NRG FACT SHEET CO2 Capture Technology/KM CDR Process® Background Flue gas CO2 capture technology separates CO2 from large CO2 emission sources derived from combusting coal, natural gas or oil fuel. In the case of coalfired power plants as shown in Figure 1, flue gas CO2 capture technology is applied downstream of the existing emissions control systems. CO2 Capture Boiler SCR FGD BH Coal Air Selective Catalytic Reduction Power Station Steam Turbine Clean Environment CO2 Capture Plant CO2 Compression NOx Captured CO2 is compressed and then used in enhanced oil recovery (EOR) where the CO2 will remain sequestered in the underground rock formations. Flue Gas Desulfurization Bag House Ash SOx CO2 EOR Enhanced Oil Recovery CCS Carbon Capture & Storage Figure 1: Coal-fired Power Plant – System Composition Technology Overview The MHI flue gas CO2 capture process, so called “KM CDR Process®” (Kansai Mitsubishi Carbon Dioxide Recovery Process) can be applied to either existing or new power plants. This technology has been co-developed by MHI and Kansai Electric Power Company (KEPCO) since 1990. 90% of CO2 is recovered from the flue gas by contacting with KS-1TM solvent Treated Flue Gas CO2 Compressor The flue gas is cooled to a process desired temperature. Compressed CO2 Absorber Regenerator C.W. 4,776 mtpd (metric ton per day) (equal to 5,265 short ton per day) C.W. (Cooling Water) MHI Energy Saving System CO2 is stripped from KS-1TM solvent in the Regenerator Flue Gas Quencher Flue Gas C.W. Steam The process is built on proven, advanced flue gas CO2 capture technologies with specific application for fossil fuel power generation facilities. It utilizes the proprietary KS-1 trademark solvent that has improved absorption and regeneration properties while also lowering corrosiveness and degradation features, compared with normal amine applications. These aspects contribute to lower energy requirements, solvent consumption and emissions of waste products. MHI is a world-leading flue gas CO2 capture technology supplier and is strategically positioned to provide the most technically proven, environmentally friendly and economically robust CO2 capture process. FOR MORE INFORMATION, CONTACT: David Knox NRG Energy 1000 Main, Houston, Texas 77002 Office: 832.357.5730 david.knox@nrgenergy.com NRG FACT SHEET KM CDR Process : • World’s largest operating flue gas CO2 capture plant – eleven operating plants for various flue gas sources including the largest post combustion CO2 capture plants in the world (as of June, 2014) • World’s most energy efficient process with KS-1 solvent – leading to reduced costs • World’s most advanced and comprehensive industrial R&D programs for more than 20 years – deployment of multiple R&D pilot plants and research facilities led to significant process and technology improvements • More than 207 patents pertaining to the KM CDR Process® all over the world (as of June, 2014) • Widespread commercial experience with large scale various Air Quality Control Systems (AQCS) equipment ® Experiences The experience gained from the deployment of eleven operating plants has been invaluable in strengthening operation and reliability in CO2 capture plants. Eleven major MHI CO2 capture plants are currently under operation as shown in Figure 3. 3 8 CO2 Recovery (CDR) Plant – IFFCO AonlaUnit (India) 1999 200 t/d Malaysia 2005 330 t/d Japan 2006 450 t/d India CO2 Recovery (CDR) Plant – IFFCO Phulpur Unit (India) 11 2006 India (Aonla) 450 Mt/d 2009 450 t/d Bahrain 2010 400 t/d UAE 2 2005 Japan 330 Mt/d 2011 U.S.A(SOCO) 500 t/d 2006 450 t/d India 2010 240 t/d Vietnam 2006 India (Phulpur) 450 Mt/d 2011 Pakistan 340 Mt/d 12 2014 Qatar 500 Mt/d 7 2009 Bahrain 450 Mt/d 10 2012 India (Vijaipur) 450 Mt/d 9 KEY 2009 450 t/d India 4 6 Plants under operation Plants under construction 2010 UAE 400 Mt/d 1 5 2010 Vietnam 240 Mt/d 1999 Malaysia 210 Mt/d 2009 India (Kakinada) 450 Mt/d Figure 3: MHI CO2 capture plant - Worldwide experience 2011 340 t/d Pakistan 2012 450 t/d India 2011 500 t/d USA 2014 500 t/d Qatar Technology Demonstration Coal-fired power plants are the largest producer of CO2 emissions. The 500 mtpd (metric ton per day) CO2 capture and sequestration project at Plant Barry in Alabama is currently the world’ s largest start-to-finish carbon capture and storage project from coal fired flue gas. The CO2 produced from the capture plant is transported via a pipeline and sequestered at the Citronelle oil field. The capture plant began successful operation on June 2, 2011 and achieved a 100,000 ton of CO2 injection until October, 2013. (Remark) KM CDR Process is a registered trademark of Mitsubishi Heavy Industries, Ltd., in Japan, the United States of America, European Union (CTM), Norway, Australia, and China. NRG is a registered servicemark of NRG Energy, Inc. The plus signs and plus clusters are servicemarks of NRG Energy, Inc. © 2014 NRG Energy, Inc. All rights reserved. Figure 4: The 500 mtpd CO2 capture plant at Plant Barry / Overview