I I" I r r r I" I" r I" r r r F F r r r 'ABW MEXICO HYDROCARBON SOURCE ROCK EVALUATION PROJECT K. ANDERSON, INC. AD.1 WISHBONE FEDERAL SEC.l, T4S, U E , SOCORRO COUNTY, NEW MEXICO API NO. 30-053-20010 NORTHWEST AREA G E ~JOB. BO. 3787 JmS Prepared for PROGRAM PARTICIPANTS D r . Geoffrey S. Bayliss and Dr. Rudy R. Schwarzer GEOCHEM LABORATORIES, INC. 1143-C BRITTMOORE ROAD HOUSTON, TEXAS 77043 (713) 467-7011 CONFIDENTIAL MARCH 1989 .. co W L3-1 I 1 I SUMMRRY FIGURE 1 LITHO LOG SRN RNDRES GLORIETR - _JDCRNRS umLRT1 X TOC HI I L -4" 1 604 L++u I 1 I I I I I 1 I I I I I I I I I I I 1 I I 1 1 I I I I I I I I I I I I I I I 1 1 I I I I I I 1 1 I 1 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 1 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 1 I 1 1 1 I I I 1 I I I I I I I 1 1 1 I I I I I I I I I I I 1 I I I I I I I 1 I I I f I I I 1 I I I I I I I I I I / I I I I I I I I I 1 1 I 1 I I I I I I I I 100 I I I I I I I I I I I 0 u I I I I .. MRDERR % I I RBO BURSUM T-MFIX I I I I IESETRBLNC I 1 KEROGEN I 101:3 + I I I I I I I I I I I I I I I I I I 1 1 I 1 TORRES 3 S2/S3 I lk rttrr I 60C I I I I -. I I I I I I I I I I I I I I I I I I I I I I I I I I I _u-LI_sI I I I I I I t I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I . 71 I I I I I I I -. . I I I I I I I I -+" I I I I 1 PI I I I I I I I I I I -... ..... I FREE HC 1 250i I I I E IL I I I I I I I I +"-r 1k 0 10r 0 .7! - - - - FIGURE - - 1- - " " FINDERSON WISHBONE LOB NUMBER 3787 SUMMRRY OF GEOCHEMICRLRNRLYSES C l - C 7 HYDROCRRBONS LITHO LOG 0 100, I I I I I I I "-tI I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 1 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I ~I I I I I I I I I I I I I I I I I I 1 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I AI I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 0 100 I 101 105 APPM C1-C4 HYOROCRRBONS X PPM C2-C4 HYDROCRRBONS PPMVALUESEXPRESSEDAS VOLUME OF GRS PER MILLION VOLUMES OF SED PPMVALUESEXPRESSEDRS VOLUMES OF GRS PER MILLION VOLUMES OF SED LEGEND FOR SUMMARY DIAGFAM DEPTH: LITHO LOG: in feet see lithology symbols STRATIGRAPHY: by age percent total organic carbon % TOC: Rock-Eval, Hydrocarbon Index= 100 S2(0/00 Wt)/TOC : HI Rock-Eval, Oxygen Index= 100 53 ( O / O O Wt)/TOC 01 : Rock-Eval, S 2 peak (ppm) HC YIELD: Rock-Eval, Ratio of S2 to S3 peak m" see Kerogen symbols KEROGEN: T-MAX : Rock-Eval, maximum temperature oE S 2 peak, in degrees CentiErade Vitrinite Reflectance (scale 0 to 5) %ROA ) : 1 to 5) Thermal Alteration Index (Scale TAI Rock-Eval, SI peak (ppm) FREE HC: Rock-Eval, Productivity Index= SI/(SI+S2) PI: - KEROGEN TYPES LITH.OLOGIES E l SILICEOUS SHALE ROCKS I HERB'ICEOUS ] E l woony EVRPORITES MUDSTONE ROCKS AMORPHOUS ml COAL SILTSTONE a INERTINITE IGNEOUSSANDSTONE CONGLOMERATE VOLCRNICS BRECCIR METRMORPHIC ROCKS LIMESTONE BASEMENT DOLOMITE OTHER HRRL MISSING SECTION r COMPUTERIZED GEOCHEMICAL SOURCE I ROCK EVALUATION INTERPRETATIVE CRITERIA r r r r Slmplified Flov Diagram STEP IlDATA 1. sample ID 1. 2. Depth Litholoiy a. % Sandstone (Ss) b. X Siltstone (St) C. X Shale (Sh) d. X Carbonate (Cb) e. X Evaporite (E) f. X Coal (C) g. Z Other (Or) X Hetamorphic (MI h. Geochemical parameters a. Pyrolysisdata 2. 3. 3. I- r F 4. r I' r r F m Volatile hydrocarbon (Sl) Generated hydrocarbon (52: Temperature ( ' C ) of 52 PC, b. Total organic carbon (TOC) C. Kerogen type 1. X hOrphoU6 ( b ) 2. X Herbaceous (H) 3. X Woody (U) 4. X COSlY (C) Therms1 Maturity indicators 1. Thermal alteration index (TAI) 2. Vitrinite reflectance (ZRI d. Y D Formations Table I11 Samoles: Tabie VI Fig. 1 Fig. 2 STEP II/LITHOLOGY M E C K If the samplei s uninterpretsble because it or mctamrphics. a statement is printed to that effect. If a significant portion of the sampleis composed of "other" lithologies. the interpretation is referred to a footnote. If the sampleis composed of 602 or more of either source rocks (shale and/or Carbonate) or nonsource rocks (siltstones and/or sandstones)the sample is interpreted in Step111 below. STEP III/II(TEWRETATIOh' PROCEDURES Interpretations are based on the following parameters: 1. Lithology 2. 'Ihermal maturity using TAI 3. 4. Volatile hydrocarbon (SI) 5. Kerogen type Total organic carbon (TOC) If a particular sample lacks only a TAI value. a TAI value is taken froma three term moving average CUNC (Figure 1). 'Ihe descriptive terminology used relative to the param~tervalues is given belov. Y Ovtput OUtPUt Formation€ Table 1 Table 11 Samples Table I\' Table V D TMLE 1 FOR'UTIOS ISTERPRETATIOS TABLE I1 FORYATIOS SLWURY INTERPRETATION This t a b l e gives a fornution by f o r r m t i o n i n t e r p r e t a t i o n of eachparameter u s e d in T a b l e I. h e d e s c r i p t i v et e r m i n o l o g y used for r o c h p a r a e t c r ir l i r t e d in the i n t r o d u c t i o n . TABLE 111 FORYATIOS S L V A R Y OF C E O M E I I W DATA Y Y ." I" I" r TABLE IV SAWLE IFTERPTCZATIOK I r r I" I r F r r r r Y Y Y (4) VoIatile hydrocarbon (SI) (5) Kerogen cype I f a T A l value is l a c k i n g f o r a n orhewise i n t e r p r e t a b l e s a m p l e . a TAI value is takenfrom a t h r e e term moving a v e r a g e p l o t of a11 t h e IAI d a t a f o r c h i c well (see Figure 1). The kerogen t y p e o i l l g a s f a c t o r e x p r e s s e d as a percentageshouldbe used as a m o d i f i e r t o t h e i n t e r p r e t a t i o n ; i . e . . a h i g h o i l f a c t o r vi11 enhancethe o i l q u a l i t yo ft h es a m p l e vhercar c o r r e s p o n d i n g l y . a high 9.6 f A C t O r w i l l eahance t h e gas r a t i o of t h e a a ~ p l e a n dd i m i n i s h the o i l p r o s p e c t i v e n e s s . TABLE V SATLE SLWY ' IKIERPREIATIOS This t a b l e g i v e s a sample by sample i n t e r p r e t a t i o n o f e a c h p a r a x t c r used ir. T a b l e II'. This d e s c r i p t i v e term.inolog). used f o re a c hp a r a m e t e r i s l i s t e d in che introduction. TABLE VI SA'IPLE SWAARY OF GEOCHCilCAL DATA p p I" ers: ABBREVIATIONS USED IN TABLE ""_ Maturity 1,4 TAT-Thermal AlterationIndex, 96RO Vitrinite Reflectance, Tmax-Rock-Ed gs: Maturity Thermal I - h t u r e, MI-Moderately I" F r 2,5 Immature, SA-Severely Altered.MT-Metamorphosed Kerogen Type: Am-Amorphous/Sapropel, H-Herbaceous , w-wav, mly/P/Inertinite (these abbreviations are byused GBXHBf, the user specifies kerogen tpyes in the LIMITS.DAT filed e r EFR" and enters their ab+x-eviations in 'this file) sample "I=: -' Table 3 , k Table 4,5,6a,b,c CT-Cuttings, C-Core, S-Sidewal Core, oc-cxltcrop Table 6a,b T ShShale. Md-Muitsone, St-Siltstone, Ss-Sandstone Cg-Conglomerate, Br-Breccia,Mr-Maral, Ls-Limestone Do-Dolomite, Si-SiliceousRocks, Ev-Evaporites, Ccoal, Ig-Igneous Rocks,Vo-Volcanics, Mt-Metamorphics Bs-Basement, Ot-Other 7 m 1: Table 2 , 3 The thermal maturity values and ratings presentedin Tables 2 and 3 are based on running averages. NOTE 2: Table A thermal maturity value or rating enclosed by brackets [ J indicates that the value was taken from a running average of the parametershown. " Y Y NOTE 3: -"_ "_ An asterisk ( $ 1 following the sampleID on Table5 indicates a sample whose complete interpretation appears on Table 4. Table 5 4,5,6a r x. I" * * X**r*********ttf*x***~****x*x~**x****x****x*x**x*****x**x*** * * " " " " " " " " " " " " " " " " ~ FBM FILE LIMITS.DAT x X****xt*txX******X*~**x**x**%***x**x******xxx*~*~x****x**xx* r THERMAL MAnnxrY I- - 1.0 1.8 2.2 2.6 3.6 4.2 5.0+ PARAMETERS Vitrinite TAI I" * LIMITS USED FOR IWERPRETATIONS x r x x APPENDIX B. 1.8 2.2 2.6 3.6 4.2 5.0 - 0.00 0.43 0.56 0.81 1.63 2.38 4.50t Thermal Maturity Rating 0.43 0.56 0.81 1.63 2.38 4.50 ' - 0 433 437 441 451 457 471t - 433 437 441 451 457 471 I MI bN M VM SA KC Immature Moderately Immature Moderately Mature Mature V e r y Mature Severly Altered Metamorphosed MATURITY HIERARCHY TAI,STAI,'%FXI,S%Kl,"PXtSM4X TCK: RICHNESS Rating Shale f - 0.00 0.13 0.26 0.51 1.01 2.01 4.01 8.01t s1 0.13 0.26 0.51 0.000 0.201 0.401 0.801 1.601 3.201t - - 0.00 0.13 0.26 0.51 1.01 2.01 4.01 8.01+ 1.01 2.01 4.01 8.01 (mg/gl 0.201 0.401 0.801 1.601 3.201 Carbonate - 0.13 0.26 0.51 1.01 2.01 4.01 8.01 Rating VERY FWR poofl FAIR GOOD VERY G o 3 D EXCELLENT LITHOLO=y LIMITS Y <20.0% (10.0% <10.0% Y >50.0% >50.0% Other Lithology Contamination Coal Ma.jor Lithology(Source or Nonsourcel Major S o m e LithologyforInterpretation Rating * * x x x I r**x*xait*tS$t~i*x*t**x*x::*si*~xx~*~x*i**~*x**i*~**::*:*x:: x x k * A!?PFNDlX B. ""_ f * ""_LIMITS "" * USED FOR wmmrmrms FROM LIMITS.DAT FILE f x x I*t*~*****f*~****x~****~x***~*~******~*~***~***ff*xxx*x***** r TYPES SPECIFIED AND OIL/GAS FAGIYR COEFFICIEWS Oil/Gas Kerogen Kerogen T;ppes Names Coeff. ' F I" F AMORPH m 0 Iiwl m 2 m 3 . HERB WOODY INERT NotDef NotDef NotDef NotDef NotDef NotDef m 4 KER5 IIERG KER7 KEm KER9 0.90 0.60 0.30 "_ 0.10 " " " " " " " "- pyRoLYsLS GAS/OIL PEmE LIMITS Ratio ""_ Hydrogen Index 0.0 150.0 300 .O+ Y Y x * * * " " " " " " " " " " " x Y * - 150.0 300.0 S2-S3 Rating - 3.00 3.00 - 5.00 5 .OO+ 0.00 GAS O/G On, W e l l Namr: AP1 Number: F i l e Name: I.at/Lonn: A n d e r s o n S I Wishbon 30-053-20010 ('lrn,lLv/stele: TABLE I : FORPIATION INTERPRET?\TION 378i NA """"""""""""""""~ Formation I D a t i o an n d l i t h o Litho Thermal Maturity Depth I t't) LocaLiorl: T o t aDl e p t h : Remark: (IO. .SEI Sec. I - 4 S - 3 E 4 Y Y 7 FT N N SOURCE Rli STUDY S,n~l,I.rl, Major """""""""""""""""""""""""""""~"""""""""""""""""""""""""""""". 0 2830 02SH OZCB " " " " " .- - 2830- 4 9 9 7 2830- 4 9 Y i ---------IPenn. 1 ---------- Not S a m p l e d - - - - - -. N n d e r a TAI TA1 SHALE MODERATELY CARB TO MATURE POOR MATURE VERY POOR POOR TO O I L SOURCE - FAIR GAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: O I L TYPE 35% GAS TYPE 65% F A l R IMMATURE O I L A N D ASSOCIATED GAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: O I L TYPE 41% G A S TYPE 59% ....................................................... 7 Well Name: Anderson a API Number: 30-053-20010 File Name: 3787 Lat/Long: NA litho and 1 TABLE 11: FORMATION SUMMARY 1NTERPRETATION """""""~"""""""""""""- Litho lftl 0 2830 County/State: Socorro CO.,NM Looation: Seo.l-4S-3E Total Depth: 4 9 9 7 FT Remark: NM SOURCE RK STUDY Wishbon Richness Tmax XRO Richness TAI Gas Index Index Index Ratio Oil " " " " " Not Sampled ---------- " " " " " Madera IPenn.1 OZSH 2830- 4Y97 SHALE 0ZCB 2 8 3 0 - 49Y7 CARB ---------- M I FAIR VERY POOR 0.56 42 GAS GAS 35 65 MM I GOOD VERY W O R 0.65 106 GAS GAS 41 59 I ! I I u J m Ln 0 01 ti Ir 1 I ! - I I I ! ! I I !I I I ! I I I i I i I I I i I I I I I I I i c r* * .SOT- 0 i c 0 V I 2 3 0 0 1 0 U V I F it' 0 0 C C .I I c .3 ?) 0 N N N ... N m c -0- Q C VI 1 0 4 ! 4J U c1 0 C .rl c 0 E m 000 3" T--Lom O N 0 O N U ... 000 mN- 99Ei m 000 N N -.0.7 000 ~ m c o ... O O N " N O . . . ." N N N ... 0 W ti LI 3 0 VI I I ! I hell Name: Anderson d l Wishbon API Number: 30-053-20010 File Name: 3787 Lat/Lone: NA Sample 1D and type Depth lftl TABLE IV: SAMPLE INTERPRETATlON " " " " " " " " " " " " " " " ~ Thermal Maturity Ma.ior Litho Socorro CO..NM Sec.l-4S-3E 4997 FT NM SOURCE RK STUDY Countp/State: Location: Total Depth: Remark: Interpretation "_ .................................................. 3787-001 CT 3787-002 CT 0 " " " " " 2830 " " " " " Not Sampled ---------MaderaIPenn.1 ---------- 30003050 TAI CARB MODERATELY MATURE POOR IMMATURE OIL AND ASSOCIATED GAS SOURCE KEROGEN TYPE OILlGAS FACTOR: OIL TYPE 44% GAS TYPE 56% 32503300 TAI SHALE MODERATELY MATURE POOR SOURCE FOR OIL/ASSOCIATED GAS OR BIOGENIC GAS KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 31% GAS TYPE 69% 3187-003 CT 33503400 TAI SHALE MODERATELY MATURE POOR SOURCE 3787-004 CT 35003550 TAI CARB MODERATELY MATURE POOR IMMATURE OIL AND ASSOCIATED GAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 38% GAS TYPE 62% 3787-005 CT FOR OIL/ASSOCIATED GAS OR BIOGENIC GAS KEROGEN TYPE OILlGAS FACTOR: OIL TYPE 31% GAS TYPE 69% 38003850 TAI CAR8 MODERATELY MATURE POOR TO FAIR IMMATURE OIL AND ASSOCIATED GAS SOURCE tiEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 3787-006 CT 38583900 TAI CARB MODERATELY MATURE POOR ~ 4000- 4050 3787-007 CT 3787-008 CT 3787-009 4050- 4100 CT 3787-012 4100- 4150 41504200 3787-010 CT 3787-011 __ _ _.. CT CT 42004250 4250- 4 3 0 0 __ -TAI TAI - TAI TAI GAS TYPE 65% OIL AND TO FAIR IMMATURE ASSOCIATED GAS SOURCE- FAIR BIOGENIC GAS SOURCE . _ . ~ R O O R N _ T V P P I L / G A S _ E B C T O R L O ~ T Y P E -36% G A S lPYEE~..64X SHALE MODERATELY MATURE POOR SOURCE FOR OIL/ASSOCIATED GAS OR BIOGENIC GAS KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 36% GAS TYPE 64% SHALE MATURE VERY POOR TO POOROILSOURCE - FAlRGAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 34% GAS TYPE VERY POOR OILSOURCE - POORTOFAIRGAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 37% TAISHALEMATURE TAI 35% 66% GAS TYPE 63% CARB MATURE POOR OIL AND ASSOCIATED GAS SOURCE KEROGEN TYPE OILlGAS FACTOR: OIL TYPE 39% GAS TYPE 61% POOR OIL AND ASSOCIATED GAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE GAS TYPE 60% SOURCE 42% GAS TYPE 58% CAR9 MATURE CARB MATURE POOR OIL AND ASSOCIATED GAS . KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 40% . - _" Well Name: API Number:. File Name: LatlLong: Anderson %1Wishbon 30-053-20010 """_""" 3787 NA Sample ID and Thermal Maturity ~""____""""""""""""""""""""""""""""~ 4997 ""___""""""""~"""""""""""" TABLE IV: SAMPLE INTERPRETATION Major t t t + + t t t i tTotal Depth ttttttttit S o c o r r o CO.,NM County/StaLe: Location: Sec.l-4S-3E Total Depth: 4997 FT Remark: NM SOURCE RK STUDY Anderson Well Name: API Number: File Nam'e: Lat/Lonrr: f l Wishbon 30-053-20010 3187 CountvlStete: Location: Total Depth: Remark: TABLE IV: SAMPLE INTERPRETATION """""_""" NA Sample ID and type Depth pretation Lithoiftl SocOrrO CO..NM Sec.l-4S-3E 4 9 9 7 FT NM SOURCE RK STUDY Thermal Major Maturity ............................................................. CT 3781-013 CT 3785-014 CT 3187-015 CT 3781-017 CT 3787-018 CT 3787-019 CT 3187-020 3781-024 3787-025 3187-026 44440500- 4 540505-0 4 545600-0 46 40 60 5 -0 4 645700-0 --4.2OO.- -4150 3787--Q2L1CT 3181-023 44345000- CT4 5 0 04 4 5 0 - 3181-016 3787-022 44330500- CT CT CT CT 4 9CT 96 4 745800-0 4 840805-0 4 845900-0 4 940905-0 4950- TAI CARB MATURE POOR OIL AND ASSOCIATED GAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 47% GAS TYPE 53% MATURE POOR OIL AND ASSOCIATED GAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 44% GAS TYPE 56% CAR8 MATURE POOR OIL AND ASSOCIATED GAS SOURCE KEROGEN TYPE OIL/OAS FACTOR: OIL TYPE 42% GAS TYPE 58% MATURE VERY POOR OIL SOURCE - GOOD GAS SOURCE 35% GAS TYPE KEROGEN TYPE OILlGAS FACTOR: OIL TYPE 65% TAI CARB TAI TAI TAT SHALE SHALE MATURE VERY POOR TO POOR OIL SOURCE - FAIR GAS SOURCE 35% KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE GAS TYPE 65% TAI SHALE MATURE VERY POOR OIL SOURCE - VERY GOOD GAS SOURCE 35% GAS TYPE KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 65% TAI TAI SHALE MATURE VERY POOR OIL SOURCE - GOOD GAS SOURCE 35% KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE GAS SHALE MATURE VERY POOR TO POOR OIL SOURCE - FAIR GAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 42% GAS TYPE -.-TAL--SHALE"MAUJRE -VERY- TAI TAI 65% 58% POOR-TO-PWBOLLSOURCE -- SAI.R..GAS . .. . SOURCE KEROGEN TYPE OILlGAS FACTOR: OIL TYPE 37% GAS TYPE 6 3 % TAI SHALE MATURE VERY POOR OIL SOURCE SOURCE KEROGEN TYPE OIL/GAS FACTOR: TAI TYPE - POOR TO FAIR GAS OIL TYPE GAS TYPE 63% SHALE MATURE VERY POOR TO POOR OIL SOURCE - FAIR GAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 37% GAS TYPE 63% SHALE MATURE VERY POOR OIL SOURCE - POOR TO FAIR GAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 35% GAS TYPE 65% SHALE MATURE VERY POOR OIL SOURCE - POOR TO FAIR GAS SOURCE KEROGEN TYPE OIL/GAS FACTOR: OIL TYPE 35% GAS TYPE 65% LITHOLOGIES SOURCE MIXED 37% - " Well Name: API Number:. File Name: Lat/Long: Anderson P I Wishhon 30-053-20010 3787 CountyIState: S o c o r r o CO..NEl Location: Sec.l-4S-3E Total Depth: 4997 FT Remark: NM SOURCE RK STUDY TABLE V: SAMPLE SUMMARY INTERPRETATION " " " " " " " " " " " " " " " " " " " NA Thermal Sample ID and type Major Litho TAI Depth I ftl Maturity -__-__-__-------____---HC TOC %RO Hyd Oxy Prod 52/93 Tmax Richness Richness Index Index Index Ratio Kerogen Oil Gas ................................................................... 0 2830 " " " " " Not Sampled ---------- " " " " " Madera iPenn.) ---------- GARB MM MI FAIR VERY POOR 0.75 400 GAS GAS 44 56 CT 3300 3250- SHALE MM I POOR VERY POOR 0.39 82 GAS GAS 31 69 i CT 3400 3350- SHALE MM 1 POOR VERY POOR 0.50 54 GAS GAS 31 69 3787-004 S CT 3550 3500- CARB MM I FAIR VERY POOR 0.59 150 GAS GAS 38 62 3787-005 X CT 3850 3800- CAR8 MM I GOOD VERY W O R 0.50 50 GAS GAS 35 65 3787-006 i CT 3900 3858- CARB MM I GOOD VERY VERY 0.22 41 GAS GAS 36 64 3787-007 t CT 4050 4000- SHALE MM 1 POOR VERY POOR ' 0.20 58 GAS GAS 36 64 3787-008 i CT 4100 4050- SHALE M I FAIR VERY POOR 0.67 50 GAS GAS 34 66 3787-009 t CT SHALE M I POOR VERY POOR 0.55 67 GAS GAS 37 63 3787-010 X CT 4200 4150- M I GOOD VERY POOR 0.80 93 GAS GAS 39 61 i CT 4250 4200- - .~ ._ VERY POOR ....- - - - .VERY POOR 0.60 GAS GAS 40 60 3787-001 t CT 30503000- 3787-002 X 3787-003 3787-011 - 4100- 4 1 5 0 ~ CARB CARB I M GOOD 3787-012 t CT 4300 4250- M CARB I GCQD 3787-013 X CT 4350 4300- M CARB I FAIR VERY 3787-014 t CT 4400 4350- M CARB 1 GOOD 3787-015 1: CT 4450 4400- M CARB I GOOD 3787-016 i 3787-017 t CT 4550 4500- 3781-018 t CT 4600 GOOD 4550VERY MT 3787-019 i CT 4650 4600- 3787-020 t CT 4700 4650- 3787-021 i CT 4750 4700- SHALE M 3787-022 X CT 4800 4750- SHALE M 3787-023 t CT 4850 4800- SHALE M CT GOOD 45004450MT M SHALE SHALE I M R FA1 M SHALE SHALE M M SHALE 107 ". " .. .- . .-..- " .- __ --- . - - 0.47 117 GAS GAS 42 58 POOR 0.85 150 GAS GAS 47 53 VERY POOR 0.88 116 GAS GAS 44 56 VERY POOR 0.71 84 GAS GAS 42 58 VERY POOR 0.34 15 GAS GAS 35 65 VERY POOR 0.58 37 GAS GAS 35 65 VERY POOR 0.47 14 i7A!3 G4S 15 55 I GOOD VERY POOR 0.60 27 GAS GAS 35 65 I FAIR VERY POOR 0.71 44 GAS GAS 42 58 FA1 VERY POOR 0.77 61 GAS GAS 37 63 POOR VERY POOR 0.75 63 GAS GAS 37 63 FA1 VERY POOR 0.67 62 GAS GAS 37 63 I . POOR R I I R i- t 'dell Name: API Number: File Name: LatfLonp: Anderson i l l Wishbon 30-053-20010 3787 3187-024 3187-025 3181-026 * * """_""""~ NA Sample I D ype and "__""""""""""""""""""""" CounCy/State: Socorro CO..NM Location: Sec.l-4S-3E Total Depth: 4997 FT Remark: NM SOURCE RK STUDY TABLE V: SAMPLE SUMMARY INTERPRETATION Depth Major . . . . .Thermal . . . . . . . . Maturity ........... TOC Prod HC Oxy Hyd SZ/S3 Ratio Index Index %RO Index Richness Richness Tmax TAI CT 4900 4850- MSHALE CT 4950 4900- SHALE CT MIXEDSOURCELITHOLOGIES 49504996 4997 tt+ttttttt M TotalDepth I POOR VERY POOR 0.80 67 GASGAS I POOR VERY POOR 1340.79 GASGAS tttttttttt Kerogen Gas Oil 35 65 35 65 Litho Well Name: API Number: F i l e Name:. Lat/Long: Anderson n l Wishbun 30-053-20010 3787 NA TABLE V I - A : CountvlState: Location: T o t a l Depth: Remark: SAMPLE SUMMARY OF GEOCHEMICAL DATA ....................... P y r o l y s i s Data ( m u / 4 1 Sample I D and Depth "~__"""_""""""""""""""""""" " " " " " " " " " " " " " " " " lftl Lithology 0 " " " " " 2830 " " " " " TOC """_M a t u r i t y S o c o r r o CO..NM Sec.l-4S-3E 4997 FT NM SOURCE RK STUDY Kerogen """""~"""~ %Oil %Gas S1 S2 s3 Tmax TAI %RO 0.13 0.09 0.03 0.52 436 2.3 " " 44 55 ---------M a d e r a1 P e n n . l ---------Not S a m p l e d 3787-001 CT 3000- 3050 3187-002 CT 3250- 3300 75Sh 20LS 5Md 0.39 0.09 0.14 0.32 413 2.5 " " 31 68 3787-003 CT 3350- 3400 75Sh 20LS 5Md 0.50 0.08 0.08 0.27 274 2.5 " " 31 68 3787-004 CT 3500- 3550 l00Ls 0.22 0.10 0.07 0.33 303 2.5 " " 38 62 3787-005 CT 3800- 3850 l00LS 0.30 0.01 0.01 0.15 262 2.5 " " 35 64 3787-006 CT 3858- 3900 l00LS 0.51 0.02 0.01 0.21 310 2.5 " " 36 63 3187-001 CT 4000- 4050 60Sh 40Ls 0.38 0.02 0.08 0.22 426 2.5 " " 36 64 3781-008 CT 4050- 4100 55Sh 40Ls 5Md 0.56 0.18 0.09 0.28 311 2.6 " " 33 66 3787-009 CT 4100- 4150 45Sh 45LS l0Md 0.45 0.16 0.13 0.30 300 2.6 " " 36 63 3787-010 CT 4150- 4200 70Ls 30Sh 0.40 0.16 0.04 0.31 274 2.6 " " 38 61 3781-01 1 CT 4200- 4250 70Le 4.250".~500- . . 30Sh 0.30 0.15 0.10 0.32 301 2.1 " " 40 59 70LS 30Sh " " iz 57- '787-012- . - l0ULS -~ - .~ - -. -- -.-- . -. - 0.36 0.11 0.19 li.3z. -3j5' -.zy7- ~~ 0.24 0.17 0.03 0.36 308 2.7 " " 46 53 0.32 0.14 0.02 0.37 259 2.7 " " 43 56 1OMd 0.37 0.12 0.05 0.31 274 2.7 " " 42 58 25LS 5Md 1.59 0.11 0.21 0.24 527 2.8 " " 35 64 70Sh 20LS 1OMd 0.68 0.14 0.10 0.25 360 2.8 " " 35 64 4550- 4600 8OSh l0LS 10Md 2.08 0.1Y 0.21 0.40 535 2.8 " " 35 64 CT 4600- 4650 60Sh 40Ss 1 .07 0.15 0.10 0.29 418 2.8 " " 35 64 :787-020 CT 4650- 4700 YUSh loss 0.77 0.15 0.06 0.34 358 2.8 " " 42 58 :787-021 CT 4100- 4150 70Sh 30Ss 0.56 0.17 0.05 0.34 296 2.8 " " 36 63 :781-022 CT 4750- 4800 IOSh 3059 0.49 0.06 0.02 0.31 274 2.8 " " 36 63 ,787-023 CT 4800- 4850 70Sh 30Ss 0.55 0.04 0.02 0.34 345 2.8 " " 36 63 1781-013 CT 4300- 4350 YOLS 5Sh 1787-014 CT 4350- 4400 70LS 30Sh :187-015 CT 4400- 4450 55Ls 35Sh 787-016 CT 4450- 4500 70Sh :781-011 CT 4500- 4550 :781-018 CT 4781-019 5Md Well Name: API Number: F i l e Name: Lat/LonB: Anderson 4 1 Wishbon TABLE V I - A : """"_"""""""_" 30-053-20010 3787 Socorro CO..NM CountvlState: Location: Sec.l-4S-3E T o t aDl e p t h4:9 9F1 T Remark: NM SOURCE RK STUDY SAMPLE SUMMARY OF GEOCHEMICAL DATA NA Pyrolysis Data imq/nl Depth Sample I D a n d type L i t h o l o gl yf t ) " " " " " " " " " " " " " " " " TOC SI S2 TAI s3 ""_ M a t u r i t y %RO Tmax Keroeen " " " " " " " " " %Oil %Gas ................................................................. 3 7 8 7 - 0 2 4 7 0 s hCT4 9 0 0 4 8 5 0 - 30s~ 3787-025 4 0 L s 6 0 S hCT 49504900- 3787-026 4 CT 0 s h4 9 9469 5 0 4997 4 0 ~ 5 zuss t t + + t t t i t +T o tDael p t h 0.42 0.08 0.02 11.28 240 2.8 ---- 35 64 0.29 0.11 0.03 0 . 3 ~ 217 2.8 ---- 35 64 0.23 0.06 0.02 0.35 2.8 ____ 38 61 tttttttt+t 201 Well Name: Andersan P I Wishbon API Number: 30-053-20010 File Name: 3787 Lat/Lonu: NA Depth Sample ID typeand - - - - - - - - """_"""""""~""""""""""" iftl CountvlState: S o c o r r o CO. ,NM Location: Sec.l-4S-3E Total Depth: 4997 FT Remark: NM SOURCE RK STUDY TABLE V1-8: SAMPLE SUMMARYOF PYROLYSIS DATA . . . . . . . . . . . . . . . . . . . . . . . Lithology TOC SI (mg/gl 52 lmg/gl s3 img/gl Prod Hyd Oxy TmaxIndexIndexIndexRatio S2/S3 " 0 " " " " " Not Sampled ---------- 2830 " " " " " Madera (Penn.1 3787-001 CT 3000- 3787-002 CT 3250-3300 75Sh 20L5 3781-003 CT 3350-3400 75Sh 2OLs 3787-004 CT3500-3550 3787-005 CT 3787-006 3050 IOOLS ---------0.13 0.OY 0.03 0.52 436 0.75 400 23 0.06 5Md 0.39 0.09 0.14 0.32 413 0.39 82 35 0.44 5Md 0.50 o.on 0.08 0.27 274 0.50 54 16 0.30 l0OLS 0.22 0.10 0.07 0.33 303 0.59 150 31 0.21 3800-3850 l00LS 0.30 0.01 0.01 0.15 262 0.50 50 3 0.07 CT 3858-3900 IOOLS 0.51 0.02 0.07 0.21 310 0.22 41 13 0.33 3787-007 CT 4000-4050 60Sh 40Ls 0.38 0.02 0.08 0.22 426 0.20 57 21 0.36 3787-008 CT 4050- 4100 55Sh 40Ls 5Md 0.56 0.18 0.09 0.28 311 0.67 50 16 0.32 3787-OOY CT4100-4150 45Sh 45Ls lOMd 0.45 0.16 0.13 0.30 300 0.55 66 28 0.43 3787-010 CT4150-4200 70Ls 30Sh 0.40 0.16 0.04 0.37 274 0.80 92 10 0.11 3787-011 CT4200-4250 70Ls 30Sh 0.30 0.15 0.10 0.32 301 0.60 106 33 0.31 3787-012 CT. 0. ..4 2. 35.5- .0.47 116 52 0.45 3787-013 CT4300-4350 90LS 5Sh 5Md 0.24 0.17 0.03 0.36 308 0.85 150 12 0.08 3787-014 CT4350-4400 70Ls 3onh 0.32 0.14 0.02 0.37 259 0.88 115 6 0.05 3787-015 CT4400-4450 55LS 35Sh lOMd 0.37 0.12 0.05 0.31 274 0.71 83 13 0.16 3787-016 CT 70Sh 25Ls 5Md 1.59 0.11 0.21 0.24 527 0.34 15 13 0.88 3187-017 CT4500-4550 70Sh 2OLslOMd 0.68 0.14 0.10 0.25 360 0.58 36 14 0.40 3787-018 CT4550- 80Sh lOLs 2.08 0.19 0.21 0.40 535 0.47 19 10 0.53 3i3?-019 CT4600-4650 60Sh 40Ss 1.07 0.15 0.10 0.29 418 0.60 27 9 0.34 3787-020 CT4650-4700 Y0Sh loss 0.77 0.15 0.06 0.34 358 0.71 44 7 0.18 3787-021 CT4700-4750 70Sh SOSS 0.56 0.17 0.05 0.34 Z96 0.7i 60 n 0.15 3787-022 CT 70Sh 30Ss 0.49 0.06 0.02 0.31 274 0.75 63 4 0.06 3787-023 CT4800-4850 70Sh 30Ss 0.55 0.04 0.02 0.34 345 0.67 61 3 0.06 __ 4250-- 4.3_00__ - 70Ls .-- .._ 30Sh _. " 4450-4500 4600 4750-4800 lOMd .L17 " . -- Well Name: Anderson Irl Wishbon API Number: 30-053-20010 ""_""_""""""" File Name: 3787 Lat/Long: NA Depth Sample ID and type CountylState: Socorro CO..NM Location:Sec.l-4S-3E Total Depth: 4,997 FT Remark: NM SOURCE RK STUDY TABLE VI-B: SAMPLE SUMMARY OF PYROLYSIS DATA Lithology (ftl TOC SI S2 (mg/gl (m4/81 s3 (mu/gl Prod OXY Tmax Index Index Index Ratio Hyd S2/S3 ................................................................. 3787-024 CT 1850- 4900 70Sh 0.42 309s 3787-025 CT 4900- 4950 60Sh 3787-026 4950CT 40Ls 40Sh 4996 4997 4OLs 2OSs tttt+tttt+ TotalDepth 0.08 0.02 0.28 240 0.80 66 0.07 4 0.29 0.11 0.03 0.39 217 134 0.19 10 0.08 0.23 0.06 0.02 0.35 207 8 0.06 t++ttt+ttt 0.75 152 Well Name: API Number: File Name: Lat/Lonp: Anderson 81 Wiehbon TABLE VI-C: SAMPLE SUMMARY 30-053-20030 3787 OF KEROGEN DATA County/State: Location: Total Depth: Remark: . ..................... NA Socorro CO..NM Sec.l-4S-3E 4997 FT NM SOURCE RK STUDY Sample Depth ID type and lftl AMORPH HERB WOODY lNERT NotDef NotDef NotDef NotDef NotDef NotDef %Oil %Gas 0 2830 ---------1Penn.I ---------- " " " " " Not Sampled -.." Madera " " " "_ "- "_ "- 34 "_ "_ "_ "_ "_ "_ "_ 30 30 "_ 36 28 36 8 26 33 33 "_ "_ 4150-4200 8 33 26 33 "_ CT 4200-4250 n 33 33 26 3787-012 CT 4250- 10 .36 27 2.7- 3787-013 CT 4300-4350 17 33 25 25 3787-014 CT 4350-4400 15 30 25 30 "_ "_ "_ "_ 3787-015 CT 4400-4450 15 25 30 30 "_ 3787-016 CT 4450-4500 10 18 36 36 3787-017 CT 4500-4550 10 18 36 36 3787-018 CT 4550-4600 10 1s 36 36 3787-019 CT 4600-4650 10 18 36 36 3787-020 CT 4650-4700 15 25 30 30 3787-021 CT 4700-4750 8 26 33 33 "_ "_ "_ "_ _" "_ 3787-022 CT 4750-4800 8 26 33 33 "_ 3787-023 CT 48004850 8 26 33 33 "_ 3787-001 CT 3000- 3 0 5 0 3787-002 CT 3787-003 11 44 11 34 3250-3300 0 28 36 36 CT 3350-3400 0 28 36 36 3787-004 CT 3500- 3550 0 40 40 20 3787-005 CT 3800-3850 0 36 36 28 3787-006 CT 3858-3900 0 44 22 3787-007 CT 4000-4050 0 40 3787-008 CT 4050-4100 0 3787-009 CT 4100-4150 3787-010 CT 3787-011 4300 ""_""""""""""""" " " 44 55 31 68 . 31 68 "_ "_ 38 62 "- "_ 35 64 _" "_ "_ "_ 36 63 36 64 33 66 36 63 38 61 40 59 42 57 46 53 43 56 42 58 35 64 35 64 35 64 35 64 42 58 36 63 36 63 36 63 """""- _" """- _" "- _" "_ _" _" _" _" " "_ "_ "_ "_ "_ "_ "_ _" "_ "_ "_ "_ "_ "_ "_ Well Name: Anderson It1 Wiahbon APINumber:30-053-20010 3787 File N m e : LatILonz: NA Depth Sample 1D type and lf'tl Countv/State: Socorro CO.,NM Location: Sec.l-4S-3E Total Depth: 4991 FT Remark: NM SOURCE RH STUDY TABLE VI-C: SAMPLE SUMMARY OF KEROGEN DATA ..................... %Oil AMORPH HERB WOODY INERT NotDef NotDef NotDef' NotDef NotDef NotDef %Gas .................................................................. 3787-024 CT 4900 4850- 3787-025 CT 4900- 3187-026 CT 4950- 4 9 9 6 4950 10 18 36 36 10 In 36 8 26 33 "_ 36 "_ 33 "_ T o t a l Depthtttttttttt 4997 tttttttttt "_"""_""""""""""""""""""" . "~ .. . . . . "_ "_ "_ "- _" "- "_ "_ "_ "_ "_ "_ _" 64 _" 64 _" 35 35 38 61 r FIGURE 1 THERMAL MATURITY PROFILE r I I I r I r r r I I Y Y Y USING THE THERMAL ALTERATIOK UQEX (TAI) T h i s f i g u r e d i s p l a y s a thermal m a t u r i t y p r o f i l e f o r t h e w e l l u s i n g t h e thermalalterationindex (TAI). The raw d a t a ' p l o t d i s p l a y s t h e TAI v a l u e s o f i n d i v i d u a ls a m p l e sp l o t t e dv e r s u sd e p t h (150 f o o t i n t e r v a l s ) . W i t h i n a particul a r i n t e r v a l an "A" i n d i c a t e s o n e T A I v a l u e s a n d a "B" i n d i c a t e s two TAI d e t e r The "AVG" g i v e st h ea v e r a g e TAI v a l u e for m i n a t i o n so ft h es a m e ' v a l u e ,e t c . thatinterval. The t h r e e term moving a v e r a g e p l o t d i s p l a y s a T A I p r o f i l e smoothed b:r a "AVG" g i v e s t h e a v e r a g e f o r t h e p a r t i c u l a t h r e e term movingaverage.The i n t e r v a l . When a s a m p l el a c k s a TAI v a l u e for i n t e r p r e t a t i o n , a TAI valu'? i s takenfromthis smoothed curve for that sample depth. The d e s c r i p t i v e t e r m i n o l o g y u s e d t o d e f i n e t h e r m a l m a t u r i t y . t h e a s s x i a t e d hydrocarbontype,and t h e n u m e r i c a lv a l u e so f TAI c o r r e s p o n d i n g t o t h i s terminology i s givenbelow. TAI Value -- 21.7. 1 - 2.5 -- 3.5 4.1 1.0 1.8 2.2 2.6 3.6 4.2 5.0 -> - 4.9 Descriptive Terminology TAI Value Immature (I) ModeratelyImmature (MI) Moderately Mature (MM) Mature (M) Very Nature (VM) S e v e r e l y Altered (SA) Metamorphosed 1.3 1.5 2.2 2.5 3.2 - 1.5 - 2.2 - 2.5 - 3.2 - > 3.8 - 3.4 Associated Hydrocarbon Typ? Biogenic Gas Biogenic Gasand Immature O i l Immature Heavy O i l Mature O i l Mature O i l . Condensate and Wet Gas P e t r o g e n i c Methane Gas Tops are shown by a dashed l i n e (---) a n d t h e names a r e i n d i c a t e d a l o n g t h e r i g h t handmargin. The e x a c t d e p t h o f t h e t o p s a r e g i v e n i n t h e I n t r o d u c t i o n . Total well depth i s i n d i c a t e d a n d l a b e l e d w i t h a p p r o p r i a t e d e p t h . Well Name: API W r : File Name: Lst/lKlng: A n d e m :I Wishton 30-053-20010 3'787 Colmty/State: TlEmAL M4lURITY m 1 L E Location: Total Depth: N4 Remark: Socorm CB..Nl Six.l-4S-3E SmDOth AVvg TAI Raw, Data Plot Values 1 2 3 4 I...;==.=......==="===================I I I IMIIMII M I W : SA ,"""""""""_"""""""""", 1960 2100 . ... . ... . .. . :.=.==.."==.....=.=====================I I I :MI:WlI M I W I SA I ,"_"""""""_""""""""""~, .. .. . . .. . .. .. . .. .. . .. .. .. . . . . . * . . . . ... . .*. . ... ! I ~" " " " " " " " " " " " " " "~ t : 3900 4050 4200 4350 4500 .. .. . . 4650 TD 4997 I 2.50 I I 2.50 I I 2.70 I I 2.73 : I 2.80 : .c .c .c : . ... . . . . . . . . . 2.80 I I 2.80 : . . .. . .. .. .. . .. .. ! . . . . .*. * .. .*. .. *. *. .. *. *. .. * . * .. .* .. ...t t* . . . I 2.30 I 2.40 I 2.43 I 2.50 I 2.50 I 2.50 ! 7 .50 , "" I 2.53 I, I 2.60 : 2.58 I 2.14 : 2.78 : 2.80 I 2.80 tttttttttttttttttAttttttt+~ttttttttttt~ 2 . 8 0 :+tttttttttttttttt*tttttttttttttttt++t+t: 2.80 ,""""""""___""""""""""~ i I IMlIWlI ,""""""""_""""""""""", 1 2 ,"""""""""_"""""""""", I IMI:mI ,"""""""""_"""""""""", , """""""""""""""""""I M I W I SA I I"""""""""_"""""""""", Y f 2.30 ! 2.50~: , """"""""""_"""""""""I Y . I I 2.50 I : 2.50 I I 2.50 I A. . ... . .~. . ! A. A. A. 3300 3450 3600 3750 4 . . . .. .. .. .. . . . El. . . . . c .. .. .c.BA 3150 ValUeS 5 I 3 ~ ,""""""""""_""""""."I .. .. .. . . . .. .A. .. 2250 2400 2 3 Term Moving Average 1 . . . 18W 4800 4950 TAI 5 ~"""""""""""""""""""I 0 k t sampl 150 300 450 600 750 900 1050 1200 1350 1500 1650 Fr 4'197 )91SYJUXRKmY I M i W : SA : ,""""""""""""."""""""I 3 4 5 1 2 3 4 5 I I TABLE I RESULTS OF TOTAL ORGANIC CARBON I" NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION JAMES K. ANDERSON, INC.NO.l WISHBONE FEDERAL S E C . l T4S, R3E, SOCORRO COUNTY, NEW MEXICO I" r I" I" r II A P T #30-053-20010 GEOCAEn SAMPLE RUHBER .. DEPTH TOTAL ORGANIC CARBOK ( %of Rock) INTERVAL (feet) ~~ 3787-001 3787-002 3787-003 3787-004 3787-005 3787-006 3787-007 3787-008 3787-009 3787-010 3787-011 3787-012 3787-013 3787-014 3787-015 3787-016 3787-017 3787-018 3787-019 3787-020 3787-021 3787-022 3787-023 3787-024 3787-025 3787-026 3000-3050 3250-3300 3350-3400 3500-3550 3800-3850 3850-3900 4000-4050 4050-4100 4100-4150 4150-4200 4200-4250 4250-4300 4300-4350 4350-4400 4400-4450 4450-4500 4500-4550 4550-4600 4600-4650 4650-4700 4700-4750 4750-4800 4800-4850 4850-4900 4900-4950 4950-4996 ~~ 0.13 0.39 0.50 0.22/0.22 0.30 0.51 0.38 0.56 0.45 0.4G 0.30 0.3U0.35 0.24 0.32 0.37 1.59 0.68 2.08 1.07 0.77/C .76 0.56 0.49 0.55 0.42 0.29 0.23 TABLE I - B C l - C7 HYDROCARBON ANALYSES O F CUTTINGS GAS BEG. GEOCHEM I D DEPTH " " " " " " " " " " 3787-001 3787-002 3787-003 3787-004 3787-005 3787-006 3787-007 3787-008 3787-009 3787-010 3787-011 3787-012 3707-013 3787-014 3707-015 3787-016 3787-017 3787-018 3787-019 3787-020 3787-021 3787-022 3787-023 3787-024 3787-025 3787-026 Y ""_"_ 3000 3250 3350 3500 3800 3850 4000 4050 4100 4150 4200 4250 4300 4350 4400 4450 4500 4550 4600 4650 4700 4750 4800 4850 4900 4950 END DEPTH "_"""_ 3050 3300 3400 3550 3850 3900 4050 4100 4150 4200 4250 4300 4350 4400 4450 4500 4550 4600 4650 4700 4750 4800 4850 4900 4950 4996 "_""""_ METHANE ETHANE 991.4 640.1 874.7 2745.2 5184.8 4804.2 2736.1 2670.4 2646.9 2280.7 1878.7 2460.9 3022.5 3803.3 6192.9 4762.5 2754.4 5012.8 3315.1 2791.8 1556.8 2413.0 2299.7 1754.1 2402.6 1631.7 " " " " " " 11.8 0.2 2.8 0.2 2.8 2.1 21.2 229.7 77.5 41.3 39.2 73.7 45.9 2.3 20.7 4 .3 36.4 44.2 5.2 40.2 69.0 35.9 1.9 28.3 6.1 0.8 1.2 26.8 24.5 13.4 20.6 116.9 .2 8.9 7.4 1 .4 16.6 PROPANE ISOBUTANE N-BrJTANE """""_ 3.4 0.9 0.6 6.0 104.1 23.6 52.0 68.5 30.5 21.6 9.4 16.0 21.5 16.9 17.4 6 .'l 8.2 5.8 6.4 8.4 5.6 8.6 8.3 5.8 2.0 5.4 """_ " " " " " " " " 1.2 30.4 5.1 4.5 3.6 8.7 5.3 4.5 7.3 1.7 1.3 1.2 1.4 0.6 0.4 1.8 0.3 0.1 1.5 20.8 2.3 2.0 1.1 3.0 2.5 1.8 3.0 2.2 1.4 1.8 0.4 0.6 0.2 0.4 0.3 0.7 0.5 0.4 0.3 0.1 1.2 C5-C7 "-" ""_ 10.3 31.9 2.8 3.6 22.4 1.2 2.6 0.7 6.0 4.0 11.3 10.6 3.8 1.5 2.5 0.2 2.5 0.6 2.7 3.3 6.1 2.8 0.8 0.6 1.1 6.4 C1 - C7 GEOCHEM BEG. END ID DEPTH DEPTH " " " " " " " " " " 3787-001 3787-002 3787-003 3787-004 3787-005 3787-006 3787-007 3787-008 3787-009 3787-010 3787-011 3787-012 3787-013 3787-014 3787-015 3787-016 3787-017 3787-018 3787-019 3787-020 3787-021 3787-022 3787-023 3787-024 3787-025 3787-026 TABLE 11-B HYDROCARBON ANALYSES OF CUTTINGS (CALCULATED VALUES) "_" _"" 3000 3250 3350 3500 3800 3850 4000 4050 4100 4150 4200 4250 4300 4350 4400 4450 4500 4550 4600 4650 4700 4750 4800 4850 4900 4950 ""_ 3050 3300 3400 3550 3850 3900 4050 4100 4150 4200 4250 4300 4350 4400 4450 4500 4550 4600 4650 4700 4750 4800 4850 4900 4950 4996 Cl-C4 ""_ C2-C4 "_" ""_ 1009.5 18.2 4.1 644.2 878.5 3.8 2776.0 30.8 385.0 5569.9 4912.8 108.6 2835.8 99.7 112.4 2790.9 3.2 2763.5 116.6 2355.9 3.2 2.175.2 1912.8 34.2 2520.6 59.7 3095.7 73.2 3866.3 63.0 6288.4 95.4 4806.6 44.1 2793.4 39.0 5025.7 12.9 3349.8 34.7 2826.2 1.2 4.234.5 1577.7 1.3 1.720.9 2444.1 31.1 2326.3 1.2 3.326.7 1769.6 15.6 2412.6 10.0 1656.3 24.6 GAS ""_"""_IC4/NC4_""_"%WET?WSS " " " " 0.7 0.7 1.2 1.4 1.5 2.2 2.3 2.3 1.3 2.4 1.4 2.4 3.2 1.5 4.1 0.9 4.1 1.43.4 4.1 3.5 1.8 0.6 0.4 1.1 6.9 2.2 3.5 4.0 4.2 1.8 2.4 1.6 0.3 1.0 2.8 1.3 0.9 2.0 2.9 1.5 1.2 0.4 TABLE I1 LITBOLOGICAL DESCRIPTIONS AND ORGANIC CARBON ANALYSES NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION JAMES K. ANDERSON, I N C . NO.l WISHBONE FEDERAL SEC. 1,T4S, R3E, SOCORRO COUNTY, NEW MEXICO API 630-053-20010 r I GEOCAW r. r r SAMPLE NUMBER 3787-001 -A lcareous, Shale, 75% r DEPTH INTERVAL (feet) .. ORGANIC CARBON GSA NO. LITHO DESCRIPTION (wt 3000-3050 0.13 3250-3300 3787-002 -A . .- -c 0.39 .. ..~ ~ ~ medium dark gray. 20% crystalline, Limestone, fine light gray. 5%-Mudstone, moderate reddish brown. N4 N7 10R-416 3350-3400 3787-003 f -C r r 3787-004 -A r r Y Y 0.50 75% Shale, noncalcareous, medium dark gray. 20% Limestone, fine crystalline, light gray. 5% Mudstone, moderate reddish brown. N4 N7 10R-4/6 3500-3550 100% Limestone, crystalline, fine N7 light to medium gray. N5 to 3800-3850 3787-005 Limestone, fine clayey, 100% -A 0.30 crystalline, medium dark gray. 3850-3900 3787-006 -A .%) 100% Limestone, crystalline, fine to N7 gray. N5 light t o medium -B , . N4 0.51 100% Limestone, clayey, fine crystalline, dark gray. N3 TABLE I1 (continued) LITHOLOGICAL DESCRIPTIONSAND ORGANIC NEW MEXICO CARBON ANALYSES HYDROCARBON SOURCE ROCK EVALUATION JAMES K. ANDERSON, INC. NO.l WISHBONE FEDERAL SEC.l, T4S, M E , SOCORRO COUNTY, NEW MEXICO API #30-053-20010 GEOCREM SAHPLE NUMBER 3787-007 DEPTH INTERVAL (feet) 4000-4050 -A - .-E- 4050-4100 ~ 45% Shale, slightly calcareous, grayish black. N2 45% Limestone, fine crystalline, medium gray. N5 10% Mudstone, moderate reddish brown. 10R-4/6 -B -C -B 0.40 4150-4200 70% Limestone, fine crystalline, light t o medium gray. 30% Shale, slightly calcareous, grayish black. Trace of red mudstone. -B 3787-011 -A 0.45 4100-4150 -A 3787-010 -A 0.56 55% Shale, slightly calcareous, grayish black. N2 40% Limestone, fine crystalline, medium gray. N5 5% Mudstone, moderate reddish brown. 10R-416 ~~ ~~ -C 3787-009 0.38 60% Shale, slightly calcareous, grayish black. N2 40% Limestone, fine crystalline, medium gray. N5 -B 3787-008 -A LITHO DESCRIPTION ORGANIC CARBON (wt.%) GSA NO. N7 N5 to N2 4200-4250 0.30 70% Limestone, fine crystalline, light to medium gray. 30% Shale, slightly calcareous, grayish black. Trace of red mudstone. N7 to N5 N2 TABLE I1 (continued) LITAOLOGICAL DESCRIPTIONS AND ORGANIC CARBON ANALYSES NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION JAMES K. ANDERSON, I N C . N O . l WISHBONE FEDERAL SEC. 1, T4S, ME, SOCORRO COUNTY, NEW MEXICO API #30-053-20010 GEOCHEM SAWPLE DEPTE ORGANIC INTERVAL "BER (feet) 3787-013 LITE0 DESCRIPTION 4300-4400 0.32 -A .~ . .- 70% Limestone, fine crystalline, N7 to ~ -B . -light to mediumgray: 30% Shale, slightly calcareous, grayish black. ~- - N5 -B -C 10%Mudstone, moderately reddish brown. 10R-4/6 1.59 4450-4500 70% Shale, slightly calcareous, grayish black. -B 25% Limestone, fine crystalline, light to medium gray. moderately reddish brown. -C N2 N7 to N5 5 % Mudstone, 10R-416 4500-4550 0.68 -A 70% Shale, slightly calcareous, -B N2 grayish black. 20% Limestone, fine crystalline, N7 to light to medium gray. N5 -C . 0.37 55% Limestone, fine crystalline, N7 to light to medium gray. N5 35% Shale, grayish black. N2 3707-017 " N2 4400-4450 -A 3787-016 -A .X) 0.24 -B 3787-015 (Wt 90% Limestone, fine crystalline, N7 to light to medium gray. N5 5% Shale, grayish black. N2 5% Mudstone, moderately . reddish brown. 10R-4/ 6 -C -~ CARBON NO. 4300-4350 -A 3787-014 GSA 10% Mudstone, moderately reddish brown. 10R-4/6 r r r I" I" GSA TABLE I1 (continued) LITROMGICAL DESCRIPTIONS AND ORGANIC CARBON ANALYSES NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION JAMES K. ANDERSON, INC. N O . l WISHBONE FEDERAL SEC.l, T4S, R3E, SOCORRO COUNTY, N E W MEXICO API #30-053-20010 GEOCBW SAMPLE UOMBER DEPTE INTERVAL (feet) 4550-4600 3787-018 -A I- 4600-4650 3787-019 --A. - __ . __ - -~- (wt.73 N2 N7 t o N5 10R-4/6 - . ~. ~ ..1.07 - ~ " N2 N9 4650-4700 0.77/0.76 90% Shale,noncalcareous, grayish black. 10% Sandstone,calcareous, f i n eg r a i n e d , clear t o white. N2 N9 4700-4750 0.56 70% Shale,noncalcareous, grayish black. 30% S a n d s t o n e ,c a l c a r e o u s , f i n eg r a i n e d , clear t o white. -B -B 602 Shale, rroncafcaleofis, grayishblack. 40% S a n d s t o n e ,c a l c a r e o u s , f i n eg r a i n e d ,c l e a rt o white. Traceredmudstone. -A 3787-022 -A NO. 2.08 -B 3787-021 LITHO DESCRIPTION 80% S h a l e , s l i g h t l y c a l c a r e o u s , g r a y i s hb l a c k . 10% L i m e s t o n e ,f i n ec r y s t a l l i n e , l i g h t t o medium g r a y . 10% Mudstone, moderately r e d d i s h brown. -B 3787-020 -A ORGAf4J.C CARBON N2 N9 4750-4800 0.49 70% Shale,noncalsareous, g r a y i s hb l a c k . 30% S a n d s t o n e ,c a l c a r e o u s , to f i n eg r a i n e d ,c l e a r white. N2 N9 TABLE 11 (continued) LITHOLOGICAL DESCRIPTIONS AND ORGANIC CARBON ANALYSES NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION JAMES K. ANDERSON, I N C . NO.l WISHBONE FEDERAL SEC.l, DEPTE T4S, F3E, SOCORRO COUNTY, N E W MEXICO A P T #30-053-20010 GEOcHEn SAMPLE INTERVAL (feet) NUMBER 4800-4850 3781-023 -A -B N2 N9 0.42 4850-4900 3787-024 -A ~. ORGANIC CARBON (wt.73 0.55 70% Shale, noncalsareous, grayish black. 30% Sandstone, calcareous, fine grained, cleart o white. -B " LITE0 DESCRIPTION GSA NO. 70% Shale, noncalcareous, ." ~ .gr-ayish black. N2 30% Sandstone, calcareous, fine grained, clearto white. N9 0.29 4900-4950 3787-025 -A 60% Shale, noncalcareous, -B grayish black. N2 40% Limestone, fine crystalline, N7 to light to medium gray. N5 Trace sandstone. 4950-4996 3781-026 -A -B -C 0.23 40% Shale, noncalcareous, grayish black. N2 40% Limestone, fine crystalline, Nl to light to medium gray. N5 20% Sandstone, calcareous, fine grained, clearto white. N9 i " 7 .E I11 SmauRY OF ORGMIC CARBON AND VISWAJ. KEROGEN DATA NEW HEXICO HYDROCARBON SOURCE ROCK EVALUATION FEDERAL JAMES K. ANDERSON, I N C . N O . 1 WISHBONE COUNTY. NEW MEXICO SEC. 1 , T 4 S , R3E, SOCORRO API 130-053-20010 GEOCBEn DEPTA INTERVAL (feet) SAWLE ArmBER .. 3787-001 3787-002 3787-003 3787-004 3787-005 3787-006 3787-007 3787-008 3187-009 .. .. ... 3787-010 3787-011 3787-012 3787-013 3787-014 3787-015 "378r-016 . 3787-017 3787-018 3787-n19 3787-020 3000-3050 3250-3300 3350-3400 3500-3550 3800-3850 3850-3900 4000-4050 4050-4100 4100-4150 4150-4200 4200-4250 4250-4300 4300-4350 4350-4400 4400-4450 -- 1i4m-450u 4500-4550 4550-4600 4600-4650 4650-4700 TUTAL ORGANIC cmon 0.56 0.~ . 4..5 0.40 0.30 0.3610.35 0.24 0.32 0.37 .. T.5T KEROGEN KEY PredominanL; 60-1002: Secondary; 20-40% - 0.68 2.08 I .07 0.7710.76 LEGEND: Trace 0-202 I TYPE 0.13 0.39 0.50 0.2210.22 0.30 0.51 0.38 " > ORGANIC MATTER H;I:Am-W W-I;H;- 44 38 28 40 36 44 40 36 26 33 33 36 33 30 25 W-1;H:- A-W:I:A-W:I:H;I:W H;W-I:- A-1:W:W-1:H;Am A-I ;W;Am H-W:I:Am H;U-I;Am H;W-I;Am H-1:W:Am W-I :H:Am W-T:Trp5 W-1:H:Am W-I;H;Am W-1:H:Am w-1:n:Am ABU " PRCE [ZED B Y i - - - -I8 18 18 18 25 il 36 36 40 36 22 30 28 33 26 33 27 25 25 30 3636 36 36 30 ALTERATION STAGE 34 36 36 2n 28 34 30 36 33 33 26 27 25 30 30 -36 36 36 36 30 IADEX 2.3 2.5 2.5 2.5 2.5 2.5 2.5 2.6 2.6 2.6 2.7 2.7 7.7 2.7 2.7 . 2+ 2+ -2t 2t -2,2t - to 3- LO 3- to 3to 3- L O 37+ m-32+ t o 3- 2r - -8- " 2.8 2.8 2.8 2.8 - - - AI - AmAm* = Algal Amorphous-Sapropel Relic Amorphous-Saproprl Herbaceous-SporelPolIcn H H* = = Degraded Herbaceous w = Woody-Structured u = Unidentified HaLcrisl I = Inerrinite = Coaly c --- TABLE 111 (continued) S W R Y OF ORGANIC CARBON AND VISUAL KEROGEN DATA NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION JAHES K. ANDERSON. INC. NO.l WISHBONE FEDERAL SEC. 1, T4S,R3E, SOCORRO COUNTY, NEW HEXICO AP1 1 3 0 - 0 5 3 - 2 0 0 1 0 r t DEPTA GEOCAEH SAUPLE H[IMBER INTERVAL (feet) 3787-021 3787-022 3787-023 3787-024 3787-025 3787-026 4700-4750 4750-4800 4800-4850 4850-4900 4900-4950 4950-4996 TOTAL ORGANIC CARBON 0.56 0.49 0.55 0.42 0.29 0.23 ORGANIC H A T E R TYPE W-1;H;Am W-1:H;Am W-1;H;Am W-1;H;Am 9-1;H:Am H-1;W:Am VISUAL ABUNDANCE CENI ZED E H I - - - r 26 26 26 18 18 33 33 33 33 36 36 26 33 33 33 36 36 33 ALTERATION STAGE 2+ 2+ 2+ 2r 2+ to 3- to 3 - 33to 321 to 3 t" LO I TBERHAL ALTERATION INDEX 2.8 2.8 2.8 2.8 2.8 2.8 ~- - - - LEGEND: KEROGEN KEY Predominant; 60-1002 Secondary: 20-402: Trace 0-20'6 Amorphous-Sapropel Relic Amorphous-Saproprl Herbaceous-SporefPollen Degraded Herbaceous Woody-Structured Unidentified Material Inertini te Cody t . t , t . " " " " " j j j j j TABLE I V RESULTS OF ROCK-€VAL PYROLYSIS ANALYSIS N E W HEXICO HYDROCARBON SOURCE ROCK EVALUATION JAMES K. ANDERSON, INC. N O . l WISHBONE FEDERAL SEC. 1. T 4 S , R3E, SOCORRO COUNTY, NEW MEXICO API # ~ O - O ~ ~ - Z O O I O ... 3787-001 3787-002 3787-003 3787-004 3787-005 3787-006 3787-007 3787-008 3787-009 3787-010 3787-011 3787-012 3787-013 3787-014 3787-015 3787-016 3787-017 3787-018 3787-019 3787-020 - 3000-3050 3250-3300 3350-3400 3500-3550 -38003850. 3850-3900 4000-4050 4050-4100 4100-4150 4150-4200 4200-4250 4250-4300 4300-4350 4350-4400 4400-4450 4450-4500 4500-4550 4550-4600 4600-465n 4650-4700 436 413 274 303 -262 310 426 31 1 300 274 301 355 308 259 274 527 360 535 418 358 - 0.09 0.52 0.09 0.32 0.08 0.03 0.14 0.10 0.07 n.ot 0.01 - 0.02 0.21 0.02 0.18 0.16 0.16 0.37 0.15 0.17 0.07 0.08 0.09 0.13 0.04 0.10 0.19 ~. 0.03 0.m 0.05 0.21 0.10 0.21 0.17 0.14 0.12 0.11 0.14 0.19 0.40 0.15 0. IS T.O.C. = Toral organic c a r b o n , w . % Free h y d r o c a r b o n s , mg Hcig o f rock SI s2 = Residual hydrocarbon pOLential (mg HClg or r u s k ) 0.08 0.10 ,O.06 s3 PC* -- PI PC. 0.27 0.33 0.75 0.41 0.50 0.67 0.01 0.01 0.01 0.01 -0.15. @.SO- ~ ~~ 0.22 0.28 0.30 0.32 0.42 .~ . 0.36 0.37 0.31 0.74 0.25 0.29 0.34 C02 produced from kerogen p y r o l y s i s (mg C02ig rock) of = 0.083 (SI 4 S2) Hydrogen Index = mg HCig o r g a n icca r b o n RYDROGEN ("t.X) INDEX 0.13 0.39 ~. 0.50 0.22 8;30 0.51 0.38 0.56 0.45 0.40 0.30 0.36 0.24 0.32 0.37 I .59 0.68 2.08 1.07 0.77 ~ -- -0.BQ 0.25 0.20 0.69 0.57 0.80 0.02 0.62 0.47 0.85 0.87 0.75 0.34 0.58 0.47 0.02 0.62 0.75 T.O.C. 0.00 0.00 0.02 0.02 0.01 ~~ 0.03 0.01 0.01 0.01 0.07 0.02 0.03 0.01 W w n Index PI THAX " 23 35 16 31 3-13 21 16 28 10 33 52 12 6 13 13 14 10 9 7 OXYGEN INDEX - ~ 400 82 54 150 .-50 41 57 50 66 92 106 116 150 115 83 15 36 19 27 44 = rng C02Ig o r g a n i c a r b o n = SllSl + s2 - Temperarure degrees Index, C. 0-4850 TABLE IV ( c o n t i n u e d ) RESULTS OF ROCK-EVAL PYROLYSISANALYSIS NEW MEXICO HYDROCARBON SOllRCE ROCK N A L U A T l O N JAMES K . ANDERSON, INC. NO.l WISHBONE FEDERAL S E C . 1 . T 4 S , R3E, SOCORRO COUNTY, NEW MEXICO A P I 630-053-20010 DEPITl IMERVAL (Feet) GEOCREH SAMPLE NUMBER 3787-021 0.02 3787-022 3787-023 3782-024. 3787-025 3787-026 . THAX (C) 0.06 4750-4800 274 345 4850-4900 4900-4950 4950-4996 240 217 207 SI (.gls) s2 (mglg) 0.17 0.05 53 (*slg) 63 ~ . .O.QS . 0.11 0.06 .- 0.02 4.02.-.~ 0.03 0.02 0.34 0.31 0.34 PI PC* 0.77 0.754 0.01 0.67 0,28--~~.-- 0.8-00.39 0.35 0.79 0.75 T.O.C. IKDEX ("t.X) 0.56 0.49 0.55 0-420.29 0.23 0.00 30.00 -C!.OO-0.01 0.00 AIDROGEN INDEX OXYGEA 8 60 61 . 10 8 ~ T.O.C. SI s2 = Total organic carbon, w 1 . Z = Free h y d r o c a r b o n s , m g H s l g of rock = Residual hydrocarbon p o t e n t i a l (mg H C l g or rock) s3 = C02 produced from kerogen p y r o l y s i s (mg C O 2 1 g of rock) = 0.083 (SI 1 S 2 ) PC+ Hydrogen Index = mg H C I g o r g a n i c carbon Oxygen Index PI TMAX - .-6.6- 134 I52 ~~ = mg C O 2 1 g o r cgaarnbi co n = S 1 I S 1 + s2 T e m p e r a t u r e Index, degrees C . - TABLE V h’ I‘ b‘ ‘I‘ ir Y A. A. GEOTHERMAL DIAGENETIC CRITERIA IGEOCnEU LIIBORI(TORIES.I~CI Y Y