Chapter 6
Pg. 158-181
Ionic Bonding
Chapter 6 Section 1
Pg. 158-164
Stable Electron Configurations
• When the highest occupied energy level of an
atom is filled with electrons, the atom is stable
and not likely to react
• Noble gases are stable (have 8 valence
electrons)
– Argon: Greek work argos, means “idle” or “inert”
• Chemical properties depend on the number of
valence electrons
Stable Electron Configurations
• Electron dot diagram- a model of an atom in
which each dot represents a valence electron
– the symbol in the center represents the nucleus
and all other electrons in the atom
Stable Electron Configurations
Practice with Electron Dot Diagram
• Br
• Kr
• Ba
• As
Ionic Bonds
• Elements that do not have complete sets of
valence electrons tend to react, which allows
them to achieve electron configurations
similar to noble gases.
• Some elements achieve stable electron
configurations through the transfer of
electrons between atoms
Ionic Bonds
Transfer of Electrons
• Chlorine has one electron
fewer than an argon atom
• If Cl gains a valence
electron, it would have the
same stable electron
arrangement as argon
• Sodium has one valence
electron (1 electron more
than Neon)
• If Sodium lost this electron,
its highest occupied energy
level would have 8 electrons
• Na would then have the
same stable electron
arrangement as neon
• At the atomic level: an
electron is transferred from
each Na atom to a Cl atom;
each atom ends up with a
more stable electron
arrangement than it had
before the transfer
Ionic Bonds
Formation of Ions
• When an atom gains or loses an electron, the
number of protons is no longer equal to the number
of electrons.
• Charge on atom is neither balanced nor neutral
• Ion- an atom that has a net positive or negative
electric charge
• Charge is represented by a plus or a minus sign
Ionic Bonds
Formation of Ions
• Cl gains electron
– Has 17 protons and 18
electrons
– Ion has -1 charge because of
the 1 extra electron
– Cl1- or Cl-
• Na loses electron
– Has 11 protons and 10
electrons
– Ion has +1 charge because of
the extra proton
– Na1+ or Na+
Naming
• Anion- ion with a negative
charge
– Named: element name plus
suffix –ide
– Cl- : chloride ion
• Cation- ion with a positive
charge
– Named: just use the element
name
– Na+ : sodium ion
Practice Naming Ions
• Ca
• F
• K
• S
Ionic Bonds
Formation of Ionic Bonds
• Remember: opposite charges attract
• When an anion and cation are close together, a
chemical bond forms between them
• Chemical Bond- the force that holds atom s or ions
together as a unit (one)
• Ionic Bond- the force that holds cations and anions
together
• An ionic bond forms when electrons are transferred
from one atom to another
Ionic Bonds
Ionization Energy
• Cations form when
electrons gain enough
energy to escape from
atoms
• This energy allows electrons
to overcome the attraction
of the protons in the
nucleus
• Ionization Energy- the
amount of energy used to
remove an electron
• Varies from element to
element
• The lower the ionization
energy, the easier it is to
remove an electron from an
atom
• Ionization energies tend to
increase from left to right
across a period
• Ionization energies tend to
decrease from the top of a
group to the bottom
• Example: easier to remove
an electron from K than
from Na (K is more reactive
than Na)
Ionic Compounds
• Compounds that contain ionic bonds are ionic
compounds, which can be represented by
chemical formulas.
• Chemical Formula- a notation that shows
what elements a compound contains and the
ratio of the atoms or ions of these elements in
the compound
Ionic Compounds
• The chemical formula for sodium chloride is
NaCl
• From the formula, you can tell that there is
one sodium ion for each chloride ion in
sodium chloride
Ionic Compounds
• What would be the formula for magnesium
chloride?
• Mg cannot reach a stable electron configuration
by reacting with just one Cl atom, it must transfer
electrons to 2 Cl atoms
• Formula is: MgCl2
• Subscripts are used to show the relative numbers
of atoms of the elements present (if only one
atom of element, no subscript is needed)
Ionic Compounds
Crystal Lattices
• A chemical formula for an
ionic compound tells you
the ratio of the ions in the
compound, but it doesn’t
tell you how the ions are
arranged in the compound.
• Salt: pieces are shaped like
cubes
• This shape is a clue to how
the sodium and chloride
ions are arranged in the
compound
• Each chloride ion is
surrounded by 6 sodium
ions and each sodium ion is
surrounded by 6 chloride
ions
• Crystals- solids whose
particles are arranged in a
lattice structure; classified
into groups based on shape;
shape depends on
arrangement
• The arrangement of the
ions depends on the ratio of
ions and their relative size
Ionic Compounds
Ionic Compounds
Crystal Lattice
• Crystals of a ruby have a six-sided, hexagonal
shape
Ionic Compounds
Properties of Ionic Compounds
• High melting point
• In solid state, poor conductor of electric
current
• When melted, good conductor of electric
current
• Solid crystals shatter when struck with
hammer
Ionic Compounds
Properties of Ionic Compounds
• The properties of an ionic compound can be
explained by the strong attractions among ions
within a crystal lattice
• Recall: the arrangement of particles in a
substance is the result of 2 opposing factors
– 1. attractions among particles in the substance
– 2. kinetic energy of the particles
• The stronger the attractions among particles, the
more kinetic energy the particles must have
before they can separate.
Chapter 6 Section 2
Pg. 165-169
Covalent Bonds
• Energy is stored in the chemical bonds of
sugar
– Elements in sugar: Carbon, Oxygen, and Hydrogen
– All are nonmetals; transfer of electrons does NOT
tend to occur between nonmetal atoms
– So how are nonmetals able to form bonds?
Covalent Bonds
• You and a friend need a total of 10 dollars to
buy some food. You have $6 and your friend
has $4. Together you have $10, so in order to
buy the food you may put your money
together and share the food.
• When nonmetals join together, they display a
similar sharing strategy
Covalent Bonds
• Sharing Electrons
– H atom has 1 electron, but if it had 2, it would
have the same electron configuration as He
(therefore it would be stable)
– 2 H atoms can achieve a stable electron
configuration by sharing their electrons and
forming a covalent bond
– Covalent Bond- a chemical bond in which 2 atoms
share a pair of valence electrons
– When 2 atoms share one pair of electrons, the
bond is called a single bond
Covalent Bonds
Covalent Bonds
• Molecules of Elements
– Molecule- a neutral group of atoms that are
joined together by one or more covalent bonds
– The attractions between the shared electrons
and the protons in each nucleus hold the atoms
together in a covalent bond
– Chemical formula can be used: H molecule= H2
– Many nonmetal elements exist as diatomic
molecules
• Diatomic means “two atoms”
– 2 halogen atoms share a valence electron from
each atom, both atoms have 8 valence electrons
Covalent Bonds
• Multiple Covalent Bonds
– N has 5 v.e.
• if they shared a pair of electrons, each one would have
only 6 v.e.
• if they shared 2 pairs of electrons, each atom would
have only 7 v.e.
• Share 3 pairs of electrons, each atom has 8 v.e.
– Each pair of shared electrons is represented by a
long dash in the structural formula
Covalent Bond
• Multiple Covalent Bond
– Triple bond- when 2 atoms share 3 pairs of
electrons
– Double bond- when 2 atoms share 2 pairs of
electrons
– Single bond- when 2 atoms share 1 pair of
electrons
Unequal Sharing of Electrons
• In general, elements on the right of the periodic
table have a greater attraction for electrons than
elements on the left have (except for noble gases)
• In general, elements at the top of a group have a
greater attraction for electrons than elements at
the bottom of a group have
• Fluorine (far right, top of group): has strongest
attraction for electrons and is the most reactive
nonmetal
Unequal Sharing of Electrons
• Polar Covalent Bonds
– Electrons may not be shared equally
– Polar covalent bond: a covalent bond in which
electrons are not shared equally (polar- “opposite
in character, nature, or direction”
– When atoms form a polar covalent bond, the
atom with the greater attraction for electrons
has a partial negative charge. The other atom has
a partial positive charge (δ- and δ+ are used to
show which atom has which charge)
Unequal Sharing of Electrons
• Polar Covalent Bond
– In a hydrogen chloride molecule, the shared
electrons spend more time near the chlorine atom
than near the hydrogen atom
Unequal Sharing of Electrons
• Polar and Nonpolar Molecules
– The type of atoms in a molecule and its shape
are factors that determine whether a molecule is
polar or nonpolar
Unequal Sharing of Electrons
• Polar and Nonpolar Molecules
– Carbon dioxide (CO2)
• Double bonds between each oxygen atom and the
central carbon atom
• O has a greater attraction for electrons than carbon
does, each double bond is polar
• Molecule is linear: all 3 atoms are lined up in a row
– The carbon-oxygen bonds are directly opposite each other;
there is an equal pull on the electrons from opposite
directions; the pulls cancel out and the molecule as a whole is
nonpolar
Unequal Sharing of Electrons
• Polar and Nonpolar Molecules
– Water molecules (H2O)
• 2 single bonds in a water molecule
• The bonds are polar because O has a greater attraction
for electrons than hydrogen does
• The water molecules has a bent shape rather than a
linear shape, the polar bonds do not cancel out
• 2 H atoms are located on the same side of the
molecule, opposite the O atom
• O partial negative charge
• H partial positive charge
Attraction Between Molecules
• Attractions between polar molecules are
stronger than attractions between nonpolar
molecules
Chapter 6 Section 3
Pg. 170-175
Describing Ionic Compounds
• The name of an ionic compound must
distinguish the compound from other ionic
compounds containing the same elements.
The formula of an ionic compound describes
the ratio of the ions in the compound.
Describing Ionic Compounds
• Binary Ionic Compounds
– A compound made from only 2 elements is a
binary compound
• Bi- means 2
– The names have a predictable patter:
• The name of the cation (+) followed by the name of the
anion (-)
• Name for cation is the name of the metal without any
change
• Name for the anion uses part of the name of the
nonmetal with the suffix –ide
Describing Ionic Compounds
• Binary Ionic Compounds
Common Anions
Element
Name
Ion Name
Ion Symbol
Ion Charge
Fluorine
Fluoride
F-
1-
Chlorine
Chloride
Cl-
1-
Bromine
Bromide
Br -
1-
Iodine
Iodide
I-
1-
Oxygen
Oxide
O2-
2-
Sulfur
Sulfide
S2-
2-
Nitrogen
Nitride
N3-
3-
Phosphorus
Phosphide
P3-
3-
Describing Ionic Compounds
• Metals with Multiple Ions
– Alkali metals, alkaline earth metals, and aluminum
form ions with positive charges equal to the group
number
• Potassium ion is K+
• Aluminum ion is Al3+
– Many transition metals form more than one type
of ion
• When a metal forms more than one ion, the name of
the ion contains a Roman numeral to indicate the
charge on the ion
Describing Ionic Compounds
• Metals with Multiple Ions
Some Metal Cations
Ion Name
Ion Symbol
Ion Name
Ion Symbol
Copper (I)
Cu+
Chromium(II)
Cr2+
Copper(II)
Cu2+
Chromium(III)
Cr3+
Iron(I)
Fe+
Titanium(II)
Ti2+
Iron(III)
Fe3+
Titanium(III)
Ti3+
Lead(II)
Pb2+
Titanium(IV)
Ti4+
Lead(V)
Pb5+
Mercury(II)
Hg2+
Describing Ionic Compounds
• Polyatomic Ions
– A covalently bonded group of atoms that has a
positive or negative charge and acts as a unit
(one)
– Poly- means “many”
– most simple polyatomic ions are anions
Describing Ionic Compounds
• Polyatomic Ions
– 1 Nitrogen and 4 Hydrogen atoms
– Called an ammonium ion
– Joined by covalent bonds
– Positive charge because: N has 7 protons, each H
atom has 1 proton= 11 total; but the group only
has 10 electrons to balance the charge on the
protons – 8 v.e. and N 2 inner electrons
Describing Ionic Compounds
• Polyatomic Ions
Some Polyatomic Ions
Name
Formula
Name
Formula
Ammonium
NH4+
Acetate
C2H3O2-
Hydroxide
OH-
Peroxide
O2-
Nitrate
NO3-
Permanganate
MnO4-
Sulfate
SO42-
Hydrogen sulfate HSO4-
Carbonate
CO32-
Hydrogen
carbonate
HCO3-
Phosphate
PO43-
Hydrogen
phosphate
HPO42-
Chromate
CrO42-
Dichromate
Cr2O72-
Silicate
SiO32-
Hypochlorite
OCl-
Describing Ionic Compounds
• Writing Formulas for Ionic Compounds
– IF you know the name of an ionic compound, you
can write its formula
• Place the symbol of the cation first, followed by the
symbol of the anion
• Use subscripts to show the ratio of the ions in the
compound, all compounds are neutral
– Total charges on the cations and anions must add
up to zero
Practice Writing Formulas
for Ionic Compounds
Describing Molecular Compounds
• The name and formula of a molecular
compound describe the type and number of
atoms in a molecule of the compound
• Naming Molecular Compounds
– General rule: the most metallic element appears first
in the name (farther left on table), if both elements
are in the same group, the more metallic element is
closer to the bottom of the group
– The name of the second element is changed to end in
the suffix -ide
Describing Molecular Compounds
• Prefixes for naming compounds
Number of Atoms
Prefix
1
Mono-
2
Di-
3
Tri-
4
Tetra-
5
Penta-
6
Hexa-
7
Hepta-
8
Octa-
9
Nona-
10
Deca-
Practice Naming Molecular
Compounds
Describing Molecular Compounds
• Writing Molecular Formulas
– Write the symbols for the elements in the order
the elements appear in the name
– Prefixes indicate the number of atoms of each
element in the molecule
• Appear as subscripts in formula
• If there is no prefix for an element in the name, there is
only one atom of that element in the molecule
Practice Writing Molecular Formulas
• Formula for diphosphorus tetrafluoride
– Phosphorus- P, di=2
– Fluoride- F, tetra=4
P2F4
The Structure of
Metals
Chapter 6 Section 4
Pg. 176-181
Metallic Bonds
• Metal atoms achieve stable electron
configurations by losing electrons.
• There is a way for metal atoms to lose and gain
electrons at the same time.
– In metals: valence electrons are free to move among
the atoms
– In effect: metal atoms become cations surrounded by
a pool of shared electrons
• Metallic bond- the attraction between a metal
cation and the shared electrons that surround it
Metallic Bonds
• The cations in a metal form a lattice that is
held in place by strong metallic bonds
between the cations and the surrounding
valence electrons.
• Although the electrons are moving among the
atoms, the total number of electrons does not
change
• Overall, metal is neutral
Metallic Bonds
• The more valence electrons an atom can
contribute to the share pool, the stronger the
metallic bonds will be.
• Bonds in alkali metal are relatively weak
because alkali metals contribute only 1
valence electron (reason for being soft, and
low melting point)
• Transition metals have more valence electrons
to contribute, therefore are harder and have
higher melting points
Explaining Properties of Metals
• The mobility of electrons within a metal lattice
explains some of the properties of metals.
– Ability to conduct electric current and malleability
• Metal has a built-in supply of charged particles
that can flow from one location to another- the
pool of electrons
– Recall that a flow of charged particles is an electric
current
• Metallic bonds also explain why metals can be
drawn into thin wires (ductile) without breaking.
Alloys
• Alloy- mixture of 2 or more elements, at least
one of which is a metal
• Alloys have characteristic properties of metals
• Example: gold jewelry- often mixed with
harder metals (zinc, nickel, silver, etc.) to be
more resistant to wear
Alloys
• Copper Alloys
– 1st important alloy was bronze (associated with
era in history- the Bronze Age)
– Bronze contains only copper and tin, which are
relatively soft metals, but when mixed together,
the metals are much harder and stronger than
either alone
• Bronze is hard, durable, used in statues, propellers
– Scientists can design alloys with specific
properties by varying the types and amounts of
elements in an alloy
Alloys
• Copper Alloys
– Brass: contains only copper and zinc; softer than
bronze and easier to shape
– Brass is also shinier than bronze, but likely to
weather more quickly
Alloys
• Steel Alloys
– Alloy of iron that contains carbon
– Stainless steel: chromium and very little carbon,
more brittle than other steels that contain more
carbon
Alloys
• Other Alloys
– If a small amount of copper or manganese is
added to aluminum, the result is a stronger
material that is still lighter than steel.