無機物理方法（核磁共振部分）
The Physical Methods in Inorganic Chemistry
(Fall Term, 2004)
Department of Chemistry
National Sun Yat-sen University
老師 The Professor
• Dr. Shangwu Ding 丁尚武
• Campus phone：3917, Office: 理東4022
• ding@mail.nsysu.edu.tw
•
http://www2.nsysu.edu.tw/sysuchem/sw_ding_home.htm
志願助教 The Teaching Assistants
吳振，梁文彥，陳彥志 ,李昆達
校內分機：3917， 理東4022
林研詩，巫秀娟，曾彥翰
校內分機：3917， 理東4022
• Lecture Hours:
• 11:00am-12:00 pm, Mondays;
• 10:00am-12:00 pm, Tuesdays.
(化4002), begins from Sept 15,2004.
• Office Hours: 4:00-6:00 pm, Tuesdays
(理東4022)
Contents
(1) The basic principles of FT-NMR spectroscopy;
(2) The mostly used liquid state NMR experiments;
(3) The typical solid state NMR experiments;
(4) Applications to inorganic chemistry and materials science.
•
•
•
•
•
•
•
•
Theory:
1. Generation of FID, vector model, basic principle of FT NMR
2. NMR parameters: chemical shift, dipolar and J-couplings, quadrupolar coupling, relation times, exchange rates
3. Simple 1D NMR experiments
4. Simple 2D NMR experiments
5. Basic applications: structure determination
6. Introductory solid state NMR
7. Applications of solid state NMR
•
NMR experiments:
•
•
•
•
•
•
Sample preparation, shimming/lock, basic commands
Single-pulse experiment
T1/T2 experiment
DEPT
COSY
CP-MAS
Purpose
• The students will have learnt the elementary
theoretical principle and experimental
techniques and employ them to assist their
respective research projects, particularly in
the area of inorganic chemistry.
Schedules
•
•
•
•
•
•
•
•
•
Theory:
1.Introduction, generation of FID, vector model, basic principle of FT NMR,
NMR parameters: chemical shift, dipolar and J-couplings, quadrupolar coupling,
relation times, exchange rates,
Simple 1D NMR experiments
2. Polarization transfer and spectral editing
3. Relaxation and exchange
4. Simple 2D NMR experiments
Basic applications: structure determination
5. Introductory solid state NMR
•
NMR experiments:
•
•
•
•
•
•
Sample preparation, shimming/lock, basic commands
Single-pulse experiment
T1/T2 experiment
DEPT
COSY/NOESY
CP-MAS
•
•
Total hours: ～21 hours
（Lecture: ～15 hours; Lab: ～6 hours）
Instruction Techniques
• 1. Lecture / NMR Lab
• 3. Quiz
• 4. Discussion
Grading Policy
Assignments/Quizzes (35 % each)
Experiments (25%)
Final exam (40%)
One Assignment/Lab Each Week
(Deadline: 17:00pm, Fridays)
Reference Books
參考書：
• 1. C. Akitt, "NMR for Chemists", Academic Press,
New York, 1988.
• 2. M. Hunter, "Introdctory NMR Spectroscopy", CFC
Press, Guelph, 1983.
• 3. M. H. Levitt, "Spin Dynamics: basics of nuclear
magnetic resonance", John Wiley & Sons, 2001.
Web Sites
• 1.磁共振光譜及成像綜合情報網：
http://spincore.com/nmrinfo/
• 2. 電子書 NMR─BASICS （nmr basics 亦
可由本課程之網頁直接下載壓縮檔，解
壓縮後離線閱讀）
• 3.本實驗室NMR網上課程