Journal of Quantitative Spectroscopy & Radiative Transfer 146 (2014) 540–548 Contents lists available at ScienceDirect Journal of Quantitative Spectroscopy & Radiative Transfer journal homepage: www.elsevier.com/locate/jqsrt Considering polarization in MODIS-based cloud property retrievals by using a vector radiative transfer code Bingqi Yi a,n, Xin Huang a, Ping Yang a, Bryan A. Baum b, George W. Kattawar c a b c Department of Atmospheric Sciences, Texas A&M University, College Station, TX 77843, USA Space Science and Engineering Center, University of Wisconsin–Madison, Madison, WI 53706, USA Department of Physics & Astronomy, Texas A&M University, College Station, TX 77843, USA a r t i c l e in f o abstract Article history: Received 6 November 2013 Received in revised form 13 May 2014 Accepted 15 May 2014 Available online 24 May 2014 In this study, a full-vector, adding–doubling radiative transfer model is used to investigate the influence of the polarization state on cloud property retrievals from Moderate Resolution Imaging Spectroradiometer (MODIS) satellite observations. Two sets of lookup tables (LUTs) are developed for the retrieval purposes, both of which provide water cloud and ice cloud reflectivity functions at two wavelengths in various sun-satellite viewing geometries. However, only one of the LUTs considers polarization. The MODIS reflectivity observations at 0.65 μm (band 1) and 2.13 μm (band 7) are used to infer the cloud optical thickness and particle effective diameter, respectively. Results indicate that the retrievals for both water cloud and ice cloud show considerable sensitivity to polarization. The retrieved water and ice cloud effective diameter and optical thickness differences can vary by as much as 7 15% due to polarization state considerations. In particular, the polarization state has more influence on completely smooth ice particles than on severely roughened ice particles. & 2014 Elsevier Ltd. All rights reserved. Keywords: Polarization Cloud property retrieval MODIS Satellite observation Vector radiative transfer model 1. Introduction Clouds are widely recognized as among the largest contributors to the global radiation balance [1,2]. A better understanding of global cloud optical and microphysical properties is critical to an improved assessment of their radiative impacts. Satellites provide global coverage for cloud radiance measurements, from which cloud properties (i.e., the cloud optical thickness and effective particle size) can be inferred using appropriate radiative transfer models and knowledge of the atmospheric base state. The satellite-retrieved cloud products are used increasingly, for example, in weather prediction, aviation safety, solar energy prediction, and climate analyses. As a result, n Corresponding author. E-mail address: bingqi.yi@tamu.edu (B. Yi). http://dx.doi.org/10.1016/j.jqsrt.2014.05.020 0022-4073/& 2014 Elsevier Ltd. All rights reserved. improving the retrieval techniques for better cloud product quality is becoming more important. While many advances have been made in the methods for using the radiance and reflectivity observations to solve the inverse problem necessary for retrievals, most do not consider the influence of polarization on the retrieval. The polarization influence includes the cloud polarization characteristics, the atmospheric molecular polarization (i.e., Rayleigh scattering), and ocean/land surface polarization. These influences can potentially affect the constructed lookup tables (LUTs) that are employed for operational retrievals and impact the cloud property retrievals in subtle ways. For example, one of the most widely used approaches to retrieve cloud properties is the Nakajima–King method [3], which uses reflectivities in several solar spectral bands to infer optical thickness and particle effective size, which in turn are used to estimate ice/liquid water path. Typically, LUTs constructed using B. Yi et al. / Journal of Quantitative Spectroscopy & Radiative Transfer 146 (2014) 540–548 reflectivities at different bands in various sun-satellite viewing geometries are pre-calculated by “scalar” radiative transfer models (i.e., DISORT [4] and Fast RTM [5]). Such “scalar” models only consider the first component of the water/ice cloud scattering phase matrix (the scattering phase function), and ignore the influence of other phase matrix elements (i.e., the linear and circular polarization). Furthermore, these models fail to consider the atmospheric molecular polarization and surface polarization (e.g., over ocean). Radiative transfer models exist in which polarization is considered [6–8], and have been applied in cloud retrieval processes involving polarized reflectivities [9,10]. Ideally, conventional cloud retrievals without polarized information should consider the influence of polarization too. To our knowledge, there has been little research to fully consider and quantify the neglected influence of polarization. This study is intended to address the question as to what extent polarization affects cloud retrievals. Another open question is whether or not the influence of polarization is sensitive to the ice particle habits assumed in building the lookup tables used in the satellite retrievals. In the remainder of this paper, the model, data and methodology used in this study are described in Section 2, major results are presented in Section 3, and the present work is summarized in Section 4. 2. Radiative transfer model, data, and methodology To consider the effects of polarization, we employ a newly developed, full vector adding–doubling radiative transfer code developed at the Texas A&M University (Huang et al. [11]). The “vector” version of the code can fully consider cloud polarization, Rayleigh scattering polarization by atmospheric particles, and the ocean/land surface polarization, while the “scalar” version uses only the first component of the cloud phase matrix (i.e., the scattering phase function). In this study, the differences in the LUTs and retrieved cloud properties caused by 541 whether or not the polarization state is taken into account are defined as the polarization effects. The “vector” and “scalar” versions of the adding–doubling code are used to simulate the reflectivities at the 0.65 μm and 2.13 μm wavelengths at the top of the atmosphere (TOA) for a range of sun-satellite geometries over ocean. The solar zenith and viewing zenith angles range from 01 to 841 in intervals of 61, and the azimuthal angles range from 01 to 1801 in steps of 121. The US 1976 standard atmosphere profile is used to provide the atmospheric base state. Single layer clouds with geometrical thickness of 1 km are assumed in a given vertical column, with a water cloud layer located at a height of 3.5 km or an ice cloud layer at 7.5 km. The Rayleigh scattering extinction and molecular absorption optical thickness above and below the cloud layer are calculated with the line-by-line radiative transfer model (LBLRTM) [12]. The ocean surface bidirectional reflectivity diffusion property is modeled using a full 4 4 Mueller matrix assuming a Cox–Munk roughened ocean surface [13] with the Kirchhoff approximation [14]. The ocean's surface wind is assumed to be 7 m s 1 in the Cox–Munk rough ocean surface model. The simulations of TOA reflectivity for the LUTs additionally need cloud single-scattering properties. For water clouds, the single-scattering properties are calculated using the Lorenz–Mie theory assuming spherical water particles. For ice clouds, the single-scattering properties of two particle habits (solid columns and aggregates of solid columns [15]), together with two kinds of ice particle surface roughness conditions (completely smooth and severely roughened [16]) are selected as the ice cloud particle models. The extinction efficiency, single-scattering albedo, asymmetry factor, absorption efficiency, and the complete scattering phase matrix of water clouds and ice clouds are integrated over the modified Gamma size distribution [17]: nðDÞ ¼ n0 Dð1 3bÞ=b e ½D=ðabÞ ; ð1Þ where n0 is a constant, a is the effective diameter, and b is the mean effective variance, here, equal to 0.1. Thus, following the Fig. 1. The scattering phase matrix of a water cloud with an effective diameter of 32 μm at a wavelength of 0.65 μm: (a) P11; (b) P12. 542 B. Yi et al. / Journal of Quantitative Spectroscopy & Radiative Transfer 146 (2014) 540–548 Fig. 2. The scattering phase matrix of an ice cloud with an effective diameter of 40 μm at a wavelength of 0.65 μm: (a) P11; (b) P12. An ice cloud model consisting of completely smooth solid columns is used. formulae given in Baum et al. [18] and Yi et al. [19], we can derive the bulk scattering properties for water/ice clouds at the 0.65 μm and 2.13 μm wavelength bands. Note that the full phase matrix will be used in the simulations using the “vector” version of the adding–doubling code, while the polarization is not included in the “scalar” version. For example, Figs. 1 and 2 show the P11 and P12 elements of the scattering phase matrix of the water and ice clouds, both at a wavelength of 0.65 μm, and with effective diameters of 32 μm and 40 μm, respectively. The ice particles in Fig. 2 are assumed to be individual solid columns (i.e., not aggregates of solid columns) with smooth surfaces. Both the water and ice clouds clearly have distinct polarization features. Larger polarization generally occurs at the forward scattering angles, for example, the water clouds have strong polarization (i.e., P12 component) at scattering angles lower than 601. While not shown, an ice cloud composed of severely roughened solid columns has a featureless phase function (i.e., without 221 and 461 halos and a much reduced backward scattering peak) and fewer polarization features. The same result occurs for the completely smooth/severely roughened column aggregate model, with the completely smooth ice column aggregate having stronger polarization features. With the use of the adding–doubling code and the water/ice cloud optical properties, LUTs are developed for a range of sun-satellite viewing geometries, cloud effective diameters, and optical thicknesses. In combination with reflectivities from direct satellite measurements, the LUTs are used to infer cloud properties. In this study, we use the level 1B (L1B) 1-km resolution reflectivity products (“MYD021KM”) from the Moderate Resolution Imaging Spectroradiometer (MODIS) instrument onboard the National Aeronautics and Space Administration (NASA) Aqua satellite. Two separate 5-min MODIS granules are selected for the water cloud and ice cloud cases. Fig. 3 shows the MODIS RGB images for two cases of water cloud Fig. 3. Aqua MODIS true color RGB images of two data granules: (a) 31 March 2013, 19:35 UTC for a water cloud case; (b) 18 October 2013, 08:00 UTC for an ice cloud case. B. Yi et al. / Journal of Quantitative Spectroscopy & Radiative Transfer 146 (2014) 540–548 Fig. 4. LUTs for the retrievals of (a) water cloud and (b) ice cloud properties using the MODIS band 1 (0.65 μm) and band 7 (2.13 μm) observations. (19:35 UTC 31 March 2013) and ice cloud (08:00 UTC 18 October 2013). Almost the entire granule located off the west coast of South America is composed of stratocumulus (water) clouds (Fig. 3a). The other case features widespread ice clouds near the equator over the eastern Indian Ocean (Fig. 3b). Approximately 2030 1354 pixels are within each granule, and, for our retrieval, the pixels are sampled at 3-km horizontal resolution. The geo-location (longitude and latitude) and sun-satellite viewing geometry (solar zenith angle, viewing zenith angle, and relative azimuthal angle) information is provided in the “MYD03” products. In our study, the MODIS Collection 5 operational level 2 product (“MYD06”) of daytime cloud phase is used to ensure that only pixels flagged as water/ice clouds are used; pixels flagged as uncertain are filtered from the analyses. 3. Results Two examples for specific geometries in the LUTs are shown in Fig. 4. For both the water and ice cloud cases, two analyses are conducted: one with polarization considered within the retrieval (hereafter referred to as the “vector case”) and the other without polarization within the retrieval (hereafter referred to as the “scalar case”). 543 Fig. 4a is for a water cloud retrieval at the solar zenith angle of 381, viewing zenith angle of 451, and relative azimuthal angle of 601. For water clouds, the largest differences between the “vector case” and the “scalar case” occur in the medium effective diameters (12–28 μm) over the entire range of optical thicknesses. The “scalar case” LUT tends to retrieve smaller optical thicknesses and effective diameters compared to their “vector case” counterparts. Fig. 4b shows the LUT for ice clouds using a completely smooth, single solid column ice cloud model at the solar zenith angle of 481, viewing zenith angle of 661, and relative azimuthal angle of 1441. The differences in the LUTs due to polarization suggest that there is greater sensitivity in the large effective diameters ( 430 μm), and the vector–scalar differences are more evident in optical thickness than effective diameter. Different from the LUT results for the water cloud, the “vector case” for ice cloud results in a lower optical thickness than the “scalar case” counterpart. The LUTs constructed based on either the severely roughened solid column ice particle model or on the completely smooth/severely roughened column aggregates (figures not shown) are found to show minimal differences between the “vector” and the “scalar” cases. The results indicate that the particle surface roughening and habit complexity contributes to a decreased polarization impact on cloud property retrievals. Note that the LUT differences between the “scalar” and “vector” cases are highly dependent on the sun-satellite viewing geometries. The results found in these two examples are illustrative but may not hold true for all cases. As a result, it is more useful to quantify the vector–scalar differences in terms of retrieved quantities. Before we begin the discussion regarding the retrieval of cloud properties using the satellite observations, synthetic radiative transfer calculations are carried out to examine the accuracy of retrievals and the sensitivity of “scalar–vector” retrieval difference to various quantities (i. e., viewing geometries, cloud optical thickness, and effective particle diameter). The synthetic radiative transfer calculations provide the cloud reflectivities at the TOA at the two wavelengths with known cloud optical thickness and effective particle diameter, and then use the LUTs to infer the cloud properties. Due to the complexities in the LUTs at small cloud optical thickness and effective diameter, as well as the interpolation schemes used in the retrieval process, retrieved cloud properties are expected to have relatively better accuracy only in certain ranges. For instance, we find reasonably accurate ice cloud property retrievals can be derived when the ice cloud optical thickness is larger than 8, the effective diameter is larger than 20 μm, and the solar and viewing zenith angles are less than 661. As an example, we quantify the relative differences in the retrieved cloud optical thickness (Fig. 5) and effective diameter (Fig. 6) in the “vector” and “scalar” cases as functions of sun-satellite viewing geometries, optical thickness, and effective diameter, assuming a completely smooth solid column ice cloud particle model. The relative difference is defined as Rrelative dif f erence ¼ V scalar V vector 100%; V vector ð2Þ 544 B. Yi et al. / Journal of Quantitative Spectroscopy & Radiative Transfer 146 (2014) 540–548 Fig. 5. The relative difference in the retrieved ice cloud optical thickness between the “vector” and “scalar” cases as a function of (a) solar zenith angle; (b) relative azimuthal angle; (c) optical thickness; (d) effective diameter. An ice cloud model consisting of completely smooth solid columns is used. where Vscalar and Vvector refer to the variables to be compared in the “scalar” and “vector” cases, respectively. Figs. 5 and 6 show some hints about when and where the “scalar” retrieval best matches the “vector” counterpart. Smaller relative differences are found when the solar zenith angle is small, while the relative differences are more diverse with the relative azimuthal angle. The relative differences are high when the cloud optical thickness (effective diameter) is small, and decrease with the increase of optical thickness (effective diameter). Comparing Figs. 5 and 6, we find that polarization has more influence on cloud optical thickness than effective diameter retrievals. Fig. 7 shows the retrieved water cloud optical thickness and effective diameter, as well as the relative differences between the “vector” and “scalar” cases in the satellite scene. The results show reasonable correspondence with the satellite true color RGB image (Fig. 3a) where stratocumulus clouds are found in the majority of the granule pixels. Notice that the sun glint region is neglected to avoid potential problems in the retrievals. The water cloud case has optical thicknesses ranging from 5 to 40, and has effective diameters that are generally larger than 32 μm. However, both the optical thickness and effective diameter retrievals could have a relative difference of up to 715%. Positive and negative relative differences appear alternatively in the scene partially because of scattered patches of small-scale cumulus clouds. Interestingly, the patterns of the relative difference share close similarities between the optical thickness and the effective diameter, and are clearly related to the sun-satellite viewing geometries. The retrieved ice cloud optical thickness and effective diameter inferred using the completely smooth solid column ice particle model are shown in Fig. 8. Again, the sun glint region is filtered out, i.e., where specular reflection occurs when the solar zenith and viewing zenith angles are similar. Additionally, pixels are filtered out where extremely large optical thickness or effective diameter values occur near the boundary of the valid range of our LUTs; extremely high values occur infrequently but any retrieval that occurs near the boundary of the LUT is suspect. For the bulk of the retrievals, relative differences up to or even greater than 15% are found. The relative difference distributions indicate that pixels having small values of optical thickness and effective diameter are overestimated in the “scalar” case, while larger values are underestimated. The relative difference patterns show a smoother transition in the ice cloud case than in the water cloud case and display a clear indication of the dependence of relative differences on the sun-satellite viewing geometries. To relate the “vector–scalar” retrieval differences to the phase functions (Figs. 1 and 2), we show the corresponding scattering angles of the MODIS granules for the water cloud and ice cloud cases in Fig. 9, where scattering angles are calculated as ϑ ¼ cos 1 ðsinθsinθ0 cosΔϕ cosθcosθ0 Þ; ð3Þ B. Yi et al. / Journal of Quantitative Spectroscopy & Radiative Transfer 146 (2014) 540–548 545 Fig. 6. The relative difference in the retrieved ice cloud effective diameter between the “vector” and “scalar” cases as a function of (a) solar zenith angle; (b) relative azimuthal angle; (c) optical thickness; (d) effective diameter. An ice cloud model consisting of completely smooth solid columns is used. Δϕ ¼ 1801 jϕ0 ϕj; ð4Þ where ϑ is the scattering angle, θ and θ0 are the solar zenith and satellite viewing zenith angles, Δϕ is the relative azimuthal angle, ϕ and ϕ0 are the solar azimuthal and satellite azimuthal angles. Fig. 10 shows histograms of the relative differences in water and ice cloud optical thickness and effective diameter. Interestingly, the majority of the retrievals are not affected significantly by the polarization state for either water clouds or ice clouds (i.e., within 75% difference); however, large polarization influences are evident under some conditions. It would be premature to provide generalizations about where the polarization influences will be most evident considering the limited analysis in this study. We also examine the retrievals derived using the LUTs generated using column aggregates, with completely smooth and severely roughened surfaces, and the severely roughened single solid column ice cloud models. None of the cases show significant differences (less than 5%) in the retrieved ice cloud properties whether or not polarization is considered. Both particle surface roughening and particle aggregation have the similar effect of decreasing the degree of polarization due to an increase in multiple scattering. Based on the above results, we conclude that the conventional scalar radiative transfer model without polarization can capture the majority of cloud features in retrievals; however, under certain circumstances, the influence of polarization is non-negligible. More work need to be done to understand the conditions for which the inclusion of polarization is important. 4. Conclusions In this study, we investigate the importance of considering polarization in the process of satellite remote sensing retrievals of cloud properties, specifically optical thickness and effective diameter. A vector radiative transfer code based on the adding–doubling method is used, which permits the use of the “vector version”, where the polarization state is fully considered, and the “scalar version”, where polarization is neglected. The polarization state includes the contributions from Rayleigh scattering by atmospheric molecules, land/ocean surface, and cloud polarization. The Rayleigh scattering optical thickness is calculated using the LBLRTM with the US 1976 standard atmospheric profile. A Cox–Munk rough ocean surface is assumed using the Kirchhoff approximation. Water clouds are assumed to have spherical water particles with the optical properties calculated by the Lorenz–Mie theory. The ice cloud particle models used are the completely smooth/severely roughened single solid column and the complex aggregate of solid columns. Both water and ice clouds are assumed to be composed of particles that follow modified Gamma size distributions with an effective variance of 0.1. Bulk scattering properties of water clouds and ice clouds at various effective diameters are calculated 546 B. Yi et al. / Journal of Quantitative Spectroscopy & Radiative Transfer 146 (2014) 540–548 Fig. 7. Retrieved water cloud optical thickness (a) and effective diameter (μm) (b) and the relative differences (c, d) between the “vector case” and “scalar case”. Fig. 8. Retrieved ice cloud optical thickness (a) and effective diameter (μm) (b) and the relative differences (c, d) between the “vector case” and “scalar case”. An ice cloud model consisting of completely smooth solid columns is used. for two solar MODIS bands at 0.65 μm and 2.13 μm (bands 1 and 7, respectively). Pre-calculated reflectivities for the two MODIS bands over a range of cloud effective diameters, optical thicknesses, and viewing geometries are used to construct lookup tables. The LUTs are used to infer the cloud properties from the MODIS satellite reflectivity measurements. Synthetic radiative transfer calculations are employed to find the conditions where the polarization has an impact. Case studies are presented for two Aqua MODIS granules B. Yi et al. / Journal of Quantitative Spectroscopy & Radiative Transfer 146 (2014) 540–548 547 Fig. 9. The scattering angles of the MODIS granules for the water cloud (a) and ice cloud (b) cases. Fig. 10. Histograms of the relative difference in the retrieved (a) water cloud optical thickness; (b) water cloud effective diameter; (c) ice cloud optical thickness; (d) ice cloud effective diameter. over ocean with predominant coverage of either water clouds or ice clouds. Our analyses are limited to those pixels identified to be water/ice clouds in the MODIS daytime cloud phase product, and the areas affected by sun glint are ignored. The retrieved cloud properties in the water cloud and ice cloud cases share some similarities, as well as discrepancies. The ice cloud case retrieved much larger optical thicknesses and effective diameters than the water cloud case. However, a similar magnitude of relative differences between the “vector case” and “scalar case” retrievals is apparent. Although the relative differences vary dramatically with the sun-satellite viewing geometries (i.e., different combinations of solar zenith angle, satellite viewing zenith angle, and the relative azimuthal angle), the maximum variation can be as large as 715%. Comparatively, such differences decrease to within 75% for LUTs generated assuming a severely roughened single solid column or when completely smooth/severely roughened complex hexagonal column aggregate ice cloud particle models are used. Results from this study suggest that it might be important to extend this study to global analyses to better gain an understanding of where polarization is important. Such analyses would help to better characterize the uncertainties in global cloud retrievals of optical thickness and particle size, as well as the resulting ice/ liquid water paths. Acknowledgments This study is supported by NASA Grants NNX11AF40G and NNX11AR06G and the associated subcontracts to Texas A&M University through the University of Wisconsin–Madison 548 B. Yi et al. / Journal of Quantitative Spectroscopy & Radiative Transfer 146 (2014) 540–548 (301K630). Bryan Baum and Ping Yang thank Drs. Ramesh Kakar and Hal Maring for their encouragement and support over the years. George Kattawar acknowledges the support of the Office of Naval Research under contracts N00014-09-11054 and N00014-11-1-0154 and also the National Science Foundation Grant OCE-1130906. References [1] Ramanathan V, Cess RD, Harrison EF, Minnis P, Barkstrom BR, Ahmad E, et al. Cloud-radiative forcing and climate – results from the earth radiation budget experiment. Science 1989;243:57–63. [2] Baran AJ. From the single-scattering properties of ice crystals to climate prediction: a way forward. Atmos Res 2012;112:45–69. [3] Nakajima T, King MD. 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