Mississippi Chemistry Summative 2010 2A. CLASSIFYING MATTER Below is an atomic model. Table of Densities Element g/cm3 Scandium 2.99 Actinium 10.07 Palladium 12.02 Rhenium 21.04 1. Monique is trying to find the density of an unknown element. She found that the mass of the element is 24 grams and the volume is 2cm3. Using the table above what is the unknown element? A. Palladium B. Scandium C. Actinium D. Rhenium 2. Which of the following could be considered as a molecule, but not a compound? A. CH3OH B. I2 C. H2O D. Kr 3. Which of the following would be considered as an element? I. Hydrogen gas II. Liquid nitrogen III. Diamonds (made all of carbon) A. B. C. D. I, II, and III I and II I and III NONE OF THE ABOVE 4. What matter is displayed in the atomic model above? A. Element B. Compound C. Heterogeneous mixture D. Homogeneous mixture 5. Which of the following would be considered a homogeneous mixture? A. Salt water B. Strawberry yogurt with fruit C. Cooking Oil D. The metal alloy brass 6. Which of the following statements is TRUE? A. Atoms are the closest together in gases. B. Atoms have the most amount of internal energy in gases. C. Atoms have the least amount of molecular motion in gases. D. Atoms do not move in gases. 7. As molecules of a substance goes from a gas liquid solid, what happens to the molecular motion of the molecules? A. Molecules speed up. B. Molecules remain at constant speed. C. Molecules slow down. D. It is impossible to determine what happens to the molecules. The graph below represents the uniform cooling of a sample of lauric acid starting as a liquid above freezing point. 8. Using the graph above, what is the phase change that takes place from point C and B? A. Melting B. Freezing C. Condensation D. Sublimation B. Dalton used the Gold Foil Experiment to determine protons are in the center of the atom. C. Bohr used the Cathode Ray Experiment to determine protons are in the center of the atom. D. Thomson used the Cathode Ray Experiment to determine protons are in the center of the atom. 11. Which of the following researchers and their model is incorrectly paired? A. Thomson : Plum Pudding Model B. Rutherford : Nuclear Theory C. Dalton : Atomic Theory D. Bohr : Nuclear Theory 12. What element does the Bohr model below represent? 2B. HISTORY OF THE ATOM 9. Which best describes the current model of an atom? A. A solid sphere with electrons and protons embedded B. A solid sphere unique for everything that exists C. A central nucleus containing protons with electrons orbiting in specific paths D. A central nucleus containing protons and neutrons with electrons orbiting in levels of high probability 10. The most current model of the model is the wave-mechanical model. Which scientist discovered that the protons in the center of the atom and what experiment did he use to discover these particles? A. Rutherford used the Gold Foil Experiment to determine protons are in the center of the atom. A. B. C. D. Carbon Beryllium Boron Nitrogen 3A. ATOMIC STRUCTURE 13. The atomic number of an atom always equal to the number of its A. protons, only B. protons plus electrons C. neutrons, only D. protons plus neutrons 14. Which two particles make up both the nucleus and the atomic mass? A. electron and neutron B. proton and electron C. proton and neutron D. electron and positron 15. An atom in the ground state contains a total of 7 electrons, 7 neutrons, and 7 protons. Which Lewis electron-dot diagram represents this atom? 19. Which two notations represent different isotopes of the same element? 32 A. 73 Li and 73 Li C. 32 15 P and 16 S B. 14 7 32 15 Be and 146 Be P and 30 15 P D. 2D. NUCLEAR CHEMISTRY Which nuclear emission has the 20. 16. Which of the following electronic configurations for Nitrogen is written correctly? A. 1p2 2p2 2s6 B. 1s2 2s2 2p6 C. 1s2 2s2 2p1 D. 2p6 17. How many neutrons are in an atom of Iridium-192 (atomic number 77)? A. 115 B. 125 C. 92 D. 77 The atomic mass and percent natural abundance of each naturally occurring isotope of Neon are given in the data table below. 18. Using the data table above, which of the following equations could be used to find the average atomic mass of Neon? A. (.88 x 19.992) + (.12 x 21.991) = B. (.88 + 19.992) x (.12 + 21.991) = C. (88 x .19992) + (12 x .21991) = D. (88 + .19992) x (12 + .21991) = greatest penetrating power? A. gamma radiation B. alpha particle C. beta particle D. positron 21. Which nuclear emission has the greatest mass? A. B. C. + D. 22. In the third step of Uranium decay, Protactium-234 goes through BETA DECAY. Which equation represents the decay? 0 234 A. 234 91Pa1 e + 92 U B. 234 91 Pa 10 e 23490Th C. 234 91 Pa42 He + D. 234 91 Pa 42 He 23490Th 234 92 U 23. If 100g of Uranium-239 went through 2 half-lives, then how much is left? A. 50g B. 25g C. 120g D. 12.5g 24. The nucleus of a radium-226 atom is unstable. What does this cause the nucleus to spontaneously do as a result of the instability? A. absorb protons B. oxidize C. decay D. absorb electrons 2E. CHEMICAL BONDS D. Both B and C 30. Which covalent bond has the greatest polarity? A. H-C B. H-O C. H-N D. H-B 25. What type of bond would be predicted when Oxygen and Sulfur form SO2? A. isotopic bond B. ionic bond C. covalent bond D. hydrogen bond 31. What electrons are shared during a covalent bond? A. Excited electrons B. Electrons closest to the nucleus C. Valence electrons D. All electrons 26. What two types of atoms bond together in ionic bonding? A. nonmetal and nonmetal B. metal and nonmetal C. metal and metal D. metal and metalloids 32. Nitrogen, Phosphorus, and Arsenic all have the same expected charge of its common ion. What is this charge? A. 5B. 3+ C. 3D. 5+ 27. Which of the following describes what happens to valence electrons in metallic bonding? A. They become delocalized amongst all atoms. B. They are shared to fill s-orbitals. C. They are given from some atoms to others to fill their valence shells. D. They remain with their original atoms but bond 28. How many more electrons does a Hydrogen atom at ground state need to complete the octet rule? A. 7 electrons B. 1 electrons C. 2 electrons D. It already satisfies the octet rule. 2G. THREE-DIMMENSIONAL ATOM 33. What is the correct Lewis dot structure for arsenic? A. C. B. D. 34. Which Lewis electron-dot diagram is correct for S2- ion? 29. Which symbol represents a particle with a total of 7 electrons? A. B2+ B. F2+ C. B2- Below is a student Lewis Dot Diagram of COH2. 35. Which of the following statements is FALSE? A. The two hydrogen atoms are stable. B. The oxygen atom is stable. C. The carbon cannot form a double bond with oxygen. D. All the valence electrons have been used in the model. Below is a student Lewis Dot Diagram drawing of NH3. 36. What should the student do to finish the Lewis Dot Diagram above? E. Add a double bond between an N and H. F. Add a lone pair to the nitrogen. G. Do nothing because everything satisfies the octet rule. H. Substitute the nitrogen with boron and the molecule will be stable 37. In a molecule what is the behavior of valence electrons? A. Valence electrons move close to each other. B. Valence electrons move away to each other. C. Both A and B D. Valence electrons are neutral, so they have do not display attractive or repulsive behavior. 38. What is the name for the molecule below? A. B. C. D. Trigonal Pyramidal Tetrahedral Trigonal Planar Bent 3B. PERIODIC TRENDS 39. When you read the periodic table from left to right what trend generally DOES NOT occur? A. The number of protons increases B. The number of electrons increases C. The atomic size increases D. The number of neutrons increases 40. In a sample of 20 Oxygen atoms, it is found that 10 are 17O and 10 are 15O. What is the average atomic mass of Oxygen? A. 16.75 g/mol B. 16 g/mol C. 16.5 g/mol D. 15.5 g/mol 41. Fill in the blank. Elements of the same ___________ share the greatest chemical characteristics. A. Period B. Group C. Type of Metal D. Nature 42. What type of element has a low density, and a low melting point? A. Metals B. Nonmetals C. Metalloids D. Transition metals 43. From lowest to highest, in what order do elements best conduct electricity and heat? A. nonmetals, metalloids, metals B. metals, metalloids, nonmetals C. nonmetals, metals, metalloids D. metals, non metals, metalloids 44. Which of the following statements is INCORRECT? A. Nitrogen is more electronegative than Carbon. B. Chlorine is more electronegative than Iodine. C. Oxygen is more electronegative than Sulfur. D. Boron is more electronegative than Carbon. 45. Which of the following statements is INCORRECT? A. As you move down a group, ionization energy decreases. B. As you move down a group, electron affinity decreases. C. As you move across a period, ionization energy decreases. D. As you move across a period, electron affinity increases 3C. CHEMICAL REACTIONS 48. Which equation represents a decomposition reaction? A. LiOH + HCl LiCl + H2O B. 2 Na + 2 H2O 2 NaOH + H2 C. CaCO3 CaO + CO2 D. CH4 + 2 O2 CO2 + 2 H2O 49. What are the coefficients of the following equations? _______NaN3 (s) ____N2 (g) + ____Na (s) A. B. C. D. 1, 1, 2 2, 3, 2 2, 6, 2 1, 3, 1 50. Which of the following metals cannot replace Tin? A. Lithium B. Zinc C. Sodium D. Silver 51. What are the products of the single replacement reaction below? Cl2 + KBr _________ E. F. G. H. Br + KCl2 KBr + Cl2 Cl2 + KBr2 Br2 + KCl 46. What type of reaction is the following? 2AlCl3 +3H2 6HCl + 2 Al A. B. C. D. Combustion Double displacement Decomposition Single displacement 47. What type of reaction is the following? C3H8 + 5 O2 3 CO2 + 4 H2O A. B. C. D. Combustion Double displacement Decomposition Single displacement 3D. THE PERIODIC TABLE 52. What is the relationship between chemical reactions and chemical equations? A. A chemical equation represents a chemical reaction. B. A chemical reaction represents a chemical equation. C. Chemical equations and chemical reactions have no similarities. D. Chemical equations and chemical reactions are the same thing. 53. For the following balanced equation: MgCl2 + 2 NaOH 2 NaCl + Mg(OH)2 If 6 moles of NaCl are to be produced, how many moles of MgCl2 must react? A. 3 B. 6 C. 1 D. 2 54. What is the approximate molecular mass of Ca(OH)2? A. 72 amu B. 43 amu C. 74 amu D. 114 amu 55. What is the percent composition by mass of aluminum in Al2(SO4)3 (atomic mass = 342 grams/mole)? A. 7.89% B. 15.8 % C. 20.8% D. 36.0 % 56. What is the empirical formula for a compound that is 37.5% C, 12.5% H, and 50% O? (3D) A. C3HO4 B. CHO C. CH4O D. C6H25O6 57. Which is an empirical formula? A. C2H4 B. C3H6 C. P2O5 D. P4O6 58. What is the molecular formula of a compound with the empirical formula C4H4S and molar mass of 168 grams? A. C2H2S B. C8H8S C. C4H4S D. C8H8S2 59. How many molecules are inside 3 moles of Carbon? A. 12.04 x 1023 B. 6.02 x 1023 C. 18.06 x 1023 D. 24.08 x 1023 60. If you have 6 moles of Boron, then how many grams do you have? I. 11g J. 66g K. 99g L. 33g 61. If you 320g of Br2 then how many moles do you have? M. 1 moles N. 3 moles O. 4 moles P. 2 moles 4B. IDEAL AND REAL GASES 62. Kenny made an observation of nitrogen gas. He found that the gas moved at different speeds and the energy was conserved in the reactions. What can he conclude about the gas? A. The gas is a real gas. B. The gas is an ideal gas. C. We cannot conclude anything about the gas. D. The gas is in a supersaturated state. 63. What are the two differences of an ideal gas and a real gas? A. Real gases have attractive forces and have mass. B. Real gases do not have attractive forces and do not have mass. C. Real gases have attractive forces and do not have mass. 64. Real gases act most like ideal gas under what conditions? A. High pressure, high temperature B. Low pressure, low temperature C. High pressure, low temperature D. Low pressure, High temperature 4C. IDEAL GAS EQUATION 65. A tire with a volume of 10L drove from Convert 560K to Celsius. A. 833oC B. 287oC C. 560oC D. 14oC 66. Convert 2280mmHg to atm. A. 1 mol B. 2 mol C. 3 mol D. 4 mol 67. Determine the number of moles of gas in a 100L container at 800K and 4atm? A. 6.09 moles B. 100 moles C. 200 moles D. 60.9 moles 68. How many moles of air are there in a .125L Erlenmeyer flask if the pressure is 760 mmHg and the temperature is 20 °C? A. .0004 moles B. 4 moles C. .005 moles D. 5 moles 69. If I put 4 moles of Helium gas into a balloon at STP, then what will the volume of the balloon be? A. 92.6L B. 89.5L C. 102L D. 20.4L 70. A bag of chips in a truck travelled from 1atm and moved to a state with a pressure .5atm. If the volume of the bag started at 25mL, then what was its final volume assuming it had constant temperature and number of moles? A. 50mL B. 100mL C. 5mL D. 10mL 71. A scuba tank changed from 1 atm to 10atm as it sunk below the water. If the scuba diver’s tank started at 300K, then what is the tank’s new temperature? (Assume there are constant moles and volume) A. 4000K B. 300K C. 400K D. 3000K 4D. THERMODYNAMICS 72. A metal rod and brick are both in the sun. Assuming that both are the same mass, which property of matter will make one hotter to the touch than the other? A. Density B. Melting point C. Specific heat D. Boiling point 73. A chemical reaction releases 91.85 kJ of energy. During the reaction, 0.681 kg of the solution heats up from 93.5°C to 98.1°C. What equation would be used to solve this problem? A. PV=nRT B. Q=mcΔT C. Q=mΔHf D. Q=mΔHv 74. When you squeeze an instant hot pack, it breaks a little baggie inside. After shaking it, the contents mix and react to feel warm. Which of the following accurately describes the situation? A. vaporization B. endothermic C. enthalpic D. exothermic 75. If table salt (NaCl) is dissolved in water, which of the following is not necessarily accurate in describing the mixing process? A. Solution B. Electrolyte C. Supersaturated D. Soluble 4E. SOLUTIONS 76. If two liquids do not mix, which of the following terms applies? A. Miscible B. Solute C. Immiscible D. Solvent 77. Which of the following will NOT increase the solubility of a substance in a solution? A. Mixing the solute in the solution B. Crushing the solute C. Heating the solution D. Cooling the solution 78. If I dissolve 10g of SO2 is 100g of H2O at 10oC then what state will the solution be in? A. Saturated B. Supersaturated C. Unsaturated D. Equalized 79. What is the molarity of a solution that contains 0.202 mol KCl in 0.798 L solution? A. 3.95 M B. 0.596 M C. 1.00 M D. 0.253M 80. A reaction calls for 20 mL of a 0.8 M solution of potassium iodide. You only have 2M and 0.5M solutions in your stock cabinet. Which could you do to make your solution? A. Mix 10mL of each of the 2M and 0.5M solutions B. Obtain 8mL of the 2M solution and dilute it to 20mL C. Obtain 12.5mL of the 0.5M solution and dilute it to 20mL D. Add 15mL of 0.5M solution to 5mL of 2.0M solution 81. If a solution of ethanol (C2H5OH) is 6.5 M. what is the percent mass of ethanol in the mixture (water’s density is 1g/mL A. 6.5% B. 30% C. 23% D. 87% Use the equation below to answer the following questions. H2(g) + F2(g) ⇌2HF(g) 82. If the reaction is at equilibrium, and I add more H2, then what will happen to the reaction? A. The reaction will shift right. B. The reaction will shift left. C. The reaction will not shift. D. The reaction will shift left, then right. 83. If the reaction is at equilibrium, and I take away 2HF, then what will happen to the reaction? A. The reaction will shift right. B. The reaction will shift left. C. The reaction will not shift. D. The reaction will shift left, then right. 5A. ACIDS AND BASE PROPERTIES 84. Like litmus paper, cabbage juice changes color based on a substances pH. Therefore, both cabbage juice and litmus paper are what? A. Detectors B. Notifies C. Magic D. Indicators 85. Acids have a _________ taste, whereas bases have a __________ taste. A. bitter, sour B. sour, sour C. bitter, bitter D. sour, bitter 86. The pH of a solution was once 7 but now is 100 times more basic. What is its new pH? A. 5 B. 8 C. 9 D. 6 87. The pH of a solution changed from 2 to 3. What happened to the concentration of H+ ions? A. decreased by a factor of 10 B. increased by a factor of 100 C. increased by a factor of 10 D. decreased by a factor of 100 88. A reaction calls for 20 mL of a 0.8 M solution of potassium iodide. You only have 2M and 0.5M solutions in your stock cabinet. Which could you do to make your solution? A. 8mL of the 2M solution and add water B. 10mL of the 0.5M solution and add water 5C. OXIDATION AND REDUCTION 93. What type of reaction occurs in the following chemical equation? C. 8mL of the 0.5M solution and add water D. 10mL of the 2M solution and add water. 5B. BRONSTED-LOWRY AND ARRHENIUS 89. In the following reaction what does the role of water play? H2O + H2S HS– + H3O+ A. B. C. D. It is a BrØnsted acid It is a BrØnsted base It is both an acid and a base It neither an acid or a base 90. Which substance is an BrØnsted base in the following reaction? HF + NaOH H2O + NaFCH3Cl A. B. C. D. NaOH H2O NaFCH3Cl HF 91. What is the product of the neutralization reaction below? H2S + 2KOH A. B. C. D. KS + H2O H3O+ + SOK K2S + 2H2O The products cannot be determined 92. Which volume of 10 M NaOH(aq) exactly neutralizes 150 milliliters of 2 M HNO3 (aq)? A. 1.5 mL B. 3.0 mL C. 30 mL D. 7.5 mL Ca Ca 2+ 2e A. synthesis B. combustion C. oxidation D. reduction Use the following reaction to answer questions 49 and 50. 2C2H2 + 5O2 4CO2 + 2H2O 94. What is the oxidation state of Carbon in C2H2? A. -1 B. +1 C. -2 D. +2 95. What is the element that is reduced? A. H B. O C. C D. All of the above