2. Name: Partner: Date: Period: Flame Test ___________________ ___________________ ___________________ ____ Prelab Questions 1. What is the purpose of this lab? __________________________________________________________________________________ __________________________________________________________________________________ __________________________________________________________________________________ 2. What happens to some electrons in elements when we heat them to high temperatures? __________________________________________________________________________________ __________________________________________________________________________________ 3. What is a photon? __________________________________________________________________________________ __________________________________________________________________________________ 4. Which has more energy, red light or blue light? 5. Given the following equation, E=h, where is the frequency of the light emitted, we can calculate the energy of the light that is being given off. If h (6.626 x 10-34 Js) is equal to Planck’s constant, what is the energy of light with a wavelength of 560 nm? 6. What would happen to the energy of the photon if the frequency increases? _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ Flame Tests for Metals CP1~1213 Background Have you ever wondered why a candle flame is yellow? The characteristic yellow of a candle flame comes from the glow of burning carbon fragments. The carbon fragments are produced by the incomplete combustion reaction of the wick and candle wax. When elements, such as the carbon fragments, are heated to high temperatures, some of their electrons are excited to higher energy levels. These excited electrons then fall back to lower energy levels, releasing excess energy in packages of light called photons, or light quanta. The color of the emitted light depends on its energy. Blue light is more energetic than red light, for example. When heated, each element emits a characteristic pattern of light energies, which is useful for identifying the element. The characteristic colors of light produced when substances are heated in the flame of a gas burner are the basis of flame tests for several elements. In this experiment, you will perform the flame tests used to identify several metallic elements. Goals • Observe the colors emitted by various metal ions. • Identify metals through flame tests. Materials solid copper(II) chloride, CuCl2 solid sodium chloride, NaCl solid barium chloride, BaCl2 solid lithium chloride, LiCl Deionized water, H2O 9 Q-tips solid potassium chloride, KCl solid calcium chloride, CaCl2 solid strontium chloride, SrCl2 Unknown solid salt Bunsen burner Note: Always wear safety goggles when working in the lab. Do not taste any of the substances or touch them with your hands. Procedure As you perform the experiment, record your observations in Table 1. 1. Dip a Q-tip into deionized water. Using metal tongs, place the Q-tip into the flame of a Bunsen burner. Record your observations, then discard the Q-tip. 2. Dip a clean Q-tip into the deionized water, then dip the wet Q-tip lightly into the first solid. Using metal tongs, place the Q-tip into the flame of a Bunsen burner. Record your observations, then discard the Q-tip as directed by your teacher. 3. Repeat Step 2 for each solid, using a clean Q-tip each time. DO NOT RE-USE QTIPS or DOUBLE-DIP THEM. 4. Once you have observed the color of the flame for each of the known solutions, observe the color of the flame for an unknown solid salt. Can you identify the metallic ion in the solid? Fig. b Name: ____________________________________ Date: _____________________ Period: ______ Data Table Flame Tests Solution (Deionized water) Cation Anion --- --- Flame Color Sodium chloride, NaCl Potassium chloride, KCl Calcium chloride, CaCl2 Barium chloride, BaCl2 Strontium chloride, SrCl2 Lithium chloride, LiCl Copper (II) chloride, CuCl2 Unknown salt solution Questions 1) Does the color depend on the cation or the anion? Explain your answer using evidence from the data table. _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ 2) Would flame tests be useful for detecting metal ions present in a mixture of metal ions? Explain. _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ 3) List the metallic elements used in the flame tests in increasing order of the energy of the light emitted. _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________ 4) Consider the colors of flames produced by various metal ions. Is there a relationship between the energies of the light emitted and the positions of the elements in the periodic table? _________________________________________________________________________________________ _________________________________________________________________________________________ _________________________________________________________________________________________