ISOTOPICS The Cleveland Section of the American Chemical Society Volume 87 Issue 8 November 2011 November Meeting Notice On Deck: January 18, 2011 Past Chairs Night Sterle‟s Slovenian Country House Speaker: TBD Wednesday, November 9, 2011 Creekside Restaurant and Bar, Brecksville 4:30 pm 5:30 pm 6:30 pm 7:30 pm Executive Committee Meeting Social Hour with hot appetizers and cash bar Dinner Presentation Making Body Parts -- Tissue Engineering with Emphasis on Bone and Cartilage Cleveland ACS Officers Chair: John Protasiewicz Department of Chemistry Case Western Reserve Univ. Phone: 216-368-5060 protasiewicz@case.edu Chair-Elect: Kat Wollyung PerkinElmer, Inc., Akron 330-686-0056 ACS.NCW.Kat@gmail.com Treasurer: John Moran Department of Science and Mathematics Phone: 216-373-6380 jmoran@ndc.edu Secretary: Alice McFarland mcfarlands1@earthlink.net Cleveland Section Web Site: http://www.csuohio.edu/sciences /dept/cleveland_acs/ William J. Landis, Ph.D., G. Stafford Whitby Chair in Polymer Science Department of Polymer Science at The University of Akron Tissue engineering is a relatively new field of research, approximately 20 years old, having tremendous clinical potential. The concept of tissue engineering is one of the design and creation of living tissues in the laboratory from a combination of cells, polymer scaffolds on which to grow the cells, and possible added growth factors and cytokines to enhance cell development. The engineered complex, or construct, would be implanted directly into a patient to augment, repair or replace damaged or diseased tissue. Fabrication of tissue-engineered bone and cartilage has been ongoing in the Landis Laboratory for many years. A number of examples of models of engineered fingers, ears and other structures of the body will be presented with key methods for molecular and structural analyses to ensure biocompatibility of the constructs. DINNER RESERVATIONS REQUIRED: Dinner Reservations Required: Please RSVP by contacting Kat Wollyung by phone at 330-686-0056 or by email at acs.ncw.kat@gmail.com by November 2nd with your name, total number of guests in your party, phone number, and selection of one of the four entrée options for each attendee. Checks made out to “Cleveland ACS” are greatly appreciated; cash otherwise. This event is limited to 50 attendees. All dinner selections include a garden tossed salad, homemade rolls and fresh vegetable, plus beverage service of soft drinks, ice tea, coffee and assorted dessert pastries. The four entrée selections are: Chicken Marala Saute (Chicken breast, mushrooms and peas sautéed in a traditional Marsala sauce. Served with roasted garlic redskin mashed potatoes.) Penne Sorento (Broiled chicken breast, sweet ball peppers, broccoli, garlic, and basil sautéed with olive oil then tossed with penne pasta and Romano cheese Penne Sorento meatless vegetarian option. Lemon Pepper Flounder (Fresh flounder fillets baked with butter, lemon pepper seasoning and panko bread crumbs. Served with rice pilaf. Page 2 Isotopics November 2011 Directions to Creekside Restaurant & Bar 803 Brecksville Rd, Brecksville, OH 44141 Creekside Restaurant & Bar is located on Rte 21 approximately a quarter mile north of the Rt 82 & Rt 21 intersection in downtown Brecksville. American Chemical Society Cleveland Section Directions from South I-77 north to Route 82 (exit 149) towards Brecksville. Make a right hand turn off of ramp and travel 1.1 miles. Make a left hand turn at Route 21 (2nd traffic light). Get in right hand lane, go .2 miles over bridge, first driveway on right. Speaker Bio Directions from North I-77 south to Route 82 (exit 149A) Towards Brecksville for 1.6 miles. Make a left hand turn at Route 21 (2nd traffic light). Get in right hand lane, go .2 miles over bridge, first driveway on right. Directions from East Via 480 Take 480 west to I 77 south towards Akron for 6.7 miles. Take Route 82 (exit 149A) towards Brecksville for 1.6 miles. Make a left hand turn at Route 21 (2nd traffic light). Get in right hand lane, go .2 miles over bridge, first driveway on right Via Route 82. Take Route 82 west and turn right at Route 21. Get in right hand lane, go .2 miles over bridge, first driveway on right. Directions from West By 480. Take 480 east to I-77 south (exit 20b) towards Akron for 6.7 miles. Take Route 82 (exit 149A) towards Brecksville for 1.6 miles. Make a left hand turn at Route 21 (2nd traffic light) Get in right hand lane, go .2 miles over bridge, first driveway on right. By Route 82 Take Route 82 east and turn left at Route 21 Get in right hand lane, go .2 miles over bridge, first driveway on right. William Landis teaches and conducts research to understand the growth and development of the skeleton and teeth of humans and other vertebrates. He holds a BS degree in Physics from the University of Massachusetts, Amherst, MA, and MS and PhD degrees in biology and biophysics, respectively, from the Massachusetts Institute of Technology, Cambridge, MA. After taking his doctorate, Dr. Landis began a postdoctoral fellowship at the Children‟s Hospital and the Harvard Medical School, Boston, and there was promoted ultimately to the rank of Associate Professor of Anatomy and Cellular Biology. In 1998, he moved to the Northeast Ohio Medical University (formerly the Northeastern Ohio Universities Colleges of Medicine and Pharmacy) in Rootstown, where he was Professor and Chair of the Department of Biochemistry and Molecular Pathology. In May, 2010, he relocated his laboratory to the University of Akron and was named the G. Stafford Whitby Chair in Polymer Science. He is a member of Phi Beta Kappa, Sigma Xi, and Alpha Omega Alpha (national medical honor society); was a Fulbright Scholar for study at the Weizmann Institute, Rehovot, Israel; has won a Kappa Delta Award for outstanding research from the American Academy of Orthopaedic Surgery and a number of other national and international prizes; and is a current editorial board member of four scientific journals. His research into various aspects of bone and cartilage molecular biology, structure and function, tissue engineering of bone and cartilage, and the effects of mechanical forces on mineralized tissues has been supported for many years by funding from the National Institutes of Health, the National Aeronautics and Space Administration, and other federal, state and local agencies. Dr. Landis has published over 135 peer- Page 3 Isotopics November 2011 reviewed papers and book chapters and has edited five books in the broad field of biomineralization. Call for Nomination: The Morley Medal By Mark J. Waner The Cleveland Section annually sponsors a regional award, which consists of the Morley Medal and an honorarium of $2,000. The next presentation of the Morley Medal will take place at the meeting of the Cleveland Section ACS in May 2012. The award is presented at a banquet, at which time the recipient will deliver the Edward W. Morley Lecture for that year. Travel expenses for the medalist and spouse will be provided. The purpose of the award is to recognize significant contributions to chemistry through achievements in research, teaching, engineering, research administration and public service, outstanding service to humanity, or to industrial progress. The area of eligibility includes those parts of the United States and Canada within about 250 miles of Cleveland. The contributions for which the award is given should have been made by the awardee when a resident of this area, or if a major contribution was made elsewhere, the nominee should have continued to make contributions while a resident of this area. Nominations may be made by any member of the American Chemical Society, The Chemical Society or the Chemical Institute of Canada. Nominations for the Morley Medal should include a letter of nomination and curriculum vitae including the candidate's education, professional experience & activities, awards & honors, offices held and specifics on significant contributions. The letter of nomination should highlight these significant contributions. A representative list of references to the candidate's more important contributions, an evaluation of the significance of these achievements, and a listing of the nominee's most significant publications and patents are also appropriate. Added consideration will be given to individuals under the age of 48 with demonstrated accomplishments and for continuing significant American Chemical Society Cleveland Section future accomplishments. Strong seconding letters are suggested. The specific reference for every publication or patent is neither required nor encouraged. Electronic submissions are preferred. Deadline for receipt of nominations is December 9, 2011. Send nomination and supporting material to: Dr. Mark J. Waner Cleveland Section Morley Medal Committee Department of Chemistry John Carroll University University Heights, OH 44118 Ph: 216-397-4791 E-mail: mwaner@jcu.edu Local Election By Alice McFarland This memo is a reminder that the local ACS election will take place in November. You should expect to receive your ballot in the mail early this month. Please take the time to vote for your local section officers. Please follow the instructions that will be included with the ballots. Last year many ballots were invalidated because they were not signed or the return address was incorrectly filled in. Because more than one person is running for two of the offices this year, it is important that your vote be counted; don‟t throw away your vote. ACS Fellows By John Protasiewicz It is my pleasure to announce that three members of our section have become 2011 ACS Fellows. All three of these outstanding chemists have served as Chairs of the Cleveland section of the ACS. Furthermore, all three continue to play an active role in the section. In brief, here are some highlights of the careers of these new Fellows. Elizabeth (Betty) Dabrowski. Betty received chemistry degrees from John Carroll University (B.S. '72) and Case Western Reserve University (M.S. '74). She then began teaching high school Page 4 Isotopics November 2011 chemistry, first at Yavne High School, then at St. Ignatius High School. She has, however, spent the majority of her career (since 1979) at Magnificat High School teaching chemistry. Magnificat High School is located in Rocky Rover and is the largest all girl Catholic high school in the state of Ohio. At Magnificat, she moderates an ACS Chartered Chemistry Club that has been actively involved in the Cleveland Section‟s NCW activities. She has also been very active in celebrating Mole Day with her students with both song and jokes, activities that spread across Magnificat High. As this is the International Year of Chemistry, she, the Chemistry club members, and students in Betty‟s classes have been participating in the Science Across the World program which encourages students to exchange data on a topic with students in other countries of the world. In addition to the scientific data that is exchanged the students share information about their home country and local school. Betty has also served Magnificat by being the Science Dept. Chair for 15 years. Her mentoring, leadership, and teaching efforts were recognized by the Cleveland ACS section in 1998 when she received the Irene C. Heller Award for High School Chemistry Teaching. Her career was also featured in Dr. Sylvia Rimm's book, "How Jane Won" that included the stories of 35 successful women and their journeys from "ordinary" to "extraordinary" (see http://www.seejanewin.com/ HowJaneWon.htm). In addition she has also done work with several publishers, including a review and the introduction to an NSTA book on Polymer Chemistry. She has attended workshops in teaching Chemistry sponsored by the Woodrow Wilson Foundation. She also served as a teacher intern in polymer research at the BF Goodrich Laboratory. Betty is currently a Trustee of the Section, chair of the Awards Committee and a member of the National Chemistry Week Committee. Past offices she has held in the Cleveland section of the ACS include: Chair-Elect, Chair, Past Chair, Secretary, co-chair of the High School Affairs American Chemical Society Cleveland Section Committee and co-chair of the National Chemistry Week Committee. She is a member of the National Science Teachers Association, the Cleveland Regional Council of Science Teachers and the Science Education Council of Ohio. Kenneth W. Street. Ken received his B.A. in Chemistry from the University of Connecticut, Storrs in 1970. He received an M.S. in Chemistry from Cleveland State University in 1973, and also a PhD degree in Analytical Chemistry from Wayne State University, Detroit, Michigan in 1977. He also received additional training as a Postdoctoral Fellow at the University of Cincinnati from 1977-1979. Ken‟s career began with academic professorships at Kent State University and Loyola University of Chicago. He later moved on to NASA Lewis (now Glenn) Research Center in Cleveland Ohio in 1989. This transition was begun while Ken held a NASA Summer Fellowship. Ken now has risen through the ranks at NASA from Research Associate to Chief, Chemical Sampling and Analysis Office then on to Materials Research Engineer (AST – Friction & Lubrication), Tribology and Surface Science Branch from 1997 to present time. His current duties include oversight of the optical microspectroscopy laboratory, interfacing with customers to provide micro-Raman and micro-FTIR surface analysis, preparation of proposals to support the laboratory and research relevant to NASA. Ken also serves as acting Branch Chief during periods of extended absence of the permanent Chief. Ken‟s work at NASA has been recognized by several awards and accolades, which include a 2007 NASA Group achievement Award for the NASA Glenn Surface Mobility Team and a 2005 NASA Group achievement Award for the Glenn Shuttle Actuators Investigation Team. In 1995 & 1996 Ken was a LeRC Nominee for NASA “Inventor of the Year Award”. In 2007 he received both a Performance Award for Distinguished Level and Best Paper in the Branch Award. Ken is also part of two key patents for his NASA work. Ken also has over 100 publications (including monographs and conference proceedings) to his credit. Page 5 Isotopics November 2011 Ken serves as an important bridge to the Society for Applied Spectroscopy (SAS), an organization he has been active in since at least 1992. Ken was also vice president of SAS for three different years, and for two other years, President of SAS (1994 and 1997). He currently is on the SAS Executive Board. Ken was a past Chair of the Cleveland Section ACS (2005), and he currently is a Director (20072012) and is Awards Committee Chair. The latter role is a rather large and complicated position for our section, and Ken has had to lead groups of judges to evaluate candidates for several types of awards. Ken was also absolutely critical to the success of the 2009 ACS Central Regional Meeting held in Cleveland. David Ball David received his B.S. in Chemistry in 1983 from , cum laude, Baylor University. David received his Ph.D. in Chemistry in 1987 from Rice University. David started his own career at Cleveland State University in 1990 and is currently Professor of Chemistry since 2002. David‟s research on low-temperature spectroscopy and computational chemistry of new high energy materials has led to over 80 publications in peer-reviewed literature. He has received research funding from various university, state, and national sources (including an NSF grant in 2001 as lead PI on proposal to make CSU an Internet2 institution). His research has reached over 60 students - undergraduate, graduate, and even high school students that have been mentored in his research labs. David has also been awarded numerous departmental-, college-, and university-level awards for quality teaching. Some of these include the College of Science Jearl Walker Outstanding Teaching Award in 2007; Northeast Ohio Council on Higher Education (NOCHE) citation for teaching excellence in October 2003; CSU Distinguished Faculty Award for Teaching in 2002; CSU Chemistry Department Teaching Award, May 2002, and „Thank A Good Teacher‟ Award, CSU Center for Teaching and Learning in January 2000. David has an impressive 18 publications in the American Chemical Society Cleveland Section Journal of Chemical Education; and also has published in other educational-related publications in venues such as Skeptical Inquirer and the World Book Encyclopedia. As a contributing editor of "The Baseline" Column in Spectroscopy magazine, David has written 59 columns that have been published to date on topics ranging from spectroscopy fundamentals to rainbows to the elemental composition of stars. Also impressively, he has 7 books currently in print. David is currently is the Director of the CSU Center for STEMM Education, April 2010 - present. In the context of service to the American Chemical Society, David served as the 1998 and 2009 Chair of the Cleveland ACS Section. David has been on both Organizing Committees of last two Regional Meetings held in Cleveland. David has also served the local section as Expositions Chair in 1998, Program Co-Chair AND Awards Chair in 2009, Treasurer from 1995-1996. David also served as a member of the ACS Committee on Chemistry and Public Affairs from 2000-2009 (reaching statutory limit). He is also currently member of Local Section Activities Committee, associate member of Nomenclature, Terminology and Symbols Committee, and the NCW planning committee for ACS Cleveland, 1998 - present. David‟s ACS activities were recognized by the National ACS when he received the Director‟s Award for ACS Member Involvement in Government Affairs, ACS in August 1998. 2011 ChemLuminary Award By John Protasiewicz NCW group wins the 2011 ChemLuminary Award for Most Creative National Chemistry Week Demonstration. In a hands-on program, over 2500 students and 150 adults were invited to go "behind the scenes" to find out how science and chemistry goes into Page 6 Isotopics November 2011 the "mystery and magic" of a movie set. Volunteers prepared self-contained kits with sufficient materials for students to participate in five individual experiments and two group experiments. See a movie of award presentation at the ACS web site, under 2011 ChemLuminary Awards. Join me in congratulating Bob Fowler, Betty Dabrowski, Don Boos, Kat Wollyung, Kristine A Lahman, Laura Sterk, Lois Kuhns, Marcia Schiele, Margaret Pafford, Mark Waner, Natalie Zarlenga, Shermila Singham, and Vince Opaskar for their hard work. Call for Nominations Irene C. Heller Award Presented to an Outstanding High School Chemistry Teacher by the Cleveland Section of the American Chemical Society The Cleveland Section of the American Chemical Society annually sponsors an award to recognize an outstanding high school chemistry teacher in the Cleveland Section. The award consists of an honorarium of $1,000 and a framed certificate. The award is named for Irene Heller of North Olmsted High School in recognition of her contributions as an outstanding high school chemistry teacher and her service to the Cleveland Section. Nominations for the award are due by close of business Friday, March 2, 2012. The nominations should consist of information on the candidate's education, professional experience and activities, awards and honors, offices held and specifics on significant contributions. The letter of nomination should highlight these significant contributions. Seconding letters are suggested. Nominations should be sponsored by at least one member of the Cleveland Section. A detailed curriculum vita of the candidate may also be included. If you do not know a local section ACS member willing to serve as Champion for your candidate, contact Ken Street at 216-433-5032 and he will provide one for you. The Cleveland Section is geographically confined to the counties of Cuyahoga, Geauga, Lorain, Medina, Huron, and Erie. Electronic nominations using Word or PDF American Chemical Society Cleveland Section will be greatly appreciated. Details regarding where to submit will follow in the January Isotopics. The award will be presented at the April, 2012 meeting of the Cleveland Section. Selected from ACS Discoveries! A scientific “go” for commercial production of vitamin-D enhanced mushrooms Journal of Agricultural and Food Chemistry A new commercial processing technology is suitable for boosting the vitamin D content of mushrooms and has no adverse effects on other nutrients in those tasty delicacies, the first study on the topic has concluded. The technology, which involves exposing mushrooms to the same kind of ultraviolet light that produces suntans, can greatly boost mushrooms‟ vitamin D content. It appears in ACS‟ Journal of Agricultural and Food Chemistry. Ryan Simon and colleagues note that many people do not get enough vitamin D in their diets. Few natural foods are high in the vitamin, and there are limits on what foods can be fortified to boost the vitamin D content. Although few people realize it, mushrooms are an excellent natural source of vitamin D. Some producers have embraced results of earlier studies, suggesting that exposing mushrooms to ultraviolet B (UVB) light can significantly boost the vitamin D content. The scientists set out to answer several questions about commercial-scale UV light processing of mushrooms. Among them: Does it produce consistently high levels of vitamin D and does it adversely affect other nutrients in mushrooms? They compared button mushrooms exposed to UVB light, those exposed to natural sunlight and those kept in the dark. The UVB-exposed mushrooms got a dramatic boost in vitamin D (700 percent more of the vitamin than those mushrooms exposed to no light) and the UVB processing had no effect on levels of vitamin C, folate, riboflavin, niacin and a host of other essential nutrients. Page 7 Isotopics November 2011 American Chemical Society Cleveland Section November Historical Events in Chemistry By Leopold May The Catholic University of America, Washington, DC Nov. 14, 1807 One hundred years and seventy-five years ago in 1836, Auguste Laurent obtained phthalic acid from naphthalene. Four years before this, he discovered anthracene and in 1841, showed that carbolic acid is phenol. Also, he constructed a saccharimeter; evolved the nucleus theory of organic radicals (with Charles F. Gerhardt), and made Laurent's acid. He was born on this date. Nov. 20, 1 886 One hundred and twenty-five years ago on this date, Karl von Frisch was born. He discovered how bees orient and communicate and shared the Nobel Prize in Physiology or Medicine in 1973 with Konrad Lorenz and Nikolaas Tinbergen for their discoveries concerning organization and elicitation of individual and social behaviour patterns. Nov. 29, 1936 Seventy-five years ago on this date, Yuan T. Lee was born. He used a specially designed mass spectrometer that could separate and identify reaction products. In 1986, he shared the Nobel Prize in Chemistry with Dudley R. Herschbach and John C. Polanyi for their contributions concerning the dynamics of chemical elementary processes. ISOTOPICS STAFF Editor: Daniel Tyson Day-Glo Color Corporation Phone: 216-391-7384 daniel_s_tyson@yahoo.com Business and Advertising: Alice McFarland mcfarlands1@earthlink.net Associate Editor Dwight Chasar dwight.chasar@yahoo.com Associate Editor Richard L. Middaugh Phone: 440-785-0293 rlmiddaugh@ameritech.net Associate Editor Meenakshi Hardi Phone: 440-941-6467 minaxie@gmail.com Associate Editor Daniel Scheiman QSC/NASA GRC Phone: 216-433-3223 daniel.a.scheiman@nasa.gov Isotopics is looking to highlight local chemistry professionals, companies, teachers, research groups, students, events, and more. If you have an idea for an Isotopics article, please contact the editor. Isotopics is also looking for local members to join our staff. Time commitments for staff members are minimal (a few hours a year!) and your contributions will be invaluable to our local section. If you are interested in joining Isotopics, please contact the editor.