II. A. MICROWAVE GASEOUS DISCHARGES Prof. S. C. Brown L. Gould J. J. McCarthy Prof. W. P. Allis N. W. Donelan J. W. Lathrop D. H. Looney K. -B. Persson G. J. Schulz CHARACTERISTICS OF MAINTAINING FIELDS IN MICROWAVE GAS DISCHARGES A perturbation solution for the electron energy distribution function has been obtained. It was found that such a solution gave an accurate representation of the exper- imental measurements, provided the electron density present remained below that necessary for plasma resonance to occur. Schumann (1) has shown that when a portion of the plasma is microwave electric field tends to be strongest in this region. in resonance, the Thus when electron den- sities are present in a resonant cavity in excess of the plasma resonance densities, a nonuniform electric field will result. incorporated in the theory. This is an effect which had not previously been Allis, Brown, and Everhart (2) have considered the varia- tion of the electric field in predicting the spatial electron distribution. It is possible, by a method similar to theirs, to take the nonuniformity of the electric field into account. The result is a nonuniform ionization frequency, which can be related to the uniform ionization frequency. In this way, uniform field data are used to predict the nonuniform field data. Experimentally this is a difficult region in which to work. A 1000-watt c-w magne- tron was obtained for use in taking the high density measurements. The measurements in this region seem to agree with the theoretical values within the experimental (10-20 percent) error. B. ELECTRON-ION RECOMBINATION IN HYDROGEN Earlier measurements of the recombination coefficient for hydrogen (3, 4) with microwave methods do not agree and have not yet been theoretically explained. The measurements have been made on a decaying plasma obeying the following equation, in which it is assumed that there are only electrons and one kind of ion in the plasma. an = 2 2 anD aV n - an at a (1) where n = electron density, Da = ambipolar diffusion coefficient, a = recombination coefficient. At higher electron densities (n = 108 - 10 9 electrons/cm 3 )the experimental results have been explained by the relation 1-=- 1 + at n n o -6- (2) (II. MICROWAVE GASEOUS DISCHARGES) which is the solution of Eq. 1 when uniform electron density is assumed. This, however, is a contradictory assumption because if the density is uniform in the bottle or the cavity containing the plasma, the wall effects cannot be neglected, the diffusion term may be dominating, and the time dependence of the decaying plasma has to be a function of the diffusion coefficient, the recombination coefficient, the spatial form of the probing microwave signal, and the initial spatial distribution of electron density. However, the two loss processes, diffusion and recombination, have different pressure and energy dependence; and therefore, with an experimental setup to measure the time dependence of the decaying electrons as a function of pressure and average energy it should be possible to separate the two pro- over ranges that are sufficiently large, cesses and calculate the recombination coefficient. This may be checked with a pertur- bation calculation when the initial conditions are known. The experimental setup for measuring the pressure and energy dependence of the decay function in the afterglow, as shown in Fig. II-1, is practically ready. It consists of a microwave cavity in the 10-cm region in the form of a rectangular parallelepiped. The dimensions of the cavity are designed so that the fundamental modes resonate at 10. 5 cm, 10 cm and 9. 5 cm wavelength. to each other. The E fields of these modes are perpendicular A variable coupling mechanism in the form of a disc on the end of the inner conductor of the coaxial line going into the cavity has been developed. Fig. II-1 Block diagram of experimental apparatus for measuring electron decay as a function of the average electron energy. -7- It is (II. MICROWAVE GASEOUS DISCHARGES) essentially a capacitive coupling which, because of its rotational symmetry, couples only to that fundamental mode whose E field is perpendicular to the disc. Use has been made of this property of the disc coupling to load down one of the modes of the cavity so that QU of that mode may be varied from 10, 000 to 200. A quartz bottle, small in relation to the dimensions of the cavity, contains the gas discharge and is introduced in the center of the cavity. The Q of the mode mentioned above may be made essentially independent of the change in loss because of the changing electron density during the decay period. This mode is used to heat the electrons, and the E field of the mode is measured in the same way as in breakdown measurements. The other two modes are used for the pulsed breakdown signal and the probing signal. The electron density as a function of time is measured in the customary way. In principle, the average energy of the electrons may be calculated from a measurement of the ambipolar diffusion coefficient. This leads to the possibility of relating the average energy of the electrons to the applied heating field and of experimentally determining the decay process as a function of the average energy of the electrons and pressure. C. OSCILLATIONS IN DC DISCHARGES The recent theoretical treatment of plasma oscillations by Bohm and Gross (5) indicates that high-frequency oscillations may be generated in a gas discharge plasma by a high-velocity electron beam. The electron beam supplies energy to the oscillation and is modulated by the plasma oscillation. The presence of the beam should modify the frequency of oscillation in the manner indicated by Eq. 3 2 Wpp 22 n 1+ 2 where (2 - (3) Vb b no 4o 2 = electron plasma frequency = ne /mE ; n = density of electrons in the exciting beam; Vb = accelerating potential of the beam; n o = plasma electron density; and o = potential of the oscillation generated. This formula indicates that the density and accelerating potential of the electron beam are the variables associated with deviations of the observed frequency from the plasma electron frequency. This electron beam can be generated by the use of a mercury discharge as a cathode in the structure shown in Fig. 11-2. Electrons in discharge A move through a hole in the kovar cup C which acts as an anode for discharge A. These electrons are accelerated by the potential Vb and enter the main plasma B. This gun produces a high-density beam for relatively low accelerating potentials when the gas pressure through the tube is of the order of 1 to 5 4 and eliminates any necessity for differential pumping. It should be noted that -8- Fig. II-2 Electron gun section. C and D are kovar assemblies. Diameter of beam is 0. 042 inch. REGION Fig. II-3 Mercury discharge tube for plasma oscillation study. -9- (II. MICROWAVE GASEOUS DISCHARGES) the density of electrons in the beam may be varied in a linear manner by changing the current passed by the gun discharge A, while the accelerating potential Vb may be varied independently of the beam density to a first order. This structure incorporates the proper variables indicated by Eq. 3. The final tube, now being assembled, is shown in Fig. 1I-3. D. BREAKDOWN IN HYDROGEN AT 100 MC/SEC Work on the breakdown of hydrogen at a frequency of 100 Mc/sec has been completed and no further work is being contemplated at this time. The meas- 3000o 2000- urements of breakdown covered a range of pressures from 1 cm to 1 atmosphere 1000700- of hydrogen, obtained from a palladium leak, and up to 2 atmospheres with the 500 - S200 100- addition of tank hydrogen. Figure II-4 shows a plot of the data. The results -THEORY at low pressures, if extended, D 100-Mc DATA 3000-Mc DATA good agreement with those obtained by are in 70 - others (6) at microwave frequencies. At intermediate pressures the results 50- follow the ~enerl 20 0 -xxx nre]irtinns nf the theory up to a p/E of 0. 11, 10 point there is 002 004 006 008 010 0.12 014 016 p/E (mm Hg- 018 020 This cm/volts) has progress at which a departure from theory. in a previous been discussed report (7). No way was found Fig. II-4 to eliminate this effect in the present Breakdown data at 100 Mc/sec. experiment. This might be due to the fact that the large cavity could not be outgassed well enough to remove small traces of 02. Further work on the breakdown of hydrogen at high pressures will be conducted at microwave frequencies, because high purity conditions (due to the smaller size of the cavity) are more easily obtained and a new 1000-watt c-w tunable magnetron (Litton Industries - 5607 magnetron) is -10- now available. MICROWAVE (II. GASEOUS DISCHARGES) References Z. 1. W. O. Schumann: P. Allis, S. Physik 7, 121, 1942 Phys. Rev. 84, C. Brown, E. Everhart: 519, 1951 2. W. 3. M. A. Biondi, S. C. Brown: 4. L. J. 5. D. Bohm, E. P. 6. A. D. 7. Quarterly Progress Report, Research Laboratory of Electronics, 1951, p. 11 Varnerin, Jr.: Phys. Rev. 84, 563, Gross: MacDonald, Phys. Rev. 76, Phys. Rev. S. C. Brown: 75, 1697, 1949 1951 1851 and 1864, Phys. Rev. -11- 76, 1949 1634, 1949 M. I. T. Oct. 15,