Gas Stoichiometry

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Gas Stoichiometry

Ideal Gas Law

Gas Stoichiometry

The Ideal Gas Law

• Putting It All Together

•PV = nRT n = moles P = pressure

Temp = must be in Kelvin

Volume = must be in Liters

Should be able to solve for any R but you won’t have to

• Use STP

Solving for R values

PV = nRT

1) Straight Ideal Gas law problem:

Sprinkled all over the AP => another way to get moles.

2) Problem: Got moles, Do stoich!

Sample Problem 1

• For an ideal gas, calculate the pressure of the gas if 0.215 moles occupies 338 mL at

32 ° C.

Sample Problem 2

• Acetic acid reacts with solid sodium carbonate.

• 5.00 grams of sodium carbonate is added to 20.0 mL of

1.50 M acetic acid. What volume of CO

0.878 atm and 23 ° C?

2 is produced at

Sample Problem 3

• Sodium metal is added to water.

• If 43.2 mL of hydrogen gas are produced at 767 torr and 59 ° C in excess water, how many grams of sodium were reacted?

Finding the Molar Mass of a

Gas

• Should be provided grams of the gas

• Use PV = nRT to find the moles

• MM = grams moles

Manipulation of the Ideal Gas Law

#1

PV = nRT n= mass mole mass so…….

PV = mass RT mole mass

Manipulation of the Ideal Gas Law

#2

PV = nRT n= mass mole mass

P = (mass R T)

(volume x mole mass) or

P = (density R T) mole mass

MM = DRT

P

Manipulation of Ideal Gas Law

• The density of a gas was measured at 1.50 atm and 27 ° C and found to be 1.95 g/L.

Calculate the molar mass of this gas.

Dalton Law of Partial Pressures

Key: P total

= P

1

+ P

2

+ P

3

+….

The total pressure = the sum of all the partial pressures

Dalton Law of Partial Pressures

Manipulation

P total

= P

1

+ P

2

+ P

3

+….

P total

= n

1

RT + n

2

RT + n

3

RT +…..

V V V

Sum of the moles of gases; who cares what they are

Application of Dalton’s Law of

Partial Pressures

HUGE!

Collecting pressure over water

P gas

P air

P water

Collecting pressure over water

P air

= P gas

P air

P gas

+ P water

P water

P water is dependent on temperature

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