Solutions Chapter 8 Objectives • Review key principles from previous chapters • Recognize how a solution differs from other types of mixtures • Name the different parts of a solution. • Distinguish how properties of solutions differ from properties of their original components. • Observe in an experiment how to separate the components of a solution. Things to Remember… PHYSICAL • A change in state is a ______________ change. • • EX) Chemical reactions REARRANGE _____________ bonds between atoms Law of Conservation of mass states that the ATOMS in the products must number of ___________ equal the number of atoms in the REACTANTS _________________. Things to Remember… COMPOUND • A ______________________ can be created through covalent or ionic bonds. A MOLECULE ________________ can only be created through a covalent bond (EX. Water Molecule). • The temperature at which a liquid becomes a solid is called its FREEZING POINT _____________________. The temperature at which a liquid rapidly becomes a gas is called its BOILING POINT ________________________. A Solution is a Type of MIXTURE 1. A solution is actually a HOMOGENOUS mixture because it ___________________ is the same throughout, but a solution SEPARATED by physical CAN be _________________ means. The substances in a mixture REACT CHEMICALLY DO NOT ____________ ____________. 2. All proportions of a solution have the SAME _____________. PROPERTIES _________ Solution or Not Kool-Aid is a SOLUTION!!!!! Water (by itself) is not a solution, but we can use water to make different solutions. Solute SOLUTE A. The ____________________ is a substance that is dissolved to make a solution. When it dissolves it separates INDIVIDUAL PARTICLES into _______________ ______________. Solvents SOLVENT B. The __________________ is a substance that dissolves a solute. WATER ______________ is the most commonly used solvent (We even call it the “Universal Solvent”) DID YOU KNOW???? • It is not possible to identify the solute and solvent as different substances when they form a solution!!! SOLUTES DISSOLVE IN SOLVENTS Types of Solutions 4. Solutions can be SOILD, LIQIUD, or GAS. • For example, Oxygen is a gas dissolved in sea water. • Page 240 Types of Solutions • Some solutions are in the same • physical state. For example: Vinegar is a solution of acetic acid and water. A. If solutions are in the same state of matter (EX. 2 Liquids), the substance present in the greatest amount is considered to be the SOLVENT ______________________. Types of Solutions • Do solutions ever exists as a solid??? • Yes, Bronze is a solid solution in which tin is the solute and copper the solvent. • Do solutions exists as gases??? • Of course, think about the air we breathe! Suspensions • In a suspension , the • particles are larger than those found in a solution. Instead of dissolving they are suspended. Solvent & Solute Particles Interact • The parts of a solution—that is, the solute and the solvent—can be physically separated because they are not changed into new substances. • However, individual particles of solute and solvent do interact. • The solute particles become evenly distributed throughout the solvent. Interaction continued… • The way compounds dissolve depends on the type of bonds in the compound. • Ionic compounds like table salt, split into individual ions. • Covalent compounds like table sugar, dissolve and each molecule stays together and is surrounded by solvent molecules. Properties of Solvents • In every solution, solutes change the physical properties of a solvent: LOWER – They always ___________________ the freezing point (Adding salt to roads during snow storms) RAISE – They always___________________ the boiling point (Adding antifreeze to your car) Lowering the Freezing Point • Page 243 Raising the Boiling Point • Putting salt in water can raise the boiling point. • The amount of salt in the water determines how much the boiling point is increased. • Example for both lowering and raising temperature: Antifreeze! • How do you think it works? Suspensions SUSPENSION 7. In a ___________________, the particles are larger than those found in a solution. EX) FLOUR IN WATER SOLUTIONS Suspensions are not ______________. 8.2 Objectives • Explain how the concentration of a solution varies. • Describe how a solute’s solubility can be changed. • Recognize that solubility depends on molecular structure. Concentration A solution’s CONCENTRATION depends on the amount of solute dissolved in a solvent at a particular temperature. EX) “Orange Juice Concentration” simply means how much juice is dissolved into water. Concentration Can Vary • A DILUTE solution has a low concentration of solutes (It has a higher level of solvents) • A SATURATED solution has a high concentration of solutes (It has a lower level of solvents) • You can raise the concentration by adding more SOLUTES or decrease the concentration by adding more SOLVENTS. • A SUPER SATURATED solution contains more solutes than is normally possible. SOLUBILITY 9. The SOLUBILITY of a substance is the amount of the substance that will dissolve in a certain amount of a solvent at a given temperature – If the solute is highly soluble, a saturated solution will be very CONCENTRATED. – If a solute has a low solubility, the saturated solution will be DILUTE. Changing Solubility • We can change the solubility of a solute. There are two different ways: – To dissolve more solid into a liquid, we simply raise the TEMPERATURE. The solid will dissolve quicker and more of it will dissolve in a given solvent. – To dissolve more gases into a liquid, we must increase the PRESSURE. Increasing the temperature of a gas will actually make it less soluble. Temperature • Increase in Temperature: – Solutes dissolves more quickly – Greater amount of solid dissolves in a given amount of solvent. – Page 249 Temperature & Gases The opposite is true for gases—an increase in temperature makes a gas less soluble in water. Pressure & Solubility • Cokes add CO2 gas at • a pressure slightly greater than normal air pressure. When you open the can, the pressure decreases and the Carbon dioxide bubbles out of solution with a fizz! • Scuba tanks include • 79% N. People breathe like this all the time without any problem, but the pressure underwater is much greater than on Earth’s surface. The higher pressure increases the solubility of N in the diver’s blood. Divers • When a diver heads up to the surface too fast, the pressure decreases, and so does the solubility of N. • The N comes out of solution and into the diver’s blood. These bubbles can cause painful and sometimes fatal condition called the “bends.” To Prevent The Bend’s • Divers can rise to the surface slowly, so bubbles stay small. • They can breathe a different mixture of gases, which contains only 66% of N. Temperature and Solubility Solute Increased Decreased Temperature Temperature Solid Increase is Solubility Decrease in Solubility Gas Decrease in Solubility Increase in Solubility This is how we make SUPER SATURATED solutions! Supersaturated Solutions Concentration • A solution’s concentration depends on the amount of solute dissolved in a solvent at a particular temperature. • Is it easier to make lemonade with or hot or cold water? Solubility Depends on Molecular Structure • When a substance dissolves, the molecules • • • separate from one another and become evenly mixed A POLAR substance attracts a POLAR substance to form solutions. “Like dissolves like” PAGE 251 What Would Happen???? • What would happen if I mixed water, oil and corn syrup in the same bottle? Do Oil and Water Mix? Review • Why will a nonpolar substance not dissolve in a polar substance? – Nonpolar solutes do not have a charged regions that would be attracted to charged regions of polar solvents. • How does pressure affect the solubility of solids? Of gases? – Solid and liquid solutes are not affected by pressure. An increase in pressure increases solubility of gases. Review • What effect does temperature have on most solid solutes? On gases solutes? – Increase in temp increases the solubility of most solid solutes. Increase in temp decreases the solubility of gases. What do these terms mean: dilute and saturated? Dilute- low concentration Saturated- Contains maximum amount of solute Acids, bases and salts Section 3 Chapter 8 Our learning goals for this section: •To learn about acids and bases •To learn how to determine if a solution is acidic or basic •To learn how acids and bases react with each other Acids & Bases Basics 12. Acids and Bases are formed when solutions are dissolved in WATER. When they dissolve they produce an ION, or charged particle. ******EX) If a hydrogen atoms loses its electron, it becomes positive (it’s actually just a PROTON.) 13. Acids and bases are classified based on their ability to either accept or donate these hydrogen ions (or PROTONS) How do we measure acids & bases • pH scale (pg 258) Properties Acids Bases Does it donate or accept hydrogen ions? Donates hydrogen ions Accepts hydrogen ions 0-6 8-14 Sour Bitter Burning/Itching Slippery pH Taste Touch Example HCl-Hydrochloric Acid NaOH-Sodium Hydroxide It is all about the IONS….. • Remember an ion is a charged particle. And if a hydrogen atom loses an electron it becomes a hydrogen ion. Which is simply a proton and has a positive charge. • An acid is defined as a substance that can donate a hydrogen ion (a proton) to H Osubstance. another 2 HCl → + H + Cl IONS CONT. • A base is a substance that can accept a hydrogen ion from another substance. H2O NaOH → Na+ + OH- • So just generally speaking the difference between an acid and a base is that acids donate protons and bases accept protons. • A~D • B~A…………….bases Characteristics of acids • Tastes sour • Strong acids are corrosive and poison • Hydronium ions in all acids • Variety of changes to indicators Characteristics of bases •Tastes bitter •Feels slippery •Strong bases can be corrosive and poison •OH- ion present in all bases Not all acids and bases are alike. They can vary in STRENGETH. -When a STRONG ACID is dissolved in water, it separates almost completely into ions (H+). -When a WEAK ACID is dissolved in water, it does not form many ions. -When a STRONG BASE is dissolved in water, it separates almost completely into ions (OH-) -When a WEAK BASE is dissolved in water, it does not form many ions. **PAGE 256 for examples Strong acid and weak acid Strong base and weak base Neutralization 16. Acids & Bases will NEUTRALIZE each other. The neutral pH is 7. ***The H+ collides with the OH- to create H2O!!! *** Other atoms will create the salts! The neutralization process • When you have an upset tummy your stomach is producing too much HCl. The pH is about 1.5. You take an antacid that contains a base and the base reacts with the acid to produce a salt and water. • So an acid + base gives a salt + water. • Two very harmful things come together to produce two very harmless things. • This is called the neutralization process. Explore acids and bases • What are some observations we can make about this cup of vinegar? • What happens when we add 2 crushed alka seltzer tablets? At the start of the demo looked like water but had a strong smell. After the addition of the alka seltzers the mixture fizzed and bubbles were produced. The vinegar odor was not as strong. So when you have a tummy ache you take an antacid to neutralize the acid being produced by the lining in your stomach. 8.4 Objectives You will learn -How metal alloys are made -How a variety of alloys are used in modern society -Why different alloys have different properties What is an alloy? • An alloy is a mixture of a metal and one or more other elements, usually metals as well. Making Alloys • First, we melt the metals • Then, mix them together • Finally, we allow them to cool to a solid • EX) Steel Alloy Properties • Alloys have different • • properties than the elements that make them up. The alloy BRONZE is harder than either copper or tin alone Nitinol (nickel & titanium) has the ability to form to a particular shape, be moved to another shape, and then reform to its original shape How Do We Use Alloys? • Steel makes up many • • • of our large buildings Steel makes up many of the ships we use (including cruise liners) Most vehicles are built with many types of alloys Medical Equipment is made of stainless steel Alloys are also used in Space Flight • They allow airplanes to be • • lightweight, yet strong Research on the space station has allowed scientist to make alloys in a microgravity environment The alloy research could lead to new innovations in robotics & creating artificial organs for humans