NOTE: This presentation was not made for public use. Please do not use this presentations without my permission and the permission of each of the authors of the photographs, quotes, and other materials that they contain. Thank you, Vicki Hughes Labs and Activities that go with this presentation: Glowstick Bracelets Marble, Cup, Spoon Catalyst Oozing Pumpkins CHEMICAL BONDING AND IONS BONDS…Chemical Bonds… …and Reactions Antoine Lavoisier: Law of Conservation of Matter “Matter is not gained or lost in chemical reactions.” Discovered the role oxygen plays in the combustion of matter. Annoying girlfriend Lavoisier O2 CO2 Chemical Formulas Na Sodium Sodium Chloride Cl Chlorine Chemical formulas tell you what elements are in a compound… H Hydrogen 2 1 Dihydrogen Hydrogen Oxide Oxide O Oxygen …and the number atoms of each element. Sometimes element names are mixed into one name. CH4 = methane OH = hydroxide Sometimes compounds have a special non-elemental name. Sometimes compounds have a chemical name and a familiar name. H20 = Dihydrogen oxide = water Familiar Name Chemical Name Chemical Formula Sand SiO2 Milk of Magnesia Silicon Dioxide Magnesium Hydroxide Mg(OH)2 Cane sugar Sucrose C12H22O11 Lime Calcium Oxide CaO Vinegar Acetic Acid CH3COOH Laughing Gas Dinitrogen Oxide N2O Table Salt Sodium Chloride NaCl When an element has a visible number following it to indicate more than one atom, the number is written in lower case and placed lower than the text line. This number is called a subscript. CH4 subscript Atoms are unstable if they have valence electrons that are unpaired. Remember, valence electrons are those that are in the outermost shell. To reach stability, atoms will bond with each other so all of the valence electrons are paired. Not paired Not paired Types of Chemical Bonds Remember, a Chemical Bond is the force that occurs when two or more atoms hold together. When one atom gives up an e- to another atom, ions are formed. The positive and negative charges caused by moving e-’s from one atom to another causes an attraction between the ions. The attraction bonds the atoms together in an IONIC BOND. Remember Lewis structures? Use Lewis structures to show bonding! + Na Describe what you just saw. Cl Sometimes atoms share electrons instead of gaining and losing them. This type of bond is called a COVALENT BOND. H O H Covalent sharing is not always equal. In water, the e-’s spend most of their time around the oxygen. A covalent bond in which the e-’s spend more time with one atom than the others is considered to be POLAR. Water is an example of a polar molecule. This unequal sharing creates a slight negative charge to one side of the molecule. The polarity of water makes it a very good solvent (can dissolve many other substances) because it can bond with lots of other atoms. Why does salt dissolve in water so easily? Multiple Bonds Triple bond N N When e-’s shift so that more than one pair is shared between two atoms, multiple bonds are formed. Remember, bonds are typically indicated with a line. Sometimes those lines are connected to form shapes. Chemical Bonding Animated Tutorials http://www.kentchemistry.com/links/bonding/bondingflashes/bond_types.swf Let’s Practice Making Bonds http://www.learner.org/interactives/periodic/groups_interactive.html Dot to Dot Puzzles HCl H2O CO2 (double bonds) CBr4 SO2 Li2S Bonus: N2O Step 1: Do Lewis structures. Na Cl Step 2: Put them together. Cl Dot to Dot Puzzles HCl H2O CO2 (double bonds) CBr4 SO2 Li2S Bonus: N2O Let’s Check It! http://www.drkstreet.com/r esources/metallic-bondinganimation.swf Metallic bonds involve a group of packed protons with a net of electrons covering them. Writing Formulas and Naming Compounds The charge on an ion is called its oxidation number. + Na Cl A binary compound is made of two elements. (Bi=2) NaCl Writing Formulas and Naming Compounds Metals always lose electrons. Nonmetals always gain electrons. NONMETALS METALOIDS METALS Gain e-’s become more negative Lose e-’s become more positive Oxidation numbers are the number of e-’s an element can gain (and become -) or lose (and become +). +1 +2 Oxidation numbers can be added to the periodic table…. METALS NONMETALS METALOIDS +3 +4 -3 -2 -1 Writing Formulas and Naming Compounds Special elements with more than one possible oxidation number. NAME OXIDATION NUMBER Copper (I) Copper (II) 1+ 2+ Iron (II) Iron (III) Chromium (II) Chromium (III) 2+ 3+ 2+ 3+ Lead (II) Lead (IV) 2+ 4+ Writing Formulas and Naming Compounds Ions alone have oxidation numbers… + Na Cl But when they combine, their compounds are neutral. NaCl Writing Formulas and Naming Compounds The oxidation numbers of the combining positive and negative ions must balance with each other. + Na Cl So that when they combine, their compounds cancel each other out. NaCl Writing Formulas and Naming Compounds You can name a binary ionic compound from the formula using these rules: ACT L8, L9 & L10 1. Write the name of the positive ion. 2. Check to see if the positive ion can have more than one oxidation number (see the previous table). If it has more than one, look at your formula and write the charge of the positive ion in roman numerals inside parentheses. Ex: Iron (II) 3. Write the root name of the negative ion. Ex: chlorine = chlor 4. Add the ending –ide to the root. Name this compound. 2+ Fe _ + 2F Fe(II)F2 Iron (II) Flor ide CHEMICAL REACTIONS Chemical Equations Scientists write out the reactions of combining chemicals as chemical equations using symbols from the periodic table. + + Na + Cl NaCl Chemical Equations Remember… The elements that are reacting with each other are called the reactants and are shown on the left side of the action arrow. + Na + Cl Reactants NaCl Products The compounds formed by the reaction are called products and are shown on the right side of the action arrow. Reduction-Oxidation Chemical Reactions Oxidation refers to a chemical reaction that commonly involves oxygen. Oxidation is a reaction in which an atom loses electrons. The atom that loses electrons is said to be oxidized. Examples: rusting of iron, burning of paper. Heat is usually given off. Which element is oxidized? Fe2O3 Reduction-Oxidation Chemical Reactions Reduction is the opposite of oxidation. Reduction involves the gaining of electrons and the element is negative. The element that gains e-’s is reduced. A reduced material takes electrons and heat is absorbed. Which element is reduced? Fe2O3 OIL RIG What this stands for is: Oxidation Is Loss of electrons Reduction Is Gain of electrons Redox is the shortened term used to identify a reductionoxidation reaction. Once upon a time… A wicked witch called Chemis cast a spell on all of Equazious turning the people into Trynots. The spell remained powerful as long as the people in the village of Ractant didn’t discover how to balance their wealth with the people of Produk, which was across the Arrow River. One day a young man named Steudint of the town of Balancia in the nearby mountains learned about a powerful potion. It was said this potion could balance the wealth of the two peoples and would create great harmony in the land forever. So Steudint searched the mountains for the ingredients in the potion and raced to the land of Equazious. However, because Chemis had learned of his plan, Steudint had to distribute the ingredients among the peoples to keep until the witch as not around. Once upon a time… Later in the season, Chemis left Equazius for a trip to visit her sisters who were also witches. While she was gone Steudint ran to the towns and told all the people who had been hiding the ingredients to quickly bring them to the river. As the people gathered on each side of the river, each holding a precious ingredient, Steudint told them that they must put the ingredients into the river. But, he said, if the ingredients were not placed in the river from each side in equal amounts the entire country would be thrown into chaos forever! Help the people of Equazius to balance the ingredients of the potion. Here are the sets of ingredients Steudint had given them. You can add new sets, but you can’t separate any set and no set can cross the river. 1 CH4 + 2 O2 1 CO2 + 2 H2O Here’s the what they did. Are the people saved?! Hint: Count the ingredients, not the sets. How does this formula relate to the “equation” demonstrated below? 1 CH4 + 2 O2 1 CO2 + 2 H2O Balancing Balancing Equations: Equations LEARN Step 1: Count the atoms in the reactants and in the products. Mg + O2 MgO 1 2 Magnesium is balanced…but Oxygen is not. 1 1 Balancing Equations: LEARN Step 2: Choose a coefficient to add more of the element that is not balanced. Mg + O2 2 MgO 1 2 1 2 2 1 The number you added indicating more than one atom of a particular element in an equation is called a coefficient. Let’s continue…Now oxygen is balanced, but magnesium is not. Balancing Equations: LEARN LEARN Step 3: Keep the first coefficient. Re-evaluate and now choose a coefficient that balances the second element. 2 Mg + O2 2MgO 21 2 2 2 Congratulations! Now everything is balanced! Balancing Equations: PRACTICE Ca + __F CaF2 Check Yourself Ca + 2 __F CaF2 Balancing Equations: LEARN Sometimes equations require a little more thought. HINT: Find the lowest common multiple of 3 and 2 to figure out how many of each ion you need. 2 Al3 + 3 O2 Al2O3 2x3=6 3x2=6 Balancing Equations: PRACTICE Practice: Write the formula for combining sodium and oxygen. Na + O2 Na2O Check Yourself 4Na + O2 2Na2O Polish your skill…Let’s play ChemBalancer. http://funbasedlearning.com/chemistry/chemBalancer/default.htm MORE PRACTICE ONLINE AT http://education.jlab.org/elementbalancing/ READY?…Balance the following equation. Li + H2O LiOH + H2 Answer: 2Li + 2H2O 2LiOH + H2 EOG L6 & L11 Matter and Energy in Chemical Reactions Reactant Reactant Reactants ENTER the reaction. Endo – inside Exo – outside Energy is absorbed or released by the reaction. Products are PRODUCED by the reaction. EXOthermic Reaction = RELEASES energy Reactant Reactant Reactants ENTER the reaction. EXOTHERMIC Energy is RELEASED by the reaction. Products are PRODUCED by the reaction. ENDOthermic Reaction = ABSORBS energy Reactant Reactant Reactants ENTER the reaction. ENDOTHERMIC Energy is ABSORBED by the reaction. Products are PRODUCED by the reaction. Exothermic Reaction = Releases Energy ACTIVATION ENERGY = energy required ENERGY to cause the reaction to occur. Energy RELEASED TIME Endothermic Reaction = Absorbs Energy ACTIVATION ENERGY = energy required to cause the reaction to occur. Energy ENERGY ABSORBED TIME Chemical Reactions and Catalysts Catalysts are special molecules that aid in making chemical reactions happen but are not used up themselves Catalysts reduce the activation energy! ACTIVATION ENERGY = energy required to cause the reaction to occur. ENERGY Activity: The marble, the cup, and the spoon. TIME Any Questions? ACT L11 Acids, Bases and pH PHET acid-base-solutions_en The pH Scale ranks the amount of hydrogen ions (H+) that are in a solution. pH Scale 0 1 H+ Gastric juice, 2 lemon juice H+ – H+ OH OH– H+ H+ H+ H+ 3 Vinegar, beer, wine, cola H+ 4 Tomato juice Acidic solution More hydrogen ions make the solution acidic. 5 Black coffee Rainwater 6 Urine OH– OH– – Less hydrogen ions make the solution basic. Battery acid H+ H+ OH OH– OH– + H H+ H+ Neutral solution Neutral [H+] = [OH–] Saliva 7 Pure water Human blood, tears 8 Seawater 9 10 Acidity and basicity are indicated by pH or litmus paper. OH– Milk of magnesia OH– OH– H+ OH– – OH– OH OH– + H Basic solution 11 Household ammonia 12 Household 13 bleach Oven cleaner 14 How do you neutralize an ACID spill? ACID BASE Indicator = changes color in response to change in pH ACT L12 pH Interactive Lab http://splash.abc.net.au/res/i/L5814/index.html STATES OF MATTER Changes in state = melting, freezing, evaporation, condensation, sublimation, deposition. ACT L13 BEHAVIOR OF GASES Kinetic Molecular Theory (of Gases) 1. constant, random motion 2. continuous movement in straight line until collision 3. mostly empty space 4. no attraction forces 5. elastic collisions (bounce) 6. kinetic energy depends on temperature Quizlet.com TJCA 8th Unit 2b Chemical Bonds and Reactions ACT L14 I’m diggin’ for questions! Got any? Let’s Get Chemical! Use the materials you have been given to design and perform tests showing each of the following physical characteristics of matter. Answer the questions and turn in your worksheet. Physical Property Materials to Use Conductivity wire, battery Magnetism magnets Malleability ball of foil Solubility salt, water Density of Liquids orange juice, tomato juice, pipet, clear cup pH lime juice, detergent, litmus paper Density of an irregular object marble, graduated cylinder, balance, water Density of regular object block, balance, ruler