CHEMISTRY 2.4 An assessment for AS90308

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CHEMISTRY 2.4

An assessment for AS90308

Describe the nature of structure and bonding in different substances.

Credits: Four

INSTRUCTIONS

Answer ALL questions.

© New Zealand Institute of Chemistry 2006

2

You should aim to spend about 40 minutes on this assessment

QUESTION ONE:

(a) (i) Circle the Lewis structures (electron dot diagrams) below that are NOT drawn correctly.

H

H

N H

H H

C C

H H

H C H

O

H O H H

Cl

C Cl

H

A B C D E

(ii) Describe the error and draw the correct structures for two of the structures circled above.

Structure letter

Description of error

(b) Draw Lewis diagrams for the following molecules:

(i) CH

3

OH (ii) N

2

Correct structure

Turn over

QUESTION TWO:

3

(a) Name the shapes of each of the four molecules whose Lewis diagrams are shown below.

O S

O

O

O O O H

H

P H

H

H

C H

H

Shape________________ _______________ _________________ ______________

(b) Discus the factors that determine the shape of a molecule with reference to the examples above.

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(c) Describe a polar bond.

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(d) (i) Label the molecules, whose Lewis diagrams are drawn below, as polar or non polar.

O C O O O

Polarity _________________ _______________________

(ii) Give reasons for your answers.

O S O

_____________________

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Turn over

QUESTION THREE:

4

(a) (i) Choose a solid from the list provided which matches each of the descriptions in the table below. Each substance can be used only once.

List: SiO

2

, NaCl, I

2

, Cu

Description:

1 A solid with a high melting point that conducts electricity.

2 A solid with a low melting point that does not conduct electricity.

3 A solid with a high melting point that dissolves in water.

4 A solid with a high melting point that does not conduct electricity.

Example of solid

(ii) Justify your answer to 1 and 2 above in terms of the structure and bonding within the solids.

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(iii) Explain why the solid chosen for 3 dissolves in water.

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(b) Discuss, in terms of structure and bonding within the compound, under what conditions lithium chloride would conduct electricity, and when it would not.

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Turn over

End of assessment

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