ACIDS ,BASES AND SALTS Q1.What are acids? Give name and chemical formula of some common acids. Give any three physical properties of acidic solutions. A=Acids are substances which release one or more H+ ions in aqueous solutions. a) Hydrochloric acid=HCl b) Sulphuric acid = H2SO4 c) Nitric acid = HNO3 d) Acetic acid = CH3COOH e) Phosphoric acid = H3PO4 Physical properties:- Acidic solutions are a)Sour to taste b)Change the colour of litmus from blue to red c)Conducts electricity Q2.What are bases? Give name and chemical formula of some common bases Give any three physical properties of basic solutions. A=Bases are substances which are capable of releasing one or more OH—ions in aqueous solutions. a) Sodium Hydroxide = NaOH b) Potassium Hydroxide = KOH c) Ammonium Hydroxide = NH4OH d) Calcium Hydroxide = Ca(OH)2 e) Barium Hydroxide = Ba(OH)2 Physical properties:- Basic solutions a) Tastes bitter b) Feels slippery c) Change the colour of litmus from red to blue d) Conducts electricity Q3.Give the name and formula of some common salts. give any three physical properties of salts. A= a) Sodium chloride = NaCl b) Sodium carbonate = Na2CO3 c) Potassium chloride = KCl d) Ammonium nitrate = NH4NO3 e) Potassium sulphate = K2SO4 Physical properties :a) Tastes salty b) Conducts electricity Q4.What are indicators. Explain with examples. Indicators are substances which indicate the nature of a particular solution whether acidic basic or neutral. Common acid base indicators Indicator colour in Neutral soln. colour in acidic soln colour in basic soln soln Litmus purple red blue Phenolphthalein colourless colourless pink Methyl orange yellow red orange Red cabbage juice purple red green Turmeric juice yellow yellow reddish or deep brown Q5.What are olfactory indicators A=The substances whose odour changes in acidic or basic media are called olfactory indicators Eg:- onion, vanilla essence, clove oil. Q6.How do acids react with metals? A=Metals displace hydrogen from acids to form salt and hydrogen. Zn(s) + H2SO4(aq) ZnSO4(aq) + H2(g) Mg(s)+ H2SO4 (aq) MgSO4(aq) + H2(g) Q6.How do bases react with metals. A=Metals like Zn,Sn,and Al react with strong alkalies to liberate H2 Zn(s) + 2 NaOH (aq) Na2ZnO2 (aq) + H2(g) Sn(s) + 2NaOH (aq) Na2SnO2(aq) + H2(g) 2Al + 2NaOH + 2H2O 2NaAlO2 (aq) + 3H2(g) Q7.How do metal carbonates react with acids? Give examples. A=Metal carbonates react with acids to evolve CO2 gas and form salts. Eg:- CaCO3 + 2HCl CaCl2 + H2O + CO2 Na2CO3 + 2HCl 2NaCl + H2O + CO2 Q8.How do metal bicarbonates react with acids? Give examples. A=Metal bicarbonates react with acids to evolve CO2 gas and form salts. Eg:- NaHCO3 + HCl NaCl + H2O + CO2 KHCO3 + HCl KCl + H2O + CO2 Q9.What will happen if CO2 is passed through lilme water first in small amount and then in excess? A=Lime water truns milky first due the the formation of insoluble calcium carbonate. Ca(OH)2 + CO2 CaCO3 + H2O The milkiness disappears when CO2 is passed in excess due to the formation of soluble calcium bi carbonate. CaCO3 + H2O + CO2 Ca(HCO3)2 Q10.What is meant by the neutralization ? A=The reaction between an acid and a base to give a salt and water is known as neutralization reaction. NaOH + HCl NaCl + H2O Base + Acid salt + water We can view neutralization reaction as H+ + OH-- H2O Q11.How do metal oxides react with acids? Give examples. A=Metal oxides react with acids to form salt and water CaO + 2HCL CaCl2 FeO + 2HCl FeCl2 + H2O MgO + H2SO4 MgSO4 + H2O Q12.Metallic oxides are said to be basic oxides whereas non metallic oxides are called acidic oxides. Explain with examples. A=Metallic oxides react with acids to form salt and water .ie metallic oxides are called basic oxides. CaO + 2HCl CaCl2 + H2O (basic oxide) (Metallic oxide) Non metallic oxides react with bases to form salt and water .ie Non metallic oxides are called acidic oxides.. SO2 + Ca(OH)2 CaSO3 + H2O CO2 + Ca(OH)2 CaCO3 + H2O (acidic oxide) (Non metallic oxide) note:- non metallic oxides dissolve in water to form acids ,metallic oxides form bases / alkali. Q13.Alcohols and glucose also contain Hydrogen,but are not referred to as acids.Explain. A=Compounds like alcohols and glucose do not undergo dissociation in water to form H+ ions.hence they do not exhibit the characheristic properties of acids. The aq solution of alcohols and glucose do not conduct electricity which shows that their aq solution do no contain ions. Q14.What happens to acids and bases in water solution? A= Acids dissociate in water to form H+ ions which exist as H3O+ ions. HCl + H2O H3O+ + Cl— (H+ + H2O H3O+) bases dissolve in water to give OH—ions. NaOH (H2O) Na+ + OH— Q15.What is an alkali? A=An alkali is a base that dissolve in water. Q16.Why does distilled water not conducts electricity where as rainwater does? A= Distilled water contains only negligible concentration of ions due to slight ionization of water.Therefore it does not conduct electricity. Rain water contains many impurities which are formed by dissolution of gases present in the atmosphere. SO2 + H2O H2SO3 CO2 + H2O H2CO3. These acids dissociate in rainwater to furnish appreciable conc. of ions. Due to the presence of these ions rainwater conducts electricity. Q17.What care must be taken while mixing conc. HNO3 / H2SO4 with water? A=The acid must be always added slowly to water with constant stirring. If water is added to conc. acids the heat generated may cause the mixture to splash out and cause burns. The glass container may break due to excessive heat. Q18.What is universal indicator? A=Universal indicator is a mixture of several indicators. This shows different colours at different concentrations of hydrogen ions in a solution. Q19.What is pH scale? A=A scale for measuring hydrogen ion concentration in a solution is called pH scale. PH is a number ( from 0 to 14 ) which indicates the acidic or basic nature of a solution. Higher the hydronium ion concentration lower is the pH value. .pH of neutral solution =7 .pH of acidic solution =less than 7 .pH of basic solution =more than 7 (pH + pOH of a solution =14., [H+] in neutral solution =10-7moles/litre [OH--] in neutral soln= 10-7moles/litre., [H+] in acidic solution > 10-7moles/litre [OH--] in acidic soln < 10-7moles/litre. [H+] in basic solution < 10-7moles/litre [OH--] in basic soln > 10-7moles/litre. [H+][OH--] = 10-14 , pH + pOH of a solution =14 Q20.Differentiate between strong acid and week acids? A=Acids with high degree of dissociation to give more H+ ions are said to be strong acids. Eg HCl Acids with low degree of dissociation to give less H+ ions are called weak acids. Eg:-CH3COOH HW Q21.Brirfly explain the importance of pH in everyday life. Q22.What will be the value of pH of a) salt of strong acid and strong base? b) Salt of strong acid and weak base? c) Salt of weak acid and strong base? A= a) Salt of strong acid and strong base are neutral with pH value of 7. Eg:-Na2SO4 b)Salt of strong acid and weak base are acidic with pH value less than 7 Eg:-CaSO4 c)Salt of weak acid and strong base are basic with pH value mare than 7 Eg:-CH3COONa , Na2CO3 Q23.How is NaOH prepared from NaCl? A= When electricity is passed through aq.solution of NaCl it decomposed to form NaOH 2NaCl (aq.) + 2H2O (l) 2NaOH (aq) + Cl2 + H2(g) Chlorine is liberated at anode H2 is liberated at cathode. This process is called Chlor-Alkali process. Q24.Explain the method of preparation of bleaching powder. A=Bleaching powder is produced by the action of chlorine on dry slaked lime. { Ca(OH)2 } Ca(OH)2 + Cl2 CaOCl2 + H2O. Q25.Give any three uses of bleaching powder. A= a)For bleaching cotton and in linen in textile industry, wood pulp in paper industry. b)As oxidizing agent in many chemical industries. c)For disinfecting drinking water. Q26.How is NaHCO3 prepared? A= It is prepared by passing NH3 and CO2 through NaCl solution. NaCl + H2O + CO2 + NH3 NH4Cl + NaHCO3 Q27.Why is NaHCO3 used in baking powder? A= Baking powder is a mixture of baking soda NaHCO3 and a mild edible acid such as tartaric acid. When baking powder is heated or mixed with water NaHCO3 reacts with acid to form CO2. NaHCO3 + H+ CO2 + H2O + Sodium salt of acid. CO2 produced causes the bread or cake to rise making them soft and spongy. Q28.How is washing soda prepared? A=By heating baking soda NaHCO3, Na2CO3 can be obtained. 2NaHCO3 Na2CO3 + H2O + CO2 Recrystallisation of Na2CO3 from water gives Na2CO3.10H2O (washing soda) Na2CO3 + 10H2O Na2CO3.10H2O Q29.Give any three uses of NaHCO3? A= a)For making baking powder b)For preparing antacids. c)In soda acid fire extinguishers. Q30.Give any three uses of washing soda? A= a)In glass ,soap and paper industries b)In the manufacture of borax c)As cleaning agent for domestic purposes, removal of permanent hardness of water. Q31.Define water of crystallization. Give examples. A= The fixed number of water molecules present in one formula unit of sat is known os water crystallization. Eg:- CuSO4.5H2O ,Na2CO3.10H2O , CaSO4.2H2O Q32.Explain the method of preparation of Plaster of Paris. A=Plaster of Paris is prepared by heating gypsum at 373k. CaSO4.2H2O CaSO4 ½ H2O + 1 ½ H2O Q33.When Plaster of Paris is mixed with water , it changes to a hard mass.Explain. A= On mixing with water plaster of Paris changes back to gypsum. CaSO4 ½ H2O + 1 ½ H2O CaSO4.2H2O Q34.What will happen if copper sulphate crystals are heated? A= When CuSO4.5H2O is heated it turns to white due to the removal of water of crystallization. CuSO4.5H2O CuSO4 Blue white If the crystals are mixed with water again blue colour of the crystals will reappear. …………………………………………………………………………………………..