New Mexico Bureau of Mines & Mineral Resources
Socorro. N M 87801
A DIVISION OF
NEW MEXICO INSTITUTE OF MININO & TECHNOLWY
Infomi~stim: 5051835.5420
Publication$: 5051835-5410
Open-FileReport
311
HYDROCARBON SOURCE ROCK EVALUATION,
STANDARD
OF
TEXAS
10-1 LILLIAN COLL,
SEC. 10, T16S, R31E, EDDY COUNTY, NEW MEXICO
By G.S.
B a y l i s s and R.R.
Schwarzer
October 1987
NEW MMICO TECH IS AN EQUAL OPPORTUNtTYlAWRNIATlVEACTION INSTINTION
-"
NEW MEXICO BUREAU OF MINES AND
MINERAL RGSOURCES open-file
-"
report 311
-"
U
T
NEW MEXICO HYDROCARBON SOURCE
ROCK EVALUATION PROJECT
STANLlABD OF TEXAS 10-1 LILLIAN COLL
SEC.10, T16S, MIE, EDDY C O W , AEW MEXICO
API
30-015-04839
SOUTBEAST-C AREA
GEOCEEM JOBNO. 3579
NO.
T
Prepared
for
PROGRAM PARTICIPANTS
T
Dr. Geoffrey S . Bayliss
and
Dr. Rudy R. Schwarzer
GEOCHEM LABORATORIES, INC.
1143°C BRITTMOORE ROAD
HOUSTON, TEXAS 77043
(713) 467-7011
CONFIDENTIAL
OCTOBER' 1987
AEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION
WELL NAME:
API NO.:
STANDARD OF TEXAS, 10-1 LILLIAN
COLL
AREA:
SOUTHEAST-C
EDDY COUNTY, NEW MEXICO
30-015-04839
LOCATION:
GEOCHEM JOB NO. :
TOTAL DEPTH:
INTERVAL SAMPLED:
TOTAL NUMBER OF SAMPLES:
3579
13400 ft.
6470-13120
19
SEC.lO, T16S, R31E
ft.
LYsES
-
I
GEOCHEM
SAMPLE
NUMBER
4
$EA'$
STRATIGRAPHIC
INTERVAL
I
v)
E
I E H
c7
3579-001
3579-005
3579-006
3579-009
3579-010
3579-011
3579-013
3579-017
3579-018
3579-019
6470-6520
6520-6570
9750-9800
10300-10350
10580-10630
10630-10690
11050-11090
11100-11130
11450-11500
11500-11550
11550-11600
11860-11900
11900-11930
11930-11960
11960-12000
12250-12300
12390-12440
13070-13090
13090-13120
Tubb
3579-002
Tubb
3579-003
Wol€camp
3579-004
Cisco
Canyon
Canyon
3579-007
Canyon
3579-008
Canyon
Atoka
Atoka
Atoka
3579-012
Morrow
Morrow
3579-014
Morrow
3579-015
Morrow
3579-016
Mississippian
Mississippian
Woodford
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
5I
E
2
-
x
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
2;
w
c9
g
I
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
4
w
aL
"7
6
H
LL
QL
a
2
>.
"7
I
I
I
"
4
I
I
It
I
I
,
I
I
I
I
I
- -.- - . . - -
I
I
"
-
I
II
II
-
7
4
m
m
m
m
-
- m
-rn
m
- .--Ln
x-
----
1
m
II ,
4
4
Ill
4
11
"""""
"
#&_"Ks-~.-~-~""x.rc
"""""""_
........................
I
I
cn
"""""""""""""
I
"-~"""""""""""-
vm
-
co
m
x m -""""""""""~"""""""""""""""""
urn -
z
m
I
-
I
m
m""""""""""""~"""-
0
\
c\I
I1
cn
m
co
-.
TABLE I
-.
BESULTS OF TOTAL ORGANIC
-.
CARBON
NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION
STANDARD OF TEXAS, 10-1 LILLIAN COLL
SEC.lO, T16S, R31E, EDDY COUNTY, NEW MEXICO
API #30-015-04839
GEOCAEH
SAMPLE
NUMBER
3579-001
3579-002
3579-003
35 79-004
3579-005
3579-006
3579-007
0.53
3579-008
3579-009
3579-010
3579-011
3579-012
3579-013
3579-014
3579-015
3579-016
3579-017
3579-018
3.48
3579-019
DEPTE
INTERVAL
TOTAL ORGANIC
(feet)
( %of Rock)
CARBON
6470-6520 0.51
0.40
0.35b1.34
1.66
0.63
0.71
6520-6570
9750-9800
10300-10350
10580-10630
10630-10690
11050-11090
11100-11130
11450-11500
11500-11550
11550-11600
11860-11900
11930-11960
11960-12000
12250-12300
12390-12440
13070-13090
13090-13120
.
0.78
0.79i0.81
0.69
0.84
1.87
11900-119301.23
4.61
1.99
1.53
0.86/0.83
3.77
TABLE I1
LITHOLOGICAL
DESCRIPTIONS
AND ORGANIC
N E W MEXICO
CARBON
ANALYSES
HYDROCARBON SOURCE
ROCK EVALUATION
STANDARD OF TEXAS, 10-1 LILLIAN COLL
SEC.10, T16S, R31E, EDDY COUNTY,
NEW MEXICO
API #30-015-04839
DEPTH GEOCEEM
SAMPLE
NUMBER
3579-001
INTERVAL
(feet)
LITHO DESCRIPTION
-A
-B
3579-004
-A
-B
3579-005
-A
-B
3579-006
0.51
6520-6570
0.40
100% Dolomite, fine crystalline,
pale
yellowish
brown.
lOYR
9750-9800
0.3510.34
10300-10350
1.66
55% Shale, calcareous, dark gray. N3
45% Limestone, fine crystalline,
N8 gray.
light
very
10580-10630
0.63
70% Shale, calcareous, dark
gray.
30% Limestone, fine crystalline,
N8 gray.
light
very
10630-10690
N3
0.71
80% Shale, slightly calcareous,
gray.
3579-007
-A
N3
-B
612
95% Shale, calcareous, dark
gray.
N3
5% Limestone, fine crystalline,
N8 gray.
lightvery
-A
-B
.%)
100% Dolomite, fine crystalline,
yellowish
palebrown.
1OYR-612
-A
3579-003
(wt
6470-6520
-A
3579-002
ORGANIC
CARBON
GSA
NO.
dark
N3
20% Limestone, fine crystalline,
gray.
lightvery
N8
11050-11090
55% Shale, slightly calcareous,
gray.
dark
45% Limestone, medium crystalline,
N8 gray.
light
very
0.53
TABLE I1 (continued)
LITHOLOGICAL
DESCRIPTIONS
AND ORGANIC
CARBON
ANALYSES
NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION
STANDARD OF TEXAS, 10-1 LILLIAN COLL
SEC.lO, T16S, R31E, EDDY COUNTY, NEW MEXICO
AF’I $30-015-04839
GEOCEEM
INTERVALSAMPLE
NUMBER
3579-008
-A
DEPTE
(feet)
11100-11130
11450-11500
-A
-B
3579-010
-A
0.7910.81
90% Shale, slightly calcareous,
dark gray.
N3
10% Limestone, fine crystalline,
dark yellowish brown.
1OYR-412
0.69
80% Shale, slightly calcareous,
dark gray.
N3
20% Limestone, fine crystalline,
very light gray.
N8
11550-11600
-A
0.84
90% Shale, slightly calcareous,
dark gray.
N3
10% Limestone, fine crystalline,
very light gray.
N8
-B
3579-012
11860-11900
1.87
-A
70% Shale, noncalcareoua, dark
-B
N3
gray.
30% Limestone, fine crystalline,
very light gray.
N8
3579-013
-A
-B
(wt . X )
0.78
11500-11550
-B
3579-011
CRGANIC
CARBON
80% Shale, slightly calcareous,
gray.wish
darkbrown.
N3
20% Limestone, medium crystalline,
N8
very light gray.
-B
3579-009
LITHO DESCRIPTION
GSA
NO.
11900-11930
1.23
85% Shale, noncalcareous, dark
N3
gray.
15% Limestone, fine crystalline,
very light gray.
N8
TABLE I1 (continued)
LITHOLOGICAL DESCRIPTIONS AND ORGANIC CARBON ANALYSES
NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION
STANDARD OF TEXAS, 10-1 LILLIAN COLL
NEW MEXICO
SEC.lO, T16S, R31E, EDDY COUNTY,
API 830-015-04839
DEPTH GEOCHEM
SAMPLE
NUMBER
3579-014
-A
INTERVAL
(feet)
11930-11960
3579-017
-A
12250-12300
N3
12390-12440
0.86/0.83
95% Shale, noncalcareous, dark
N3
gray.
5% Limestone, fine crystalline,
N8
very light gray.
13070-13090
3.48
95% Shale, noncalcareous,
brownish black.
5YR-211
5% Limestone, fine crystalline,
N8
very light gray.
-B
-A
1.53
100% Shale, noncalcareous, dark
gray.
-A
3579-019
1.99
90% Shale, noncalcareous, dark
N3
gray
10% Limestone, fine crystalline,
very light gray.
N8
-B
3579-018
(wt . X )
4.61
11960-12000
-B
3579-016
-A
ORGANIC
CARBON
95% Shale, noncalcareous, dark
N3
gray.
20% Limestone, fine crystalline,
very light gray.
N8
-B
3579-015
-A
LITHO DESCRIPTION
GSA
NO.
13090-13120
3.77
100% Shale, noncalcareous,
brownish black.
5YR-211
4
4
4
4
4
4
5
4
4
4
d
d
i
i
TABLE 111
S
W
Y
OF ORGANIC
CARBONAAI) VISUAL KERCGEM DATA
NEW HexIC0 HYDROCARRON SOURCE ROCK EVALUATION
STANDAUD OF TEXAS. 10-1 LlLLlAN COLL
.
SEC.lO, T16S, R31E, EbDY~COUNTY,NEW KEXlCO
API #30-015-04839
~~~~~
PXAL
ORGANIC
CARBON
ORGANIC l!L4ITBR
TYPE
~~~
3979-001
3579-005
3579-006
3579-007
3579-008
3579-009
3579-010
3579-011
3579-015
3579-016
3579-017
3579-018
3579-019
6470-6520
10630-10690
11550-11600
11860-11900
11900-11930
11930-11960
11960-12000
12250-12300
12390-12440
13070-13090
13090-13120
0.51
0.40
0.35/0.34
1.66
0.63
0.71
0.53
0.78
0.79f0.81
0.69
1.99
1.53
0.86f0.83
3.48
3.77
~
Awn*;-;-
~~
Tt
VIS
50
37
22
38
0
10
W-I;H;Am*
0
0
0
0
0
0
0
AOrR*;1;w
0
Am-E*;I;-
0
8
23
0
20
0
33
15
31
40
H;Am*;W-I
A*;h;W
n;w-1:-
H;W-I;-
n;w-1;Am*
A-W;I;Am*
H;W-I;Am
A;W-I;Am
A;W-I;Am
H;AnrW;I
H;W-I;A;Anrl;W
A;W;T
Am”A;U-I;-
L
mu
LACE
-
0
0
13
15
8
I3
W
50
63
56
50
46
46
33
31
42
50
42
39
60
50
50
33
23
31
40
0
0
11
12
27
27
27
31
25
20
25
23
20
10
30
17
31
15
0
t
0
0
11
0
27
27
27
23
25
20
25
15
20
20
20
17
31
23
20
----
LEGEND:
Al
KEROGEN KEY
Predominant; Secondary; Trace
60-100%
20-40%
0-20%
mm
R a w IzgD E T Am
I
- - -- 0
0
0
0
0
0
0
0
0
n;Am;-
~~
AL’CERATIOII
STAGK
ALTERATION
2- to 2
2- to 2
2 to T+
2 to 2+
2 to 2+
2 to 2+
2 to 2+
2 to 2+
2 to 2+
2 to 2+
2 to ?+
2 to 2’
2 to 2’.
2 to 2’
2+
2+
2+
2+ to 32+ to 3-
2.1
2.1
2.3
2.3
2.3
2.3
2.4
2.4
2.5
2.5
2.5
2.5
2.5
2.5
2.6
2.6
2.6
2.7
2.7
-
-
-
-
INDEX
Algal
Amorphous-Sapropel
Relic Amorphous-Sapropel
Herbafeous-SporefPollen
Degraded Herbaceous
Woody-Structured
Unidentified Material
Inertinice
Cody
i
j l
L
L
L
4'
4
4
4
4
4
4
4
4
4
4
4
TABLE I V
RESULTS OF ROCK-BVAL PYROLYSIS
ACW MEXICO A Y D R O W O N
ANALYSIS
SOURCE ROCK EVALUATION
STANDARD OF TEKAS, 10-1 LILLIAN COLL
SEC.lO, T165, R31E, EDDY COUNTY, NeW HEXlCO
AP1 #30-015-04839
~~
~
6470-6520
6520-6570
9750-9800
10300-10350
10580-10630
10630-10690
11050-11090
11100-11130
11450-11500
11500-11550
11550-11600
11860-11900
11900-11930
11930-11960
11960-12000
12250-12300
12390-12440
~~~.
.
..
13070-13090
13090-13120
3579-001
3579-002
3579-003
3579-004
3579-005
3579-006
3579-007
3579-008
3579-009
3579-010
3579-011
3579-012
3579-013
3579-014
3579-015
3579-016
3579-017
3579-018
3579-019
T.O.C.
S1
52
-
427
430
428
444
439
442
436
437
439
443
443
446
455
452
455
442
436
434
438
0.27
0.22
0.04
0.67
0.12
0.03
0.11
0.12
0.20
0.17
0.09
0.34
0.11
1.19
0.26
0.31
0.19
Residual
hydrocarbon
potential
(mg HCIg orHydrogen
rock)
0.81
3.97
4.72
1.36
1.68
= Total organic carbon, w t . Z
Free hydrocarbons, mg Hclg of rock
=
0.74
0.53
0.10
1.98
0.49
0.30
0.47
0.56
0.53
0.36
0.41
1.78
0.62
5.00
1.30
1.80
53
0.51
0.50
0.99
0.54
0.34
0.48
0.46
0.48
0.44
0.55
0.45
0.43
0.42
0.50
0.56
0.53
0.40
0.56
0.67
0.27
0.30
0.29
0.25
0.20
0.09
0.19
0.18
0.04
0.28
0.33
0.18
0.16
0.15
0.19
0.17
0.15
0.19
0.26.
0.26
COZ produced from kerogen pyrolysis
(wCO2/g
PC*
~~
=
of rock)
0.083 (SI + SZ)
0.08
0.06
0.51
0.40
0.35
1.66
0.63
0.01
0.22
0.05
0.02
0.04
0.05
0.06
0.71
0.53
0.78
0.80
0.69
0.84
1.87
1.23
4.61
1.99
1.53
0.85
3.48
3.77
0.04
0.17
0.06
0.51
0.13
0.1 7
0.08
0.44
0.53
Oxygen
Index
PI
"X
lndex
= mg RC/g organic carbon
--
145
132
28
119
77
42
88
71
66
52
48
95
50
108
65
117
95
114
125
100
125
282
32
53
67
86
61
55
79
53
22
34
10
28
34
47
16
17
rg C 0 2 l g organic carbon
S 1 I S 1 + 52
TemperatureIndex,degrees
C.
LEGEND FOR
SUMMARY
DIAGRAM
U.
m
DEPTH :
LITHO LOG:
in feet
see lithology symbols
STRATIGRAPHY: by age
% TOC:
percent total organic carbon
= 100 S2(0/00 Wt)/TOC
Rock-Eval,
Hydrocarbon Index
HI :
=
100
53 (O/OO Wt)/TOC
Rock-Eval,
Oxygen
Index
01:
Rock-Eval, S 2 peak (ppm)
AC YIELD:
Rock-Eval, Ratio ofS2 to 53 peak
see Kerogen symbols
KEROGEN:
T-MAX :
Rock-Eval, maximum temperature of S2 peak, in degrees Centigrade
-A,:
Vitrinite Reflectance (scale 0 t o 5 )
rn
Thermal Alteration Index (Scale 1 5)to
Rock-Eval, SI peak (ppm)
FREE HC:
Rock-Eval, Productivity Index= SI/(SI+S2)
PI :
-
-
KEROGEN TYPES
LITHOLOGIES
"
SHALE
SILICEOUS ROCKS
MUDSTONE
EVAPORITES
11- -_- SILTSTONE
IGNEOUS
a
""." WOODY
m
COAL
'
SANDSTONE
ROCKS
VOLCRNICS
CONGLOMERATE
METAMORPHIC
BRECCIA
BASEMENT
ROCKS
LIMESTONE
DOLOMITE
1E
-A
.L
.L
MARL
I
!
OTHER
D<IMISSING
AMORPHOUS
0HERBRCEOUS
SECTION
INERTINITE
."
."