6.1 Elements Combine to from Compounds Compounds form when two or more different atoms combine. Properties of compounds depend on which atoms are in the compound and how the atoms are arranged. Properties of compounds are different than that of just elements that make them up. Ex) Water is made out of Hydrogen and Oxygen, and H and O are both colorless gas at room temperature. But when these two elements make a compound, they are liquid at room temperature. Compounds always contain atoms with a specific ratio. Ex) Ammonia (NH3)has a 3:1 (3 to 1) ratio of hydrogen to nitrogen If this ratio was different, we would not have ammonia anymore. For example if we had a 1:3 ratio of hydrogen to nitrogen we would not have a compound called Hydrazoic Acid (HN3). Ammonia (NH3) Hydrazoic Acid (HN3) Chemical formulas like that for ammonia, NH3, uses the chemical symbols for the element to represent the atoms in a compound. Ex) Carbon dioxide has one carbon and two oxygens in it. Step 1: Find the chemical symbols for the elements Carbon—C Oxygen—O Write these side by side–CO Step 2: To show that there are two oxygens, you must write a “2” by it on the right in a subscript. Step 3: Now you have your compound—CO2 Counting Atoms Directions: 1. Write down the different elements in each compound. 2. Write down how many of that particular atom there are 3. How many atoms are there total in the compound. 2 H2SO4 2 Mg(SO)4 1) CH4 2) 4 HNO3 3) 4 Mg(OH)2 4) MgCl2 5) 4 Li2O 6) (NH4)3PO4 Bonding and Valence Electrons 1. Atoms bond because they want to be Stable ________________. Stable 2. Atoms are _____________ when they have 8 electrons in the outer shell. (Octet Rule) ___ 8 3. In order to get ___ electrons in the outer give shell, atoms _________, _________ take share or__________ electrons with/from other atoms. Noble Gases 4. The 18th Group, the _______________are already stable. Valence Electrons Electrons in the outer shell are called _________________electrons valence Valence electrons ____________________ are the electrons responsible for bonding two atoms together Noble gases are stable because they have 8 valence electrons; all other atoms ____ want the stability that noble gases have Valence Electrons (Continued) The number of Valence electrons can be group determined by the number of the ___________ Group #1 has ____ 1 valence electron; 2 valence electrons; Group #2 has ____ 7 valence electrons Group #17 has ____ Chlorine—Halogen Sodium—Alkali Metal Ionic Bonding Notes Ions are formed when atoms gain lose ______________ or ____________ electrons Losing ___________ electrons makes a positive ion Gaining ___________ electrons makes a negative ion 8 electrons Metals lose electrons to have ___ in their outer shell gain electrons to have 8 Nonmetals ______ electrons in their outer shell. Ionic Bonding Ionic bonds form when there is an attraction between positive and negative ions. We know that the Alkali Metals like to form positive ions (lose e-), and the Halogens like to form negative ions (gain e-). This means that if Sodium (Na) loses an electron, Chlorine (Cl) will pick it up. We now have a sodium ion (Na+) and a chloride ion (Cl-). These opposite charges will attract one another and they will bond and this is called an ionic bond. Ionic Bonding (Continued) Chlorine, a nonmetal, makes a negative ion Chlorine Sodium, a metal, makes a positive ion Sodium OPPOSITES ATTRACT Naming Ionic Compounds The name for the positive ion stays the same from the atom from which it was formed. The name for the negative ion is formed by dropping the last part of its name and adding the suffix “–ide” to it. To complete the name of the compound put the positive ion first followed by the negative ion. Ex) Table salt Na+ and Cl- come together to form NaCl Na+ is now “sodium” Cl- was chlorine, but since it is the negative ion it changes to “chloride” Result: sodium chloride Covalent Bonds covalent bond A __________is a pair of shared electrons nonmetals between two atoms that are________. When forming covalent bonds, neither gains loses atom ______or _____ electrons, so no ion is formed. Covalent bonds are often represented by a line between two atoms. Most common is the ball-and-stick model. Covalent Bonds (cont.) The number of covalent bonds that an atom can make depends on the number of Valence electrons ____________that it has. Ex) The Halogens (Group 17) and Hydrogen only 7 have ___valence electrons. This means that they can only form one covalent bond. 6 Ex) The atoms in Group 16 have ___ valence electrons. This means that they can from two covalent bonds. Remember that all atoms want to be stable and have 8 ____valence electrons. Ex) The atoms in Group 15 ( 5 valence e-) can form three ______covalent bonds. Ex) The atoms in Group 14 (4 valence e-) can from four ______ covalent bonds. Covalent Bonds (cont.) four Ex) Methane, CH4, can form _____ four covalent bonds because carbon has ____ valence electrons. These are all single bonds because carbon is sharing only one _____ pair of electrons with each hydrogen. Double Bonds When atoms share more than one pair of double bond valence electrons, a _________can from. two pairs A double bond forms when ________ of valence electrons are shared. Ex) The carbon atom in carbon dioxide, CO2, forms double bonds with each oxygen _________ atom. Triple Bonds A triple bond forms when an atoms share three pairs of valence electrons. ____ Ex) Two nitrogen atoms can because they have 5 valence electrons each atom, and they want 8. Because they want to get to 8, they each share 3 valence electrons. This results in the two 6 nitrogen atoms sharing ____electrons, or three pairs. N N A group of atoms held together by molecule covalent bonds is called a________. Molecules can have anywhere from two to thousands _________of atoms in them. Some molecules have only atoms of one element. diatomic These are called _______molecules. H2, N2, O2, F2, Cl2, Br2, and I2 Polar Covalent Bonds In a iodine (I2) molecule, both atoms are the same and the shared electrons are attracted equally to both nuclei. If the two atoms involved in a covalent bond very different are __________then some electrons will be attracted to one nucleus more than the other. A covalent bond in which the electrons are shared unequally is called a Polar covalent bond ______________. Remember that “polar” means that something has to extremes, like a magnet with to opposite poles. Polar Covalent Bonds (cont.) In a water molecule (H2O), the oxygen atom attracts electrons more strongly than hydrogen atoms do. Because oxygen has eight protons in its nucleus and the hydrogen only has one proton, the oxygen pulls electrons stronger towards it. This means that the oxygen side has a slightly negative charge and the hydrogen side has a slightly positive charge. Ionic Compounds Most ionic compounds have a regular crystal structure. Their structures depend on the ratio of their atoms and the sizes of the ions that make them up. Covalent Compounds Unlike ionic compounds, _______ compounds can covalent exist as individual molecules. Chemical bonds give each molecule a specific, molecular three-dimensional shape called its ________ structure. molecule Molecular structure can influence how a ________ interacts with other substances. Molecular structure can also affect how we detect them or how our bodies respond to them. Molecules with certain shapes will fit into certain receptors in our nose that we can smell. Some drugs work while other don’t because specific receptors in the body only allow certain shapes to fit. Lewis Dot Structures These depend on the number of valence electrons. These are the outer-most electrons. polar covalent bond ionic bond