Introduction to Metamorphic Petrology Recommended Textbook: J.D. Winter (2001) An Introduction to Igneous and Metamorphic Petrology: Prentice Hall Pub. Scope of Metamorphic petrology Metamorphic petrology is the study of the subsolidus changes that a rock undergoes when exposed to physicochemical conditions different from those prevailing near the surface of the Earth. Metamorphism produces changes in mineral assemblages and textures that reflect re-equilibration of the rock to the new physicochemical conditions, i.e., minimization of the energy of the system. Metamorphism is commonly isochemical (except for volatile components, e.g., H2O, CO2). Where the system is open, the process is referred to as metasomatism. Metamorphic Reactions Dehydration KAl3Si3O10(OH)2 + SiO2 = KAlSi3O8 + AlSi2O5 + H2O Muscovite Quartz K-Feldspar Sillimanite Decarbonation CaCO3 + SiO2 = CaSiO3 + CO2 Calcite Quartz Wollastonite Solid-Solid NaAlSi3O8 = NaAlSi2O6 + SiO2 Albite Jadeite Quartz Prograde and Retrograde Metamorphism Retrograde Path Prograde Path Metamorphic Facies A metamorphic facies is a domain of Pressure-Temperature Space Metamorphic facies are defined by characteristic mineral assemblages specific to particular bulk-rock compositions Conditions of Metamorphism and Metamorphic Facies Types of Metamorphism Contact or Thermal Metamorphism Regional Metamorphism Orogenic Metamorphism Burial Metamorphism Ocean Floor Metamorphism Hydrothermal Metamorphism (Alteration) Impact or Shock Metamorphism Contact or Thermal Metamorphism Contact Metamorphism of Limestone Limestone Marble Diabase Marble Limestone Thermally Metamorphosed Clastic Sediments Plagioclase Garnet Pyroxene Orogenic Metamorphism Orogenic Metamorphism Orogenic Metamorphism and differential stress Foliation (or Cleavage) and Lineation s1 s1 > s2 = s3 foliation and no lineation s1 = s2 > s3 lineation and no foliation s1 > s2 > s3 both foliation and lineation Onset of Orogenic Metamorphism Shale Slate Progressive Orogenic Metamorphism Phyllite Schist Progressive Orogenic Metamorphism Gneiss Anatexis Anatexis or Partial Melting of Metasedimentary Rocks (Migmatites) Burial Metamorphism Burial Metamorphism Subduction Metamorphism Paired Metamorphic Belts Amphibolite Facies Blueschist Facies Subduction Metamorphism Ocean Floor Metamorphism Ocean Floor Metamorphism Metamorphic Isograd Mapping (Index Minerals) Metamorphic Index Minerals Cordierite (Mg,Fe)2Al4Si5O18 (Porphyroblasts) Staurolite (Fe,Mg)2Al9Si4O23(OH) Garnet (Fe,Mg)3Al2Si3O12 The Aluminosilicates Al2SiO5 Andalusite Kyanite Sillimanite Sillimanite Metamorphic Isograds and P-T Paths Barrow Zones Buchan Zones Aluminosilcates as Indicators of Metamorphic Grade Metamorphic reactions and metamorphic grade Muscovite + Quartz = K-feldspar + sillimanite + H2O Muscovite Quartz Sillimanite K-feldspar Metamorphic Facies and Isograds Oslo: K-Feldspar- Cordierite Orijärvi: Biotite-muscovite 2 KMg3AlSi3O10(OH)2 + 6 KAl2AlSi3O10(OH)2 (Ms) + 15 SiO2 = 3 Mg2Al4Si5O18 + 8 KAlSi3O8 + 8 H2O Facies Series Pressure-Temperature-Time Paths