Lecture 1 – Basic Met Pet Announcements Syllabus is online Project – get two rocks, make thin sections, ID minerals, take photos, determine protolith, conditions of met. (generally). Turn in full description, with photos. Due in three weeks – no time to lose! Later: will do geothermobarometry, and make pseudosections. Objectives & schedule: under construction Field trip: 10/12-10/13. More info to come. Pre-course assessment (take 15 minutes). Textbooks Two needed to address phase equilibria and textures. Metamorphism = change What do metamorphic petrologists do? Try to deduce protolith Try to infer nature of metamorphic and deformation events Numerous ways of classifying metamorphism (ASK don’t’ TELL): Style Thermal Dynamic Dynamothermal Geologic Setting Contact Regional Contact Shock High-strain = fault / shear zone forms cataclasite (brittle) or mylonite (ductile) Regional Burial Ocean-floor / ocean-ridge Orogenic Tectonic Setting Plate interior contact, burial, regional (deep, and must be exhumed somehow) Divergent margin ocean-floor/ridge, contact Transform margin high-strain Convergent orogenic, dynamothermal, regional contact high-strain Agents of metamorphism Temperature (200 – melt migration) How do rocks heat up? Igneous Isothermal relaxation after burial (sedimentary or tectonic) Pressure How do rocks get pressurized? Burial Units SI unit for pressure is Pa = 1 kg m-1 s-2 Traditional: bars or kilobars (kb) 1 kbar = 0.1 GPa 1 bar ~ 1 atm 1 bar = 105 Pa = 100 kPa = 0.1 MPa What is the pressure under 1 km of granite ( = 2700 kg/m3)? P = g h At the same depth, under the same type of rock, how much greater is the pressure in the Himalayas (being squeezed) vs. in Kansas? (< 100 bars) Stress Leads to most textures Fluids typically H2O-CO2 solutions typically supercritical fluid under at least middle-crust conditions. can transport elements in or out of a rock = metasomatism generally liberated by reactions as temperature rises affects shape of reaction in P-T space Bulk composition determines the minerals that form (primary compositional effect) determines the position of reactions in P-T space (detailed compositional effect) determined by Protolith ± metasomatism Silicic (SiO2) quartzite Quartzofeldspathic (SiO2-Al2O3-CaO-K2O-Na2O-H2O) Greywacke Granitoid Feldspathic sandstone Pelitic (SiO2-Al2O3-FeO-MgO-K2O-Na2O-H2O) shale Calcareous pelite limey shale (marl) Carbonate (CaO-MgO-CO2) Limestone / dolostone Calc-silicate (SiO2-CaO-MgO-CO2-H2O) Limey sandstone reaction of granitic fluid & limestone (contact aureoles) Mafic (Spear: “basic”) (SiO2-Al2O3-FeO-MgO-Na2O-H2O-CO2) Mafic volcanics Volcanic sediments Ultramafic (SiO2-CaO-MgO-FeO-H2O) Peridotite Progressive metamorphism: P-T paths Orogenic metamorphism tectonic burial Barrow, Scotland: chl – bio – grt – sta – ky – sill Buchan: bio – crd – and – sill Suggestive of increasing grade (Temperature) – linked to each mineral Facies Eskola: found that the key was the set of minerals (assemblage) that are linked to PT conditions Facies = a set of metamorphic mineral assemblages, repeatedly associated in time and space and showing a regular relationship between mineral composition and bulk chemical compositions, such that different metamorphic facies (sets of mineral assemblages) appear to be related to different metamorphic conditions, in particular temperature and pressure, although other variables may also be important. Name all facies Describe parageneses (Qm assemblage of mineral phases) Correlate with Pelitic zones (Spear p. 16) Facies Series (varying P/T ratio) Very high P/T: Franciscan (z-pp-bs-ec) High P/T: Sanbagawa (z-pp-bs-gs-am) Medium P/T: Barrovian (ky – sil) Low P/T: Buchan / Abukuma (and – sil) Very Low P/T: Contact/Sanidinite Grade = Temperature Isograd = Reaction on the ground Note that many zonal boundaries are not isograds in a strict sense Combinations of many isograds in slightly different bulk compositions