SNC2D REVIEW Please Note: I did not teach this current class so I do not know what your teacher may have focused on. This review is an overview and does not cover specific details. This does not included everything that you may have covered and may include things you did not cover. STUDY TIPS Review and correct old tests. Try rewriting them. Go over unit review questions and self quiz sections Go over notes and make study notes. Write out key terms from each unit. Chemistry Review SNC2D Classification of matter Matter Pure Substance Compound Mixture Element Homogeneous Mixture Heterogeneous Mixture Particle Theory 1. 2. 3. 4. All Matter is made up of extremely tiny particles Each Pure substance has its own kind of particles, different from the particles of other pure substances Particles are always moving. Particles at a higher temperature are generally moving faster, on average than particles at a lower temperature. Particles attract each other Physical Properties Solid retain their shape. Have a fixed volume Liquid Gases Liquids take the shape Gases take the shape of their containers of the containers Have a fixed volume Volume can change. Chemical Properties 1. Combustibility is the ability of a substance to burn. In order to burn a substance requires Oxygen Chemical Properties Light sensitivity is a chemical property of that can cause new substances to form when light hits it. Chemical Properties 3. Reacting with an acid is a chemical property where when acid is poured on a substance it produces a gas and bubbles. Physical changes In a physical change, the substance involved remains the same. The substance may change form or state, however. All changes of state are physical changes. There are other physical changes that are not changes of state. Dissolving is a physical change. When sugar is dissolved it spreads out in the water but the sugar is still sugar. If the water was boiled off there would be sugar left over. Most Physical changes can be reversed. Chemical changes In a chemical Change the substance is changed into one or more different substances. The new substances have different properties from the original substance. Most chemical changes are difficult to reverse and most cannot be. The new substances are not likely to combine and form the original substance. Often during a chemical change you cannot see the change that has occurred in the substance, but you can observe the results of the change. There are clues that suggest that a chemical change has taken place. Clues that a chemical change has occurred Change in colour Final product(s) may have a different colour than the colours of the starting material(s). Formation of a solid (precipitate) Final materials may include a substance in a state that differs from the staring material(s): Precipitate Clues that a chemical change has occurred Formation of a gas Release or absorption of heat Final materials may include a substance in a state that differs from the staring material(s); commonly, a gas Energy (light, electricity, sound or most commonly heat) is given off or absorbed. The change cannot be reversed or it is difficult to. Important Features of the Table The elements are also organized in two fashions horizontal vertical and horizontal lines called groups and periods. Groups- elements with similar chemical properties in a vertical column in the main part of the table; Period – elements, arranged in a horizontal row, whose properties change from metallic on the left to non-metallic on the right Metals- left side of the periodic table The majority of elements on the periodic table are metals. All metals, except for mercury are solids at room temperature. Metals have the following properties. Malleable Lustre Ductile Conductors Non-Metals – Right side of the periodic table Most of the remaining elements in the periodic table are non-metals Non-metals generally have these properties: Non-conductor of electricity in its solid form At room temperature most are gasses or solids Solids are brittle and lack the lustre of metals Metalloids- middle right of the periodic table Some elements do not fit as metals or non-metals. These fit on either side of the staircase that divides the metals and the non-metals. They have some properties of metals and some properties of nonmetals. Group Names Alkali Metals: First group in the periodic table. Soft, Silvery coloured solids. React violently with water. Most reactive metal family Group Names Alkaline earth metals: Second group in the periodic table. Light React violently Group Names Transition metals: Theses metals have a wide variety of properties and reactivates. Hard, Strong Conduct electricity Group Names Representative elements: Groups 1,2 and 13-17. Metals and non-metals All states of matter found Follow periodic law. Group Names Halogens: Non-metals in group 17. Solids, liquids and gases Extremely reactive. Group Names Noble gasses: Gasses at room temperature. Low MP and BP Un-reactive Elements and Atomic Structure Atoms are composed of three subatomic particles Protons- Heavy positively charged particle found in the nucleus Neutrons -are neutral particles that have the same mass as protons and are located in the nucleus Electrons- Negatively charged particles with almost no mass. They circle the nucleus at different energy levels. The atomic number (Z) refers to the number of protons that are located in the nucleus of the atom. This number also provides the elements placement on the periodic table. If the atom is electronically neutral it will also contain the same number of electrons. ( x number of (+ive) protons + x number of ( -ive) electrons = 0 Charge Bohr Diagrams To represent electron arrangements at various orbits we use Bohr diagrams. Each orbit has a set number of electrons. Orbit # 1 2 3 4 # of Electrons 2 8 8 18 Every row in the period contains a shell. The farther you move down the table the more shells you added to the diagram. H = 1 shell, Li = 2 shells, K = 3 shells. Moving left to right on the periodic table adds valence electrons to the shells of that row. Na has 1 valence e-, Mg has 2 valence e-, Al has 3 valence e-, etc. how an ionic bond forms: • Example+ Li F Li F how an ionic bond forms: • Example 2 O Na Na Na O Na The Cross over rule • This rule allows you to figure out how many atoms you will need of each element for bonding to occur without the need to draw Bohr diagrams Cross Over Rule • Step 1. • Write the symbols, with the metal first (the element with the positive charge) • Mg I • Step 2. • Write the Ionic charge above each symbol to indicate the stable ion that each element forms. 2+ 1Mg I Cross Over Rule • Step 3. Draw an arrow from the metals charge to the non-metal and an arrow from the non-metal charge to the metal. (Cross over the arrows) 2+ Mg 1I Cross Over Rule • Step 4. Fill in the number of atoms from each element will have by following the arrows. If need be reduce to lowest terms (in other words, if they are the same number, you don’t write those numbers down because you could divide the whole molecule by that number which would = 1) MgI2 • (if the number crossed is a 1, the 1 is not shown) Ionic Binary Compounds: IUPAC Naming Consists of two types of monoatomic ions 1. The metal ion is always written first and retains its whole name 2. The non-metal is written second and has a slight change, the ending (suffix) is changed to –ide Do not write ones (Ex Na1Cl1) and if both elements have the same number reduce to lowest terms (Ca2O2 = CaO) Example Example: Na+ Cl- use the cross over method NaCl IUPAC name: sodium chloride The metal name is written in full and the non-metal has the –ide suffix added to it. Sodium chloride Ionic Multivalent Binary Compounds A multivalent compound is one that may have varied numbers of electrons in its valence shell. This occurs with elements that fall outside of the representative elements. The transition metals are elements that commonly have multiple valence shell electrons. This means that they can form compounds in various proportions. Example: Copper + Oxygen Copper and oxygen could have two different formulas with two completely different properties. CuO and Cu2O In order to differentiate the two compounds we must use a different method to name them to avoid confusion. Ionic Multivalent Binary Compounds: IUPAC Naming Same as Ionic Binary but it indicates the metals charge List the metal name first After the metal name indicate the ion charge in brackets using roman numerals. The non-metal has -ide suffix added. Polyatomic Ions • Polyatomic Ions are ions that are composed of more than one atom. The entire molecule carries a charge to it. Polyatomic Ions • Example- NO3 - SO4 O 2- PO4 2- O 3- O S O O P O O O 3- Bonding • Ionic Bonding with polyatomic ions occurs in the same manner as it does with binary atomic molecules. – Use the crossover method – Be sure that the charge that is crossed over applies to the whole polyatomic ion. If the charge is greater than 1, use brackets around the polyatomic ion to indicate the number applies to the whole ion. Example 1 Step 1 Na + NO3- Step 2 1+ Na Step 3 1- 1+ NO3 Na 1NO3 Step 4 NaNO3 Naming Ionic Polyatomic compounds: IUPAC • Multivalent: Metal (charge) polyatomic ion • Monovalent: Metal polyatomic ion • Tertiary ionic compounds are comprised of a metal ion and a polyatomic ion. Write the polyatomic ions in the same way as monatomic ions. Examples • NaOH = – sodium hydroxide • Cu(ClO4)2 = – copper (II) perchlorate • Tin (IV) chlorate = – Sn (ClO3)4 Oxyanions • Oxyanions = a polyatomic ion that includes oxygen. • Their name depends on how many Oxygen’s it has in the poly atomic ion. Oxyanions • Example • ClO- hypochlorite ion hypo-_________-ite • ClO2- chlorite ion ___________-ite • ClO3- chlorate ion __________-ate • ClO4- perchlorate ion per-_______-ate • • This also applies to Br and I Naming Binary Molecular Compounds: IUPAC Write down the name of the first element. If there is more than one atom of this element attach a Greek prefix. (if there is only one atom do not attach the prefix) Attach a Greek prefix (relating to the number of atoms) to the second elements name and add ide. Example: CO = Carbon monoxide CO2 = Carbon dioxide Word Equations examples. Silver nitrate + copper silver + copper (II) nitrate Reactants Products Hydrogen + Oxygen water vapour Reactants Products The Conservation of Mass Build This Balancing Equations Methane + oxygen water + carbon dioxide CH4 + O2 H2O + CO2 CH4 + 2O2 2H2O + CO2 Types of chemical reactions 1. Combustion Reaction - The reaction of a substance with oxygen, producing oxides and energy • Fuel + oxygen oxides + energy • AB + oxygen common oxides of A and B (ex AO, BO) 2. Synthesis Reaction • -A chemical reaction in which two or more substances combine to form a more complex substance. • A + B AB • Example: • 2CO(g) + O2(g) pt 2CO2(g) 3. Decomposition reaction • -A chemical reaction in which a compound is broken down into two or more simpler substances. • AB A + B • Example: The decomposition of water. • 2H2O(l) + electricity 2 H2(g) + O2(g) Chemical reactions in solution • A Solution is a homogenous mixture in which a pure substance, called the solute, is dissolved in another pure substance called the solvent. • • The solution is often an aqueous solution which is a solution where water is the solvent. 4. Single Displacement reaction • -A reaction of an element with a compound to produce a new element and a new compound. The reaction will only occur if the element is higher on the reactivity series than the metal in the compound. • A + BC AC + B • Example: • Cu(s) + 2AgNO3(aq) 2Ag(s) + Cu(NO3)2(aq) 5. Double displacement reaction • - A reaction in which aqueous ionic compounds rearrange cations and anions, resulting in the formation of new compounds. • AB + CD AD + CB • Example: • Pb(NO3)2 (aq) + 2KI (aq) PbI2 (s) + 2KNO3 (aq) Double displacement is likely to occur if; • - a precipitate is produced • - a gas is produced • - a acid base neutralization occurs 4 Factors that affect rates of reactions Temperature When the reactants are heated, they bounce and contact more vigorously with other reactant molecules. This increases the number of successful collision and the rate of reaction. This is the most important factor. 4 Factors that affect rates of reactions Concentration Concentration is defined as the number of molecules of reactants per unit volume. The more the concentration of reactant molecules, the higher the probability of collision due to their sheer number. Excess concentration may have no effect if one of the reactants is used up. 4 Factors that affect rates of reactions Surface Area By increasing surface area, the number of molecules exposed for collisions is increased. This allows more collisions between molecules to occur and increases the rate of reaction. 4 Factors that affect rates of reactions Catalyst Catalysts, are chemicals or substances that catalyze or promote a chemical reaction to occur and remaining unchanged in the end. They are like parts of an assembling mechanism that help making the final product but then detach themselves from it. They lower the activation energy. You can identify an acid from its name or from its chemical formula. Usually, the name of an acid ends with the word “acid.” If you are given the chemical formula of a substance, you know that it is an acid if: 1. the chemical formula starts with H (the symbol for a hydrogen atom) OR 2. the chemical formula ends with COOH (the formula for a carboxyl polyatomic ion) Example – HF(aq) hydrofluoric acid, CH3COOH(aq) acetic acid. There are two rules for naming acids when the chemical formula of an acid starts with H and has only one other non-metallic element Step Examples HCl 1. Start with the Prefix “hydro” (aq) hydro HF (aq) Hydro 2.To the first part of the name of Hydrochl Hydroflu the non-metallic element, add oric acid oric acid the suffix “ic” and add the word “acid” Some acids contain a polyatomic ion. When the polyatomic ion in an acid contains an oxygen atom (O) and its name ends in “ate”, the acid can be named by the steps shown below. Step 1. Start with the name of the element in the polyatomic ion that is not oxygen 2.Add the suffix “ic” and the word “acid” Examples H2SO4(aq) H3PO4(aq) sulphur phosphorus sulphuric acid phosphorus ic acid Table 1 Examples of common acids include Common name Formula Source or use Vinegar (acetic acid) HC2H3O2 or HC2H2OOH Salad dressing Citric acid HC6H7O7 Oranges, lemons Ascorbic acid HC6H7O6 Vitamin C Lactic acid HC3H5O3 Sour milk or tired muscles Sulfuric acid H2SO4 Car batteries A base can also be identified from its name or its chemical formula. A substance is a base if its name begins with the name of a metallic ion and ends with the word “hydroxide.” A substance is also a base if: the chemical formula starts with a metallic ion or with the ammonium ion NH4+ AND the chemical formula ends with OH (called a hydroxyl group) The name of a base can be determined from its chemical formula by following the steps shown in Table 5.5. Notice that all bases (in this class) are followed by the word “hydroxide.” Step Examples KOH (aq) NH4OH (aq) 1. Write the name of the positively charged metallic ion that is at the beginning of the chemical formula. This step remains the same if the positively charged ion is a polyatomic ion. Potassium Ammonium 1. Add the word “hydroxide” Potassium hydroxide Ammonium hydroxide Common Name Formula Source or use Sodium hydroxide NaOH Drain cleaner Potassium hydroxide Aluminum hydroxide Ammonium hydroxide Sodium bicarbonate Potassium sulphite KOH Soap, cosmetics Al(OH)3 Antacids NH4OH Window cleaner. NaHCO3 Baking soda, used in baking Food preservative K2SO3 THE STRENGTH OF ACIDS AND BASES Some acids and bases are classified as being strong while others are called weak. -Strong acids and bases are extremely reactive and corrosive. -Weak acids and bases are mostly unreactive and corrosive. THE PH SCALE (POWER OF HYDROGEN) pH scale is used to represent how acidic or basic a solution is. The scale ranges from 0-14 with very acidic being 0, neutral being 7, and very basic being 14. Every point on the scale represents a 10 base exponent difference. Ex lemons (pH = 2.0) are 100 times more acidic than tomatoes (pH = 4.0) 7.0 is neutral (neither acidic nor basic (alkaline)). Acids range from 0-6.9 Bases range from 7.1 -14 THE PH SCALE (POWER OF HYDROGEN) NEUTRALIZATION REACTIONS (317-319) The products of a neutralization reaction of an acid and a base are salt and water. Acid + Base Salt + water Biology: Unit Review Cell Theory: 1. All cells are similar to each other, but not identical. 2. Every living organism is made of cells 3. New cells are created by old cells dividing into two. 4. A cell contains everything that it needs to live and grow. 5. Cells take nutrients from its environment and release waste products into the environment. Cell Parts and Their Functions All living things are made of cells. Our bodies are made up of between 10 trillion (1013) and 100 trillion (1014) cells. A cell is the basic unit of life. KNOW CELL STRUCTURES It would take too much time to cover all of them now. Differences between Plant and Animal Cells - Plants • Contain Chlorophyll – photosynthesis • Large central Vacuole • Store energy in the forms such as cornstarch and oil Differences between Plant and Animal Cells - Animals • Small Vacuole • Store energy in form of glycogen, carbohydrates, and lipids (fat) • Some have specialized compounds for haemoglobin and cholesterol Differences between Plant and Animal Cells - Animals • Centrioles – Paired structures used in cell division. • Cilia or flagellum –used for movement COMPOUND LIGHT MICROSCOPE The compound light microscope uses two sets of lenses to magnify the object. Illumination is provided by a light source on the base of the microscope. The magnification typically ranges from approximately 40 X to 2,000 X. This means that it can magnify the object that many times. The total magnification can be found by multiplying the power of the objective lens by the ocular lens. ELECTRON MICROSCOPES Transmission Electron Microscope (TEM) is capable of magnifications of up to 1 500 000 X . Uses a beam of electrons instead of light. Since a beam of electrons can pass through thin slices, only thin sections of cells can be examined. Only dead cells can be observed. SCANNING ELECTRON MICROSCOPE (SEM) provides information about the surface features of a specimen. The SEM operates up to a magnification of 300 000 x and produces threedimensional images of cells. Mitosis Movie The Cell Cycle There are four phases in the cell cycle: • First growth phase (G1) • Synthesis phase (S) • Second growth phase (G2) • Mitosis (M) The Three Phases of Interphase (IPMAT) • -A cell spends 90 percent of its time in interphase. 1. First Growth Phase (G1) • Period of growth • Produces new proteins and organelles 2. Synthesis Phase (S) • Makes (synthesizes) an entire copy of the DNA of the cell. • Key proteins associated with chromosomes also copied The Three Phases of Interphase (IPMAT) 3. Second Growth Phase (G2) • Produces organelles and structures needed for cell division Mitosis (PMAT) • When the cell is ready to divide it enters mitosis. • All preparation up until this phase must be complete as it requires a lot of energy. • Contains 4 stages 1. Prophase(IPMAT) Early Prophase • The chromatin condenses to form chromosomes. • The centrioles move toward the poles. • - Spindle fibres form. 1. Prophase(IPMAT) Late Prophase • The nuclear envelope breaks down. • Each chromosome is connected to a spindle fibre at its centromere. • Centrioles move to opposite ends of cell forming poles of the mitotic spindles 2. Metaphase (IPMAT) • -Each chromosome becomes completely condensed. • -The chromosomes move toward the centre of the cell and line up at the middle of the cell. • - The mitotic spindle is completely attached from the mitotic spindle to the centromere 3. Anaphase (IPMAT) • Sister chromatids separate at the centromere. • Each chromatid is now a complete chromosome. • The separated chromosomes are pulled to opposite poles of the cell. 4. Telophase and Cytokinesis (IPMAT) • Mitotic Spindle breaks down • Two new nuclei form • The cytoplasm and cell membrane pinch in half to form two new daughter cells. 4. Telophase and Cytokinesis (IPMAT) • The process of splitting the cytoplasm is known as cytokinesis. • In plant cells, the cell plate forms the cell wall and inner plasma membrane in each of the new cells. • Each of the new cells enters the G1 phase of the cell cycle, and the cell cycle is repeated. CANCER CELLS A cell that divides uncontrollably is called a cancer cell. Cancer cells develop when a change occurs in the cell that affects how that cell divides. When a cell’s DNA is changed, it is known as a mutation. A cancer cell divides differently from a normal cell. CANCER CELLS Cancer cells ignore the usual densitydependent inhibition of growth, multiplying after contact with other cells is made, piling up until all nutrients are exhausted. The cancer cells proliferate to form mass of cancer cells called a tumour. As the tumour grows larger, it begins to release proteins from the cell to attract new blood vessel growth (this is called angiogenesis). I don’t know if you covered Stem cells and specialized cells or not. TYPES OF TISSUES IN ANIMALS (4) TYPES OF TISSUES IN ANIMALS (4) 1. Epithelial Tissues The main purpose of epithelial tissues is to protect the organism from dehydration while also providing a resistance to friction. These thin sheets of tightly packed cells cover surfaces such as skin as well as the lining of internal organs. TYPES OF TISSUES IN ANIMALS (4) 2. Connective Tissue The main purpose of connective tissues is to provide support and insulation. These cells and fibers are held together by a liquid, a solid or a gel, known as a matrix. 3. MUSCLE TISSUE The main purpose of muscles tissues is to allow for the body to move. They are made of long, thin fibers that contain specialized proteins capable of shortening or contracting. There are three types of muscle tissue 3. MUSCLE TISSUE 1.Skeletal muscle cells are large, multinucleate, and column shaped cells; they are chiefly attached to the skeleton. 3. MUSCLE TISSUE 2. Smooth muscle cells are small and mononucleate; they are found in the walls of tubes such as blood vessels, glandular ducts, and the digestive system 3. MUSCLE TISSUE Cardiac muscle cells of the heart are small, striated, and branched. 4. NERVOUS TISSUE The main purpose of nervous tissues is to provide sensory sensations which allow for communication with the brain which allow for the coordination of body functions (including reactions). These thin cells with fine branches at the ends are capable of conducting electrical impulses. Plant Tissues (4) All four types of plant tissue are grown from groups of meristematic cells known as meristematic tissue 1. Epidermal Tissue The epidermal tissue on both the top and underside of the leaf is clear and very thin. 2. Vascular Tissue Vascular tissue plays an important role in transporting water and nutrients throughout the plant. 3. Ground Tissue Most of the plant is made of ground tissue. In the roots, ground tissue is involved in food and water storage. 4. Meristematic Tissue Unspecialized tissue found in the roots and capable of specialization into any other type of plant tissue. Animal Organs Recall that there are four types of animal tissues: epithelial, connective, muscle, and nervous tissue. Tissues join together to form organs that have specialized functions. For example, skin is an organ that covers and protects your body, while the heart transports materials around your body. Most organs are made of several different tissues. For example, the heart is made of muscle tissue, connective tissue, nervous tissue, and epithelial tissue Skin - The largest organ in the body The skin protects the inner cells from damage, acts as a defence against disease organisms, insulates, releases heat, and excretes bodily wastes. The skin is made up of two different layers of tissues: the epidermis and the dermis. Lungs As air is breathed in through the nose or mouth, the air passes through the pharynx into the trachea. A flexible tube that is ringed with cartilage. Air moves down the trachea to the bronchus, into smaller bronchial tubes, and then into tiny air sacs, called alveoli, which are made of a thin layer of epithelial tissue. Circulatory system Organs of Digestion Ingestion – the taking in of nutrients Digestion – The breakdown of complex organic molecules into smaller components by physical and chemical means Absorption – the taking up of digested materials into the cells of the digestive tract Egestion – the removal of waste food materials from the body. Plant Organs A flowering plant is made up of four types of plant tissues: epidermal, ground, vascular, and meristematic. These plant tissues group together to form organs that perform special functions for the plant. The organs in a plant are the roots, the leaves, the stem, and the flower or fruit. Know Organ systems Humans have 11 Plants have 2 X-Ray - The most common form of medical imaging. An X-ray is high-energy radiation that can easily penetrate materials such as skin and tissues but cannot easily penetrate metals and bone. A radiograph is produced when X-rays pass through the body to produce an image. Xrays are absorbed by dense structures such as bone, the bones appear whiter than other structures Fluoroscopy Fluoroscopy is a technique that uses a continuous beam of X-rays to produce images that show the movement of organs, such as the stomach, intestine, and colon, in the body Ultrasound Ultrasound imaging uses high-frequency sound waves to produce images of body tissues and organs. A transducer produces the sound waves that enter the body and are reflected back to the transducer by internal body structures. This reflection makes an image of the body structure, which is recorded on a screen and viewed by a technician. Computed Tomography (CT) / Computer Assisted Tomography (CAT) Uses X-ray equipment to form a three dimensional image from a series of images taken at different angles of the body Used to diagnose cancer, abnormalities of the skeletal system, and vascular diseases. Magnetic Resonance Imaging (MRI) Magnetic resonance imaging (MRI) uses powerful magnets and radio waves to produce detailed images of the body. The magnet in an MRI machine produces a strong magnetic field that interacts with the hydrogen atoms. A combination of the magnetic field and different radio frequencies makes it possible for a specialized computer to generate an image. Magnetic Resonance Imaging (MRI) It is also used to diagnose forms of cancer, brain diseases, and cardiovascular conditions. An MRI machine is about the size of a car and looks like a hollow cylinder. Nuclear Medicine Nuclear medicine uses radioisotopes to provide images of how tissues or organs function by attaching a radioisotope to a chemical that is absorbed by certain organs. As the radioisotope emits radiation, a special camera and computer detect the radiation and convert it into an image Positron Emission Tomography (PET) A type of nuclear medicine where a patient is given a radioisotope that emits particles called positrons. PET is used most often to detect cancer in tissues or to examine the effects of cancer treatments. PET is also used to detect heart disease and some brain disorders, such as Alzheimer’s disease and epilepsy. Biophotonics Biophotonics imaging uses the interactions of light with cells and tissues to diagnose and treat abnormalities. Public Health and diseases I don’t know what your class specifically covered Social and Ethical Issues in Systems Biology Ex – cloning Transgenic Techniques