Episodic exhumation in the Western Alps Barbara Carrapa* Jan Wijbrans* Giovanni Bertotti* Faculteit der Aardwetenschappen, Vrije Universiteit Amsterdam, De Boelelaan 1085, 1081 HV Amsterdam, The Netherlands ABSTRACT Oligocene to Miocene clastic sediments of the Tertiary Piedmont Basin (northwest Italy) were derived from erosion of Western Alps source rocks. Detrital white micas from different stratigraphic units and from sands of three present-day rivers draining the internal Western Alps have been analyzed by 40Ar/39Ar geochronology. Our data suggest a widespread, fast cooling and exhumation event prior to ca. 38 Ma followed by a .30 m.y. period of slower cooling and exhumation combined with erosion of crustal rocks with uniform 40Ar/39Ar signatures. These processes have resulted in a pattern of regularly increasing lag time up section. Keywords: Western Alps, cooling, exhumation, steady state. INTRODUCTION The relationships between orogen dynamics, topography creation, erosion, and clastic deposition in synorogenic basins have in recent years resulted in stimulating, if fairly theoretical, numerical and analogue models (e.g., Willett and Brandon, 2002, and references therein). Through investigation of the detrital mineral record derived from the Western Alps, this study provides new constraints on the cooling and exhumation evolution of the orogen since before 30 Ma. OROGENS AND STEADY STATE Orogens are considered to undergo a constructional phase during which material is accreted, a steady-state phase when the quantities of material accreted and eroded are in balance, and a destructive phase during which removal of material predominates (Jamieson and Beaumont, 1989). The steady-state concept is of particular interest because it is representative of the orogen maturity (Willett and Brandon, 2002). One way to investigate orogen dynamics is to look at the ages recorded by different thermochronometers across it (Willett and Brandon, 2002). However, this approach investigates only a limited time segment because significant volumes of crust have been eroded. The sedimentary record represents the archive of past cooling and exhumation histories (e.g., Copeland and Harrison, 1990). Steady-state exhumation can be recognized by dating clastic minerals recording isotopic ages related to upward rock motion through isotherms (Bernet et al., 2001; Willett and Brandon, 2002). One parameter used in these studies is lag time (Brandon and Vance, 1992), defined as the difference between the isotopic age of a given detrital mineral and the stratigraphic age of the sediment containing the mineral. A *E-mail addresses: carb@geo.vu.nl; wijj@geo. vu.nl; bert@geo.vu.nl. short lag time corresponds to fast exhumation, whereas a long lag time corresponds to slow exhumation (Garver et al., 1999). Steady-state exhumation is represented by constant lag times (Bernet et al., 2001). However, episodic rapid cooling and fast exhumation will tend to produce rocks with isotopically indistinguishable ages (Brandon and Vance, 1992) that, once eroded and deposited in progressively younger sedimentary formations, will result in a systematic increase in lag times. Fission-track dating on zircons and 40Ar/ 39Ar dating on white micas (von Eynatten et al., 1999; Spiegel et al., 2000; Bernet et al., 2001) in sedimentary rocks derived mainly from the Central Alps suggest thermal overprinting during the Neogene. In contrast, the lack of data on detrital minerals coming from the Western Alps has, until now, limited the interpretation of the Tertiary to present cooling and exhumation patterns of this large segment of the Alps. SOURCE AND SINK AREAS IN THE WESTERN ALPS The Western Alps, formed following Eurasia and Africa plate collision (Platt et al., 1989), display a dominant vergence toward the European foreland (i.e., westward) and a subordinate one toward the Adriatic foreland (i.e., eastward). Intense exhumation is typically associated with axial zones; high- to ultrahighpressure rocks (HP, UHP) are exposed in various localities along the internal part of the arc (e.g., Voltri Group, Dora Maira Massif, Gran Paradiso; Fig. 1A). The Western Alps, similar to the Central Alps, underwent cooling following peak Alpine metamorphism between 40 and 32 Ma, as indicated by the youngest ages recorded in the orogen (Fig. 1B). The Tertiary Piedmont Basin (TPB, Fig. 1A) represents an ideal place for investigating source rock cooling and exhumation patterns as the basin received sediments eroded from the internal Western Alps over a period of .30 m.y. The basin hosts .4 km of lower Oligocene to upper Miocene sedimentary rocks (Gnaccolini et al., 1998) unconformably overlying Alpine-Apennine tectonic structures (Miletto and Polino, 1992). Rivers continue to erode and drain the internal Western Alps (Fig. 1A). METHODS The 40Ar/39Ar geochronology on detrital white micas shed light on cooling and exhumation processes over time (e.g., Copeland and Harrison, 1990; Renne et al., 1990; Najman et al., 1997). The 40Ar/39Ar geochronology (see Appendix)1 has been applied to single white micas (250–500 mm in size) separated from eight different Oligocene– Miocene Tertiary Piedmont Basin formations and from three present-day river sands for a total of .500 individual total-fusion experiments (Fig. 2; Table DR1; see footnote 1). White micas have been chosen because of their wide occurrence, their resistance to resetting by mild thermal disturbances owing to their sufficiently high closure temperature (;350–420 8C; McDougall and Harrison, 1999 and references therein), and their resistance to mechanical and chemical breakdown (Heller et al., 1992). Probability density diagrams (Sircombe, 2000) have been compiled for each formation and present-day river sand sample in order to isolate youngest peaks (Fig. 3; Table DR2; see footnote 1). The youngest peaks are here considered as representative of regional signatures. In a few cases youngest ages are different from youngest peaks and are probably related to local events (Table 1). The biostratigraphic age (in the framework of the time scale of Berggren et al., 1995) of the selected samples is based on a detailed study of planktic and benthic foraminifera and calcareous nannofossils (Gnaccolini et al., 1998, and references therein; Table DR1 [see footnote 1]). RESULTS A southward marine transgression started in the easternmost part of the Tertiary Piedmont Basin in the early Oligocene and extended into the southwest part of the basin during the 1GSA Data Repository item 2003086, Appendix (description of laser analysis), Table DR1 (sample descriptions), and Table DR2 (age data for Fig. 3), is available from Documents Secretary, GSA, P.O. Box 9140, Boulder, CO 80301-9140, editing@ geosociety.org, or at www.geosociety.org/pubs/ ft2003.htm. q 2003 Geological Society of America. For permission to copy, contact Copyright Permissions, GSA, or editing@geosociety.org. Geology; July 2003; v. 31; no. 7; p. 601–604; 4 figures; 1 table; Data Repository item 2003086. 601 Figure 1. A: Tectonic map of Western and Central Alps showing three major nappe complexes, modified after Bigi et al. (1983). LA—Ligurian Alps; AGM—Argentera Massif; DM—Dora Maira; GP—Gran Paradiso; TPB— Tertiary Piedmont Basin; VG—Voltri Group. Black-line rectangle—study area. B: Western Alpine basement rocks and related youngest 40Ar/39Ar phengite ages: (1) Monié (1990); (2) Monié and Chopin (1991); (3) Hunziker et al. (1992); (4) Scaillet et al. (1992); (5) Inger et al. (1996); and (6) Cortiana et al. (1998). late Oligocene. Transgressive gravels to sands (Molare Formation), mainly derived from the south, were deposited (Gnaccolini et al., 1998). Their isotopic age signatures cluster mainly around 60–32 Ma and 330–270 Ma (Fig. 2). The youngest age derived from sandstones of Rupelian age (zone P20 and P21 of the early Oligocene) is 31.6 6 1.7 Ma, whereas the youngest peak is 37 Ma (Fig. 3; Table 1). Transgressive sedimentary rocks are overlain by lower Oligocene–Aquitanian shallowwater conglomerates and sandstones belonging to the Rocchetta and Monesiglio Formations (Gnaccolini et al., 1998). Paleocurrent data and sandstone petrography from these sedimentary rocks indicate a southwestern or western provenance (Gnaccolini et al., 1998, and references therein). The 40Ar/39Ar ages for both formations are mainly between 160 and 37 Ma; there are a few Variscan ages (Fig. 2). The youngest age in the Rocchetta Formation is 22.7 6 0.4 Ma and is indistinguishable from the youngest peak (ca. 23 Ma) (Fig. 3; Table DR2 [see footnote 1]). However, this anomalous youngest peak is the result of a duplicate analysis of a single sample of Aquitanian age (ca. 23.8–20.5 Ma) derived from the south. Therefore we reject the implied youngest peak ca. 23 Ma and consider instead the second peak at 38 Ma as the more relevant and regional youngest peak (Table 1). Figure 2. Plot of detrital-mineral 40Ar/39Ar ages vs. minimum stratigraphic ages characteristic of each formation and present-day river sands. Only analyses with errors of <10% are considered here. For more details see Table DR2 (see footnote 1 in text) (Carrapa, 2002). 602 Support for rejection comes from the sedimentologically similar Monesiglio Formation, which yielded a youngest peak of 37 Ma and a youngest age of 37.2 6 0.4 Ma (Fig. 3; Table 1). Aquitanian to Tortonian sedimentation was characterized by regular turbiditic bodies deposited in a deep-marine environment covering the whole basin and associated with an increase in sedimentation rates (Gnaccolini et al., 1998), basin accommodation space, and possibly source-area reorganization (Carrapa et al., 2003). Petrographic and paleocurrent data indicate fairly uniform west to east transport (Gnaccolini et al., 1998, and references therein). The Cortemilia and Paroldo Formations (Aquitanian–Langhian) show ages spanning mainly 38 Ma to 160 Ma, and few Variscan ages (Fig. 2). The youngest age of 37.0 6 0.9 Ma is indistinguishable from the youngest peak of 37 Ma (Fig. 3; Table 1). The Murazzano and Cassinasco Formations (Langhian–Serravallian) have comparable isotopic signatures and are characterized by ages between 180 and 37 Ma and a few ages between 320 and 240 Ma (Fig. 2). In the Murazzano Formation, the youngest age observed is 37.5 6 1.1 Ma and corresponds to the youngest peak (38 Ma; Fig. 3; Table 1). Similar data were obtained from the Cassinasco Formation, which is characterized by a youngest age of 37.5 6 0.8 Ma corresponding to the youngest peak (39 Ma; Fig. 3; Table 1). Two main isotopic signatures characterize the Lequio Formation (Serravallian–Tortonian); its detrital-mineral ages are mainly between GEOLOGY, July 2003 TABLE 1. TERTIARY PIEDMONT BASIN SAMPLES Samples Tanaro (present-day sand) Maira (present-day sand) Lequio (11.2–7.12 Ma) Cassinasco (16.4–11.2 Ma) Murazzano (16.4–11.2 Ma) Cortemilia 1 Paroldo (23.8–14.8 Ma) Monesiglio (28.5–14.8 Ma) Rocchetta (28.5–20.5 Ma) Molare (33.7–23.8? Ma) N DA (Ma) 21 21 58 87 32 58 38 95 109 0 0 11.2–7.12 14.8–11.2 14.8–11.2 20.5–14.8 20.5–14.8 23.8–20.5 33.7–28.5 YA (Ma) YP (Ma) Minimum cooling rates (C8/m.y.) 6 6 6 6 6 6 6 6 6 38 9–11 38 39 38 37 37 38 37 14–11 15–13 16–13 18–15 18–15 24–20 49–41 35.7 39.7 38.2 37.5 37.5 37 37.2 22.7 31.6 1.5 1.3 0.5 0.8 1.0 0.9 0.4 0.4 1.7 Note: General depositional ages for each formation in brackets, N is the number of total analyses, DA is the specific depositional age for the sample in which the youngest detrital age (YA) has been measured, YP is the youngest peak calculated with probability density diagram (Fig. 3). Minimum cooling rates are calculated by using the minimum depositional age (underlined values) and the YP. çonnais rocks. The general spectrum is characterized by ages between 320 and 35 Ma (Fig. 2); the minimum detrital mineral age is 35.7 6 1.5 Ma (Table 1). Figure 3. Probability density diagrams of ages younger than 45 Ma and characteristic of each formation and present-day river sands with indication of youngest peaks. Probability curves are generated by summing Gaussian distribution of each individual measurement (defined by age and its error). 130 and 38 Ma, and a minor fraction of the detrital minerals contributed ages between 330 and 270 Ma (Fig. 2). The youngest age is 38.2 6 0.5 Ma, corresponding to the youngest peak (38 Ma; Fig. 3; Table 1). Present river sands were sampled from the Maira, Stura, and Tanaro Rivers (Fig. 1). The Maira drains the polymetamorphic HP-UHP units of the southern part of the Dora Maira Massif. Ages range mainly between 90 and 50 Ma; the minimum detrital mineral age is 39.7 6 1.3 Ma (Fig. 2; Table 1). The Stura River primarily drains the Variscan Argentera Massif. The main age group ranges between 302 and 204 Ma (Fig. 2), and Alpine ages are absent. The Tanaro River comes from the Ligurian Alps and drains Piemontese and BrianGEOLOGY, July 2003 DISCUSSION The youngest peak ages versus depositional ages of Oligocene to Holocene sedimentary units show a persistence of the youngest signature (ca. 38 Ma) in all samples, resulting in increasing lag time up sequence (Fig. 4). Cooling rates are calculated here by assuming a closure temperature between 420 and 350 8C and minimum depositional ages. If we consider the youngest peak of 37 Ma for the Molare Formation as the regional signature recorded by sedimentary rocks from both the southern and western domains and 28.5 Ma as the minimum main depositional age, a lag time of 8.5 m.y. is obtained. This means that in 8.5 m.y., the sample cooled by 420–350 8C, yielding cooling rates of 49–41 8C/m.y. (Table 1). The youngest age of 32 Ma of the Molare Formation suggests that local fast cooling of ;100 8C/m.y. affected the Ligurian Alps during the Oligocene. This event only partially reset the regional late Eocene signature. Cooling rates in the Central and Western Alps averaged ,20 8C/m.y. and were locally as fast as 85–100 8C/m.y. (e.g., Giger and Hurford, 1989; Schlunegger and Willett, 1999, and references therein). We interpret our data as representative of cooling following the regional middle Tertiary HP-UHP metamorphism in the Western Alps and subsequent fast exhumation (e.g., Hurford et al., 1991; Monié and Chopin, 1991; Rubatto and Hermann, 2001). The presence of the 38 Ma signature in both the present-day river sands and the rock outcrops (Fig. 1B) suggests that the decrease in apparent cooling rates observed in progressively younger sedimentary rocks (Table 1) is not simply the result of reworking processes (e.g., Sherlock, 2001). The general persistence of youngest peaks and of youngest ages (ca. 38 Ma) indicates that the Eocene (prior to ca. 38 Ma) fast cool- Figure 4. Youngest peaks characteristic of each formation and present-day river sands. Black diamond—Tanaro River; open square—Stura River; open triangle—Maira River; open circle— Lequio Formation (Fm.); filled circle—Cassinasco Fm.; black triangle—Murazzano Fm.; cross—Cortemilia and Paroldo Fm.; open diamond—Monesiglio Fm.; black triangle—Rocchetta Fm.; filled triangle—Molare Fm. 603 ing and exhumation event was able to produce sufficient crustal material with a uniform Ar isotopic signature to supply .30 m.y. of erosive products to the Tertiary Piedmont Basin. Thus, erosion from the late Oligocene to the present was relatively slow, because it did not exhume deeper units with presumably younger isotopic ages. The slowness of the late Oligocene–Holocene erosion is in sharp contrast with the Eocene very fast cooling and exhumation event (e.g., Rubatto and Hermann, 2001). Our data show that a fast and short-lived tectonic exhumation event in the Western Alps produced a constant isotopic age signature in Tertiary Piedmont Basin sedimentary rocks for .30 m.y. CONCLUSIONS Our data set supports an episodic, fast, cooling and exhumation event prior to ca. 38 Ma followed by relatively slow and continuous erosion of crustal material with a uniform 40Ar/39Ar signature. Thus, we propose a rapid change in cooling and exhumation patterns within the Western Alps in the Eocene. This inferred abrupt change may correspond to the cessation of the major deformation in the Western Alpine domain. Our data further show a substantially different thermal history for the Western Alps when compared to the Central Alps, where thermal overprinting over the past 20 m.y. is widely recorded by different thermochronometers (e.g., von Eynatten et al., 1999; Spiegel et al., 2000). For the Western Alps, we suggest a pattern of episodic exhumation that cannot be reconciled by a steady-state model such as has been assumed to regulate the Alps (Bernet et al., 2001). Therefore, our new results not only shed light on regional differences in cooling and exhumation patterns within the Alpine orogen, but also highlight the need for studies that use different thermochronological systems in order to understand orogenic evolution in time and space. This study demonstrates that 40Ar/39Ar geochronology on detrital white micas can be applied with success to exhumation studies of orogens, because it yields detailed information on exhumation processes in the past. ACKNOWLEDGMENTS We thank the reviewers Mark Brandon, Yani Najman, Hilmar von Eynatten, and two anonymous readers for their constructive advice and Glen Murrell for the English review. Supported by the Netherlands Organization for Scientific Research (NWO). 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