Heat and Thermal Energy Iceland Volcanoes! The Thermal Energy of a substance is the total energy of all of its molecules and atoms. It consists of both the potential and kinetic energy of the molecules of the substance as they vibrate back and forth. Physics people usually call this internal energy. Temperature Scales Fahrenheit freezing at 32o, boiling at 212o Celsius freezing at 0o, boiling at 100o Absolute C + 273o There is not an absolute upper limit for temperature….the temperature inside of many stars is over 30 million degrees, and even higher temperatures are likely inside supernovas and black holes… The is an absolute lower limit. Gas samples (like the air inside a balloon) change their volume based on the temperature. At –273oC the volume of a gas sample will go to zero – this means basically that all molecular energy stops! We have been within a few tenths of a degree of this temperature, but will have difficulty actually reaching it. -273oC = 0o Kelvin = Absolute Zero! piston gas Zero volume! When pressure is held constant, the volume of a gas changes (decreases) by 1/273 for each degree C the temperature decreases. An assortment of absolute temperatures Some Definitions…. Matter can contain thermal energy (or internal energy). Heat is the flow of thermal energy – from a hotter object to a cooler one. Heat is thermal energy in transition. Heat! High Thermal Energy Low Thermal Energy There is no such physical property as Cold….. Cold is simply the absence of heat! How do we measure Heat?? Heat is a form of energy. A physics person measures heat in a unit called a Joule. We use a different unit: A calorie is the amount of heat required to to raise the temperature of 1 gram (1 cm3 or 1 ml) of water by 1oC. A Calorie (like we look at on the candy bar wrapper!) is really 1000 calories! Specific Heat Capacity The crust and the filling of the pie come out of the oven at the same temperature….. but the crust cools much more quickly. If you bite into a big bite of pie, you’ll probably burn your mouth! The part of the pie that has a lot of liquid (which is water!) “holds” its heat much longer than the crust. Some substances take more heat to warm up than others, and, once warmed, take longer to cool (give up their heat!) It takes much more energy to warm up a kilogram of water than it does a kilogram of oil! (or wood, air, glass, etc…!) The Eastern Shore has cooler summers and milder winters than the western shore because the Bay stores and gives up energy…! “Day after Tomorrow” web link Ocean current provide the major mechanism to transfer the excess of solar thermal energy from the tropics to the polar regions. When molecules of a substance are heated, they gain energy and “move” faster. This makes them push apart from each other and the volume of the substance expands. (volume is how much space something takes up!) This is called Thermal Expansion, and must be considered by engineers and architects! Not allowing for thermal expansion can cause problems….. What’s wrong with this picture?? The base of a landbased bridge has one side which can move! Most bridges have expansion joints which allow the sections of the bridge to move relative to each other “bi-metallic”strips can be used in thermostats to turn a device on or off as temperature changes An old-ish thermostat! Unique Properties of Water As water cools to near the freezing point, ice crystals start to form in it – decreasing the density! The water molecules (H2O) in ice are farther apart than they are in water. This makes the density of ice LESS Density = mass/volume! Normally, substances become more dense as they cool, and water does until it gets to 4oC – at which point ice crystals start to form and density decreases! This makes fish very happy…