Question: You can just write the variables. If the pressure in the balloon is 1 atm at 23C and it was placed in the oven with a temperature of 85C. What is the final pressure? Agenda: Discuss B, C, and G-L worksheet In-class worksheet on B, C, and G-L Homework: Ch. 10 sec. 4-6 reading notes BOYLES CHARLES & GAY-LUSSAC Worksheet Provide Boyles Law formula. P1V1 = P2 V2 1. If some neon gas at 75.0 kPa were allowed to shrink from 6.0 dm3 to 3.0 dm3 without changing the temperature, what pressure would the neon gas exert under these new conditions? (75.0 kPa) (6.0 dm3) = 450 kPa 3.0 150 kPa (X) (3.0 dm3) = (X) 2. A quantity of gas under a pressure of 2.25 atm has a volume of 345 cm3. The pressure is increased to 3.10 atm, while the pressure remains constant. What is the new volume? (2.25 atm) (345 cm3) = 776.25 cm3 3.10 250 3 cm (3.10 atm) (X) = (X) 3. A 25.0 L sample of gas exerts a pressure of 135 kPa. What pressure will the gas exert if its volume is reduced to 15.3 L?(constant temperature) (135 kPa) (25.0 L) = 3375 kPa 15.3 221 kPa (X) (15.3L) = (X) 4. A container that has 3.00 L of a gas is at 2.50 atm. What pressure is obtained when the volume is 7.5 L? (2.50 atm) (3.00L) = 7.5 atm 7.5 1.0 atm (X) (7.5L) = (X) Provide Charles Law formula. V1 V2 = T1 T2 1. The temperature inside my refrigerator is about 60 Celsius. If I place a balloon in my fridge that initially has a temperature of 300 C and a volume of 1.5 liters, what will be the volume of the balloon when it is fully cooled by my refrigerator? X L 1.5 L = 303K 279K T =30 + 273 = 303K 1 V1 = 1.5 L T2 = 6 + 273 = 279 K V2 = X L 418.5 = (X) (303) 418.5= X 303 1.38 L OR 1 L 2. A man heats a balloon in the oven. If the balloon initially has a volume of 0.25 liters and a temperature of 30 0C, what will the volume of the balloon be after he heats it to a temperature of 325 0C? 303K T1 =30 + 273 = 303K V1 = 0.25 L T2 = 325 + 273 = 598K V2 = X L 0.49 L 598K = 0.25 L X L 149.5 = (X) (303) 149.5= X 303 3. On hot days, you may have noticed that potato chip bags seem to “inflate”, even though they have not been opened. If I have a 250 mL bag at a temperature of 23 0C, and I leave it in my car which has a temperature of 400 C, what will the new volume of the bag be? 296K T1 =23 + 273 = 296K V1 = 250 mL T2 = 40 + 273 = 313 K V2 = X L 313K = 250 mL X L 78250 = (X) (296) 78250 = X 296 264 mL OR 260 ml 4. A soda bottle is flexible enough that the volume of the bottle can change even without opening it. If you have an empty soda bottle (volume of 2 L) at of a temperature 17 0C, what will the new volume be if you put it in your freezer (-4 0C)? 290K T1 =17 + 273 = 290K V1 = 2 L T2 = -4 + 273 = 269 K V2 = X L 2L 269K = XL 538 = (X) (290) 538= X 290 1.85 L OR 2L Provide Gay-Lussac’s Law formula. P1 P 2 = T1 T2 1. The pressure inside a container is 625 mmHg at a temperature of 47oC. What would the pressure be at 70oC? 625 mmHg P1 = 625 mmHg T1 = 47 + 273 = 320K P2 = X T2 = 70 + 273 = 343K X mmHg = 320 K 343 K 214375 = (X) (320) 214375 = X 320 669.9 or 670 mmHg 2. A rigid container is at a temperature of 12oC. When heated to 125oC, the pressure was 360 kPa. What was the initial pressure? X kPa P1 = X kPa T1 = 12 + 273 = 285K P2 = 360 kPa T2 = 125 + 273 = 398K 360 kPa = 285 K 398 K 102600 = (X) (497) 102600 = X 398 258 kPa OR 260 kPa 3. If a gas is cooled from 225 K to 125 K and the volume is kept constant what final pressure would result if the original pressure was 630.0 mm Hg? 630 mmHg P1 = 630 mmHg T1 = 225 K P2 = X mmHg T2 = 125 K X mmHg = 225 K 125 K 78750 = (X) (225) 78750 = X 225 350 mmHg 4. A gas has a pressure of 0.135 atm at 45.0 °C. What is the pressure at -12˚C ? 0.135 atm P1 = 0.135 atm T1 = 45 + 273= 318 K P2 = X atm T2 = -12 + 273= 261 K X atm = 318 K 261 K 35.24 = (X) (318) 35.24 = X 318 0.11 atm BOYLES CHARLES & GAY-LUSSAC Self Check Provide Boyles Law formula. P1V1 = P2 V2 1. If some neon gas at 30.0 kPa were allowed to expand from 7.7 dm3 to 12.0 dm3 without changing the temperature, what pressure would the neon gas exert under these new conditions? (30.0 kPa) (7.7 dm3) = 231 kPa 12.0 19.3 kPa (X) (12.0 dm3) = (X) 2. A quantity of gas under a pressure of 3.2 atm has a volume of 650 cm3. The pressure is increased to 4.3 atm, while the pressure remains constant. What is the new volume? (3.20 atm) (650 cm3) = 2080 cm3 4.30 480 3 cm (4.30 atm) (X) = (X) 3. A 5.0 L sample of gas exerts a pressure of 175 kPa. What pressure will the gas exert if its volume is reduced to 2.5 L?(constant temperature) (175 kPa) (5.0 L) = 875 kPa 2.5 350 kPa (X) (2.5 L) = (X) 4. 10.0 L of a gas is at 0.85 atm. What pressure is obtained when the volume is 5.0 L? (0.85 atm) (10.0L) = 8.5 atm 5.0 1.7 atm (X) (5.0 L) = (X) Provide Charles Law formula. V1 V2 = T1 T2 1. The temperature inside my refrigerator is about 90 Celsius. If I place a balloon in my fridge that initially has a temperature of 220 C and a volume of 0.3 liters, what will be the volume of the balloon when it is fully cooled by my refrigerator? X L 0.3 L = 295K 282K T =22 + 273 = 295K 1 V1 = 0.3 L T2 = 9 + 273 = 282 K V2 = X L 84.6 = (X) (295) 84.6= X 295 0.286 L or 0.3 L 2. A man heats a balloon in the oven. If the balloon initially has a volume of 0.70 liters and a temperature of 27 0C, what will the volume of the balloon be after he heats it to a temperature of 35 0C? 300K T1 =27 + 273 = 300K V1 = 0.7 L T2 = 35 + 273 = 308K V2 = X L 0.76 L 308K = 0.7 L X L 215.6 = (X) (300) 215.6= X 300 3. On hot days, you may have noticed that potato chip bags seem to “inflate”, even though they have not been opened. If I have a 250.0 mL bag at a temperature of 22.0 0C, and I leave it in my car which has a temperature of 50.00 C, what will the new volume of the bag be? 295K T1 =22 + 273 = 295K V1 = 250 mL T2 = 50 + 273 = 323 K V2 = X L 323K = 250 mL X L 80750 = (X) (295) 80750= X 274 mL 295 4. A soda bottle is flexible enough that the volume of the bottle can change even without opening it. If you have an empty soda bottle (volume of 2 L) at room temperature (25 0C), what will the new volume be if you put it in your freezer (-4 0C)? 298K T1 =25 + 273 = 298K V1 = 2 L T2 = -4 + 273 = 269 K V2 = X L 2L 269K = XL 538 = (X) (298) 538= X 298 1.81 L OR 2 L Provide Gay-Lussac’s Law formula. P1 P 2 = T1 T2 1. The pressure inside a container is 650 mmHg at a temperature of 75oC. What would the pressure be at 55oC? 650 mmHg P1 = 650 mmHg T1 = 75 + 273 = 348K P2 = X T2 = 55 + 273 = 328K X mmHg = 348 K 328 K 213200 = (X) (348) 267960= X 348 613 OR 610 mmHg 2. A rigid container is at a temperature of 3.0oC. When heated to 75oC, the pressure was 2.5 kPa. What was the initial pressure? X kPa P1 = X kPa T1 = 3.0 + 273 = 276K P2 = 2.5 kPa T2 = 75 + 273 = 348K 2.5 kPa = 276 K 348 K 690 = (X) (348) 690 = X 348 1.98 or 2.0 kPa 3. If a gas is cooled from 303.0 K to 200.5 K and the volume is kept constant what final pressure would result if the original pressure was 550.0 mm Hg? 550 mmHg P1 = 550 mmHg T1 = 303.0 K P2 = X mmHg T2 = 200.5 K X mmHg = 303.0 K 200.5 K 110275 = (X) (303) 110275 = X 303 363.9 mmHg 4. A gas has a pressure of 0.370 atm at 50.0 °C. What is the pressure at 22˚C ? 0.370 atm P1 = 0.370 atm T1 = 50 + 273= 323 K P2 = X atm T2 = 22 + 273= 295 K X atm = 323 K 295 K 109.15 = (X) (323) 109.15 = X 323 0.338 atm OR 0.34 atm