Program -Sample Site List.
Table 2.
Numbers of samples on which various groups of analyses were performed.
Table 3a. Analytes for routine monitoring program.
Table 3b. Dioxin and furan compounds as part of routine monitoring program.
Table 4.
Summary of mercury statistics with comparison to previous studies.
Table 5.
Summary of PCB statistics with comparison to previous studies.
Table 6.
Summary of DDX, chlordanes, aldrin and dieldrin analyzed in the 2002 Monitoring
program.
Table 7.
Summary of selected OCPs (endosulfan, BHC and heptachlor) analyzed in the 2002
Monitoring program.
Table 8.
Summary of furan and dioxin concentrations from species collected from the Passaic
River at Garfield and Dundee Lake.
Table 9.
DDX (sum of p,p' DDT, p,p' DDE and p,p' DDD). Comparison of NJDEP 1986-7
data and ANSP 1998-9 data. 1998-9 and 2000 data use one-half the detection limit for
component compounds less than the detection limit. For 2000 data, means are
averages of site means, and # indicates the number of sites and total number of
specimens.
Table 10. Comparison of chlordane (sum of cis- and trans-) concentrations in NJ monitoring
surveys. All sites in the 2002 study are treated as part of the Northeast.
Table 11. Individual fish exceeding stated criteria. Data are based on sums with component
compounds below detection limit treated as 0. No fish were caught which exceeded
the criteria for aldrin & dieldrin (300 ng/g) or heptachlor (300 ng/g).
Table 12. Proportion of fish by different classes with respect to NJ mercury consumption
advisories.
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LIST OF FIGURES
Figure 1.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Boonton
Reservoir in the 1996-1997 and 2002 ANS monitoring programs.
Figure 2.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Canistear
Reservoir in the 1992-1993 and 2002 ANS monitoring programs.
Figure 3.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Echo Lake
1996-1997 and 2002 ANS monitoring programs.
Figure 4.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Green Turtle
Lake in the 1996-1997 and 2002 ANS monitoring programs.
Figure 5.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Greenwood
Lake in the 1996-1997 and 2002 ANS monitoring programs.
Figure 6.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Monksville
Reservoir in the 1992-1993 and 2002 ANS monitoring programs.
Figure 7.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Oradell
Reservoir in the 1994 and 2002 ANS monitoring programs.
Figure 8.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Oak Ridge
Reservoir in the 1996-1997 and 2002 ANS monitoring programs.
Figure 9.
Concentrations of mercury (:g/g wet weight) in largemouth bass from the Passaic
River at East Hanover (Hatfield Swamp in 1996 and Eagle Rock Ave. in 2002) and
Elmwood Park in the 1996-2002 ANS monitoring programs.
Figure 10.
Concentrations of mercury (:g/g wet weight) in largemouth bass from the Passaic
River at Great Piece to mouth of Pompton River in the 1992-1993 (Great Piece) and
1998 (mouth of Pompton River) ANS monitoring programs.
Figure 11.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Pompton
Lake in the 1992-1993 and 2002 ANS monitoring programs.
Figure 12.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Pompton
River in the 1996-1997 and 2002 ANS monitoring programs.
Figure 13.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Branch
Brook Park, Overpeck Creek, and Ramapo Lake in the 2002 ANS monitoring
program.
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Figure 14.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Weequahic
and Wawayanda Lakes in the 2002 ANS monitoring program.
Figure 15.
Concentrations of total PCBs (ng/g wet weight) in striped bass from the Passaic
River at Garfield in the 2002 survey and in comparison sites from the 1998 ANS
monitoring program, as functions of total length (top) and lipid content (bottom).
Figure 16.
Concentrations of total PCBs (ng/g wet weight) in common carp from the Passaic
and Pompton Rivers in the 2002 and 1998 ANS monitoring program, as functions
of total length (top) and lipid content (bottom).
Figure 17.
Concentrations of total PCBs (ng/g wet weight) in American eels from the Passaic
River in the 2002 program and in comparison sites from the 1998 ANS monitoring
program, and 1986-7 NJDEP sampling program, as functions of total length (top)
and lipid content (bottom).
Figure 18.
Concentrations of total PCBs (ng/g wet weight) in largemouth bass and smallmouth
bass in the 2002 program and in comparison sites from the 1998 ANS monitoring
program, as functions of total length (top) and lipid content (bottom). Data are for
largemouth bass, except where indicated as smallmouth bass in the key.
Figure 19.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Tappan
Reservoir in the 2002 ANS monitoring program.
Figure 20.
Concentrations of mercury (:g/g wet weight) in largemouth bass from Wanaque
Reservoir in the 2002 ANS monitoring program.
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INTRODUCTION
Background
In July 2002, the Academy of Natural Sciences (ANS) began a Routine Monitoring Program for
Toxics in Fish for the New Jersey Department of Environmental Protection (NJDEP). The
purpose of the monitoring program is to provide NJDEP with current and more comprehensive
data on concentrations of toxic contaminants in fish and shellfish in order to assess human health
risks and thus update/recommend fish consumption advisories. There has been a clear need for a
continuous monitoring program for toxics in fish to regularly assess the status and trends of fish
contamination and related consumption advisories in New Jersey waters, as many of the current
consumption advisories are based on data up to 10 years old and there are limited data on some
species and water bodies.
Fish and shellfish consumption advisories due to toxic chemical contamination were announced
in New Jersey in the 1980s and 1990s. Data from Division of Science, Research and Technology
(DSRT) studies revealed that unacceptable risks existed for eating certain species of fish and
shellfish from particular waters in the State. These advisories particularly apply to pregnant
women, nursing mothers and young children because polychlorinated biphenyls (PCBs), dioxin
and mercury are known to cause birth defects, developmental problems, neurological problems
and/or cancer (Appel 2003, Clarkson 2002,Watanabe and Satoh 1996, Schoeny 1996, Ratcliffe et
al. 1996). However, until the implementation of this routine monitoring program, there has been
no mechanism to regularly screen and update data on fish contamination.
New Jersey’s “Year 2000 Water Quality Inventory Report” noted that 100% of assessed public
lakes only partially support fish consumption designated use due to advisories to limit
consumption and that 76% of assessed stream miles only partially support fish consumption
designated use. However, both of these determinations were made on data between 5 and 10
years old.
In 1994, research on freshwater fish found mercury concentrations exceeding the risk-based
health criteria established by the State. The NJDEP/Department of Health and Senior Services
(DHSS) issued statewide, regional and lake-specific fish consumption advisories for two species,
largemouth bass and chain pickerel. Additional data were developed and reported in ANSP
(1999) and Ashley and Horwitz (2000). These data have been used to develop water quality
assessments for specific waterways (see NJDEP 2004 for most current list). The state’s 303d list
of impaired sites (derived from the Clean Water Act) drives the development of Total Maximum
Daily Limits (TMDL) and other contaminant control strategies. The results of this Routine
Monitoring Program will be used to enhance waterbody assessments, to amend existing
advisories or, if necessary, develop new advisories and to assist the NJDEP in evaluating trends
in contaminant concentrations of these selected species.
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Monitoring Program
The monitoring program developed by NJ DEP and implemented by ANS builds upon DSRT
fish contamination research that identified:
•
widespread mercury contamination in the fresh waters of the state;
•
chlordane, PCB and dioxin contamination in site-specific locations; and
•
PCB contamination, predominantly in several coastal estuarine and marine fish species.
The program focuses on collection of those fish species currently under consumption advisories
from waterways identified as having a specified chemical contamination, and on providing new
information on areas or taxa with little existing information. These data provide a tool to assess
the status and trends of these contaminants in the state’s aquatic systems.
Sampling Sites
Due to the large number of water bodies in the state, the sampling program is based on a
rotating assessment of contamination of 5 regions of the state on a 5-year cycle:
1. Passaic River Region;
2. Marine/Estuarine Coastal Region.
3. Raritan River Region;
4. Atlantic Coastal Inland Waterways Region; and
5. Upper and Lower Delaware River Region;
Sampling in the Passaic Region commenced in July of 2002 and the majority of samples were
collected by the fall of 2002 and Spring of 2003. Table 1 presents the Year-1 Routine
Monitoring Program Sample Site List, which was developed by NJDEP. Numbers of samples are
summarized in Table 2. The list incorporates some changes in scope made after the initiation of
sampling. This list includes the selected sample sites and the chemical contaminants to be
analyzed in the various fish species collected at that particular site. The list represents 488
analyses on 382 fish samples collected from 28 freshwater lakes, reservoirs and rivers within the
Passaic River region within the State of New Jersey.
Among sites previously sampled, sites and taxa which showed relatively high levels of
contaminants in previous studies (i.e., above or near DEP or FDA thresholds) were chosen.
Other taxa were analyzed which may be expected to have similar or higher contaminant
concentrations based on species ecology and physiology (i.e., trophic level, lipid content, benthic
habitat, long life, etc.). New sites were chosen which may have the potential for contamination,
based on potential sources of contamination, presence of species with high bioaccumulation
potential, etc.
Previous NJDEP monitoring identified several areas of particular concern. Samples were
collected from representative sites in these regions, except where indicated otherwise.
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Table 1. Sampling design for Year 1 (Passaic River drainage) of the NJ Contaminant Routine
Monitoring Program.
WMA Waterbody
3
3
3
3
3
3
3
3
3
3
3
3
3
3
6
6
6
6
6
5
5
4
4
4
Analytes
Trophic Groups
Anal.
Pred. For. Benthic
X
X
X
Cp
X
X
X
Lmb
X
X
X
Lmb
X
X
X
Lmb ,Cp, Bbh, Ybh
X
X
X
Lmb
X
X
X
Lmb, Wp
X
X
X
Lmb, Cp, Wall, Smb, Wp, Sf, Bbh
X
X
X
Lmb, Cp, Smb, Wp, Wcf, Bbh
X
X
X
X
X
Lmb, Wp
X
X
X
X
X
Lmb
X
X
X
X
X
Lmb, Sf. Smb, Bc, Rb, Bbh, Ybh
X
X
X
X
X
Lmb, Pike, Yp
X
X
X.
X
X
Lmb, Sf, Bc, Carp, Ybh
X
X
X.
X
X
Lmb, Cp, Ybh, Bbh
X
X
X
X
X
Lmb, Wcf, Bbh
X
X.
X
X
Lmb, Sf
X
X
X
X
X
X.
X
X
Wawayanda Lake
Canistear Reservoir
Clinton Reservoir
Oak Ridge Reservoir
Echo Lake
Greenwood Lake
Monksville Reservoir
Wanaque Reservoir
Sheppard Pond
Green Turtle Lake
Ramapo Lake
Pompton Lake
Mercury
Mercury
Mercury
Mercury
Mercury
Mercury
Mercury
Mercury
Mercury
Mercury
Mercury
Mercury
PCBs/pest.
Ramapo R @ Pompton Feeder
Mercury
(=Pompton R @ Pequannock R) PCBs/pest.
Pompton R @ Lincoln Park Rt
Mercury
202
PCBs/pest.
Passaic R. @ Hanover (Pompton Mercury
to Great Piece to Hatfield Swamp) PCBs/pest.
Rockaway R.@ Powerville
Mercury
Split Rock Reservoir
Mercury
Boonton Reservoir
Mercury
PCBs/pest.
Speedwell Lake
Mercury
Overpeck Creek
Mercury
PCBs/pest.
Weequahic Lake
Mercury
PCBs/pest.
Branch Brook Park
Mercury
PCBs/pest.
Oradell Reservoir
Mercury
Lake Tappan
Mercury
Passaic R @ Elmwood Park
PCBs/pest.
(Upriver)
Mercury
Passaic R Lake Dundee
Dioxin
(Upstream of Dundee Dam)
PCBs/pest.
Mercury
Passaic R @ Garfield
Dioxin
(Downstream of Dundee Dam
PCBs/pest.
Mercury
4
Passaic R @ Lyndhurst
(Downstream of Dundee Dam)
See next page for Legend
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Species under Advisory
X
X
X.
X
X.
X
X
X
X
X
PCBs/pest.
X
X
X
X
X
X
X
X
X
X
X
X
X
X
Lmb, Carp, Ybh
Smb, Carp, Ybh
Lmb, Bbh
All Species under Dioxin
Advisory Downriver of Dundee
Dam
X
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PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Legend for Table 2:
Except where noted Mercury Advisories are listed by species
WMA = Watershed Management Area
Trophic levels of target species:
Predator (Pred.): largemouth bass (Lmb), smallmouth bass (Smb), chain pickerel (Cp),
striped bass (Sb), walleye (Wall), walleye and/or northern pike (Pike)
Forage (For.): bluegill (Sf), redbreast sunfish (Sf), black crappie (Bc), rock bass (Rb),
white perch (Wp) and/or yellow perch (Yp)
Benthic invertivore/omnivore (Benthic): common carp (Carp), white sucker (Ws), yellow
bullhead (Ybb), brown bullhead (Bbh) and/or American eel (Eel).
Table 2.
Numbers of samples on which various groups of analyses performed.
Analyses
Hg, PCB/pesticides and dioxins/furans
Hg and PCB/pesticides
PCB/pesticides and dioxins/furans
PCB/pesticides
Hg
TOTALS
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Hg
11
65
273
349
4
PCB/pesticides
11
65
19
14
Dioxins/furans
11
109
30
19
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METHODS
Specimen Collection
Specimens were obtained by a variety of techniques and were selected to be of a size which
would typically be eaten by anglers. Most fish were collected by boat electroshocking, which
was effective in lakes and large rivers with access. Fish were also caught using gill nets (some
fish at Clinton Lake, most fish at Split Rock Reservoir), tow-barge electroshocking (all fish from
Passaic River at Garfield), backpack electroshocking (all fish from Passaic River at Powerville,
and four sunfish from Clinton Lake), traps (walleye and bluegill at Monksville Reservoir, and
one rock bass at Clinton Lake), angling (3 specimens) and dip netting (2 specimens).
Virtually all fish were caught between July 1 and October 31, 2002, with most fish caught in
September-October, 2002. Green Turtle Lake, Greenwood Lake, Ramapo Lake, Ramapo River,
and Wanaque Reservoir were sampled in July, 2002. Pompton Lake, several Passaic River sites
(Eagle Rock and Lincoln Park), Rockaway River, Wawayanda Lake and Shepherds Lake were
sampled in August, 2002. Some additional fish from Shepherds Lake and Wawayanda Lake were
collected in October, 2002. Walleye from Monksville Reservoir were collected in April, 2003.
Specimen Handling
During collection and initial processing, specimens were held in ambient water. After initial
processing, fish were individually wrapped in muffled aluminum foil secured with duct tape.
Specimens were given unique serial numbers, container ID# and specimen ID#. A uniquelynumbered Floy anchor tag in the head of the fish was used as an additional specimen ID for
some specimens. At the field site and during transport to the laboratory, wrapped specimens
were held in wet or dry ice.
In the laboratory, all specimens were logged in to the Patrick Center for Environmental Research
(PCER) Fisheries database and were retained at ANS-PCER in freezers at #20.0°F. All
transfers of samples were properly documented throughout transport and analysis (internal lab
chain-of-custody). All laboratory equipment was properly calibrated as per each method
completed (see Appendix). Careful cleaning of all laboratory equipment and instruments using
the appropriate soaps, solvents, acids, and double deionized water (DDW) was employed
throughout this program.
Tissue preparation of fish followed common preparation methods for consumption. The
specimens were filleted using clean methods for both trace metals and organic contaminants as
outlined in EPA (1995; ANSP SOP-14-12r4). In brief, the samples were filleted with skin off
using either titanium or stainless steel utensils on glass plates. All fish samples were individual
fillets, typically the left side fillet, with the remains (right side, remaining carcass and head)
retained for archival material. The archived sample material remains (including the extra sample
homogenate not analyzed) will be retained by PCER for a period of one year following project
data submission.
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Chemical Analyses
Individual tissue samples were analyzed for one or more of three groups of contaminants (Table
2):
•
chlorinated organic contaminants including congener-specific PCBs, chlordanes (i.e., "
and ( chlordane, heptachlor, heptachlor epoxide, cis- and trans- nonachlor) and o,p and
p,p forms of DDE, DDT, and DDD (total DDTs);
•
total mercury;
•
dioxins and furans. Additional information such as lipid content and size of fish were
also collected for correlation with contaminant levels.
Each tissue sample was minced and tissuemized and placed into separate pre-cleaned jars
(certified ICHEM) for trace metals and organic analysis. Chemical analysis was performed by
PCER using modified U.S. EPA and NOAA Status and Trends approved methods (ANSP SOPs
P-16-84r4, P-16-111, P-16-109r1, and P-16-108). Chemical contaminants and ancillary
parameters are listed in Table 3.
As part of quality assurance and quality control (QA/QC), Standard Reference Material (SRM)
were analyzed as part of the QA/QC procedure. This material was obtained from the National
Institute of Standards and Technology (NIST) or equivalent agency (see NOAA, 1992) and
consisted of NRC (National Research Council) DORM-2, NRC TORT-2 and NIST (National
Institute of Standards and Technology) SRM 1946 for mercury analysis and NIST SRM 1974B
(Organics in Mussel Tissue) and SRM 1946 (Lake Superior Fish Tissue ) for organic analyses.
Also, additional duplicate samples were analyzed to help assess laboratory variations in the
analysis of fish tissue, which provided critical information for the assessment of both
geographical and temporal trends.
All glassware and materials coming into contact with the fish were pre-cleaned with the
appropriate cleaning agent (e.g., micro soap, acids, deionized water, solvents, etc) pertaining to
the specific parameter or group of parameters. The various procedures are provided in the
Appendix.
Mercury
Extractions and Analyses: Strong acid digestions were performed using 10 ml nitric acid on
approximately 1 g homogenized wet fish material in a CEM MDS 2100 microwave digestion
system. Mercury quantitation was subsequently accomplished using a Perkin Elmer Fimms 400
Cold Vapor AA. Multiple point calibrations, laboratory blanks, intercalibration verification
samples, and instrument duplicates were part of this program to ensure instrument performance
and accuracy.
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Polychlorinated Biphenyls and Organochlorine Pesticides
Extractions and Analyses: Homogenized fish samples were stored frozen until extraction. For
extraction, samples were thawed and 2 g of the homogenate was sub-sampled using a stainless
steel spatula. An additional 2-5 g sub-sample was taken for moisture analysis. Approximately
30 g of Na2SO4 (previously extracted with hexane using a Soxhlet extractor and dried) was added
to the sub-sample to eliminate water. The dried sample was then placed in a glass thimble and
extracted using a Soxhlet extractor with ca. 200 ml dichloromethane (DCM) for a minimum of
18 h. The extracts were then sub-sampled for gravimetric lipid determination. For this, a known
volume of extract was transferred to a pre-weighed aluminum pan. The solvent was evaporated
at 110/ C for at least 24 h. The residue remaining (lipid) was weighed and percent lipid
calculated.
Lipids were removed from sample extracts by gel permeation chromatography (GPC) using
DCM as the mobile phase. The collected fraction containing analytes was concentrated by
roto-evaporation and a N2 stream. Solid-liquid chromatography using florisil was performed as
an additional clean-up step. Using this technique, PCBs (as well as heptachlor, nonachlors, and
DDEs) were eluted from the chromatographic column containing florisil using petroleum ether
(F1 fraction). The remaining organochlorine pesticides were eluted using 50:50 petroleum ether
and dichloromethane (F2 fraction).
Congener-specific PCBs and organochlorine pesticides (Table 3) were analyzed using a Hewlett
Packard 5890 gas chromatograph equipped with a 63Ni electron capture detector and a 5%
phenylmethyl silicon capillary column. The identification and quantification of PCB congeners
follows a method described by Swackhamer (1987) in which the identities and concentrations of
each congener in a mixed Aroclor standard (25:18:18 mixture of Aroclors 1232, 1248 and 1262)
were determined by calibration with individual PCB congener standards. Congener identities in
the sample extracts were based on their chromatographic retention times relative to the internal
standards added. In cases where two or more congeners could not be chromatographically
resolved, the combined concentrations were reported (Table 3). Organochlorine pesticides
(OCPs) were identified and quantified based on comparisons (retention times and peak areas)
with a known calibration standard prepared from individual compounds. Quality assurance and
control measures were included at a frequency of 10% of the total number of samples. These
measures included: evaluation of surrogate recoveries, calculation of blank-based detection
limits, use of NIST standard reference materials and involvement in NIST’s annual
inter-laboratory comparison to assess PCER’s accuracy and precision in quantifying PCBs and
OCPs, duplicate analysis, and spike recoveries. The quantitated congeners include two coplanar
congeners (77 and 81) which co-elute with non-coplanar congeners.
Dioxin
The 30 samples prepared for dioxin/furans analysis (Table 3b) were sent to the Texas A&M
University, Geochemical and Environmental Research Group (GERG). Quality assurance and
control measures followed by GERG are summarized in the QA/QC report accompany this
report (Appendix Vii).
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Table 3a. Analytes for routine monitoring program.
Organochlorinated Pesticides Polychlorinated biphenyls1
BHC (alpha, beta, gamma
1
31,28
74
134,144
delta)
Heptachlor
3 33,21,53 70,76
107
Heptachlor epoxide
4,10
22 66,95
149
Chlordanes (gamma and alpha)
6
45
91
118
Nonachlors (cis2 and trans)
7
46 56,60
134
Dieldrin
8,5
52
101
131
DDDs (o,p and p,p)
14
49
99
146
DDEs (o,p3 and p,p)
19
48,47
DDTs (o,p and p,p)
Aldrin
Endosulfan I and II
Endrin
12,13
18
17
24,27
44
37,42
41,71
64
29
40
Oxychlordane
83 132,153,1
05
97
141
81,87
137,176
85
158
136
129,178
185
207
174
177
201,171
172,197
180
193
194
205
206
209
16,324
163,13
84
25
191
199
170,190
198
201
63
151
128
208,19
5
77,11
187,182 203,196
0
26
100
82
183
189
Total Mercury (T Hg)
1
PCB congeners appearing as pairs or triplets will coelute and will be reported as sum.
2
o,p-DDE coelutes with PCB congeners 92,85.
3
Evidence for PCB coelution with cis-nonachlor.
4
PCB congeners not listed in draft work plan.
Table 3b. Dioxin and furan compounds as part of routine monitoring program.
Dioxin Compounds
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
Furan Compounds
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2,3,4,6,7,8-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
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RESULTS AND DISCUSSION
Temporal and Spatial Changes in Contaminant Concentrations
Summary statistics (means, minimum and maximum values) for each station are presented in
Table 4 (mercury), Table 5 (PCBs), Tables 6 and 7 (Organochlorine Pesticides), and Table 8
(dioxins and furans). The concentrations of mercury (for all samples) and the measured organic
contaminants for specimens are presented in Appendix I (mercury) and Appendix II (organic
contaminants). Unless otherwise indicated, units are reported as ng/g wet weight for organic
compounds and :g/g wet weight for mercury. The taxa and stations sampled in the study were
designed to supplement data for the Passaic region from previous contaminant surveys.
Comparisons with earlier data (ANSP1994, Horwitz, et al. 1995, ANSP 1999, Ashley and
Horwitz 2000) may show temporal changes, particularly comparing stations sampled in the
earlier studies (1992-1994) with those sampled in the current study (2002-2003). Where
temporal changes are not evident, the current data provide greater coverage of species and size
groups and provide more precision from the larger sample size. Mercury and PCB concentrations
in fishes from the Passaic Region from earlier studies are also presented in Tables 4 and 5,
respectively. Data on diadromous fish from 1998 (i.e., striped bass and American eel; Ashley
and Horwitz 2000) from coastal sites are also presented. Relationships between contaminant
concentrations and size/age of fish (most contaminants) and/or lipid content (organic
contaminants) are shown in Figures 1-20. Lipid-normalized PCB concentrations (Table 5) also
adjust for organic concentration-lipid relationships.
Mercury
Most sites sampled in 1992-1994 and in the current study show no difference in mercury-length
relationships among the two sampling periods for largemouth bass, the primary indicator species
(Figures 1-14). These sites include Tappan Reservoir, Wanaque Reservoir, Oradell Reservoir,
Oak Ridge Reservoir, Greenwood Lake, Boonton Lake, Pompton Lake, and the Passaic River
near the mouth of Pompton River (including Great Piece). Two sites, Monksville Reservoir
(Figure 6) and Canistear Reservoir (Figure 2), appear to show lower mercury concentrations in
2002 than in 1992, although the small sample size precludes statistical comparisons.
No between-survey differences were seen for most sites sampled in the 1996 or 1998 survey and
the current survey. These sites include Green Turtle Lake (Figure 4), Echo Lake (Figure 3), the
Passaic River at Elmwood Park (Figure 9), and Passaic River at East Hanover (Figure 9; Hatfield
Swamp and Eagle Rock Road). Mercury concentrations in bass from the Pompton River at
Lincoln Park (Figure 12) appeared lower in 2002 than in 1996. However, sample size was too
small to make statistical comparisons.
There are differences in mercury concentrations among stations, taking into account the
mercury-fish length relationships, although sample sizes at each station are too low for statistical
comparisons. The highest values (based on approximate concentrations in a mid-sized bass) were
seen at the Ramapo River at Pompton Feeder and the Pompton River at Lincoln Park in 1996.
Relatively high concentrations (e.g., approximately 0.7-0.8 :g/g for a 40-cm largemouth bass)
were seen at Lake Wanaque, Monksville Reservoir in 1998, Pompton River at Lincoln Park in
2002, and Oak Ridge Reservoir. Intermediate concentrations (approximately 0.5-0.6 :g/g for a
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40-cm bass) were seen at Branch Brook Lake, Boonton Reservoir, Lake Canistear, Wawayanda
Lake, and the Passaic River sites. Lower concentrations (approximately 0.3-0.4 :g/g for a 40 cm
bass) were seen at Monksville Reservoir in 2002, Green Turtle Pond, Greenwood Lake and Echo
Lake. The lowest concentrations (<0.3 for a 40 cm bass) were seen at Weequahic Lake, Lake
Tappan, Overpeck Lake, and Oradell Reservoir.
Polychlorinated Biphenyls
Polychlorinated biphenyls (PCBs), globally ubiquitous despite their production ban in the mid
1970s, are of particular concern due to their bioaccumulative nature. PCBs were measured in ten
fish species at various locations within the Passaic River region (Table 5). For yellow bullhead,
northern pike, and redbreast sunfish, concentrations of total PCB (t-PCB defined as the sum of
all quantified PCB congeners on a wet weight basis) were well below 100 ng/g, likely due to a
combination of factors such as trophic position (e.g., low such as redbreast sunfish) and/or lipid
content (e.g., relatively lean fish such as pike). White sucker, channel catfish, and bluegill from
the Passaic River had t-PCB concentrations ranging from 190 to 334 ng/g.
PCBs were measured in striped bass from the Passaic River at Garfield. Spatial comparisons can
be made with other coastal striped bass measured in the 1998 study (Ashley and Horwitz, 2000).
The PCB concentrations in the Passaic River fish were similar to typical values in the previous
study (Figure 15). The Passaic River fish were smaller than the fish sampled at the other sites,
but there is not a clear PCB concentration-length relationship among the larger fish from the
other sites. The PCB concentrations in the Passaic River fish were in range, though on the high
end, of typical concentrations of fish with similar lipid content.
PCBs were measured in common carp from a number of sites in the Passaic River (Figure 16).
Carp were analyzed from one of these sites and in Lake Dundee as part of the 1998 study
(Ashley and Horwitz, 2000). There was no clear relationship between PCB concentration and
length among the fish analyzed (all fish were relative large, so accumulation patterns between
juvenile and adult fish cannot be discerned). In addition, t-PCB concentration increased with
lipid content of the fish. The pattern was similar among all the stations, and there was no obvious
temporal difference in concentration.
PCBs were measured in American eels from three sites on the Passaic River (Figure 17). Eels
from one of these sites (Passaic River at Elmwood Park) had been analyzed in the 1998 study
(Ashley and Horwitz, 2000). In the current study, t-PCB concentrations increased with lipid
content. The pattern was similar among most of the stations sampled in 1998 and the current
study, except for higher concentrations in some of the eels from Raritan Bay in the 1998 study.
Comparison of eels from Northeastern sites (1986-7) to the more recent data sets (1998 and this
current study), shows a decrease in PCB body burdens over time (Figure 17). This relationship
is largely driven by four northeastern eels of low to moderate lipid content (and length from
around 30 to 55 cm) having concentrations higher than 1500 ng/g.
PCBs were measured in largemouth bass and smallmouth bass from several sites in the 1998 and
current study (Figure 18). PCB concentration tended to increase with both length and lipid
content of the fish in both studies. Concentrations were similar among fish from most sites. The
highest concentrations were seen in largemouth and smallmouth bass from Boonton Reservoir.
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These fish were both larger and had higher lipid content than the other fish, so it cannot be
determined whether this is a spatial pattern or due to individual fish condition.
Organochlorine Pesticides
Organochlorine pesticide (OCP) concentrations, grouped according to location and species
(Tables 6 and 7), reveal considerable variation for some analytes. DDXs had the highest
concentrations, across species and location. In this report, DDXs are comprised of the two
isomers (p,p and o,p) of DDT (1,1,1-trichloro-2,2-bis-(p-chlorophenyl)ethane), which was
widely used to control insect pests on agricultural crops and those carrying infectious diseases,
and the two isomers (p,p and o,p) of each of its metabolites, DDE
(1,1-dichloro-2,2-bis(p-chlorophenyl)ethylene) and DDD (1,1-dichloro-2, 2-bis(p-chlorophenyl)
ethane). Four of six of the highest mean DDX concentrations (ranging from approximately 200
to 950 ng/g) were found in carp (Table 6). The highest detected DDX concentration came from
a carp from Branch Brook Park; the second highest from an American eel from Overpeck Creek.
Comparisons with several historical surveys can be done for some species in some areas (Table
9). These do not show clear, consistent changes in concentrations, which may reflect differences
in precise locations, size and condition of fish analyzed in the various studies.
Following DDXs, chlordanes had the highest concentrations across species and location. In the
U.S., chlordane was used as a pesticide on crops such as corn and citrus and on home lawns and
gardens from 1948 to 1988. Chlordane is comprised of pure chlordane (cis and trans isomers) as
well as many related chemicals (cis- and trans-nonachlor, oxychlordane, alpha-, beta- and
gamma-chlordene, and chlordene). Total chlordane is reported as the sum of all these quantified
compounds, except for comparisons with the FDA action limit, which is based on the sum of cis
and trans isomers only.
In most locations of this study, elevated levels of chlordane within a species mirrored the
elevated DDX concentrations (e.g., American eels from Overpeck Creek, common carp from the
Passaic River at Lincoln Park and Eagle Rock Ave.) (Table 6). However, this was not the case
for carp and largemouth bass collected from Branch Brook Park, which had elevated DDXs
concentrations but very low chlordane levels, indicating a distinct source of DDT or its
metabolites in this area but not of chlordane. Comparisons with results of previous surveys
(Table 10) suggest decreases in some species and locations between samples from the 1980's and
the later samples (1990-2002) or possibly between the 2002 and earlier samples (e.g., eels from
the northeast region). These comparisons depend on the precise locations, size and condition of
fish.
Aldrin and dieldrin, both chlorinated cyclodiene insecticides, were popular pesticides for
agricultural crops such as corn and cotton in the 1950s-1970. Aldrin breaks down into dieldrin in
the environment. The Environmental Protection Agency banned all uses of dieldrin and aldrin in
1974 with the exception of termite control. In 1987, the agency banned all uses. Because
dieldrin and aldrin are so closely related both in structure and toxicity, they are reported and
regulated together. Aldrin and dieldrin concentrations were low across all species and locations
(Table 6). Highest concentrations were observed in American eels from the Passaic River at
Dundee Lake (up to 64 ng/g) and Garfield (up to 27 ng/g), and in common carp from the Passaic
River at Lyndhurst (up to 26 ng/g).
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Alpha and beta forms of endosulfan (or I and II) make up the technical form of the insecticide
endosulfan, which was used to control insects on grains, tea, fruit, and vegetables though the
majority of applications were made to tobacco and cotton. Though the pesticide has not been
produced in the US since 1982, it is still currently used on crops and is used to produce other
chemicals. Concentrations of total endosulfan (I and II) were very low for all sites and species,
with the highest reported value only being 25 ng/g from a common carp collected from the
Passaic River Eagle Rock Ave. (Table 7).
Total benzene hexachlorides (alpha, beta, and delta BHC) were exceptionally low at each
location and species. The highest value reported (6 ng/g) was observed in common carp from
the Passaic River at Lyndhurst and at Elmwood Park (Table 7).
Heptachlor was used as an insecticide in the US from 1953 to 1974. The pesticide was
commonly used to control termites as well as kill insects in seed grains and on crops but by
1974, nearly all registered uses of this pesticide were cancelled. Heptachlor concentrations were
very low at all locations and for all species (Table 7). The highest concentration was observed in
common carp from the Passaic River at Lyndhurst (23 ng/g).
Dioxins and Furans
Dioxins are a group of structurally similar compounds (congeners), which are produced
inadvertently by a number of human activities, such as the combustion of fuel and commercial or
municipal waste. Specific industrial processes such as chlorine bleaching of pulp and paper,
certain types of chemical manufacturing and processing, and other industrial processes can
create small quantities of dioxins and furans.
Total furans and dioxins (i.e., the sum of quantitated congeners) were measured in American eel,
common carp, and largemouth bass from the Passaic River at Dundee Lake and in American eel,
white sucker, common carp, channel catfish and striped bass from the Passaic River at Garfield.
Mean concentrations were higher at the downstream site (Garfield) than at Dundee Lake (Table
8). Striped bass had the highest concentration of these contaminants. Being anadromous, striped
bass body burdens are likely reflective of not only recent exposure within the estuarine waters of
the Passaic River but of the their historic migrations into and out of other contaminated areas.
Carp and catfish had the second most abundant dioxin burdens, likely due to their close
association with sediments, which harbor these hydrophobic organic molecules. Surprisingly,
eels from both locations did not have elevated concentrations of either furans or dioxins.
Risk Assessment based on Exceedances of FDA Action Levels
The FDA nationally promulgates guidelines for the consumption of fish and fishery products by
issuing action limits. The primary purpose of these limits is to represent the point at or above
which the administration will take legal action to remove products from the market. While fish
caught by recreational anglers do not fall under FDA purview, the FDA limits are often used as a
benchmark for the minimum concentration above which ingestion is not recommended. The US
EPA and individual states, including New Jersey, have promulgated other action limits. These
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are often based on risk assessments, may vary with target population and may recommend
frequency of consumption rather than setting a single “do not eat” level. These USEPA and state
levels are often lower than those of FDA. USEPA (2004) defines screening values as
“concentrations of target analytes in fish or shellfish tissue that are of potential public health
concern and that are used as threshold values against which levels of contamination in similar
tissue collected from the ambient environment can be compared”. For comparison, screening
values (SV) for recreational fishermen (SVrf) are used below (Table 5-4 in USEPA 2004). SV
for different groups depend on the balance between different consumption rates and lower body
weights of children. For noncarcinogens, relationships between SV for different groups are more
complex, since reference does (e.g., related to developmental or reproductive effects) differ
among groups as well.
Mercury
The FDA action limit for total mercury in fish tissue is 1 :g/g on a wet weight basis (or 1 ppm).
Nine fish, all largemouth bass, exceeded this criterion (Table 11). Two relatively small bass from
Ramapo River at Pompton Feeder exceeded this criterion. Otherwise, all bass with concentration
greater than 1 :g/g were relatively large (greater than 47 cm total length) fish from lakes or
reservoirs.
New Jersey has used risk assessment to assign consumption advisories for high and low risk
groups in the population. For each group, categories may be “no restrictions”, “1 meal per
week”, “1 meal per month”, or “do not eat”. For the high risk group, some restriction would be
applicable for most species at most stations for the 2002 data (Table 12). The most severe
restrictions (“do not eat” or “eat once a month”) apply mainly to carp or larger predatory fish,
i.e., largemouth bass, striped bass, chain pickerel and walleye. However, some other species fall
into these groups, e.g., sunfish (bluegill, redbreast sunfish, black crappie and rock bass) at
several lakes and some rivers, and yellow bullhead at a few sites. For the low risk groups, no fish
fall into the category where no consumption is advised, and no consumption restrictions would
be applied to a number of species and sites (Table 12). Advisories would apply mainly to
predatory fish, i.e., largemouth bass, striped bass, walleye, smallmouth bass and chain pickerel,
as well as to carp and yellow bullhead at some sites. At a few sites, some, but not most, of the
bluegill and rock bass analyzed would fall into the “eat 1 meal per week” category.
PCBs
The US FDA “do not eat” limit is 2,000 ng/g for total PCBs. None of the fish exceeded this
limit from this study. However, many states and organizations recognize that this limit may be
too high and use lower limits. Five of the fish from this study exceeded 1,000 ng/g (Table 11),
three of the five being common carp.
The New Jersey DEP has developed risk-based consumption advisories (Post, et al. 2001). These
set consumption advisories for total PCBs based on different cancer risk levels (Appendix IV).
As with mercury advisories, these range from “do not eat” to maximal recommended frequencies
of consumption (“once per year”, “once per 3 months”, “once per month”, or “one meal per
week”). The study found a general correspondence between the advisories for cancer risk of 10-5
and 10-4 and risk for high risk groups (children, pregnant women and women of child-bearing
age) based on developmental and reproductive endpoints. However, intermediate frequency
consumption advisories (“once per month” or “once per 3 months”) are not recommended for the
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developmental and reproductive endpoints, to protect against single high dosages which might
be allowed under these intermediate consumption frequencies.
Some consumption advisories would be appropriate for all of the 109 fish analyzed in the 2002
study. For the more restrictive endpoint (cancer risk less than or equal to 10-5), all fish fall above
the “one meal per month” criterion, 84% above the “one meal per 3 months” criterion, 61%
above the “one meal per year” criterion, and 17% above the “do not eat” criterion. For the less
restrictive risk endpoint (cancer risk of 10-4), all fish are above the “one meal per week”
criterion, 67% above the “one meal per month” criterion, and 20% above the “one meal per 3
months” criterion. Only 1 fish fell above the “one meal per year” criterion, and no fish above the
“do not eat” criterion. Since species and sites varied in PCB concentration, and the study
targeted sites and species with higher contamination, these proportions are not representative of
the overall state fish populations. Specific consumption advisories for species and sites would
require a more detailed analysis of exceedance frequencies by species and site.
Chlordane
The US FDA has set an action limit of 300 ng/g wet weight (or 0.3 ppm) for chlordane (cis and
trans forms, equivalent to alpha and gamma forms) in fish. Total chlordane values were
calculated based on the US FDA guidelines with the exception that no chlordanes were included
in the sum. Only one sample, an American eel from Overpeck Creek, exceeded this limit (Table
11). The SVrf for total chlordanes is 114 ng/g wet weight (based on carcinogenic effects. An
additional 14 fish, including common carp and American eel from the Passaic River and
Overpeck Creek, and carp from the Pompton River and Pompton Lake, exceeded this limit
(Table 11).
DDXs
Because of its bioaccumulative nature and toxicity, the US FDA has set an action limit for DDXs
(sum of DDTs, DDEs, and DDDs) at 5.0 ppm (5000ng/g). None of the samples exceeded this
limit. The SVrf for total DDXs is 117 ng/g, based on carcinogenic effects. Thirty-four fish
exceeded this limit (Table 11), including common carp, American eel and a few striped bass
from the Passaic River, and carp and/or eel from several other sites (Overpeck Creek, Pompton
River, Pompton Lake, Branch Brook Park, Weequahic Lake). Largemouth bass from several
sites (Branch Brook Park, Overpeck Creek, and Boonton Reservoir) also exceeded this limit.
Dieldrin, Aldrin, Heptachlor and Heptachlor Epoxide
The US FDA’s action limit for aldrin and dieldrin in fish is 0.3ppm (300ng/g). Based on the
concentrations determined in this monitoring study, none of the collected fish exceeded the
action limit for dieldrin and aldrin (Table 6). The SVrf for dieldrin is 2.5 ng/g based on
carcinogenic effects. Forty-six fish exceeded this limit (Table 11), mainly fishes from the Passaic
River. Heptachlor expoxide is an oxidation product of heptachlor formed by many organisms
including humans. Based on their toxicity, both heptachlor and heptachlor expoxide action
limits in food were set by the US FDA. For fish, the two compounds, either individually or in
combination, should not exceed 0.3 ppm. For this study, concentrations for all collected species
fell well below the action limit (Table 6). However, the SVrf for heptachlor epoxide based on
carcinogenic effects is low (4.4 ng/g). Thirty-one fish exceeded this limit (Table 11), including
several species from the Passaic River and Overpeck Creek. Ninety of the 109 fish specimens
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analyzed (82%) exceeded the more stringent limit (0.54 ng/g) for subsistence fishermen.
Organochlorine Pesticides of Concern Having No Action Limits
The are no federal action limits or consumption guidelines for foods containing benzene
hexachlorides (alpha, beta, and delta BHC). Concentrations of BHCs were very low. Lindane,
another compound having no FDA fish actions limits, is used as an insecticide and fumigant on a
wide variety of crops and seeds and as a means to control insect-borne diseases. Lindane is
primarily comprised of the gamma isomer of hexachlorocyclohexane ((-HCH). The SVrf for
lindane is 31 ng/g. All of the specimens analyzed were below this limit. Endrin has been used
as a pesticide to control insects and rodents. It is no longer produced or sold for general use in
the US. To date, there are no federal consumption guidelines for foods containing endrin. The
SVrf for endrin is 1200 ng/g and SV for subistence fishermen is 147. All of the specimens
analyzed were well below this limit. Lastly, in this country, there are no federal consumption
guidelines for foods containing endosulfan. The SVrf for endosulfan (I and II combined ) is
24000 ng/g and the SV for subsistence fishermen is 2949. The concentrations of the two forms of
endosulfan were well below these limits in all samples analyzed.
Regions and Species of Concern
One of the main objectives of this program was to determine potential human health impacts
based on contaminant data encompassing a wide range of fish species and locations. As stated,
this will be a multi-year investigation that will assess contamination in fishes from specific
regions each year. Based on the results of the 2002 chemical analyses described within this
report and the identification of the exceedances of action limits for PCBs, mercury, DDXs and
chlordanes, recommendations can be made about potential species and regions of concern. For
mercury, some advisories to high risk groups would be applicable to most species at most sites
sampled. For low risk groups, advisories would be applicable to some fish (mostly larger
predatory fish, carp and yellow bullhead) from a number of sites, especially some of the larger
lakes. In addition to these relatively general recommendations, some sites of particular concern
can be noted:
1. Branch Brook Park; carp from this site showed relatively high concentrations of DDX,
possibly indicating a local source. Consumption advisories based on mercury would also apply
to some fish from this site.
2. Overpeck Creek; fish with relatively high levels of PCBs, DDX, chlordane, dieldrin and/or
heptachlor epoxide were found at this site.
3. The Ramapo Lake, Ramapo River, Pompton Lake and Pompton River; some fish from these
sites showed relatively high levels of mercury and/or PCBs. Some fish from Pompton Lake and
Pompton River also showed relatively high concentrations of chlordane, dieldrin and/or
heptachlor epoxide relative to SV.
THE ACADEMY OF NATURAL SCIENCES
15
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
4. Passaic River; fish from some sites showed relatively high concentrations of PCBs, DDX,
chlordane, dieldrin, heptachlor epoxide and/or mercury based on risk-based criteria; fish from
the Rockaway River at Powerville showed relatively high concentrations for the species
analyzed.
5. Boonton Reservoir, Canistear Reservoir, Clinton Reservoir, Echo Lake, Monksville Reservoir,
Oak Ridge Reservoir, Sheppard Pond, Wanaque Reservoir and Wawayanda Lake, which had
some fish for which do not eat advisories for high risk groups would be applicable for mercury.
Other lakes, such as Greenwood Lake, Weequahic Lake, Lake Tappan, Split Rock Reservoir,
Lake Oradell, Speedwell Lake, showed some fish with an advisory of eat less than 1 meal per
month for high risk groups. A few largemouth bass from Boonton Reservoir showed relatively
high concentrations of DDX and/or dieldrin relative to SV.
THE ACADEMY OF NATURAL SCIENCES
16
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
REFERENCES
.
Academy of Natural Sciences of Philadelphia (ANSP). 1994. Preliminary Assessment of Total
Mercury Concentrations in fishes from rivers, lakes and reservoirs of New Jersey. Report 9315F. Submitted to New Jersey Department of Environmental Protection and Energy, Division of
Science and Research. Contract P-35272. 92 pp.
Academy of Natural Sciences of Philadelphia (ANSP). 1999. Phase II Assessment of total
mercury concentrations in fishes from rivers, lakes and reservoirs of New Jersey. Report 99-7.
Submitted to New Jersey Department of Environmental Protection and Energy, Division of
Science and Research. 155 pp.
Appel, K.E. 2003. Risk assessment of non-dioxin-like PCBs- report on a WHO-consulation.
Fresenius Env. Bull. 12(3):268-275.
Ashley, J. And R. Horwitz. 2000. Assessment of PCBs, selected organic pesticides and mercury
in fishes from New Jersey: 1998-1999 Monitoring Program, Academy of Natural Sciences
Report No. 00-20F. 112 pp.
Clarkson, T.W. 2002. The three modern faces of mercury. Env. Health Perspectives. 110, Suppl
1. pp. 11-23.
Horwitz, RJ, B Ruppell, S Wisniewski, P Kiry, M Hermanson and C Gilmour. 1995. Mercury
concentrations in freshwater fishes in New Jersey. Wat., Air and Soil Poll. 80:885-888.
New Jersey Department of Environmental Protection (NJ DEP). 2004. NJ Integrated Water
Quality Monitoring and Assessment Report (305(b) and 303(d)). Water Assessment Team.
NJDEP. www.state.nj.us/dep/wmm/sgwqt/wat/integratedlist/2004report.html
Post, G., G. Buchanan, P. Cohn, J. Klotz, B. Ruppel and A. Stern. 2001. Options for
development of Risk-based fish consumption advisories for PCBs. Report by New Jersey Risk
Assessment Subcommittee of the Interagency Toxics in Biota Committee. October 10, 2001. 4
pp.
Ratcliffe, H.E., G.M. Swanson and L.J. Fischer. 1996. Human exposure to mercury: a critical
assessment of the evidence of adverse health effects. J. Tox. Env. Health. 49:221-270.
Schoeny, R. 1996. Use of genetic toxicology data in U.S.EPA risk assessment: the mercury study
report as an example. Env. Health Perspectives 104, Suppl 3. pp. 663-678.
THE ACADEMY OF NATURAL SCIENCES
17
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Swackhamer, D.L. 1987. Quality Assurance Plan for Green Bay Mass Balance Study - PCBs and
Dieldrin. U.S. Environmental Protection Agency, Great Lakes National Program Office.
United States Environmental Protection Agency (USEPA). 2004. Guidance for assessing
chemical contaminant data for use in fish advisories. Volume 1. Fish sampling and analysis.
Third Edition. www.epa.gov/waterscience/fishadvice/volume1/.
Watanabe, C. and H. Satoh. 1996. Evolution of our understanding of methylmercury as a health
threat. Env. Health Perspectives 104, Suppl 2. pp 367-379.
THE ACADEMY OF NATURAL SCIENCES
18
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Tables 4 - 12
THE ACADEMY OF NATURAL SCIENCES
19
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 4.
Summary of mercury statistics with comparison to previous studies.
Station
Station Name
Hg (µg/g wet weight)
Mean
Min
Max
Total Length (cm)
Mean
Min
Survey
Number
Max
Greenwood Lake
1998
4
0.05
0.05
0.07
15.7
15.0
16.8
Boonton Reservoir
1996
1
0.54
0.54
0.54
40.0
40.0
40.0
Canistear Reservor
Clinton Reservoir
Echo Lake Reservoir
Greenwood Lake
Monksville reservoir
Oradell Reservoir
Oradell Reservoir
Oak Ridge Reservoir
Oak Ridge Reservoir
Passaic River @ Hatfield Swamp
Pompton River @ Pequannock River
Passaic River at Elmwood Park
Rockaway River near Powerville
Rockaway River at Powerville
Ramapo River at Pompton Feeder
Tappan Reservoir
Wanaque Reservoir
Wawayanda Lake
2002
2002
2002
2002
2002
1994
2002
1998
2002
1996
1998
2002
1992
2002
2002
1994
2002
2002
4
4
4
4
2
2
4
1
2
1
1
2
1
3
4
3
4
3
0.16
0.51
0.11
0.08
0.12
0.03
0.04
0.25
0.17
0.11
0.80
0.20
0.15
0.17
0.54
0.07
0.13
0.37
0.12
0.43
0.07
0.06
0.11
0.03
0.03
0.25
0.10
0.11
0.80
0.15
0.15
0.10
0.51
0.04
0.08
0.30
0.19
0.74
0.16
0.11
0.13
0.04
0.05
0.25
0.23
0.11
0.80
0.24
0.15
0.28
0.63
0.14
0.17
0.45
25.6
28.8
24.6
62.4
21.2
18.2
21.6
24.5
25.5
21.4
26.2
24.5
21.2
20.6
24.0
23.8
20.1
28.3
24.0
28.5
22.1
20.9
19.5
16.0
17.6
24.5
23.0
21.4
26.2
20.0
21.2
16.2
22.6
20.3
16.1
26.8
27.2
29.2
27.5
181.7
22.8
20.4
26.5
24.5
28.0
21.4
26.2
29.0
21.2
23.0
26.2
29.3
22.6
30.0
Boonton Reservoir
Lake Dundee
Overpeck Creek
Oradell Reservoir
Oak Ridge Reservoir
Passaic River at Elmwood Park
Rockaway River near Powerville
Shepherds lake
Speedwell Lake
Split Rock Reservoir
Weequahic Lake
1996
1992
2002
1994
1998
1998
1992
2002
1996
2002
2002
2
2
3
1
2
3
1
3
1
2
3
0.02
0.20
0.04
0.03
0.02
0.08
0.12
0.09
0.01
0.04
0.03
0.01
0.19
0.03
0.03
0.02
0.06
0.12
0.06
0.01
0.04
0.03
0.02
0.20
0.04
0.03
0.02
0.11
0.12
0.13
0.01
0.04
0.03
31.7
28.2
22.7
27.4
33.8
25.1
31.0
31.1
21.0
33.9
29.3
30.5
27.1
21.1
27.4
33.0
17.5
31.0
28.3
21.0
29.8
27.3
32.8
29.3
24.6
27.4
34.5
29.4
31.0
35.4
21.0
37.9
31.4
Alewife
GWL
White catfish
BTR
Yellow bullhead
CAN
CL
EL
GWL
MV
ORA
ORA
ORR
ORR
PHS
PPQ
PRE
ROC
RWH
RPF
TAP
WQ
WWL
Brown bullhead
BTR
LDD
OPP
ORA
ORR
PRE
ROC
SH
SPE
SPL
WEE
THE ACADEMY OF NATURAL SCIENCES
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 4.
Cont'd.
STATION Station Name
Hg (µg/g wet weight)
Mean
Min
Max
Total Length (cm)
Mean
Min
Survey
Number
Max
Boonton Reservoir
Clinton Reservoir
Pompton River at Lincoln Park
Pompton River @ Pequannock River
Ramapo River at Pompton Feeder
Rockaway River at Powerville
Shepherds lake
2002
2002
2002
1998
2002
2002
2002
4
3
3
3
3
4
2
0.22
0.34
0.69
0.48
0.37
0.34
0.18
0.13
0.18
0.60
0.43
0.32
0.29
0.15
0.27
0.65
0.83
0.57
0.46
0.41
0.20
21.7
16.5
21.8
20.8
17.2
23.6
17.8
20.5
15.7
21.0
19.2
16.3
22.9
15.0
22.3
17.9
23.4
22.0
17.9
24.2
20.6
Overpeck Creek
Oradell Reservoir
2002
2002
3
3
0.14
0.07
0.12
0.06
0.16
0.08
49.1
70.1
35.7
61.4
63.5
81.1
Clinton Reservoir
2002
3
0.23
0.19
0.25
44.4
43.3
45.4
Branch Brook Park
Overpeck Creek
Oradell Reservoir
Passaic River at Eagle Rock Ave
Pompton River at Lincoln Park
Pompton Lake
Passaic River at Elmwood Park
Passaic River at Pompton
Speedwell Lake
Tappan Reservoir
Weequahic Lake
2002
2002
1994
2002
2002
2002
1998
1998
2002
1994
2002
4
3
3
4
4
4
3
3
4
3
3
0.14
0.10
0.06
0.19
0.34
0.41
0.15
0.34
0.11
0.10
0.08
0.07
0.09
0.04
0.15
0.22
0.23
0.12
0.31
0.05
0.09
0.04
0.19
0.11
0.07
0.23
0.47
0.66
0.19
0.38
0.14
0.12
0.10
64.6
56.8
59.9
55.7
53.9
63.6
54.5
50.9
60.8
53.9
59.2
49.8
50.5
54.9
49.7
49.5
53.6
51.7
50.3
57.4
52.5
50.8
71.8
64.2
64.0
59.5
58.5
75.1
57.6
51.3
63.0
55.3
71.3
Pompton River @ Pequannock River
1998
3
0.06
0.05
0.07
9.3
8.2
9.8
Passaic River at Eagle Rock Ave
Pompton River @ Lincoln Park
2002
1996
2
3
0.18
0.39
0.15
0.17
0.20
0.59
42.8
45.5
41.2
27.8
44.3
66.6
Canistear Reservor
Clinton Reservoir
Echo Lake Reservoir
Green Turtle Lake
Monksville Reservoir
Monksville reservoir
Oak Ridge Reservoir
Pompton River @ Lincoln Park
2002
2002
2002
1996
1992
2002
1998
1996
4
2
3
3
3
3
4
1
0.19
0.52
0.28
0.13
0.57
0.22
0.28
0.23
0.14
0.43
0.20
0.11
0.21
0.15
0.24
0.23
0.25
0.61
0.37
0.15
1.14
0.31
0.30
0.23
41.1
47.5
48.3
39.8
48.6
40.7
35.4
22.7
39.2
44.5
41.7
28.1
39.3
34.9
25.0
22.7
44.0
50.4
60.0
46.6
64.0
49.5
58.0
22.7
Rock bass
BTR
CL
PLP
PPQ
RPF
RWH
SH
American eel
OPP
ORA
White sucker
CL
Common carp
BBP
OPP
ORA
PER
PLP
POMP
PRE
PRP
SPE
TAP
WEE
Creek chubsucker
PPQ
Northern pike
PER
PLP
Chain pickerel
CAN
CL
EL
GTL
MKR
MV
ORR
PLP
THE ACADEMY OF NATURAL SCIENCES
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 4.
Cont'd.
STATION
ROC
SPE
SPL
WAN
WWL
WWL
Channel catfish
PRG
Redbreast sunfish
CL
ORR
PPQ
PRE
PRP
SH
Pumpkinseed
ORR
PHS
PPQ
Bluegill
BBP
CAN
EL
GTL
GWL
GWL
MV
OPP
ORA
ORR
ORR
PHS
POMP
PRE
RL
RWH
RWH
SPE
SPE
Station Name
Rockaway River
Speedwell Lake
Split Rock Reservoir
Wanaque Reservoir
Wawayanda Lake
Wawayanda Lake
Hg (µg/g wet weight)
Mean
Min
0.23
0.15
0.16
0.09
0.30
0.26
0.63
0.33
0.32
0.25
0.32
0.23
Number
5
3
5
2
6
5
Passaic River at Garfield
2002
2
0.27
0.23
0.31
48.7
47.0
50.3
Clinton Reservoir
Oak Ridge Reservoir
Pompton River @ Pequannock River
Passaic River at Elmwood Park
Passaic River at Pompton
Shepherds lake
2002
1998
1998
1998
1998
2002
4
3
2
3
3
3
0.19
0.04
0.37
0.18
0.31
0.19
0.16
0.03
0.32
0.15
0.22
0.18
0.25
0.05
0.41
0.21
0.45
0.20
13.4
10.8
14.8
15.6
15.1
14.9
12.7
10.6
13.7
15.1
14.2
14.0
14.0
11.1
15.8
16.0
16.7
15.5
Oak Ridge Reservoir
Passaic River @ Hatfield Swamp
Pompton River @ Pequannock River
1998
1996
1998
3
2
6
0.03
0.07
0.28
0.02
0.06
0.11
0.05
0.07
0.78
9.7
12.5
11.4
9.3
12.4
9.1
9.9
12.6
14.5
Branch Brook Park
Canistear Reservor
Echo Lake Reservoir
Green Turtle Lake
Greenwood Lake
Greenwood Lake
Monksville reservoir
Overpeck Creek
Oradell Reservoir
Oak Ridge Reservoir
Oak Ridge Reservoir
Passaic River @ Hatfield Swamp
Pompton Lake
Passaic River at Elmwood Park
Ramapo Lake
Rockaway River near Whippany
Rockaway River at Powerville
Speedwell Lake
Speedwell Lake
2002
2002
2002
2002
1996
2002
2002
2002
2002
1998
2002
1996
2002
2002
2002
1996
2002
1996
2002
3
4
4
4
4
4
4
3
3
4
4
1
4
3
4
1
3
2
4
0.18
0.14
0.09
0.22
0.02
0.09
0.12
0.08
0.04
0.04
0.20
0.19
0.26
0.19
0.23
0.12
0.12
0.12
0.12
0.15
0.10
0.06
0.07
0.01
0.07
0.08
0.07
0.03
0.03
0.11
0.19
0.17
0.12
0.19
0.12
0.11
0.12
0.10
0.24
0.23
0.11
0.58
0.03
0.13
0.17
0.09
0.05
0.05
0.28
0.19
0.47
0.24
0.28
0.12
0.13
0.13
0.16
15.4
20.1
17.4
17.9
13.3
18.2
18.2
15.5
16.8
9.5
18.6
18.9
17.5
17.0
18.9
14.5
15.3
19.0
16.9
14.8
18.2
16.1
16.9
13.0
18.0
16.8
15.0
14.9
9.0
17.1
18.9
16.4
16.1
17.3
14.5
15.0
18.3
15.0
16.0
21.7
19.0
19.3
13.6
18.6
19.8
16.3
19.0
10.4
19.9
18.9
18.2
18.1
21.0
14.5
15.5
19.7
19.6
THE ACADEMY OF NATURAL SCIENCES
Max
0.31
0.26
0.32
0.93
0.44
0.50
Total Length (cm)
Mean
Min
37.8
30.6
36.5
24.8
52.8
45.6
47.1
38.7
39.6
35.0
31.5
25.7
Survey
1992
2002
2002
1992
1996
2002
Max
44.7
55.6
60.0
55.5
42.4
43.7
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 4.
Cont'd.
STATION
SPL
TAP
WEE
WQ
WWL
Smallmouth bass
BTR
ORR
PPQ
RPF
TAP
TAP
WAN
Largemouth bass
BBP
BTR
BTR
CAN
CAN
CLI
EL
EL
GPC
GTL
GTL
GWL
GWL
LDD
MKR
MV
OPP
ORA
ORA
ORR
ORR
PER
PHS
PLP
PLP
Survey
Number
Station Name
Split Rock Reservoir
Lake Tappan
Weequahic Lake
Wanaque Reservoir
Wawayanda Lake
2002
2002
2002
2002
2002
4
4
3
4
3
Boonton Reservoir
Oak Ridge Reservoir
Pompton River @ Pequannock River
Ramapo River at Pompton Feeder
Tappan Reservoir
Lake Tappan
Wanaque Reservoir
2002
1998
1998
2002
1994
2002
1992
4
1
4
3
4
3
2
0.51
0.49
0.96
0.75
0.07
0.29
0.43
0.39
0.49
0.57
0.65
0.04
0.06
0.34
0.75
0.49
1.14
0.91
0.10
0.43
0.51
41.5
40.2
29.9
29.7
30.7
43.9
32.7
36.3
40.2
25.4
25.3
24.4
27.6
27.5
47.2
40.2
36.8
35.1
35.4
58.1
37.9
Branch Brook Park
Boonton Reservoir
Boonton Reservoir
Canistear Reservoir
Canistear Reservor
Clinton Reservoir
Echo Lake
Echo Lake
Passaic River Great Piece
Green Turtle Lake
Green Turtle Lake
Greenwood Lake
Greenwood Lake
Lake Dundee
Monksville Reservoir
Monksville reservoir
Overpeck Creek
Oradell Reservoir
Oradell Reservoir
Oak Ridge Reservoir
Oak Ridge Reservoir
Passaic River at Eagle Rock Ave
Passaic River @ Hatfield Swamp
Pompton River at Lincoln Park
Pompton River at Lincoln Park
2002
1996
2002
1992
2002
1992
1996
2002
1992
1996
2002
1998
2002
1992
1992
2002
2002
1994
2002
1998
2002
2002
1996
1996
2002
4
3
5
7
4
6
4
4
6
3
5
5
5
5
3
5
3
9
4
4
4
2
3
2
3
0.74
0.58
0.71
0.60
0.46
0.71
0.15
0.64
0.52
0.24
0.38
0.18
0.29
0.44
0.66
0.24
0.12
0.21
0.33
0.65
0.79
0.40
0.31
0.59
0.53
0.56
0.33
0.36
0.41
0.29
0.39
0.12
0.43
0.19
0.17
0.20
0.11
0.21
0.27
0.45
0.13
0.09
0.03
0.20
0.38
0.65
0.27
0.17
0.50
0.35
0.99
0.81
1.08
0.74
0.67
0.85
0.17
0.79
0.66
0.32
0.74
0.32
0.31
0.62
1.00
0.39
0.14
0.46
0.51
0.89
0.90
0.54
0.53
0.68
0.74
43.8
40.6
46.4
40.8
44.1
35.7
32.2
46.7
32.9
28.1
38.0
35.6
40.7
34.1
33.7
32.9
38.6
40.8
46.9
43.8
41.5
34.0
27.5
35.5
36.4
40.2
35.0
40.9
36.0
40.0
28.2
29.0
43.7
29.4
23.6
31.4
31.4
38.3
31.1
28.7
26.4
36.0
28.9
45.0
36.8
40.3
29.7
23.0
35.4
34.3
46.5
45.1
52.0
45.7
50.0
44.1
35.0
49.6
34.5
34.7
49.4
40.0
42.3
36.0
38.4
43.0
40.5
51.0
48.3
48.0
44.0
38.2
36.0
35.5
39.4
THE ACADEMY OF NATURAL SCIENCES
Hg (µg/g wet weight)
Mean
Min
0.14
0.10
0.07
0.05
0.12
0.09
0.28
0.22
0.19
0.14
Max
0.21
0.09
0.15
0.41
0.21
Total Length (cm)
Mean
Min
21.6
21.0
14.2
11.9
17.1
16.3
20.0
19.3
17.7
17.0
Max
22.1
15.3
17.5
21.0
18.3
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 4.
Cont'd.
Survey
STATION
POM
POMP
PPQ
PRDL
PRE
PRE
PRP
RL
ROC
RPF
RWH
SH
SPE
SPL
TAP
TAP
WAN
WQ
WEE
WWL
White perch
GWL
ORA
TAP
WEE
Striped bass
AOC
AOS
PRG
Golden shiner
ORR
Rainbow trout
ROC
Yellow perch
CAN
GTL
MV
ORA
ORR
PLP
SPL
TAP
Number
Hg (µg/g wet weight)
Mean
Min
0.45
0.22
0.86
0.45
1.17
0.99
0.20
0.15
0.47
0.22
0.22
0.17
0.41
0.35
0.50
0.29
0.56
0.36
0.89
0.44
0.92
0.92
0.66
0.56
0.28
0.10
0.40
0.32
0.36
0.02
0.21
0.05
0.85
0.40
0.83
0.23
0.28
0.20
0.56
0.29
1992
2002
1998
2002
1998
2002
1998
2002
1992
2002
1996
2002
1996
2002
1994
2002
1992
2002
2002
2002
9
5
2
5
3
3
3
4
3
3
1
5
3
5
9
5
6
5
4
5
Greenwood Lake
Oradell Reservoir
Tappan Reservoir
Weequahic Lake
1996
1994
1994
2002
4
3
3
3
0.00
0.12
0.09
0.09
-0.01
0.08
0.04
0.08
0.00
0.19
0.13
0.10
18.2
19.7
16.4
18.0
17.2
17.3
16.0
17.7
19.2
24.3
17.1
18.1
Atlantic Ocean, Asbury Park to Atlantic City
Atlantic Ocean, Atlantic City to Cape May
Passaic River at Garfield
1998
1998
2002
5
4
4
0.42
0.69
0.51
0.26
0.56
0.33
0.77
0.78
0.66
76.5
90.7
52.3
68.7
81.4
48.8
88.2
100.5
56.6
Oak Ridge Reservoir
1998
2
0.02
-0.03
0.06
13.9
9.6
18.1
Rockaway River
1992
1
0.04
0.04
0.04
53.6
53.6
53.6
Canistear Reservor
Green Turtle Lake
Monksville reservoir
Oradell Reservoir
Oak Ridge Reservoir
Pompton River @ Lincoln Park
Split Rock Reservoir
Tappan Reservoir
2002
1996
2002
1994
1998
1996
2002
1994
3
2
2
3
2
2
4
3
0.23
0.09
0.17
0.11
0.04
0.23
0.18
0.04
0.18
0.09
0.17
0.06
0.04
0.21
0.10
0.02
0.29
0.10
0.17
0.19
0.04
0.26
0.34
0.07
28.3
22.7
30.9
20.7
17.5
22.5
28.2
22.4
24.3
20.8
27.5
19.5
16.7
21.0
25.4
18.5
34.4
24.6
34.2
22.1
18.3
24.0
29.8
26.3
THE ACADEMY OF NATURAL SCIENCES
Max
0.94
1.30
1.36
0.35
0.63
0.24
0.52
1.05
0.73
1.19
0.92
0.76
0.38
0.52
0.72
0.31
1.18
1.47
0.39
0.78
Total Length (cm)
Mean
Min
35.6
30.1
41.0
31.7
39.4
39.0
29.7
25.1
39.1
34.0
31.8
27.2
30.8
27.9
35.8
29.4
28.9
26.4
29.6
25.4
39.8
39.8
38.5
35.5
32.0
27.5
36.8
34.2
41.1
25.8
40.7
26.7
39.7
32.8
40.3
28.5
40.2
33.3
39.6
32.9
Station Name
Pompton Lake
Pompton Lake
Pompton River @ Pequannock River
Passaic River at Dundee Lake
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Pompton
Ramapo Lake
Rockaway River
Ramapo River at Pompton Feeder
Rockaway River near Whippany
Shepherds lake
Speedwell Lake
Split Rock Reservoir
Lake Tappan
Lake Tappan
Wanaque Reservoir
Wanaque Reservoir
Weequahic Lake
Wawayanda Lake
Max
45.8
52.3
39.8
37.5
44.0
34.6
34.6
47.3
31.5
33.8
39.8
40.5
36.1
39.4
50.5
47.7
46.4
47.2
47.5
45.1
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 4.
Cont'd.
Survey
STATION
Black crappie
PER
PHS
PLP
PPQ
RWH
Walleye
GWL
MV
Number
Station Name
Hg (µg/g wet weight)
Mean
Min
Max
Total Length (cm)
Mean
Min
Max
Passaic River at Eagle Rock Ave
Passaic River @ Hatfield Swamp
Pompton River at Lincoln Park
Pompton River @ Pequannock River
Rockaway River near Whippany
2002
1996
2002
1998
1996
4
4
3
1
1
0.16
0.23
0.21
0.24
0.21
0.12
0.21
0.15
0.24
0.21
0.25
0.26
0.29
0.24
0.21
19.2
19.3
19.7
19.3
17.9
16.2
18.1
17.6
19.3
17.9
25.2
20.0
21.0
19.3
17.9
Greenwood Lake
Monksville reservoir
2002
2002
5
5
0.30
0.51
0.18
0.35
0.47
0.78
55.7
51.6
49.0
43.0
61.1
59.4
THE ACADEMY OF NATURAL SCIENCES
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 5. Summary of PCB statistics with comparison to previous studies.
Station Name
Yellow bullhead
Passaic River at Elmwood Park
Ramapo River at Pompton Feeder
Brown bullhead
Passaic River at Elmwood Park
American eel
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Dundee Lake
Passaic River at Garfield
Overpeck Creek
Navesink River
Raritan Bay at Rt. 1
Shrewsbury River
Shark River
White sucker
Passaic River at Garfield
Common carp
Branch Brook Park
Overpeck Creek
Weequahic Lake
Passaic River at Eagle Rock Ave
Pompton River at Lincoln Park
Pompton Lake
Passaic River at Pompton
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Dundee Lake
Passaic River at Garfield
Passaic River at Lyndhurst
Total PCBs (ng/g wet weight)
Station Survey Number Mean Minimum Maximum
Total PCBs/
%Lipid
% Lipid
Total Length (cm)
Mean Minimum Maximum
PRE
RPF
2002
2002
2
3
37.8
BDL*
36.5
BDL
39.1
34.3
5201
6864
0.7
0.3
24.5
24.3
20.0
22.6
29.0
26.2
PRE
1998
3
109.7
26.0
260.2
4985
2.2
25.1
17.5
29.4
PRE
PRE
PRDL
PRG
OPP
NVR
RBM
SBR
SKR
2002
1998
2002
2002
2002
1998
1998
1998
1998
3
206.3
4
539.9
5
312.1
3
229.8
3
789.4
3
218.3
4 1468.8
7
241.2
6
458.7
184.1
183.5
182.3
88.1
326.1
112.3
377.4
131.1
BDL
223.4
730.3
492.8
445.3
1589.6
275.0
2308.3
547.8
1303.9
10967
15177
5250
19666
78023
5617
14384
4916
6887
2.1
5.0
7.8
1.9
4.1
4.1
11.1
7.3
9.2
53.8
50.4
49.7
55.5
49.1
41.0
42.6
54.2
57.3
47.2
40.2
34.5
48.7
35.7
35.6
28.8
39.8
39.3
58.1
60.6
61.5
68.7
63.5
47.1
49.0
64.8
78.3
PRG
2002
3
189.6
124.0
277.3
16237
1.3
43.3
40.6
46.5
BBP
OPP
WEE
PER
PLP
POMP
PRP
PRE
PRE
PRDL
PRG
PRL
2002
2002
2002
2002
2002
2002
1998
2002
1998
2002
2002
2002
3
338.9
3
483.4
3
265.0
3
326.8
3
591.2
3
323.9
4
911.8
4
350.5
6 1020.8
5
374.0
3
662.1
7
901.5
229.1
224.5
154.6
146.8
228.1
128.5
774.5
144.7
309.4
320.6
327.4
622.2
405.9
766.1
386.1
419.5
1192.8
703.5
969.3
610.4
2237.6
440.2
1148.4
1260.1
5683
30226
4951
10297
11409
7102
13701
11608
26843
8076
19459
19792
5.9
1.6
5.6
3.3
4.7
4.0
6.8
2.9
4.0
5.1
3.3
4.9
69.6
58.9
59.2
57.7
55.2
66.9
50.6
54.6
53.4
56.7
60.9
52.9
68.0
52.0
50.8
56.0
49.5
59.1
49.6
51.0
48.7
53.2
59.5
48.2
71.8
64.2
71.3
59.5
58.5
75.1
51.3
62.8
57.6
62.4
62.4
57.0
*BDL Below detection limitof 24ng/g wet weight
THE ACADEMY OF NATURAL SCIENCES
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 5. Cont'd.
Station Name
Northern pike
Passaic River at Eagle Rock Ave
Channel catfish
Passaic River at Garfield
Redbreast sunfish
Passaic River at Elmwood Park
Passaic River at Pompton
Bluegill
Passaic River at Elmwood Park
Weequahic Lake
Smallmouth bass
Boonton Reservoir
Ramapo River at Pompton Feeder
Largemouth bass
Branch Brook Park
Overpeck Creek
Weequahic Lake
Boonton Reservoir
Ramapo River at Pompton Feeder
Pompton Lake
Pompton River at Lincoln Park
Passaic River at Pompton
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Dundee Lake
Passaic River at Eagle Rock Ave
Striped bass
Passaic River at Garfield
Atlantic Ocean, Asbury Park to Atlantic City
Atlantic Ocean, North of Asbury Park
Atlantic Ocean, Atlantic City to Cape May
Raritan Bay upper
THE ACADEMY OF NATURAL SCIENCES
Total PCBs (ng/g wet weight)
Station Survey Number Mean Minimum Maximum
Total PCBs/
%Lipid
% Lipid
Total Length (cm)
Mean Minimum Maximum
PER
2002
2
59.1
45.9
72.3
17335
0.3
42.8
41.2
44.3
PRG
2002
2
334.4
265.6
403.2
11176
3.1
48.7
47.0
50.3
PRE
PRP
1998
1998
3
3
60.6
54.0
50.2
45.8
66.3
63.3
12078
13300
5.8
0.5
15.6
15.1
15.1
14.2
16.0
16.7
PRE
WEE
2002
2002
3
3
275.8
BDL
23.0
BDL
740.9
24.1
61546
2523
0.6
0.8
17.0
17.1
16.1
16.3
18.1
17.5
BTR
RPF
2002
2002
2
3
503.0
48.9
384.1
BDL
621.8
96.4
13947
6015
3.6
0.9
44.6
29.7
42.0
25.3
47.2
35.1
BBP
OPP
WEE
BTR
RPF
POMP
PLP
PRP
PRE
PRE
PRDL
PER
2002
2002
2002
2002
2002
2002
2002
1998
2002
1998
2002
2002
3
3
3
3
3
3
3
3
3
3
5
2
98.5
481.2
118.6
561.0
81.2
64.2
60.3
71.0
75.1
172.4
65.1
40.9
65.3
346.4
64.7
209.4
47.1
34.2
BDL
51.1
70.7
119.2
51.1
35.4
128.4
706.5
179.8
1018.4
144.1
93.1
112.2
108.6
82.4
248.7
97.4
46.3
6769
34888
8296
30520
9673
10873
7443
15607
9077
20324
8666
7326
1.5
1.4
1.4
2.0
0.8
0.6
0.7
0.5
0.8
0.8
0.8
0.7
45.0
38.6
42.5
49.1
29.6
46.1
36.4
30.8
31.8
39.1
29.7
34.0
43.7
36.0
35.6
47.6
25.4
37.4
34.3
27.9
27.2
34.0
25.1
29.7
46.5
40.5
47.5
52.0
33.8
52.3
39.4
34.6
34.6
44.0
37.5
38.2
PRG
AOC
AON
AOS
RBU
2002
1998
1998
1998
1998
4
7
9
6
5
475.2
305.1
461.5
481.2
430.4
308.7
85.6
227.3
179.8
139.1
563.6
824.6
863.9
1091.5
819.0
46624
19605
17460
17788
33187
1.3
1.9
3.9
3.5
2.3
52.3
74.6
79.3
97.2
69.0
48.8
68.4
73.0
81.4
59.5
56.6
88.2
91.5
125.8
76.6
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 6. Summary of DDX, chlordanes, aldrin and dieldrin (all ng/g wet weight) analyzed in the 2002 Monitoring program.
Data are based on using one-half the detection limit for component compounds less than the detection limit.
Total DDX
Total chlordanes
Aldrin+Dieldrin
Station Name
Common Name
Mean Minimum Maximum Mean Minimum Maximum Mean Minimum Maximum
Booton Reservoir
largemouth bass
148
45
270
44
16
80
1.9
0.6
2.7
smallmouth bass
109
108
110
46
37
55
2.8
2.1
3.5
Branch Brook Park
common carp
956
700
1280
28
19
35
0.4
0.3
0.4
largemouth bass
311
196
398
9
6
11
0.5
0.4
0.7
Overpeck Creek
American eel
299
70
659
180
34
444
7.9
0.4
22.6
common carp
130
42
249
86
28
181
2.0
0.5
4.5
largemouth bass
139
78
204
99
51
140
2.6
1.2
3.7
Ramapo River at Pompton Feeder
largemouth bass
15
5
30
7
6
8
0.4
0.2
0.7
smallmouth bass
4
2
5
5
3
7
0.2
0.2
0.18
5
4
8
4
2
5
yellow bullhead
Pompton Lake
common carp
104
42
220
71
36
131
1.1
0.9
1.4
largemouth bass
17
10
23
10
7
12
0.4
0.4
0.4
Pompton River at Lincoln Park
common carp
209
87
429
106
52
214
2.6
1.2
4.9
largemouth bass
23
7
49
13
4
25
0.8
0.5
1.2
Passaic River at Hanover
common carp
393
172
528
195
84
290
4.2
1.8
6.5
largemouth bass
35
33
36
18
13
23
0.8
0.8
0.8
northern pike
37
26
47
21
16
26
0.5
0.4
0.6
Passaic River at Lyndhurst
common carp
196
128
278
150
104
215
15.0
8.9
26.3
Passaic River at Elmwood Park
American eel
77
66
86
75
55
88
11.1
7.8
14.9
bluegill
13
4
21
21
5
44
1.7
1.7
1.7
common carp
65
33
103
71
37
102
7.3
3.9
12.5
largemouth bass
19
19
19
20
18
21
1.9
1.5
2.2
8
7
9
13
11
15
0.4
0.3
0.5
yellow bullhead
THE ACADEMY OF NATURAL SCIENCES
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 6. Cont'd.
Station Name
Total DDX
Total chlordanes
Aldrin+Dieldrin
Common Name
Mean Minimum Maximum Mean Minimum Maximum Mean Minimum Maximum
Passaic River at Dundee Lake
American eel
130
76
241
149
73
261
36.8
11.1
63.6
common carp
88
73
101
109
88
139
11.8
5.3
15.9
largemouth bass
12
11
16
18
15
22
2.5
1.6
4.1
Passaic River at Garfield
American eel
88
35
181
79
32
172
10.5
1.7
26.9
channel catfish
108
100
116
89
88
90
11.2
8.6
13.8
common carp
145
65
219
104
43
137
7.8
4.5
11.1
striped bass
127
105
174
64
34
79
5.9
5.0
7.1
white sucker
60
35
78
68
37
110
7.8
3.9
14.5
Weequahic Lake
bluegill
7
5
10
2
1
3
common carp
234
98
421
38
22
51
0.6
0.3
0.9
largemouth bass
58
32
88
9
4
13
0.2
0.2
0.2
THE ACADEMY OF NATURAL SCIENCES
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 7. Summary of selected OCPs (endosulfan, BHC and heptachlor) analyzed in the 2002
Monitoring program. Data are based on using one-half the detection limit for component compounds
less than the detection limit. All data are ng/g wet weight.
Total endosulfan
Total BHC
Heptachlor
Station Name
Common Name
Mean Minimum Maximum Mean Maximum Mean Maximum
Boonton Reservoir
largemouth bass
1.2
0.6
1.8
0.5
0.6
0.2
0.3
smallmouth bass
1.4
1.3
1.5
0.8
0.9
0.2
0.3
Branch Brook Park
common carp
3.3
2.1
4.0
0.4
0.5
0.8
1.1
largemouth bass
1.1
0.9
1.5
0.4
0.4
0.1
0.2
Overpeck Creek
American eel
1.7
1.7
1.7
0.4
0.5
2.0
4.5
common carp
0.6
0.6
0.6
0.5
0.5
8.6
16.7
largemouth bass
1.5
0.9
1.9
0.5
0.5
12.3
17.7
Ramapo River at Pompton Feeder
largemouth bass
0.6
0.2
0.9
0.6
0.7
0.1
0.3
smallmouth bass
0.2
0.2
0.3
0.7
0.8
0.1
0.1
yellow bullhead
0.3
0.3
0.4
0.5
0.5
0.1
0.2
Pompton Lake
common carp
2.8
1.3
5.1
0.5
0.7
0.7
1.4
largemouth bass
1.2
1.0
1.4
0.4
0.4
0.1
0.1
Pompton River at Lincoln Park
common carp
4.2
2.0
8.3
0.8
0.8
2.8
5.4
largemouth bass
0.7
0.5
1.1
0.8
1.1
0.4
1.0
Passaic River at Hanover
common carp
14.1
5.3
24.9
0.9
1.4
2.5
3.8
largemouth bass
4.5
4.5
4.6
0.7
0.9
0.2
0.4
northern pike
4.7
3.7
5.6
0.3
0.3
Passaic River at Lyndhurst
common carp
4.2
2.1
7.1
3.8
5.9
14.3
23.4
Passaic River at Elmwood Park
American eel
5.2
3.6
6.7
1.9
2.7
0.5
0.8
bluegill
2.5
1.3
4.7
0.4
0.4
0.2
0.4
common carp
6.1
3.5
10.2
4.0
5.7
1.2
1.6
largemouth bass
3.7
3.0
4.0
2.3
3.1
0.4
0.4
yellow bullhead
1.3
1.3
1.3
0.2
0.2
Passaic River at Dundee Lake
American eel
12.2
7.3
15.4
2.2
3.0
1.9
2.8
common carp
6.8
2.8
9.2
1.2
1.6
8.6
13.4
largemouth bass
1.6
1.2
2.2
0.6
0.9
1.2
1.8
Passaic River at Garfield
American eel
4.3
1.4
9.6
1.0
1.5
0.5
1.1
channel catfish
5.0
4.0
5.9
1.1
1.2
1.8
2.2
common carp
2.4
2.4
2.4
0.4
0.4
6.5
11.3
striped bass
3.4
2.4
4.8
0.4
0.4
6.5
7.9
white sucker
8.3
3.3
17.3
0.4
0.4
3.2
4.2
Weequahic Lake
bluegill
0.2
0.2
0.2
0.4
0.4
0.1
0.1
common carp
0.5
0.5
0.8
0.9
largemouth bass
0.5
0.5
0.1
0.2
Table 8. Summary of Furan and Dioxin concentrations from species collected from the Passiac
River at Garfield and Dundee Lake.
Total
Total
Total
Total
Dioxins
Furans
Dioxins
Fish # LTL (cm) % solid % Lipid Furans
(pg/g dry weight)
(pg/g wet weight)
Station
Common Name
Passaic River at Dundee Lake
American eel
F-2484
34.5
F-2485
45.3
F-2486
56.0
F-2482
51.0
F-2487
61.5
Mean
49.7
% Detect
common carp
F-2481
58.2
F-2480
55.0
F-2479
54.7
F-2478
53.2
F-2483
62.4
Mean
56.7
% Detect
largemouth bass
F-2475
37.5
F-2476
25.1
F-2477
30.8
F-2474
26.6
F-2473
28.5
Mean
29.7
% Detect
Passaic River at Garfield
American eel
F-2500
49.0
F-2499
48.7
F-2501
68.7
Mean
55.5
% Detect
white sucker
F-2496
46.5
F-2502
42.9
F-2494
40.6
Mean
43.3
% Detect
30.8
23.8
22.1
29.5
30.5
27.3
43.6
18.9
11.3
32.8
31.6
27.6
1.5
0.0
0.0
0.0
0.0
0.3
0.20
0.0
0.0
0.0
9.2
0.0
1.8
0.20
4.2
0.0
0.0
0.0
0.0
0.8
0.20
0.0
0.0
0.0
25.9
0.0
5.2
0.20
26.5
26.2
22.1
15.0
25.7
23.1
19.9
24.2
9.8
19.0
20.7
18.7
0.0
0.0
0.0
1.5
3.0
0.9
0.60
17.9
23.2
15.0
23.2
0.0
15.9
0.80
0.0
0.0
0.0
8.3
9.8
3.6
0.60
56.3
73.6
56.8
128.6
0.0
63.1
0.80
19.0
22.8
22.7
21.5
22.4
21.7
1.7
1.7
2.4
2.1
1.9
2.0
0.0
0.7
1.4
2.8
3.4
1.7
0.80
0.0
4.6
0.0
0.9
3.3
1.7
0.60
0.0
2.4
5.3
10.7
12.8
6.2
0.80
0.0
16.9
0.0
3.3
12.1
6.5
0.60
20.4
22.0
24.1
22.2
5.2
5.5
18.7
9.8
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
15.0
20.3
19.8
18.4
9.4
6.0
5.6
7.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
3.1
1.0
0.33
0.0
0.0
0.0
0.0
0.0
0.0
0.0
13.2
4.4
0.33
Table 8. Cont'd
Fish #
LTL (cm) % solid % Lipid
Total
Total
Furans
Dioxins
(pg/g dry weight)
Total
Total
Furans
Dioxins
(pg/g wet weight)
Station
Common Name
Passaic River at Garfield
common carp
F-2498
62.4
F-2497
59.5
F-2495
60.8
Mean
60.9
% Detect
channel catfish
F-2492
50.3
F-2493
47.0
Mean
48.7
% Detect
striped bass
F-2491
54.6
F-2489
56.6
F-2490
48.8
F-2488
49.0
Mean
52.3
% Detect
22.8
23.6
22.5
23.0
15.9
17.6
10.1
14.5
0.0
0.0
0.0
0.0
0.0
0.0
24.0
0.0
8.0
0.33
0.0
0.0
0.0
0.0
0.0
0.0
84.9
0.0
28.3
0.33
22.6
21.8
22.2
12.7
16.0
14.3
1.1
14.5
7.8
1.0
1.4
8.8
5.1
1.0
3.9
55.6
29.8
1.0
5.3
33.8
19.5
1.0
19.9
21.6
21.7
26.2
22.4
4.6
2.4
2.8
7.8
4.4
7.5
0.0
16.9
0.0
6.1
0.50
93.2
0.0
48.1
3.1
36.1
0.75
31.4
0.0
64.8
0.0
24.0
0.50
389.6
0.0
184.9
9.8
146.1
0.75
Table 9. DDX (sum of p,p' DDT, p,p' DDE and p,p' DDD). Comparison of NJDEP 1986-7 data and ANSP 1998-9 data. 1998-9 and 2002 data use onehalf the detection limit for component compunds less than the detection limit. For 2000 data, means are averages of site means, and # spec. @ # sites
indicates the total number of specimens and the number of sites.
1986-7
Scientific
KRRegion
Region
Ameiurus nebulosus
Ameiurus nebulosus
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Cyprinus carpio
Cyprinus carpio
Micropterus salmoides
Micropterus salmoides
Morone americana
Morone saxatilis
Morone saxatilis
Morone saxatilis
Pomatomus saltatrix
Pomatomus saltatrix
Pomatomus saltatrix
Camden
Northeast
Camden
Delaware
Northeast
Camden
Northeast
Camden
Northeast
Northeast
North Coast
Northeast
South Coast
North Coast
Northeast
South Coast
Camden
Raritan-Passaic
Camden
Delaware River and tribs
Raritan-Passaic
Camden
Raritan-Passaic
Camden
Raritan-Passaic
Raritan-Passaic
Atlantic Ocean north
Raritan-Passaic
Atlantic Ocean south
Atlantic Ocean north
Raritan-Passaic
Atlantic Ocean south
1998-9
2002
Mean
ng/g wet
#
Mean
ng/g wet
#
177
193
1300
412
261
540
425
74
30
193
194
189
193
104
102
96
8
2
7
9
10
13
4
5
1
6
10
16
5
24
11
29
33
19
373
554
361
666
179
163
17
263
100
72
135
91
76
118
19
3
1
25
8
30
10
15
6
8
9
5
6
9
10
8
Mean
ng/g wet
# spec. @
# sites
148
38@4
252
47@10
78
37@10
127
4@1
Table 10. Comparison of Chlordane (sum of cis- and trans-) concentrations in NJ monitoring surveys. All sites in the 2002 study
are treated as part of the Northeast.
1986-7
Scientific
KRRegion
Mean
1988-1991
#
(ng/g wet
weight)
Mean
#
(ng/g wet
weight)
1998-9
Mean
SD
2002
#
(ng/g wet weight)
Mean
SD
1986-7
#
1998-9
Prop>300 Prop>300 Prop>300
(ng/g wet weight)
Ameiurus nebulosus
Camden
124
8
102
8
15
12
38
0.13
0
Ameiurus nebulosus
Northeast
73
2
53
1
15
18
6
0
0
Anguilla rostrata
Camden
630
7
15
1
0.57
0
Anguilla rostrata
Delaware
62
9
18
18
25
0
0
Anguilla rostrata
Northeast
73
10
63
44
8
0
0
Cyprinus carpio
Camden
260
13
275
1
111
80
60
0.31
0.017
Cyprinus carpio
Northeast
334
4
149
1
55
32
20
0
0
Micropterus salmoides Camden
21
5
48
2
19
21
30
0
0
Micropterus salmoides Northeast
13
1
6
5
6
0
0
Morone americana
Northeast
North
Coast
64
6
44
13
8
0
0
61
10
8
4
9
0
0
Northeast
South
Coast
North
Coast
50
16
14
15
5
0
0
64
5
9
8
5
0
0
37
24
7
4
9
0
0
Northeast
South
Coast
30
11
8
5
10
0
0
33
29
10
9
8
0
0
Morone saxatilis
Morone saxatilis
Morone saxatilis
Pomatomus saltatrix
Pomatomus saltatrix
Pomatomus saltatrix
THE ACADEMY OF NATURAL SCIENCES
2002
32
51
7
3
45
37
10
1
14
36
31
4
0
0
0
0
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 11. Individual fish exceeding stated criteria. Data are based on sums with component compounds below detection limit treated as 0.
No fish were caught which exceeded the criteria for aldrin & dieldrin (300 ng/g) or heptachlor (300 ng/g). All concentrations are on a wet
weight basis.
Station Name
Station
Common Name
Fish Anal #
LTL
% Lipid
(cm)
Hg
(µg/g)
Total
PCBs
(ng/g)
>1000
Boonton Reservoir
BTR
largemouth bass
F-2374
47.6
1.68
Overpeck Creek
OPP
American eel
F-2048
63.5
11.06
1590
Pompton River at
Lincoln Park
PLP
common carp
F-2418
58.5
8.07
1193
Passaic River at
Garfield
PRG
common carp
F-2498
62.4
3.74
1148
Passaic River at
Lyndhurst
1260
1.08
Total DDX
Chlordane
(ng/g)
>5000
(ng/g)
>300
1018
PRL
common carp
F-2522
56.5
5.11
Passaic River at Eagle
Rock Ave
PER
common carp
F-2426
57.6
3.85
528
Branch Brook Park
BBP
common carp
F-2037
68
6.54
1280
Branch Brook Park
BBP
common carp
F-2039
71.8
6.79
888
Branch Brook Park
BBP
common carp
F-2040
68.9
4.37
700
Overpeck Creek
OPP
American eel
F-2048
63.5
11.06
659
Wanaque Reservoir
WQ
largemouth bass
F-2631
47.2
1.47
Wanaque Reservoir
WQ
largemouth bass
F-2634
47
1.15
Wanaque Reservoir
WQ
largemouth bass
F-2336
44.8
1.03
Ramapo River at
Pompton Feeder
RPF
largemouth bass
F-2403
29.5
1.02
Ramapo River at
Pompton Feeder
RPF
largemouth bass
F-2408
33.8
1.19
Pompton Lake
POMP
largemouth bass
F-2424
52.3
1.24
Pompton Lake
POMP
largemouth bass
F-2425
48.5
1.30
Ramapo Lake
RL
largemouth bass
F-2569
47.3
1.05
371
Table 12. Proportion of fish at stations with mercury concentrations in different classes with respect to NJ consumption advisories.
Station
Species
Branch Brook Park
bluegill
common carp
largemouth bass
Boonton Reservoir
largemouth bass
rock bass
smallmouth bass
Canistear Reservor
bluegill
chain pickerel
largemouth bass
yellow bullhead
yellow perch
Clinton Reservoir
chain pickerel
redbreast sunfish
rock bass
white sucker
yellow bullhead
Echo Lake
bluegill
chain pickerel
largemouth bass
yellow bullhead
THE ACADEMY OF NATURAL SCIENCES
High Risk Population
Low Risk Population
Total # No restr. 1/week 1/month Do not eat No restr. 1/week 1/month Do not eat
<0.07
0.07-0.18 0.19-0.54
>0.54
<0.34 0.35-0.93 0.94-2.81
>2.81
3
4
4
0
0
0
0.67
0.5
0
0.33
0.5
0
0
0
1
1
1
0
0
0
0.75
0
0
0.25
0
0
0
5
4
4
0
0
0
0
0.25
0
0.2
0.75
0.75
0.8
0
0.25
0
1
0
0.8
0
1
0.2
0
0
0
0
0
4
4
4
4
3
0
0
0
0
0
0.75
0.5
0
0.75
0.33
0.25
0.5
0.75
0.25
0.67
0
0
0.25
0
0
1
1
0.25
1
1
0
0
0.75
0
0
0
0
0
0
0
0
0
0
0
0
2
4
3
3
4
0
0
0
0
0
0
0.5
0.33
0
0
0.5
0.5
0.33
1
0.75
0.5
0
0.33
0
0.25
0
1
0.67
1
0
1
0
0.33
0
1
0
0
0
0
0
0
0
0
0
0
4
3
4
4
0.25
0
0
0
0.75
0
0
1
0
1
0.25
0
0
0
0.75
0
1
0.67
0
1
0
0.33
1
0
0
0
0
0
0
0
0
0
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
High Risk Population
Table 12. Cont'd
Station
Species
Green Turtle Lake
bluegill
largemouth bass
Greenwood Lake
bluegill
largemouth bass
walleye
yellow bullhead
Monksville reservoir
bluegill
chain pickerel
largemouth bass
walleye
yellow bullhead
yellow perch
Overpeck Creek
American eel
bluegill
brown bullhead
common carp
largemouth bass
Oradell Reservoir
American eel
bluegill
largemouth bass
yellow bullhead
THE ACADEMY OF NATURAL SCIENCES
Total # No restr.
<0.07
1/week
Low Risk Population
1/month Do not eat No restr.
0.07-0.18 0.19-0.54
>0.54
<0.34
1/week
1/month Do not eat
0.35-0.93 0.94-2.81
>2.81
4
5
0
0
0.75
0
0
0.8
0.25
0.2
0.75
0.6
0.25
0.4
0
0
0
0
4
5
5
4
0.25
0
0
0.25
0.75
0
0.2
0.75
0
1
0.8
0
0
0
0
0
1
1
0.8
1
0
0
0.2
0
0
0
0
0
0
0
0
0
4
3
5
5
2
2
0
0
0
0
0
0
1
0.33
0.4
0
1
1
0
0.67
0.6
0.6
0
0
0
0
0
0.4
0
0
1
1
0.8
0
1
1
0
0
0.2
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
3
3
3
3
0
0.33
1
0
0
1
0.67
0
1
1
0
0
0
0
0
0
0
0
0
0
1
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
3
4
4
0.67
1
0
1
0.33
0
0
0
0
0
1
0
0
0
0
0
1
1
0.75
1
0
0
0.25
0
0
0
0
0
0
0
0
0
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 12. Cont'd
Station
Species
Oak Ridge Reservoir
bluegill
largemouth bass
yellow bullhead
Passaic River at Hanover
black crappie
common carp
largemouth bass
northern pike
Pompton River at Lincoln Park
black crappie
common carp
largemouth bass
rock bass
Pompton Lake
bluegill
common carp
largemouth bass
Passaic River at Dundee Lake
largemouth bass
Passaic River at Elmwood Park
bluegill
largemouth bass
yellow bullhead
Passaic River at Garfield
channel catfish
striped bass
THE ACADEMY OF NATURAL SCIENCES
High Risk Population
Total # No restr.
<0.07
1/week
Low Risk Population
1/month Do not eat No restr.
0.07-0.18 0.19-0.54
>0.54
<0.34
1/week
1/month Do not eat
0.35-0.93 0.94-2.81
>2.81
4
4
2
0
0
0
0.5
0
0.5
0.5
0
0.5
0
1
0
1
0
1
0
1
0
0
0
0
0
0
0
4
4
2
2
0
0
0
0
0.75
0.5
0
0.5
0.25
0.5
1
0.5
0
0
0
0
1
1
0.5
1
0
0
0.5
0
0
0
0
0
0
0
0
0
3
4
3
3
0
0
0
0
0.33
0
0
0
0.67
1
0.67
0
0
0
0.33
1
1
0.5
0
0
0
0.5
1
1
0
0
0
0
0
0
0
0
4
4
5
0
0
0
0.5
0
0
0.5
0.75
0.2
0
0.25
0.8
0.75
0.5
0
0.25
0.5
0.6
0
0
0.4
0
0
0
5
0
0.8
0.2
0
0.8
0.2
0
0
3
3
2
0
0
0
0.33
0.33
0.5
0.67
0.67
0.5
0
0
0
1
1
1
0
0
0
0
0
0
0
0
0
2
4
0
0
0
0
1
0.5
0
0.5
1
0.25
0
0.75
0
0
0
0
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 12. Cont'd
High Risk Population
Low Risk Population
Station
Total # No restr. 1/week 1/month Do not eat No restr. 1/week 1/month Do not eat
Species
<0.07
0.07-0.18 0.19-0.54
>0.54
<0.34 0.35-0.93 0.94-2.81
>2.81
Ramapo Lake
bluegill
4
0
0
1
0
1
0
0
0
largemouth bass
4
0
0
0.75
0.25
0.75
0
0.25
0
Ramapo River at Pompton Feeder
largemouth bass
3
0
0
0.33
0.67
0
0.33
0.67
0
rock bass
3
0
0
1
0
0.67
0.33
0
0
smallmouth bass
3
0
0
0
1
0
1
0
0
4
yellow bullhead
0
0
0.75
0.25
0
1
0
0
Rockaway River at Powerville
bluegill
3
0
1
0
0
1
0
0
0
rock bass
4
0
0
1
0
0.75
0.25
0
0
3
yellow bullhead
0
0.67
0.33
0
1
0
0
0
Sheppards lake
brown bullhead
3
0.33
0.67
0
0
1
0
0
0
largemouth bass
5
0
0
0
1
0
1
0
0
redbreast sunfish
3
0
0.33
0.67
0
1
0
0
0
rock bass
2
0
0.5
0.5
0
1
0
0
0
Speedwell Lake
bluegill
4
0
1
0
0
1
0
0
0
chain pickerel
3
0
0.67
0.33
0
1
0
0
0
common carp
4
0.25
0.75
0
0
1
0
0
0
THE ACADEMY OF NATURAL SCIENCES
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Table 12. Cont'd
Station
Species
Split Rock Reservoir
bluegill
brown bullhead
chain pickerel
largemouth bass
yellow perch
Lake Tappan
bluegill
largemouth bass
smallmouth bass
Weequahic Lake
bluegill
brown bullhead
common carp
largemouth bass
white perch
Wanaque Reservoir
bluegill
largemouth bass
yellow bullhead
Wawayanda Lake
bluegill
chain pickerel
largemouth bass
yellow bullhead
THE ACADEMY OF NATURAL SCIENCES
High Risk Population
Total # No restr.
<0.07
1/week
Low Risk Population
1/month Do not eat No restr.
0.07-0.18 0.19-0.54
>0.54
<0.34
1/week
1/month Do not eat
0.35-0.93 0.94-2.81
>2.81
4
2
5
5
4
0
1
0
0
0
0.75
0
0
0
0.75
0.25
0
1
1
0.25
0
0
0
0
0
1
1
1
0.4
1
0
0
0
0.6
0
0
0
0
0
0
0
0
0
0
0
4
5
3
0.5
0.2
0.33
0.5
0.2
0
0
0.6
0.67
0
0
0
1
1
0.33
0
0
0.67
0
0
0
0
0
0
3
3
3
4
3
0
1
0.33
0
0
1
0
0.67
0
1
0
0
0
1
0
0
0
0
0
0
1
1
1
0.75
1
0
0
0
0.25
0
0
0
0
0
0
0
0
0
0
0
4
5
4
0
0
0
0
0
1
1
0.4
0
0
0.6
0
0.75
0.4
1
0.25
0
0
0
0.6
0
0
0
0
3
5
5
3
0
0
0
0
0.33
0
0
0
0.67
1
0.4
1
0
0
0.6
0
1
0.6
0.4
0.33
0
0.4
0.6
0.67
0
0
0
0
0
0
0
0
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Figures 1 - 20
______________________________________________________________________________________________________
THE ACADEMY OF NATURAL SCIENCES
41
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Figure 5. Largemouth Bass Greenwood Lake
Concentrations of mercury in largemouth bass from Greenwood Lake in the 1996-1997 and 2002 ANS monitoring programs.
The legend box shows the actual years of collection.
Hg Concentration (ug/g wet)
1.6
1.4
1997
2002
1.2
1.0
0.8
0.6
0.4
0.2
0.0
20
25
30
35
40
45
50
55
Total Length (cm)
Figure 6. Largemouth Bass Monksville Reservoir
Concentrations of mercury in largemouth bass from Monksville Reservoir in the 1992-1993 and 2002 ANS monitoring programs.
The legend box shows the actual years of collection.
Hg Concentration (ug/g wet)
1.2
1992
1.0
2002
0.8
0.6
0.4
0.2
0.0
24
26
28
30
32
34
36
38
40
42
44
Total Length (cm)
______________________________________________________________________________________________________
The Academy of Natural Sciences
44
Patrick Center For Environmental Research
Figure 9. Largemouth Bass Passaic River
Concentrations of Mercury in largemouth bass from the Passaic River at East Hanover (Hatfield Swamp in 1996, Eagle Rock Ave in 2002) and
Elmwood Park (including Lake Dundee) in the 1992-2002 ANS monitoring programs. The legend box shows the actual years of collection.
1.6
East Hanover 1996
East Hanover 2002
Elmwood Park 1992
Elmwood Park 1998
Elmwood park 2002
Hg Concentration (ug/g wet)
1.4
1.2
1.0
0.8
0.6
0.4
0.2
0.0
20
25
30
35
40
45
50
55
Total Length (cm)
Figure 10. Largemouth Bass Passaic River
Concentrations of mercury in largemouth bass from the Passaic River at Great Piece (1992-1993) and mouth of Pompton
River (1998) during ANS monitoring Programs. The legend box shows the actual years of collection.
1.6
Hg Concentration (ug/g wet)
1.4
Great Piece/Pompton R 1992
Great Piece/Pompton River 1998
1.2
1.0
0.8
0.6
0.4
0.2
0.0
20
25
30
35
40
Total Length (cm)
45
50
55
______________________________________________________________________________________________________
The Academy of Natural Sciences
46
Patrick Center For Environmental Research
Figure 17. American Eel
Passaic River Elmwood Park 2002
Passaic River Garfield 2002
PCB Concentrations (ng/g wet)
2500
Passaic River Dundee Lake 2002
Passaic River Elmwood Park 1998
Navesink River 1998
2000
mid Raritan Bay 1986-7
Shark River 1998
Shrewsbury River 1998
1500
1000
500
0
20
30
40
50
60
70
80
90
Total Length (cm)
PCB Concentrations (ng/g wet)
2500
2000
1500
1000
500
0
0
5
10
15
% Lipid
20
25
APPENDIX I
Mercury Concentrations In Individual Fish Specimens
______________________________________________________________________________
THE ACADEMY OF NATURAL SCIENCES
54
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I.
Mercury concentrations in individual fish specimens
Units: mg/g wet wt
Serial Number
NJT02-OPPBS1
NJT02-OPPBS1
NJT02-OPPBS1
NJT02-ORABS1
NJT02-ORABS1
NJT02-ORABS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PLPBS1
NJT02-PLPBS1
NJT02-PLPBS1
NJT02-PERBS1
NJT02-PERBS1
Station Station Name
OPP Overpeck Creek
OPP Overpeck Creek
OPP Overpeck Creek
ORA Oradell Reservoir
ORA Oradell Reservoir
ORA Oradell Reservoir
PRDL Passaic River at Dundee Lake
PRDL Passaic River at Dundee Lake
PRDL Passaic River at Dundee Lake
PRDL Passaic River at Dundee Lake
PRDL Passaic River at Dundee Lake
PRG Passaic River at Garfield
PRG Passaic River at Garfield
PRG Passaic River at Garfield
PRE Passaic River at Elmwood Park
PRE Passaic River at Elmwood Park
PRE Passaic River at Elmwood Park
PLP
Pompton River at Lincoln Park
PLP
Pompton River at Lincoln Park
PLP
Pompton River at Lincoln Park
PER Passaic River at Eagle Rock Ave
PER Passaic River at Eagle Rock Ave
THE ACADEMY OF NATURAL SCIENCES
Scientific
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Pomoxis nigromaculatus
Pomoxis nigromaculatus
Pomoxis nigromaculatus
Pomoxis nigromaculatus
Pomoxis nigromaculatus
Common Name
American eel
American eel
American eel
American eel
American eel
American eel
American eel
American eel
American eel
American eel
American eel
American eel
American eel
American eel
American eel
American eel
American eel
black crappie
black crappie
black crappie
black crappie
black crappie
FTL cm LTL cm Fish Anal #
49.0
48.0
F-2423
35.8
35.7
F-2041
63.7
63.5
F-2048
61.5
61.4
F-2147
67.4
67.9
F-2152
83.5
81.1
F-2153
51.2
51.0
F-2482
34.7
34.5
F-2484
45.5
45.3
F-2485
56.2
56.0
F-2486
61.5
61.5
F-2487
48.9
48.7
F-2499
49.5
49.0
F-2500
69.5
68.7
F-2501
56.8
56.2
F-2515
46.5
47.2
F-2516
58.6
58.1
F-2517
21.4
21.0
F-2095
20.3
20.6
F-2096
17.5
17.6
F-2097
16.6
16.2
F-2100
25.0
25.2
F-2102
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0259
1
0.12
0277
1
0.14
0284
1
0.16
0489
1
0.06
0494
1
0.08
0495
1
0.07
9433
0
NR
9435
0
NR
9436
0
NR
9437
0
NR
9438
0
NR
9458
0
NR
9459
0
NR
9460
0
NR
9536
0
NR
9537
0
NR
9538
0
NR
0405
1
0.15
0406
1
0.29
0407
1
0.19
0410
1
0.12
0412
1
0.25
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-PERBS1
PER Passaic River at Eagle Rock Ave
NJT02-PERBS1
PER Passaic River at Eagle Rock Ave
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-MVSD3
MV
Monksville reservoir
NJT02-MVSD1
MV
Monksville reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-RWHBP1 RWH Rockaway River at Powerville
NJT02-RWHBP1 RWH Rockaway River at Powerville
NJT02-RWHBP2 RWH Rockaway River at Powerville
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-SPEBS1
SPE
Speedwell Lake
NJT02-SPEBS1
SPE
Speedwell Lake
NJT02-SPEBS1
SPE
Speedwell Lake
NJT02-SPEBS1
SPE
Speedwell Lake
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-WEEBS1 WEE Weequahic Lake
THE ACADEMY OF NATURAL SCIENCES
Scientific
Pomoxis nigromaculatus
Pomoxis nigromaculatus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Common Name
black crappie
black crappie
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
FTL cm LTL cm Fish Anal #
17.6
17.8
F-2104
18.3
17.7
F-2108
21.2
21.0
F-2603
20.4
19.8
F-2604
20.2
19.3
F-2605
20.6
20.0
F-2606
19.9
19.8
F-2607
18.5
16.8
F-2608
19.8
19.5
F-2609
17.8
16.8
F-2610
19.1
18.1
F-2615
19.0
18.2
F-2616
20.1
18.6
F-2617
19.2
18.0
F-2618
16.1
15.5
F-2619
16.0
15.4
F-2620
15.8
15.0
F-2621
18.3
18.3
F-2342
18.2
17.0
F-2343
17.9
17.8
F-2344
20.5
19.6
F-2356
18.6
17.6
F-2357
15.8
15.5
F-2358
15.4
15.0
F-2359
16.4
16.3
F-2434
17.3
17.5
F-2435
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0414
1
0.16
0418
1
0.12
0001
1
0.41
0002
1
0.23
0003
1
0.22
0004
1
0.27
0005
1
0.13
0006
1
0.08
0007
1
0.17
0008
1
0.11
0013
1
0.13
0014
1
0.08
0015
1
0.09
0016
1
0.07
0017
1
0.13
0018
1
0.11
0019
1
0.11
0039
1
0.21
0040
1
0.21
0041
1
0.14
0053
1
0.16
0054
1
0.13
0055
1
0.10
0056
1
0.10
0270
1
0.12
0271
1
0.15
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-POMPBS1 POMP Pompton Lake
NJT02-POMPBS1 POMP Pompton Lake
NJT02-POMPBS1 POMP Pompton Lake
NJT02-POMPBS1 POMP Pompton Lake
NJT02-BBPBS1
BBP Branch Brook Park
NJT02-BBPBS1
BBP Branch Brook Park
NJT02-BBPBS1
BBP Branch Brook Park
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-TAPBS1
TAP Lake Tappan
NJT02-TAPBS1
TAP Lake Tappan
NJT02-TAPBS1
TAP Lake Tappan
NJT02-TAPBS1
TAP Lake Tappan
NJT02-ORABS1 ORA Oradell Reservoir
NJT02-ORABS1 ORA Oradell Reservoir
NJT02-ORABS1 ORA Oradell Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-CANBS1 CAN Canistear Reservor
NJT02-CANBS2 CAN Canistear Reservor
NJT02-CANBS2 CAN Canistear Reservor
THE ACADEMY OF NATURAL SCIENCES
Scientific
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Common Name
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
FTL cm LTL cm Fish Anal #
17.4
17.5
F-2036
16.4
16.4
F-2079
18.3
18.2
F-2081
17.1
17.0
F-2082
18.3
18.2
F-2083
14.5
14.8
F-2088
15.3
15.5
F-2089
15.5
16.0
F-2090
16.4
16.3
F-2103
14.7
15.0
F-2109
15.1
15.1
F-2110
14.1
14.5
F-2124
15.0
15.0
F-2125
11.8
11.9
F-2126
15.2
15.3
F-2127
19.0
19.0
F-2144
14.7
14.9
F-2145
16.4
16.5
F-2146
17.9
17.4
F-2154
19.0
19.0
F-2155
18.5
17.2
F-2156
16.4
16.1
F-2157
18.5
18.2
F-2170
21.8
21.7
F-2173
21.2
20.8
F-2174
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0272
1
0.09
0389
1
0.18
0391
1
0.47
0392
1
0.17
0393
1
0.22
0398
1
0.16
0399
1
0.15
0400
1
0.24
0413
1
0.07
0419
1
0.09
0420
1
0.09
0466
1
0.06
0467
1
0.05
0468
1
0.08
0469
1
0.09
0486
1
0.05
0487
1
0.03
0488
1
0.05
0496
1
0.06
0497
1
0.11
0498
1
0.11
0499
1
0.10
0512
1
0.11
0515
1
0.11
0516
1
0.23
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-CANBS2 CAN Canistear Reservor
NJT02-ORRBS1 ORR Oak Ridge Reservoir
NJT02-ORRBS1 ORR Oak Ridge Reservoir
NJT02-ORRBS1 ORR Oak Ridge Reservoir
NJT02-ORRBS1 ORR Oak Ridge Reservoir
NJT02-PREBS1
PRE Passaic River at Elmwood Park
NJT02-PREBS1
PRE Passaic River at Elmwood Park
NJT02-PREBS1
PRE Passaic River at Elmwood Park
NJT02-RLBS1
RL
Ramapo Lake
NJT02-RLBS1
RL
Ramapo Lake
NJT02-RLBS1
RL
Ramapo Lake
NJT02-RLBS1
RL
Ramapo Lake
NJT02-SPLA1
SPL
Split Rock Reservoir
NJT02-SPLGN1
SPL
Split Rock Reservoir
NJT02-SPLGN2
SPL
Split Rock Reservoir
NJT02-SPLGN1
SPL
Split Rock Reservoir
NJT02-GTLBS1
GTL Green Turtle Lake
NJT02-GTLBS1
GTL Green Turtle Lake
NJT02-GTLBS1
GTL Green Turtle Lake
NJT02-GTLBS1
GTL Green Turtle Lake
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-OPPBS1
OPP Overpeck Creek
THE ACADEMY OF NATURAL SCIENCES
Scientific
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Ameiurus nebulosus
Ameiurus nebulosus
Ameiurus nebulosus
Ameiurus nebulosus
Ameiurus nebulosus
Common Name
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
bluegill
brown bullhead
brown bullhead
brown bullhead
brown bullhead
brown bullhead
FTL cm LTL cm Fish Anal #
21.0
19.8
F-2175
20.0
19.9
F-2193
17.5
17.1
F-2194
18.1
17.8
F-2195
19.9
19.7
F-2196
18.1
18.1
F-2503
16.4
16.1
F-2504
16.9
16.7
F-2505
21.1
21.0
F-2570
19.2
19.2
F-2571
19.0
18.2
F-2572
17.5
17.3
F-2573
21.2
21.0
F-2574
22.6
22.1
F-2575
22.0
22.0
F-2576
21.4
21.2
F-2577
17.9
17.2
F-2594
18.6
18.2
F-2595
19.9
19.3
F-2596
17.7
16.9
F-2597
27.2
27.3
F-2078
30.0
29.2
F-2080
31.0
31.4
F-2087
25.0
24.6
F-2105
22.6
22.3
F-2106
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0517
1
0.10
0539
1
0.28
0540
1
0.15
0541
1
0.11
0542
1
0.24
9462
0
0.24
9463
0
0.12
9464
0
0.21
9848
1
0.28
9849
1
0.26
9850
1
0.19
9851
1
0.19
9890
1
0.13
9891
1
0.12
9892
1
0.10
9893
1
0.21
9974
1
0.09
9975
1
0.14
9976
1
0.58
9977
1
0.07
0388
1
0.03
0390
1
0.03
0397
1
0.03
0415
1
0.04
0416
1
0.03
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-SHBS1
SH
Shepherds lake
NJT02-SHBS1
SH
Shepherds lake
NJT02-SHBS1
SH
Shepherds lake
NJT02-SPLGN7
SPL
Split Rock Reservoir
NJT02-SPLGN7
SPL
Split Rock Reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-WWLA1
WWL Wawayanda Lake
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-SPEBS1
SPE
Speedwell Lake
NJT02-SPEBS1
SPE
Speedwell Lake
NJT02-SPEBS1
SPE
Speedwell Lake
NJT02-CLGN4
CL
Clinton Reservoir
NJT02-CLGN1
CL
Clinton Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-CANBS2 CAN Canistear Reservor
NJT02-CANBS1 CAN Canistear Reservor
THE ACADEMY OF NATURAL SCIENCES
Scientific
Ameiurus nebulosus
Ameiurus nebulosus
Ameiurus nebulosus
Ameiurus nebulosus
Ameiurus nebulosus
Ameiurus nebulosus
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Common Name
brown bullhead
brown bullhead
brown bullhead
brown bullhead
brown bullhead
brown bullhead
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
FTL cm LTL cm Fish Anal #
21.2
21.1
F-2107
29.5
29.5
F-2558
36.1
35.4
F-2559
28.9
28.3
F-2560
39.0
37.9
F-2587
30.7
29.8
F-2588
35.5
34.9
F-2350
51.1
49.5
F-2351
38.4
37.7
F-2352
44.5
43.7
F-2365
28.0
27.5
F-2366
26.4
25.7
F-2367
27.1
26.8
F-2368
33.9
33.9
F-2369
25.9
24.8
F-2383
31.8
29.1
F-2384
59.6
55.6
F-2385
45.2
50.4
F-2116
53.0
44.5
F-2117
45.6
43.1
F-2162
62.8
60.0
F-2163
43.5
41.7
F-2165
47.2
44.0
F-2181
44.0
41.3
F-2183
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0417
1
0.04
9836
1
0.13
9837
1
0.07
9838
1
0.06
9911
1
0.04
9912
1
0.04
0047
1
0.15
0048
1
0.31
0049
1
0.19
0062
1
0.44
0063
1
0.23
0064
1
0.23
0065
1
0.23
0066
1
0.50
0158
1
0.09
0159
1
0.11
0160
1
0.26
0426
1
0.61
0427
1
0.43
0504
1
0.27
0505
1
0.37
0507
1
0.20
0523
1
0.16
0525
1
0.14
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-CANBS2 CAN Canistear Reservor
NJT02-CANBS1 CAN Canistear Reservor
NJT02-SPLGN7
SPL
Split Rock Reservoir
NJT02-SPLGN10 SPL
Split Rock Reservoir
NJT02-SPLGN10 SPL
Split Rock Reservoir
NJT02-SPLGN4
SPL
Split Rock Reservoir
NJT02-SPLGN1
SPL
Split Rock Reservoir
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-SPEBS1
SPE
Speedwell Lake
NJT02-SPEBS1
SPE
Speedwell Lake
NJT02-SPEBS1
SPE
Speedwell Lake
NJT02-SPEBS1
SPE
Speedwell Lake
NJT02-PLPBS1
PLP
Pompton River at Lincoln Park
NJT02-PLPBS1
PLP
Pompton River at Lincoln Park
NJT02-PLPBS1
PLP
Pompton River at Lincoln Park
NJT02-PERBS1
PER Passaic River at Eagle Rock Ave
NJT02-PERBS1
PER Passaic River at Eagle Rock Ave
NJT02-PERBS1
PER Passaic River at Eagle Rock Ave
NJT02-POMPBS1 POMP Pompton Lake
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-BBPBS1
BBP Branch Brook Park
NJT02-POMPBS1 POMP Pompton Lake
NJT02-BBPBS1
BBP Branch Brook Park
THE ACADEMY OF NATURAL SCIENCES
Scientific
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Esox niger
Ictalurus punctatus
Ictalurus punctatus
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Common Name
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
chain pickerel
channel catfish
channel catfish
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
FTL cm LTL cm Fish Anal #
41.8
39.2
F-2184
41.5
39.7
F-2185
54.5
53.8
F-2589
46.8
45.6
F-2590
49.0
48.3
F-2591
61.0
60.0
F-2592
57.0
56.4
F-2593
50.4
50.3
F-2492
48.2
47.0
F-2493
62.5
61.5
F-2386
61.7
61.2
F-2387
63.6
63.0
F-2388
57.7
57.4
F-2389
49.9
49.5
F-2416
57.5
57.5
F-2417
58.7
58.5
F-2418
58.5
57.6
F-2426
56.5
56.0
F-2427
60.3
59.5
F-2428
75.5
75.1
F-2429
61.2
60.5
F-2433
69.0
68.0
F-2037
66.8
66.4
F-2038
72.5
71.8
F-2039
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0526
1
0.25
0527
1
0.19
9913
1
0.30
9914
1
0.30
9915
1
0.32
9916
1
0.26
9917
1
0.32
9451
1
0.31
9452
1
0.23
0161
1
0.14
0162
1
0.10
0163
1
0.05
0164
1
0.13
0252
1
0.47
0253
1
0.28
0254
1
0.39
0262
1
0.23
0263
1
0.18
0264
1
0.15
0265
1
0.66
0269
1
0.10
0273
1
0.19
0274
1
0.45
0275
1
0.07
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-BBPBS1
BBP Branch Brook Park
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-POMPBS1 POMP Pompton Lake
NJT02-PLPBS1
PLP
Pompton River at Lincoln Park
NJT02-BBPBS1
BBP Branch Brook Park
NJT02-PERBS1
PER Passaic River at Eagle Rock Ave
NJT02-POMPBS1 POMP Pompton Lake
NJT02-PRDLBS1 PRDL Passaic River at Dundee Lake
NJT02-PRDLBS1 PRDL Passaic River at Dundee Lake
NJT02-PRDLBS1 PRDL Passaic River at Dundee Lake
NJT02-PRDLBS1 PRDL Passaic River at Dundee Lake
NJT02-PRDLBS1 PRDL Passaic River at Dundee Lake
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-PREBS1
PRE Passaic River at Elmwood Park
NJT02-PREBS1
PRE Passaic River at Elmwood Park
NJT02-PREBS1
PRE Passaic River at Elmwood Park
NJT02-PREBS1
PRE Passaic River at Elmwood Park
THE ACADEMY OF NATURAL SCIENCES
Scientific
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Common Name
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
common carp
FTL cm LTL cm Fish Anal #
69.5
68.9
F-2040
50.5
50.8
F-2043
50.0
50.5
F-2044
56.2
55.6
F-2046
51.7
52.0
F-2049
63.7
64.2
F-2050
71.0
71.3
F-2051
58.8
59.1
F-2068
49.5
49.9
F-2069
60.5
49.8
F-2070
50.3
49.7
F-2071
54.2
53.6
F-2072
53.5
53.2
F-2478
54.8
54.7
F-2479
54.8
55.0
F-2480
58.7
58.2
F-2481
62.9
62.4
F-2483
60.8
60.8
F-2495
60.5
59.5
F-2497
62.9
62.4
F-2498
51.8
51.6
F-2506
53.0
53.0
F-2507
63.5
62.8
F-2513
51.6
51.0
F-2514
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0276
1
0.19
0279
1
0.04
0280
0
NR
0282
1
0.08
0285
1
0.09
0286
1
0.11
0287
1
0.10
0378
1
0.30
0379
1
0.22
0380
1
0.10
0381
1
0.21
0382
1
0.23
9429
0
NR
9430
0
NR
9431
0
NR
9432
0
NR
9434
0
NR
9454
0
NR
9456
0
NR
9457
0
NR
9465
0
NR
9466
0
NR
9534
0
NR
9535
0
NR
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-PRLBS1
PRL Passaic River at Lyndhurst
NJT02-PRLBS1
PRL Passaic River at Lyndhurst
NJT02-PRLBS1
PRL Passaic River at Lyndhurst
NJT02-PRLBS1
PRL Passaic River at Lyndhurst
NJT02-PRLBS1
PRL Passaic River at Lyndhurst
NJT02-PRLBS1
PRL Passaic River at Lyndhurst
NJT02-PRLBS1
PRL Passaic River at Lyndhurst
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-MVBS1
MV
Monksville reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-WWLBS1 WWL Wawayanda Lake
THE ACADEMY OF NATURAL SCIENCES
Scientific
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Common Name
common carp
common carp
common carp
common carp
common carp
common carp
common carp
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
FTL cm LTL cm Fish Anal #
54.2
54.2
F-2518
57.5
57.0
F-2519
49.0
48.9
F-2520
53.6
53.5
F-2521
54.5
56.5
F-2522
51.8
51.8
F-2523
48.2
48.2
F-2524
48.0
47.2
F-2631
34.2
34.0
F-2632
30.7
28.5
F-2633
47.5
47.0
F-2634
45.2
44.8
F-2336
42.7
40.8
F-2337
42.6
42.1
F-2338
39.9
38.3
F-2339
42.0
40.2
F-2340
44.4
42.3
F-2341
26.5
26.4
F-2345
28.0
27.2
F-2346
31.5
31.2
F-2347
36.9
36.5
F-2348
44.0
43.0
F-2349
33.0
32.9
F-2360
33.4
33.5
F-2361
Hg
Total Hg
Chem Anal # workup ug/g wet wt
9539
0
NR
9540
0
NR
9541
0
NR
9542
0
NR
9543
0
NR
9544
0
NR
9545
0
NR
0029
1
1.47
0030
1
0.23
0031
1
0.28
0032
1
1.15
0033
1
1.03
0034
1
0.21
0035
1
0.31
0036
1
0.31
0037
1
0.31
0038
1
0.29
0042
1
0.20
0043
1
0.18
0044
1
0.13
0045
1
0.32
0046
1
0.39
0057
1
0.29
0058
1
0.33
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-PLPBS1
PLP
Pompton River at Lincoln Park
NJT02-PERBS1
PER Passaic River at Eagle Rock Ave
NJT02-PLPBS1
PLP
Pompton River at Lincoln Park
NJT02-PERBS1
PER Passaic River at Eagle Rock Ave
NJT02-PLPBS1
PLP
Pompton River at Lincoln Park
NJT02-POMPBS1 POMP Pompton Lake
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-OPPBS1
OPP Overpeck Creek
NJT02-POMPBS1 POMP Pompton Lake
NJT02-POMPBS1 POMP Pompton Lake
NJT02-BBPBS1
BBP Branch Brook Park
NJT02-BBPBS1
BBP Branch Brook Park
NJT02-BBPBS1
BBP Branch Brook Park
THE ACADEMY OF NATURAL SCIENCES
Scientific
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Common Name
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
FTL cm LTL cm Fish Anal #
44.1
43.9
F-2362
42.9
42.7
F-2363
45.3
45.1
F-2364
41.6
40.9
F-2370
45.0
43.8
F-2371
48.7
47.8
F-2372
52.2
52.0
F-2373
48.3
47.6
F-2374
29.4
25.4
F-2402
30.1
29.5
F-2403
34.2
33.8
F-2408
34.6
34.3
F-2409
38.8
38.2
F-2410
39.2
39.4
F-2411
30.2
29.7
F-2412
35.2
35.5
F-2414
37.6
37.4
F-2419
36.4
36.0
F-2420
39.9
39.4
F-2421
41.2
40.5
F-2422
52.3
52.3
F-2424
49.0
48.5
F-2425
43.6
43.7
F-2430
47.0
46.5
F-2431
44.5
44.7
F-2432
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0059
1
0.66
0060
1
0.78
0061
1
0.73
0079
1
0.36
0080
1
0.59
0081
1
0.73
0082
1
0.80
0083
1
1.08
0238
1
0.44
0239
1
1.02
0244
1
1.19
0245
1
0.35
0246
1
0.54
0247
1
0.74
0248
1
0.27
0250
1
0.50
0255
1
0.45
0256
1
0.09
0257
1
0.12
0258
1
0.14
0260
1
1.24
0261
1
1.30
0266
1
0.71
0267
1
0.99
0268
1
0.71
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-BBPBS1
BBP Branch Brook Park
NJT02-POMPBS1 POMP Pompton Lake
NJT02-POMPBS1 POMP Pompton Lake
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-TAPBS1
TAP Lake Tappan
NJT02-TAPBS1
TAP Lake Tappan
NJT02-TAPBS1
TAP Lake Tappan
NJT02-TAPBS1
TAP Lake Tappan
NJT02-TAPBS1
TAP Lake Tappan
NJT02-ORABS1 ORA Oradell Reservoir
NJT02-ORABS1 ORA Oradell Reservoir
NJT02-ORABS1 ORA Oradell Reservoir
NJT02-ORABS1 ORA Oradell Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-CANBS2 CAN Canistear Reservor
NJT02-CANBS1 CAN Canistear Reservor
NJT02-CANBS2 CAN Canistear Reservor
NJT02-CANBS2 CAN Canistear Reservor
NJT02-ORRBS1 ORR Oak Ridge Reservoir
THE ACADEMY OF NATURAL SCIENCES
Scientific
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Common Name
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
FTL cm LTL cm Fish Anal #
35.1
35.6
F-2042
47.5
47.5
F-2045
45.9
44.4
F-2047
40.0
40.2
F-2073
35.0
35.0
F-2074
33.5
31.7
F-2075
34.0
33.3
F-2094
26.7
26.7
F-2133
48.3
47.7
F-2134
40.6
40.0
F-2135
43.5
43.4
F-2136
46.5
45.9
F-2139
47.1
47.1
F-2148
47.9
47.2
F-2149
46.0
45.0
F-2150
48.6
48.3
F-2151
48.1
46.9
F-2164
45.6
43.7
F-2166
49.4
46.7
F-2167
50.5
49.6
F-2168
41.7
40.0
F-2179
43.8
42.9
F-2182
44.5
43.5
F-2186
51.4
50.0
F-2187
41.6
40.4
F-2199
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0278
1
0.20
0281
1
0.39
0283
1
0.31
0383
1
0.56
0384
1
0.73
0385
1
0.56
0404
1
0.21
0475
1
0.05
0476
1
0.28
0477
1
0.31
0478
1
0.21
0481
1
0.18
0490
1
0.26
0491
1
0.51
0492
1
0.33
0493
1
0.20
0506
1
0.61
0508
1
0.43
0509
1
0.72
0510
1
0.79
0521
1
0.38
0524
1
0.29
0528
1
0.51
0529
1
0.67
0545
1
0.65
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-ORRBS1 ORR Oak Ridge Reservoir
NJT02-ORRBS1 ORR Oak Ridge Reservoir
NJT02-ORRBS1 ORR Oak Ridge Reservoir
NJT02-PRDLBS1 PRDL Passaic River at Dundee Lake
NJT02-PRDLBS1 PRDL Passaic River at Dundee Lake
NJT02-PRDLBS1 PRDL Passaic River at Dundee Lake
NJT02-PRDLBS1 PRDL Passaic River at Dundee Lake
NJT02-PRDLBS1 PRDL Passaic River at Dundee Lake
NJT02-PREBS1
PRE Passaic River at Elmwood Park
NJT02-PREBS1
PRE Passaic River at Elmwood Park
NJT02-PREBS1
PRE Passaic River at Elmwood Park
NJT02-SHBS1
SH
Shepherds lake
NJT02-SHBS1
SH
Shepherds lake
NJT02-SHBS1
SH
Shepherds lake
NJT02-SHBS1
SH
Shepherds lake
NJT02-SHBS1
SH
Shepherds lake
NJT02-RLBS1
RL
Ramapo Lake
NJT02-RLBS1
RL
Ramapo Lake
NJT02-RLBS1
RL
Ramapo Lake
NJT02-RLBS1
RL
Ramapo Lake
NJT02-SPLGN7
SPL
Split Rock Reservoir
NJT02-SPLGN1
SPL
Split Rock Reservoir
NJT02-SPLGN1
SPL
Split Rock Reservoir
NJT02-SPLH1
SPL
Split Rock Reservoir
NJT02-SPLA1
SPL
Split Rock Reservoir
THE ACADEMY OF NATURAL SCIENCES
Scientific
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Common Name
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
FTL cm LTL cm Fish Anal #
41.3
40.3
F-2200
42.2
41.2
F-2201
45.1
44.0
F-2202
28.2
28.5
F-2473
27.0
26.6
F-2474
37.8
37.5
F-2475
25.2
25.1
F-2476
31.1
30.8
F-2477
34.0
33.6
F-2508
34.6
34.6
F-2510
27.0
27.2
F-2512
41.1
40.5
F-2553
40.4
39.3
F-2554
39.7
39.2
F-2555
39.0
38.0
F-2556
39.2
35.5
F-2557
37.5
36.0
F-2566
30.6
29.4
F-2567
30.9
30.4
F-2568
48.7
47.3
F-2569
35.5
34.7
F-2582
39.4
38.2
F-2583
38.0
37.6
F-2584
40.5
39.4
F-2585
35.9
34.2
F-2586
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0546
1
0.90
0547
1
0.81
0548
1
0.82
9424
0
0.18
9425
0
0.16
9426
0
0.35
9427
0
0.16
9428
0
0.15
9467
1
0.24
9469
1
0.24
9471
1
0.17
9831
1
0.60
9832
1
0.67
9833
1
0.56
9834
1
0.76
9835
1
0.71
9844
1
0.29
9845
1
0.33
9846
1
0.34
9847
1
1.05
9906
1
0.32
9907
1
0.48
9908
1
0.32
9909
1
0.52
9910
1
0.38
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-GTLBS1
GTL Green Turtle Lake
NJT02-GTLBS1
GTL Green Turtle Lake
NJT02-GTLBS1
GTL Green Turtle Lake
NJT02-GTLBS1
GTL Green Turtle Lake
NJT02-GTLBS1
GTL Green Turtle Lake
NJT02-PERBS1
PER Passaic River at Eagle Rock Ave
NJT02-PERBS1
PER Passaic River at Eagle Rock Ave
NJT02-CLBP1
CL
Clinton Reservoir
NJT02-CLBP1
CL
Clinton Reservoir
NJT02-CLBP1
CL
Clinton Reservoir
NJT02-CLBP1
CL
Clinton Reservoir
NJT02-SHBS2
SH
Shepherds lake
NJT02-SHBS2
SH
Shepherds lake
NJT02-SHBS2
SH
Shepherds lake
NJT02-RWHBP1 RWH Rockaway River at Powerville
NJT02-RWHBP1 RWH Rockaway River at Powerville
NJT02-RWHBP1 RWH Rockaway River at Powerville
NJT02-RWHBP2 RWH Rockaway River at Powerville
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
THE ACADEMY OF NATURAL SCIENCES
Scientific
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Esox lucius
Esox lucius
Lepomis auritus
Lepomis auritus
Lepomis auritus
Lepomis auritus
Lepomis auritus
Lepomis auritus
Lepomis auritus
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Common Name
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
northern pike
northern pike
redbreast sunfish
redbreast sunfish
redbreast sunfish
redbreast sunfish
redbreast sunfish
redbreast sunfish
redbreast sunfish
rock bass
rock bass
rock bass
rock bass
rock bass
rock bass
rock bass
rock bass
rock bass
rock bass
rock bass
FTL cm LTL cm Fish Anal #
31.7
31.4
F-2598
38.9
38.0
F-2599
49.4
49.4
F-2600
40.0
39.5
F-2601
32.5
31.9
F-2602
41.3
41.2
F-2413
44.5
44.3
F-2415
13.8
13.6
F-2111
14.1
14.0
F-2112
13.2
13.3
F-2113
12.7
12.7
F-2114
15.9
15.5
F-2563
14.6
14.0
F-2564
15.6
15.3
F-2565
24.1
24.0
F-2611
23.3
22.9
F-2612
23.9
23.2
F-2613
24.5
24.2
F-2614
22.3
22.3
F-2379
20.7
20.5
F-2380
22.2
22.0
F-2381
22.3
21.9
F-2382
18.3
17.9
F-2091
17.0
16.3
F-2092
17.6
17.5
F-2093
Hg
Total Hg
Chem Anal # workup ug/g wet wt
9978
1
0.20
9979
1
0.32
9980
1
0.74
9981
1
0.36
9982
1
0.26
0249
1
0.15
0251
1
0.20
0421
1
0.16
0422
1
0.16
0423
1
0.19
0424
1
0.25
9841
1
0.20
9842
1
0.19
9843
1
0.18
0009
1
0.34
0010
1
0.29
0011
1
0.41
0012
1
0.32
0154
1
0.22
0155
1
0.13
0156
1
0.27
0157
1
0.26
0401
1
0.32
0402
1
0.46
0403
1
0.33
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-PLPBS1
PLP
Pompton River at Lincoln Park
NJT02-PLPBS1
PLP
Pompton River at Lincoln Park
NJT02-PLPBS1
PLP
Pompton River at Lincoln Park
NJT02-CLGN4
CL
Clinton Reservoir
NJT02-CLGN4
CL
Clinton Reservoir
NJT02-CLB2
CL
Clinton Reservoir
NJT02-SHBS2
SH
Shepherds lake
NJT02-SHBS2
SH
Shepherds lake
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-BTRBS1
BTR Boonton Reservoir
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-TAPBS1
TAP Lake Tappan
NJT02-TAPBS1
TAP Lake Tappan
NJT02-TAPBS1
TAP Lake Tappan
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-MVSD1
MV
Monksville reservoir
NJT02-MVSD1
MV
Monksville reservoir
NJT02-MVSD1
MV
Monksville reservoir
THE ACADEMY OF NATURAL SCIENCES
Scientific
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Ambloplites rupestris
Micropterus dolomieu
Micropterus dolomieu
Micropterus dolomieu
Micropterus dolomieu
Micropterus dolomieu
Micropterus dolomieu
Micropterus dolomieu
Micropterus dolomieu
Micropterus dolomieu
Micropterus dolomieu
Morone saxatilis
Morone saxatilis
Morone saxatilis
Morone saxatilis
Stizostedion vitreum
Stizostedion vitreum
Stizostedion vitreum
Common Name
rock bass
rock bass
rock bass
rock bass
rock bass
rock bass
rock bass
rock bass
smallmouth bass
smallmouth bass
smallmouth bass
smallmouth bass
smallmouth bass
smallmouth bass
smallmouth bass
smallmouth bass
smallmouth bass
smallmouth bass
striped bass
striped bass
striped bass
striped bass
walleye
walleye
walleye
FTL cm LTL cm Fish Anal #
20.8
21.0
F-2098
23.7
23.4
F-2099
21.5
21.1
F-2101
15.9
15.8
F-2118
15.8
15.7
F-2119
18.2
17.9
F-2120
15.3
15.0
F-2561
20.9
20.6
F-2562
43.4
42.0
F-2375
48.4
47.2
F-2376
38.9
36.3
F-2377
41.0
40.6
F-2378
29.7
28.6
F-2399
26.4
25.3
F-2400
35.0
35.1
F-2401
27.7
27.6
F-2132
46.4
45.9
F-2137
48.4
58.1
F-2138
49.6
49.0
F-2488
57.6
56.6
F-2489
49.0
48.8
F-2490
54.4
54.6
F-2491
47.8
47.1
F-2390
51.6
50.2
F-2391
59.8
59.4
F-2392
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0408
1
0.64
0409
1
0.83
0411
1
0.60
0428
1
0.19
0429
1
0.18
0430
1
0.65
9839
1
0.20
9840
1
0.15
0084
1
0.52
0085
1
0.75
0086
1
0.39
0087
1
0.39
0235
1
0.70
0236
1
0.65
0237
1
0.91
0474
1
0.06
0479
1
0.38
0480
1
0.43
9447
1
0.33
9448
1
0.66
9449
1
0.41
9450
1
0.64
0165
1
0.55
0166
1
0.42
0167
1
0.78
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-MVSD1
MV
Monksville reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-GWLBS2 GWL Greenwood Lake
NJT02-GWLBS2 GWL Greenwood Lake
NJT02-GWLBS2 GWL Greenwood Lake
NJT02-GWLBS2 GWL Greenwood Lake
NJT02-GWLBS2 GWL Greenwood Lake
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-WEEBS1 WEE Weequahic Lake
NJT02-CLGN5
CL
Clinton Reservoir
NJT02-CLGN4
CL
Clinton Reservoir
NJT02-CLGN1
CL
Clinton Reservoir
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-PRGWS1 PRG Passaic River at Garfield
NJT02-RWHBP1 RWH Rockaway River at Powerville
NJT02-RWHBP1 RWH Rockaway River at Powerville
NJT02-RWHBP2 RWH Rockaway River at Powerville
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-GWLBS1 GWL Greenwood Lake
NJT02-MVBS1
MV
Monksville reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-WWLBS1 WWL Wawayanda Lake
THE ACADEMY OF NATURAL SCIENCES
Scientific
Stizostedion vitreum
Stizostedion vitreum
Stizostedion vitreum
Stizostedion vitreum
Stizostedion vitreum
Stizostedion vitreum
Stizostedion vitreum
Morone americana
Morone americana
Morone americana
Catostomus commersoni
Catostomus commersoni
Catostomus commersoni
Catostomus commersoni
Catostomus commersoni
Catostomus commersoni
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Common Name
walleye
walleye
walleye
walleye
walleye
walleye
walleye
white perch
white perch
white perch
white sucker
white sucker
white sucker
white sucker
white sucker
white sucker
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
FTL cm LTL cm Fish Anal #
54.0
58.5
F-2393
44.4
43.0
F-2394
54.8
F-2188
56.4
F-2189
49.0
F-2190
57.1
F-2191
61.1
F-2192
18.0
18.1
F-2084
17.9
18.1
F-2085
17.7
17.7
F-2086
44.5
43.3
F-2121
45.5
44.6
F-2122
46.8
45.4
F-2123
42.0
40.6
F-2494
47.3
46.5
F-2496
44.0
42.9
F-2502
23.5
23.0
F-2622
22.5
22.5
F-2623
16.6
16.2
F-2624
23.7
23.3
F-2625
23.8
181.7
F-2626
21.4
20.9
F-2627
23.6
23.6
F-2628
19.4
19.5
F-2629
23.0
22.8
F-2630
29.9
30.0
F-2353
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0168
1
0.35
0169
1
0.44
0530
1
0.30
0531
1
0.28
0532
1
0.18
0533
1
0.28
0534
1
0.47
0394
1
0.09
0395
1
0.08
0396
1
0.10
0431
1
0.25
0432
1
0.19
0433
1
0.24
9453
0
NR
9455
0
NR
9461
0
NR
0020
1
0.14
0021
1
0.28
0022
1
0.10
0023
1
0.07
0024
1
0.11
0025
1
0.06
0026
1
0.09
0027
1
0.11
0028
1
0.13
0050
1
0.36
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-WWLBS1 WWL Wawayanda Lake
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-WQBS1
WQ
Wanaque Reservoir
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-RPFBS1
RPF
Ramapo River at Pompton Feeder
NJT02-CLGN4
CL
Clinton Reservoir
NJT02-CLGN4
CL
Clinton Reservoir
NJT02-CLGN4
CL
Clinton Reservoir
NJT02-CLGN4
CL
Clinton Reservoir
NJT02-ORABS1 ORA Oradell Reservoir
NJT02-ORABS1 ORA Oradell Reservoir
NJT02-ORABS1 ORA Oradell Reservoir
NJT02-ORABS1 ORA Oradell Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-ELBS1
EL
Echo Lake Reservoir
NJT02-CANBS1 CAN Canistear Reservor
NJT02-CANBS2 CAN Canistear Reservor
NJT02-CANBS2 CAN Canistear Reservor
THE ACADEMY OF NATURAL SCIENCES
Scientific
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Common Name
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
FTL cm LTL cm Fish Anal #
28.3
28.2
F-2354
27.1
26.8
F-2355
18.8
16.1
F-2395
22.9
22.6
F-2396
19.9
20.0
F-2397
22.2
21.7
F-2398
24.5
24.0
F-2404
23.4
22.6
F-2405
26.9
26.2
F-2406
22.5
23.2
F-2407
28.4
28.9
F-2128
28.2
28.5
F-2129
29.7
29.2
F-2130
28.3
28.7
F-2131
23.7
23.5
F-2140
27.0
26.5
F-2141
18.6
18.6
F-2142
18.3
17.6
F-2143
22.9
22.5
F-2158
28.6
27.5
F-2159
26.4
26.4
F-2160
22.4
22.1
F-2161
25.1
24.8
F-2172
28.6
27.2
F-2176
24.5
24.0
F-2177
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0051
1
0.45
0052
1
0.30
0170
1
0.10
0171
1
0.17
0172
1
0.08
0173
1
0.16
0240
1
0.63
0241
1
0.52
0242
1
0.51
0243
1
0.52
0470
1
0.44
0471
1
0.43
0472
1
0.45
0473
1
0.74
0482
1
0.04
0483
1
0.05
0484
1
0.03
0485
1
0.04
0500
1
0.14
0501
1
0.07
0502
1
0.16
0503
1
0.09
0514
1
0.17
0518
1
0.19
0519
1
0.12
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix I. Cont'd.
Serial Number
Station Station Name
NJT02-CANBS2 CAN Canistear Reservor
NJT02-ORRBS1 ORR Oak Ridge Reservoir
NJT02-ORRBS1 ORR Oak Ridge Reservoir
NJT02-PREBS1
PRE Passaic River at Elmwood Park
NJT02-PREBS1
PRE Passaic River at Elmwood Park
NJT02-MVBS1
MV
Monksville reservoir
NJT02-MVBS1
MV
Monksville reservoir
NJT02-CANBS1 CAN Canistear Reservor
NJT02-CANBS2 CAN Canistear Reservor
NJT02-CANBS2 CAN Canistear Reservor
NJT02-SPLGN5
SPL
Split Rock Reservoir
NJT02-SPLGN5
SPL
Split Rock Reservoir
NJT02-SPLH1
SPL
Split Rock Reservoir
NJT02-SPLGN5
SPL
Split Rock Reservoir
Scientific
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Perca flavescens
Perca flavescens
Perca flavescens
Perca flavescens
Perca flavescens
Perca flavescens
Perca flavescens
Perca flavescens
Perca flavescens
Common Name
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow bullhead
yellow perch
yellow perch
yellow perch
yellow perch
yellow perch
yellow perch
yellow perch
yellow perch
yellow perch
FTL cm LTL cm Fish Anal #
27.6
26.3
F-2178
28.5
28.0
F-2197
23.8
23.0
F-2198
29.1
29.0
F-2509
20.5
20.0
F-2511
34.9
34.2
F-2076
27.6
27.5
F-2077
25.3
24.3
F-2169
27.5
26.3
F-2171
20.5
34.4
F-2180
26.2
25.4
F-2578
30.0
29.8
F-2579
29.5
28.5
F-2580
30.0
29.1
F-2581
Hg
Total Hg
Chem Anal # workup ug/g wet wt
0520
1
0.16
0543
1
0.23
0544
1
0.10
9468
1
0.24
9470
1
0.15
0386
1
0.17
0387
1
0.17
0511
1
0.18
0513
1
0.22
0522
1
0.29
9894
1
0.10
9895
1
0.34
9896
1
0.15
9897
1
0.13
Totals
NR = Not Run or Requested
THE ACADEMY OF NATURAL SCIENCES
342
Summary Stats
Min
0.03
Max
1.47
Median
0.22
Mean
0.30
Stdev
0.25
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
APPENDIX II.i.
INDIVIDUAL SAMPLE DATA ORGANIC CONTAMINANTS:
KEY
______________________________________________________________________________
THE ACADEMY OF NATURAL SCIENCES
71
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix II.i.
Key to Summary of PCB and OCP Concentrations
CHEM ID Fish #
81
82
83
84
85
235
236
237
238
239
240
241
242
244
245
247
248
249
251
252
253
254
255
256
257
258
259
260
261
262
263
264
265
266
267
268
269
270
271
272
273
274
275
276
277
278
279
281
282
283
284
285
286
287
378
9424
9425
9426
9427
9428
9429
9430
9431
9432
9433
9434
9435
9436
9437
9438
9447
9448
9449
9450
9451
9452
F-2372
F-2373
F-2374
F-2375
F-2376
F-2399
F-2400
F-2401
F-2402
F-2403
F-2404
F-2405
F-2406
F-2408
F-2409
F-2411
F-2412
F-2413
F-2415
F-2416
F-2417
F-2418
F-2419
F-2420
F-2421
F-2422
F-2423
F-2424
F-2425
F-2426
F-2427
F-2428
F-2429
F-2430
F-2431
F-2432
F-2433
F-2434
F-2435
F-2036
F-2037
F-2038
F-2039
F-2040
F-2041
F-2042
F-2043
F-2045
F-2046
F-2047
F-2048
F-2049
F-2050
F-2051
F-2068
F-2473
F-2474
F-2475
F-2476
F-2477
F-2478
F-2479
F-2480
F-2481
F-2482
F-2483
F-2484
F-2485
F-2486
F-2487
F-2488
F-2489
F-2490
F-2491
F-2492
F-2493
Fish Anal #
Serial Number
Station
Station Name
Scientific
Common Name
F-2372
F-2373
F-2374
F-2375
F-2376
F-2399
F-2400
F-2401
F-2402
F-2403
F-2404
F-2405
F-2406
F-2408
F-2409
F-2411
F-2412
F-2413
F-2415
F-2416
F-2417
F-2418
F-2419
F-2420
F-2421
F-2422
F-2423
F-2424
F-2425
F-2426
F-2427
F-2428
F-2429
F-2430
F-2431
F-2432
F-2433
F-2434
F-2435
F-2036
F-2037
F-2038
F-2039
F-2040
F-2041
F-2042
F-2043
F-2045
F-2046
F-2047
F-2048
F-2049
F-2050
F-2051
F-2068
F-2473
F-2474
F-2475
F-2476
F-2477
F-2478
F-2479
F-2480
F-2481
F-2482
F-2483
F-2484
F-2485
F-2486
F-2487
F-2488
F-2489
F-2490
F-2491
F-2492
F-2493
NJT02-BTRBS1
NJT02-BTRBS1
NJT02-BTRBS1
NJT02-BTRBS1
NJT02-BTRBS1
NJT02-RPFBS1
NJT02-RPFBS1
NJT02-RPFBS1
NJT02-RPFBS1
NJT02-RPFBS1
NJT02-RPFBS1
NJT02-RPFBS1
NJT02-RPFBS1
NJT02-RPFBS1
NJT02-PLPBS1
NJT02-PLPBS1
NJT02-PERBS1
NJT02-PERBS1
NJT02-PERBS1
NJT02-PLPBS1
NJT02-PLPBS1
NJT02-PLPBS1
NJT02-POMPBS1
NJT02-OPPBS1
NJT02-OPPBS1
NJT02-OPPBS1
NJT02-OPPBS1
NJT02-POMPBS1
NJT02-POMPBS1
NJT02-PERBS1
NJT02-PERBS1
NJT02-PERBS1
NJT02-POMPBS1
NJT02-BBPBS1
NJT02-BBPBS1
NJT02-BBPBS1
NJT02-OPPBS1
NJT02-WEEBS1
NJT02-WEEBS1
NJT02-WEEBS1
NJT02-BBPBS1
NJT02-POMPBS1
NJT02-BBPBS1
NJT02-BBPBS1
NJT02-OPPBS1
NJT02-WEEBS1
NJT02-WEEBS1
NJT02-WEEBS1
NJT02-WEEBS1
NJT02-WEEBS1
NJT02-OPPBS1
NJT02-OPPBS1
NJT02-OPPBS1
NJT02-WEEBS1
NJT02-POMPBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRDLBS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
BTR
BTR
BTR
BTR
BTR
RPF
RPF
RPF
RPF
RPF
RPF
RPF
RPF
RPF
PLP
PLP
PER
PER
PER
PLP
PLP
PLP
POMP
OPP
OPP
OPP
OPP
POMP
POMP
PER
PER
PER
POMP
BBP
BBP
BBP
OPP
WEE
WEE
WEE
BBP
POMP
BBP
BBP
OPP
WEE
WEE
WEE
WEE
WEE
OPP
OPP
OPP
WEE
POMP
PRDL
PRDL
PRDL
PRDL
PRDL
PRDL
PRDL
PRDL
PRDL
PRDL
PRDL
PRDL
PRDL
PRDL
PRDL
PRG
PRG
PRG
PRG
PRG
PRG
Booton Reservoir
Booton Reservoir
Booton Reservoir
Booton Reservoir
Booton Reservoir
Ramapo River at Pompton Feeder
Ramapo River at Pompton Feeder
Ramapo River at Pompton Feeder
Ramapo River at Pompton Feeder
Ramapo River at Pompton Feeder
Ramapo River at Pompton Feeder
Ramapo River at Pompton Feeder
Ramapo River at Pompton Feeder
Ramapo River at Pompton Feeder
Pompton River at Lincoln Park
Pompton River at Lincoln Park
Passaic River at Eagle Rock Ave
Passaic River at Eagle Rock Ave
Passaic River at Eagle Rock Ave
Pompton River at Lincoln Park
Pompton River at Lincoln Park
Pompton River at Lincoln Park
Pompton Lake
Overpeck Creek
Overpeck Creek
Overpeck Creek
Overpeck Creek
Pompton Lake
Pompton Lake
Passaic River at Eagle Rock Ave
Passaic River at Eagle Rock Ave
Passaic River at Eagle Rock Ave
Pompton Lake
Branch Brook Park
Branch Brook Park
Branch Brook Park
Overpeck Creek
Weequachic Lake
Weequachic Lake
Weequachic Lake
Branch Brook Park
Pompton Lake
Branch Brook Park
Branch Brook Park
Overpeck Creek
Weequachic Lake
Weequachic Lake
Weequachic Lake
Weequachic Lake
Weequachic Lake
Overpeck Creek
Overpeck Creek
Overpeck Creek
Weequachic Lake
Pompton Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Dundee Lake
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Garfield
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus dolomieu
Micropterus dolomieu
Micropterus dolomieu
Micropterus dolomieu
Micropterus dolomieu
Micropterus salmoides
Micropterus salmoides
Ameiurus natalis
Ameiurus natalis
Ameiurus natalis
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Esox lucius
Esox lucius
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Anguilla rostrata
Micropterus salmoides
Micropterus salmoides
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Cyprinus carpio
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Anguilla rostrata
Micropterus salmoides
Cyprinus carpio
Micropterus salmoides
Cyprinus carpio
Micropterus salmoides
Anguilla rostrata
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Micropterus salmoides
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Anguilla rostrata
Cyprinus carpio
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Morone saxatilis
Morone saxatilis
Morone saxatilis
Morone saxatilis
Ictalurus punctatus
Ictalurus punctatus
largemouth bass
largemouth bass
largemouth bass
smallmouth bass
smallmouth bass
smallmouth bass
smallmouth bass
smallmouth bass
largemouth bass
largemouth bass
yellow bullhead
yellow bullhead
yellow bullhead
largemouth bass
largemouth bass
largemouth bass
largemouth bass
northern pike
northern pike
common carp
common carp
common carp
largemouth bass
largemouth bass
largemouth bass
largemouth bass
American eel
largemouth bass
largemouth bass
common carp
common carp
common carp
common carp
largemouth bass
largemouth bass
largemouth bass
common carp
bluegill
bluegill
bluegill
common carp
common carp
common carp
common carp
American eel
largemouth bass
common carp
largemouth bass
common carp
largemouth bass
American eel
common carp
common carp
common carp
common carp
largemouth bass
largemouth bass
largemouth bass
largemouth bass
largemouth bass
common carp
common carp
common carp
common carp
American eel
common carp
American eel
American eel
American eel
American eel
striped bass
striped bass
striped bass
striped bass
channel catfish
channel catfish
The Academy of Natural Sciences
FTL cm LTL cm
48.7
52.2
48.3
43.4
48.4
29.7
26.4
35.0
29.4
30.1
24.5
23.4
26.9
34.2
34.6
39.2
30.2
41.3
44.5
49.9
57.5
58.7
37.6
36.4
39.9
41.2
49.0
52.3
49.0
58.5
56.5
60.3
75.5
43.6
47.0
44.5
61.2
16.4
17.3
17.4
69.0
66.8
72.5
69.5
35.8
35.1
50.5
47.5
56.2
45.9
63.7
51.7
63.7
71.0
58.8
28.2
27.0
37.8
25.2
31.1
53.5
54.8
54.8
58.7
51.2
62.9
34.7
45.5
56.2
61.5
49.6
57.6
49.0
54.4
50.4
48.2
47.8
52
47.6
42
47.2
28.6
25.3
35.1
25.4
29.5
24
22.6
26.2
33.8
34.3
39.4
29.7
41.2
44.3
49.5
57.5
58.5
37.4
36
39.4
40.5
48
52.3
48.5
57.6
56
59.5
75.1
43.7
46.5
44.7
60.5
16.3
17.5
17.5
68
66.4
71.8
68.9
35.7
35.6
50.8
47.5
55.6
44.4
63.5
52
64.2
71.3
59.1
28.5
26.6
37.5
25.1
30.8
53.2
54.7
55
58.2
51
62.4
34.5
45.3
56
61.5
49
56.6
48.8
54.6
50.3
47
Patrick Center for Environmental Research
Appendix II.i. Cont'd. Key to Summary of PCB and OCP Concentrations
CHEM ID Fish #
9453
9454
9455
9456
9457
9458
9459
9460
9461
9462
9463
9464
9465
9466
9467
9468
9469
9470
9471
9542
9544
9545
0246R2
0250R
9534R
9535R
9536R
9537R
9538R
9539R
9540R
9541R
9543R
F-2494
F-2495
F-2496
F-2497
F-2498
F-2499
F-2500
F-2501
F-2502
F-2503
F-2504
F-2505
F-2506
F-2507
F-2508
F-2509
F-2510
F-2511
F-2512
F-2521
F-2523
F-2524
F-2410
F-2414
F-2513
F-2514
F-2515
F-2516
F-2517
F-2518
F-2519
F-2520
F-2522
Fish Anal #
Serial Number
Station
Station Name
Scientific
Common Name
F-2494
F-2495
F-2496
F-2497
F-2498
F-2499
F-2500
F-2501
F-2502
F-2503
F-2504
F-2505
F-2506
F-2507
F-2508
F-2509
F-2510
F-2511
F-2512
F-2521
F-2523
F-2524
F-2410
F-2414
F-2513
F-2514
F-2515
F-2516
F-2517
F-2518
F-2519
F-2520
F-2522
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PRGWS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PRLBS1
NJT02-PRLBS1
NJT02-PRLBS1
NJT02-PERBS1
NJT02-PLPBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PREBS1
NJT02-PRLBS1
NJT02-PRLBS1
NJT02-PRLBS1
NJT02-PRLBS1
PRG
PRG
PRG
PRG
PRG
PRG
PRG
PRG
PRG
PRE
PRE
PRE
PRE
PRE
PRE
PRE
PRE
PRE
PRE
PRL
PRL
PRL
PER
PLP
PRE
PRE
PRE
PRE
PRE
PRL
PRL
PRL
PRL
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Garfield
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Lyndhurst
Passaic River at Lyndhurst
Passaic River at Lyndhurst
Passaic River at Eagle Rock Ave
Pompton River at Lincoln Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Elmwood Park
Passaic River at Lyndhurst
Passaic River at Lyndhurst
Passaic River at Lyndhurst
Passaic River at Lyndhurst
Catostomus commersoni
Cyprinus carpio
Catostomus commersoni
Cyprinus carpio
Cyprinus carpio
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Catostomus commersoni
Lepomis macrochirus
Lepomis macrochirus
Lepomis macrochirus
Cyprinus carpio
Cyprinus carpio
Micropterus salmoides
Ameiurus natalis
Micropterus salmoides
Ameiurus natalis
Micropterus salmoides
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Micropterus salmoides
Micropterus salmoides
Cyprinus carpio
Cyprinus carpio
Anguilla rostrata
Anguilla rostrata
Anguilla rostrata
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
Cyprinus carpio
white sucker
common carp
white sucker
common carp
common carp
American eel
American eel
American eel
white sucker
bluegill
bluegill
bluegill
common carp
common carp
largemouth bass
yellow bullhead
largemouth bass
yellow bullhead
largemouth bass
common carp
common carp
common carp
largemouth bass
largemouth bass
common carp
common carp
American eel
American eel
American eel
common carp
common carp
common carp
common carp
The Academy of Natural Sciences
FTL cm LTL cm
42.0
60.8
47.3
60.5
62.9
48.9
49.5
69.5
44.0
18.1
16.4
16.9
51.8
53.0
34.0
29.1
34.6
20.5
27.0
53.6
51.8
48.2
38.8
35.2
63.5
51.6
56.8
46.5
58.6
54.2
57.5
49.0
54.5
40.6
60.8
46.5
59.5
62.4
48.7
49
68.7
42.9
18.1
16.1
16.7
51.6
53
33.6
29
34.6
20
27.2
53.5
51.8
48.2
38.2
35.5
62.8
51
56.2
47.2
58.1
54.2
57
48.9
56.5
Patrick Center for Environmental Research
APPENDIX II.ii.
INDIVIDUAL SAMPLE DATA ORGANIC CONTAMINANTS
______________________________________________________________________________
THE ACADEMY OF NATURAL SCIENCES
74
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix II.ii.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
The Academy of Natrual Sciences
9424 Data 9425 Data 9426
Data
9427 Data 9428
Data
F-2473 Label F-2474 Label F-2475 Label F-2476 Label F-2477 Label
9429
F-2478
Data
Label
9430
F-2479
0.77
2.026
0.86
2.117
0.70
2.059
0.63
2.028
0.79
2.068
5.08
2.19
2.56
2.188
109
88
90
102
84
84
98
81
84
100
85
87
108
95
98
134
98
101
124
102
105
52.0
10.6
15.5
67.8
15.1
21.7
0.268
1.199
0.110
51.1
10.7
17.3
0.365
57.2
10.2
15.2
0.310
0.854
0.136
97.4
10.2
19.2
410.1
90.8
113.4
342.4
82.8
88.0
0.872
1.885
0.233
0.093
0.275
2.236
0.257
0.095
4.146
2.109
0.408
5.028
BDL
0.523
0.096
BDL
0.375
0.432
0.072
0.076
0.581
0.349
0.157
0.517
0.101
BDL
0.054
0.641
0.091
BDL
ND
0.473
0.049
ND
0.562
0.354
BDL
0.698
BDL
0.184
ND
0.516
0.295
0.153
0.543
BDL
0.224
BDL
1.504
0.446
0.666
0.117
0.061
1.241
1.120
2.098
0.459
0.909
0.496
1.470
0.130
0.184
0.125
0.918
1.214
3.705
0.291
1.446
1.640
1.099
0.069
0.556
0.468
0.606
0.065
2.465
0.149
0.420
0.257
0.268
1.219
1.765
0.020
0.567
4.276
0.059
0.153
3.988
0.301
0.145
1.230
0.535
0.638
0.068
0.303
0.241
0.245
0.095
0.200
1.593
0.207
0.042
0.013
1.312
0.632
0.807
0.067
0.479
0.034
0.305
0.023
0.416
0.028
ND
BDL
0.059
0.489
0.130
0.023
0.443
0.435
BDL
BDL
BDL
0.858
BDL
0.201
BDL
1.085
0.680
0.663
0.112
0.059
0.958
0.913
1.692
0.516
0.918
0.637
1.399
0.191
0.155
0.122
0.864
0.730
3.290
0.248
1.341
1.342
0.950
0.071
0.492
0.391
0.508
0.064
1.984
0.185
0.389
0.227
0.235
1.116
1.737
0.021
0.611
4.403
0.076
0.161
3.980
0.314
0.173
1.493
0.609
0.682
0.083
0.359
0.315
0.588
0.206
0.235
2.146
0.261
0.049
0.035
1.546
0.853
1.068
0.080
0.650
0.048
0.426
0.033
0.614
0.038
BDL
0.061
0.636
0.078
0.025
0.714
0.470
0.591
0.155
ND
1.786
0.779
0.836
0.144
0.080
1.398
1.351
2.614
0.417
1.256
0.763
1.393
0.219
0.226
0.187
1.201
1.246
4.605
0.350
1.767
1.949
1.326
0.097
0.685
0.546
0.794
0.107
2.926
0.204
0.528
0.300
0.331
1.526
2.220
0.026
0.779
5.901
0.090
0.189
5.402
0.390
0.226
1.787
0.767
0.917
0.107
0.444
0.368
0.725
0.247
0.281
2.462
0.306
0.061
0.031
1.902
0.881
1.210
0.152
0.679
0.057
0.423
0.039
0.544
0.035
ND
1.027
0.126
BDL
0.323
BDL
1.404
0.674
0.705
0.119
0.061
1.266
1.135
2.059
0.408
1.028
0.696
1.651
0.191
0.207
0.125
0.913
1.068
3.729
0.322
1.353
1.638
1.112
0.075
0.546
0.438
0.589
0.068
2.392
0.190
0.430
0.248
0.272
1.233
1.790
0.023
0.627
4.813
0.079
0.159
4.289
0.324
0.210
1.493
0.677
0.732
0.090
0.416
0.373
0.642
0.220
0.245
2.152
0.392
0.079
0.055
1.619
0.813
1.050
0.091
0.619
0.046
0.427
0.033
0.571
0.037
ND
1.658
0.348
0.098
0.314
2.839
0.449
0.046
4.481
2.492
0.493
6.005
BDL
2.546
1.133
1.082
0.208
0.085
1.830
1.760
3.242
0.435
1.469
0.808
2.437
0.286
0.475
0.188
1.421
1.937
5.791
0.514
3.085
2.576
1.675
0.113
0.782
0.666
0.820
0.206
3.353
0.242
1.051
0.525
0.414
2.544
2.555
0.050
1.081
8.821
0.335
0.349
7.362
0.501
0.465
2.906
1.431
1.079
0.238
1.098
0.938
1.089
0.445
0.529
4.797
0.477
0.129
0.066
3.665
1.632
2.089
0.195
1.207
0.062
0.913
0.076
0.751
0.036
BDL
1.748
0.798
15.593
6.261
5.665
1.176
0.498
9.851
9.832
11.257
1.957
10.136
6.306
13.739
1.892
0.809
0.929
7.313
10.934
29.852
2.607
10.388
11.054
8.346
0.688
3.860
3.159
ND
0.879
17.556
1.373
3.048
2.109
1.702
8.275
11.068
0.191
3.701
29.441
0.963
ND
27.091
1.776
1.438
9.576
4.308
4.302
0.724
3.088
2.709
3.726
1.730
1.740
17.111
1.838
0.408
0.234
12.316
6.244
8.119
0.776
5.521
0.321
3.573
0.236
4.705
0.262
Data
Label
BDL
1.610
0.610
13.678
5.765
4.965
1.175
0.522
8.598
7.937
8.209
2.098
9.306
5.641
12.521
1.638
0.560
0.738
5.899
9.108
26.525
2.363
8.881
9.460
6.147
0.619
3.322
2.717
2.772
0.859
16.307
1.258
2.973
2.040
1.470
8.157
8.335
0.174
2.958
22.622
0.966
1.019
20.875
1.421
1.142
7.898
3.016
3.154
0.578
2.924
2.424
2.692
1.413
1.328
11.226
1.173
0.468
0.267
8.244
4.862
5.693
0.717
4.067
0.239
2.379
0.166
3.638
0.219
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9424 Data 9425 Data 9426
Data
9427 Data 9428
Data
F-2473 Label F-2474 Label F-2475 Label F-2476 Label F-2477 Label
9429
F-2478
Data
Label
9430
F-2479
Data
Label
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
alpha BHC
beta BHC
delta BHC
lindane
0.265
3.049
3.173
0.369
4.816
4.330
BDL
0.556
3.544
10.587
BDL
0.788
4.834
15.137
BDL
ND
0.677
BDL
0.135
1.088
1.080
1.843
1.236
3.583
0.903
5.810
15.543
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
2.025
1.480
0.355
BDL
1.145
1.367
2.292
2.082
5.179
1.083
8.536
21.683
2.230
BDL
BDL
1.665
0.520
BDL
1.285
1.016
1.471
1.004
3.240
0.860
6.331
15.205
3.973
0.096
1.458
BDL
1.005
0.347
1.792
0.887
1.561
1.135
3.042
1.862
8.903
19.182
1.809
BDL
BDL
0.974
0.305
3.194
28.503
10.603
BDL
6.844
29.489
90.774
BDL
BDL
ND
BDL
BDL
BDL
BDL
3.604
37.391
13.446
0.665
1.946
10.250
BDL
BDL
BDL
BDL
0.785
1.147
1.040
2.817
4.477
0.942
6.116
17.324
0.960
0.263
0.484
5.010
2.146
0.558
3.345
10.224
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.361
3.178
2.783
0.855
3.384
10.673
BDL
0.322
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
0.341
3.180
2.913
BDL
8.294
32.204
82.798
BDL
0.972
BDL
0.460
BDL
BDL
0.441
0.331
12.469
5.408
5.677
17.524
34.654
5.868
31.798
113.398
11.246
2.586
3.421
15.641
26.399
4.292
24.394
87.978
10.135
0.180
0.623
7.323
1.337
4.878
0.182
0.416
2.061
0.787
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9431
F-2480
Data
9432
Data
Label F-2481 Label
9433
F-2482
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
6.64
2.04
5.48
2.0545
9.32
2.008
5.51
2.018
12.92
2.003
4.06
2.004
2.01
2.028
135
95
99
123
98
102
121
107
107
144
95
99
120
92
90
114
96
101
123
103
108
440.2
100.5
139.3
1.118
1.800
0.455
0.131
0.371
3.264
0.163
0.079
3.735
2.319
0.331
3.982
357.0
91.2
117.3
0.285
1.024
0.226
0.148
0.318
2.889
0.087
0.110
2.487
1.385
0.234
2.330
265.1
120.5
156.5
0.447
2.130
0.100
320.6
72.4
87.8
1.691
1.782
0.378
0.151
0.290
3.149
0.735
0.068
4.198
2.946
0.530
5.780
328.5
99.5
141.7
0.408
0.994
0.249
291.7
110.9
111.9
0.232
0.721
0.099
182.3
75.6
73.1
The Academy of Natrual Sciences
BDL
2.219
0.895
19.148
4.385
6.521
0.711
0.125
12.062
12.091
7.192
1.580
11.825
4.725
11.697
1.784
0.497
1.059
7.565
12.291
31.638
2.574
11.014
11.702
7.578
0.682
3.911
3.290
1.953
0.886
17.946
1.306
3.962
2.257
1.865
9.376
11.688
0.188
4.134
33.019
1.046
1.212
30.650
1.947
1.724
12.240
4.687
4.480
0.775
3.273
3.069
4.072
1.656
2.027
20.226
1.965
0.464
0.236
13.556
7.277
9.006
0.721
6.118
0.364
4.217
0.264
5.515
0.280
BDL
0.043
0.461
0.064
0.087
0.207
0.169
BDL
0.396
BDL
1.475
0.569
14.620
3.098
5.336
1.508
0.115
8.838
8.479
5.060
1.130
8.579
3.403
8.845
1.093
0.266
0.837
6.475
10.050
26.295
1.764
8.999
10.265
7.127
0.568
3.528
2.970
1.871
0.715
14.488
0.840
3.064
1.872
1.722
7.194
10.955
0.177
3.471
28.436
0.830
1.136
26.995
1.718
1.360
10.095
4.000
3.916
0.561
2.455
2.939
3.471
1.215
1.438
16.024
1.430
0.360
0.197
11.279
6.113
7.457
0.771
5.002
0.337
3.376
0.166
4.530
0.243
Data
Label
9434
F-2483
BDL
0.370
0.553
2.947
0.504
3.910
0.789
0.082
7.326
1.450
7.506
0.642
2.129
0.811
9.468
0.387
2.109
0.603
6.001
0.837
10.117
1.069
2.694
5.552
5.350
0.387
0.846
1.255
1.974
0.269
18.317
0.374
1.052
0.839
0.941
7.320
10.582
0.309
4.666
28.955
0.325
0.999
31.350
1.911
1.526
14.794
3.782
4.051
0.236
1.519
3.076
1.725
1.154
1.225
11.901
2.067
0.317
0.126
8.815
5.176
5.293
0.575
3.110
0.245
1.733
0.292
2.317
0.112
Data
9435
Data
9436
Label F-2484 Label F-2485
BDL
0.054
0.814
0.108
0.085
0.434
0.223
BDL
BDL
0.140
BDL
0.340
BDL
3.064
0.639
4.460
0.236
0.225
9.629
2.047
9.051
0.538
3.717
1.611
7.539
0.948
0.550
0.540
4.708
0.676
15.480
1.509
2.697
6.436
15.417
0.538
1.355
1.899
3.420
0.474
21.326
0.701
4.284
0.941
1.125
12.586
11.642
0.260
5.539
33.465
0.730
1.121
38.275
1.806
1.700
20.511
3.389
3.806
0.327
2.286
3.151
1.573
1.121
4.261
14.634
6.943
0.331
0.062
8.945
6.172
4.697
0.613
2.596
0.131
1.578
0.088
1.944
0.075
BDL
BDL
BDL
0.266
0.030
0.019
0.127
0.066
0.456
BDL
BDL
0.114
BDL
2.430
0.477
3.028
0.123
0.120
8.384
1.791
7.234
0.632
3.257
1.210
7.971
0.401
0.440
0.465
4.789
0.510
12.529
1.254
2.637
5.949
7.085
0.482
1.860
2.024
3.398
0.303
19.426
0.574
1.449
0.750
0.970
7.157
14.524
0.247
4.867
34.792
0.498
1.339
36.942
2.457
1.538
10.537
3.900
4.539
0.201
1.945
2.837
1.693
1.337
4.357
17.215
3.996
0.421
0.048
10.009
4.750
5.240
0.595
2.869
0.158
1.832
0.105
2.031
0.083
Data
Label
BDL
BDL
BDL
BDL
0.349
9437
F-2486
1.014
0.327
0.055
0.050
0.254
0.174
0.687
BDL
1.595
0.564
15.567
2.220
5.503
1.049
0.670
8.998
8.946
10.270
1.639
9.753
5.629
11.716
1.951
0.723
0.735
5.420
9.539
24.894
2.014
8.061
8.108
4.117
0.554
2.756
2.215
2.528
0.697
13.984
1.067
2.677
1.526
1.171
7.524
8.187
0.165
2.566
19.680
0.723
0.801
19.480
1.165
0.932
6.748
2.452
2.148
0.498
2.251
2.023
1.336
0.942
3.295
11.972
3.044
0.281
0.109
6.864
3.506
4.143
0.556
2.458
0.120
1.696
0.119
2.148
0.106
Data
Label
BDL
0.939
0.190
1.568
ND
0.046
4.481
0.680
3.897
0.368
1.045
0.497
4.733
0.170
0.300
0.255
3.915
0.155
4.271
0.497
1.154
2.639
2.732
0.304
0.523
0.724
0.768
0.088
7.066
0.112
0.262
0.231
0.520
3.587
6.872
0.266
3.837
24.577
0.104
1.293
25.479
1.655
1.313
8.905
3.091
2.848
0.113
0.750
2.219
2.303
0.917
3.762
13.802
3.743
0.317
0.022
7.601
4.192
4.546
0.492
2.732
0.135
1.700
0.136
1.988
0.093
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9431
F-2480
Data
9432
Data
Label F-2481 Label
9433
F-2482
3.371
39.188
18.036
2.809
35.549
15.946
3.381
60.989
21.856
0.945
0.765
32.530
120.465
Data
Label
9434
F-2483
Data
9435
Data
9436
Label F-2484 Label F-2485
Data
Label
9437
F-2486
Data
Label
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
BDL
5.694
34.228
100.519
BDL
3.829
33.073
91.206
BDL
4.855
40.727
16.488
BDL
5.021
24.347
72.391
BDL
1.621
35.789
99.479
BDL
0.595
33.253
110.859
0.738
0.523
1.269
0.490
0.319
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
4.469
7.945
8.236
25.537
52.056
5.579
35.481
139.304
1.548
7.138
7.526
18.372
45.131
4.825
32.724
117.262
2.261
20.964
15.113
11.273
14.815
13.062
79.003
156.491
13.416
6.006
3.633
15.939
7.707
7.711
33.398
87.811
2.842
20.799
10.424
14.632
14.201
13.917
64.889
141.705
1.392
10.208
9.952
5.741
6.356
14.331
63.919
111.899
0.583
5.007
2.264
0.791
0.500
13.904
50.064
73.114
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
14.746
0.124
1.107
6.749
1.804
14.264
0.113
1.278
3.342
1.424
42.060
0.224
0.676
0.596
14.788
11.275
62.800
0.212
0.814
2.561
12.140
25.037
ND
1.362
ND
BDL
ND
0.167
15.362
75.584
0.601
ND
2.240
BDL
1.632
51.676
6.747
0.709
1.109
BDL
3.495
55.083
18.433
alpha BHC
beta BHC
delta BHC
lindane
1.351
BDL
5.149
28.492
9.383
2.556
BDL
BDL
0.343
7.885
1.343
BDL
1.127
BDL
BDL
0.476
ND
BDL
10.859
BDL
0.252
0.954
10.312
BDL
0.287
0.259
7.024
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9438
F-2487
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
10.74
2.049
2.26
2.037
0.79
2.11
0.83
2.182
116
90
99
115
95
99
116
95
105
492.8
240.5
261.1
308.7
173.8
33.7
0.365
0.725
0.159
563.6
118.8
73.8
0.189
0.465
The Academy of Natrual Sciences
Data
Label
BDL
0.531
0.129
BDL
BDL
0.283
0.098
0.109
0.248
0.122
BDL
0.315
9447
F-2488
BDL
3.575
0.141
5.266
0.862
0.116
10.169
2.134
10.129
2.024
3.571
3.316
13.008
0.579
0.680
0.817
5.571
0.860
19.041
1.689
5.313
7.035
11.407
0.704
2.168
2.680
6.738
0.319
26.123
0.747
1.865
0.900
1.554
8.930
23.860
0.202
8.020
60.123
0.631
2.550
59.081
4.046
2.547
17.450
7.820
7.288
0.309
3.327
5.294
3.062
2.104
9.017
40.883
7.193
0.766
0.070
22.151
10.313
12.265
1.153
7.025
0.402
4.862
0.316
6.005
0.249
9448
Data
F-2489 Label
0.187
0.983
0.220
0.024
2.922
1.767
0.258
3.370
9451
F-2492
Data
9452
Data
Label F-2493 Label
1.26
2.059
2.79
2.017
3.36
2.016
116
101
111
111
90
98
115
95
99
120
98
102
484.7
106.6
70.5
543.6
104.7
78.7
0.196
0.574
403.2
115.7
90.3
265.6
99.9
88.4
0.204
0.578
0.275
BDL
BDL
BDL
0.033
0.413
0.052
0.029
0.741
0.544
BDL
1.108
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.351
0.252
0.695
0.054
0.037
0.468
0.463
1.689
0.469
3.222
0.863
1.961
0.344
0.135
7.471
7.609
10.036
1.711
5.357
4.045
7.556
1.194
2.047
1.026
9.940
10.411
30.964
2.500
10.365
14.347
15.274
0.410
4.907
3.540
6.091
0.760
21.454
1.309
5.342
2.332
2.540
10.568
18.549
0.162
7.405
52.499
1.071
1.546
42.406
2.828
1.691
14.485
8.096
4.483
1.065
2.957
2.245
5.968
1.804
7.175
38.217
5.552
0.762
0.098
19.668
6.617
11.046
1.314
5.362
0.277
4.234
0.203
3.378
0.163
Data
Label
0.040
0.609
0.083
0.027
1.275
0.996
0.946
BDL
0.735
0.257
5.770
1.260
2.197
0.407
0.132
10.146
10.930
13.136
2.475
7.478
5.977
14.487
1.569
2.359
1.334
11.837
17.556
38.537
3.169
15.261
17.328
17.807
0.399
6.143
4.371
7.580
0.887
26.133
1.765
5.847
2.528
2.803
12.025
19.873
0.184
7.609
54.340
1.260
1.466
45.527
3.022
1.824
15.163
8.276
5.022
1.084
3.247
2.547
6.566
2.268
7.923
37.148
5.887
0.677
0.108
19.390
7.603
11.583
1.739
6.126
0.392
4.593
0.265
4.270
0.220
Data
9450
Label F-2491
0.484
0.053
0.458
0.043
0.020
0.847
0.606
BDL
1.156
0.434
11.045
1.253
3.440
0.936
0.411
10.224
7.938
7.812
1.510
9.327
4.968
7.652
1.772
0.706
0.892
8.122
9.810
28.426
1.677
13.755
8.009
8.955
4.978
2.529
1.958
2.947
0.608
12.593
0.890
3.405
1.452
1.359
5.545
10.076
0.397
3.612
23.584
0.632
0.775
17.328
0.869
1.381
6.059
2.712
1.440
0.346
1.180
1.502
2.594
0.826
2.476
12.601
1.588
0.240
0.040
6.225
2.264
3.512
0.484
1.787
0.101
1.096
0.046
1.365
0.094
9449
F-2490
BDL
BDL
BDL
BDL
0.550
Data
Label
0.661
0.110
0.044
0.798
0.461
BDL
0.974
BDL
1.102
0.443
10.697
2.319
3.217
0.567
0.164
11.211
11.099
13.037
2.101
9.001
6.551
11.787
1.498
1.986
1.193
11.008
19.677
35.156
2.933
14.386
14.526
16.383
0.860
5.211
3.584
5.883
0.769
22.935
1.460
4.710
2.106
2.299
10.224
17.163
0.275
6.966
50.141
0.999
1.640
40.637
2.593
1.597
15.075
8.179
4.225
0.953
2.956
2.489
6.235
2.101
7.980
38.366
5.251
0.712
0.079
18.338
8.333
13.079
1.505
6.783
0.411
5.284
0.264
5.203
0.259
BDL
BDL
BDL
0.443
BDL
0.106
BDL
0.134
BDL
0.762
0.239
1.431
0.945
0.056
2.770
5.648
9.548
1.075
0.936
1.523
6.380
0.370
1.239
0.773
9.034
0.453
18.221
1.030
6.522
7.454
17.737
0.654
0.834
1.156
4.164
0.102
6.288
0.138
3.226
1.367
1.966
3.139
16.919
0.242
6.883
54.245
0.320
0.419
40.598
3.149
2.347
16.169
8.315
5.008
0.676
3.163
0.421
3.477
1.763
9.344
41.789
6.859
0.794
0.063
21.268
8.946
12.120
1.172
6.047
0.305
5.219
0.241
4.171
0.150
BDL
1.619
0.386
1.593
1.200
0.096
3.074
4.930
7.504
0.752
1.078
1.833
2.451
0.335
1.357
0.505
7.217
0.392
15.208
1.349
4.818
5.739
6.841
0.543
0.844
0.605
3.144
0.166
2.369
0.040
2.697
1.402
0.938
4.885
10.927
0.237
4.502
35.948
0.665
0.288
23.578
1.798
1.629
10.093
4.964
2.736
0.633
3.307
0.596
3.449
1.169
5.310
24.560
3.778
0.475
0.094
12.135
5.042
6.523
0.812
3.390
0.171
2.621
0.136
2.307
0.092
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9438
F-2487
Data
Label
9447
F-2488
Data
Label
9448
Data
F-2489 Label
9449
F-2490
Data
9450
Label F-2491
3.022
91.619
8.352
2.813
79.926
9.204
3.445
80.050
7.441
Data
Label
9451
F-2492
Data
9452
Data
Label F-2493 Label
2.181
84.459
8.421
2.741
68.822
7.509
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
alpha BHC
beta BHC
delta BHC
lindane
4.563
144.333
34.286
2.230
1.562
53.552
240.526
7.946
140.433
1.709
BDL
3.640
20.065
173.795
BDL
2.731
BDL
1.407
14.402
118.803
ND
BDL
BDL
BDL
1.305
BDL
BDL
1.539
13.147
106.628
BDL
BDL
1.079
12.712
104.727
BDL
BDL
BDL
BDL
1.335
19.288
115.684
BDL
0.216
BDL
1.788
19.015
99.875
BDL
0.697
BDL
BDL
1.004
BDL
BDL
0.606
0.377
0.132
0.160
0.236
0.427
0.469
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
2.187
14.353
22.815
13.891
44.905
12.514
150.394
261.060
6.117
2.726
0.366
1.027
0.195
8.619
14.615
33.664
6.444
1.832
0.896
1.388
1.107
16.514
45.575
73.755
5.292
1.793
2.102
2.103
2.200
14.956
42.088
70.534
7.949
2.987
1.224
1.596
2.557
16.170
46.221
78.704
1.371
3.613
3.008
7.756
3.547
17.746
53.219
90.260
2.199
7.905
3.359
8.597
4.282
14.187
47.854
88.383
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
41.005
0.104
0.448
0.995
11.254
6.150
4.904
BDL
BDL
3.423
0.392
4.894
BDL
BDL
1.319
1.054
6.950
ND
BDL
1.455
1.107
8.481
BDL
0.193
2.870
1.889
13.551
BDL
BDL
1.811
2.217
BDL
0.233
3.266
2.675
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
The Academy of Natrual Sciences
9453
Data
9454
Data
F-2494 Label F-2495 Label
9455
F-2496
Data
Label
9456
F-2497
Data
Label
9457
F-2498
Data
9458
Data
9459
Data
Label F-2499 Label F-2500 Label
0.89
2.003
2.13
2.04
1.83
2.008
4.15
2.003
3.74
2.018
0.59
2.016
0.46
2.019
115
95
99
116
93
101
118
96
103
99
77
84
118
95
114
109
95
101
100
82
89
167.3
34.1
37.2
0.220
0.764
327
65
43
0.258
0.533
124.0
77.6
109.7
510.4
149.1
130.6
1148.4
219.4
137.2
0.197
0.413
0.100
0.045
0.126
1.677
0.210
0.050
4.676
1.282
0.350
4.996
88.1
34.1
32.5
156.0
46.5
31.3
BDL
BDL
0.050
0.449
0.090
0.046
0.454
0.567
BDL
BDL
0.038
0.488
BDL
BDL
0.755
0.327
BDL
1.034
BDL
BDL
0.063
0.512
0.102
0.022
0.351
0.568
BDL
0.568
BDL
0.279
BDL
1.071
BDL
0.496
BDL
2.268
1.138
1.337
0.458
0.180
0.744
3.387
3.799
0.469
2.933
2.003
4.383
0.422
0.335
0.382
3.532
3.434
10.903
1.019
3.803
4.142
6.730
0.149
1.734
1.375
2.052
0.274
9.221
0.511
1.252
0.746
0.862
4.032
6.443
0.098
2.229
17.510
0.387
0.434
14.625
0.918
0.672
4.245
2.051
1.492
0.303
0.995
0.882
0.847
0.687
2.331
9.596
2.807
0.217
0.046
4.988
1.919
2.548
0.321
1.467
0.077
0.992
0.068
1.076
0.050
BDL
0.426
BDL
0.109
1.122
0.191
0.050
2.480
1.021
0.220
2.972
BDL
0.274
BDL
5.258
0.886
1.913
0.481
0.055
4.767
4.382
1.576
0.471
4.193
1.333
4.827
0.695
0.608
0.534
4.629
4.783
16.131
1.155
5.345
8.436
5.791
0.463
2.652
2.081
0.954
0.384
13.885
0.697
1.915
1.658
1.193
9.108
10.582
0.223
4.118
36.683
0.769
1.232
28.681
1.819
1.769
10.127
6.178
2.454
0.850
4.551
3.410
3.695
1.361
6.883
32.942
4.512
0.582
0.175
15.662
6.776
10.087
0.926
5.274
0.242
4.496
0.214
3.185
0.166
BDL
0.387
0.136
BDL
2.004
0.424
1.563
0.826
0.191
0.557
2.511
2.144
0.397
2.397
1.639
3.682
0.347
0.207
0.351
2.638
3.502
8.892
0.950
3.994
3.103
2.473
0.207
1.472
1.211
1.230
0.219
7.955
0.621
0.739
0.744
0.618
3.573
5.298
0.053
1.324
10.196
0.231
0.413
9.848
0.681
0.365
2.254
1.003
0.997
0.117
0.889
0.782
0.599
0.404
1.184
3.861
9.630
0.105
0.028
2.507
1.051
1.358
0.231
0.784
0.038
0.512
0.046
0.458
0.019
BDL
0.950
0.317
11.287
1.458
3.979
0.771
0.304
9.703
9.313
9.141
1.861
9.591
6.060
13.727
1.574
0.717
0.880
8.730
11.260
34.817
3.106
12.841
13.435
7.896
0.707
4.652
3.785
4.916
0.945
23.313
1.608
3.679
2.775
1.938
13.236
16.776
0.154
5.280
43.871
1.428
1.780
38.484
2.429
2.046
13.226
7.213
3.899
1.074
6.432
4.669
5.301
1.929
8.016
36.696
9.325
0.658
0.242
19.903
8.040
11.308
1.271
5.921
0.239
5.029
0.269
3.372
0.151
ND
BDL
BDL
BDL
BDL
BDL
BDL
0.018
BDL
BDL
BDL
BDL
BDL
BDL
2.445
0.451
24.288
3.149
9.066
1.844
0.410
21.946
23.341
20.451
5.336
24.463
16.632
37.598
3.501
1.229
2.836
28.818
21.785
91.208
6.739
40.932
29.463
17.739
1.704
10.897
9.469
11.234
1.699
51.308
3.828
7.264
5.877
5.071
28.004
46.176
0.408
13.165
100.899
2.780
4.171
89.607
6.590
4.162
26.436
15.440
9.203
2.289
11.679
9.516
5.638
4.066
15.095
69.231
16.414
1.099
0.407
37.244
15.663
22.558
2.600
11.617
0.574
8.313
0.460
8.297
0.451
0.030
ND
BDL
BDL
BDL
BDL
BDL
0.034
0.019
BDL
0.029
BDL
BDL
BDL
0.023
BDL
0.188
BDL
BDL
BDL
0.028
0.989
0.088
1.195
BDL
0.158
0.083
0.295
0.145
0.055
1.179
0.086
2.702
BDL
0.141
0.123
1.201
0.025
0.112
0.074
0.332
BDL
0.173
0.245
1.619
0.031
0.306
0.084
0.435
BDL
0.932
0.149
0.401
0.430
1.119
0.079
0.114
BDL
1.357
0.144
0.482
0.690
3.858
0.143
0.209
BDL
0.676
0.054
2.918
0.025
0.031
0.117
0.247
1.144
3.381
0.021
1.962
13.780
0.028
0.563
13.187
0.902
0.872
4.555
1.990
1.560
BDL
1.772
0.040
4.822
0.081
0.064
0.201
0.502
1.769
6.544
0.044
3.203
25.157
0.148
0.750
21.282
1.357
1.567
7.417
3.622
2.184
ND
0.327
1.435
1.458
0.466
2.487
8.121
1.975
0.200
ND
4.659
2.711
3.224
0.332
1.960
0.100
1.297
0.081
1.434
0.060
ND
0.653
2.188
2.682
0.818
4.366
16.800
3.368
0.345
0.100
9.210
4.410
5.538
0.552
3.022
0.163
2.120
0.132
2.368
0.099
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9453
Data
9454
Data
F-2494 Label F-2495 Label
9455
F-2496
1.626
21.981
3.478
2.643
39.568
13.819
2.084
2.964
16.490
77.569
Data
Label
9456
F-2497
Data
Label
9457
F-2498
Data
9458
Data
9459
Data
Label F-2499 Label F-2500 Label
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
2.369
46.468
4.565
BDL
0.810
6.223
34.118
BDL
0.838
10.469
64.709
BDL
BDL
BDL
BDL
BDL
BDL
5.202
87.489
17.410
5.611
33.422
149.134
0.200
0.328
0.133
0.346
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
2.782
2.129
0.862
2.850
1.777
6.505
20.315
37.220
0.721
2.169
1.087
4.612
1.964
9.842
22.805
43.200
2.574
4.884
7.323
14.156
31.527
5.113
44.089
109.665
7.322
4.673
5.775
20.980
35.154
8.482
48.240
130.627
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
4.887
14.208
0.123
0.263
16.567
0.737
10.824
3.432
0.260
5.032
4.382
3.782
0.518
ND
BDL
1.804
0.620
NQ
NQ
NQ
NQ
BDL
alpha BHC
beta BHC
delta BHC
lindane
BDL
BDL
9.367
210.022
BDL
0.244
219.389
BDL
NQ
NQ
NQ
NQ
0.825
ND
ND
11.328
NQ
NQ
NQ
NQ
24.399
101.487
137.213
ND
NQ
NQ
NQ
NQ
NQ
0.370
21.239
6.071
0.276
32.826
6.404
BDL
0.076
6.380
34.136
BDL
BDL
6.977
46.483
BDL
BDL
BDL
ND
BDL
0.185
BDL
BDL
0.256
1.258
3.215
0.275
0.792
2.248
BDL
3.973
2.242
21.520
32.463
BDL
3.177
3.752
21.104
31.348
2.824
1.534
BDL
BDL
BDL
1.808
ND
BDL
BDL
1.276
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
The Academy of Natrual Sciences
9460
Data
9461
Data
9462
Data
9463
Data
9464
Data 9465
Data
9466
Data
F-2501 Label F-2502 Label F-2503 Label F-2504 Label F-2505 Label F-2506 Label F-2507 Label
4.59
2.015
1.20
2.0075
0.43
2.007
0.86
2.006
0.52
2.002
2.60
2
3.21
2.004
105
94
101
101
88
95
100
83
98
89
84
88
97
84
90
128
97
105
94
84
90
445.3
181.4
171.8
277.3
68.4
56.1
740.9
21.3
43.6
63.4
14.8
15.2
23.0
3.6
4.3
366.3
65.4
76.1
280.5
60.4
68.8
0.252
0.997
0.135
0.036
0.163
1.596
0.096
0.046
2.460
1.292
0.263
2.374
BDL
4.711
BDL
0.578
BDL
BDL
BDL
0.134
0.033
0.017
0.079
0.052
BDL
0.096
BDL
BDL
0.032
0.465
0.175
0.168
0.436
0.837
0.168
1.549
BDL
0.148
BDL
1.615
0.388
0.046
6.078
0.507
6.776
0.364
1.068
0.420
7.658
0.222
0.541
0.431
2.122
0.185
5.568
0.882
1.575
5.086
7.263
0.345
0.477
1.699
3.373
0.152
17.066
0.150
0.287
0.726
1.354
8.339
16.725
0.140
10.153
61.384
0.199
3.096
60.592
5.001
4.458
20.199
10.066
8.403
0.136
1.709
6.988
7.573
2.425
12.168
39.882
9.858
0.925
0.023
23.962
12.305
14.999
1.467
8.389
0.421
5.903
0.350
6.163
0.208
BDL
BDL
BDL
0.029
0.506
0.086
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
0.230
0.254
0.686
2.505
0.530
1.372
0.166
0.033
1.960
1.463
1.672
0.449
1.374
0.746
2.073
0.158
0.105
0.156
1.040
1.925
4.839
0.350
1.717
2.127
1.324
0.083
0.593
0.550
0.748
0.160
3.355
0.219
0.658
0.342
0.224
1.739
2.006
0.029
0.669
5.069
0.167
0.222
4.302
0.687
0.248
1.514
0.620
0.522
0.112
0.471
0.413
0.279
2.239
25.376
1.982
0.815
BDL
0.112
0.083
0.637
0.132
1.023
1.352
0.467
1.018
0.048
0.044
2.637
2.152
3.146
0.549
0.457
0.674
1.688
0.301
0.543
0.498
5.593
6.423
16.665
2.835
3.471
41.408
28.910
0.073
11.455
8.847
24.262
0.266
31.095
0.494
7.497
5.356
5.809
19.847
60.977
0.239
16.353
113.497
0.252
3.337
138.963
30.946
1.393
10.918
9.205
27.554
0.809
1.731
2.356
4.721
28.073
3.199
6.210
1.772
3.632
0.120
3.369
0.266
2.216
0.039
0.270
0.048
0.533
0.305
0.271
BDL
4.618
1.037
1.773
0.275
0.232
0.589
5.597
6.708
1.149
4.734
3.655
9.376
0.628
0.646
0.654
6.254
8.256
19.188
1.541
8.695
6.283
6.434
0.229
2.949
2.230
3.728
0.387
15.237
0.943
1.863
1.264
1.379
6.334
11.147
0.057
3.894
28.513
0.571
0.778
24.327
1.520
1.312
7.044
3.485
2.477
0.394
1.633
1.510
1.454
1.127
3.881
15.758
3.277
0.567
0.096
8.504
3.219
4.408
0.663
2.391
0.156
1.623
0.138
1.655
0.072
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.182
0.148
BDL
ND
BDL
0.399
0.305
0.056
0.507
0.997
BDL
0.326
BDL
0.095
0.753
0.953
0.260
0.635
0.029
BDL
0.437
0.350
BDL
BDL
0.330
0.225
0.295
0.056
0.030
0.043
0.302
0.509
1.053
0.060
0.486
0.472
0.354
0.018
0.149
BDL
ND
0.155
1.667
0.434
0.033
0.019
1.133
0.602
0.736
0.070
0.412
0.018
0.243
0.019
0.279
0.016
BDL
0.636
0.146
0.051
0.116
1.065
0.074
0.034
1.328
0.738
0.193
1.452
0.189
0.023
0.543
0.037
0.158
0.083
0.057
0.398
0.695
0.006
0.248
2.688
0.045
0.065
2.023
0.277
0.151
0.743
0.401
0.200
0.048
0.142
0.191
0.251
0.099
0.098
1.334
0.312
0.042
0.014
0.711
0.480
0.619
0.080
0.318
0.025
0.238
0.020
0.314
0.019
BDL
0.857
0.450
7.567
1.592
2.907
0.498
0.298
8.362
6.077
2.850
0.570
7.147
2.998
7.583
1.014
0.124
0.692
5.270
7.562
25.599
1.728
6.962
11.745
6.504
0.654
3.918
3.067
2.893
0.904
18.832
1.416
3.195
2.354
1.328
10.543
12.869
0.173
4.338
36.712
1.046
1.447
32.077
4.793
1.716
11.023
5.422
3.943
0.875
3.749
3.592
3.809
1.507
1.494
19.838
1.615
0.425
0.277
12.747
6.471
8.412
1.123
5.274
0.252
3.836
0.211
3.191
0.137
BDL
1.185
0.783
11.128
2.917
4.281
0.625
0.113
7.133
6.333
3.264
1.076
7.518
2.298
7.066
1.091
0.208
0.634
4.712
7.598
21.736
1.416
6.573
7.690
4.403
0.521
2.588
1.947
1.834
0.628
12.769
0.791
2.349
1.575
0.823
7.111
7.382
0.125
2.788
22.487
0.773
0.829
19.000
2.755
1.129
7.711
3.338
2.262
0.533
2.580
2.208
2.647
1.126
0.977
12.074
1.615
0.270
0.201
7.649
5.283
6.321
0.608
4.290
0.237
2.657
0.143
3.858
0.179
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9460
Data
9461
Data
9462
Data
9463
Data
9464
Data 9465
Data
9466
Data
F-2501 Label F-2502 Label F-2503 Label F-2504 Label F-2505 Label F-2506 Label F-2507 Label
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
2.369
108.771
33.040
1.477
0.523
35.204
181.385
1.910
42.192
7.992
0.969
1.737
13.636
68.436
alpha BHC
beta BHC
delta BHC
lindane
BDL
0.514
0.166
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
1.064
9.817
17.662
7.478
26.699
14.471
94.591
171.783
4.218
1.523
3.519
3.914
11.530
6.755
24.681
56.140
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
26.454
0.222
0.398
0.174
9.457
3.752
0.238
8.188
7.206
1.699
1.061
2.911
21.303
BDL
BDL
BDL
1.306
BDL
BDL
BDL
BDL
BDL
0.146
0.746
4.701
BDL
1.338
16.815
19.858
43.603
ND
ND
BDL
BDL
BDL
2.945
0.391
0.490
4.009
4.661
0.820
0.615
4.216
14.810
0.907
0.705
0.100
0.998
1.073
BDL
0.159
1.240
3.570
ND
ND
ND
BDL
0.413
BDL
3.101
26.666
13.153
0.874
3.500
18.100
65.394
2.717
17.382
12.360
0.948
4.669
22.346
60.421
0.293
1.508
0.254
2.701
ND
ND
0.175
0.288
0.434
0.408
0.400
1.607
2.214
0.639
2.800
0.575
6.954
15.188
0.071
1.016
0.730
1.022
3.988
4.886
13.501
28.426
3.552
20.703
76.078
0.971
4.458
4.036
14.667
26.852
3.003
14.785
68.774
5.960
0.336
6.446
0.399
BDL
0.886
BDL
1.617
4.321
1.548
ND
BDL
BDL
BDL
BDL
3.702
0.987
0.978
0.289
BDL
5.466
0.956
BDL
2.661
0.839
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
The Academy of Natrual Sciences
9467
Data
F-2508 Label
9468
F-2509
Data
9469
Data
9470
Data
9471
Data
Label F-2510 Label F-2511 Label F-2512 Label
9534R
F-2513
Data 9535R Data
Label F-2514 Label
0.92
2.065
0.73
2.076
0.88
2.009
0.72
2.012
0.70
2.009
4.12
2.114
1.64
2.201
109
87
100
112
99
111
109
86
98
113
89
103
114
84
98
90
81
92
102
82
93
82.4
19.4
20.4
39.1
8.6
15.4
72.2
19.3
18.4
36.5
6.9
11.0
70.7
19.1
20.8
610.4
102.9
101.8
0.248
4.870
0.200
0.079
0.189
1.774
0.115
0.051
2.700
1.629
0.299
2.888
144.7
32.2
36.5
0.327
1.153
BDL
0.470
BDL
0.476
BDL
BDL
0.106
0.322
0.036
0.197
0.607
0.331
BDL
BDL
BDL
0.164
BDL
0.057
0.098
0.031
BDL
0.548
BDL
0.146
BDL
0.235
0.600
1.861
0.956
0.842
0.126
0.083
1.756
1.398
1.560
0.872
1.288
0.648
1.987
0.193
0.131
0.184
1.327
1.641
5.576
0.377
1.756
2.416
1.621
0.095
0.727
0.572
1.018
0.109
3.733
0.241
0.672
0.393
0.323
2.169
2.964
0.024
1.161
9.082
0.111
0.230
7.447
1.147
0.383
2.689
1.145
0.842
0.130
0.570
0.574
0.511
0.321
0.268
3.322
0.164
0.075
0.023
2.271
1.167
1.435
0.142
0.817
0.039
0.570
0.032
0.652
0.027
BDL
BDL
BDL
0.186
0.303
0.049
0.114
0.454
0.216
0.173
0.405
BDL
0.069
0.612
0.363
BDL
0.464
0.043
0.028
0.731
0.497
BDL
0.311
0.326
0.194
0.621
0.060
0.043
0.086
0.617
0.153
2.229
0.118
0.604
1.010
0.849
0.031
0.168
BDL
0.544
0.034
1.238
0.017
0.283
0.168
0.132
0.760
1.864
0.005
0.630
4.517
0.077
0.077
4.411
0.664
0.196
1.462
0.636
0.507
0.088
0.370
0.142
0.218
0.186
0.198
2.623
0.195
0.063
0.018
1.700
0.910
1.142
0.136
0.642
0.030
0.462
0.024
0.490
0.029
BDL
BDL
BDL
BDL
BDL
0.431
0.160
BDL
0.028
0.115
0.061
BDL
BDL
BDL
0.287
0.042
0.084
0.444
0.263
BDL
0.175
BDL
0.215
0.376
1.281
0.355
0.755
0.095
0.065
1.524
1.236
1.445
0.721
1.020
0.739
1.706
0.167
0.132
0.155
1.232
1.316
5.115
0.356
1.552
2.389
1.577
0.092
0.682
0.557
1.021
0.103
3.451
0.192
0.598
0.357
0.274
1.987
2.812
0.025
0.944
7.550
0.093
0.223
6.673
1.017
0.285
2.127
0.869
0.828
0.124
0.467
0.411
0.387
0.280
0.251
2.888
0.342
0.060
0.041
2.023
1.000
1.229
0.138
0.714
0.048
0.494
0.031
0.598
0.027
BDL
0.368
BDL
0.468
BDL
0.049
0.700
0.298
0.181
0.252
0.052
0.021
0.561
0.447
BDL
BDL
0.433
0.199
0.517
0.060
0.029
0.059
0.306
0.137
2.226
0.175
0.404
0.807
0.625
0.053
0.240
0.268
0.403
0.092
1.788
0.081
0.467
0.208
0.110
1.414
0.969
0.015
0.607
3.662
0.129
0.162
3.617
0.434
0.210
2.128
0.535
0.356
0.096
0.561
0.383
0.268
0.177
0.191
2.142
0.236
0.038
0.034
1.310
1.070
1.006
0.074
0.781
0.033
0.413
0.028
0.580
0.040
BDL
0.207
0.388
1.779
0.519
0.895
0.111
0.055
1.703
1.315
1.329
BDL
1.205
0.747
1.813
0.162
0.103
0.147
1.165
1.777
5.354
0.362
1.852
2.331
1.600
0.083
0.672
0.560
0.886
0.111
3.524
0.220
0.605
0.365
0.247
1.930
2.689
0.021
0.873
7.124
0.111
0.211
6.059
0.965
0.253
1.894
0.811
0.724
0.105
0.492
0.414
0.375
0.256
0.236
2.644
BDL
0.052
0.015
1.846
0.847
1.089
0.124
0.613
0.027
0.462
0.032
0.452
0.022
BDL
0.035
0.073
0.628
0.088
0.018
0.890
0.545
BDL
1.155
BDL
1.777
0.800
15.418
3.615
6.149
0.712
0.141
12.103
10.794
5.260
1.280
12.799
4.320
14.360
2.097
0.272
1.056
9.486
14.167
40.819
2.608
14.006
16.771
9.445
0.907
5.536
4.347
4.338
1.513
28.473
2.047
5.891
4.200
1.791
18.212
17.431
0.238
6.699
57.644
2.257
2.221
48.414
7.282
3.304
18.843
10.025
5.356
1.634
8.822
6.760
4.309
2.530
2.730
36.953
0.871
0.629
0.523
24.176
11.254
14.875
1.346
8.519
0.278
6.885
0.317
4.588
0.158
BDL
0.459
BDL
3.688
0.661
1.549
0.297
0.174
2.923
2.639
2.813
0.307
2.865
1.743
3.302
0.515
0.242
0.246
1.838
2.874
8.996
0.676
2.656
3.637
2.389
0.220
1.059
0.874
1.323
0.333
5.142
0.447
1.189
0.762
0.465
3.303
3.767
0.055
1.612
13.139
0.431
0.459
10.546
1.561
1.077
4.961
2.159
1.146
0.303
1.278
1.494
1.473
0.702
0.661
8.551
0.332
0.156
0.113
4.765
3.609
4.351
0.374
2.925
0.139
1.999
0.089
2.885
0.115
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9467
Data
F-2508 Label
9468
F-2509
Data
9469
Data
9470
Data
9471
Data
Label F-2510 Label F-2511 Label F-2512 Label
9534R
F-2513
Data 9535R Data
Label F-2514 Label
4.740
40.878
19.140
1.422
5.074
31.680
102.934
1.376
9.884
7.629
2.617
10.655
32.161
0.509
4.855
0.345
0.469
1.572
0.498
0.392
1.292
5.697
6.796
22.067
40.022
1.569
2.333
2.011
7.401
13.261
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
0.546
5.331
5.902
0.943
1.061
5.656
19.438
alpha BHC
beta BHC
delta BHC
lindane
1.040
0.225
0.229
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
0.423
1.462
2.584
2.150
5.353
1.092
7.333
20.397
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
1.718
0.152
3.510
2.697
0.497
6.219
5.860
0.790
1.007
4.944
19.316
0.262
1.352
2.057
0.717
0.441
2.097
6.927
0.286
0.099
0.252
0.221
2.672
0.216
0.382
0.166
0.748
0.213
1.259
1.943
1.931
4.617
0.507
4.967
15.437
0.429
1.330
2.782
1.549
4.309
0.948
7.099
18.445
0.160
0.717
1.239
2.001
3.471
0.355
3.010
10.953
0.301
0.145
1.398
BDL
0.240
2.011
8.611
BDL
BDL
BDL
3.349
0.656
ND
ND
2.442
0.525
ND
ND
0.966
BDL
BDL
0.436
1.629
2.995
2.268
5.817
0.766
6.860
20.772
0.165
ND
BDL
BDL
0.842
0.444
0.556
5.877
5.611
0.649
1.001
5.386
19.080
0.924
0.349
BDL
BDL
3.351
0.648
BDL
ND
2.091
ND
BDL
BDL
ND
25.886
101.761
9.925
36.500
12.039
0.651
0.502
8.967
1.250
3.731
0.231
0.218
3.786
0.430
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9536R
F-2515
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
1.50
2.024
1.58
1.907
3.08
2.127
3.85
2.678
6.92
2.219
6.85
2.313
3.98
2.026
109
87
104
127
95
111
130
94
113
131
83
107
132
85
109
140
90
108
121
83
104
184.1
78.7
82.9
0.516
1.265
211.4
66.4
55.5
0.371
1.177
223.4
86.0
87.8
0.575
1.697
0.117
934.3
248.7
152.7
0.388
2.265
0.264
0.088
0.275
2.193
0.490
0.101
6.608
3.237
0.717
8.508
790.4
204.1
195.3
0.421
1.458
0.315
0.089
0.357
3.121
0.772
0.124
11.127
5.460
1.264
13.564
938.5
184.1
158.2
1.064
3.972
0.379
0.135
0.423
3.755
0.692
0.148
10.283
5.559
1.059
12.821
622.2
128.4
103.7
0.548
1.909
0.299
0.097
0.372
3.964
0.686
0.139
8.899
5.141
0.811
10.818
The Academy of Natrual Sciences
Data 9537R Data 9538R Data 9539R Data 9540R Data 9541R Data
Label F-2516 Label F-2517 Label F-2518 Label F-2519 Label F-2520 Label
BDL
0.035
0.053
0.180
BDL
BDL
BDL
0.176
BDL
0.070
BDL
0.040
BDL
0.047
0.191
0.042
BDL
0.098
BDL
0.087
BDL
0.138
BDL
BDL
BDL
0.526
BDL
1.272
0.063
0.065
3.130
0.534
3.058
BDL
1.096
0.033
0.040
4.025
0.653
3.259
BDL
0.873
0.888
3.249
0.159
0.183
0.305
1.419
0.226
5.671
0.578
1.430
2.727
5.070
0.261
0.510
0.758
2.524
0.165
9.033
0.205
0.643
0.326
0.466
4.398
8.539
0.077
3.944
27.371
0.229
0.831
26.074
3.877
1.793
9.681
3.320
3.169
0.103
1.046
2.154
2.581
ND
0.912
11.375
1.014
0.220
0.026
7.348
4.008
4.309
0.396
2.549
0.088
1.712
0.096
1.798
0.066
BDL
0.177
0.080
0.802
BDL
0.069
0.306
0.075
0.145
0.171
0.079
BDL
1.160
1.014
3.595
0.127
0.151
0.238
1.124
0.166
5.757
0.576
1.126
3.971
4.146
0.283
0.704
1.058
2.014
0.158
11.636
0.168
0.693
0.510
0.574
6.474
8.733
0.097
5.676
29.717
0.228
1.113
31.100
4.345
2.048
16.583
3.702
3.471
0.107
1.232
2.830
2.463
1.003
1.059
10.837
1.866
0.216
0.019
7.304
5.114
4.542
0.429
2.626
0.097
1.892
0.096
1.577
0.055
BDL
0.223
0.341
1.239
0.136
1.853
0.091
0.120
4.553
0.882
4.803
0.254
1.353
1.312
4.929
0.290
0.306
0.498
2.664
0.386
7.780
0.615
2.336
3.521
6.812
0.253
0.676
1.198
3.525
0.211
12.086
0.305
1.034
0.483
0.628
4.321
11.796
0.097
4.255
30.912
0.344
0.908
29.685
4.303
2.103
9.845
3.531
3.553
0.168
1.242
2.313
1.162
1.037
0.976
13.088
1.556
0.236
0.031
8.234
4.359
4.660
0.461
2.913
0.128
1.787
0.102
2.076
0.098
BDL
2.514
0.990
21.415
10.349
8.196
2.166
0.890
22.357
22.694
24.346
3.947
25.539
16.268
35.541
4.645
2.612
2.372
19.715
16.002
75.402
5.322
26.528
26.505
17.324
1.780
8.757
6.628
10.873
2.007
43.578
3.034
7.587
5.254
2.999
23.081
27.238
0.288
9.709
73.767
2.455
2.572
62.054
9.463
3.542
23.317
11.465
6.967
1.919
9.915
6.250
7.996
3.819
3.322
41.930
3.863
0.846
0.602
28.360
12.630
17.381
2.006
10.216
0.464
8.036
0.424
6.922
0.261
BDL
4.521
1.473
37.014
4.630
13.424
3.144
1.487
24.806
23.795
25.355
4.408
29.830
17.811
40.231
5.311
2.403
1.980
18.257
25.217
73.283
4.287
29.611
19.939
12.080
1.386
6.862
4.927
8.243
1.737
34.328
2.683
6.202
3.862
2.168
16.870
18.712
0.231
6.079
45.868
1.895
1.626
39.614
5.333
2.058
15.025
6.114
3.990
1.124
6.194
4.265
4.624
2.149
1.626
23.581
2.419
0.531
0.411
15.093
6.912
8.991
1.323
5.242
0.254
3.776
0.199
3.414
0.134
9542
F-2521
BDL
4.149
1.785
39.514
4.927
14.536
2.854
1.340
25.865
26.621
28.105
5.735
29.865
18.542
40.850
5.160
2.876
2.331
20.407
31.014
83.607
6.071
33.273
27.479
18.517
1.815
9.191
7.041
11.428
2.163
46.379
3.463
7.117
5.008
3.320
20.601
29.046
0.315
8.151
62.710
2.034
2.238
55.942
8.234
2.179
15.022
7.295
6.641
1.056
6.842
4.904
2.885
3.123
2.285
28.237
3.324
0.744
0.385
18.056
7.505
9.621
1.615
6.177
0.304
4.212
0.314
3.699
0.154
Data
Label
BDL
3.076
1.417
31.906
4.615
10.217
2.145
1.038
17.652
17.287
18.266
4.549
21.026
12.645
28.086
3.650
1.737
1.459
12.606
21.503
53.983
3.152
22.417
15.885
8.882
1.154
5.415
3.773
6.077
1.350
25.764
1.929
4.650
2.910
1.620
13.408
14.565
0.178
4.727
38.285
1.613
1.345
31.672
4.111
1.936
12.104
5.452
3.159
0.968
4.856
3.549
3.980
2.030
1.543
20.415
2.127
0.446
0.302
12.701
6.554
8.254
1.036
5.402
0.300
3.759
0.291
3.509
0.133
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9536R
F-2515
Data 9537R Data 9538R Data
Label F-2516 Label F-2517 Label
9539R
F-2518
Data
Label
9540R Data 9541R Data
9542
F-2519 Label F-2520 Label F-2521
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
1.144
31.885
23.188
2.187
0.680
19.655
78.737
alpha BHC
beta BHC
delta BHC
lindane
0.225
1.646
0.954
33.233
13.402
3.658
0.872
14.235
66.355
1.373
40.947
21.513
2.116
0.620
19.478
86.046
8.586
128.739
24.054
0.445
18.854
68.064
248.742
8.545
81.441
23.275
1.658
24.664
64.501
204.084
9.372
97.271
17.271
1.443
15.610
43.101
184.069
6.237
63.715
12.156
0.882
12.201
33.249
128.440
0.298
0.967
0.091
0.336
0.240
2.271
0.143
0.422
0.393
3.737
0.142
0.547
0.363
5.159
0.415
0.546
0.238
3.160
0.268
0.390
0.239
3.412
0.111
0.284
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
0.433
4.536
11.298
7.669
21.930
2.873
34.128
82.867
0.373
3.873
5.917
4.614
14.162
2.943
23.615
55.499
0.795
7.319
13.298
6.469
19.512
3.825
36.587
87.804
16.411
5.536
5.268
31.634
51.037
7.681
35.131
152.699
23.418
9.822
6.851
47.394
73.388
4.910
29.532
195.317
21.727
6.824
4.420
32.440
51.988
6.957
33.865
158.220
17.178
3.928
2.697
21.703
32.962
3.685
21.542
103.695
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
10.553
0.107
7.668
0.146
14.672
0.236
0.186
0.500
6.191
12.930
0.797
25.950
0.572
0.309
5.577
1.517
17.451
0.885
9.799
0.167
BDL
BDL
BDL
0.343
5.032
BDL
0.425
3.198
BDL
2.996
1.282
BDL
5.341
1.053
1.962
0.644
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9543R
F-2522
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
5.11
2.066
3.89
1.976
128
82
110
1260.12
277.70
123.61
0.414
1.649
0.409
0.127
0.449
5.119
0.365
The Academy of Natrual Sciences
Data
Label
ND
11.583
6.422
0.995
13.063
9544
F-2523
81
F-2372
Data
82
Data
Label F-2373 Label
83
F-2374
3.38
2.032
2.83
2.001
1.42
2.063
1.68
2.075
3.27
2.044
112
93
99
101
91
95
100
91
97
102
100
104
102
93
103
104
93
99
874.2
180.0
215.1
0.271
1.020
0.320
0.067
0.183
2.560
0.333
0.116
7.384
3.560
0.535
7.916
890.5
150.5
104.0
0.372
0.582
0.312
0.073
0.239
2.521
0.325
0.026
7.169
4.004
0.513
8.079
455.1
127.8
37.3
209.4
45.3
16.3
1018.4
269.5
79.6
0.243
0.844
384.1
109.6
36.6
BDL
4.616
1.835
46.597
13.419
15.333
2.654
0.378
27.819
28.795
23.738
5.913
32.529
16.460
41.575
6.255
1.230
2.648
26.564
30.833
96.015
5.428
39.138
30.522
21.051
1.960
10.313
9545
F-2524
BDL
2.740
0.839
22.398
5.985
10.476
6.318
0.368
21.078
20.170
ND
ND
9.327
2.427
46.633
3.911
10.530
6.307
4.329
28.578
35.534
0.382
13.418
101.506
3.284
3.270
82.458
12.017
4.952
38.267
16.555
8.371
2.487
12.467
9.215
11.190
3.975
4.612
67.657
5.611
1.005
0.815
43.791
18.540
26.295
2.621
14.942
0.601
13.460
0.486
10.095
0.347
Data
Label
5.343
24.907
11.870
27.741
4.689
1.982
1.930
15.446
18.985
64.663
5.075
29.894
21.372
13.493
1.532
7.694
5.538
25.242
1.785
36.588
2.686
7.500
4.707
2.751
22.419
22.901
0.472
9.466
67.447
2.618
0.649
58.316
8.154
2.568
24.639
11.192
7.936
1.805
9.515
6.636
8.296
2.780
3.545
40.360
4.449
1.028
0.642
28.270
14.089
19.267
1.789
11.847
0.797
8.717
0.562
9.711
0.259
Data
Label
BDL
0.560
0.644
0.056
0.104
0.163
BDL
BDL
BDL
BDL
BDL
BDL
0.026
0.238
0.103
0.055
0.059
BDL
BDL
BDL
0.179
BDL
2.998
0.846
25.899
7.396
10.092
1.906
0.316
22.038
22.643
18.045
4.627
25.340
12.402
29.676
5.014
1.055
2.298
18.041
20.351
69.921
5.166
26.033
24.179
14.749
1.528
8.899
5.924
5.612
1.980
36.583
2.580
7.790
5.107
3.239
22.431
25.693
0.564
10.447
71.860
2.830
2.745
60.011
8.361
3.847
22.155
11.090
8.600
1.813
8.618
7.084
7.971
2.578
3.204
36.565
17.718
1.020
0.661
25.405
11.946
15.856
1.641
9.192
0.522
6.498
0.382
6.496
0.188
BDL
0.321
0.082
BDL
0.071
BDL
1.030
0.165
0.716
0.138
0.050
3.157
2.253
2.611
0.478
2.156
1.216
2.866
0.618
0.335
0.343
2.261
4.144
18.698
2.183
6.849
13.505
9.045
1.008
3.763
2.601
4.489
1.023
20.717
1.404
5.940
3.660
2.131
16.449
14.528
0.385
10.551
68.301
1.574
3.997
57.369
7.194
3.461
17.186
9.556
9.489
1.269
5.576
6.187
6.421
2.186
2.690
29.291
3.017
0.693
0.222
19.868
8.627
11.386
1.097
5.171
0.341
4.123
0.237
2.855
0.066
84
F-2375
BDL
0.429
0.418
BDL
0.027
0.210
BDL
0.035
0.086
0.033
BDL
0.145
BDL
0.113
BDL
0.122
BDL
0.069
BDL
1.179
0.188
0.691
0.199
0.079
4.789
3.648
3.666
0.977
2.616
1.977
4.401
BDL
0.746
0.611
4.394
7.214
36.374
4.507
12.613
27.950
20.768
2.041
8.042
6.041
12.072
1.412
45.409
2.600
13.167
7.901
5.032
35.822
35.006
0.733
23.385
151.201
2.517
8.852
134.565
19.792
7.749
37.817
24.285
25.974
2.982
12.535
13.140
8.998
5.199
6.923
80.022
6.525
1.413
0.326
51.501
19.178
26.215
2.099
11.589
0.747
9.754
0.583
5.521
0.101
Data
Label
BDL
0.039
0.063
0.195
0.048
0.075
0.202
0.088
BDL
0.049
0.422
0.417
0.077
0.226
0.048
0.023
1.373
0.913
1.179
0.276
0.657
0.430
1.142
0.213
0.149
0.145
0.976
1.702
8.117
0.952
2.941
6.222
3.879
0.370
1.597
1.187
1.659
0.325
8.964
0.488
2.587
1.457
0.977
7.437
6.806
0.142
4.846
33.283
0.552
1.296
26.482
3.267
1.568
8.755
4.542
4.021
0.569
2.329
2.732
3.027
1.011
1.373
14.143
1.357
0.317
0.071
9.155
4.331
5.888
0.472
2.744
0.201
2.213
0.148
1.669
0.039
Data
Label
BDL
0.937
0.147
0.850
0.136
0.026
2.897
2.260
2.193
0.577
1.596
1.078
2.469
0.613
0.256
0.324
2.507
3.653
17.602
2.088
5.864
11.511
7.401
0.929
3.115
2.413
4.545
0.920
18.666
1.176
5.013
3.366
1.695
14.035
12.754
0.484
8.282
56.430
1.697
ND
47.738
5.895
3.039
14.009
7.763
7.983
1.057
5.061
5.889
5.449
1.971
2.341
24.739
2.166
0.494
0.223
16.402
7.381
9.223
0.744
4.331
0.278
3.503
0.207
2.247
0.044
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
9543R
F-2522
Data
Label
9544
F-2523
Data
Label
9545
F-2524
ND
5.290
68.759
18.385
Data
Label
81
F-2372
Data
82
Data
Label F-2373 Label
83
F-2374
BDL
1.769
81.475
13.777
1.767
2.933
26.031
127.752
0.625
29.636
5.922
0.976
0.885
7.273
45.318
185.458
32.891
4.349
5.581
41.261
269.539
Data
Label
84
F-2375
Data
Label
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
10.553
165.167
19.184
1.157
20.252
61.389
277.703
alpha BHC
beta BHC
delta BHC
lindane
0.310
4.600
0.322
0.383
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
10.515
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
45.519
32.029
1.346
16.994
84.101
179.988
BDL
1.928
BDL
1.295
BDL
NQ
NQ
31.217
43.076
9.181
29.622
123.610
12.794
0.504
BDL
2.773
0.764
8.349
49.754
150.539
BDL
BDL
BDL
BDL
BDL
0.273
BDL
BDL
BDL
0.230
0.228
5.515
6.904
7.347
42.485
71.741
7.975
73.112
215.080
5.289
4.073
3.028
24.320
24.572
6.923
35.826
104.032
0.287
0.785
2.850
1.423
3.842
4.891
23.246
37.324
15.658
0.372
0.362
1.749
1.834
8.695
0.181
0.173
1.232
0.828
2.551
0.080
0.161
1.195
0.496
1.477
2.007
10.930
16.345
BDL
0.322
BDL
BDL
BDL
BDL
BDL
1.684
BDL
0.672
0.078
BDL
0.211
0.851
2.622
1.658
3.777
5.547
21.944
36.610
2.338
BDL
BDL
BDL
0.494
ND
69.994
10.878
1.830
2.952
23.969
109.623
0.293
0.474
3.823
1.844
5.599
11.933
55.599
79.565
0.408
BDL
BDL
BDL
1.132
ND
1.991
0.104
BDL
0.145
1.371
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
85
F-2376
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
3.85
2.045
1.01
2.003
0.86
2.02
0.76
2.038
0.89
2.043
0.79
2.003
0.29
2.014
110
97
109
104
93
97
100
92
96
104
95
100
101
93
97
94
85
85
89
83
81
621.8
107.8
55.0
31.6
3.5
3.8
18.7
1.6
2.7
96.4
4.8
6.6
47.1
4.9
8.1
52.4
11.4
6.4
0.324
0.627
15.2
5.2
4.3
The Academy of Natrual Sciences
Data
235
Data
236
Data
237
Data
238
Data
239
Data
240
Data
Label F-2399 Label F-2400 Label F-2401 Label F-2402 Label F-2403 Label F-2404 Label
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.349
0.656
BDL
0.036
0.263
BDL
0.038
0.163
0.098
0.020
0.070
0.058
BDL
0.166
0.095
BDL
BDL
BDL
0.040
BDL
0.035
BDL
0.361
BDL
0.124
0.067
BDL
0.329
0.304
BDL
BDL
0.349
0.239
0.538
0.064
0.038
0.065
0.507
0.440
2.156
0.177
0.638
1.088
0.697
0.077
0.338
0.320
0.387
0.050
1.299
0.104
0.272
0.205
0.151
1.146
1.330
0.023
0.544
3.631
0.072
BDL
0.133
0.032
0.721
0.044
0.151
0.142
0.092
0.759
0.738
0.016
0.324
2.146
0.055
BDL
1.850
0.255
0.484
0.575
0.223
0.334
0.036
0.233
0.205
0.153
0.068
0.107
0.744
0.953
0.018
0.015
0.473
0.258
0.260
0.035
0.168
0.014
0.111
0.022
0.098
0.009
0.146
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.027
BDL
0.261
0.089
0.144
0.030
0.042
0.504
0.498
0.367
0.128
BDL
ND
0.079
0.048
BDL
0.280
BDL
BDL
0.328
0.263
0.630
0.069
0.114
0.074
0.686
0.613
2.527
0.206
0.746
1.733
1.198
0.061
0.466
0.371
1.398
0.036
1.923
0.105
0.368
0.112
0.222
1.561
2.037
0.038
0.923
6.301
0.066
BDL
5.164
0.673
0.193
1.369
0.607
0.820
0.076
0.353
0.280
0.350
0.176
0.217
1.754
3.207
0.044
BDL
0.095
BDL
BDL
BDL
1.081
0.191
0.612
0.148
0.113
1.746
1.350
1.890
0.549
1.132
0.802
0.910
0.216
0.120
0.133
1.202
1.428
4.841
0.311
2.089
1.788
1.253
0.341
0.539
1.042
0.672
0.055
2.131
0.202
0.361
0.267
0.211
1.366
1.953
0.021
0.536
4.114
0.060
0.198
3.376
0.573
0.134
0.729
0.435
0.491
0.077
0.306
0.234
0.263
BDL
0.025
0.313
0.230
BDL
0.237
BDL
0.025
0.354
0.341
ND
BDL
0.203
0.149
0.255
0.030
BDL
0.047
0.410
0.236
1.348
0.072
0.526
0.474
0.451
0.052
0.123
0.463
0.202
0.027
0.673
ND
0.138
0.111
0.084
0.424
0.639
0.009
0.233
1.507
0.038
0.065
1.360
0.226
0.069
0.336
0.191
0.176
0.050
0.113
0.066
0.078
ND
BDL
1.263
0.557
0.689
0.098
0.415
0.045
0.240
0.030
0.265
0.014
0.034
0.179
0.153
0.325
0.089
0.239
0.030
0.033
0.671
0.540
BDL
BDL
0.293
0.249
0.610
0.086
0.050
0.107
0.802
0.424
3.495
0.374
0.770
2.860
2.131
0.155
0.814
0.630
1.630
0.167
3.363
0.281
1.018
0.670
0.479
3.834
4.019
0.082
2.113
14.466
0.441
0.233
12.109
1.521
0.443
3.675
1.670
1.867
0.216
1.262
1.125
1.045
0.505
0.528
4.796
5.792
0.114
0.067
3.208
1.962
2.120
0.173
1.354
0.119
0.728
0.057
0.950
0.034
0.399
0.311
0.044
ND
0.059
0.082
BDL
BDL
BDL
BDL
BDL
BDL
0.101
0.039
BDL
0.290
0.177
0.140
0.250
0.039
0.047
0.034
0.373
0.208
1.257
0.081
0.373
0.614
0.430
0.040
0.196
ND
3.004
0.384
0.151
0.926
0.363
0.484
0.056
0.332
0.282
0.277
0.120
0.164
1.244
2.084
0.036
0.023
0.768
0.521
0.556
0.063
0.348
0.025
0.212
BDL
0.239
0.012
0.142
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.027
0.191
0.173
0.069
0.027
0.556
0.484
BDL
0.391
0.051
BDL
BDL
BDL
BDL
BDL
0.084
0.097
1.078
0.205
0.803
0.195
0.038
4.360
3.236
3.384
0.593
2.685
1.704
3.748
0.894
0.384
0.523
3.424
5.528
28.116
3.375
8.852
17.899
11.796
1.466
5.005
3.879
12.183
1.456
29.324
1.805
8.002
5.344
2.744
23.663
21.362
0.648
13.767
90.467
2.788
4.359
78.318
9.804
4.850
22.202
12.672
13.675
1.715
8.381
9.228
8.879
2.956
3.573
38.446
3.956
0.706
0.326
26.397
11.270
14.256
1.164
6.718
0.419
5.263
0.306
3.322
0.069
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.119
1.070
1.109
0.047
0.043
0.866
0.434
0.529
0.131
0.320
0.038
0.196
ND
BDL
0.471
BDL
BDL
0.015
0.385
0.166
0.217
0.047
0.122
0.017
0.065
ND
0.215
0.070
ND
0.083
0.033
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
85
F-2376
Data
235
Data
236
Data
237
Data
238
Data
239
Data
240
Data
Label F-2399 Label F-2400 Label F-2401 Label F-2402 Label F-2403 Label F-2404 Label
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
alpha BHC
beta BHC
delta BHC
lindane
2.863
45.702
18.013
2.690
3.091
35.432
107.791
ND
1.400
1.577
BDL
0.103
0.372
3.453
BDL
0.471
0.285
0.952
4.154
2.086
6.367
7.289
33.826
54.959
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
3.353
0.120
BDL
0.490
0.391
2.433
3.779
0.164
0.093
0.122
0.318
BDL
BDL
BDL
0.197
0.945
BDL
0.261
1.245
4.610
6.649
0.030
0.077
BDL
0.485
0.758
5.662
8.103
BDL
BDL
BDL
BDL
BDL
BDL
0.167
0.145
BDL
0.641
3.471
5.944
BDL
0.160
1.200
11.417
0.049
BDL
0.222
BDL
BDL
BDL
BDL
0.283
0.425
0.302
0.733
0.759
0.514
0.926
0.306
2.816
6.356
0.125
0.359
0.645
0.573
0.962
ND
1.657
4.323
0.510
BDL
BDL
0.358
0.196
0.158
1.491
2.652
0.631
0.273
5.204
0.309
0.502
BDL
BDL
BDL
0.268
0.258
1.653
2.680
ND
BDL
BDL
BDL
BDL
BDL
BDL
0.161
0.340
BDL
BDL
0.736
4.919
0.541
BDL
0.397
BDL
BDL
BDL
0.068
ND
1.268
2.915
0.325
4.849
0.449
BDL
BDL
BDL
0.111
1.194
BDL
BDL
BDL
ND
2.366
2.157
0.091
0.265
1.638
0.302
BDL
BDL
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
ND
0.410
0.871
ND
BDL
BDL
BDL
BDL
0.777
0.173
0.171
0.175
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
The Academy of Natrual Sciences
241
Data
242
Data
244
Data
245
Data
F-2405 Label F-2406 Label F-2408 Label F-2409 Label
0246R2
F-2410
Data
247
Data
248
Data
Label F-2411 Label F-2412 Label
0.37
2.034
0.36
2.053
0.84
2.007
1.18
2.024
1.02
2.004
0.38
2.022
0.35
2.033
89
83
82
86
72
72
91
88
89
92
81
82
141
91
99
66
59
57
85
79
78
21.3
3.6
2.5
34.3
7.5
4.7
144.0
29.5
6.8
112.2
48.6
25.3
0.408
46.3
33.1
22.9
3.736
0.330
22.2
6.9
3.4
0.212
35.4
36.3
13.3
BDL
BDL
BDL
BDL
BDL
0.222
BDL
BDL
BDL
BDL
BDL
0.239
BDL
ND
0.109
0.073
BDL
BDL
0.114
BDL
0.064
0.283
0.378
0.094
0.399
0.031
0.022
0.860
0.871
BDL
0.241
0.108
0.257
0.038
0.032
0.813
0.628
BDL
BDL
BDL
0.108
0.806
0.327
2.484
0.125
1.162
0.727
0.480
0.092
0.205
0.591
0.337
0.020
1.295
0.029
0.126
0.105
0.094
0.627
0.783
0.005
0.216
1.269
0.026
0.065
1.268
0.197
0.063
0.343
0.182
0.167
0.022
0.119
0.070
0.070
ND
BDL
0.406
BDL
BDL
0.010
0.372
0.184
0.253
0.044
0.134
0.013
0.075
0.017
0.081
0.031
BDL
0.035
0.331
BDL
BDL
0.149
0.101
0.144
0.148
BDL
0.034
0.427
0.333
0.733
0.040
0.082
BDL
BDL
0.116
0.062
0.180
BDL
BDL
BDL
BDL
0.497
0.217
0.530
0.065
0.027
0.095
0.810
0.207
2.997
0.181
1.101
1.220
0.949
0.116
0.351
0.933
0.605
0.066
1.867
0.118
0.324
0.225
0.178
1.242
1.621
0.020
0.530
3.217
0.080
0.214
3.360
0.578
0.152
0.844
0.381
0.472
0.058
0.401
0.308
0.187
BDL
0.025
0.022
0.936
0.484
0.527
0.080
0.306
0.020
0.178
BDL
0.180
0.084
0.621
0.070
0.305
2.564
0.445
BDL
BDL
0.405
0.342
0.328
0.525
0.099
0.124
0.095
0.864
0.704
3.157
0.288
1.216
3.864
3.148
0.309
1.034
1.370
1.292
0.046
3.324
0.158
0.968
0.561
0.699
3.966
6.031
0.027
3.577
28.607
1.107
0.501
20.171
3.368
0.543
5.980
3.291
2.248
0.283
0.923
0.664
1.379
BDL
ND
BDL
BDL
BDL
BDL
0.185
0.113
BDL
0.231
BDL
BDL
ND
ND
0.979
0.802
BDL
0.073
BDL
0.528
0.089
0.389
0.077
0.047
0.814
0.725
BDL
3.104
0.389
0.282
0.151
0.078
0.055
0.048
0.537
0.504
0.955
0.222
1.220
1.579
1.017
0.104
0.367
0.819
0.390
0.059
2.007
0.054
0.322
0.247
0.147
1.389
1.475
0.016
0.575
4.290
0.064
0.098
3.753
0.705
0.149
1.180
0.439
0.329
0.086
0.235
0.171
0.221
0.045
0.121
1.280
BDL
0.190
0.086
0.418
0.473
0.828
0.063
BDL
0.486
0.134
0.490
0.090
0.068
0.794
0.752
BDL
BDL
0.490
0.362
0.501
0.080
0.038
0.063
0.615
0.657
2.156
0.136
1.197
0.721
0.478
0.090
0.230
0.509
0.276
0.024
0.877
0.075
0.133
0.116
0.074
0.520
0.747
0.010
0.226
1.726
0.016
0.045
1.371
0.175
0.060
0.364
0.184
0.170
0.031
0.120
0.106
0.092
BDL
BDL
0.586
0.366
0.451
0.115
0.040
0.059
0.521
0.684
2.490
0.286
1.288
1.325
0.846
0.211
0.390
0.784
0.477
0.066
1.737
0.123
0.355
0.222
0.152
1.289
1.291
0.022
0.506
3.837
0.054
0.117
3.061
0.477
0.127
0.950
0.434
0.403
0.062
0.258
0.191
0.225
ND
0.098
0.600
BDL
0.058
0.029
0.972
0.660
0.757
0.140
0.402
0.030
0.268
0.028
0.344
0.094
0.543
0.162
0.146
0.220
ND
0.352
2.634
0.360
0.087
0.019
2.107
0.839
1.051
0.238
0.514
0.031
0.386
0.027
0.350
0.111
0.116
0.040
0.385
0.072
1.079
0.250
0.495
0.117
0.287
0.379
1.765
0.426
0.909
0.206
0.127
2.653
2.043
2.593
0.491
1.560
0.978
1.178
0.243
0.178
0.201
1.689
1.870
7.291
0.667
2.726
5.180
3.801
0.813
1.447
2.221
1.666
0.111
5.634
0.313
0.782
0.602
0.509
3.149
5.808
0.048
1.587
12.258
0.054
0.441
11.176
2.115
0.231
1.681
0.938
1.622
0.120
0.510
0.398
0.540
ND
1.126
10.556
0.497
0.250
0.017
6.938
2.978
4.206
0.849
1.769
0.177
1.511
0.124
1.512
0.505
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
0.045
0.813
0.290
0.273
0.533
0.755
0.290
0.906
0.036
0.344
0.265
0.193
0.244
0.080
0.262
0.507
0.525
ND
0.142
1.273
BDL
ND
0.121
1.144
BDL
0.016
0.012
0.485
0.218
0.275
0.058
0.148
BDL
0.112
BDL
BDL
0.018
0.878
0.501
0.626
0.075
0.342
0.028
0.206
BDL
0.129
0.045
BDL
0.285
0.124
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
241
Data
242
Data
244
Data
245
Data
F-2405 Label F-2406 Label F-2408 Label F-2409 Label
0246R2
F-2410
Data
247
Data
248
Data
Label F-2411 Label F-2412 Label
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
alpha BHC
beta BHC
delta BHC
lindane
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
0.152
0.979
1.420
0.771
0.407
2.124
3.519
0.972
BDL
0.279
3.601
BDL
0.451
7.472
BDL
BDL
BDL
BDL
0.239
17.664
10.280
0.926
0.128
0.271
29.508
0.214
BDL
0.074
0.379
0.218
0.232
0.076
0.228
0.109
0.338
0.225
0.452
0.605
0.153
0.311
0.351
0.796
1.104
0.079
0.185
0.298
ND
0.763
2.493
0.249
0.120
BDL
0.379
ND
1.987
4.702
ND
BDL
BDL
0.262
0.269
0.951
1.711
1.945
1.901
4.224
0.892
BDL
0.254
BDL
1.503
3.377
0.614
0.195
0.155
0.580
0.216
BDL
0.585
0.118
0.596
0.471
2.882
2.578
2.837
4.920
0.588
9.135
22.941
BDL
0.689
0.361
1.283
1.526
1.307
2.939
ND
BDL
5.760
13.346
ND
BDL
3.954
0.604
0.907
7.693
18.674
1.372
0.724
6.904
36.273
0.121
0.369
BDL
ND
0.307
0.500
0.564
0.325
2.127
2.521
0.821
0.207
0.879
6.880
BDL
BDL
14.610
25.341
ND
BDL
BDL
0.113
0.075
1.099
15.694
7.168
0.875
1.671
6.592
33.099
0.636
0.343
0.110
0.251
ND
5.821
6.763
ND
BDL
BDL
0.171
0.141
1.337
16.774
23.210
1.178
1.100
5.045
48.644
0.605
BDL
BDL
BDL
0.315
0.160
2.046
2.494
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
The Academy of Natrual Sciences
249
Data
F-2413 Label
0250R
F-2414
Data
251
Data
Label F-2415 Label
252
F-2416
Data
253
Data
Label F-2417 Label
254
F-2418
Data
255
Data
Label F-2419 Label
0.29
1.989
0.67
2.095
0.39
1.985
3.02
1.868
2.94
2.586
8.07
2.091
0.63
2.191
101
92
88
123
92
95
98
89
86
102
85
83
94
86
80
96
92
92
85
88
85
45.9
25.5
16.2
46.6
14.3
9.9
1.731
72.3
47.4
25.6
352.7
111.1
53.2
228.1
86.6
51.6
0.167
0.327
0.117
1192.8
429.1
214.3
0.276
0.513
0.287
34.2
9.3
7.4
ND
0.454
ND
BDL
BDL
BDL
0.064
0.016
0.327
BDL
0.854
0.841
0.172
0.214
0.050
ND
ND
BDL
BDL
0.136
0.570
0.251
0.284
0.363
BDL
0.065
BDL
0.168
0.050
0.032
1.104
1.605
BDL
0.242
ND
0.699
0.444
0.452
0.741
0.280
0.319
0.136
ND
0.072
1.194
1.101
1.171
1.841
0.631
0.469
0.526
0.077
0.072
0.147
0.973
0.984
1.866
0.277
1.428
1.801
1.034
0.072
0.505
0.944
0.587
0.043
2.221
0.120
0.298
0.224
0.170
1.165
1.777
0.016
0.495
4.146
0.047
0.153
3.568
0.699
0.099
0.772
0.392
0.385
0.090
0.151
0.141
0.185
0.033
0.104
1.086
BDL
BDL
0.028
0.017
0.930
0.481
0.617
0.102
0.318
0.030
0.215
ND
0.231
0.052
BDL
1.226
0.207
0.617
0.176
0.032
1.685
2.288
1.282
1.048
0.443
0.637
0.207
0.066
0.146
0.978
1.845
5.506
0.587
1.899
3.217
1.768
0.160
0.862
1.624
0.804
0.190
4.703
0.322
0.784
0.625
0.429
2.542
2.459
0.044
0.978
7.928
0.177
0.255
6.398
0.971
0.222
1.479
0.725
0.986
0.114
0.577
0.451
0.302
0.186
0.313
2.314
0.443
0.139
0.021
1.575
0.860
1.100
0.021
0.702
0.069
0.316
0.035
0.391
0.042
BDL
0.105
1.350
0.330
BDL
1.058
0.450
0.322
1.797
BDL
0.108
ND
BDL
BDL
BDL
BDL
BDL
ND
BDL
BDL
BDL
BDL
1.012
0.238
0.115
0.090
0.255
0.620
0.108
0.561
1.212
3.844
0.337
1.371
1.974
1.007
0.110
0.568
1.022
0.516
0.113
2.861
0.190
0.435
0.339
0.212
1.649
1.438
0.026
0.562
4.652
0.066
0.137
3.795
0.503
0.136
0.883
0.559
0.497
0.065
0.366
0.272
0.274
0.128
0.222
1.904
0.884
0.068
0.032
0.708
0.646
0.722
0.254
0.827
0.082
0.242
0.073
0.618
0.064
ND
BDL
ND
BDL
ND
BDL
BDL
1.251
0.830
0.417
2.164
BDL
0.559
0.339
6.757
0.942
2.775
1.055
0.184
11.444
10.641
8.549
1.517
11.642
5.934
8.072
1.591
BDL
0.947
9.571
9.431
37.496
2.561
13.865
13.889
10.371
0.953
5.112
8.406
5.649
0.716
21.057
1.676
2.561
2.261
1.664
7.411
12.369
0.172
3.392
27.489
0.704
1.169
24.503
4.149
0.895
4.503
2.512
4.020
0.425
1.636
1.945
0.742
1.268
1.292
7.907
1.412
0.385
0.052
5.330
2.794
3.523
0.083
2.184
0.206
1.328
0.124
1.589
0.166
BDL
BDL
BDL
0.148
2.906
0.907
0.034
3.778
1.915
1.242
7.459
BDL
0.651
0.351
5.534
1.147
2.574
1.072
0.254
8.786
7.326
5.716
1.303
7.954
4.925
5.320
1.121
0.108
0.711
5.472
6.779
22.709
1.592
8.772
8.344
5.638
0.591
2.951
4.868
3.076
0.530
12.571
1.073
1.667
1.397
0.978
5.128
7.193
0.112
2.175
16.613
0.363
0.611
14.414
2.315
0.464
3.149
1.392
2.382
0.240
1.050
1.043
0.565
0.570
0.661
4.835
0.595
0.147
0.028
3.247
1.842
2.229
0.039
1.402
0.079
0.809
0.067
1.250
0.126
BDL
0.684
0.213
0.231
BDL
0.022
0.279
0.065
ND
0.101
BDL
2.147
1.165
18.076
3.308
10.107
4.312
0.865
35.100
32.115
28.303
3.574
35.488
23.574
26.047
4.829
0.053
2.236
31.053
32.152
118.762
8.866
48.710
43.498
35.759
2.967
15.878
28.375
17.506
2.237
71.667
5.243
8.252
7.694
5.494
27.777
44.209
0.521
12.505
90.829
1.768
3.863
87.407
15.387
2.392
19.434
8.379
16.644
1.199
7.098
5.616
2.848
3.409
4.143
30.849
2.450
1.171
0.150
20.583
12.645
13.908
0.163
7.426
0.596
5.083
0.312
6.549
0.590
BDL
0.047
BDL
0.440
0.170
0.288
0.048
0.042
0.737
0.563
BDL
0.966
0.536
0.349
0.336
0.114
BDL
0.056
0.487
0.782
2.802
0.248
0.736
1.572
0.863
0.078
0.451
0.816
0.426
0.087
2.038
0.150
0.444
0.285
0.206
1.058
1.111
0.020
0.466
3.677
0.062
0.172
2.897
0.398
0.105
0.580
0.296
0.490
0.055
0.244
0.179
0.205
0.088
0.105
1.058
BDL
0.016
BDL
0.661
0.342
0.409
0.031
0.317
0.018
0.137
0.040
0.137
0.024
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
249
Data
F-2413 Label
0250R
F-2414
Data
251
Data
Label F-2415 Label
252
F-2416
Data
253
Data
Label F-2417 Label
254
F-2418
Data
255
Data
Label F-2419 Label
0.572
6.133
3.761
1.713
25.707
7.683
0.622
2.411
9.239
47.375
5.758
72.190
18.615
4.624
49.447
12.158
19.022
305.020
48.605
1.203
10.043
45.169
429.063
0.684
4.853
2.692
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
1.096
12.564
4.745
BDL
1.565
5.518
25.487
alpha BHC
beta BHC
delta BHC
lindane
BDL
ND
ND
ND
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
0.207
1.014
1.446
3.146
5.038
0.126
5.184
16.161
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
0.283
BDL
ND
0.165
ND
0.337
0.094
BDL
0.333
1.413
2.470
4.578
7.149
0.498
9.139
25.580
1.467
3.383
3.172
8.211
11.624
2.692
22.635
53.183
0.435
BDL
5.175
0.419
0.149
1.031
9.260
0.268
BDL
BDL
ND
BDL
ND
0.323
1.710
0.596
BDL
ND
0.333
ND
1.352
BDL
BDL
1.396
0.607
0.147
1.561
3.605
2.834
8.659
13.233
1.588
20.144
51.625
1.016
BDL
BDL
BDL
3.581
16.793
86.604
BDL
ND
BDL
ND
0.116
4.380
9.928
0.496
0.151
BDL
2.734
11.846
111.143
BDL
ND
ND
0.072
1.131
1.141
1.118
2.087
ND
BDL
3.495
0.216
BDL
0.682
3.128
14.275
0.070
ND
ND
5.374
11.241
10.588
34.357
51.938
9.190
91.576
214.264
0.113
0.825
0.799
0.648
0.948
0.245
3.832
7.410
4.390
0.208
0.543
6.083
2.205
0.208
BDL
BDL
0.837
0.129
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
256
F-2420
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
The Academy of Natrual Sciences
Data
Label
257
F-2421
Data
258
Data
Label F-2422 Label
259
F-2423
1.31
2.876
1.56
2.313
1.17
2.0858
0.24
2.164
0.52
2.3694
0.70
2.1388
3.85
2.2465
96
94
88
104
98
96
98
100
92
93
93
91
98
97
94
93
98
93
119
99
98
390.7
134.8
106.0
706.5
203.7
140.4
346.4
77.1
51.0
452.5
169.8
60.4
93.1
22.7
11.5
65.3
17.8
11.0
414.3
528.3
211.2
0.316
0.624
0.076
0.080
0.109
1.441
0.082
0.114
1.187
0.445
0.157
1.662
BDL
0.343
0.345
0.052
0.201
1.732
0.663
0.017
2.716
3.126
0.906
4.917
BDL
BDL
0.402
0.048
0.254
2.097
0.743
BDL
0.149
1.302
0.477
3.777
3.817
1.140
6.085
BDL
2.597
2.307
0.703
3.653
BDL
3.125
2.121
20.789
3.080
7.544
1.502
1.000
19.985
19.631
32.864
2.910
16.674
9.724
12.406
3.509
5.162
1.822
12.551
22.740
58.545
4.477
18.435
21.526
12.699
1.165
6.367
10.513
6.722
2.097
31.831
2.289
10.019
5.424
3.998
16.283
14.406
0.296
7.003
50.575
1.974
2.010
39.398
6.731
4.013
13.426
8.876
5.807
1.469
6.973
4.415
5.692
1.726
4.055
32.078
3.960
0.919
0.090
20.658
9.195
12.825
0.129
6.823
0.397
5.569
0.302
4.212
0.459
BDL
BDL
BDL
BDL
0.355
0.219
BDL
BDL
2.300
1.495
12.795
2.045
5.987
0.604
0.706
13.323
12.466
18.468
2.866
11.411
6.485
7.707
2.270
2.991
1.200
7.328
12.545
36.039
2.858
10.812
12.908
7.562
0.697
3.557
5.987
4.016
1.142
19.215
1.389
5.393
2.971
2.188
8.559
7.904
0.193
3.540
26.053
0.959
1.175
20.133
3.430
1.790
6.182
4.024
2.770
0.845
2.641
1.951
2.587
0.781
1.653
12.413
1.828
0.453
0.046
7.982
3.417
4.614
0.040
2.366
0.127
1.770
0.083
1.445
0.161
BDL
0.043
0.376
0.081
0.022
0.105
0.075
BDL
BDL
BDL
0.197
BDL
BDL
0.179
0.111
BDL
BDL
BDL
0.125
0.077
BDL
0.176
BDL
0.061
BDL
0.148
BDL
0.082
BDL
0.356
0.240
0.586
0.081
0.075
2.789
0.588
17.965
0.799
0.864
0.836
3.052
0.114
3.152
0.318
1.612
0.329
2.206
0.756
2.590
5.660
12.874
0.208
1.387
0.914
5.705
0.118
19.850
0.240
0.437
1.013
2.079
8.461
18.041
0.240
9.742
71.103
0.383
2.089
54.987
9.617
4.797
17.656
11.417
9.543
0.186
2.712
6.520
7.640
2.414
5.041
37.238
5.438
1.000
0.015
23.785
11.938
15.934
0.114
9.371
0.619
5.991
0.270
6.678
0.877
BDL
BDL
BDL
BDL
BDL
0.367
0.025
0.174
0.122
BDL
1.763
1.339
12.028
1.289
4.274
0.961
0.617
12.639
11.840
14.847
2.809
9.805
5.707
6.709
1.785
2.040
1.134
7.281
13.080
16.421
2.286
11.792
12.374
7.253
0.693
3.796
5.964
3.963
0.918
16.567
1.347
4.038
2.231
1.748
8.009
8.152
0.119
3.257
26.102
0.635
0.812
20.320
3.192
1.154
5.769
3.474
3.114
0.493
2.454
1.685
2.491
0.696
1.573
12.098
1.602
0.355
0.039
7.498
3.598
5.055
0.049
2.778
0.208
1.907
0.112
2.196
0.305
Data
260
Data
261
Data
Label F-2424 Label F-2425 Label
BDL
0.069
BDL
0.983
0.199
0.497
0.113
0.031
1.708
1.303
1.250
0.279
1.186
0.722
0.891
0.227
0.104
0.145
1.065
1.883
5.945
0.529
1.531
3.909
2.148
0.207
1.101
1.816
1.020
0.202
4.939
0.384
1.248
0.749
0.563
2.765
3.125
0.052
1.527
11.442
0.178
0.452
8.811
1.317
0.407
2.378
1.298
1.506
0.166
0.737
0.681
0.690
0.406
0.606
4.447
BDL
0.684
0.136
0.358
0.073
0.029
1.312
1.084
BDL
0.320
0.816
0.565
0.638
0.136
0.073
0.108
0.912
1.408
4.522
0.368
1.204
3.108
1.759
0.134
0.830
1.478
0.793
0.122
3.681
0.257
0.856
0.523
0.402
1.930
2.594
0.031
1.082
8.315
0.116
0.354
6.542
1.007
0.473
1.483
0.813
1.053
0.102
0.463
0.450
0.384
0.078
0.312
2.739
ND
0.106
0.011
2.943
1.689
2.108
0.030
1.201
0.085
0.792
0.032
0.941
0.143
262
F-2426
BDL
0.583
0.271
5.104
1.875
2.934
0.361
0.192
8.888
8.005
5.749
0.596
7.008
4.288
4.442
1.126
ND
0.548
5.084
7.341
28.275
3.028
11.630
14.279
8.886
1.250
4.479
7.972
4.366
ND
23.387
1.064
3.639
ND
2.151
12.174
14.924
0.268
6.189
45.081
0.958
2.249
38.282
7.757
1.411
10.032
4.687
7.268
0.605
3.231
2.600
2.007
ND
BDL
0.085
BDL
1.835
0.924
1.149
BDL
0.639
0.045
0.402
0.022
0.477
0.074
Data
Label
2.927
18.211
2.381
0.479
0.068
13.010
7.165
9.442
0.215
6.015
0.411
3.661
0.278
4.671
0.509
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
256
F-2420
Data
Label
257
F-2421
Data
258
Data
Label F-2422 Label
259
F-2423
11.407
114.764
27.384
1.054
7.239
41.892
203.741
5.579
41.243
11.812
1.256
128.489
24.802
0.561
0.166
14.499
169.774
Data
260
Data
261
Data
Label F-2424 Label F-2425 Label
262
F-2426
Data
Label
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
8.137
70.709
18.349
0.854
6.048
30.688
134.785
alpha BHC
beta BHC
delta BHC
lindane
0.214
0.087
0.636
0.145
0.474
0.501
0.157
0.179
0.177
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
12.838
6.424
6.132
12.435
26.788
2.638
38.783
106.038
17.658
5.104
7.298
12.145
32.317
4.262
61.598
140.383
6.503
2.102
3.662
4.738
10.938
0.336
22.731
51.009
0.276
0.990
3.926
1.107
9.241
0.900
44.004
60.445
0.131
0.853
1.442
0.719
1.706
0.115
6.560
11.526
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
3.261
0.064
0.465
0.459
1.169
2.427
BDL
2.914
15.561
77.110
0.241
ND
BDL
BDL
BDL
BDL
0.852
BDL
0.442
0.385
1.539
BDL
0.492
BDL
BDL
BDL
BDL
BDL
0.092
0.221
0.098
0.712
1.591
0.643
1.041
BDL
6.929
11.014
BDL
BDL
0.875
0.290
BDL
0.141
1.798
17.817
0.277
BDL
BDL
BDL
1.583
0.865
10.576
4.438
0.242
2.408
22.663
BDL
BDL
BDL
0.313
0.223
0.688
1.211
13.527
5.275
0.221
0.152
BDL
0.691
0.664
12.053
389.726
44.321
1.733
14.873
65.588
528.294
0.359
0.286
0.291
0.689
2.649
12.577
10.218
40.736
67.182
4.571
73.284
211.217
3.549
0.266
0.719
10.596
1.581
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
263
F-2427
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
The Academy of Natrual Sciences
Data
Label
264
F-2428
Data
265
Data
Label F-2429 Label
266
F-2430
1.30
2.3855
4.75
2.0171
2.23
2.4349
1.29
2.4522
99
103
100
121
102
99
104
94
94
146.8
171.1
83.6
0.528
0.348
419.5
480.4
289.7
0.489
128.5
50.3
47.1
BDL
BDL
0.053
0.498
0.094
0.056
0.505
0.225
0.101
1.539
0.120
BDL
BDL
0.282
0.226
2.451
0.290
2.706
1.498
0.700
0.176
1.988
0.396
0.966
0.703
6.460
BDL
ND
2.382
1.108
1.321
0.597
ND
2.07
2.008
1.63
2.196
98
95
90
106
96
91
98
97
92
106
94
91
65.3
196.2
6.2
128.4
397.7
9.8
101.7
340.2
11.0
459.5
98.7
47.6
ND
ND
ND
BDL
BDL
BDL
0.032
ND
0.184
ND
0.037
3.729
2.725
ND
ND
0.277
1.988
3.742
ND
0.605
2.826
5.892
3.128
0.322
1.678
3.041
0.795
0.415
8.804
0.544
1.681
1.239
0.762
5.336
5.514
0.102
2.022
15.802
0.448
0.672
13.308
1.680
0.653
3.474
1.748
1.354
0.312
1.507
1.421
ND
0.622
0.680
5.021
ND
BDL
2.013
0.543
0.602
0.222
0.045
1.632
1.057
BDL
0.417
1.085
0.615
0.370
0.163
0.077
0.099
1.052
2.380
4.436
0.224
7.706
2.222
1.213
0.293
0.545
1.039
0.719
0.086
2.448
0.148
0.594
0.418
0.342
1.648
2.107
0.044
0.828
6.491
0.156
0.169
4.575
0.672
0.266
1.383
0.727
0.459
0.217
0.427
0.448
0.732
0.210
0.280
2.203
ND
0.163
0.099
3.672
1.928
2.255
0.403
1.428
0.105
0.864
0.094
0.911
0.279
ND
ND
ND
BDL
0.155
0.156
0.137
ND
ND
BDL
0.326
3.124
1.094
1.488
0.528
ND
ND
BDL
BDL
0.069
0.332
0.036
0.026
0.753
0.260
ND
0.378
0.115
0.339
0.283
3.085
0.730
1.326
0.288
0.041
2.886
1.964
1.752
0.761
2.222
1.146
1.309
0.324
0.140
0.221
1.786
4.136
8.437
0.483
15.992
4.422
2.374
0.578
1.043
2.020
0.098
5.309
0.379
1.197
0.813
0.566
3.294
4.077
0.056
1.584
13.646
0.132
0.325
9.659
1.304
0.659
2.673
1.530
0.871
0.133
0.789
0.737
0.917
0.298
0.587
4.694
0.322
0.098
0.038
2.714
1.693
2.161
0.501
0.985
0.117
0.683
0.254
0.543
0.087
BDL
0.557
ND
ND
0.208
BDL
0.122
1.342
0.432
0.018
2.933
1.848
0.690
3.559
BDL
0.355
BDL
ND
ND
0.061
0.026
1.469
0.860
1.063
0.248
0.545
0.044
0.381
0.059
0.462
0.059
Data
Label
0.600
0.199
0.265
0.087
0.278
BDL
2.121
0.380
0.804
267
F-2431
ND
BDL
0.703
5.402
10.256
6.920
3.219
14.194
16.953
8.168
1.129
4.677
9.444
4.331
1.773
27.131
1.795
7.070
3.309
2.160
18.274
15.591
0.242
6.147
45.638
1.121
1.791
42.316
5.813
1.729
16.806
4.158
4.160
0.865
3.890
3.753
2.209
0.517
1.758
13.763
0.446
0.245
10.070
7.603
7.055
1.164
3.677
0.736
2.679
0.666
3.639
0.740
1.24
2.1622
0.360
0.140
0.137
0.404
10.416
10.100
5.030
0.823
7.662
4.499
5.867
1.623
ND
0.355
1.839
3.100
10.702
1.191
4.883
5.729
3.409
1.229
1.713
3.101
1.509
0.455
8.776
0.643
1.700
1.220
0.695
4.290
4.879
0.092
1.912
14.477
0.311
0.528
12.773
2.351
0.545
3.170
1.527
2.648
0.366
0.994
1.112
0.848
0.753
4.728
0.648
0.289
0.029
4.101
2.318
3.030
0.069
1.878
0.144
1.121
0.279
1.931
0.238
ND
ND
ND
0.089
0.066
ND
ND
ND
ND
0.116
3.146
2.641
Data
269
Data
Label F-2433 Label
0.091
ND
0.590
268
F-2432
ND
ND
ND
BDL
BDL
BDL
BDL
Data
Label
3.946
1.072
1.266
0.350
0.096
2.892
2.054
1.799
0.573
2.150
1.184
1.259
0.337
0.142
0.202
1.668
4.259
3.246
0.452
14.692
3.581
1.731
0.538
0.878
1.851
0.989
0.166
4.650
0.380
0.951
0.663
0.375
2.618
2.813
0.050
1.021
8.946
0.223
0.314
6.371
0.905
0.392
1.659
0.990
0.595
0.154
0.691
0.597
0.996
0.095
0.334
2.964
ND
0.085
0.040
1.875
1.067
1.301
0.247
0.621
0.054
0.425
0.042
0.409
0.071
ND
1.465
0.928
10.084
4.972
3.170
0.774
0.451
10.864
10.365
12.748
1.558
8.430
4.887
6.071
1.360
0.848
0.886
5.830
8.972
13.118
1.760
9.096
13.158
7.991
0.633
3.719
5.754
3.581
0.851
14.795
1.053
3.618
2.227
1.766
9.962
11.979
0.142
6.056
54.865
1.199
1.482
35.080
5.410
1.981
12.991
7.511
2.765
0.862
3.632
3.392
2.462
1.229
2.936
31.394
3.385
0.617
0.268
16.711
9.323
14.049
1.726
8.528
0.718
6.118
0.302
8.638
2.889
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
263
F-2427
Data
Label
264
F-2428
Data
265
Data
Label F-2429 Label
266
F-2430
3.281
26.442
13.932
BDL
0.983
163.083
1.673
2.828
3.160
24.432
196.159
Data
Label
267
F-2431
Data
Label
268
F-2432
Data
269
Data
Label F-2433 Label
2.192
273.328
2.780
5.808
8.292
47.761
340.160
4.863
56.890
8.552
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
5.649
114.212
18.916
6.200
26.151
171.128
16.585
289.896
67.891
1.541
20.876
83.591
480.380
alpha BHC
beta BHC
delta BHC
lindane
0.201
0.196
0.131
0.476
0.493
0.548
0.331
1.130
0.271
0.172
0.254
0.167
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
1.158
4.953
4.050
16.700
23.101
1.281
32.357
83.600
3.761
17.056
13.545
67.152
95.852
4.240
88.079
289.684
0.289
4.932
3.255
10.813
15.276
12.547
47.111
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
1.441
0.080
0.405
4.473
0.817
5.475
0.116
1.005
22.694
2.249
0.691
0.174
0.224
0.892
0.957
BDL
0.811
5.884
50.350
1.930
338.003
2.884
4.447
6.616
43.786
397.666
BDL
BDL
0.096
BDL
ND
ND
0.345
0.752
0.756
0.932
0.926
2.523
6.235
0.200
BDL
BDL
0.157
0.676
1.026
1.373
2.140
1.685
3.911
10.968
0.567
ND
BDL
0.752
0.167
BDL
BDL
BDL
BDL
0.105
0.161
0.086
0.347
1.063
1.133
1.467
0.914
4.759
9.769
BDL
0.216
0.114
0.638
5.541
2.802
1.669
9.978
14.608
ND
13.039
47.638
0.505
ND
BDL
0.762
0.211
BDL
6.069
22.313
98.688
0.847
BDL
ND
1.194
0.282
BDL
BDL
0.159
0.482
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
The Academy of Natrual Sciences
270
Data
271
Data
F-2434 Label F-2435 Label
272
F-2036
Data
Label
273
F-2037
Data
Label
274
F-2038
Data
Label
275
F-2039
Data
Label
276
F-2040
0.82
2.028
0.82
2.01
0.67
2.019667
6.54
2.022
6.06
2.021
6.79
2.015
4.37
2.025
94
93
86
102
96
90
99
94
56
98
94
90
103
90
92
82
87
95
89
95
94
24.1
9.0
2.5
15.1
5.9
1.5
18.6
4.7
1.3
381.5
1280.1
34.9
703.5
220.0
131.3
405.9
887.8
29.3
229.1
700.3
19.1
ND
ND
BDL
BDL
ND
ND
BDL
ND
ND
BDL
BDL
BDL
BDL
0.033
ND
BDL
BDL
BDL
ND
ND
BDL
ND
ND
ND
BDL
BDL
BDL
0.025
BDL
0.374
0.084
0.291
0.049
BDL
0.254
0.333
ND
0.315
0.539
0.400
0.207
0.224
BDL
BDL
0.234
0.132
BDL
BDL
BDL
ND
BDL
ND
0.026
BDL
BDL
BDL
0.432
0.365
0.085
0.044
0.236
0.609
1.535
0.098
1.300
0.877
0.364
0.038
0.198
0.587
0.262
0.084
1.157
0.081
0.321
0.168
0.098
0.879
0.557
0.013
0.353
2.884
0.119
0.107
1.890
0.266
0.213
0.767
0.433
0.166
0.091
0.256
0.273
0.288
0.110
0.172
1.075
BDL
0.290
ND
BDL
ND
0.025
0.027
0.167
0.355
0.459
0.070
0.883
0.613
0.266
0.035
0.150
0.452
0.175
0.042
0.464
0.036
0.230
0.117
0.069
0.507
0.425
0.010
0.258
2.047
0.072
0.085
1.343
0.202
0.142
0.523
0.307
0.120
0.079
0.122
0.191
0.180
0.065
BDL
BDL
BDL
0.015
0.617
0.341
0.436
0.053
0.210
0.019
0.160
0.016
0.112
0.029
BDL
BDL
0.250
0.152
BDL
0.035
BDL
0.657
ND
0.053
0.018
0.842
0.483
0.631
0.116
0.337
0.031
0.219
0.078
0.158
0.030
ND
ND
BDL
BDL
BDL
ND
BDL
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.054
0.177
0.496
0.946
0.087
0.964
0.659
0.267
0.036
0.154
0.499
0.173
0.063
0.913
0.078
0.241
0.135
0.078
0.680
0.443
0.012
0.274
2.051
0.089
0.096
1.409
0.224
0.166
0.567
0.336
0.127
0.080
0.177
0.198
0.199
0.073
0.100
0.819
ND
ND
ND
0.084
0.276
3.225
0.170
0.550
3.667
1.396
0.232
2.617
1.055
1.154
0.611
15.434
4.020
4.469
1.052
0.304
8.205
6.064
4.604
1.037
7.401
3.101
3.200
1.218
0.246
0.578
5.053
12.733
9.580
1.313
47.572
10.840
6.451
1.834
2.957
5.540
0.019
0.016
0.759
0.420
0.519
0.093
0.300
0.024
0.211
0.018
0.138
0.032
0.028
0.686
BDL
ND
1.631
0.503
0.234
1.541
0.084
1.368
0.127
ND
ND
ND
0.741
9.137
13.429
18.797
3.063
11.563
26.218
19.218
1.546
7.944
13.899
7.870
1.613
31.115
2.445
7.898
4.915
3.477
20.523
30.279
0.417
12.001
95.055
2.289
3.766
76.569
11.968
3.059
19.592
9.670
8.334
1.327
6.223
7.710
3.795
1.243
4.107
36.636
4.185
0.735
0.376
25.135
12.353
15.156
2.204
8.808
0.627
6.054
0.331
5.968
1.758
ND
BDL
BDL
BDL
BDL
0.393
0.036
BDL
BDL
ND
0.974
0.443
12.990
6.733
8.415
5.665
5.688
0.586
3.414
0.583
3.795
0.843
ND
BDL
BDL
BDL
2.952
1.157
0.265
2.427
0.412
0.268
7.805
1.038
3.419
0.692
0.130
13.022
11.218
8.180
2.187
10.979
6.430
8.261
1.689
0.805
12.896
0.947
4.191
2.637
1.409
7.964
11.176
0.116
4.213
33.393
1.415
1.378
27.594
4.547
1.652
9.482
4.757
3.222
0.663
2.807
4.491
5.443
1.813
2.564
BDL
ND
ND
BDL
BDL
BDL
1.338
0.270
BDL
0.737
BDL
1.291
0.912
11.767
3.389
4.833
0.726
0.232
6.902
5.554
4.431
0.667
6.186
3.344
3.771
0.958
0.201
0.451
4.042
10.928
8.020
1.049
31.370
9.516
4.551
1.387
2.706
5.175
BDL
0.582
0.360
6.741
1.287
1.885
0.475
0.104
4.898
3.356
2.723
0.588
5.234
1.768
2.275
0.514
0.201
0.339
3.278
7.990
7.535
0.819
28.144
7.280
3.996
0.989
1.999
4.004
ND
0.557
10.661
1.374
3.316
1.875
1.090
7.574
11.192
0.271
4.414
34.549
0.994
1.427
27.572
3.912
1.286
8.848
3.707
2.747
0.586
2.326
3.124
2.223
0.423
1.314
16.076
ND
0.451
9.232
0.649
2.233
1.488
1.015
5.584
8.000
0.096
2.904
23.917
0.672
0.912
19.050
2.635
1.422
5.331
2.343
1.615
0.376
1.546
2.068
1.335
0.854
1.050
9.215
ND
0.524
0.394
13.141
6.346
7.397
ND
30.231
0.644
43.939
5.957
ND
1.177
Data
Label
ND
0.253
0.121
6.239
3.295
4.089
0.805
2.180
0.143
1.531
0.159
1.801
0.345
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
270
Data
271
Data
F-2434 Label F-2435 Label
272
F-2036
Data
Label
273
F-2037
Data
Label
274
F-2038
Data
Label
275
F-2039
Data
Label
276
F-2040
Data
Label
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
0.232
4.792
0.920
0.134
2.910
0.618
BDL
0.156
2.941
9.042
BDL
0.117
2.124
5.903
alpha BHC
beta BHC
delta BHC
lindane
BDL
BDL
BDL
ND
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
BDL
BDL
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
0.457
0.346
0.362
BDL
BDL
1.670
4.686
BDL
BDL
BDL
BDL
0.198
ND
BDL
BDL
1.080
1.777
2.138
7.166
9.172
2.400
11.186
34.919
0.134
0.301
0.271
0.200
ND
BDL
0.216
ND
0.846
1.480
ND
BDL
ND
BDL
6.009
1033.428
8.556
3.108
27.278
201.706
1280.085
BDL
BDL
BDL
ND
BDL
1.289
2.454
0.115
0.194
2.263
0.522
ND
0.581
1.336
ND
BDL
ND
BDL
BDL
ND
BDL
BDL
BDL
0.082
9.516
152.730
33.114
0.861
3.195
20.617
220.033
0.211
BDL
BDL
BDL
0.090
BDL
0.137
0.089
0.996
1.404
1.388
6.371
6.880
4.291
8.013
29.344
BDL
0.227
1.059
1.253
3.686
4.716
1.982
6.160
19.084
0.296
ND
BDL
3.941
1.181
BDL
BDL
ND
0.834
BDL
BDL
3.231
565.096
4.920
2.163
15.126
109.730
700.266
BDL
BDL
0.223
1.414
8.651
6.299
23.509
37.456
5.917
48.048
131.293
0.230
3.676
0.293
4.712
706.392
7.667
2.326
20.550
146.153
887.801
0.143
BDL
BDL
3.468
0.365
BDL
BDL
1.800
0.273
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
The Academy of Natrual Sciences
277
Data
278
Data
279
Data
F-2041 Label F-2042 Label F-2043 Label
281
F-2045
Data
Label
282
F-2046
Data
283
Data
Label F-2047 Label
284
F-2048
1.04
2.078
1.04
2.022
5.81
2.054
1.73
2.044667
6.15
2.011
1.35
2.079
11.06
2.07
100
93
91
99
87
85
90
83
84
99
96
93
105
95
92
101
99
95
125
97
99
326.1
69.5
34.4
0.236
64.7
32.0
4.2
0.470
154.6
97.9
22.1
179.8
87.9
13.1
254.4
182.3
40.1
111.4
54.9
9.7
1589.6
658.7
444.4
ND
BDL
BDL
ND
ND
0.550
BDL
0.250
ND
BDL
ND
0.051
ND
BDL
0.210
0.056
ND
ND
BDL
BDL
BDL
0.441
BDL
0.487
0.054
BDL
2.724
BDL
BDL
0.564
0.164
BDL
BDL
0.940
0.368
0.129
BDL
0.073
0.035
0.066
0.500
0.639
1.258
0.124
2.393
1.927
0.940
0.109
0.473
0.804
0.418
0.047
1.852
0.097
0.705
0.348
0.261
1.830
1.715
0.015
1.240
8.916
0.074
0.261
6.328
0.908
0.529
2.866
1.581
0.539
0.212
0.606
0.528
0.981
0.337
0.628
5.379
0.562
0.153
0.025
3.302
1.740
2.390
0.278
1.065
0.073
0.865
0.077
0.621
0.090
0.322
0.139
BDL
0.668
ND
ND
5.293
4.170
3.378
0.596
4.491
1.677
3.189
0.379
BDL
1.159
0.238
0.445
0.114
0.093
1.709
1.177
0.883
0.179
0.019
0.482
0.232
BDL
0.552
1.240
0.754
0.886
0.221
0.127
0.193
1.142
2.429
3.223
0.356
4.834
3.678
1.664
0.236
0.935
1.783
0.928
0.292
4.472
0.397
1.596
0.907
0.483
3.768
2.741
0.047
1.878
14.013
0.419
0.618
9.819
1.400
1.023
4.016
2.461
0.872
0.319
1.522
1.276
1.557
0.401
0.837
7.668
0.778
0.243
0.071
4.667
2.542
3.284
0.494
1.527
0.099
1.209
0.123
0.845
0.118
BDL
2.967
0.303
16.494
ND
BDL
ND
0.151
3.401
8.082
7.702
0.951
12.997
8.177
4.267
0.609
0.918
4.975
2.626
0.883
13.856
0.854
3.932
2.592
1.096
9.106
6.939
0.137
3.663
29.976
1.344
1.275
21.988
2.810
2.066
7.256
4.007
1.875
0.586
3.787
3.196
2.733
0.949
1.527
12.881
1.397
0.356
0.177
8.324
4.069
4.638
0.886
2.301
0.138
1.745
0.119
1.156
0.174
BDL
BDL
BDL
BDL
BDL
0.340
1.218
0.133
4.097
0.641
2.171
0.368
ND
ND
BDL
0.141
BDL
BDL
2.554
1.703
1.491
0.424
2.032
1.074
1.261
0.383
0.120
0.247
1.806
3.152
4.333
0.511
7.573
5.633
2.728
0.367
1.450
2.832
1.610
0.343
7.123
0.604
2.535
1.374
0.784
5.679
4.793
0.060
3.043
22.952
0.540
0.855
16.939
2.314
1.558
6.595
3.839
1.456
0.492
2.442
2.117
2.531
0.667
1.472
13.265
1.311
0.300
0.073
8.011
4.124
5.256
0.711
2.468
0.168
2.037
0.143
1.387
0.205
0.150
0.060
0.072
1.573
0.221
0.850
0.197
ND
ND
BDL
BDL
ND
ND
BDL
ND
BDL
BDL
BDL
0.082
1.791
4.751
4.906
0.616
8.434
5.350
2.232
0.374
1.383
2.785
1.523
0.576
7.674
0.704
2.254
1.491
0.586
5.772
3.598
0.072
1.974
17.239
0.807
0.654
12.260
1.511
1.108
4.257
2.519
1.018
0.381
2.349
1.913
1.712
0.422
0.822
7.741
0.728
0.209
0.117
5.239
2.710
3.251
0.559
1.694
0.103
1.190
0.078
0.939
0.126
0.375
0.034
0.016
0.776
0.204
0.829
0.122
2.765
0.459
1.287
0.257
0.038
3.558
2.266
1.591
0.514
2.975
1.631
2.151
0.697
BDL
BDL
BDL
BDL
BDL
BDL
0.289
ND
BDL
0.221
0.036
0.044
0.723
0.766
ND
BDL
BDL
BDL
BDL
BDL
BDL
BDL
0.374
0.041
0.155
BDL
2.155
0.158
0.234
7.914
3.365
9.674
0.886
4.432
2.408
4.089
0.444
0.914
0.537
3.782
0.863
14.509
0.956
3.118
5.078
6.837
0.354
1.356
3.055
3.198
0.323
12.931
0.415
1.027
0.658
1.082
5.850
10.598
0.108
5.533
46.828
0.508
1.218
33.341
5.131
2.780
11.307
6.733
3.141
0.195
1.871
4.104
5.240
1.593
2.371
23.121
2.636
0.536
0.063
14.219
8.340
10.974
1.051
3.479
0.522
4.123
0.257
5.993
1.561
ND
BDL
BDL
BDL
BDL
ND
Data
Label
11.880
0.590
0.359
62.417
15.824
81.230
5.084
26.862
18.850
36.235
2.400
6.254
4.024
30.166
5.508
111.884
5.997
23.986
40.099
51.152
3.543
8.969
24.565
17.733
3.025
92.727
3.123
10.714
6.342
6.056
39.378
51.621
0.812
21.210
158.923
4.543
5.758
123.717
21.420
11.472
37.843
23.665
13.072
1.951
17.228
15.670
19.277
5.935
8.522
84.509
9.375
1.786
0.484
52.866
25.632
33.943
3.811
19.911
1.398
13.809
0.789
15.156
3.402
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
277
Data
278
Data
279
Data
F-2041 Label F-2042 Label F-2043 Label
281
F-2045
2.082
46.191
8.330
0.600
0.666
11.670
69.540
1.937
58.199
5.207
0.805
4.579
17.128
87.854
Data
Label
282
F-2046
Data
283
Data
Label F-2047 Label
284
F-2048
3.868
112.184
9.142
0.909
11.938
44.222
182.263
1.397
33.163
3.738
0.592
3.594
12.455
54.939
26.532
376.530
95.474
4.538
6.115
149.538
658.728
Data
Label
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
alpha BHC
beta BHC
delta BHC
lindane
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
0.353
16.044
1.956
0.596
4.233
8.831
32.013
BDL
BDL
0.076
0.175
BDL
BDL
0.187
ND
1.309
2.587
1.847
4.001
9.907
BDL
ND
ND
14.733
34.384
0.432
0.584
0.750
0.615
1.829
4.209
0.249
ND
BDL
BDL
ND
1.685
2.674
49.594
5.313
0.976
10.683
28.654
97.895
BDL
BDL
0.117
0.329
0.627
1.556
1.932
6.244
6.346
0.222
5.183
22.110
0.157
0.613
1.555
1.731
2.951
ND
6.113
13.119
0.056
0.092
BDL
BDL
BDL
ND
BDL
BDL
ND
0.095
BDL
BDL
BDL
BDL
0.213
ND
0.212
0.332
0.244
BDL
ND
BDL
ND
ND
BDL
ND
0.873
3.674
4.157
7.901
11.204
0.863
11.434
40.106
0.149
0.412
1.149
1.291
2.388
ND
4.287
9.676
0.433
0.080
ND
ND
BDL
ND
0.502
ND
0.578
0.263
0.486
BDL
ND
4.656
4.478
32.222
36.932
48.049
132.576
14.561
175.579
444.397
20.545
4.140
2.077
ND
24.281
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
285
F-2049
Data
286
Data
Label F-2050 Label
287
F-2051
Data
378
Data
Label F-2068 Label
LIPID PERCENT (%)
EXTRACTION MASS (wet wt/g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
Concentrations (ng/g wet wt)
TOTAL PCBs
TOTAL DDXs
TOTAL CHLORDANES
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
2.29
2.045
0.77
2.086
4.79
2.001
3.55
2.0095
108
94
95
101
100
97
105
93
91
104
99
96
766.1
249.4
181.1
224.5
41.1
28.0
386.1
421.2
51.5
139.8
42.4
35.8
The Academy of Natrual Sciences
BDL
ND
0.347
0.037
0.148
2.098
0.615
ND
ND
0.089
BDL
0.063
0.402
0.210
ND
4.418
3.499
1.126
6.745
ND
1.500
0.843
0.382
2.103
BDL
3.175
1.439
21.069
2.215
6.162
1.290
0.707
22.854
22.467
33.738
2.312
20.516
11.314
16.242
3.457
2.853
1.839
15.095
23.272
60.990
4.170
19.457
22.927
14.597
1.373
6.639
11.706
6.078
1.846
28.896
2.430
8.372
4.688
3.015
19.653
18.039
0.287
7.357
63.209
2.900
2.427
45.917
6.783
4.612
17.056
8.988
3.861
1.381
8.324
6.788
6.773
2.303
3.250
33.698
3.866
0.717
0.477
21.270
10.624
13.719
1.762
8.286
0.521
5.653
0.387
5.516
1.489
ND
ND
BDL
ND
0.042
0.273
0.032
0.021
1.040
0.235
0.242
BDL
BDL
0.227
0.080
BDL
0.806
BDL
0.831
0.515
5.197
1.116
1.698
0.422
0.276
6.693
5.944
7.791
0.959
4.920
2.662
3.480
0.757
0.426
0.423
2.983
5.031
7.819
1.069
4.736
7.393
3.688
0.321
1.948
3.192
1.832
0.526
9.620
0.642
2.106
1.294
0.815
6.107
5.793
0.075
2.533
24.245
0.634
0.595
15.696
2.066
0.593
5.831
3.179
1.260
0.438
2.083
1.274
0.933
0.842
1.259
12.975
1.092
0.288
0.143
7.020
3.808
6.028
0.833
3.560
0.354
2.735
0.163
3.919
1.409
ND
BDL
BDL
ND
BDL
BDL
0.253
BDL
0.238
0.276
5.084
0.596
2.253
0.737
0.041
7.694
5.046
3.890
0.990
6.370
3.450
4.378
1.187
BDL
0.132
BDL
3.983
0.615
1.928
0.171
0.035
4.645
3.581
BDL
0.284
3.894
1.070
2.052
0.555
ND
0.497
4.649
9.919
10.295
1.299
19.172
12.570
5.429
1.106
3.417
6.723
4.379
1.177
16.843
1.450
5.275
3.292
1.562
13.483
10.099
0.202
5.468
46.290
1.975
1.511
33.176
4.240
3.385
11.814
6.865
2.783
0.832
5.675
5.492
4.760
1.364
2.586
22.428
2.641
0.716
0.323
13.980
7.668
9.128
1.765
4.773
0.313
3.448
0.221
2.340
0.581
ND
0.204
2.268
5.264
5.424
0.759
3.897
6.260
3.113
0.377
1.766
3.230
0.839
0.390
8.969
0.690
1.841
1.233
0.666
4.977
5.119
0.085
1.881
15.058
0.521
0.634
12.274
1.620
0.609
2.913
1.335
1.255
0.240
1.198
1.164
0.507
0.389
0.534
4.452
0.625
0.110
0.087
3.417
1.782
2.047
0.391
1.338
0.101
0.819
0.090
0.900
0.276
Patrick Center For Environmental Research
Appendix II.ii. Cont'd.
Summary of PCB and OCP Concentrations
CHEM ID
Fish-number
285
F-2049
Data
286
Data
Label F-2050 Label
287
F-2051
Data
378
Data
Label F-2068 Label
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
12.515
136.128
27.020
0.656
12.079
61.008
249.406
2.929
19.580
5.017
5.298
304.450
11.851
11.742
20.530
67.362
421.233
3.139
23.596
8.290
alpha BHC
beta BHC
delta BHC
lindane
0.244
0.076
0.835
0.155
0.225
0.148
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
16.683
8.512
6.254
38.428
58.551
3.586
1.332
0.913
5.853
9.402
0.835
1.658
3.253
9.467
11.961
9.940
14.336
51.451
ORGANOCHLORINE PESTICIDES
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
BDL
2.985
10.599
41.110
BDL
BDL
BDL
ND
6.929
28.015
3.920
0.185
0.579
0.379
0.285
BDL
BDL
BDL
0.109
BDL
9.666
35.781
1.063
ND
BDL
ND
0.705
BDL
0.472
4.109
2.806
7.683
10.762
0.524
ND
BDL
ND
ND
1.359
0.205
ND
ND
52.639
181.068
BDL
1.103
6.226
42.354
BDL
0.328
0.670
0.638
BDL - Below Detection Limit
ND - Not Detected
The Academy of Natrual Sciences
Patrick Center For Environmental Research
APPENDIX II.iii.
INDIVIDUAL SAMPLE DATA ORGANIC CONTAMINANTS
Furans
______________________________________________________________________________
THE ACADEMY OF NATURAL SCIENCES
107
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix II.iii. Individual Sample Data Organic Contaminants: furans. Samples below detection limit for a contaminant are shown as 0.00.
St.
Sp.
Fish Anal
Total
#
Length cm
% solid
% Lipid
Total
Furans
dry
2,3,7,8TCDF
1,2,3,7,8- 2,3,4,7,8- 1,2,3,4,7,8- 1,2,3,6,7,8- 2,3,4,6,7,8- 1,2,3,7,8,9- 1,2,3,4,6,7, 1,2,3,4,7,8,
HxCDF
HxCDF
HxCDF
HxCDF
8-HpCDF
9-HpCDF
PeCDF
PeCDF
Total
OCDF Furans wet
(ng/g wet
weight)
(ng/g dry weight)
Passaic River at Dundee Lake (PRDL)
American eel
F-2484
34.5
30.8
F-2485
45.3
23.8
F-2485
45.3
23.8
F-2486
56.0
22.1
F-2486
56.0
22.1
F-2482
51.0
29.5
F-2487
61.5
30.5
F-2487
61.5
30.5
common carp
F-2481
58.2
26.5
F-2480
55.0
26.2
F-2479
54.7
22.1
F-2478
53.2
15.0
F-2483
62.4
25.7
largemouth bass
F-2475
37.5
19.0
F-2476
25.1
22.8
F-2477
30.8
22.7
F-2474
26.6
21.5
F-2473
28.5
22.4
Passaic River at Garfield (PRG)
American eel
F-2500
49.0
20.4
F-2500
49.0
20.4
F-2499
48.7
22.0
F-2499
48.7
22.0
F-2501
68.7
24.1
F-2501
68.7
24.1
43.6
18.9
18.9
11.3
11.3
32.8
31.6
31.6
1.54
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.54
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
5.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
19.9
24.2
9.8
19.0
20.7
0.00
0.00
0.00
1.49
3.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3.02
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.49
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
9.91
11.74
1.7
1.7
2.4
2.1
1.9
0.00
0.65
1.44
2.75
3.43
0.00
0.00
1.44
0.00
0.00
0.00
0.00
0.00
0.00
3.43
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.65
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.75
0.00
0.00
2.86
6.36
12.79
15.31
5.2
5.2
5.5
5.5
18.7
18.7
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
APPENDIX II.iv.
INDIVIDUAL SAMPLE DATA ORGANIC CONTAMINANTS
Dioxins
______________________________________________________________________________
THE ACADEMY OF NATURAL SCIENCES
109
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Apppendix II.iv. Individual sample data organic contaminants: dioxins. Samples with non-detection of a contaminant are shown as 0.00.
St. Sp. Fish Anal #
LTL
% solid
% Lipid
Total
Dioxin
dry
2,3,7,8TCDD
1,2,3,7,8PeCDD
1,2,3,4,7,8HxCDD
1,2,3,6,7,8- 1,2,3,7,8,9- 1,2,3,4,6,7,8HxCDD
HpCDD
HxCDD
OCDD
(ng/g dry weight)
Passaic River at Dundee Lake (PRDL)
American eel
F-2484
34.5
30.8
F-2485
45.3
23.8
F-2485
45.3
23.8
F-2486
56.0
22.1
F-2486
56.0
22.1
F-2482
51.0
29.5
F-2487
61.5
30.5
F-2487
61.5
30.5
common carp
F-2481
58.2
26.5
F-2480
55.0
26.2
F-2479
54.7
22.1
F-2478
53.2
15.0
F-2483
62.4
25.7
largemouth bass
F-2475
37.5
19.0
F-2476
25.1
22.8
F-2477
30.8
22.7
F-2474
26.6
21.5
F-2473
28.5
22.4
Passaic River at Garfield (PRG)
American eel
F-2500
49.0
F-2500
49.0
F-2499
48.7
F-2499
48.7
F-2501
68.7
F-2501
68.7
20.4
20.4
22.0
22.0
24.1
24.1
0.00
0.00
0.00
0.00
0.00
9.17
0.00
0.00
Total
dioxins
wet
(ng/g wet
wt.)
43.6
18.9
18.9
11.3
11.3
32.8
31.6
31.6
0.00
0.00
0.00
0.00
0.00
9.17
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
31.04
0.00
0.00
19.9
24.2
9.8
19.0
20.7
17.92
23.17
15.05
23.16
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
4.59
9.71
0.00
6.85
0.00
1.7
1.7
2.4
2.1
1.9
0.00
4.64
0.00
0.85
3.25
0.00
0.00
0.00
0.00
1.58
0.00
0.00
0.00
0.85
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.21
0.00
0.00
1.67
0.00
3.43
0.00
0.00
0.00
0.00
20.31
0.00
3.97
14.52
5.2
5.2
5.5
5.5
18.7
18.7
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
13.33 67.55
13.46 88.29
15.05 68.18
16.31 154.37
0.00
0.00
Apppendix II.iv. (cont.) Individual sample data organic contaminants: dioxins. 0.00 indicates samples below detection limit or non-detect.
St. Sp. Fish Anal #
LTL
% solid
% Lipid
Total
Dioxin
dry
2,3,7,8TCDD
1,2,3,7,8PeCDD
1,2,3,4,7,8HxCDD
1,2,3,6,7,8- 1,2,3,7,8,9- 1,2,3,4,6,7,8HxCDD
HpCDD
HxCDD
OCDD
(ng/g dry weight)
white sucker
F-2496
F-2502
F-2502
F-2494
common carp
F-2498
F-2498
F-2497
F-2497
F-2495
channel catfish
F-2492
F-2493
striped bass
F-2491
F-2489
F-2489
F-2490
F-2490
F-2488
F-2488
Total
dioxins
wet
(ng/g wet
wt.)
46.5
42.9
42.9
40.6
15.0
20.3
20.3
19.8
9.4
6.0
6.0
5.6
0.00
0.00
0.00
3.12
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3.12
0.00
0.00
0.00
15.79
62.4
62.4
59.5
59.5
60.8
22.8
22.8
23.6
23.6
22.5
15.9
15.9
17.6
17.6
10.1
0.00
0.00
24.00
24.00
0.00
0.00
0.00
20.90
20.90
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
3.10 101.86
3.10 101.86
0.00
0.00
50.3
47.0
22.6
21.8
12.7
16.0
1.43
8.83
0.00
0.00
0.00
0.00
1.43
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
8.83
54.6
56.6
56.6
48.8
48.8
49.0
49.0
19.9
21.6
21.6
21.7
21.7
26.2
26.2
4.6
2.4
2.4
2.8
2.8
7.8
7.8
93.16
0.00
0.00
48.14
48.14
3.10
3.10
93.16
0.00
0.00
48.14
48.14
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00 467.58
0.00
0.00
0.00
0.00
0.00 221.93
0.00 221.93
3.10 11.80
3.10 11.80
6.31
40.53
APPENDIX III
Hg Quality Assurance Summary
______________________________________________________________________________
THE ACADEMY OF NATURAL SCIENCES
112
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix III.
NJ Toxics Hg Quality Assurance Summary
Runs from 11/7/03 to 3/25/04
SRM Name >>
DORM 2
Cert Conc (ug/g 4.64 ± 0.26
dry wt
Tort
SRM 1946
0.27 ± 0.06
0.433 ± 0.009
dry wt
wet wt
Averages
Run 1 QC Summary
11/7/2003
% Recovery
% Recovery
% Recovery
% Recovery
% Recovery
Dorm (SRM)
91.3
95.7
94.6
91.7
95.7
Spike Rec
96.6
101.4
101.1
93.3
99.6
98.5
102.4
RPDs
RPDs
RPDs
RPDs
RPDs
RPDs
RPDs
13
3
3
0.0
0.0
0.0
0.0
% Recovery
Duplicate
Run 2 QC Summary
% Recovery
% Recovery
% Recovery
Dorm (SRM)
93.1
91.4
99.8
93.1
Spike Rec
93.3
96.7
103.0
99.0
97.3
RPDs
RPDs
RPDs
RPDs
RPDs
6.3
1.4
2.6
3.7
8.6
Run 3 QC Summary
% Recovery
93.8
99.0
2.7
12/19/2003
% Recovery
Duplicate
% Recovery
94.4
97.9
4.5
12/22/2003
% Recovery
% Recovery
% Recovery
Dorm (SRM)
100.5
99.0
95.0
98.2
Spike Rec
101.0
98.0
95
98.0
RPDs
RPDs
RPDs
1.6
20
17
Duplicate
Run 4 QC Summary
12.9
3/8/2004
% Recovery
% Recovery
% Recovery
% Recovery
% Recovery
138.0
133.0
137.0
121.0
113.0
Dorm (SRM)
92.6
94.0
Spike Rec
100.0
101.0
100.0
100.0
104.0
RPDs
RPDs
RPDs
RPDs
RPDs
1.3
2.1
11.3
0.5
0.1
Tort (SRM)
Duplicate
128.4
93.3
101.0
3.1
Appendix III. Cont'd.
Run 5 QC Summary
3/19/2004
% Recovery
% Recovery
% Recovery
% Recovery
Tort (SRM)
105.9
112.2
116.9
104.9
Dorm (SRM)
91.3
87.0
86.5
SRM 1946
97.0
94.0
Spike Rec
97.0
95.0
95.0
96.0
95.0
RPDs
RPDs
RPDs
RPDs
RPDs
0.3
6.9
4.8
4.6
1.3
Duplicate
Run 6 QC Summary
% Recovery
% Recovery
110.0
88.3
95.5
95.6
3/24/2004
% Recovery
% Recovery
Tort (SRM)
101.5
SRM 1946
95.9
96.3
97.2
96.5
Spike Rec
98.0
95.0
100.0
97.7
RPDs
RPDs
RPDs
42.2
7.7
5.4
% Recovery
% Recovery
% Recovery
% Recovery
% Recovery
% Recovery
Duplicate
Run 7 Summary
101.5
18.4
3/25/2004
Tort (SRM)
101.6
SRM 1946
96.2
97.6
97.2
95.7
101.3
97.4
97.6
Spike Rec
100.0
109.0
108
109
109
110
107.5
RPDs
RPDs
RPDs
RPDs
RPDs
RPDs
17.4
0.1
0.7
0.6
0.3
Duplicate
101.6
3.8
APPENDIX IV
Proposed risk-based consumption advisories
for PCBs (ppb = ng/g wet weight)
in fish developed by the NJ Risk Assessment sub-committee
of the Interagency toxics in biota committee.
______________________________________________________________________________
The Academy of Natural Sciences
115
Patrick Center For Environmental Research
Appendix IV. Proposed risk-based consumption advisories for PCBs (ppb = ng/g wet
weight) in fish developed by the NJ Risk Assessment sub-committee of the Interagency
toxics in biota committee.
Consumption Frequency
Cancer Risk
1 x 10
-5
1 x 10-4
Unlimited (based on daily)
<1.5
<15
Weekly
1.5 - 11
15-110
Monthly
11-47
110-470
Once per 3 months
Yearly*
47-140
140-560
470-1400
1400-5600
Do not eat (based on greater than
yearly)
>560
>5600
Boldface: Protective of high risk group for developmental/reproductive endpoints
* Different levels might be required for some endpoints.
THE ACADEMY OF NATURAL SCIENCES
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
APPENDIX V.i.
QA/QC Report
______________________________________________________________________________
The Academy of Natural Sciences
117
Patrick Center For Environmental Research
NJ Fish Tissue Analysis for the Evaluation of Spatial Trends
and Human Health Impacts
Quality Assurance/Quality Control Summary
Linda Zaoudeh, Matt Wilhelm, Jeffrey Ashley, David Velinsky and Robin Davis
Environmental Geochemistry Section
Patrick Center for Environmental Research
Academy of Natural Sciences
Philadelphia, PA 19103
The following report is a modification of the Quality Assurance/Quality Control summary
prepared for finalization of the data. The original report was approved on April 4, 2004, by
Robin Davis, Quality Assurance Officer for the project. The version presented here contains
textual changes for clarity and updates of table references to conform with the final report; it
does not contain any substantive changes. The original report is maintained on file at the
Academy of Natural Sciences of Philadelphia.
The following report summarizes the results of the chemical analyses performed for the NJDEP
project entitled “New Jersey Routine Monitoring Program for Fish”. This report also
summarizes the results of the quality assurance and control (QA/QC) measures that were
followed for analyses for mercury, polychlorinated biphenyls (PCBs), organochlorinated
pesticides (OCPs), and dioxin in fish tissue. Table 1 outlines the specific analytes measured in
this study while Appendices I & II provide contaminant information for all fish samples
analyzed during this study. Finally, Appendix Vii includes the results from dioxin analyses by
the Geochemical and Environmental Research Group (GERG) at Texas A&M and the associated
QA/QC report.
I. Mercury
a) Extractions and Analyses:
Fish homogenate were digested using 10 mL nitric acid with approximately 0.7g to 1.0 gram in a
CEM MDS 2100 microwave digestion system. Carefully cleaned Teflon vessels were used for
all digestions. Mercury analysis was subsequently accomplished on a Perkin Elmer FIMMS 400
Cold Vapor AA following manufacturers specifications.
b) Analytical Quality Assurance:
The PE FIMMS 400 was calibrated using working standard dilutions of Certipur Stock Standard
(1000µg/L) from 0.2 to 20.0 µg/L. Calibration blanks, working stock standards and instrument
duplicates were analyzed to insure instrument performance and accuracy throughout the sample
run. Sample blanks, duplicates, spikes (1.0 ng Hg), and several Standard Reference Materials
were digested with the samples to insure adequate digestion recoveries. The QA samples were
run at a 10 to 15% level throughout the study. The samples were digested in seven runs from
2003 to early 2004.
The SRMs used were NRC (National Research Council) DORM-2, NRC TORT-2 and NIST
(National Institute of Standards and Technology) SRM 1946. Certified values of the SRMs are
shown in Appendix III and Appendix V Table 2. These SRMs were chosen to be within the
range of expected concentrations in unknown samples, based on previous data. Percent recovery
for DORM-2 ranged from 87 to 101% with an average recovery of 94 ± 4%. TORT-2 recoveries
ranged from 102 to117% with an average recovery of 108 ± 6%. Due to the use of low sample
weight for TORT-2 used for one of the seven runs, the data were excluded due to high sample
recoveries (121-138%). SRM 1946 recoveries ranged from 94 to 101% with an average
recovery of 97 ± 2%. A summary of the quality control data are shown in Appendix III.
Intercalibration verification samples (i.e., duplicate/spike samples and continuing calibration
standards) were all 96-117% of the actual concentration except for the 0.2 µg/L standard, which
showed a broader range of recovery (85-137%) due to its proximity to the detection limits of the
instrument. The relative percent difference (RPD) for instrument duplicates were < 1, while
RPDs for sample duplicates ranged from 0 to13, excluding those samples with concentrations of
less than 0.06 ug/g wet wt. Finally, sample spikes (1 ug spikes) were analyzed and recoveries
ranged between 93 and 110% of added concentrations. The method detection limit (MDL) based
on the digestion blanks and the 0.2 ug/L and 0.5 ug/L standards ranged from 0.017 to 0.029 ug/g
wet wt. All samples were above the MDL, with only 18 out of 342 less than twice the average
detection limit (0.023 ug/g wet wt).
The final data are shown in Appendix I.
II. Polychlorinated Biphenyls and Organochlorine Pesticides:
a) Extractions and Analyses:
Homogenized fish samples were stored frozen until extraction. Samples were thawed and 2 g of
the homogenate was sub-sampled using a stainless steel spatula. Approximately 30 g of Na2SO4
(previously baked at 450° C for four hours) was added to the sub-sample to eliminate water. The
dried sample was placed into a Soxhlet extractor (using DCM rinsed glass wool as filter) with ca.
200 mL dichloromethane (DCM) for a minimum of 18 hours. The extracts were sub-sampled for
gravimetric lipid determination. For this, a known volume of extract (1mL) was transferred to a
pre weighed aluminum pan. The samples were placed into a fume hood and allowed to
evaporate for at least 12 hours. The residue remaining (lipid) was weighed and percent lipid was
calculated.
Lipids were removed from sample extracts by gel permeation chromatography (GPC) using
DCM as the mobile phase. The collected fraction containing analytes was concentrated by rotoevaporation and an N2 stream. Solid-liquid chromatography using florisil was done as an
additional clean-up step. Using this technique, PCBs (as well as heptachlor, nonachlors, and
DDEs) were eluted from the chromatographic column containing florisil using petroleum ether
(F1 fraction). The remaining organochlorine pesticides were eluted using 50:50 petroleum ether
and dichloromethane (F2 fraction).
Congener-specific PCBs and organochlorine pesticides (Table 1 of this Appendix) were
analyzed using a Hewlett Packard 5890 gas chromatograph equipped with a 63Ni electron capture
detector and a 5% phenylmethyl silicon capillary column. The identification and quantification
of PCB congeners followed the ‘610 Method’ (Swackhamer, 1987) in which the identities and
concentrations of each congener in a mixed Aroclor standard (25:18:18 mixture of Aroclors
1232, 1248 and 1262) were determined by calibration with individual PCB congener standards.
Congener identities in the sample extracts were based on their chromatographic retention times
relative to the internal standards added. In cases where two or more congeners could not be
chromatographically resolved, the combined concentrations were reported (Table 1).
Organochlorine pesticides (OCPs; Table 1) were identified and quantified based on comparisons
(retention times and peak areas) with a known calibration standard prepared from individual
compounds.
b) Analytical Quality Assurance:
Surrogate Recoveries: Analyte loss through analytical manipulations was assessed by the
addition of surrogate PCB congeners 14, 65 and 166 prior to extraction by Soxhlet apparatus.
These surrogates were not industrially prepared and therefore are not present in the environment.
Average recoveries of congeners 14, 65 and 166 were 107 ± 13%, 91 ± 8% and 95 ± 13%
(calculated by averaging the recoveries of all analyzed samples shown in Appendix II). Due to
the relatively high surrogate recoveries and the low standard deviations, no reported values for
PCB and OCP concentrations in this study were corrected for analyte loss.
Detection Limits: Matrix blanks (12) were generated to monitor possible laboratory
contamination and to calculate the detection limits for PCBs and OCPs. Each matrix blank,
consisting of approximately 30 g of clean Na2SO4, was analyzed using the same procedures as the
samples. Average surrogate recoveries for these blanks were 89%, 87% and 88% for PCBs 14,
65 and 166, respectively (Appendix II). Chromatograms of most blanks were void of significant
peaks suggesting that little contamination through laboratory exposure occurred.
The detection limits for PCBs and OCPs were calculated as the mass plus three times the
standard deviation of the mass. The matrix blank-based detection limits for PCBs and OCPs
ranged from 0.01 to 2.17 ng (Table 4). Based on 12 matrix blanks, the detection limit for total
PCBs (the sum of all quantified PCB congeners) was 6.62 ng.
Analytical Accuracy: National Institute for Standards and Technology (NIST) standard
reference materials (SRM 1974B, Organics in Mussel Tissue; SRM 1946, Lake Superior Fish
Tissue ) were used to evaluate extraction efficiency and analytical accuracy (Tables 5 and 6,
respectively). For SRM 1974B, PCB congener recoveries ranged from 56% (congener 101) to
193% (congener 18). Although the concentrations for some PCB congeners were well above or
below the NIST certified values, the majority (61%) fell within 30% (Tables 5 and 6). For SRM
1946, PCB congener recoveries ranged from 46% (congeners 66+95) to 848% (congener 201)
(Table 6). In this case, the variation from the certified values was greater than observed in
SRM1974, however the majority (65%) fell within 30%.
Concentrations for OCPs were also assessed using both SRM 1974B and SRM 1946. In SRM
1974 B, some of the OCPs (trans-nonchlor, o,p-DDE, heptachlor, cis-nonchlor, and p,p-DDT)
had relatively high recoveries (> 300%). However, a reasonable explanation for such an
occurrence is due to very low values as compared to the minimum detection limits (MDL) for
each OCP. For instance, NIST reports a value of 0.212 µg/kg (wet-mass basis) for heptachlor,
while PCER reports a value of 3.139 ng/g, giving a recovery of 1480%. NIST’s reported value
is very close to the MDL for heptachlor (0.121 ng), so that accurate recoveries are difficult to
determine. Other OCPs in this SRM had recoveries between 42% (alpha chlordane) and 124%
(o,p-DDD).
OCP values recoveries for SRM 1946 generally ranged from 73% (p,p-DDD) to 140%
(lindane). Some recoveries were above 200 percent ( heptachlor epoxide (218%), o,p-DDE
(511%) and o,p-DDT (424%). Values this high usually indicate one of two things: a problem
with the concentration value assigned for that analyte in the calibration standard or a problem
with the ability to resolve that analyte without interference (from PCB congeners or other
unidentifiable compounds) using the analytical instrumentation. Original standard
concentrations were verified through preparation of new analyte standards. Therefore, high
recoveries for certain analytes are most likely attributable to interfering components of the fish
matrices.
Analytical Precision: To assess precision of the organic contaminant analyses, sample duplicates
of randomly selected samples were performed at a frequency of 10% (Tables 7 and 8). In
addition to duplicate analysis, random triplicate analyses were completed on three different
samples: F-9454, F-0272, and F-0281 (Table 8). The mean RPD for t-PCBs was 3 ± 2 (Tables 79). The mean RPD for F2 duplicates (most of the OCPs) was 12 ± 8 (Table 9). Duplicate
analyses revealed exceptional precision. The mean RPD for triplicate analyses for total PCBs
was 5 ± 3 (Table 9). The mean RPD for F2 triplicates was 11 ± 0.3 (Table 9). Again, these data
reveal an exceptional level of precision within replicate analyses of fish samples, for all organic
analytes.
Additional Quality Assurance: Additions of known volumes of calibration standards to matrix
blanks, or ‘spiked samples’, were used to further evaluate quality assurance of the analytical
procedure. Analytes were quantified and resulting masses were compared to the masses initially
spiked into the matrix prior to extraction. For most PCB congeners, recoveries ranged from 41 %
(congener 24/27) to 75 % (congener 187/182) (Table 10). Some congeners had recoveries that
fell below 40% (congeners 29, 87/81, 158, and 209), while others exceeded 130% (congeners
41/47, 172/197, and 193). The sum of these ‘outlier’ congeners represent <9% of the total mass
in most fish tissues. Recoveries that are above 130% reflect the difficulty in quantifying
congeners whose masses in spiked standards (and in actual samples) are so low.
All organic contaminant data are shown in Appendix II.
III. Dioxins
Dioxin analysis for 30 fish was completed by GERG, Texas A & M. The most commonly
detected dioxin compound was OCDD (octachlorinated dibenzo-p-dioxin), followed by
1,2,3,4,6,7,8-Hp CDD. Although OCDD was frequently detected, the highest concentrations
were found to be from 2,3,7,8-TCDD (tetrachlorinated dibenzo-p-dioxin). A narrative
highlighting the QA/QC results, composed by GERG, appears in Appendix Vii.
References
Swackhamer, D.L. 1987. Quality Assurance Plan for Green Bay Mass Balance Study - PCBs and
Dieldrin. U.S. Environmental Protection Agency, Great Lakes National Program Office.
APPENDIX V.ii.
GERG Dioxin QA/QC Narrative
______________________________________________________________________________
The Academy of Natural Sciences
123
Patrick Center for Environmental Research
APPENDIX V.
Tables 1 - 10
______________________________________________________________________________
The Academy of Natural Sciences
127
Patrick Center for Environmental Research
Appendix V. Table 1. List of Analytes for Project
POLYCHLORINATED BIPHENYLS
1
85
3
136
4+10
77+110
7
82
6
151
8+5
135+144
19
107
12+13
149
18
118
17
131
24+27
146
16+32
153+132+105
29
141
26
137+176
25
163+138
31+28
158
53+33+21
129+178
22
187+182
45
183
46
128
52
185
49
174
47
177
48
202+171
44
157+200
37+42
172+197
41+71
180
40
193
100
191
63
199
74
170+190
70+76
201
66+95
203+196
91
189
56+60
208+195
101
207
99
194
83
205
97
206
87+81
209
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
alpha BHC
beta BHC
delta BHC
lindane
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
MERCURY
APPENDIX V. TABLE 2: SRM Certified Concentrations
SRM Name
Cert Conc (µg/g)
Conc. Basis
DORM 2
4.64 ± 0.26
dry wt
TORT 2
0.27 ± 0.06
dry wt
SRM 1946
0.433 ± 0.009
wet wt
Appendix V Table 3. (Duplicate of Appendix III)
NJ Toxics Hg Quality Assurance Summary
Runs from 11/7/03 to 3/25/04
SRM Name >>
DORM 2
Cert Conc (ug/g 4.64 ± 0.26
dry wt
Tort
SRM 1946
0.27 ± 0.06
0.433 ± 0.009
dry wt
wet wt
Averages
Run 1 QC Summary
11/7/2003
% Recovery
% Recovery
% Recovery
% Recovery
% Recovery
Dorm (SRM)
91.3
95.7
94.6
91.7
95.7
Spike Rec
96.6
101.4
101.1
93.3
99.6
98.5
102.4
RPDs
RPDs
RPDs
RPDs
RPDs
RPDs
RPDs
13
3
3
0.0
0.0
0.0
0.0
% Recovery
Duplicate
Run 2 QC Summary
% Recovery
% Recovery
% Recovery
Dorm (SRM)
93.1
91.4
99.8
93.1
Spike Rec
93.3
96.7
103.0
99.0
97.3
RPDs
RPDs
RPDs
RPDs
RPDs
6.3
1.4
2.6
3.7
8.6
Run 3 QC Summary
% Recovery
93.8
99.0
2.7
12/19/2003
% Recovery
Duplicate
% Recovery
94.4
97.9
4.5
12/22/2003
% Recovery
% Recovery
% Recovery
Dorm (SRM)
100.5
99.0
95.0
98.2
Spike Rec
101.0
98.0
95
98.0
RPDs
RPDs
RPDs
1.6
20
17
Duplicate
Run 4 QC Summary
12.9
3/8/2004
% Recovery
% Recovery
% Recovery
% Recovery
% Recovery
138.0
133.0
137.0
121.0
113.0
Dorm (SRM)
92.6
94.0
Spike Rec
100.0
101.0
100.0
100.0
104.0
RPDs
RPDs
RPDs
RPDs
RPDs
1.3
2.1
11.3
0.5
0.1
Tort (SRM)
Duplicate
128.4
93.3
THE ACADEMY OF NATURAL SCIENCES
101.0
3.1
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
Appendix V. Table 3 Cont'd.
Run 5 QC Summary
3/19/2004
% Recovery
% Recovery
% Recovery
% Recovery
Tort (SRM)
105.9
112.2
116.9
104.9
Dorm (SRM)
91.3
87.0
86.5
SRM 1946
97.0
94.0
Spike Rec
97.0
95.0
95.0
96.0
95.0
RPDs
RPDs
RPDs
RPDs
RPDs
0.3
6.9
4.8
4.6
1.3
Duplicate
Run 6 QC Summary
% Recovery
% Recovery
110.0
88.3
95.5
95.6
3/24/2004
% Recovery
% Recovery
Tort (SRM)
101.5
SRM 1946
95.9
96.3
97.2
96.5
Spike Rec
98.0
95.0
100.0
97.7
RPDs
RPDs
RPDs
42.2
7.7
5.4
% Recovery
% Recovery
% Recovery
% Recovery
% Recovery
% Recovery
Duplicate
Run 7 Summary
101.5
18.4
3/25/2004
Tort (SRM)
101.6
SRM 1946
96.2
97.6
97.2
95.7
101.3
97.4
97.6
Spike Rec
100.0
109.0
108
109
109
110
107.5
RPDs
RPDs
RPDs
RPDs
RPDs
RPDs
17.4
0.1
0.7
0.6
0.3
Duplicate
101.6
THE ACADEMY OF NATURAL SCIENCES
3.8
PATRICK CENTER FOR ENVIRONMENTAL RESEARCH
APPENDIX V Table 4. Blank-based Limits of Detection for PCB Congeners and Organochlorine Pesticides
BLANKS
11503
12703
13003
20403
50503
51303
80403
81303
81903
82703
90303
90903
POLYCHLORINATED BIPHENYLS
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
ng
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
0.129
0.013
0.038
0.004
0.020
0.087
0.023
0.018
0.032
0.022
0.008
0.100
0.014
0.010
0.024
0.220
0.112
0.169
0.037
0.004
0.099
0.053
2.013
0.119
0.100
0.052
0.064
0.016
0.002
0.019
0.038
0.109
0.218
0.008
0.115
0.054
0.023
0.003
0.022
0.039
0.005
0.007
0.102
0.008
0.010
0.018
0.004
0.068
0.066
0.005
0.020
0.144
0.011
0.043
0.130
0.029
0.005
0.003
0.012
0.029
0.002
0.022
0.027
0.009
0.001
0.012
0.049
0.137
0.195
0.052
0.003
0.012
0.111
0.023
0.006
0.020
0.018
0.023
0.056
0.010
0.012
0.024
0.070
0.096
0.089
0.029
0.011
0.083
0.040
0.616
0.031
0.061
0.048
0.040
0.015
0.018
0.016
0.036
0.099
0.176
0.010
0.077
0.047
0.022
0.005
0.015
0.046
0.000
0.006
0.081
0.008
0.009
0.016
0.013
0.028
0.032
0.001
0.021
0.113
0.004
0.030
0.090
0.035
0.007
0.003
0.015
0.020
0.001
0.012
0.011
0.002
0.014
0.004
0.050
0.159
0.285
0.029
0.009
0.020
0.134
0.013
0.017
0.020
0.018
0.022
0.036
0.011
0.013
0.020
0.069
0.055
0.062
0.020
0.012
0.058
0.060
0.210
0.013
0.018
0.033
0.033
0.006
0.011
0.006
0.037
0.082
0.094
0.004
0.027
0.015
0.010
0.004
0.004
0.047
0.001
0.002
0.023
0.011
0.003
0.007
0.006
0.039
0.052
0.001
0.016
0.039
0.006
0.009
0.028
0.057
0.003
0.184
0.034
0.013
0.001
0.035
0.086
0.031
0.005
0.026
0.024
0.002
0.054
0.011
0.009
0.013
0.058
0.065
0.075
0.002
0.006
0.075
0.062
0.422
0.031
0.038
0.026
0.030
0.006
0.003
0.006
0.031
0.056
0.169
0.008
0.044
0.041
0.026
0.006
0.014
0.091
0.004
0.004
0.067
0.010
0.009
0.011
0.005
0.060
0.060
0.001
0.018
0.125
0.003
0.027
0.093
0.009
0.004
0.006
0.015
0.015
0.002
0.009
0.009
0.010
0.006
0.116
0.070
0.017
0.096
0.026
0.006
0.018
0.093
0.033
0.009
0.020
0.027
0.024
0.028
0.013
0.021
0.040
0.079
0.043
0.009
0.022
0.079
0.019
0.022
0.048
0.025
0.033
0.052
0.013
0.014
0.005
0.097
0.049
0.123
0.021
0.016
0.165
0.114
0.840
0.054
0.103
0.071
0.071
0.023
0.015
0.012
0.094
0.106
0.317
0.025
0.109
0.094
0.053
0.016
0.031
0.108
0.022
0.008
0.133
0.016
0.025
0.023
0.020
0.092
0.096
0.005
0.048
0.295
0.011
0.070
0.194
0.043
0.011
0.059
0.034
0.034
0.006
0.027
0.020
0.035
0.019
0.107
0.106
0.043
0.183
0.143
0.035
0.039
0.097
0.046
0.009
0.027
0.030
0.236
0.076
0.092
0.012
0.307
0.112
0.027
0.126
0.012
0.013
0.035
0.055
0.051
0.026
0.213
0.109
0.027
0.025
0.010
0.117
0.035
0.004
0.004
0.027
0.065
0.085
0.077
0.015
0.048
0.161
0.066
0.124
0.011
0.012
0.102
0.100
0.053
0.221
0.079
0.062
0.086
0.024
0.013
0.015
0.085
0.137
0.141
0.024
0.177
0.116
0.060
0.010
0.038
0.159
0.203
0.042
0.024
0.010
0.105
0.033
0.005
0.015
0.025
0.112
0.090
0.095
0.014
0.089
0.165
0.067
0.118
0.011
0.021
0.047
0.070
0.037
0.116
0.060
0.036
0.120
0.021
0.021
0.017
0.054
0.074
0.063
0.014
0.153
0.035
0.019
0.009
0.015
0.183
0.520
0.051
0.040
0.016
0.163
0.035
0.011
0.027
0.025
0.089
0.101
0.084
0.029
0.322
0.122
0.085
0.154
0.020
0.023
0.036
0.055
0.083
0.048
0.056
0.036
0.100
0.024
0.024
0.023
0.060
0.081
0.045
0.014
0.140
0.022
0.025
0.017
0.019
0.034
0.013
0.193
0.013
0.023
0.021
0.014
0.080
0.094
0.003
0.059
0.301
0.008
0.012
0.240
0.053
0.012
0.069
0.023
0.021
0.022
0.028
0.025
0.016
0.032
0.049
0.093
0.028
0.011
0.057
0.018
0.024
0.018
0.016
0.036
0.030
0.002
0.080
0.256
0.011
0.012
0.065
0.062
0.027
0.039
0.030
0.012
0.015
0.015
0.018
0.016
0.024
0.048
0.038
0.154
0.117
0.029
0.031
0.011
0.146
0.026
0.006
0.071
0.038
0.045
0.065
0.077
0.008
0.075
0.138
0.092
0.073
0.010
0.005
0.078
0.020
0.023
0.184
0.058
0.017
0.059
0.014
0.004
0.009
0.027
0.088
0.206
0.011
0.091
0.051
0.021
0.004
0.020
0.118
0.012
0.004
0.080
0.003
0.013
0.005
0.009
0.031
0.028
0.001
0.009
0.124
0.006
0.002
0.084
0.019
0.003
0.018
0.011
0.013
0.004
0.009
0.008
0.007
0.003
0.015
0.035
0.237
0.149
0.032
0.037
0.012
0.204
0.029
0.012
0.078
0.046
0.060
0.079
0.068
0.016
0.180
0.149
0.077
0.105
0.011
0.025
0.088
0.065
0.019
0.396
0.073
0.036
0.024
0.021
0.030
0.009
0.041
0.092
0.185
0.011
0.109
0.037
0.023
0.010
0.017
0.110
0.016
0.017
0.066
0.020
0.026
0.018
0.015
0.025
0.027
0.002
0.026
0.116
0.013
0.008
0.104
0.044
0.010
0.020
0.013
0.013
0.020
0.012
0.030
0.028
0.000
0.006
0.000
0.002
0.002
0.003
0.005
0.016
0.012
0.104
0.048
0.068
0.010
0.010
0.102
0.053
0.701
0.025
0.032
0.036
0.044
0.009
0.010
0.018
0.035
0.060
0.155
0.006
0.031
0.031
0.020
0.006
0.010
0.095
0.012
0.004
0.050
0.005
0.005
0.014
0.007
0.035
0.039
0.001
0.022
0.099
0.007
0.012
0.067
0.039
0.004
0.018
0.014
0.012
0.007
0.007
0.007
0.007
0.007
0.023
0.021
0.099
0.111
0.028
0.024
0.026
0.052
0.107
0.174
0.007
0.118
0.031
0.013
0.020
0.015
0.433
0.023
0.008
0.070
0.016
0.011
0.016
0.008
0.021
0.036
0.004
0.021
0.169
0.010
0.027
0.097
0.108
0.012
0.043
0.034
0.021
0.018
0.009
0.021
0.025
0.010
0.067
0.027
0.017
0.018
0.048
0.023
0.012
0.018
0.023
0.031
0.015
0.003
0.094
0.228
0.009
0.012
0.056
0.060
0.021
0.064
0.030
0.017
0.005
0.014
0.035
0.020
0.039
0.041
0.045
0.019
0.040
Average
Std. Dev
LOD
0.138
0.165
0.044
0.019
0.019
0.119
0.029
0.010
0.032
0.027
0.060
0.069
0.047
0.015
0.101
0.122
0.070
0.107
0.016
0.013
0.081
0.062
0.422
0.105
0.061
0.046
0.065
0.017
0.015
0.015
0.049
0.091
0.162
0.012
0.099
0.048
0.026
0.009
0.018
0.121
0.015
0.009
0.081
0.012
0.014
0.015
0.012
0.045
0.048
0.002
0.036
0.167
0.008
0.022
0.104
0.046
0.010
0.031
0.019
0.018
0.008
0.014
0.018
0.015
0.015
0.043
0.049
0.070
0.135
0.033
0.015
0.010
0.037
0.009
0.006
0.022
0.008
0.064
0.024
0.037
0.006
0.117
0.047
0.024
0.035
0.010
0.007
0.036
0.025
0.582
0.114
0.026
0.022
0.033
0.007
0.009
0.006
0.021
0.023
0.073
0.007
0.048
0.029
0.015
0.006
0.009
0.121
0.011
0.005
0.045
0.006
0.008
0.005
0.006
0.023
0.026
0.002
0.028
0.083
0.003
0.019
0.060
0.025
0.008
0.025
0.011
0.008
0.008
0.008
0.010
0.010
0.013
0.037
0.028
0.348
0.571
0.143
0.063
0.048
0.230
0.055
0.028
0.099
0.051
0.253
0.140
0.159
0.031
0.451
0.264
0.142
0.211
0.045
0.034
0.188
0.136
2.168
0.447
0.141
0.113
0.164
0.039
0.042
0.034
0.113
0.159
0.381
0.032
0.242
0.136
0.071
0.026
0.045
0.484
0.048
0.024
0.216
0.031
0.038
0.031
0.030
0.115
0.127
0.007
0.119
0.418
0.017
0.079
0.283
0.122
0.033
0.105
0.051
0.041
0.032
0.038
0.048
0.046
0.052
0.154
0.133
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
0.000
0.008
0.017
0.025
0.023
0.029
0.000
0.009
0.000
0.010
0.001
0.006
0.007
0.008
0.003
0.005
0.013
0.012
0.020
0.002
0.001
0.000
0.003
0.002
0.007
0.007
0.009
0.000
0.003
0.004
0.003
0.011
0.009
0.001
0.001
0.006
0.004
0.007
0.009
0.295
0.023
0.002
0.045
0.016
0.025
0.018
0.060
0.003
0.013
0.009
0.019
0.009
0.013
0.003
0.002
0.020
0.015
0.026
0.019
0.027
0.010
0.014
0.011
0.009
0.009
0.013
0.004
0.009
0.058
0.032
0.066
0.004
0.014
0.006
0.024
0.003
0.028
0.008
0.010
0.004
0.003
0.020
0.013
0.024
0.008
0.007
0.016
0.016
0.005
0.018
0.014
0.068
0.007
0.002
0.055
0.039
0.065
0.010
0.092
0.007
0.033
0.015
0.031
0.005
0.077
0.015
0.006
0.077
0.050
0.064
0.008
0.038
0.012
0.020
0.019
0.040
0.004
0.011
0.005
0.003
0.044
0.016
0.008
0.003
0.005
0.006
0.006
0.005
0.012
0.006
0.078
0.015
0.004
0.028
0.014
0.018
0.003
0.018
0.010
0.030
0.011
0.041
0.004
0.014
0.010
0.005
0.056
0.020
0.064
0.007
0.016
0.007
0.019
0.011
0.020
0.007
0.050
0.008
0.005
0.037
0.021
0.035
0.008
0.024
0.006
0.016
0.008
0.020
0.008
0.083
0.007
0.004
0.022
0.013
0.023
0.006
0.027
0.005
0.009
0.006
0.013
0.003
0.297
0.028
0.018
0.103
0.060
0.104
0.025
0.106
0.021
0.044
0.025
0.057
0.016
Total PCB's
5.224
3.201
2.210
3.219
2.872
5.050
4.180
4.755
3.819
3.008
4.277
4.000
3.818
0.935
6.624
0.031
0.037
ORGANOCHLORINE PESTICIDES
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
0.026
0.029
0.009
0.022
0.128
0.078
0.126
0.026
0.051
0.013
0.093
0.024
0.015
0.005
0.031
0.021
0.015
0.024
0.060
0.007
0.105
0.012
0.005
0.040
0.311
0.093
0.027
0.020
0.117
0.091
0.286
0.028
0.238
0.159
1.020
0.047
0.042
0.078
0.159
0.198
0.207
0.030
0.177
0.028
0.114
0.177
0.054
0.068
0.036
0.246
0.046
0.228
0.025
0.117
0.067
0.210
0.020
0.043
0.037
0.022
0.060
0.217
0.029
0.061
0.031
0.085
0.073
0.242
0.036
0.094
0.018
0.092
0.058
0.262
0.028
0.064
0.086
0.361
0.246
1.028
0.118
0.286
alpha BHC
beta BHC
delta BHC
lindane
0.009
0.023
0.020
0.115
0.025
0.145
0.004
0.057
0.009
0.016
0.004
0.052
0.071
0.138
0.009
0.045
0.032
0.220
0.027
0.069
0.022
0.239
0.014
0.046
0.071
0.016
0.061
0.027
0.027
0.046
0.023
0.084
0.023
0.047
0.034
0.119
0.120
0.035
0.112
0.144
0.226
0.076
0.062
0.151
0.261
0.034
0.057
0.168
0.075
0.086
0.035
0.090
0.085
0.080
0.032
0.048
0.331
0.325
0.131
0.233
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
0.016
0.004
0.067
0.271
0.125
0.042
0.068
0.087
0.018
0.005
0.283
0.043
0.076
0.173
0.084
0.012
0.007
0.168
0.012
0.058
0.086
0.051
0.014
0.009
0.238
0.084
0.097
0.191
0.062
0.011
0.031
0.053
0.049
0.066
0.062
0.075
0.010
0.152
0.124
0.191
0.049
0.182
0.025
0.008
0.017
0.049
0.021
0.021
0.036
0.030
0.131
0.092
0.521
0.145
0.098
0.247
0.043
0.195
0.057
0.025
0.040
0.136
0.155
0.046
0.066
0.031
0.010
0.033
0.010
0.099
0.054
0.036
0.029
0.037
0.015
0.135
0.023
0.064
0.031
0.026
0.068
0.020
0.066
0.116
0.053
0.045
0.044
0.154
0.065
0.071
0.120
0.023
0.059
0.043
0.152
0.059
0.040
0.069
0.121
0.223
0.173
0.609
0.241
0.191
0.328
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
0.031
0.066
0.292
0.067
0.104
0.014
0.010
0.011
0.060
0.046
0.021
0.041
0.004
0.037
0.040
0.026
0.045
0.064
0.043
0.015
0.031
0.033
0.062
0.034
0.018
0.005
0.031
0.088
0.127
0.083
0.036
0.037
0.062
0.068
0.168
0.036
0.088
0.038
0.134
0.036
0.100
0.029
0.070
0.043
0.061
0.031
0.069
0.052
0.053
0.023
0.058
0.060
0.069
0.049
0.007
0.034
0.081
0.041
0.025
0.045
0.160
0.304
0.193
0.123
NOTE: Average Surrogate Recoveries for PCBs were 89, 87, and 88 % for Congeners 14, 65, and 166, respectively
0.057
0.059
APPENDIX V Table 5. Comparison between PCER and NIST for SRM 1974B- Mussel Tissue
Compound
1974B
trial a
ng/g
1974B
trial b
ng/g
1974B
trial c
ng/g
PCER average
PCER Std Dev
NIST value
NIST std. dev
% Recovery
ng/g
SD
ng/g
SD
%
1.729
9.964
5.547
0.568
5.255
5.344
0.555
19.373
4.740
10.032
1.025
3.835
6.124
0.798
6.178
1.255
1.759
4.795
1.442
14.343
0.693
11.215
1.653
1.471
1.643
9.091
5.524
0.616
5.228
5.293
0.548
19.326
4.749
10.220
0.960
4.118
6.095
0.730
6.188
1.291
1.717
4.617
1.428
14.240
0.708
11.371
1.666
1.499
1.487
8.992
5.169
0.583
4.945
4.992
0.526
18.102
4.456
9.368
0.904
3.599
5.653
0.705
6.014
1.285
1.587
4.624
1.346
13.664
0.710
10.819
1.482
1.386
1.620
9.349
5.413
0.589
5.142
5.210
0.543
18.934
4.649
9.873
0.963
3.851
5.957
0.744
6.127
1.277
1.688
4.679
1.405
14.082
0.704
11.135
1.600
1.452
0.122
0.535
0.212
0.025
0.172
0.190
0.015
0.721
0.166
0.448
0.061
0.260
0.264
0.048
0.098
0.019
0.090
0.101
0.052
0.366
0.009
0.285
0.103
0.059
0.84
6.31
3.85
0.5
5.66
6.26
0.46
12.41
3.55
10.56
1.16
5.92
10.7
1.03
10.3
1.79
1.92
7.01
1.86
18.73
1.00
11.22
1.17
1.25
0.13
0.48
0.2
0.18
0.23
0.37
0.14
0.73
0.23
0.72
0.14
0.27
1.1
0.12
0.4
0.12
0.16
0.28
0.16
1.23
0.10
1.45
0.1
0.03
193
148
141
118
91
83
118
153
131
93
83
65
56
72
59
71
88
67
76
75
70
99
137
116
PCB Congeners
PCB 18
PCB 28+31
PCB 44
PCB 45
PCB 49
PCB 52
PCB 63
PCB 66+95
PCB 74
PCB 77+110
PCB 82
PCB 99
PCB 101
PCB 107
PCB 118
PCB 128
PCB 146
PCB 149
PCB 151
PCB 153+132+105
PCB 158
PCB 163+138
PCB 180
PCB 183
Organochlorine Pesticides
alpha chlordane
trans chlordane(gamma)
trans nonachlor
op DDE
pp DDE
op DDD
pp DDD
heptachlor
oxychlordane
dieldrin
cis-nonachlor
op, DDT
pp, DDT
100
0.646
0.288
6.404
2.066
4.100
1.598
11.004
3.490
0.682
1.333
4.023
0.511
0.000
NOTE: Values in bold denote uncertified NIST values
0.464
0.336
6.462
2.049
3.906
1.250
13.080
2.945
0.346
1.076
3.241
0.690
1.092
0.596
0.137
6.391
1.951
3.903
1.193
10.014
2.981
0.299
0.623
3.344
0.474
2.847
0.568
0.254
6.419
2.022
3.969
1.347
11.366
3.139
0.442
1.011
3.536
0.559
1.313
0.094
0.104
0.038
0.062
0.113
0.219
1.565
0.305
0.209
0.360
0.425
0.115
1.436
1.36
1.14
1.3
0.336
4.15
1.09
3.34
0.212
0.362
0.62
0.64
0.894
0.396
0.1
0.17
0.14
0.044
0.38
0.16
0.22
0.084
0.072
0.13
0.16
0.057
0.096
42
22
494
602
96
124
340
1480
122
163
552
62
332
APPENDIX V Table 6. Comparison between PCER and NIST for SRM 1946-Lake Superior Fish Tissue
Compound
Wet Weight Basis
1946
trial a
ng/g
1946 dup
trial b
ng/g
1946 trip
trial c
ng/g
PCER average
PCER Std Dev
NIST value
NIST std. dev
% Recovery
ng/g
SD
ng/g
SD
%
0.97
3.48
4.27
2.74
5.88
4.69
10.01
5.48
26.75
21.90
22.46
7.34
28.85
25.98
202.83
27.14
22.67
11.60
136.44
8.81
77.89
24.66
11.59
13.14
25.51
8.46
0.87
0.53
2.53
3.80
2.69
5.13
4.54
11.70
4.76
22.96
19.76
20.64
6.56
26.80
14.96
192.99
25.24
21.27
9.81
125.98
8.10
73.47
21.93
11.84
11.85
22.62
7.40
0.71
1.15
5.11
3.91
2.60
5.26
4.52
8.90
4.56
25.44
21.58
21.07
7.00
28.65
23.14
196.09
25.95
21.87
10.15
132.69
8.42
78.10
23.58
12.07
12.97
23.89
7.74
0.86
0.89
3.71
3.99
2.68
5.42
4.58
10.21
4.93
25.05
21.08
21.39
6.97
28.10
21.36
197.30
26.11
21.94
10.52
131.70
8.45
76.49
23.39
11.83
12.65
24.01
7.87
0.81
0.32
1.31
0.25
0.07
0.40
0.09
1.41
0.48
1.92
1.15
0.95
0.39
1.13
5.72
5.03
0.96
0.70
0.95
5.30
0.36
2.61
1.38
0.24
0.70
1.45
0.54
0.09
0.84
3.46
4.66
3.8
8.1
1.28
22.2
4.83
23.127
25.6
34.6
8.86
52.1
22.8
195.73
30.1
26.3
7.66
146.8
9.3
74.4
21.9
5.78
13
2.83
5.4
1.3
0.11
0.44
0.86
0.39
1
0.19
3.2
0.51
2.025
2.3
2.6
0.2
1
1.9
10.66
3.5
1.3
0.88
13.8
1.3
4
2.5
0.72
1.3
0.13
0.43
0.21
105
107
86
70
67
358
46
102
108
82
62
79
54
94
101
87
83
137
90
91
103
107
205
97
848
146
63
6.12
1.12
12.35
16.77
24.74
8.96
8.64
91.56
492.85
1.33
12.93
40.43
5.47
96.39
5.26
2.45
11.69
17.97
24.03
8.59
8.85
91.39
470.09
3.10
12.93
39.94
5.44
93.40
6.72
1.23
11.90
18.64
25.01
8.67
8.30
90.81
487.50
1.31
12.72
42.96
5.04
93.87
6.03
1.60
11.98
17.79
24.60
8.74
8.59
91.25
483.48
1.91
12.86
41.11
5.31
94.55
0.73
0.73
0.33
0.94
0.51
0.19
0.28
0.39
11.90
1.03
0.12
1.62
0.24
1.61
5.72
1.14
5.5
18.9
32.5
8.36
59.1
99.6
373
2.2
17.7
37.2
1.04
22.3
0.65
0.18
0.23
1.5
1.8
0.91
3.6
7.6
48
0.25
2.8
3.5
0.29
3.2
105
140
218
94
76
105
15
92
130
87
73
111
511
424
PCB Congeners
PCB 18
PCB 31+28
PCB 44
PCB 49
PCB 52
PCB 63
PCB 66+95
PCB 74
PCB 77+110
PCB 99
PCB 101
PCB 107
PCB 118
PCB 128
PCB 132+153+105
PCB 146
PCB 149
PCB 158
PCB 163+138
PCB 174
PCB 180
PCB 183
PCB 193
PCB 194
PCB 201
PCB 206
PCB 209
Organochlorine Pesticides
alpha BHC
lindane
Heptachlor Epoxide
Oxychlordane
alpha chlordane
trans chlordane(gamma)
cis nonachlor
trans nonachlor
pp DDE
op DDD
pp DDD
pp DDT
op, DDE
op, DDT
NOTE: Values in bold denote uncertified NIST values
APPENDIX V Table 7. Results of Duplicate Analysis for Individual PCB Congeners
and Organochlorine Pesticides
CHEM ID
F-number
LIPID PERCENT (%)
EXTRACTION MASS (g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
9432F1
F-2481
5.45
2.057
9432dupF1
F-2481
5.51
2.052
average
percent difference
5.48
2.05
1
0
121
96
98
125
100
106
123
98
102
3
4
8
347.9
86.8
115.9
366.2
95.6
118.6
357.0
91.2
117.3
5
10
2
PCB's
ng/g
ng/g
ng/g
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
0.321
0.725
0.222
0.153
0.313
2.936
0.086
0.107
2.502
1.387
0.225
2.336
BDL
1.454
0.585
14.065
3.046
5.201
1.437
0.120
8.786
8.372
4.557
1.249
8.441
3.388
8.777
1.066
0.259
0.848
6.310
9.762
25.813
0.250
1.323
0.229
0.144
0.322
2.842
0.088
0.112
2.472
1.383
0.243
2.325
BDL
1.496
0.554
15.175
3.150
5.470
1.579
0.109
8.890
8.586
5.563
1.010
8.716
3.418
8.913
1.119
0.274
0.827
6.640
10.338
26.777
0.285
1.024
0.226
0.148
0.318
2.889
0.087
0.110
2.487
1.385
0.234
2.330
BDL
1.475
0.569
14.620
3.098
5.336
1.508
0.115
8.838
8.479
5.060
1.130
8.579
3.403
8.845
1.093
0.266
0.837
6.475
10.050
26.295
TOTAL PCBs (ng/g dw)
TOTAL DDXs (ng/g dw)
TOTAL CHLORDANES (ng/g dw)
25
58
3
6
3
3
1
4
1
0
8
0
3
5
8
3
5
9
10
1
3
20
21
3
1
2
5
6
2
5
6
4
(APPENDIX V Table 7 Cont'd.)
9432dupF1
ng/g
average
ng/g
percent difference
PCB's
9432F1
ng/g
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
1.710
8.791
10.114
6.856
0.576
3.425
2.890
1.793
0.713
14.172
0.801
2.955
1.864
1.663
7.064
10.658
0.176
3.392
27.888
0.813
1.088
26.319
1.651
1.283
9.877
3.873
3.765
0.519
2.366
2.844
3.363
1.186
1.391
15.283
1.606
0.368
0.184
10.763
5.873
7.220
0.725
4.854
0.339
3.218
0.160
4.388
0.232
1.819
9.208
10.417
7.398
0.561
3.632
3.050
1.949
0.717
14.803
0.879
3.173
1.881
1.780
7.323
11.251
0.179
3.549
28.983
0.846
1.184
27.671
1.784
1.436
10.312
4.126
4.066
0.604
2.545
3.034
3.578
1.244
1.485
16.765
1.254
0.351
0.209
11.796
6.353
7.695
0.817
5.150
0.335
3.534
0.172
4.672
0.253
1.764
8.999
10.265
7.127
0.568
3.528
2.970
1.871
0.715
14.488
0.840
3.064
1.872
1.722
7.194
10.955
0.177
3.471
28.436
0.830
1.136
26.995
1.718
1.360
10.095
4.000
3.916
0.561
2.455
2.939
3.471
1.215
1.438
16.024
1.430
0.360
0.197
11.279
6.113
7.457
0.771
5.002
0.337
3.376
0.166
4.530
0.243
6
5
3
8
3
6
5
8
1
4
9
7
1
7
4
5
1
5
4
4
8
5
8
11
4
6
8
15
7
6
6
5
7
9
25
5
13
9
8
6
12
6
1
9
7
6
9
(APPENDIX V Table 7 Cont'd.)
9432dupF1
ng/g
average
ng/g
percent difference
ORGANOCHLORINE PESTICIDES
9432F1
ng/g
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
2.691
32.819
15.646
BDL
3.621
32.036
86.813
2.927
38.280
16.245
BDL
4.037
34.110
95.599
2.809
35.549
15.946
BDL
3.829
33.073
91.206
8
15
4
alpha BHC
beta BHC
delta BHC
lindane
BDL
1.201
ND
0.570
BDL
1.016
ND
0.632
BDL
1.109
ND
0.601
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
1.318
6.795
7.171
19.362
45.269
4.636
31.340
115.890
1.778
7.480
7.881
17.382
44.992
5.014
34.108
118.635
1.548
7.138
7.526
18.372
45.131
4.825
32.724
117.262
30
10
9
11
1
8
8
2
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
13.940
0.101
1.121
3.311
1.474
14.587
0.126
1.435
3.373
1.374
14.264
0.113
1.278
3.342
1.424
5
22
25
2
7
average of total OCP's
11
6
10
17
10
11
(APPENDIX V Table 7 Cont'd.)
CHEM ID
F-number
LIPID PERCENT (%)
EXTRACTION MASS (g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
9461F1
F-2502
1.25
2.001
9461Dup
F-2502
1.15
2.014
average
percent difference
1.20
2.008
9
1
101
89
96
102
87
95
101
88
95
0
3
1
284.8
69.5
56.9
269.9
67.4
55.4
277.3
68.4
56.1
5
3
3
PCB's
ng/g
ng/g
ng/g
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
ND
0.726
BDL
BDL
0.033
0.475
0.113
0.197
0.413
0.817
BDL
1.536
BDL
0.500
BDL
4.732
0.991
1.760
0.276
0.198
0.579
5.783
6.981
1.252
4.953
3.793
9.761
0.660
0.612
0.641
6.475
8.548
19.796
BDL
0.430
BDL
BDL
0.031
0.456
0.238
0.139
0.460
0.857
0.168
1.561
BDL
0.514
BDL
4.505
1.084
1.786
0.274
0.266
0.598
5.411
6.434
1.045
4.514
3.518
8.990
0.597
0.679
0.667
6.034
7.964
18.581
BDL
0.578
BDL
BDL
0.032
0.465
0.175
0.168
0.436
0.837
0.168
1.549
BDL
0.507
BDL
4.618
1.037
1.773
0.275
0.232
0.589
5.597
6.708
1.149
4.734
3.655
9.376
0.628
0.646
0.654
6.254
8.256
19.188
TOTAL PCBs (ng/g dw)
TOTAL DDXs (ng/g dw)
TOTAL CHLORDANES (ng/g dw)
51
6
4
71
34
11
5
2
3
5
9
1
1
29
3
7
8
18
9
8
8
10
10
4
7
7
6
(APPENDIX V Table 7 Cont'd.)
9461Dup
ng/g
average
ng/g
percent difference
PCB's
9461F1
ng/g
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
1.553
9.028
6.516
6.416
0.248
3.077
2.319
3.876
0.398
15.862
0.985
1.968
1.333
1.446
6.468
11.369
0.056
4.007
29.205
0.536
0.774
24.969
1.536
1.066
7.261
3.600
2.558
0.381
1.643
1.506
1.460
1.137
3.965
16.025
3.491
0.669
0.096
8.761
3.340
4.604
0.636
2.373
0.134
1.698
0.132
1.670
0.074
1.530
8.363
6.050
6.452
0.209
2.820
2.141
3.579
0.376
14.613
0.900
1.758
1.195
1.312
6.200
10.926
0.058
3.782
27.821
0.606
0.782
23.686
1.504
1.557
6.827
3.370
2.395
0.406
1.623
1.514
1.447
1.117
3.797
15.492
3.064
0.466
0.096
8.247
3.097
4.211
0.690
2.409
0.178
1.549
0.143
1.640
0.070
1.541
8.695
6.283
6.434
0.229
2.949
2.230
3.728
0.387
15.237
0.943
1.863
1.264
1.379
6.334
11.147
0.057
3.894
28.513
0.571
0.778
24.327
1.520
1.312
7.044
3.485
2.477
0.394
1.633
1.510
1.454
1.127
3.881
15.758
3.277
0.567
0.096
8.504
3.219
4.408
0.663
2.391
0.156
1.623
0.138
1.655
0.072
2
8
7
1
17
9
8
8
6
8
9
11
11
10
4
4
5
6
5
12
1
5
2
37
6
7
7
6
1
1
1
2
4
3
13
36
0
6
8
9
8
2
28
9
8
2
5
(APPENDIX V Table 7 Cont'd.)
9461Dup
ng/g
average
ng/g
percent difference
ORGANOCHLORINE PESTICIDES
9461F1
ng/g
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
1.925
42.891
8.079
1.004
1.745
13.811
69.456
1.894
41.493
7.905
0.933
1.728
13.461
67.415
1.910
42.192
7.992
0.969
1.737
13.636
68.436
2
3
2
7
1
3
3
alpha BHC
beta BHC
delta BHC
lindane
BDL
BDL
BDL
0.182
BDL
BDL
BDL
0.151
BDL
BDL
BDL
0.166
18
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
4.049
1.552
3.527
3.951
11.498
7.055
25.237
56.868
4.386
1.495
3.512
3.876
11.562
6.455
24.126
55.412
4.218
1.523
3.519
3.914
11.530
6.755
24.681
56.140
8
4
0
2
1
9
5
3
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
3.870
BDL
BDL
3.061
0.428
3.634
BDL
BDL
2.829
0.355
3.752
BDL
BDL
2.945
0.391
6
average of total OCP's
8
18
6
(APPENDIX V Table 7 Cont'd.)
CHEM ID
F-number
LIPID PERCENT (%)
EXTRACTION MASS (g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
9471F1
F-2512
0.77
2.016
9471DupF1
F-2512
0.63
2.002
average
percent difference
0.70
2.009
19
1
111
80
93
117
89
102
114
84
98
5
11
9
69.2
19.1
20.6
72.2
19.1
20.9
70.7
19.1
20.8
4
0
1
PCB's
ng/g
ng/g
ng/g
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
BDL
0.382
BDL
BDL
0.278
0.292
0.039
0.143
0.472
0.239
0.262
0.427
BDL
0.191
0.425
1.730
0.359
0.875
0.102
0.051
1.652
1.248
1.270
0.868
1.155
0.732
1.734
0.163
0.088
0.130
1.092
1.687
5.203
BDL
0.354
BDL
BDL
BDL
0.282
0.045
0.024
0.416
0.286
BDL
0.510
BDL
0.224
0.351
1.827
0.678
0.916
0.119
0.058
1.754
1.383
1.388
BDL
1.255
0.762
1.891
0.162
0.119
0.165
1.238
1.868
5.506
BDL
0.368
BDL
BDL
BDL
0.287
0.042
0.084
0.444
0.263
BDL
0.468
BDL
0.207
0.388
1.779
0.519
0.895
0.111
0.055
1.703
1.315
1.329
BDL
1.205
0.747
1.813
0.162
0.103
0.147
1.165
1.777
5.354
TOTAL PCBs (ng/g dw)
TOTAL DDXs (ng/g dw)
TOTAL CHLORDANES (ng/g dw)
8
4
14
143
13
18
18
16
19
5
62
5
16
12
6
10
9
8
4
9
0
30
24
12
10
6
(APPENDIX V Table 7 Cont'd.)
9471DupF1
ng/g
average
ng/g
percent difference
PCB's
9471F1
ng/g
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
0.392
1.766
2.224
1.618
0.082
0.645
0.528
0.867
0.106
3.377
0.211
0.570
0.344
0.238
1.876
2.603
0.021
0.844
6.955
0.119
0.220
5.870
0.941
0.234
1.857
0.780
0.696
0.098
0.474
0.406
0.368
0.245
0.227
2.580
0.191
0.047
0.013
1.733
0.827
1.035
0.109
0.591
0.025
0.472
0.029
0.437
0.021
0.332
1.938
2.438
1.582
0.084
0.698
0.593
0.905
0.117
3.672
0.230
0.640
0.385
0.256
1.984
2.775
0.021
0.902
7.293
0.104
0.201
6.249
0.990
0.273
1.931
0.841
0.751
0.113
0.510
0.421
0.382
0.268
0.245
2.707
BDL
0.057
0.016
1.959
0.866
1.144
0.138
0.635
0.029
0.452
0.035
0.467
0.022
0.362
1.852
2.331
1.600
0.083
0.672
0.560
0.886
0.111
3.524
0.220
0.605
0.365
0.247
1.930
2.689
0.021
0.873
7.124
0.111
0.211
6.059
0.965
0.253
1.894
0.811
0.724
0.105
0.492
0.414
0.375
0.256
0.236
2.644
BDL
0.052
0.015
1.846
0.847
1.089
0.124
0.613
0.027
0.462
0.032
0.452
0.022
17
9
9
2
3
8
12
4
10
8
9
11
11
7
6
6
0
7
5
14
9
6
5
15
4
7
8
15
7
4
4
9
8
5
18
17
12
5
10
24
7
13
4
20
7
7
(APPENDIX V Table 7 Cont'd.)
9471DupF1
ng/g
average
ng/g
percent difference
ORGANOCHLORINE PESTICIDES
9471F1
ng/g
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
0.565
5.431
5.840
0.654
0.962
5.601
19.053
0.547
6.323
5.382
0.644
1.040
5.171
19.107
0.556
5.877
5.611
0.649
1.001
5.386
19.080
3
15
8
2
8
8
0
alpha BHC
beta BHC
delta BHC
lindane
ND
1.154
0.279
0.229
ND
0.778
BDL
BDL
ND
0.966
BDL
BDL
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
0.394
1.663
3.138
2.129
5.747
0.812
6.749
20.633
0.478
1.595
2.852
2.407
5.888
0.719
6.971
20.911
0.436
1.629
2.995
2.268
5.817
0.766
6.860
20.772
19
4
10
12
2
12
3
1
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
2.162
0.193
BDL
3.326
0.663
2.021
BDL
BDL
3.377
0.632
2.091
BDL
BDL
3.351
0.648
7
average of total OCP's
39
2
5
9
(APPENDIX V Table 7 Cont'd.)
CHEM ID
F-number
LIPID PERCENT (%)
EXTRACTION MASS (g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
9543R F1
F-2522
4.93
2.106
9543dup F1
F-2522
5.29
2.026
average
percent difference
5.11
2.066
7
4
134
86
116
122
78
104
128
82
110
9
9
11
1275.0
275.9
119.4
1245.3
279.5
127.8
1260.1
277.7
123.6
2
1
7
PCB's
ng/g
ng/g
ng/g
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
0.320
1.000
0.424
0.138
0.464
5.159
0.357
ND
11.824
6.584
1.006
13.264
BDL
4.774
1.997
48.764
13.737
15.603
2.797
0.374
28.510
29.029
22.563
6.926
33.257
16.948
42.385
6.121
1.196
2.755
27.065
31.381
97.950
0.509
2.298
0.394
0.115
0.435
5.080
0.373
0.069
11.343
6.260
0.983
12.863
BDL
4.458
1.673
44.429
13.100
15.063
2.511
0.383
27.127
28.560
24.913
4.900
31.801
15.971
40.765
6.390
1.264
2.542
26.064
30.284
94.080
0.414
1.649
0.409
0.127
0.449
5.119
0.365
ND
11.583
6.422
0.995
13.063
BDL
4.616
1.835
46.597
13.419
15.333
2.654
0.378
27.819
28.795
23.738
5.913
32.529
16.460
41.575
6.255
1.230
2.648
26.564
30.833
96.015
TOTAL PCBs (ng/g dw)
TOTAL DDXs (ng/g dw)
TOTAL CHLORDANES (ng/g dw)
46
79
7
18
6
2
4
4
5
2
3
7
18
9
5
4
11
2
5
2
10
34
4
6
4
4
5
8
4
4
4
(APPENDIX V Table 7 Cont'd.)
9543dup F1
ng/g
average
ng/g
percent difference
PCB's
9543R F1
ng/g
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
5.555
39.435
31.424
21.173
1.977
10.571
ND
9.398
2.492
47.550
3.803
10.804
6.327
4.276
29.026
35.912
0.373
13.604
103.181
3.380
3.282
83.629
11.869
4.852
38.770
16.650
8.275
2.530
12.604
9.435
11.315
4.133
4.730
67.352
5.490
0.999
0.806
44.544
18.975
26.682
2.527
15.234
0.578
13.734
0.473
10.195
0.361
5.301
38.840
29.620
20.930
1.942
10.054
7.205
9.256
2.362
45.715
4.019
10.256
6.287
4.382
28.130
35.156
0.391
13.233
99.831
3.187
3.258
81.287
12.165
5.052
37.764
16.459
8.466
2.444
12.330
8.996
11.065
3.818
4.494
67.963
5.733
1.011
0.824
43.038
18.106
25.907
2.716
14.651
0.624
13.187
0.500
9.995
0.332
5.428
39.138
30.522
21.051
1.960
10.313
ND
9.327
2.427
46.633
3.911
10.530
6.307
4.329
28.578
35.534
0.382
13.418
101.506
3.284
3.270
82.458
12.017
4.952
38.267
16.555
8.371
2.487
12.467
9.215
11.190
3.975
4.612
67.657
5.611
1.005
0.815
43.791
18.540
26.295
2.621
14.942
0.601
13.460
0.486
10.095
0.347
5
2
6
1
2
5
2
5
4
6
5
1
2
3
2
5
3
3
6
1
3
2
4
3
1
2
3
2
5
2
8
5
1
4
1
2
3
5
3
7
4
8
4
6
2
8
(APPENDIX V Table 7 Cont'd.)
9543dup F1
ng/g
average
ng/g
percent difference
ORGANOCHLORINE PESTICIDES
9543R F1
ng/g
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
10.457
166.719
18.368
1.197
18.937
60.203
275.881
10.649
163.616
20.001
1.118
21.566
62.576
279.526
10.553
165.167
19.184
1.157
20.252
61.389
277.703
2
2
9
7
13
4
1
alpha BHC
beta BHC
delta BHC
lindane
0.222
4.686
0.354
0.353
0.398
4.514
0.290
0.412
0.310
4.600
0.322
0.383
57
4
20
15
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
10.759
NQ
NQ
30.393
40.192
8.870
29.209
119.422
10.270
NQ
NQ
32.042
45.960
9.492
30.035
127.799
10.515
NQ
NQ
31.217
43.076
9.181
29.622
123.610
5
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
11.968
0.424
BDL
2.570
0.911
13.620
0.584
BDL
2.975
0.618
12.794
0.504
BDL
2.773
0.764
average of total OCP's
5
13
7
3
7
13
32
15
38
14
(APPENDIX V Table 7 Cont'd.)
CHEM ID
F-number
LIPID PERCENT (%)
EXTRACTION MASS (g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
9544-F1
F-2523
3.89
1.994
9544dup-F1
F-2523
3.90
1.958
average
percent difference
3.89
1.976
0
2
111
93
100
112
93
98
112
93
99
1
0
2
880.8
177.6
211.0
867.6
182.4
219.1
874.2
180.0
215.1
2
3
4
PCB's
ng/g
ng/g
ng/g
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
0.220
1.197
0.321
0.070
0.170
2.642
0.347
0.149
7.321
3.627
0.490
8.030
BDL
2.784
0.778
23.003
7.482
10.641
5.528
0.404
21.009
19.812
ND
5.997
24.920
11.651
27.581
4.797
2.190
1.922
15.308
18.748
64.034
0.322
0.843
0.319
0.063
0.197
2.477
0.319
0.083
7.448
3.493
0.581
7.803
BDL
2.697
0.901
21.793
4.488
10.311
7.109
0.332
21.148
20.529
6.029
4.690
24.894
12.089
27.901
4.581
1.774
1.937
15.584
19.221
65.292
0.271
1.020
0.320
0.067
0.183
2.560
0.333
0.116
7.384
3.560
0.535
7.916
BDL
2.740
0.839
22.398
5.985
10.476
6.318
0.368
21.078
20.170
ND
5.343
24.907
11.870
27.741
4.689
1.982
1.930
15.446
18.985
64.663
TOTAL PCBs (ng/g dw)
TOTAL DDXs (ng/g dw)
TOTAL CHLORDANES (ng/g dw)
38
35
1
11
15
6
8
57
2
4
17
3
3
15
5
50
3
25
20
1
4
24
0
4
1
5
21
1
2
2
2
(APPENDIX V Table 7 Cont'd.)
9544dup-F1
ng/g
average
ng/g
percent difference
PCB's
9544-F1
ng/g
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
5.121
30.349
21.332
13.117
1.530
7.703
5.588
32.166
1.755
36.517
2.709
7.505
4.686
2.693
22.277
22.873
0.485
9.378
67.299
2.603
0.544
58.380
8.322
1.798
24.856
11.362
8.181
1.873
9.473
6.610
8.294
2.760
3.538
41.138
4.119
1.102
0.667
28.659
14.195
19.487
1.832
12.119
0.858
8.985
0.628
9.905
0.266
5.028
29.439
21.411
13.868
1.534
7.684
5.487
18.318
1.815
36.659
2.663
7.496
4.727
2.810
22.561
22.928
0.458
9.555
67.596
2.633
0.754
58.253
7.985
3.339
24.422
11.021
7.690
1.736
9.556
6.661
8.298
2.801
3.552
39.581
4.780
0.955
0.616
27.882
13.983
19.046
1.747
11.575
0.737
8.448
0.495
9.516
0.253
5.075
29.894
21.372
13.493
1.532
7.694
5.538
25.242
1.785
36.588
2.686
7.500
4.707
2.751
22.419
22.901
0.472
9.466
67.447
2.618
0.649
58.316
8.154
2.568
24.639
11.192
7.936
1.805
9.515
6.636
8.296
2.780
3.545
40.360
4.449
1.028
0.642
28.270
14.089
19.267
1.789
11.847
0.797
8.717
0.562
9.711
0.259
2
3
0
6
0
0
2
55
3
0
2
0
1
4
1
0
6
2
0
1
32
0
4
60
2
3
6
8
1
1
0
1
0
4
15
14
8
3
2
2
5
5
15
6
24
4
5
(APPENDIX V Table 7 Cont'd.)
ORGANOCHLORINE PESTICIDES
9544-F1
ng/g
9544dup-F1
ng/g
average
ng/g
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
ND
43.098
31.837
1.124
17.172
84.334
177.565
ND
47.939
32.220
1.568
16.816
83.868
182.411
ND
45.519
32.029
1.346
16.994
84.101
179.988
alpha BHC
beta BHC
delta BHC
lindane
BDL
1.951
BDL
0.215
BDL
1.906
BDL
0.245
BDL
1.928
BDL
0.230
13
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
5.384
6.949
7.291
42.393
66.885
8.040
74.068
211.010
5.646
6.860
7.403
42.576
76.597
7.911
72.155
219.149
5.515
6.904
7.347
42.485
71.741
7.975
73.112
215.080
5
1
2
0
14
2
3
4
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
15.918
0.337
0.362
1.836
1.812
15.397
0.406
0.362
1.662
1.857
15.658
0.372
0.362
1.749
1.834
3
19
0
10
2
average of total OCP's
percent difference
11
1
33
2
1
3
2
6
(APPENDIX V Table 7 Cont'd.)
CHEM ID
F-number
LIPID PERCENT (%)
EXTRACTION MASS (g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
0238-F1
F-2402
0.97
2.016
0238dup-F1
F-2402
0.80
2.070
average
percent difference
0.89
2.043
19
3
95
90
94
107
96
100
101
93
97
11
7
6
47.5
5.2
8.2
46.7
4.7
8.0
47.1
4.9
8.1
2
11
3
PCB's
ng/g
ng/g
ng/g
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
BDL
1.155
BDL
BDL
0.029
0.151
BDL
0.139
BDL
0.090
BDL
BDL
BDL
0.022
BDL
0.327
0.088
0.225
0.032
0.035
0.664
0.525
BDL
BDL
0.322
0.257
0.659
0.072
0.110
0.072
0.705
0.608
2.527
BDL
BDL
BDL
BDL
BDL
0.140
0.030
0.064
BDL
0.029
BDL
BDL
BDL
0.031
BDL
0.322
0.091
0.253
0.029
0.031
0.678
0.556
BDL
0.327
0.333
0.269
0.601
0.067
0.118
0.075
0.666
0.619
2.528
BDL
BDL
BDL
BDL
BDL
0.146
BDL
0.101
BDL
0.059
BDL
BDL
BDL
0.027
BDL
0.325
0.089
0.239
0.030
0.033
0.671
0.540
BDL
BDL
0.328
0.263
0.630
0.069
0.114
0.074
0.686
0.613
2.527
TOTAL PCBs (ng/g dw)
TOTAL DDXs (ng/g dw)
TOTAL CHLORDANES (ng/g dw)
8
74
102
36
2
3
11
9
13
2
6
3
5
9
8
7
4
6
2
0
(APPENDIX V Table 7 Cont'd.)
0238dup-F1
ng/g
average
ng/g
percent difference
PCB's
0238-F1
ng/g
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
0.203
0.737
1.724
1.202
0.061
0.457
0.362
1.378
0.031
1.953
0.097
0.346
0.085
0.218
1.570
2.030
0.043
0.902
6.312
0.074
BDL
5.174
0.698
0.180
1.381
0.627
0.833
0.080
0.360
0.285
0.360
0.181
0.222
1.790
3.106
0.047
BDL
1.233
0.564
0.688
0.091
0.386
0.030
0.242
0.042
0.270
0.014
0.208
0.755
1.743
1.194
0.062
0.476
0.379
1.418
0.040
1.893
0.112
0.390
0.138
0.227
1.551
2.045
0.032
0.945
6.289
0.058
BDL
5.154
0.648
0.206
1.357
0.588
0.808
0.072
0.346
0.275
0.341
0.171
0.213
1.717
3.308
0.041
BDL
1.293
0.551
0.690
0.105
0.445
0.060
0.237
0.018
0.260
0.015
0.206
0.746
1.733
1.198
0.061
0.466
0.371
1.398
0.036
1.923
0.105
0.368
0.112
0.222
1.561
2.037
0.038
0.923
6.301
0.066
BDL
5.164
0.673
0.193
1.369
0.607
0.820
0.076
0.353
0.280
0.350
0.176
0.217
1.754
3.207
0.044
BDL
1.263
0.557
0.689
0.098
0.415
0.045
0.240
0.030
0.265
0.014
2
2
1
1
3
4
5
3
25
3
15
12
47
4
1
1
28
5
0
25
0
7
13
2
6
3
10
4
3
5
5
4
4
6
12
5
2
0
15
14
66
2
80
4
9
(APPENDIX V Table 7 Cont'd.)
ORGANOCHLORINE PESTICIDES
0238-F1
ng/g
0238dup-F1
ng/g
average
ng/g
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
ND
1.356
3.068
BDL
BDL
0.758
5.182
ND
1.181
2.762
BDL
BDL
0.713
4.656
ND
1.268
2.915
BDL
BDL
0.736
4.919
alpha BHC
beta BHC
delta BHC
lindane
BDL
0.533
BDL
BDL
BDL
0.471
BDL
BDL
BDL
0.502
BDL
BDL
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
BDL
0.200
0.988
BDL
0.510
0.786
5.753
8.238
0.113
0.195
0.901
BDL
0.459
0.729
5.572
7.969
BDL
0.197
0.945
BDL
0.485
0.758
5.662
8.103
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
0.064
BDL
BDL
0.378
0.207
0.034
BDL
BDL
0.339
0.185
0.049
BDL
BDL
0.358
0.196
average of total OCP's
percent difference
14
10
6
11
12
3
9
11
8
3
3
61
11
11
13
(APPENDIX V Table 7 Cont'd.)
CHEM ID
F-number
LIPID PERCENT (%)
EXTRACTION MASS (g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
0248-F1
F-2412
0.40
2.007
0248dup-F1
F-2412
0.30
2.059
average
percent difference
0.35
2.033
31
3
75
69
68
95
88
87
85
79
78
23
24
24
36.5
24.3
14.0
34.4
48.2
12.7
35.4
36.3
13.3
6
66
9
PCB's
ng/g
ng/g
ng/g
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
BDL
BDL
BDL
BDL
BDL
0.549
0.039
BDL
0.173
0.114
BDL
0.193
BDL
0.078
BDL
0.514
0.106
0.463
0.085
0.066
0.831
0.776
BDL
BDL
0.581
0.359
0.456
0.119
0.042
0.064
0.536
0.718
2.496
BDL
BDL
0.089
BDL
BDL
0.536
BDL
ND
0.196
0.112
0.165
0.187
BDL
0.069
BDL
0.457
0.161
0.516
0.095
0.070
0.757
0.728
BDL
0.244
0.592
0.373
0.446
0.112
0.038
0.053
0.506
0.651
2.484
BDL
BDL
BDL
BDL
BDL
0.543
BDL
BDL
0.185
0.113
BDL
0.190
BDL
0.073
BDL
0.486
0.134
0.490
0.090
0.068
0.794
0.752
BDL
BDL
0.586
0.366
0.451
0.115
0.040
0.059
0.521
0.684
2.490
TOTAL PCBs (ng/g dw)
TOTAL DDXs (ng/g dw)
TOTAL CHLORDANES (ng/g dw)
2
13
2
3
12
12
41
11
11
5
9
6
2
4
2
6
10
19
6
10
0
(APPENDIX V Table 7 Cont'd.)
0248dup-F1
ng/g
average
ng/g
percent difference
PCB's
0248-F1
ng/g
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
0.300
1.330
1.397
0.863
0.227
0.416
0.771
0.507
0.068
1.821
0.121
0.374
0.232
0.156
1.360
1.377
0.022
0.541
4.049
0.054
0.094
3.210
0.468
0.114
0.987
0.447
0.411
0.064
0.265
0.205
0.242
ND
0.101
1.237
BDL
0.042
0.024
0.921
0.529
0.663
0.074
0.355
0.035
0.232
0.014
0.290
0.136
0.272
1.247
1.254
0.829
0.194
0.363
0.797
0.448
0.065
1.653
0.124
0.336
0.212
0.148
1.218
1.206
0.023
0.472
3.625
0.055
0.141
2.912
0.486
0.139
0.914
0.420
0.394
0.060
0.250
0.178
0.207
ND
0.140
1.052
BDL
BDL
0.013
0.835
0.474
0.589
0.077
0.330
0.021
0.180
BDL
0.280
0.113
0.286
1.288
1.325
0.846
0.211
0.390
0.784
0.477
0.066
1.737
0.123
0.355
0.222
0.152
1.289
1.291
0.022
0.506
3.837
0.054
0.117
3.061
0.477
0.127
0.950
0.434
0.403
0.062
0.258
0.191
0.225
ND
0.121
1.144
BDL
BDL
0.018
0.878
0.501
0.626
0.075
0.342
0.028
0.206
BDL
0.285
0.124
10
6
11
4
16
14
3
12
5
10
2
11
9
5
11
13
3
14
11
2
41
10
4
20
8
6
4
5
6
15
16
32
16
62
10
11
12
4
7
50
25
4
18
0248dup-F1
ng/g
average
ng/g
percent difference
ORGANOCHLORINE PESTICIDES
0248-F1
ng/g
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
0.909
7.941
10.553
0.732
0.751
3.464
24.349
0.906
7.445
26.796
2.011
0.697
10.343
48.198
0.907
7.693
18.674
1.372
0.724
6.904
36.273
0
6
87
93
7
100
66
alpha BHC
beta BHC
delta BHC
lindane
0.579
0.206
BDL
0.491
0.581
0.225
0.523
0.680
0.580
0.216
BDL
0.585
0
9
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
0.366
1.278
1.625
1.374
3.337
ND
5.991
13.971
0.356
1.288
1.426
1.241
2.542
0.339
5.529
12.721
0.361
1.283
1.526
1.307
2.939
BDL
5.760
13.346
3
1
13
10
27
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
0.632
BDL
BDL
2.219
0.362
0.578
4.903
BDL
1.873
4.627
0.605
BDL
BDL
2.046
2.494
9
average of total OCP's
32
8
9
17
171
33
(APPENDIX V Table 7 Cont'd.)
CHEM ID
F-number
LIPID PERCENT (%)
EXTRACTION MASS (g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
0257-F1
F-2421
1.55
2.058
0257dup-F1
F-2421
1.57
2.568
average
percent difference
1.56
2.313
1
22
105
99
96
104
96
95
104
98
96
1
3
1
704.7
201.2
138.8
708.3
206.3
142.0
706.5
203.7
140.4
1
3
2
PCB's
ng/g
ng/g
ng/g
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
BDL
BDL
0.394
0.051
0.252
2.085
0.736
BDL
3.751
3.794
1.125
6.018
BDL
3.112
2.082
20.403
2.802
7.350
1.522
0.989
19.994
19.605
32.724
3.010
16.495
9.592
12.267
3.387
5.119
1.858
12.354
22.631
58.219
BDL
0.250
0.410
0.044
0.256
2.108
0.750
0.014
3.802
3.840
1.156
6.153
ND
3.139
2.159
21.174
3.358
7.738
1.482
1.011
19.976
19.657
33.004
2.810
16.853
9.856
12.546
3.630
5.204
1.786
12.748
22.848
58.872
BDL
BDL
0.402
0.048
0.254
2.097
0.743
BDL
3.777
3.817
1.140
6.085
BDL
3.125
2.121
20.789
3.080
7.544
1.502
1.000
19.985
19.631
32.864
2.910
16.674
9.724
12.406
3.509
5.162
1.822
12.551
22.740
58.545
TOTAL PCBs (ng/g dw)
TOTAL DDXs (ng/g dw)
TOTAL CHLORDANES (ng/g dw)
4
16
2
1
2
1
1
3
2
1
4
4
18
5
3
2
0
0
1
7
2
3
2
7
2
4
3
1
1
(APPENDIX V Table 7 Cont'd.)
0257dup-F1
ng/g
average
ng/g
percent difference
PCB's
0257-F1
ng/g
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
4.538
18.375
21.582
12.560
1.167
6.427
10.578
6.686
2.117
31.778
2.278
10.027
5.442
4.015
16.311
14.363
0.302
7.018
50.573
1.988
2.031
39.278
6.724
4.022
13.473
8.896
5.759
1.592
7.007
4.440
5.687
2.061
4.153
32.447
3.891
0.989
0.098
20.450
9.218
12.641
0.147
6.917
0.431
5.546
0.329
4.107
0.472
4.415
18.496
21.469
12.837
1.162
6.307
10.449
6.757
2.076
31.884
2.299
10.011
5.406
3.981
16.254
14.449
0.290
6.988
50.578
1.960
1.990
39.517
6.739
4.004
13.379
8.856
5.856
1.347
6.940
4.389
5.696
1.391
3.956
31.708
4.030
0.849
0.083
20.867
9.173
13.009
0.112
6.729
0.363
5.591
0.276
4.316
0.447
4.477
18.435
21.526
12.699
1.165
6.367
10.513
6.722
2.097
31.831
2.289
10.019
5.424
3.998
16.283
14.406
0.296
7.003
50.575
1.974
2.010
39.398
6.731
4.013
13.426
8.876
5.807
1.469
6.973
4.415
5.692
1.726
4.055
32.078
3.960
0.919
0.090
20.658
9.195
12.825
0.129
6.823
0.397
5.569
0.302
4.212
0.459
3
1
1
2
0
2
1
1
2
0
1
0
1
1
0
1
4
0
0
1
2
1
0
0
1
0
2
17
1
1
0
39
5
2
4
15
17
2
0
3
27
3
17
1
18
5
6
(APPENDIX V Table 7 Cont'd.)
0257dup-F1
ng/g
average
ng/g
percent difference
ORGANOCHLORINE PESTICIDES
0257-F1
ng/g
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
11.182
113.327
26.741
1.175
7.526
41.208
201.160
11.632
116.201
28.026
0.933
6.953
42.577
206.322
11.407
114.764
27.384
1.054
7.239
41.892
203.741
4
3
5
23
8
3
3
alpha BHC
beta BHC
delta BHC
lindane
0.301
BDL
0.147
0.445
0.180
BDL
0.143
0.503
0.241
BDL
0.145
0.474
50
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
17.446
5.240
7.421
12.004
32.505
4.212
59.972
138.800
17.871
4.969
7.175
12.287
32.129
4.312
63.223
141.967
17.658
5.104
7.298
12.145
32.317
4.262
61.598
140.383
2
5
3
2
1
2
5
2
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
2.506
BDL
0.477
0.382
1.541
2.348
0.127
0.407
0.389
1.536
2.427
BDL
0.442
0.385
1.539
7
average of total OCP's
3
12
16
2
0
8
(APPENDIX V Table 7 Cont'd.)
CHEM ID
F-number
LIPID PERCENT (%)
EXTRACTION MASS (g)
SURROGATE RECOVERY (%)
PCB 14
PCB 65
PCB 166
0378-F1
F-2068
3.57
2.01
0378dup-F1
F-2068
3.53
2.009
average
percent difference
3.55
2.010
1
0
103
100
95
106
99
97
104
99
96
3
0
2
138.6
41.5
35.6
140.9
43.2
36.0
139.8
42.4
35.8
2
4
1
PCB's
ng/g
ng/g
ng/g
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
ND
ND
BDL
ND
0.056
0.218
0.047
0.058
0.255
0.092
BDL
0.268
BDL
0.134
BDL
3.892
0.660
1.941
0.170
0.049
4.572
3.471
BDL
0.260
3.758
0.982
2.014
0.531
ND
0.218
2.221
5.280
5.493
ND
BDL
BDL
ND
ND
0.265
ND
BDL
0.198
0.067
BDL
0.237
BDL
0.130
BDL
4.074
0.571
1.915
0.171
0.022
4.719
3.690
BDL
0.308
4.031
1.158
2.091
0.579
ND
0.190
2.314
5.248
5.355
ND
BDL
BDL
ND
BDL
0.242
BDL
BDL
0.227
0.080
BDL
0.253
BDL
0.132
BDL
3.983
0.615
1.928
0.171
0.035
4.645
3.581
BDL
0.284
3.894
1.070
2.052
0.555
ND
0.204
2.268
5.264
5.424
TOTAL PCBs (ng/g dw)
TOTAL DDXs (ng/g dw)
TOTAL CHLORDANES (ng/g dw)
20
25
32
12
3
5
15
1
1
77
3
6
17
7
16
4
9
14
4
1
3
(APPENDIX V Table 7 Cont'd.)
0378dup-F1
ng/g
average
ng/g
percent difference
PCB's
0378-F1
ng/g
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
0.740
3.877
6.207
3.135
0.357
1.751
3.213
0.909
0.397
8.911
0.697
1.844
1.259
0.655
4.821
4.978
0.082
1.852
14.731
0.549
0.624
12.071
1.621
0.624
2.802
1.379
1.232
0.237
1.202
1.136
0.501
0.415
0.544
4.458
0.632
0.130
0.095
3.410
1.750
2.044
0.412
1.373
0.114
0.836
0.128
0.936
0.279
0.779
3.917
6.312
3.091
0.398
1.781
3.248
0.769
0.383
9.028
0.682
1.838
1.207
0.677
5.133
5.259
0.089
1.909
15.385
0.493
0.644
12.478
1.619
0.595
3.023
1.291
1.279
0.243
1.194
1.191
0.512
0.363
0.524
4.447
0.618
0.090
0.079
3.425
1.814
2.050
0.371
1.302
0.088
0.801
0.052
0.863
0.272
0.759
3.897
6.260
3.113
0.377
1.766
3.230
0.839
0.390
8.969
0.690
1.841
1.233
0.666
4.977
5.119
0.085
1.881
15.058
0.521
0.634
12.274
1.620
0.609
2.913
1.335
1.255
0.240
1.198
1.164
0.507
0.389
0.534
4.452
0.625
0.110
0.087
3.417
1.782
2.047
0.391
1.338
0.101
0.819
0.090
0.900
0.276
5
1
2
1
11
2
1
17
4
1
2
0
4
3
6
5
8
3
4
11
3
3
0
5
8
7
4
3
1
5
2
13
4
0
2
37
18
0
4
0
11
5
26
4
85
8
3
(APPENDIX V Table 7 Cont'd.)
0378dup-F1
ng/g
average
ng/g
percent difference
ORGANOCHLORINE PESTICIDES
0378-F1
ng/g
opDDE
ppDDE
op ddt
pp ddt
o,p ddd
p,p ddd
Total DDXs
3.031
22.888
8.246
BDL
1.160
6.218
41.544
3.247
24.304
8.334
BDL
1.045
6.234
43.164
3.139
23.596
8.290
BDL
1.103
6.226
42.354
7
6
1
alpha BHC
beta BHC
delta BHC
lindane
BDL
BDL
0.125
ND
BDL
BDL
0.092
BDL
BDL
BDL
0.109
BDL
heptaclor
heptachlor epoxide
oxychlordane
gamma chlordane
alpha chlordane
cis nonachlor
trans nonachlor
Total Chlordanes
0.504
4.157
2.827
7.793
10.954
ND
9.355
35.590
0.441
4.062
2.785
7.572
10.571
0.566
9.976
35.971
0.472
4.109
2.806
7.683
10.762
BDL
9.666
35.781
13
2
2
3
4
dieldrin
endrin
aldrin
endosulfan 1
endosulfan II
1.062
BDL
0.342
0.621
0.619
1.065
BDL
0.315
0.718
0.657
1.063
BDL
0.328
0.670
0.638
0
average of total OCP's
BDL - Below Detection Limit
ND - Not Detected
10
0
4
30
6
1
8
15
6
7
Mean RPD
12
Std. Dev
8
APPENDIX V Table 8. Results of Triplicate Analysis for Individual PCB Congeners
and Organochlorine Pesticides
CHEM ID
9454F1
9454dupF1
9454tripF1
Average
Standard Deviation
Relative
Standard Deviation
F-number
F-2495
F-2495
LIPID PERCENT (%)
2.13
2.15
F-2495
2.12
2.13
0.01
1
EXTRACTION MASS (g)
1.988
1.999
2.124
2.04
0.08
4
PCB 14
112
122
114
116
5
5
PCB 65
88
98
92
93
5
6
PCB 166
97
107
101
101
5
5
TOTAL PCBs (ng/g dw)
310
339
333
327
15
5
TOTAL DDXs (ng/g dw)
58.9
67.7
67.6
65
5
8
TOTAL CHLORDANES (ng/g dw)
39.6
44.8
45.2
43
3
7
PCBs
ng/g
ng/g
ng/g
1
0.374
0.215
0.184
0.258
0.102
40
3
0.872
0.399
0.327
0.533
0.296
56
4+10
BDL
BDL
BDL
BDL
SURROGATE RECOVERY (%)
7
BDL
BDL
BDL
BDL
6
0.049
0.036
0.028
0.038
0.010
27
8+5
0.492
0.498
0.473
0.488
0.013
3
19
0.045
BDL
BDL
BDL
12+13
0.026
0.016
BDL
BDL
18
0.728
0.778
0.759
0.755
0.025
3
17
0.312
0.340
0.331
0.327
0.014
4
24+27
BDL
BDL
BDL
BDL
16+32
0.532
0.583
0.588
0.568
0.031
5
0.021
4
29
BDL
BDL
BDL
BDL
26
0.472
0.510
0.506
0.496
25
BDL
BDL
BDL
BDL
31+28
4.954
5.330
5.491
5.258
0.275
5
53+33+21
0.830
0.944
0.884
0.886
0.057
6
22
1.801
1.968
1.970
1.913
0.097
5
45
0.465
0.485
0.493
0.481
0.015
3
46
0.052
0.055
0.057
0.055
0.003
5
52
4.474
4.974
4.854
4.767
0.261
5
49
4.119
4.555
4.472
4.382
0.232
5
47
1.517
1.690
1.522
1.576
0.099
6
48
0.488
0.480
0.445
0.471
0.023
5
44
3.954
4.444
4.179
4.193
0.245
6
37+42
1.450
1.643
0.906
1.333
0.382
29
41+71
4.487
5.196
4.799
4.827
0.356
7
40
0.642
0.729
0.714
0.695
0.047
7
100
0.608
0.629
0.587
0.608
0.021
3
63
0.494
0.576
0.532
0.534
0.041
8
74
4.315
4.849
4.722
4.629
0.279
6
70+76
4.434
5.124
4.791
4.783
0.345
7
66+95
15.133
17.029
16.232
16.131
0.952
6
91
1.092
1.182
1.191
1.155
0.055
5
56+60
5.093
5.562
5.378
5.345
0.236
4
101
7.897
8.791
8.620
8.436
0.474
6
99
7.446
4.895
5.031
5.791
1.435
25
83
0.433
0.504
0.453
0.463
0.037
8
97
2.469
2.737
2.749
2.652
0.159
6
87+81
1.930
2.163
2.151
2.081
0.131
6
85
0.895
1.013
0.955
0.954
0.059
6
(APPENDIX V Table 8 Cont'd)
CHEM ID
9454F1
9454dupF1
9454tripF1
Average
Standard Deviation
Relative
Standard Deviation
136
0.367
0.401
0.384
0.384
0.017
4
77+110
12.906
14.441
14.306
13.885
0.850
6
82
0.623
0.739
0.730
0.697
0.065
9
151
1.753
2.025
1.968
1.915
0.144
7
135+144
1.548
1.735
1.691
1.658
0.098
6
107
1.074
1.277
1.228
1.193
0.106
9
149
8.484
9.590
9.251
9.108
0.567
6
118
10.054
10.919
10.772
10.582
0.463
4
131
0.215
0.223
0.231
0.223
0.008
4
146
3.867
4.307
4.181
4.118
0.227
6
153+132+105
34.570
38.213
37.267
36.683
1.890
5
5
141
0.729
0.804
0.775
0.769
0.037
137+176
1.153
1.271
1.273
1.232
0.069
6
163+138
26.909
29.846
29.287
28.681
1.560
5
158
1.707
1.882
1.869
1.819
0.097
5
129+178
2.094
1.626
1.588
1.769
0.282
16
187+182
9.536
10.530
10.314
10.127
0.523
5
183
5.823
6.404
6.308
6.178
0.312
5
128
2.335
2.514
2.514
2.454
0.103
4
185
0.810
0.887
0.854
0.850
0.038
5
174
4.289
4.701
4.664
4.551
0.228
5
177
3.217
3.524
3.489
3.410
0.168
5
202+171
3.480
3.808
3.796
3.695
0.186
5
157+200
1.276
1.431
1.376
1.361
0.078
6
172+197
6.453
7.176
7.021
6.883
0.381
6
180
31.314
33.699
33.814
32.942
1.411
4
193
3.644
4.864
5.029
4.512
0.757
17
191
0.538
0.575
0.632
0.582
0.048
8
199
0.168
0.173
0.183
0.175
0.008
4
170+190
14.572
16.240
16.174
15.662
0.945
6
201
6.350
7.014
6.963
6.776
0.369
5
203+196
9.418
10.424
10.418
10.087
0.579
6
189
0.869
0.957
0.953
0.926
0.050
5
208+195
4.899
5.447
5.476
5.274
0.325
6
207
0.220
0.248
0.257
0.242
0.019
8
194
4.172
4.655
4.663
4.496
0.281
6
205
0.203
0.212
0.229
0.214
0.013
6
206
2.955
3.316
3.284
3.185
0.200
6
209
0.154
0.174
0.171
0.166
0.011
7
(APPENDIX V Table 8 Cont'd)
ORGANOCHLORINE PESTICIDES
CHEM ID
9454F1
9454dupF1
9454tripF1
ng/g
ng/g
ng/g
Average
Standard Deviation
Relative
Standard Deviation
opDDE
2.219
2.465
2.423
2.369
0.131
6
ppDDE
42.101
48.229
49.074
46.468
3.805
8
op ddt
4.244
4.885
4.566
4.565
0.321
7
pp ddt
BDL
BDL
BDL
BDL
o,p ddd
0.682
0.887
0.944
0.838
0.138
16
p,p ddd
9.615
11.228
10.564
10.469
0.811
8
Total DDXs
58.861
67.694
67.571
64.709
5.065
8
alpha BHC
BDL
BDL
BDL
BDL
BDL
beta BHC
0.327
ND
0.511
delta BHC
BDL
BDL
BDL
BDL
lindane
0.320
0.386
0.280
0.328
0.053
16
heptaclor
0.665
0.743
0.755
0.721
0.049
7
heptachlor epoxide
2.077
2.159
2.270
2.169
0.097
4
oxychlordane
0.962
1.217
1.082
1.087
0.127
12
gamma chlordane
3.830
4.492
5.515
4.612
0.849
18
alpha chlordane
1.683
2.333
1.876
1.964
0.334
17
cis nonachlor
9.475
9.906
10.145
9.842
0.339
3
trans nonachlor
20.881
23.987
23.548
22.805
1.681
7
Total Chlordanes
39.572
44.837
45.191
43.200
3.147
7
dieldrin
4.057
4.432
4.658
4.382
0.304
7
endrin
ND
ND
ND
ND
aldrin
BDL
0.175
BDL
BDL
endosulfan 1
1.554
1.850
2.008
1.804
0.230
13
endosulfan II
0.516
0.730
0.613
0.620
0.107
17
10
BDL - Below Detection Limit
ND - Not Detected
(APPENDIX V Table 8 Cont'd)
CHEM ID
0272-F1
0272dup-F1
0272trip-F1
Average
Standard Deviation
Relative
Standard Deviation
F-number
F-2036
F-2036
LIPID PERCENT (%)
0.52
0.71
F-2036
0.77
0.669
0.131
20
EXTRACTION MASS (g)
2.032
2.017
2.01
2.020
0.011
1
PCB 14
100
99
98
98.822
1.080
1
PCB 65
92
92
98
93.981
3.545
4
PCB 166
84
85
0
56.368
48.820
87
TOTAL PCBs (ng/g dw)
18.5
18.3
19.1
18.616
0.417
2
TOTAL DDXs (ng/g dw)
5.0
5.0
4.1
4.686
0.550
12
TOTAL CHLORDANES (ng/g dw)
1.3
1.6
1.1
1.336
0.257
19
PCBs
ng/g
ng/g
ng/g
1
ND
ND
ND
SURROGATE RECOVERY (%)
ND
3
ND
ND
ND
ND
4+10
BDL
BDL
BDL
BDL
7
BDL
BDL
BDL
BDL
6
ND
BDL
ND
BDL
8+5
ND
ND
ND
ND
19
BDL
0.034
BDL
BDL
12+13
ND
ND
ND
ND
18
ND
BDL
ND
BDL
17
ND
BDL
ND
BDL
24+27
BDL
BDL
BDL
BDL
16+32
BDL
BDL
BDL
BDL
29
BDL
BDL
BDL
BDL
26
0.048
0.028
BDL
BDL
25
BDL
BDL
BDL
BDL
0.014
31+28
0.315
0.342
0.342
0.333
53+33+21
BDL
BDL
BDL
BDL
0.016
5
22
0.312
0.331
0.226
0.290
45
BDL
ND
BDL
BDL
0.056
19
46
0.026
ND
BDL
BDL
52
0.422
0.400
0.475
0.432
0.038
9
49
0.318
0.412
0.365
0.365
0.047
13
47
BDL
BDL
BDL
BDL
48
BDL
BDL
BDL
BDL
44
0.240
0.255
0.254
0.250
0.009
4
37+42
0.117
0.133
0.206
0.152
0.047
31
0.010
30
41+71
ND
ND
BDL
BDL
40
0.042
0.040
0.023
0.035
100
0.052
0.026
BDL
BDL
63
0.067
0.066
0.029
0.054
0.022
40
74
0.179
0.167
0.185
0.177
0.009
5
70+76
0.515
0.465
0.507
0.496
0.027
5
66+95
1.197
1.212
0.430
0.946
0.447
47
91
0.091
0.084
0.087
0.087
0.003
4
56+60
0.954
0.952
0.985
0.964
0.018
2
101
0.629
0.645
0.703
0.659
0.039
6
99
0.256
0.256
0.288
0.267
0.018
7
83
0.045
0.034
0.028
0.036
0.009
24
10
97
0.150
0.141
0.172
0.154
0.016
87+81
0.515
0.477
0.505
0.499
0.020
4
85
0.195
0.151
0.174
0.173
0.022
13
(APPENDIX V Table 8 Cont'd)
CHEM ID
0272-F1
0272dup-F1
0272trip-F1
Average
Standard Deviation
Relative
Standard Deviation
136
0.075
0.062
0.051
0.063
0.012
77+110
0.922
0.871
0.944
0.913
0.038
19
4
82
0.099
0.070
0.064
0.078
0.019
24
11
151
0.242
0.214
0.265
0.241
0.026
135+144
0.131
0.124
0.148
0.135
0.012
9
107
0.079
0.064
0.090
0.078
0.013
17
149
0.638
0.694
0.709
0.680
0.037
6
118
0.434
0.428
0.468
0.443
0.021
5
131
0.014
0.010
0.010
0.012
0.002
19
146
0.285
0.254
0.284
0.274
0.018
6
153+132+105
1.991
1.954
2.207
2.051
0.137
7
141
0.089
0.083
0.094
0.089
0.006
6
137+176
0.103
0.084
0.102
0.096
0.011
11
163+138
1.354
1.347
1.526
1.409
0.101
7
158
0.229
0.194
0.251
0.224
0.029
13
129+178
0.173
0.165
0.159
0.166
0.007
4
187+182
0.527
0.548
0.626
0.567
0.052
9
183
0.308
0.320
0.380
0.336
0.039
11
128
0.121
0.120
0.140
0.127
0.012
9
185
0.080
0.083
0.077
0.080
0.003
3
174
0.174
0.156
0.201
0.177
0.023
13
177
0.188
0.183
0.223
0.198
0.022
11
202+171
0.194
0.184
0.218
0.199
0.018
9
157+200
0.075
0.061
0.082
0.073
0.011
15
172+197
0.100
0.089
0.113
0.100
0.012
12
180
0.759
0.781
0.917
0.819
0.085
10
193
ND
BDL
ND
BDL
191
0.018
0.018
0.022
0.019
0.002
12
199
0.015
0.016
0.018
0.016
0.002
10
170+190
0.739
0.734
0.805
0.759
0.040
5
201
0.393
0.391
0.474
0.420
0.047
11
203+196
0.486
0.484
0.589
0.519
0.060
12
189
0.103
0.108
0.068
0.093
0.022
23
208+195
0.288
0.300
0.311
0.300
0.012
4
207
0.021
0.029
0.023
0.024
0.004
18
194
0.202
0.203
0.228
0.211
0.015
7
205
0.021
0.018
0.017
0.018
0.002
13
206
0.134
0.134
0.147
0.138
0.007
5
209
0.027
0.031
0.037
0.032
0.005
15
(APPENDIX V Table 8 Cont'd)
ORGANOCHLORINE PESTICIDES
CHEM ID
0272-F1
0272dup-F1
0272trip-F1
Average
Standard Deviation
Relative
ng/g
ng/g
ng/g
opDDE
0.178
0.208
0.195
0.194
0.015
8
ppDDE
2.546
2.657
1.587
2.263
0.588
26
op ddt
0.506
0.516
0.544
0.522
0.020
4
pp ddt
BDL
BDL
BDL
BDL
o,p ddd
0.109
BDL
BDL
BDL
p,p ddd
1.644
1.641
1.726
1.670
0.048
3
Total DDXs
4.983
5.022
4.051
4.686
0.550
12
alpha BHC
BDL
BDL
BDL
BDL
BDL
Standard Deviation
beta BHC
BDL
BDL
BDL
delta BHC
BDL
BDL
BDL
BDL
lindane
BDL
0.224
ND
BDL
heptaclor
ND
ND
BDL
BDL
heptachlor epoxide
0.171
0.131
BDL
BDL
0.028
0.030
11
0.049
23
oxychlordane
0.284
0.237
0.293
0.271
gamma chlordane
BDL
0.506
BDL
BDL
alpha chlordane
0.202
0.175
0.270
0.216
cis nonachlor
ND
ND
ND
ND
trans nonachlor
0.598
0.577
0.567
0.581
0.016
3
Total Chlordanes
1.254
1.625
1.130
1.336
0.257
19
0.010
12
dieldrin
ND
ND
ND
ND
endrin
BDL
BDL
BDL
BDL
BDL
aldrin
BDL
BDL
BDL
endosulfan 1
BDL
BDL
BDL
BDL
endosulfan II
0.092
0.073
0.082
0.082
11
BDL - Below Detection Limit
ND - Not Detected
(APPENDIX V Table 8 Cont'd)
CHEM ID
0281-F1
0281dup-F1
0281trip-F1
Average
Standard Deviation
Relative
Standard Deviation
F-number
F-2045
F-2045
LIPID PERCENT (%)
1.85
1.74
F-2045
1.61
1.731
0.122
7
EXTRACTION MASS (g)
2.026
2.092
2.016
2.045
0.041
2
PCB 14
98
103
94
98.522
4.688
5
PCB 65
99
99
91
96.314
4.505
5
PCB 166
96
95
88
93.187
4.311
5
TOTAL PCBs (ng/g dw)
192.2
184.9
162.3
179.799
15.586
9
TOTAL DDXs (ng/g dw)
96.3
90.4
76.9
87.854
9.971
11
TOTAL CHLORDANES (ng/g dw)
13.6
13.8
12.0
13.119
0.992
8
PCBs
ng/g
ng/g
ng/g
1
ND
ND
ND
ND
SURROGATE RECOVERY (%)
3
ND
BDL
BDL
BDL
4+10
BDL
BDL
BDL
BDL
7
BDL
BDL
BDL
BDL
6
ND
BDL
BDL
BDL
8+5
ND
BDL
ND
BDL
19
BDL
BDL
BDL
BDL
12+13
BDL
0.023
BDL
BDL
18
0.348
0.332
0.285
0.322
0.033
10
17
0.154
0.142
0.122
0.139
0.016
12
24+27
BDL
BDL
BDL
BDL
16+32
0.293
0.281
0.291
0.289
0.006
2
29
0.088
BDL
BDL
BDL
26
0.166
0.106
0.093
0.122
0.039
32
25
0.474
BDL
BDL
BDL
31+28
1.696
1.617
1.405
1.573
0.151
10
53+33+21
0.173
0.264
0.228
0.221
0.046
21
22
0.924
0.939
0.687
0.850
0.142
17
45
0.209
0.215
0.167
0.197
0.026
13
46
0.094
0.035
ND
BDL
52
2.698
2.666
2.299
2.554
0.222
9
49
1.798
1.743
1.570
1.703
0.119
7
47
1.674
1.469
1.332
1.491
0.172
12
48
0.445
0.436
0.390
0.424
0.030
7
44
2.113
2.124
1.858
2.032
0.150
7
37+42
1.135
0.969
1.118
1.074
0.092
9
41+71
1.481
1.056
1.247
1.261
0.213
17
40
0.401
0.398
0.352
0.383
0.028
7
100
0.115
0.129
0.115
0.120
0.008
6
63
0.244
0.256
0.242
0.247
0.008
3
74
1.939
1.850
1.628
1.806
0.160
9
70+76
3.388
3.218
2.850
3.152
0.275
9
66+95
4.701
4.451
3.847
4.333
0.439
10
91
0.563
0.515
0.454
0.511
0.055
11
56+60
7.979
7.932
6.809
7.573
0.662
9
101
5.979
5.850
5.069
5.633
0.492
9
99
2.923
2.826
2.436
2.728
0.258
9
83
0.390
0.381
0.330
0.367
0.033
9
97
1.547
1.500
1.302
1.450
0.130
9
87+81
3.061
2.886
2.549
2.832
0.260
9
85
1.862
1.521
1.449
1.610
0.221
14
(APPENDIX V Table 8 Cont'd)
CHEM ID
0281-F1
0281dup-F1
0281trip-F1
Average
Standard Deviation
Relative
Standard Deviation
136
0.365
0.356
0.309
0.343
0.030
9
77+110
7.726
7.304
6.338
7.123
0.712
10
82
0.635
0.642
0.537
0.604
0.059
10
151
2.752
2.608
2.245
2.535
0.261
10
135+144
1.461
1.419
1.241
1.374
0.117
9
107
0.862
0.793
0.697
0.784
0.083
11
149
5.877
5.900
5.260
5.679
0.363
6
118
5.219
4.896
4.264
4.793
0.486
10
131
0.064
0.064
0.053
0.060
0.006
11
146
3.224
3.149
2.757
3.043
0.251
8
153+132+105
24.141
23.730
20.984
22.952
1.716
7
141
0.551
0.561
0.509
0.540
0.028
5
137+176
0.952
0.864
0.750
0.855
0.102
12
163+138
18.091
17.426
15.299
16.939
1.458
9
158
2.505
2.345
2.090
2.314
0.209
9
129+178
1.604
1.626
1.443
1.558
0.100
6
187+182
6.948
6.878
5.959
6.595
0.552
8
183
4.131
3.956
3.429
3.839
0.365
10
128
1.564
1.489
1.316
1.456
0.127
9
185
0.507
0.492
0.477
0.492
0.015
3
174
2.609
2.511
2.207
2.442
0.210
9
177
2.256
2.190
1.906
2.117
0.186
9
202+171
2.692
2.596
2.303
2.531
0.203
8
157+200
0.690
0.723
0.588
0.667
0.071
11
10
172+197
1.598
1.500
1.317
1.472
0.142
180
14.107
13.704
11.983
13.265
1.128
9
193
1.266
1.532
1.134
1.311
0.203
15
191
0.302
0.320
0.279
0.300
0.020
7
199
0.072
0.073
0.072
0.073
0.001
1
170+190
8.688
8.201
7.143
8.011
0.790
10
201
4.390
4.274
3.708
4.124
0.365
9
203+196
5.644
5.387
4.738
5.256
0.467
9
189
0.784
0.737
0.613
0.711
0.088
12
208+195
2.632
2.513
2.257
2.468
0.192
8
207
0.178
0.170
0.155
0.168
0.012
7
194
2.203
2.068
1.839
2.037
0.184
9
205
0.151
0.159
0.119
0.143
0.021
15
206
1.475
1.420
1.265
1.387
0.109
8
209
0.217
0.204
0.196
0.205
0.011
5
(APPENDIX V Table 8 Cont'd)
ORGANOCHLORINE PESTICIDES
CHEM ID
0281-F1
0281dup-F1
0281trip-F1
ng/g
ng/g
ng/g
Average
Standard Deviation
Relative
Standard Deviation
opDDE
2.035
2.057
1.719
1.937
0.189
10
ppDDE
65.445
59.062
50.090
58.199
7.714
13
op ddt
5.266
5.259
5.096
5.207
0.096
2
pp ddt
0.754
0.898
0.764
0.805
0.080
10
o,p ddd
4.580
4.832
4.324
4.579
0.254
6
p,p ddd
18.214
18.310
14.859
17.128
1.965
11
Total DDXs
96.294
90.417
76.852
87.854
9.971
11
alpha BHC
BDL
BDL
BDL
BDL
BDL
beta BHC
BDL
BDL
BDL
delta BHC
BDL
BDL
BDL
BDL
lindane
BDL
ND
ND
BDL
heptaclor
0.168
0.187
0.115
0.157
0.037
24
heptachlor epoxide
0.480
0.812
0.546
0.613
0.176
29
oxychlordane
1.547
1.509
1.608
1.555
0.050
3
gamma chlordane
1.843
1.915
1.435
1.731
0.259
15
alpha chlordane
3.057
2.987
2.808
2.951
0.129
4
cis nonachlor
ND
ND
ND
ND
trans nonachlor
6.487
6.385
5.467
6.113
0.562
9
Total Chlordanes
13.582
13.794
11.979
13.119
0.992
8
dieldrin
BDL
BDL
BDL
BDL
endrin
BDL
BDL
BDL
BDL
aldrin
BDL
BDL
BDL
BDL
endosulfan 1
ND
ND
ND
ND
endosulfan II
0.320
0.344
0.333
0.332
0.012
4
BDL - Below Detection Limit
ND - Not Detected
APPENDIX V Table 9. Summary of Duplicate and Triplicate Results for
Total PCBs, DDXs, and Chlordanes
Duplicates
CHEM ID
9432
9432dup
AVG
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
347.9
86.8
115.9
366.2
95.6
118.6
357.0
91.2
117.3
CHEM ID
9461
9461dup
AVG
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
284.8
69.5
56.9
269.9
67.4
55.4
277.3
68.4
56.1
CHEM ID
9471
9471dup
AVG
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
69.2
19.1
20.6
72.2
19.1
20.9
70.7
19.1
20.8
AVG
CHEM ID
9543R 9543dup
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
1275.0
275.9
119.4
1245.3
279.5
127.8
1260.1
277.7
123.6
CHEM ID
9544
9544dup
AVG
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
880.8
177.6
211.0
867.6
182.4
219.1
874.2
180.0
215.1
CHEM ID
238
0238dup
AVG
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
47.5
5.2
8.2
46.7
4.7
8.0
47.1
4.9
8.1
CHEM ID
248
0248dup
AVG
36.504
24.349
13.971
34.383
48.198
12.721
35.443
36.273
13.346
257
0257dup
AVG
704.655
201.160
138.800
708.314
206.322
141.967
706.485
203.741
140.383
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
CHEM ID
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
RPD
%
5
10
2
RPD
%
5
3
3
RPD
%
4
0
1
RPD
%
2
1
7
RPD
%
2
3
4
RPD
%
2
11
3
RPD
%
6
66
9
RPD
%
1
3
2
Appendix V Table 9 cont'd.
CHEM ID
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
378
0378dup
AVG
138.588
41.544
35.590
140.936
43.164
35.971
139.762
42.354
35.781
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
RPD
%
2
4
1
Mean RPD
STD DEV
3
11
4
2
21
3
All Units in ng/g wet wt
Triplicates
CHEM ID
9454
9454dup
9454trip
AVG
STD DEV
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
310.1
58.9
39.6
339.2
67.7
44.8
332.8
67.6
45.2
327.4
64.7
43.2
15.3
5.1
3.1
CHEM ID
272
0272dup
0272trip
AVG
STD DEV
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
18.5
5.0
1.3
18.3
5.0
1.6
19.1
4.1
1.1
18.6
4.7
1.3
0.4
0.5
0.3
CHEM ID
281
0281dup
0281trip
AVG
STD DEV
192.2
96.3
13.6
184.9
90.4
13.8
162.3
76.9
12.0
179.8
87.9
13.1
15.6
10.0
1.0
RSD
%
9
11
8
STD DEV
Mean RSD
3
2
7
5
10
11
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
TOTAL PCBs (ng/g)
TOTAL DDXs (ng/g)
TOTAL CHLORDANES (ng/g)
All Units in ng/g wet wt
RSD
%
5
8
7
RSD
%
2
12
19
APPENDIX V Table 10. Spike Recoveries for PCB Congeners.
Congeners
SPIKE A
ng
SPIKE B
ng
SPIKE C
ng
Average
ng
Std. Dev
Mullins Mixture "610"
ng
% Recovery
1
3
4+10
7
6
8+5
19
12+13
18
17
24+27
16+32
29
26
25
31+28
53+33+21
22
45
46
52
49
47
48
44
37+42
41+71
40
100
63
74
70+76
66+95
91
56+60
101
99
83
97
87+81
85
136
77+110
82
151
135+144
107
149
118
131
146
153+132+105
141
137+176
22.18
16.02
1.32
1.22
2.36
26.63
0.58
0.51
7.05
4.26
0.34
7.07
0.01
1.35
0.42
24.06
9.71
6.70
1.51
0.77
6.68
5.44
3.03
2.27
9.25
5.56
11.90
1.96
0.34
0.50
4.81
13.46
16.98
0.88
11.80
2.90
1.50
0.23
1.26
0.96
1.36
0.83
4.57
0.82
3.45
1.32
0.23
6.60
2.20
0.04
0.98
13.27
3.05
0.84
23.49
17.56
1.43
1.31
2.50
28.52
0.59
0.54
7.50
4.51
0.38
7.55
0.01
1.43
0.43
25.95
10.29
7.01
1.61
0.81
7.08
5.75
3.34
2.52
9.83
5.89
12.65
2.08
0.33
0.52
5.17
14.46
18.03
0.94
12.69
3.13
1.66
0.26
1.37
1.01
1.44
0.87
4.93
0.87
3.72
1.43
0.23
6.81
2.14
0.04
0.98
13.69
3.11
0.88
24.73
16.60
1.40
1.29
2.53
28.65
0.59
0.53
7.55
4.46
0.35
7.53
0.01
1.44
0.43
25.71
10.28
7.11
1.59
0.80
7.02
5.70
3.37
2.38
9.79
5.85
12.56
2.05
0.37
0.51
5.15
14.36
18.22
0.92
12.62
3.11
1.60
0.26
1.39
1.03
1.54
0.91
4.95
0.85
3.66
1.40
0.22
6.83
2.43
0.05
1.04
14.01
3.23
0.91
23.47
16.73
1.38
1.27
2.46
27.93
0.59
0.53
7.37
4.41
0.36
7.38
0.01
1.41
0.43
25.24
10.09
6.94
1.57
0.80
6.93
5.63
3.25
2.39
9.62
5.77
12.37
2.03
0.35
0.51
5.04
14.09
17.74
0.91
12.37
3.04
1.59
0.25
1.34
1.00
1.45
0.87
4.82
0.84
3.61
1.38
0.23
6.75
2.26
0.04
1.00
13.66
3.13
0.88
1.28
0.78
0.05
0.04
0.09
1.13
0.00
0.02
0.27
0.13
0.02
0.27
0.00
0.05
0.01
1.03
0.33
0.21
0.05
0.02
0.21
0.16
0.19
0.13
0.33
0.18
0.41
0.06
0.02
0.01
0.20
0.55
0.67
0.03
0.50
0.13
0.08
0.02
0.07
0.03
0.09
0.04
0.21
0.03
0.14
0.05
0.00
0.13
0.15
0.00
0.03
0.37
0.09
0.03
43
26
2.8
2.2
4.2
50
1
0.92
13
7.4
0.87
13.1
0.18
2.3
1
38
16.7
11
2.7
1.4
12
9
5
4
15
8.8
9.4
3.3
0.5
0.74
8.1
21
27.2
1.4
18
4.8
2.3
0.36
1.9
3.32
2.1
1.4
7.1
1.3
5.7
2.2
0.33
11
3.5
0.091
1.6
21.6
5.2
1.388
55
64
49
58
59
56
59
57
57
60
41
56
7
61
43
66
60
63
58
57
58
63
65
60
64
66
132
61
70
69
62
67
65
65
69
63
69
69
70
30
69
62
68
65
63
63
69
61
64
48
63
63
60
63
163+138
158
129+178
187+182
183
128
185
174
177
202+171
157+200
172+197
180
193
191
199
170+190
201
203+196
189
208+195
207
194
205
206
209
6.41
0.34
2.11
10.85
4.63
0.26
1.35
6.80
3.52
2.39
1.32
4.39
21.40
3.78
0.31
0.45
7.88
9.44
10.75
0.22
4.89
0.28
4.46
0.23
2.77
0.02
6.74
0.35
2.16
11.38
4.86
0.29
1.43
7.17
3.69
2.51
1.45
4.60
22.83
4.09
0.32
0.48
8.36
9.97
11.42
0.24
5.23
0.30
4.80
0.25
2.94
0.02
6.84
0.35
2.12
11.53
4.90
0.31
1.45
7.28
3.74
2.56
1.37
4.50
23.05
4.18
0.41
0.48
8.48
10.11
11.61
0.28
5.31
0.30
4.82
0.26
2.98
0.02
6.66
0.35
2.13
11.25
4.80
0.29
1.41
7.09
3.65
2.48
1.38
4.50
22.43
4.02
0.35
0.47
8.24
9.84
11.26
0.25
5.15
0.29
4.69
0.25
2.90
0.02
0.22
0.01
0.02
0.36
0.14
0.03
0.05
0.25
0.11
0.08
0.07
0.11
0.90
0.21
0.05
0.02
0.31
0.36
0.45
0.03
0.22
0.01
0.20
0.01
0.11
0.00
9.8
1.2
3.7
15
7.7
0.47
2.2
11
5.7
3.69
2.067
2.14
24
2.4
0.45
1
12.1
15
17
0.48
8.0776
0.48
6.9
0.4
4.2
0.095
68
29
58
75
62
61
64
64
64
67
67
210
93
167
77
47
68
66
66
51
64
60
68
62
69
18
Average Recovery
65