Name ___________________ Period _____ Date _________ Chapter 8 and 9 Study Guide 1. Define the following terms a. Percent composition (sometimes called mass percent) b. Empirical Formula c. Molecular Formula d. Mole Ratio e. Stoichiometry f. Limiting Reactant g. Theoretical Yield h. Percent Yield i. Actual Yield j. Molar Mass 2. Calculate the percent composition of the element listed first in the formulas for each of the following compounds. a. H2SO4 b. Ca(OH)2 c. HC2H3O2 d. CO2 e. N2O f. NaOCl 3. Give the empirical formula that corresponds to each of the following molecular formulas. a. Na2O2 b. C8H6O4 c. C12H12N2O3 d. C4H6Cl2 4. A compound was analyzed and was found to contain the following percentages of the elements by mass: 89.56% barium; 10.44% oxygen. Determine the empirical formula. 5. A compound used in the nuclear industry contains uranium and fluorine. The compound is made up of 67.61% uranium. a. What is percent composition of fluorine? b. What is the empirical formula of the compound? 6. During excessive physical activity, lactic acid (molar mass = 90.08 g/mol) forms in muscle tissue and is responsible for muscle soreness. Elemental analysis shows that this compound contains 40% C, 6.71% H, and 53.3% O. a. Determine the empirical formula of lactic acid. b. Determine the molecular formula. 7. Consider the balanced chemical equation 4Al(s) + 3O2 (g) ® 2Al 2O3 (s) a. What mole ratio would you use to calculate how many moles of oxygen gas would be needed to react completely with a given number of moles of aluminum metal? b. What mole ratio would you use to calculate the number of moles of product that would be expected if a given number of moles of aluminum metal reacts completely? 8. For each of the following balanced chemical equations, calculate how many moles of product(s) would be produced if 0.500 mole of the first reactant were to react completely. a. 3H 2SO4 (aq) + 2Fe(s) ® Fe2 SO4 (aq) + 3H 2 (g) ( ) 3 b. SiCl 4 (l) + 2H2O(l) ® SiO2 (s) + 4HCl(g) 9. For each of the following unbalanced equations calculate how many grams of each product would be produced by complete reaction of 12.5 g of the reactant indicated in boldface. Indicate clearly the mole ratio used for the conversion. a. TiBr4 (g) + H2 (g) ® Ti(s) + HBr(g) b. SiH4 (g) + NH3 (g) ® Si3 N4 (s) + H 2 (g) c. Cu2S(s) ® Cu(s) +S(g) 10. Lead (II) Carbonate, also called “white lead,” was formerly used as a pigment in white paints. However, because of tis toxicity, lead can no longer be used in paints intended for residential homes. Lead (II) carbonate is prepared industrially by reaction of aqueous lead (II) acetate with carbon dioxide gas. The unbalanced equation is Pb C2 H3O2 (aq) + H 2O(l) + CO2 (g) ® PbCO3 (s) + HC2 H3O2 (aq) ( ) 2 Suppose an aqueous solution containing 1.25 g of lead (II) acetate is treated with 5.95 g of carbon dioxide. Calculate the theoretical yield of lead (II) carbonate. 11. According to his prelab theoretical yield calculations, a student’s experiment should have produced 1.44 g of magnesium oxide. When he weighed his product after reaction, only 1.23 g of magnesium oxide was present. What was his percent yield?