New Mexico Bureau of Mines & Mineral Resources Socorro. N M 87801 A DIVISION OF NEW MU(IC0 INSTITUTE OF MINING TECHNOLOGY Open-File Report 317 HYDROCARBON SOURCE ROCK EVALUATION OF CASTLE & WIGZELL, NO. 1 KELLY FEDERAL, SEC. 11, TZON, R9E, SANTA FE COUNTY, NEW MEXICO By G.S. Bayliss and R.R. Schwarzer January 1988 NEW MEXICO TECH IS AN EQUAL OPPORTUNllYlAFFlRMATIM ACTION lNSTl"I0N r r I" I" r r I* r r r r r r r r F Y NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION PROJECT CASTLE 6 WIGZELL, NO. KELLY FEDERAL S E C . l l , TZON, R9E. SANTA FE CO., NEW MEXICO API NO. 30-049-05001 N O R ~ S AREA T GEOCBEM JOB NO. 3611 Prepared for PROGRAM PARTICIPANTS Dr. Geoffrey S . Bayliss and Dr. Rudy R. Schwarzer GEOCHEM LABORATORIES, INC. 1143-C BRITTMOORE ROAD HOUSTON, TEXAS 77043 (713) 467-7011 CONFIDENTIAL JANUARY 1988 NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION WELL NAME: API NO.: AREA: LOCATION: GEOCHEM JOB NO.: TOTAL DEPTH: INTERVAL SAMPLED: TOTAL NUMBER OF SAMPLES: CASTLE 6 WIGZELL, NO.l KELLY FEDERAL 30-049-05001 NORTHWEST SANTA FE COUNTY,NEW MEXICO SEC.ll, TZON, R9E 3611 2703 f t . 302-2695 f t 4 . f GEOCHEM SAMPLE NUMBER SAMPLE DEPTH STRATIGRAPHIC INTERVAL U 2 H 8 tl 3611-001 3611-002 361 1-003 3611-004 302-383 850-950 2500-2600 2600-2695 Tertiary Tertiary Pennsylvanian Pennsylvanian X X X X X X X X 4 w CLL 3 0 H I" 1- #a M U e m I - I I I m - b -m - . - """""""""""""""""""""""""""" b - m I a"- "_" ~~ __ ---~ ~ I .~ I - .~ - Lo 4 ~ m - m m -m - - m cr) -Lo m 4 m N - m -Ln m m w m -co - m m m m - m m "" "_ - - - - - x___ -x-" I I I I I I m -19 I m m - m I " " . = . . . " " - """"""""i"""""""""""""""""""- - - " -- - - - - -E.---- - I - 1 I I I 1 I ~ - W L n LLJON Lo m u . 1 k a u m nL - b? m ~~ m xa m ----"------"""""""""""""-"""""" z 07 1 _""_" " " " " " " " " " " I ~"_""""""""""""""""""""""""" LE: m m-- co \ N cn m 0: m I ............................ - I ........................... ~""""""""""""""""""----""------"--- m m w ~ m 19m """""""""-"""""""-----"-----"""- m qjnJ =I-+ > 0 Tr m 1 0 O Ibe m I -x v 6-4 Ci F TABLE' I RESULTS OF TOTAL ORGANIC CARBON NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION r r r I r Y Y Y CASTLE & WIGZELL, N O . l KELLY FEDERAL TZON, R9E, SANTA FE COUNTY, N E W MEXICO API #30-049-05001 SEC.ll, GEOCHEM SAMPLE NlMBER 3611-001 3611-002 3611-003 3611-004 DEPTE INTERVAL (feet) 302-383 850-950 2500-2600 2600-2695 TOTAL ORGANIC CARBON ( X of Ro-k) 0.18 0.08 0.83/0.81 0.79 TABLE I1 LITROLOGICAL DESCRIPTIONS AND ORGANIC CARBON ANALYSES NEW MEXICO HYDROCARBON SOURCE ROCK EVALUATION CASTLE 6 WIGZELL, NO.l KELLY FEDERAL SEC.ll, T20N, R9E, SANTA FE COUNTY, NEW MEXICO API #30-049-05001 GEOCREM SAMPLE NUMBER DEPTE INTERVAL DESCRIPTION LITRO (feet) GSA NO. 100% Mudstone, sandy, very ' calcareous, light brown. 5YR-614 0.08 850-950 3611-002 -A 100% Mudstone, sandy, very calcareous, lightbrown 5YR-614 0.8310.81 3611-003 2500-2600 -A 100% Limestone, fine crystalline, medium dark gray. N4 0.79 3611-004 2600-2695 -A ( w t .%) 0.18 302-383 3611-001 -A ORGANIC CARBON 100% Limestone, fine crystalline, medium dark gray. N4 TABLE 111 SrmpuRY OF ORGARIC CARBOA At7D VISUAL KEROGEN DATA NEW HWICO HYDROCARBON SOURCEROCK EVALUATION CASTLE 6 w I a E u , ~0.1 KELLY FEDERAL SEC.11, TZON, W E , SANTA FE COUNTY, NEU HWICO API 430-049-05001 GEocRgn SAWLE mRIBER DEPTB INITXVAL ORGANIC U A IYPE (feet) T- - . I N mu [ZED H - - - 44 23 43 - - 3611-001 3611-002 3611-003 3611-004 ...,... .... . . 302-383 850-950 2500-2600 2600-2695 0.18 0.08 0.8310.81 0.79 0 0 0 0 I VI! NORI Am 33 0 20 27 51 50 45 I TBBERPUL ALT?ZATIOA STAGE 2* t o 32+ 10 2+ 2+ IO 2.8 2.6 2.6 2.6 - - r LEGEND: Algal KEROGEN KEY Predominant; 60-1002 Secondary; 20-40% Trace 0-20% Amorphous-Sapropel Relic Amorphous-Saprope1 Herbaceous-SporeIPollen Degraded Herbaceous Woody-Structured LhidentifiedMaterial Inertinite Cody TABLE IV RESOLIS OF ROCK-WAL PYROLYSIS MALYSIS NEW HEXICO UYLIROCARBON SOURCE ROCK EVALUATION CASTLE 6 WIGZELL, N O . l KELLY FEDERAL TZON, R9W, SANTA FE COUNTY, HEW PEXICO API 130-049-05001 SEC.11. T.O.C. PI 331 . .... 302-383 3611-001 3611-002 2500-2600 3611-003 2600-2695 3611-004 3s T.O.C. SI 52 0.03 0.15 850-950 0.79 -- 0.02 0.37 0.15 1.29 320 0.26 0.25 0.68 439 452 0.21 0.07 1.19 M.% Free hydrocarbons, mg A c i g o f rock = Residual hydrocarbon potential (mg RClg or rock) Total organiccarboo, s3 m Aydrogen Index PC+ 0.25 0.09 0.62 0.61 0.72 0.28 - 0.02 0.08 C02 produced from kerogen pyrolysie (ms C02ig of Index rock) W'gen 0.083 (SI + 52) PI degrees THAX mg RC/g organic carbon EYDROGHR OXYGEN (vt . X ) m E X INDEX 0.18 0.08 139 717 112 0.82 88 762 83 151 -- mg CO21g organic carbon SllSl + 52 Index, = Temperature C. ..: E LEGENDFORSUMMARYDIAGR'AM in Eeet see lithology symbols STRATIGRAPHY: by age percent total organic carbon % TOC: Rock-Eval, Hydrocarbon Index = 100 S2(0/00 Wt)/TOC : HI Rock-Eval, Oxygen Index = 100 S3 ( O / O O Wt)/TOC 01 : Rock-Eval, 5 2 peak (ppm) HC Y I E L D : Rock-Eval, Ratio of S2 t o 53 peak sz!s3: see Kerogen symbols KEROGEN: T-MAX : Rock-Eval, maximum temperature of S 2 peak, in degrees Centisrade Reflectance (scale 0 to 5 ) Vicrinite m A): Thermal Alteration Index (Scale 1 to 5 ) TAI ( * ) : Rock-Eval, S 1 peak (pprn) FREE HC: Rock-Eval, Productivity Index = Sl/(SI+S2) PI : DEPTH: LOG: KEROGElf TYPES LITHOLOGIES P I SHALE SILICEOUS ROCKS MUOSTONE NRPORITES SILTSTONE COFlL E ROCKS IGNEOUS ] SANDSTONE VOLCRNICS BRECCIR METRMORPHICROCKS LIMESTONE BASEMENT MARL p..- ....i NoOD)' INERTINITE CONGLOMERATE DOLOMITE AMORPHOUS HERBRCEOUS 0 OTHER MISSING SECTION APPENDIX A Brief Deac~IetlOnOf Olaanlc Geochemical analyses Carried C,-C- nvdrocarbon Y _" mt by Q s C h e m APPENDIX (mntInued) .-. .-.. r II" GEOTHERMAL DIAGENETIC CRITERIA I M W Y U E M A T O R I E S . IhC 1 F . Y. "