Acids and Bases Unit 13 Acids 1) Acids start with hydrogen, and some react with active metals to liberate hydrogen gas. Ba(s) + H2SO4(aq) BaSO4 (aq) + H2(g) Properties of Acids 2) Acids change the color of dyes known as “acid-base indicators” Acids turn litmus paper turns red. Properties of Acids 1) Acids have a sour taste. Properties of Acids 4) Acids react with bases to produce salt and water. This is a neutralization reaction. Mg(OH)2 + HCl --> MgCl2 + HOH 5) Acids conduct electrical currents in an aqueous solution. Acids are electrolytes. 6) Acids produce hydrogen ions when dissolved in water. Bases 1) End with (OH) hydroxide 2) Change the color of acidbase indicators litmus paper: red blue 3) Bases feel slippery. Properties of Bases 4) 5) Bases react with acid to produce salt and water. This is called neutralization reaction. Bases are electrolytes. What? Bases produce hydroxide ions when dissolved in water. 6) Neutralization Reactions A reaction between traditional acids (hydrodium ions) and bases (hydroxide ions) produces water and one of a class of compounds called salts Acid Base Reactions 1. Salt- ionic compound composed of a OH- from an Arrhenius base and an H3O+ from an Arrhenius acid 2HNO3 + Ca(OH)2 Ca2+ (NO3-)2 + 2HOH H2S + 2NaOH Na2+ S2- + 2HOH Double Replacement What is pH? • A pH scale is how we measure how acidic or basic something is. • When we dissolve an acid in water, it ionizes and produces excess Hydrogen Ions, H+ • pH is formally how we measure the activity of those Hydrogen Ions in solutions. Where Do Common Substances Fall on the Scale? pH is a range that usually is expressed as going from 0 to 14, though it can go beyond that range. Acid Rain • Normal rain pH of 5.3 •Acid rain pH of 4.2-4.4 Acid Rain • Man-Made Causes – Burning of fossil fuels (coal production – yucky!) –carbon dioxide + water => carbonic acid Traditional Acid Definition: An Arrhenius acid is a chemical compound that increases the concentration of hydrogen ions, H+, in aqueous solution. HNO3 + H2O H3O+ + NO3- B. Acid- Base reactions- Arrhenius (traditional) Acid – Base Reactions • 1. An acid-base reaction occurs in aqueous solution between a strong Arrhenius acid that completely dissociates to produce H3O+, and a strong Arrhenius base that completely dissociates to produce OH− • HCl(aq) + NaOH(aq) NaCl(aq) + H2O(l) c. Their water solutions are known as aqueous acids. All pure aqueous acids are electroytes. HNO3(l) + H2O(l) HCl(g) + H2O(l) H3O+(aq) + NO3−(aq) H3O+(aq) + Cl−(aq) Traditional Bases Arrhenius base is a substance that contains hydroxide ions (OH ) and dissociates to produce hydroxide ions (OH-) into solutions NaOH(s) Na+(aq) + OH−(aq)