Design environmental surveys Assignment 1 Analysis of survey methods Student name Click here to enter text. Assessor Adam Samuelson Assessment ID DES-1 Due Date End of Semester 1 Total Marks Available 111 Marks Gained Teacher to mark Final score (%) Teacher to mark Date Marked Teacher to mark Weighting This assignment will form 15% of your overall assessment mark Design environmental surveys Assignment 1 Purpose This assignment relates the field and laboratory activities you perform to real world standards associated with water quality monitoring for environmental compliance purposes. Under State legislation (POEO Act and EP&A Act in NSW) certain industrial activities are described as ‘scheduled premises or activities’ and as such frequently require environmental monitoring of waters to ensure compliance with the law. This work involves using standard procedures (such as the Australian Standards) to develop sampling, analysis and water quality monitoring surveys and plans. Laboratories and consultancies hire people such as graduates from our courses to perform these duties and as such, you need to have a comprehensive understanding of what is required from you when performing these tasks. The purpose of this assignment is to determine the correct procedures for working with a water quality monitoring framework and highlight the differences between the correct procedures and what we do at TAFE (which has many restrictions which hinder the correct implementation of these procedures). Assignment You will acquire the following documents; AS/NZS 5667.1:1998 Water Quality – Sampling. Part 1: Guidance on the design of sampling programs, sampling techniques and the preservation and handling of samples. You will read and summarise the standard and answer the questions on the following pages that relate to the standard and the field sampling that you perform (either at Toronto or on campus in Throsby/Styx Creeks). All of this will be performed in this document (written or typed). MSDS for five common field chemicals which are available for download from the DES study materials page. Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 1 Design environmental surveys Assignment 1 Safety precautions 1. Using Safety Data Sheet as a source of information, complete the following table for the following five chemicals that you take in the field, highlighting the threat that the chemical poses to you and the environment. (5 mk) Personal hazard Environmental hazard Risk Control Hydrazine sulfate Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. pH 10 Buffer Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Phosphate reagent Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Sodium sulfite Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Redox calibration solution Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Chemical Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 2 Design environmental surveys Assignment 1 2. If a site were to be deemed ‘unsafe’, what could be done to ensure sampling would continue? (2 mk) Click here to enter text. 3. What specific WHS training should field technicians have? Explain how you protect yourself from natural hazards such as exposure and wildlife? (2 mk) Click here to enter text. 4. How important is direct communication between field staff and their supervisors? By what techniques can this communication be achieved? What are the potential consequences of poor (or no) communication? (2 mk) Click here to enter text. Factors affecting sampling 5. Considering the variability of natural aquatic systems (such as creeks and lakes), describe, using your knowledge of representative sampling, why it is so important to ensure that sampling occurs at the exact location each time? (4 mk) Click here to enter text. 6. After reading Clause 4.1.1, describe how sampling locations should be identified in the field. (2 mk) Click here to enter text. 7. Of all the tests you perform, which analytes/tests are the most likely to change as a direct result of environmental changes such as diurnal or seasonal? (2 mk) Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 3 Design environmental surveys Assignment 1 Click here to enter text. 8. From Clause 4.2.2 & 4.2.4, list the key factors to consider when sampling from lakes and streams. (4 mk) Click here to enter text. 9. What are the general requirements for sampling microbiological analytes? (1 mk) Click here to enter text. 10. Describe the general method for correctly obtaining a sample using a sterile microbiological container? (2 mk) Click here to enter text. 11. Explain which key sample characteristics could change when using composite sampling methods. Would time weighted samples be different to flow weighted samples? (6 mk) Click here to enter text. Quality control samples 12. After reading sections 1, 5 & 8, describe the difference between, and the purpose of the following four terms in from a quality assurance and control perspective; (4 mk) a. Control Click here to enter text. b. Blank Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 4 Design environmental surveys Assignment 1 Click here to enter text. c. Duplicate Click here to enter text. d. Replicate Click here to enter text. 13. From Section 5.1, what is the difference between a control sample and a control site? What purpose does each serve in the quality assurance of a water quality monitoring program? (4 mk) Click here to enter text. 14. At what stages of the sampling event can sample contamination occur? (3 mk) Click here to enter text. 15. List and describe the blanks which are used to determine the point at which contamination occurs? (4 mk) Click here to enter text. Sample containers 16. List the predominant criteria used for selecting sampling container material. (4 mk) Click here to enter text. 17. List four other factors needed when considering container materials. (4 mk) Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 5 Design environmental surveys Assignment 1 Click here to enter text. 18. After reading Clauses 7.2.1-5, list the main types of sample container materials used in sample collection. (7 mk) Click here to enter text. 19. Under specific circumstances it may be necessary to wash (or otherwise prepare) sample containers for use before sampling. Read Section 7.3 and list some of the general techniques available for preparing sample containers for use. (3 mk) Click here to enter text. 20. Read Section 9.2.2 and describe the sampling equipment used to collect samples specific depths. (2 mk) Click here to enter text. 21. What techniques should be employed when collecting samples for dissolved gas measurements? (3 mk) Click here to enter text. Sample identification and transport 22. Sample labels should contain enough information that enable the sample to be traced back to the site and time of sample. Based on this knowledge, what is the minimum information that should be on a label? (2 mk) Click here to enter text. 23. List the key points required for correct packaging of samples in sample transport Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 6 Design environmental surveys Assignment 1 containers (such as Esky’s™). (4 mk) Click here to enter text. 24. The ‘record of samples sent’ mentioned in Clause 10.4 refers to Chain of Custody (CoC) procedures. What is the purpose of a chain of custody procedure? (4 mk) Click here to enter text. 25. Obtain a copy of a Chain of Custody document and list the key or most important information it contains. (5 mk) Click here to enter text. Sample preservation 26. Based on the Standard, complete the following table which identifies the sample containers, preservation and storage for the samples you collect at Toronto (or Newcastle). (7 mk) Analyte/Test pH Conductivity Dissolved oxygen Lead Nitrate Phosphorus (sol.) Turbidity Container type Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Preservative Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Holding time Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Do we do it? (Y/N) Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Click here to enter text. Flow measurements Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 7 Design environmental surveys Assignment 1 27. We monitor indicator analytes for the determination of potential pollution events. What does the standard mean when it states that; ”…pollution loads cannot be assessed without flow measurements.”? (4 mk) Click here to enter text. 28. Under what circumstances could the direction of water flow change in surface water bodies? (2 mk) Click here to enter text. 29. How could you describe the direction of water flow? (2 mk) Click here to enter text. 30. How could you measure the velocity of water? (2 mk) Click here to enter text. 31. How could you measure the quantitative flow rate (discharge) of a river? (2 mk) Click here to enter text. 32. If the discharge rate of a creek is 20 L/s, and the concentration of nitrates is 64 mg/L, how much nitrate is entering the receiving body in 24hrs? (2 mk) Click here to enter text. Types of sampling program Appendix A (and Section 2.2 – A-D) of the standard discusses the three most common types of sampling programs that the standard is used for (in relation to compliance monitoring). Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 8 Design environmental surveys Assignment 1 33. Based on your knowledge of the Toronto/Newcastle monitoring programs, which type of sampling program do we run? Explain your answer based on how you sample and what you analyse for. (5 mk) Click here to enter text. Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 9 Design environmental surveys Assignment 1 Comparison Task (compulsory, but worth 0 marks) This task relates the fieldwork we do at Toronto to what the Standard says. The reason this is compulsory is for you to understand that sometimes studying is different to reality, and we cannot fully impose real conditions in the field for a variety of reasons. Your job here is to understand which aspects of the Standard we do comply with and which aspects we don’t. You cannot do this task without experiencing the fieldwork, so the due date for this assignment is at the end of semester. Comparison task: Safety Precautions a) Generally speaking (using the Standard as a comparison) how do the safety requirements in the field compare to those stated in the standards? Click here to enter text. b) Using the information in the fieldwork manual, describe the communication tools we use in the field. If it needs improving, what should be done to improve it? Click here to enter text. c) With reference to Section 3.6 from the Standard, describe the safety of the sites you sample from. Click here to enter text. Comparison task: Factors affecting sampling d) What technique do we use to identify specific sampling points? Describe its accuracy. Click here to enter text. Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 10 Design environmental surveys Assignment 1 e) Group 1 also sample using a Rising Stage Sampler. These sample bottles are designed to sample creek water after significant rain events at different heights. The nozzles of these sample bottles can either face into the flow of the water, or away from the flow of water. Describe the difference each direction would have on the water quality characteristics of the sample collected. Click here to enter text. f) Section 4.1.2 mentions ‘ease of access’. Use the table below to rate the ease of access of the sites in your group (either Toronto or Newcastle). Click here to enter text. Comparison task: Quality control samples g) Based on what we do in the field (Toronto or Newcastle), which quality control samples do we not use? Click here to enter text. h) How does this affect the quality of the program? In your answer explain where contamination could occur and which quality assurance technique we would need to quantify the level of contamination. Click here to enter text. i) For one of your sites, provide a correct procedure (according to the Standard) as to how a quality program should be implemented. Click here to enter text. Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 11 Design environmental surveys Assignment 1 Comparison task: Sample containers j) Do we use sample containers for testing dissolved gases? Which technique is better? Why is this technique better? Click here to enter text. Comparison task: Sample identification and transport k) Complete the commercial CoC document your teacher has given you for your group. Using a highlighter pen, identify the information that we do not provide. Click here to enter text. Comparison task: Flow measurement l) How do we perform flow measurements? Click here to enter text. Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 12 Design environmental surveys Assignment 1 Where to get help Contact your teacher if you run into any trouble this unit. You would be surprised how flexible we are at accommodating your needs, but communication is the key. If you don’t let us know you are having trouble, we may have trouble trying to help you. References AS-5667.1 1998 SMWW Your teacher ALS Chain of Custody form CFFET Fieldwork A manual (Surface waters) Submission Students are to submit all assessments by the due date to the subject teacher by email using the following filename format; firstname-surname-assessmentname-duedate Visit cffet.net/env/assessment for more information on submitting assessments, file names and available file extensions that you can use. Other resources Note that some of these resources might be available from your teacher or library Just the references – do not use general internet searches for this as the questions are very specific to the Australian Standard. Chemical, Forensic, Food & Environmental Technology [cffet.net] Version 1.0 30/05/2016 Page | 13