Using Life Cycle Assessment to Determine Greenhouse Gas Emissions from Bioenergy Systems Timothy A. Volk SUNY – ESF SURE 2010, Syracuse, NY November 4, 2010 Overview • Brief overview of LCA • LCA of willow biomass crops • LCA of electricity generating systems using different feedstocks: – hybrid poplar – wood residues – coal – natural gas Assessing GHG Balances • Need to use a consistent framework • To compare systems need to: – agree on the goal and scope – use the same functional units – have common boundaries – use the same life cycle inventory and calculation techniques » Computation and quantification of inputs and outputs » Allocation of inputs and outputs » Conversion and weighting factors (McMillan 2006) (McMillan 2006) (McMillan 2006) Willow Biomass Production Cycle Three-year old after coppice Site Preparation Planting Harvesting One-year old after coppice Coppice First year growth Early spring after coppicing LCA of Willow Crops - Boundaries (Heller et al. 2003) (Heller et al. 2003) Primary Energy Use Management Scenarios sulfur coated urea requires more energy to manufacture than ammonia (76 MJ kg−1 N vs.55 MJ kg−1) (Heller et al. 2003) GHG Flows in Willow Biomass Crops LCA Results from Heller et al. (2003) Current Study CO2 (Mg CO2 ha-1) Other GHG (Mg CO2 eq ha-1) Total (Mg CO2 eq ha-1) Diesel fuel 3.1 0.1 3.2 Agriculture Inputs 2.9 0.4 3.4 N2O from N fertilizer 3.9 (+ 3.2) 3.9 N2O from foliage 7.3 (+ 5.8) 7.3 Emissions C Sequestration Below ground Soil C Net Total Harvested Biomass -14.1 -14.1 0 0 -8.0 -499.2 11.7 (+ 9.0) 3.7 -499.2 CO2 (Mg CO2 eq ha-1) Changes in Soil Carbon in Willow in Biomass Crops Across a 19 Year Chronosequence Mg ha-1 in top 45 cm 200 180 160 140 120 100 80 60 40 20 0 0-yr old 5-yr old 12-yr old 14-yr old 19-yr old (Pacaldo et al. 2010) Above and Below Ground Biomass 60 belowground biomass 50 aboveground biomass Mg ha-1 40 30 20 10 Previous estimate was 7.6 Mg ha-1 0 5-yr old 12-yr old 14-yr old 19-yr old (Pacaldo et al. 2010) Change in Below Ground Biomass • 21 Mg ha-1 of below ground biomass equated to 38.5 Mg CO2eq – woody biomass is about 50% C – Convert from Mg C to Mg CO2 by multiplying by 44/12 • Previous estimate of 7.6 Mg ha-1 (14.1 Mg CO2eq) below ground biomass was based on measurements in young willow biomass crops GHG Flows in Willow Biomass Crops Current Study LCA Results from Heller et al. (2003) CO2 (Mg CO2 ha-1) Other GHG (Mg CO2 eq ha-1) Total (Mg CO2 eq ha-1) Total (Mg CO2 eq ha-1) Diesel fuel 3.1 0.1 3.2 3.2 Agriculture Inputs 2.9 0.4 3.4 3.4 N2O from N fertilizer 3.9 (+ 3.2) 3.9 3.9 N2O from foliage 7.3 (+ 5.8) 7.3 7.3 -14.1 -14.1 -38.5 0 0 0 3.7 -20.8 -499.2 -499.2 Emissions C Sequestration Below ground Soil C Net Total Harvested Biomass -8.0 -499.2 11.7 (+ 9.0) (Pacaldo et al. 2010) A Comparison of the Environmental Consequences of Power from Biomass, Coal, and Natural Gas Margaret K. Mann National Renewable Energy Laboratory Golden, Colorado USA Purpose of Studies • Coal and natural gas LCAs the foundation for quantifying the benefits of biomass power. • Direct-fired biomass system describes current biomass power industry. • Cofiring LCA examined near-term option for biomass utilization. • Each assessment conducted separately - common systems not excluded. Systems Examined Biomass IGCC Indirectly-heated gasification Dedicated hybrid poplar feedstock Zero soil carbon sequestration in base case Average coal Pulverized coal / steam cycle Illinois #6 coal - moderate sulfur, bituminous Surface mining Systems Examined Biomass / coal 15% cofiring by heat input cofiring Biomass residue (urban, mostly) into PC boiler 0.9 percentage point efficiency derating Credit taken for avoided operations including decomposition (i.e., no biomass growth) Direct-fired biomass Biomass residue Avoided emissions credit as with cofiring Natural gas Combined cycle Upstream natural gas losses = 1.4% of gross Scope of Systems Studied • Different studies used common – – – – Goal and scope Boundaries functional unit life cycle inventory and calculation techniques • Allows for a direct Boundaries and material and energy flows in electricity generation systems with coal and biomass feedstocks (Mann and Spath 1999) comparison of the different processes Energy Balance • The total energy consumed by each system includes the fuel energy consumed plus the energy contained in raw and intermediate materials that are consumed by the systems Net Energy Ratios Life Cycle Energy Balance 30 net energy ratio 25 external energy ratio 20 15 10 5 0 Dedicated biomass IGCC Average PC coal Coal/biomass cofiring Direct-fired biomass residue NGCC Carbon Cycle (GHG Emissions) Example flows: • Biomass energy crop - photosynthesis, carbon sequestration in soil • Biomass residue - avoided decomposition emissions • Coal - coal mine methane, coal mine waste • Natural gas- fugitive emissions, leaks • General - incomplete combustion, upstream fossil fuel consumption Key question: On a life cycle basis, what are the net greenhouse gas emissions of these systems? Life Cycle Greenhouse Gas Emissions 1200 GWP (g CO2-equivalent / kWh) 1000 800 600 400 200 0 -200 -400 -600 Wind and solar GHG emissions are in the range of 10 – 60 g CO2equiv/kWh Dedicated biomass IGCC Direct-fired biomass residue Average PC coal Coal/biomass Cofiring NGCC Other Air Emissions 15 5 CH4 -5 Particulates SOx NOx CO NMHCs -15 Average PC coal 15% Coal / biomass cofiring Direct biomass residue Dedicated biomass IGCC NGCC -41 g/kWh Biomass IGCC also emits isoprene at 21 g/kWh Summary • Need to use a consistent and reliable method for • • • assessing GHG emissions from different energy systems Biomass systems based on short rotation woody crops are C neutral or C sinks based on recent data In a side by side comparison of electricity generating systems, biomass has GHG emissions that are ~95% lower than coal and ~90% less than natural gas GHG emissions from biomass to electricity are similar to wind and solar electricity generating systems Questions