QUARTER 4 EXAM REVIEW – CHEMISTRY June 2015 Chapter 12 – Solutions 1. What are the different types of solutions? 2. What do the terms solute and solvent mean? 3. How can you distinguish between suspensions, solutions, and colloids? 4. What is the Tyndall effect? 5. What makes a solution an electrolyte or a nonelectrolyte? 6. How can the rate of dissolving a solid in a liquid be increased? What about a gas in a liquid? 7. What is meant by saturated, supersaturated, and unsaturated? 8. What is meant by the rule “like dissolves like”? 9. Be able to calculate molarity, molality and % concentration or solve for any missing parts of the equation. 10. What is the difference between exothermic and endothermic reactions? Which one has a positive heat of solution? A negative heat of solution? Which one increases the temperature of a solution? Which one decreases the temperature of a solution? 11. What do miscible and immiscible mean? 12. What is the % by mass of a solution prepared by dissolving 1.35 mol of calcium chloride in 550 mL of water? 13. What is the molarity of a solution prepared by dissolving 5.75 g of potassium iodide in enough water to make 125 mL of solution? 14. How many grams of glucose (C6H12O6) will be dissolved in 500. mL of water to make a solution that is 0.65 m glucose? Chapter 13 – Ions in Aqueous Solutions hydration conductors precipitation nonelectrolyte net ionic equation dissociation nonconductors precipitate spectator ions strong vs. weak electrolyte ionization aqueous solution electrolyte ionic equation hydronium ion 1. Write the equation for the dissolving of 0.75 mol of aluminum nitrate in water. How many moles of each ion are produced? How many TOTAL moles of ions are produced? What process is this called? 2. Write the equation(s) for the reaction between HCl and water. What is this process called? 3. Use the solubility rules to decide if a substance is soluble or insoluble in water. Do this for sodium nitrate, barium phosphate, and calcium sulfide. 4. Write the balanced equation, the ionic equation, and the net ionic equation for the reaction between aqueous solutions of aluminum sulfate and barium chloride. Also identify the spectator ions. 5. What is the boiling point elevation of a solution made by dissolving 35.0 g of glucose in 250 mL of water? What is the new boiling point of the solution? 6. What is the freezing point depression of a solution made by dissolving 7.6 g of sodium chloride in 100 mL of water? What is the new freezing point? Chapter 14 – Acids and Bases Arrhenius acid Bronsted-Lowry base conjugate acid amphoteric Arrhenius base Lewis acid conjugate base salt Bronsted-Lowry acid Lewis base neutralization 1. Be able to identify the type of acid or base involved in a reaction. What type of base is involved in the following reaction? HCl + H2O H3O+ + Cl- 2. Be able to label the Bronsted-Lowry acid, the Bronsted-Lowry base, the conjugate acid, and the conjugate base for a reaction. Be able to identify acid-base pairs and determine the direction the reaction is favored. Do so for the following equation: H2 CO3 + H2O HCO3- + H3O+ 3. Be able to write the balanced equation, the ionic equation, and the net ionic equation for a neutralization reaction. Also identify the spectator ions. Do so for the reaction between sulfuric acid and aqueous sodium hydroxide. 4. Be able to write the conjugate base or acid of a substance. What is the conjugate base of HCl? What is the conjugate acid of water? 5. Write the 2-step ionization for sulfurous acid? 6. Be able to write the formula of an acid when given its name and vice versa. Be able to do the same for bases. Determine whether and acid is monoprotic, diprotic, or triprotic and whether a base is monobasic, dibasic, or tribasic. 7. What are the main characteristics of acids and bases? Chapter 15 – Acid-Base Titration and pH self-ionization titration ionization constant (K) neutral standard solution pOH indicator acid end point pH transition interval base equivalence point 1. What are the pH and pOH values for acids, bases, and neutral substances? 2. What is the pH for each of the following solutions: A. [H3O+] = 1 x 10-4 M E. 0.04 M H2SO4 B. [H3O+] = 1 x 10-4 M F. 0.05 M NaOH C. [OH-] = 1 x 10-4 M G. [OH-] = 2.56 x 10-11 M D. 0.0025 M HCl H. 0.02 M Ca(OH)2 3. Be able to determine if a substance is acidic, basic, or neutral when given its hydronium or hydroxide concentration. 4. What is the concentration of hydronium and hydroxide in pure water at 25oC? 5. Determine the hydronium and hydroxide concentrations from the following values: A. pH = 9 D pH = 3 B. pH = 6.4 E pOH = 4 C. pOH = 10 F. pOH = 3.6 6. If the hydronium ion concentration is 1.5 x 10-6 M, what is the hydroxide concentration? 7. If 45.0 mL of 0.100 M HCl is used to neutralize 31.0 mL of barium hydroxide, what is the molar concentration of the base?