Name_______________________________ HW-2b Due Date____________ Period______ 1. What is the speed of all forms of electromagnetic radiation? __________________________ 2. List all forms of electromagnetic radiation according to increasing frequency:_________________________________ __________________________________________________________________________________________________ 3. List the colors of light in the visible spectrum according to increasing energy:__________________________________ __________________________________________________________________________________________________ 4. Which theory of light, the wave or particle theory, best explains the following phenomena? a. the interference of light?_______________________ b. the photoelectric effect?______________________ c. The emission of electromagnetic radiation by an excited atom?________________________ 5. Distinguish between the ground state and an excited state of an atom:_______________________________________ __________________________________________________________________________________________________ 6. According to Bohr’s model of the hydrogen atom, how is hydrogen’s emission spectrum produced?_______________ __________________________________________________________________________________________________ __________________________________________________________________________________________________ 7. Solve for the frequency of light whose wave length is 4.257 x 10-7 cm.________________________________________ 8-9. a. What is the principle quantum number?_________________________________________________________ b. How is it symbolized?___________ c. What are shells?____________________________________________________________________________ d. What does n relate to the number of electrons allowed per main energy level?_________________________ 10. a. What information is given by the angular momentum quantum number?______________________________ b. What are sublevels, or subshells?______________________________________________________________ 11. a. What information is given by the magnetic quantum?_____________________________________________ b. What many orbital orientations are possible in each of the sublevels? s____ p____ d____ f____ 12. a. What information is given by the spin quantum number?_______________________________________________ b. What are the possible values for this quantum number?_______________________________________________ s= 13. a. Sketch the shape of an s orbital and a p orbital. p= b. How does a 2s orbital differ from a 1s orbital?__________________________________________________________ c. How do a 2px and a 2py orbital differ?_________________________________________________________________ 14-15. a. In your own words, state the Aufau principle.______________________________________________________ __________________________________________________________________________________________________ b. State Hund’s rule:_________________________________________________________________________________ __________________________________________________________________________________________________ c. State the Pauli exclusion principle_____________________________________________________________________ __________________________________________________________________________________________________ d. What is the significance of the spin quantum number?____________________________________________________ __________________________________________________________________________________________________ 16. Determine the highest occupied energy level in the following elements. He_____ Be______ Al______ Ca______ Sn_______ 17. Write the orbital notation for the following elements: F Na 18-19. Write both the complete electron-configuration notation and the noble-gas notation for each of the elements: a. Na b. Sr c. Cu 20-21. Identify each of the following atoms on the basis of its electron configuration: a. 1s22s22p5 c. [Ne] 3s23p5 b. [Ar] 4s1 d. [Ar] 4s23d6 22. Draw a chart showing the electron orbital filling order. 23-24. Write the short-hand (noble gas) notation for the electron configurations of each of the following elements: a. As b. Pb c. La d. Lr 25. How do the electron configurations of chromium and copper contradict the Aufbau principle?___________________ __________________________________________________________________________________________________ 26-28. a. Write the electron configuration for phosphorus: b. How many electrons are in each atom? c. What is the atomic number of this element? d. Write the orbital notation for this element: e. How many unpaired electrons does an atom of phosphorus have? f. What is its highest occupied energy level? g. How many inner-shell electrons does the atom contain? h. In which orbital(s) are these inner-shell electrons located? ______29. What is the maximum number of unpaired electrons that can be placed in a 3p sublevel? a. 1 b. 2 c. 3 d. 4 30. (Refer to the “photoelectric effect” in you book [p.99]) When blue light shines on potassium metal in a photocell, electrons are emitted. But when yellow light shines on the metal, no current is observed. Explain: __________________________________________________________________________________________________ __________________________________________________________________________________________________ __________________________________________________________________________________________________ __________________________________________________________________________________________________