New Mexico Bureau of Mines & Mineral Resources Socorro, N M 87801 ”. A DIVISION OF NEW MEXICO INSTITUTE OF MINING & TECHNOLOGY Infomalion: 50518354420 Publicalias: 50518354410 OPEN-FILEREPORT I 328 HYDROCARBON SOURCE ROCK EVALUATION O F HOUSTON O I L & MINERALS, NO. 1 LEWELLING, SEC. 1 2 , T12S, R9E, OTERO COUNTY, NEW MEXICO G.S. B a y l i s s and R.R. Schwarzer February 1 9 8 8 Y Y Y NEW MEXICO TECH IS AN EQUAL OPPORTUNlTYlAFFlRMATMACTION INSTITUTION REW MFXICO HYDROCARBON SOURCE ROCK EVALUATION PROJECT HOUSTON OIL & MINEWS, RO.1 LEWELLING SEC.12, T12S, R9E, OTERO COUNTY, NEW MEXICO API NO. 30-035-20010 SOUTHEAST AREA GEOCBEM JOB NO. 3620 Prepared for PR0CR-h PARTICIPANTS Dr. Geoffrey S. Bayliss and Dr. Rudy R. Schwarzer GEOCHEM LABORATORIES, INC. 1 1 4 3 4 BRITTMOORE ROAD HOUSTON, TEXAS 77043 (713) 467-7011 CONFIDENTIAL FEBRUARY 198‘ t-iOUSTON LEWELLING J O B NUMBER 3620 LITHO LOG 0 SUMMRRY FIGURE - HI % TOC 100 ! I"" 600 0 t I ""_ GLORIETR ""_ YESO? ""_ I I I ""_ I I I I I I I I I I ""_ CISCO ""_ I I I I I I I I I I I I I I I I I I I I I I I I I I I I I 1 I 1 .I I 1 I I I I I I I I I I I I I I I I I I I I I 1 1 1 1 I 1 I 1 I I I 1 I 1 1 1 I 1 I I I I I 1 I I I I 1 I I 1 1 1 1 1 1 1 I I I I I 1 I 1 I I I I I I I I I I I I I I I I I I I I I I I I I I I 1 1 I 1 I I I I I I I I 600 0 30t I I I I I 1 1 I I I 1 I I I I I I I I I 1 I I I I I I I I I 1 I I I 1 I I I I I 1 I I I I I I 1 1 1 I I 1 1 1 1 1 I 1 I 1 I I I I I I I 1 1 1 1 I I I I I I I 1 I I I 1 I 1 I I I I I 1 I 1 I I I "r- 1 I I I I I 1 I I I I -I-" i L 1 I I I I I I I I I I I 1 I I I I -E4 ER5Q I I I I MONTOYA ""_ 1 I I I 1 I I I I I 1 I I I I I I I I I I I I I I I I 1 ' ' I I I I I 1 I I I I I I 1 1 I 1 I I I I I I 1 I I I ""_ ""_ 1 I I I I I I I I I 1 I - EISZ 1 I I I RTOKR? ""_ + KEROGEN 0 100 I I I I I I 1 1 I 1 STRRWN I S2/S3 1 1I I 1 I I I ""_ 100 1 I 1 I 1 1 1 I I I I I I I I I CRNYON 0 I I I I I 1 I I I WOLFCRMP I 1 I I I 1 I RBO 301i I I I I I 1 I SRN RNDRE 01 HC Y I EL0 I 250I; +"-L- : 250k I I I I I I I I I I -"r- 11i 0 100 NEW MEXICO BYDROCARBON SOURCE ROCK EVALUATION WELL NAME: API NO. : AREA: LOCATION: GEOCHEM J O B NO.: TOTAL DEPTH: INTERVAL SAMPLED: TOTAL NUMBER OF SAMPLES: HOUSTON O I L & MINERALS. N O . l LEWELLING 30-035-20010 SOUTHEAST OTERO COUNTY, NEW MEXICO SEC.12, T12S, R9E 3620 9358 f t . 870-9250 f t . 24 7-GEOCHEM SAMPLE NUMBER LYSES 4> SAMPLE DEPTH STRATIGRAPHIC INTERVAL ' t q z 8 z - E l.7C c) 0 I X X X X X X X X X X X X X X X X X X X X X X X X x x x x x x x x x x x x x x x x x x x x x x x x r7 3620-001 3620-002 3620-003 3620-004 3620-005 3620-006 3620-007 3620-008 3620-009 3620-010 3620-011 3620-012 3620-013 3620-014 3620-015 3620-016 3620-017 3620-018 3620-019 3620-020 3620-021 3620-022 3620-023 3620-024 870-920 1400-1450 2100-2150 2960-3000 6130-6170 6590-6640 6860-6910 6940-6970 7020-7060 7350-7380 7580-7620 7800-7830 7850-7880 8020-8050 8130-8170 8200-8230 8280-8310 8360-8390 8450-8490 8710-8750 8810-8820 8900-8930 9100-9140 9220-9250 San Andres San Andres Yeso Yeso Wolfcamp Wolfcamp Cisco Cisco Cisco Canyon Canyon Strawn Strawn Strawn Strawn Strawn A t oka Atoka Atoka Mississippian Devonian Fusselman Montoya L s . E l Paso L s . X X X X X X X. X X X X X X X X X X X X X X X X X - x x x x x x x x x x x x x x x x x x x x x x x x .' TABLE I RESULTS OF TOTAL ORGANIC CARBON NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION HOUSTON O I L h MINERALS, N O . l LEWELLING SEC.12, T l Z S , R9E, OTERO COUNTY, N E W MEXICO APT #3o-035-20010 GEOCAEM SAMPLE NUMBER 3620-001 3620-002 3620-003 3620-004 3620-005 3620-006 3620-007 3620-008 3620-009 3620-010 3620-011 3620-012 3620-013 3620-014 3620-015 3620-016 3620-017 3620-018 3620-019 3620-020 3620-021 3620-022 3620-023 3620-024 Y Y - DEPTH INTERVAL (feet) TOTAL ORGANIC 870-920 1400-1450 2100-2150 2960-3000 6130-6170 6590-6640 6860-6910 6940-6970 7020-7060 7350-7380 7580-7620 7800-7830 7850-7880 8020-8050 8130-8170 8200-8230 8280-8310 8360-8390 8450-8490 8710-8750 8810-8820 8900-8930 9100-9140 9220-9250 0.19 0.47 0.31/0.33 0.20 0.06 0.24 0.34 0.65 0.14 0.13 0.20 0.20/0.22 0.41 0.32 0.34 0.13 0.18 0.28 0.36 0.13/0.14 0.98 0.04 0.04 0.07 CARBON ( X of Rack) TABLE I1 LITHOLOGICAL DESCRIPTIONSAND ORGANIC CARBON ANALYSES NEW MEXICO HYDROCARBON SOURCE ROCK EVALITATION HOUSTON OIL & MINERALS, NO.l LEWELLING SEC.12, TIZS, R9E, OTERO COUNTY, NEW MEXICO API #30-035-20010 DEPTB GEOCEEM SAMPLE - h"BER INTERVAL (feet) 3620-001 870-920 -A 3620-003 -A -C N4 to 2100-2150 N2 0.31/0.33 75% Limestone, fine crystalline, medium dark gray to grayish N4 to black. 25% Sandstone, slightly calcareous, veryfine grained, white (cave). N9 2960-3000 gray. -B 1OR-416 0.47 100% Limestone, fine crystalline, medium dark gray to grayish black. Trace red mudstone. -A N3 10YR-612 to 10YR-412 1400-1450 -B 3620-004 ORGANIC CARBON (wt . X ) 0.19 85% Limestone, fine crystalline, pale yellowish brown to dark yellowish brown. 15% Mudstone, calcareous, brown moderate reddish (cave). Trace dark gray shale. -B 3620-002 -A LITHO DESCRIPTION GSA NO. N2 0.20 90% Limestone, fine crystalline, dark 5% Sandstone, slightly calcareous, veryfine grained, white (caved). N9 5% Mudstone, calcareous, moderate reddish brown 10R-4/6 (cave). TABLE I1 (continued) LITHOLOGICAL DESCRIPTIONSAND ORGANIC CARBON ANALYSES NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION HOUSTON OIL h MINERALS, NO.l LEWELLING SEC.12, T12S, R9E, OTERO COUNTY,NEW MEXICO API #30-035-20010 GEOCHW SAHPLE NUMBER 3620-005 DEPTH INTERVAL (feet) 6590-6640 3620-007 6860-6910 gray. 0.65 95% Limestone, fine crystalline, dark 5% Mudstone, calcareous, moderate reddish brown 10R-416 (cave). 0.14 7020-7060 100% Limestone,fine crystalline, to dark mediumlightgray gray. Trace red mudstone. -A -B 0.34 6940-6970 -A -A 0.24 to 95% Limestone, fine crystalline, N9 to white to gray. dark N3 5% Mudstone, calcareous, moderate reddish brown 10R-416 (cave). -B 3620-010 N9 to 100% Limestone, fine crystalline, N9 gray. dark N3 white to Trace red mustone. -A 3620-009 .%) 0.06 100% Limestone, fine crystalline, white to N3 gray. dark Trace red mudstone. 3620-006 -A N3 -B (wt 6130-6170 -A 3620-008 LITHO DESCRIPTION ORGANIC CARBON GSA NO. N6to N4 0.13 7350-7380 90% Limestone, fine crystalline, mediumlightgray to dark gray. 10% Mudstone, calcareous, moderate reddish brown 10R-416 (cave). N6to N4 TABLE 11 (continued) LITHOLOGICAL DESCRIPTIONS AND ORGANIC CARBONANALYSES NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION HOUSTON O I L & MINERALS, NO.l LEWELLING SEC.12, T12S, R9E, OTERO COUNTY, NEW MEXICO API #30-035-20010 GEOCHEM INTERVAL SAMPLE ROMBER DEPTE (feet) 7580-7620 3620-011 -A LITE0 DESCRIPTION ORGANIC CARBON GSA NO. (wt 0.20 gray. -B 95% Limestone, fine crystalline, medium light gray N6 to to dark N4 5% Mudstone, calcareous, moderate reddish brown 10R-4/6 (cave). Trace wood fibers. 7800-7830 3620-012 0.20/0.22 -A gray. 100% Limestone, fine crystalline, medium light gray to N6 to N4 dark Trace red mudstone. 0.41 7850-7880 3620-013 -A gray. -B 95% Limestone, fine crystalline, medipm light gray to N6 to dark 5% Shale, noncalcareous, pyritic, grayish black. N2 Trace red mudstone. N4 8020-8050 3620-014 0.32 -A gray. -B 8130-8170 3620-015 -A N4 -B .%) 95% Limestone, fine crystalline, N6 to medium light gray to dary N4 5% Shale, noncalcareous, pyritic, grayish black. N2 Trace wood fragments. 0.34 gray. 95% Limestone, fine crystalline, medium light gray N6 to dark 5% Shale, noncalcareous, pyritic, grayish black. N2 Trace red mudstone. to TABLE I1 (continued) LITHOLOGICAL DESCRIPTIONSAND ORGANIC CARBON ANALYSES NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION HOUSTON OIL & MINERALS, NO.l LEWELLING SEC.12, T12S, R9E, OTERO COUNTY,NEW MEXICO API #30-035-20010 GEOCHEM SAMPLE NUMBER 3620-016 DEPTH IM'ERVAL (feet) 8200-8230 -A 3620-017 DESCRIPTION LITHO GSA (wt NO. 3620-018 -A 8360-8390 3620-019 8450-8490 .%) 0.13 100% Limestone, fine crystalline, white to medium gray. N5 N9 to 100% Limestone, fine crystalline, white to medium gray. N5 Trace wood fragments. N9 to 8280-8310 -A ORGANIC CARBON 0.18 0.28 100% Limestone, fine crystalline, mediumlightgray to dark N6 to N4 gray. Trace red mudstone. 0.36 -A 60% Limestone, fine crystalline, mediumlightgray to darkN6to -B 40% Shale, calcareous, pyritic, gray. N4 micaceous, grayish black. N2 Trace red mudstone. 3620-020 -A 8710-8750 3620-021 8810-8820 -A -B C.13/0.14 100% Limestone, fine crystalline, N9 to gray. N5 white t o medium Trace red mudstone. 0.98 95% Shale, noncalcareous, micaceous, grayish black. N2 5% Limestone, fine crystalline, N9 to white to medium gray. N5 Trace red mudstone. TABLE I1 (continued) LITHOLWICAL DESCRIPTIONS AND ORGANIC CARBON ANALYSES NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION HOUSTON O I L & MINERALS, NO.l LEWELLING SEC.12, T12S, R9E, OTERO COUNTY, N E W MEXICO API #30-035-20010 GEOCHEH SAMPLE DEPTH INTERVAL R[IMBER (feet) LITHO DESCRIPTION GSA NO. 89090-8930 3620-022 -A 9100-9140 3620-023 -A 9220-9250 3620-024 -A ." Y ORGANIC CARBON (wt . X ) 0.04 100% Dolostone, fine crystalline, white to medium gray. N9 to N5 0.04 100% Dolostone, fine crystalline, white to medium gray. N5 100% Dolostone, fine crystalline, white to medium gray. N9 to N5 N9 to 0.07 - TABLE 111 Sm(luRY OF ORGANIC CAE3ON Am) VISUAL KEROGEN DATA NEd MEXICO HYDROCARBON SOURCE ROCK EVALUATION HOUSTUN OILS h MINERALS, N0.1 LEWELLING SEC.12, TIZS, R9E, DTERO COUNTY, NEU MEXICO API 830-035-20010 TOTAL ORGANIC ORGANIC UATTER CARBON 3620-001 3620-002 3620-003 3620-004 3620-005 3620-006 3620-007 3620-008 3620-009 3620-010 3620-011 3620-012 3620-013 3620-014 3620-015 3620-016 3620-017 3620-018 3620-019 3620-020 3620-021 3620-022 3620-023 3620-024 870-920 1400-1450 2100-2150 2960-3000 6130-6170 6590-6640 6860-6910 6940-6970 7020-7060 7350-7380 7580-7620 7800-7830 7850-7880 8020-8050 8130-8170 8200-8230 8280-8310 8360-8390 8450-8490 8710-8750 8810-8820 8900-8930 9100-9140 9220-9250 0.19 0.47 0.31/0.33 0.20 0.06 0.24 0.34 0.65 0.14 0.13 0.20 0.2010.22 0.41 0.32 0.34 0.13 0.1R 0.28 0.36 0.1310.14 0.98 0.04 0.04 0.07 TYPE A-1;W;h;R-W;I A-I.-.hr*-W * I A;I;Am €l;1;- W-I;A;W-I;H;Am"* W-1;H;R-I;-;W !+I;R;- W-I;H;A-I;-;W H-1;W;W-1;H;W-1;H;H-I;Am**-W;w1;w;W-I;H;W-1;H;A-I;h";W Am*;H-I;W h"*;H-I;- .. Am";-;R-I h**.-.A-I T T VISUAL ABIIADANCE NOW - AI lim B I - - - - 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 - 0 45 10 12 0 0 9 0 0 0 0 0 0 0 0 17 0 0 0 22 44 50 68 68 - 40 22 40 50 57 20 19 20 44 28 20 44 40 20 20 33 40 20 20 33 22 25 16 16 t 20 22 10 0 0 40 36 40 12 36 40 12 20 40 40 17 20 40 40 12 12 0 0 0 40 I1 40 38 43 40 36 40 44 36 40 44 40 40 40 33 40 40 40 33 22 25 16 16 ALTERATION STAGE 2 7 -37+ -3 -33 -3 -33 -3 3 3 3 3 3 3 3 3 3 3 3 3 to to ALTERATION 2' 2+ to 3to 3+ t o 3+ to 3+ t o 3, LO 3c to 3c t o 3+ to 3r to 3+ .to 3+ to 3.1 to 34 LO 3+ to 3c to 3' to 3' to 3+ to 3+ to 3+ t o 3+ 2.6 2.7 3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.5 3.6 3.6 3.6 3.6 3.6 3.6 3.7 3.7 3.6 3.6 3.6 3.6 - - - LEGEND: AI KEROGEN KEY Predominant; 60-1002 Secondary; 20-40% h Am" Trace 0-207, H R* W u I C AlWl Amorphoue-Saprope1 Relic Amorphous-Sapropel Herbeceous-SporelPoll~~ Degraded Herbaceoue Woody-Structured Unidentified Haterial Inertinite Coal y 1 1 RHSIIITS OF RCCK-EVAL PYROLYSIS ANALYSIS NEW MEXICO HYDROCARBON SOVRCE ROCK NALUATlON HOUSTON OIL h HINERALS. NO.l LEUELLlNG SEC.12, T12S, R9E, OTERO COUNTY, NEW MEXICO API 830-035-20010 GEOCAW DEPTFi SAMPLE IRTERVAL OXYGER UOIBER (Feat) IADEX 870-920 1400-1450 2100-2150 2960-3000 6130-6170 6590-6640 6860-6910 6940-6970 0.09 7020-7060 7350-7380 7580-7620 7800-7830 7850-7880 8020-8050 0.02 8130-8170 0.02 8200-8230 8280-8310 8360-8390 8450-8490 8710-8750 8810-8820 8900-8930 9100-9140 9220-9250 0.03 3620-001 3620-002 3620-003 3620-004 3620-005 3620-006 3620-007 3620-008 3620-009 3620-01 0 3620-011 3620-012 3620-013 3620-014 3620-015 3620-016 3620-017 3620-018 3620-019 3620-020 3620-021 3620-022 3620-023 3620-024 T.O.C. SI S2 -- 436 421 275 321 266 275 320 296 236 268 241 245 210 217 192 0.02 0.08 0.03 0.09 0.03 0.05 0.00 0.00 0.03 0.05 0.15 0.05 0.02 0.03 0.07 0.02 0.00 0.05 0.03 0.00 0.08 0.07 0.02 0.01 0.00 0.02 0.03 0.00 0.02 0.01 0.48 0.32 316 275 199 229 0.50 0.50 0.83 0.50 0.1s 1.oo 0.16 0.35 0.42 0.47 0.58 0.58 0.55 0.56 0.50 0.50 0.38 0.28 0.35 ~~ 0.02 0.02 0.17 0.10 0.00 0.02 0.00 0.00 0.00 Total organiccarbon, wt.% Free hydrocarbone, mg Ecfg of rock = Residual hydrocarbon potential (mg ACfg or rock) 0.48 0.36 0.33 0.35 s3 PC* - 0.60 0.24 0.48 0.32 .oo = 0.083 (SI + 52) = mg HCfg organic carbon 0.01 0.00 0.00 0.00 0.00 0.01 0.00 0.62 0.00 1.oo 0.87 0.00 0.00 1.00 0.00 0.50 0.50 0.01 0.50 0.75 0.75 0.50 0.65 0.98 0.00 1 .oo 1 .oo 0.19 0.47 0.32 0.20 0.06 0.24 0.34 0.65 0.14 0.13 0.20 0.21 0.41 0.32 0.34 0.13 0.01 1 .oo C02 produced from kerogen pyrolysis ( m g C02lg of rock) Hydrogen Index 1 0.70 0.64 0.00 0.00 0.00 0.00 0.00 0.18 0.00 0.00 0.00 0.02 0.00 0.00 0.00 0.28 0.36 0.14 16 19 9 25 0 0 9 8 0 23 0 5 0 6 9 0 11 4 6 14 10 0.04 0.04 0.07 oxygen Index PI TMAX -- 0 0 0 25 77 103 175 300 67 I03 65 336 446 290 262 137 156 147 292 156 I25 133 229 61 600 1200 800 mg COZlg organic carbon S I I S I + s2 = Temperature Index. degrees C. I t t LEGEND FOR SUMMARYDIAGF"AM DEPTH: LLTHO LOG: in feet see lithology symbols STRATIGRAPHY: by age percent total organic carbon % TOC: Rock-Eval, Hydrocarbon Index= LOO S2(0/00 Wt)/TOC HI : Rock-Eval, Oxygen Index= 100 S3 ( O / O O Wc)/TOC 01 : Rock-Eval, S2 peak (ppm) HC YIELD: Rock-Eval, Racio of S 2 co 53 peak s2/s3: see Kerogen symbols KEROGEN: Rock-Eval, maximum temperature of5 2 peak, in degrees Centigrade T-MAX : Vitrinice Reflectance (scale0 to 5 ) -A ): Thermal Alteration Index (Scale1 co 5) TAI Rock-Eval, S I peak (pprn) FREE HC: Rock-Eval, Productivity Index= Sl/(SI+S2) PI : - - KEROGEN TYPES LITH.OLOGIES "" SHALE SILICEOUS ROCKS MUDSTONE EVAPORITES SILTSTONE COAL SANDSTONE IGNEOUS ROCKS CONGLOMERATE VOLCRNICS BRECCIA ROCKSMETAMORPHIC LIMESTONE DOLOMITE I L AA MARL BASEMENT I OTHER MISSINGSECTION "" AMORPHOUS I HEREQCEOUS ] p _..__.. i woooy INEKTINITE Y