Objective 4 Element Compound Mixture Elements, Compounds & Mixtures Classify samples from everyday life as being element, compound or mixtures 10th grade only Periodic Table Relate the chemical behavior of an element including bonding to its placement on the periodic table •Matter is anything that takes up space and has mass. All matter can be identified by its characteristics. • Element. Composed of one kind of atom • Examples 1. • Gold, Au copper, Cu 2. • •Compounds are two or more elements chemically combined together. This means that in order to separate the elements from the compound requires chemical reactions. All compounds will have a definite chemical formula (a formula that is always the same ratio of elements). • Examples: 1. • Table salt, NaCl Water, H2O 2. • •Mixtures are two or more substances (a substance is any type of matter) that is combined, but not chemical bonded together. Can be separated by simply means (tweezers, magnets, evaporation). • Examples concrete 1. • 2. • bag full of garbage •Mixtures can be of two types, heterogeneous and homogeneous. •Heterogeneous means that it has different consistence throughout the mixture. • Examples garbage bag of trash 1. • 2. • chocolate chip cookie •Homogeneous mixtures are the same consistence throughout. • Examples 1. • Kool-aid 2. • milk •Solutions are another name for homogeneous mixtures. • Solutions have two parts: • solute = what is dissolved • solvent = what does the dissolving • Nine types of solutions. Solute can be liquid, solid or gas; solvent can be solid, liquid, or gas. If the solvent is water, the solution is called an aqueous solution. • Examples 1. • oxygen dissolved in nitrogen (AIR) solute = gas, solvent = gas 2. • Dr. Pepper solute = carbon dioxide (gas), solvent = water (liquid) 3. • Acetic acid in water (vinegar) solute = liquid, solvent = liquid To help you decide if a homogeneous substance is a solution or a compound, ask yourself this questions: "Are there more than one type of this substance?" If you answer yes, then it is a solution (mixture), if no, then it is more likely a compound. To help you decide if a mixture is homogeneous or heterogeneous, ask yourself "is it the same through out?" if yes = homogeneous, no = heterogeneous. The following flowchart will help. . Comparing Solutions, Colloids, and Suspensions Description Solutions Colloids Suspensions Homogenous Heterogeneous Heterogeneous mixture mixture mixture Settle while NO NO YES standing Can be separated NO NO YES using filter paper Sizes of particles 0.1 - 1 nm 1 - 100 nm Greater than 100 nm Scatter light NO YES YES The Atom (Simple Bohr Model) Atom is the smallest part of an element that retains all the properties of that element. Atoms are made up of even smaller particles--a nucleus consisting of protons and neutrons and electrons in shells around the nucleus. The most common way to picture an atom is the solar system model. The number of protons in the nucleus determines the element, as well determining the number of electrons. Solar system model The solar system model of the atom is that the atom is like a tiny solar system, with the nucleus in the center and electrons rotating around the nucleus in orbits, similar to how the planets rotate around the Sun. It is also called the Bohr model, after Neils Bohr, who discovered electron shells in 1913. Electrons rotating around the neon nucleus There are some newer models of how the electrons appear in the atom. Nucleus The nucleus consists of a number of positively charged protons and uncharged neutrons. They are approximately the same size and weight. Since like charges repel, there is some sort of "nuclear glue" that holds the nucleus together. There must usually be more neutrons than protons for a nucleus to be stable, so it has been thought that neutrons had something to do with this nuclear glue. Present theories state that there is a sub-nuclear particle called a gluon that holds the nucleus together. The atomic number of an element is the number of protons in the nucleus of an atom of that element. Electrons Atoms are neutral and therefore have the same number of negatively charged electrons in orbit around the nucleus as there are positively charged protons in the nucleus. In situations where there are either more or less electrons in orbit than there are protons in the nucleus, the atom is called an ion. Electron Energy Levels Electrons are arranged in energy levels (shells) or orbits around the nucleus. Maximum number There is a definite arrangement of the electrons in these shells and a maximum number of electrons possible in each shell. 12 3 4 5 Shell or Orbit Number Maximum Number of Electrons 2 8 18 32 50 The maximum number of electrons in the first energy level is 2. After the energy level is filled, the second starts filling up, according to the number of positive charges in the nucleus. The maximum number of electron in the second energy level is 8 electrons. Then the third shell starts to fill. Electron shells for a Sodium atom (atomic number 11, with 11 electrons) Filling order complicated. After the second orbit or shell is filled, things start to get complicated. The third shell fills until it gets to 8, and then the fourth shell starts adding electrons until it too has 8 electrons. Then the third shell fills until it gets to 18. Outer shell basis of Chemistry (For TAKS Only) Periodic Table LElements listed by atomic number= number of protons = number electrons LThe elements are listed by their abbreviations. H = Hydrogen, He = Helium, and so on. LThey also usually include the atomic weight of each element in the Periodic Table LThe number of each Period or row (1, 2, 3, 4,...) also indicates how many orbits all the elements in that row have. Thus every element in row 2 has two orbits or electron energy levels or shells. LGroups are vertical columns and are now numbered 1-18. All elements in the same group have the same number of valence electrons (electrons in the outer energy level) and react similarly. Now, you know that there are a maximum number of electrons allowed in each orbit. Only 2 can be in the first orbit, 8 in the second, 18 in the third, 32 in the fourth, and so on. Outer Orbit +1 +2 +3 4 -3 -2 -1 Full Orbits 1 1H 2 3 Li 4 Be 5B 3 11 Na 12 Mg 13 Al 14 Si 15 P 16 S 17 Cl 4 19 K 20 Ca * * * * 33 Br 34 Kr The Periodic Table (partial version) 2 He 6C 7N 8O 9F 10 Ne 18 Ar LChemical reactions -The Periodic Table helps to predict chemical reactions. Completing orbitsÆ Elements will lose or gain electrons to have eight electrons (same as noble gas) in their outer energy level. As you know, atoms "like" to have their outer orbit completely filled or completely empty. (Only for TAKS) Thus Hydrogen has 1 more electron than having its orbit empty. Since Boron (B) already has its first orbit full and will allow a maximum of 8 electrons in its second orbit, +3 indicates it has 3 more electrons than having its outer orbit empty. Likewise, Chlorine (Cl) is one electron short (-1) of filling up its outer orbit or energy level. Groups are or vertical columns and are now numbered 1-18. All elements in the same group have the same number of valence electrons (electrons in the outer energy level) and react similarly. Elements will lose or gain electrons to have eight electrons (same as noble gas) in their outer energy level. GROUP 1 (IA) VALENCE ELECTRONS 1 2 (IIA) 2 13 (IIIA) 3 14 (IVA) 4 15 (VA) 5 16 (VIA) 6 FAMILY NAME REACT Alkali metal Lose 1 electron & be become an ion with a +1 charge. Lose 2 electron & be become an ion with a +2 charge MetalÆLose 3 electron & be become an ion with a +3 charge NonmetalÆ gain 4 electrons and form ion with a -4 charge. NonmetalÆ gain 3 electrons and form ion with a -3 charge NonmetalÆ gain 2 electrons and form ion with a -2 charge Alkaline metal 17 (VIIA) 7 Halogens 18 (VIIIA) 8 Nobel Gases NonmetalÆ gain 1 electrons and form ion with a -1 charge Non-reactive LArrangement of elements The elements in the following Periodic Table are arranged in rows (Periods) according to atomic number and in columns (Groups) according to the configuration of the outer orbit (energy level). Periods Ærows and GroupÆcolumns If you go along a period from left to right, the elements are numbered 1 - H, 2 - He, 3 - Li, 4 - Be, 5 - B, and so on. The atomic number is also the number of protons in the element's nucleus. If you go down a group, each element has the same number of electrons in its outer orbit or shell. For example, H, Li, Na, K and so on, all have one electron in the outer energy level. On the other hand, O, S, Se, etc. all have 6 electrons in the outer orbit. The number of electrons in the outer energy level determines the element's chemical properties. LProperties Metals, nonmetals and Metalloids (semimetals) Elements B, Si, Ge, As, Sb, Te, and At are metalloids. They conduct heat and electricity better than nonmetals, but not as well as metals. They are easier to shape than nonmetals, but not as easy as metals. All are solid at room temperature. Elements on the right of the periodic table are Nonmetals. They are poor conductors of heat and electricity and not easily formed into shapes. Most are gases at room temperature, except for C, P, S, Se and I, which are solids and Br, which is a liquid. H is also a nonmetal. Elements on the left side of the periodic table are metals. They are solid substances that are a good conductors of heat and electricity. They can be formed into many shapes. g What is Chemical Bonding? Chemical Bonding - the combining of atoms of elements to form new substances (compounds) Atoms contain a positively charged center or nucleus. Outside the nucleus are negatively charged electrons. The atom as a whole is neutral - the positive charge balances the negative charge. The positively charged nucleus attracts the negative electrons. This holds the atom together. Electrons are not pulled into the nucleus. They remain in a region called the electron cloud. The electron cloud is made up of energy levels. The 1st level can hold 2 electrons. The 2nd can hold 8 electrons. The 3rd can hold 8 electrons if the 3rd level is the outermost level (the valance electrons) or up to 18 if it is not the outermost. Valance electrons - the electrons in the outermost energy level. The maximum number is 8. These are the electrons involved in chemical bonding. If the outer energy level is filled with 8 electrons, the atom is stable and does not react (such as the Noble gases - Family VIIIA) To achieve stability (which means a filled outer energy level), an atom will either gain or lose electrons. Atoms that gain electrons will bond with other atoms that lose electrons if the bonding gives both atoms a complete outer energy level with 8 electrons. Ionic Bonding – Between a metal and a nonmetal atom bonding that involves a transfer of electrons. It involves a formation of ions or "charged" atoms. One atom gains electrons and the other atom loses electrons. An atom that gains electrons has a negative charge. It is a negative ion. Example: A neutral fluorine atom gains one electron to form a fluoride ion (F-1)with a -1 charge. An atom that loses electrons has a positive charge. It is a positive ion. Example: a neutral sodium atom loses 1 electron to become a sodium ion (Na+1) with a positive 1 charge. Positive ions attract negative ions and form ionic bonds. For example, during the reaction of sodium with chlorine: sodium (on the left) loses its one valence electron to chlorine (on the right), resulting ina positively charged sodium ion (left) and a negatively charged chlorine ion (right). Covalent Bonds Between Nonmetal Atoms Covalent bonds are forces of attraction formed when atoms of a molecule share electrons. The term sharing electrons indicates that the valance electrons of the atoms become part of the orbitals of more than one atom of the molecule.This is illustrated in the following diagrams In the figure below are shown two individual hydrogen atoms. Each atom has one valance electron and a nucleus with one proton. In the figure below two hydrogen atoms share the electrons of the valance orbital of the individual hydrogen atoms so that each hydrogen atom is now sharing two electrons. In this figure are also shown two other ways of depicting the hydrogen molecule. The depiction on the left is a capital H with a subscript 2 indicating there are two hydrogen atoms make up this hydrogen molecule. In the depiction on the right are two H's connected by a line. This line represents the single covalent bond composed of two shared electrons. Example water Metallic Bonds – Only Metal Atoms bonds formed by the atoms of metals, in which the outer electrons of the atoms form a common electron cloud or "sea" of electrons. The positive nuclei of metal atoms are surrounded by free-moving or mobile electrons that are attracted by the nuclei Only Metal Atoms