Protective and Decorative Acrylic-Based Technologies for Concrete Curing and Sealing Reach New Levels of Performance Valued for its durability, structural capabilities and aesthetic possibilities, concrete is a popular material for a wide range of interior and exterior commercial, industrial, residential and infrastructure applications. But whether it is used on a patio or a parking deck, proper curing and sealing are essential steps to ensuring the longest life possible for functional and decorative concrete materials. Dow Construction Chemicals has more than 30 years of experience in water-based chemistries, and we continue to lead the way in meeting exceedingly low volatile organic compound (VOC) regulations. We offer acrylic technology engineered to enhance performance of cure membrane, sealer, and cure and seal formulations – and we have application experts available to help you formulate the right products for your customers. Wherever your curing and sealing challenges take you … start here. 2 Solutions from Concrete Curing to Extended Surface Protection When concrete is first placed, keeping moisture in is the goal. But once it has cured, the challenge is to keep moisture out – particularly when the concrete will be subjected to repeated freezing and thawing. Beyond helping to keep this moisture balance in check, concrete cure membranes, cure and seal formulations, and sealers can each play a role in developing and protecting the long-term integrity of concrete materials in many other ways. Depending on the requirements of your application, our water-based and solvent-based technology platforms can be tailored to deliver strong performance in several areas, including: • Excellent water retention to help promote optimal hydration • Ultraviolet (UV) stability • Stain resistance • Long-term color enhancement • Cost-effectiveness • Adhesion Cure Membranes for Efficient Hydration Moist-curing is widely held to be the best method for concrete curing, but it is not always practical. However, liquid cure membranes from Dow offer an efficient and economical way to restrict moisture evaporation during the critical hydration process and promote proper curing when traditional techniques are not feasible. Applied to freshly placed concrete (within two hours), cure membranes form a film to slow water evaporation, enabling more extensive hydration of Portland cement. This increases the strength of the concrete and helps minimize shrinkage cracking. Most cure membranes are designed to wear off after 28 days when hydration is largely complete. A sealer may then be applied to provide more extensive protection to the concrete surface. Dow’s acrylic technology is an essential ingredient to form cure membranes, helping to improve key concrete properties. Dow Solutions for Cure Membranes Products Improved Membrane Performance RHOPLEX™ CS-3800 styrene-acrylic copolymer • • Hydrophobicity Meets ASTM specifications at low solids RHOPLEX CS-4000 acrylic polymer emulsion • • Excellent UV resistance Excellent exterior durability 3 We Can Help You Seal the Deal Sealers for Long-Term Protection and Beauty Sealers, applied to fully cured concrete (after 28 days), typically provide higher levels of protection and color enhancement to concrete surfaces over a longer period of time. Acrylic-based sealers work via a film-forming process, during which they form a coating (1-10 mils thick) on top of the concrete surface to help prevent water penetration and efflorescence and provide good stain resistance (see Figure 1). This differs from penetrating sealers, such as silanes and siloxanes, which react chemically with the concrete to form their water repellency. Figure 1: How Water- and Solvent-Based Sealers Work WATER-BASED SEALER water evaporation SOLVENT-BASED SEALER water evaporation continues solvent evaporation continues polymer particles deform and fuse together polymer particles solvent evaporation polymer chains entangle polymer chains water solvent concrete concrete concrete In water-based acrylic sealers, polymer particles are dispersed in water. During application, these particles move closer together as the water evaporates. As evaporation continues, the particles deform and fuse to eventually form a continuous coating. concrete concrete concrete concrete With solvent-based sealers, the polymer chains and the solvent form a continuous solution. During application, the polymer chains are drawn together and entangle as the solvent continues to evaporate, creating a continuous coating. Cleaner, Sturdier, Better Sealers based on acrylic polymer and resin technology from Dow Construction Chemicals fill in the gaps – literally. Besides improving the appearance of, and providing excellent stain resistance for, concrete applications, acrylic-based film-forming sealers greatly reduce water penetration, cracking and efflorescence when compared to unsealed concrete, as shown in Figure 2. Figure 2: Unsealed vs. Sealed Concrete 4 Unsealed Sealed Marks of Distinction While water- and solvent-based sealers have some differentiating characteristics, once applied and cured, they function in a similar way. Both types of sealers have these key attributes in common: • Toughness and durability – Providing resistance to stains, abrasion, water, chemicals and hot tire pickup (HTPU), waterand solvent-based acrylic sealers enable effective protection of concrete surfaces that can last for two to three years. • Application ease – Both water- and solvent-based acrylic sealers are available in fully formulated, ready-to-apply one-pack variations. They can either be sprayed or rolled on and will easily adhere with little or no surface preparation. Acrylic-based sealers can be applied to new or old concrete, unlike their silane- and siloxane-based penetrating sealer counterparts that cannot be applied to new concrete. • UV resistance – 100 percent acrylic sealers are fully transparent to UV light and will not undergo the photochemical breakdown experienced by more UV-absorbent polymers such as nonaliphatic polyurethanes and most epoxies. UV resistance enhances a sealer’s durability and protective qualities. • Easy removal – If acrylic-based sealers need to be removed, it is relatively easy – unlike epoxies and urethane-based sealers, which often require harsh chemicals and/or sandblasting to remove them. While acrylic-based sealers have a more glossy finish than other types, there are some subtle differences in the appearance of water- and solvent-based sealers (see Figures 3 and 4). Beyond appearance, distinctions between water- and solvent-borne systems have become more subtle as advances in technology are making it possible to offer both types of systems with very similar environmental and performance benefits. Every application has different requirements, and our technical experts can help you find the solution that is right for your sealer application. Figure 3: Water-Based Sealers Figure 4: Solvent-Based Sealers During application, water-based sealers appear milky white, and they typically cure to a lower-gloss, matte finish. Solvent-based sealers generally have a more glossy finish that enhances the color of underlying concrete. 5 Performance Attributes Performance attributes of both water- and solvent-based sealers are demonstrated in Figure 5. Figure 5: Dow Construction Chemicals Concrete Sealer Recommendations Water-Based Sealers Solvent-Based Sealers RHOPLEX™ EI-6000 RHOPLEX™ CS-4000 RHOPLEX™ WL-91 PARALOID™ B-66 PARALOID™ B-67 Formulation to 100 g/l VOC +++ + 0 + - Exterior Durability +++ ++ + ++ ++ Water Whitening Resistance ++ + + +++ +++ Hot Tire Pickup Resistance 0 + +++ +++ +++ Abrasion Resistance + ++ ++ +++ +++ Chemical Resistance + ++ +++ + + Hydrophobicity + ++ ++ +++ +++ Adhesion 0 + +++ +++ +++ Food Stain Resistance 0 + ++ +++ +++ Good for Interior Use √ √ √ √ √ Good for Exterior Use √ √ √ √ √ For Use on Vertical Surfaces √ √ √ √ √ For Use on Horizontal Surfaces √ √ √ √ √ +++EXCELLENT +GOOD ++ 0AVERAGE 6 VERY GOOD - POOR √ACCEPTABLE Cure and Seal for Maximum Convenience Cure and seal formulations, particularly popular for decorative concrete surfaces, are a quick and cost-effective way to achieve both effective curing and excellent short-term surface protection in a single step. Applied to fresh concrete, the cure and seal product acts initially as a cure membrane and then remains on the concrete surface, sealing and protecting it. Two core products from Dow combine the ability to retain water for curing purposes with long-term durability in sealer applications, delivering excellent performance in cure and seal formulations. In addition, both of these polymers are lowvoc capable. Dow Solutions for Cure and Seal Formulations Products Improved Cure and Seal Performance RHOPLEX™ CS-3800 styrenated acrylic polymer • Hydrophobicity RHOPLEX™ CS-4000 acrylic polymer • • Excellent durability High gloss Start Here with Dow Construction Chemicals Dow Construction Chemicals is the market leader and first choice for meaningful, innovative and differentiated solutions for the building and construction industry. We have the people, technology, reach and quality to help you meet your goals. People • Dedicated and reliable employees with application expertise • Responsive support with an extensive network of Technical Support Centers Technology • Broad portfolio of proven chemistry • Expansive network of world-class research capabilities • Analytical, toxicological and environmental capabilities • Innovative new technologies Reach • Building industry knowledge • Global organization with worldwide network • Reliable supply chain network Quality • Commitment to product quality and consistency • Operational excellence • Manufacturing know-how 7 Want to Learn More? Start Here. DowConstructionChemicals.com This document is designed as a general overview of Dow Construction Chemicals products. Always review specific product literature/safety data sheets for current information. Please contact your local Dow Construction Chemicals representative for detailed technical information applicable to individual requirements. 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