Sound wave – longitudinal wave of compressions and rarefactions. What are those black circles? divide lines Pressure Speeds: of molecular motion; of the collective motion of the air; of the sound wave. Normal conversation – speed of collective motion 45 µ m/s. Amplitude – 10 nm. displacement Speed of a wave on a string v= F µ • Tension of the string, F, provides the restoring force • Mass per unit length, µ = m/L, measures inertia of the string, that slows down any wave propagation Speed of sound ? v= B ρ • Bulk modulus of elasticity, B, defines the restoring force • Density of the medium, ρ , measures inertia of the medium that slows down any wave propagation ∆P B=− ∆V / V ∆ V/V is the fractional change of volume (can be measured in %) Large bulk modulus of elasticity corresponds to a large change of pressure – vigorous restoring force – at small fractional change of volume v= B ρ ∆P B=− ∆V / V • A hard material with a low compressibility and low density ­ Aluminum ­ high speed of sound. • A soft material with a high density – Lead – low speed of sound. Speed of sound in a gas v= B ρ Can we calculate the bulk modulus of elasticity, B, of a gas? What process should we assume? ∆P B=− ∆V / V Sound waves are propagating quickly. No time for heat exchange! ⇒ Adiabatic process. γ PV = c = const P = cV dP P −γ −1 = −γ cV = −γ dV V −γ Speed of sound in a gas v= B ρ ∆P dP B=− = −V ∆V / V dV dP P = −γ dV V γP v= ρ B = γP γ = Cp/Cv – the constant for an adiabatic process in the gas P pressure of the gas ρ ­ density of the gas Speeds of sound for different gases at normal conditions γP v= ρ γ = Cp/Cv – the constant for an adiabatic process in the gas P pressure of the gas ρ ­ density of the gas For two different gases, the ratio of the sound speeds can be calculated as γ 2P γ 1P v2 / v1 = / ρ2 ρ1 If the two gases are at the same pressure, P: γ2 ρ1 v2 / v1 = ⋅ γ1 ρ2 Example: air and Helium at normal conditions Ratio of the sound speeds: γ2 ρ1 γ2 M1 v2 / v1 = ⋅ = ⋅ γ1 ρ2 γ1 M2 The volume occupied by one mole of a gas at the normal conditions is the same for all gases – 22.4 liters. Therefore, the ratio of densities is equal to the ratio of molar weights. (1) Air – a mixture of N2 ( M = 28 g/mole) and O2 ( M = 32 g/mole) Average molar weight – M1 = Mair = 29 g/mole. Composed of diatomic molecules, γ 1 = γ air = 1.4. (2) Helium M2 = MHe = 4 g/mole. A monatomic molecule, γ 2 = γ 1.67. 1.67 29 In air, v1 = 343 m/s. v2 / v1 = 1.4 ⋅ 4 = 2.94 He = In Helium, v2 = 1008 m/s Intensity of sound I – average intensity 1 I = s0ω∆P0 s0 – the amplitude of displacement of the air 2 ∆ P the amplitude of pressure variations ∆P I= 2 ρv 2 0 Expressions making a bit more sense: Quadratic in the amplitude of pressure variations – proportional to potential energy of the gas deformations. 1 2 2 2 I = ρ ωs0 v = ρ v osc v = 2 K ⋅ v 2 Quadratic in the amplitude of velocity of the oscillations of the gas and the gas density. Proportional to kinetic energy of the gas motion and the wave speed. −6 I = 10 W/m , v = 343 m/s ⇒ v osc = 45 μm/s 2 Sensitivity of human ear.. Most sensitive at about 4000 Hz. 343 m/s λ = v/ f = = 4000 Hz = 8.6 cm Eardrum ­ about 1 cm in diameter