What color is the sun? • Contrary to popular belief, the sun is actually white! • When viewed from outside our atmosphere the sun appears white. Why? The Sun as Seen by ISS Image via Nasa.gov RAINBOWS! How does a Rainbow Form White Light is Composed of all Colors: ROY G BIV WHITE LIGHT PRISM White Light is Composed of all Colors: ROY G BIV How Does a WHITE LIGHT PRISM Prism Work? • As light enters a new material or medium (e.g. from air to glass) it changes speed which causes it to bend or refract. • Different colors of light bend different amounts. Thus, white light separated into a full rainbow of colors. Simple Refraction Demo Arrow and a glass cup. • Why Does the Sun Appear to be Yellow? • A simple explanation is that all the particles in our atmosphere filter out all the colors but yellow making the sun appear yellow. • Likewise, grass is green because the pigment chlorophyll inside of grass is very good at absorbing blue and red light, leaving the green to be reflected. • Why are Sunrises and Sunsets Red/Orange? • At dawn/dusk the sun has to travel through a longer path in the atmosphere to reach us which scatters out the blue normally making up our sky color. X The size of our atmosphere is EXTREMELY exaggerated! EARTH If Earth was the Size of an Apple • The atmosphere would be much thinner than the skin on the apple. • The atmosphere is about 60 miles thick whereas earth has a radius of about 4,000 miles. How Does a Rainbow Form? Sunlight strikes water droplets in the atmosphere. The water droplets behave like a prism and separate the light into a full rainbow of colors. THE SUN MUST BE AT YOUR BACK TO SEE A RAINBOW As white sunlight enters a raindrop it refracts into a full spectrum of color. Refraction The light will then reflect or bounce off the opposite side of the drop and exit on the same side it entered (refracting again!) Reflection Refraction Activity: Grab a spectroscope and use it to look at the following: • • • • • Sunlight (not directly) Fluorescent Light Helium Tube Oxygen Tube Hydrogen Tube Use colored pencils and markers to draw the spectral lines (color pattern). Explain the differences that you see. Image via openstax When light passes through a diffraction grating (slit) of a certain size it the light separates into its respective colors. In this unit we want to understand what creates light and why each element has a unique set of spectral lines. In order to do that we need to take a deeper look at electrons… Spectroscopic Analysis • Astronomy! We can’t get to the stars so spectral analysis is crucial to understand what these objects are made of. • Helium was discovered on the sun before it was found on Earth. How Light Forms 2-8-8-2 rule [1] Energy strikes an atom [2] Electrons in their grounds state become excited and jump up to a higher energy level [3] Electrons in higher energy levels are unstable. They drop back down to their ground state and emit the energy they absorbed. [4] That energy is emitted as photons or small packets of light Light Wave Mechanical Atom (Lab) • Understanding electrons allows us to understand light and how and why atoms join together. • Electron location is based upon probability. • Electrons orbits are quantized. STUDENTS PLEASE DON’T FART • • • • S (2 electrons) P (6 electrons) D (10 electrons) F (14 electrons) 1. 2. 3. 4. 5. 6. 7. Draw the numbers 1-7 down and put an s after them Draw the numbers 2-7 and put a p after them. Draw the numbers 3-6 and put a d after them Draw the numbers 4-7 and put an f after them Inset arrows diagonally starting with the 1s Follow the the arrows (top to bottom) and write the order out. Now insert the SPDF numbers as exponents. 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 7p Aufbau Principle S(2) P(6) D(10) F(14) 1s2s2p3s3p4s3d4p5s4d5p6s4f5d6p7s5f6d7p 3d 4d 5d 6d 7d 4f 5f 6f 7f Writing the standard, ground state electron configuration order. 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f146d107p6 Orbital shape Containers that hold electrons 2 1s Energy Level # of Electrons 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f146d10 Practice Configuration and Boxes • Hydrogen • Oxygen • Fluorine • Neon-21 • Al3+ You have to fill up one orbital before going into the next one! HANDOUT 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f146d10 http://www.vincentsapone.com Hund’s Rule Pauli Exclusion Principle Aufbau Principle __ __ 1s2 __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 __ __ 1s2 __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 __ __ 1s2 __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 __ __ 1s2 __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ 2 2p Sulfur 3s2 3d10 4p6 6s2 4f14 __ __ 1s2 __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ __ 6s2 4f14 __ __ 1s2 __ __ 1s2 __ __ 1s2 Neon2s 6 6 3p Krypton __ __ __ 2 4s Oxygen __ Nitrogen Mg2+5s __ __ __ __ __ __ __ __ __ __ __ 2 S2-4d 10 __ __ __ __ __ 6 10 2s2 in the 2p6 diagram 3s2 3p 4s2 out3d 4p6 configuration 5s2 4d10 Fill and write the electron __ __ __ __ __ __ 14C5p 6 __ __ __ 5p6 7s2 6p 6s2 5d10 6 4f14 5s2 5p 4p 4s2 3s2 2s2 4d10 6 3d10 6 3p 6 2p 6 Hydrogen Lithium Sodium Potassium Rubidium Caesium 1s2 http://www.vincentsapone.com Valence Electrons 1s 2s 3s 4s 5s 6s 7s 2p 3p 4p 5p 6p 7p 3d 4d 5d 6d 7d 4f 5f 6f 7f • Electrons in the outermost energy level of an atom. • The most important electrons in an atom, they determine chemical bonds and properties. • They are the furthest from the Nucleus and therefore, when two atoms/molecules come into contact with one another it is the outer electrons that interact first. 1s22s22p63s23p64s23d104p65s24d105p66s24f145d106p67s25f146d10 1s22s22p63s23p64s23d104p65s2… • Determine the number of Valence Electrons • Carbon • Neon • Argon • Iron 1. First you need to determine the total number of electrons each element has. 2. You need to write out its ground state electron configuration. 3. Count the number of electrons in the highest energy level. 1s22s22p63s23p64s23d104p65s2… • Determine the number of Valence Electrons • Carbon 1s22s22p2 =4 • Neon 1s22s22p6 =8 • Argon 1s22s22p63s23p6 =8 • Iron 1s22s22p63s23p64s23d6 =2 Handout 1. First you need to determine the total number of electrons each element has. 2. You need to write out its ground state electron configuration. 3. Count the number of electrons in the highest energy level. Column Number 1A-8A is the number of Valence electrons • • • • • • • • Selenium Tin Strontium Krypton Iodine Potassium Sodium Gallium How Many Valence Electrons? 18 8A 1 1A Alkali Metals 1 H Alkaline Earth Metals Transition Lanthanides Actinides Metals Other Metals Metalloids Other Halogens Nonmetals Noble Gases 2 http://www.vincentsapone.com He Helium Hydrogen 1.0079 3 2 2A 13 3A 4 Li Be Lithium 6.941 Beryllium 11 12 5 All column 1A elements have 1 valence electron 9.0122 Na Mg Sodium 22.990 Magnesium 19 20 24.305 3 4 5 6 7 8 9 21 22 23 24 25 26 27 10 28 11 12 29 30 14 4A 6 15 5A 7 16 6A 8 17 7A 4.003 9 10 Ne B C N O F Boron Carbon Nitrogen Oxygen Fluorine Neon 10.811 12.011 14.007 15.999 18.998 20.180 13 14 15 16 17 18 Al Si P S Cl Ar Aluminum Silicon Phosphorus Sulfur Chlorine Argon 26.982 28.086 30.974 32.066 35.453 39.948 31 32 33 34 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Potassium 39.098 Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton 40.078 44.956 47.88 50.942 51.996 54.938 55.933 58.933 58.693 63.546 65.39 69.732 72.61 74.922 78.09 79.904 84.80 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Xe Rb Sr Y Zr Rubidium 85.468 Strontium Yttrium Zirconium Niobium Nb Mo 87.62 88.906 91.224 92.906 95.94 55 56 72 73 74 Tc Ru Rh Pd Ag Cd In Sn Sb Te I Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon 98.907 101.07 102.906 106.42 107.868 112.411 114.818 118.71 121.760 127.6 126.904 131.29 75 76 77 78 79 80 81 82 83 84 85 86 Rn Molybdenum Technetium Cs Ba * Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Cesium 132.91 Barium 57-71 Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon 137.33 178.49 180.948 183.85 186.207 190.23 192.22 195.08 196.967 200.59 204.383 207.2 208.980 [208.982] 209.987 222.018 87 88 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 Fr Ra ** Rf Db Sg Bh Hs Mt Ds Rg Francium [223] Radon 89-103 Rutherfordium Dubnium Seaborgium Bohrium Hassium [261] [262] [266] [264] [269] [268] [269] [272] [277] unknown [289] unknown [298] unknown unknown 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 La Ce [226] Atomic mass in [brackets] is for the most stable isotope . * Lanthanum Cerium 140.115 138.906 89 ** 90 Pr Nd Pm Sm Praseodymium Neodymium Promethium Cn Uut Meitnerium Darmstadtium Roentgenium Copernicium Ununtrium Fl Uup Lv Uus Uuo Flerovium Ununpentium Livermorium Ununseptium Ununoctium Eu Gd Tb Dy Ho Er Tm Yb Lu Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium 140.908 144.24 144.24 150.36 151.966 157.25 158.925 162.50 164.930 167.26 168.934 173.04 174.967 91 92 93 94 95 96 97 98 99 100 101 102 103 Cf Es Ac Th Pa U Np Actinium 227.028 Thorium Protactinium Uranium Neptunium Plutonium Pu Am Cm Americium Curium Berkelium Bk 232.038 231.036 238.029 237.048 244.064 243.061 247.070 247.070 Californium Einsteinium 251.080 [254] Fm Md No Lr Fermium Mendelevium Nobelium Lawrencium 257.095 258.1 259.101 [262] 18 8A 1 1A Alkali Metals 1 H Alkaline Earth Metals Transition Lanthanides Actinides Metals Other Metals Metalloids Other Halogens Nonmetals Noble Gases 2 http://www.vincentsapone.com He Helium Hydrogen 1.0079 3 2 2A 13 3A 4 Li Be Lithium 6.941 Beryllium 11 12 5 All column 2A elements have 2 valence electrons 9.0122 Na Mg Sodium 22.990 Magnesium 19 20 24.305 3 4 5 6 7 8 9 21 22 23 24 25 26 27 10 28 11 12 29 30 14 4A 6 15 5A 7 16 6A 8 17 7A 4.003 9 10 Ne B C N O F Boron Carbon Nitrogen Oxygen Fluorine Neon 10.811 12.011 14.007 15.999 18.998 20.180 13 14 15 16 17 18 Al Si P S Cl Ar Aluminum Silicon Phosphorus Sulfur Chlorine Argon 26.982 28.086 30.974 32.066 35.453 39.948 31 32 33 34 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Potassium 39.098 Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton 40.078 44.956 47.88 50.942 51.996 54.938 55.933 58.933 58.693 63.546 65.39 69.732 72.61 74.922 78.09 79.904 84.80 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Xe Rb Sr Y Zr Rubidium 85.468 Strontium Yttrium Zirconium Niobium Nb Mo 87.62 88.906 91.224 92.906 95.94 55 56 72 73 74 Tc Ru Rh Pd Ag Cd In Sn Sb Te I Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon 98.907 101.07 102.906 106.42 107.868 112.411 114.818 118.71 121.760 127.6 126.904 131.29 75 76 77 78 79 80 81 82 83 84 85 86 Rn Molybdenum Technetium Cs Ba * Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Cesium 132.91 Barium 57-71 Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon 137.33 178.49 180.948 183.85 186.207 190.23 192.22 195.08 196.967 200.59 204.383 207.2 208.980 [208.982] 209.987 222.018 87 88 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 Fr Ra ** Rf Db Sg Bh Hs Mt Ds Rg Francium [223] Radon 89-103 Rutherfordium Dubnium Seaborgium Bohrium Hassium [261] [262] [266] [264] [269] [268] [269] [272] [277] unknown [289] unknown [298] unknown unknown 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 La Ce [226] Atomic mass in [brackets] is for the most stable isotope . * Lanthanum Cerium 140.115 138.906 89 ** 90 Pr Nd Pm Sm Praseodymium Neodymium Promethium Cn Uut Meitnerium Darmstadtium Roentgenium Copernicium Ununtrium Fl Uup Lv Uus Uuo Flerovium Ununpentium Livermorium Ununseptium Ununoctium Eu Gd Tb Dy Ho Er Tm Yb Lu Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium 140.908 144.24 144.24 150.36 151.966 157.25 158.925 162.50 164.930 167.26 168.934 173.04 174.967 91 92 93 94 95 96 97 98 99 100 101 102 103 Cf Es Ac Th Pa U Np Actinium 227.028 Thorium Protactinium Uranium Neptunium Plutonium Pu Am Cm Americium Curium Berkelium Bk 232.038 231.036 238.029 237.048 244.064 243.061 247.070 247.070 Californium Einsteinium 251.080 [254] Fm Md No Lr Fermium Mendelevium Nobelium Lawrencium 257.095 258.1 259.101 [262] 18 8A 1 1A Alkali Metals 1 H Alkaline Earth Metals Transition Lanthanides Actinides Metals Other Metals Metalloids Other Halogens Nonmetals Noble Gases 2 http://www.vincentsapone.com He Helium Hydrogen 1.0079 3 2 2A 13 3A 4 Li Be Lithium 6.941 Beryllium 11 12 5 All column 3A elements have 3 valence electrons and so on… 9.0122 Na Mg Sodium 22.990 Magnesium 19 20 24.305 3 4 5 6 7 8 9 21 22 23 24 25 26 27 10 28 11 12 29 30 14 4A 6 15 5A 7 16 6A 8 17 7A 4.003 9 10 Ne B C N O F Boron Carbon Nitrogen Oxygen Fluorine Neon 10.811 12.011 14.007 15.999 18.998 20.180 13 14 15 16 17 18 Al Si P S Cl Ar Aluminum Silicon Phosphorus Sulfur Chlorine Argon 26.982 28.086 30.974 32.066 35.453 39.948 31 32 33 34 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Potassium 39.098 Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton 40.078 44.956 47.88 50.942 51.996 54.938 55.933 58.933 58.693 63.546 65.39 69.732 72.61 74.922 78.09 79.904 84.80 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Xe Rb Sr Y Zr Rubidium 85.468 Strontium Yttrium Zirconium Niobium Nb Mo 87.62 88.906 91.224 92.906 95.94 55 56 72 73 74 Tc Ru Rh Pd Ag Cd In Sn Sb Te I Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon 98.907 101.07 102.906 106.42 107.868 112.411 114.818 118.71 121.760 127.6 126.904 131.29 75 76 77 78 79 80 81 82 83 84 85 86 Rn Molybdenum Technetium Cs Ba * Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Cesium 132.91 Barium 57-71 Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon 137.33 178.49 180.948 183.85 186.207 190.23 192.22 195.08 196.967 200.59 204.383 207.2 208.980 [208.982] 209.987 222.018 87 88 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 Fr Ra ** Rf Db Sg Bh Hs Mt Ds Rg Francium [223] Radon 89-103 Rutherfordium Dubnium Seaborgium Bohrium Hassium [261] [262] [266] [264] [269] [268] [269] [272] [277] unknown [289] unknown [298] unknown unknown 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 La Ce [226] Atomic mass in [brackets] is for the most stable isotope . * Lanthanum Cerium 140.115 138.906 89 ** 90 Pr Nd Pm Sm Praseodymium Neodymium Promethium Cn Uut Meitnerium Darmstadtium Roentgenium Copernicium Ununtrium Fl Uup Lv Uus Uuo Flerovium Ununpentium Livermorium Ununseptium Ununoctium Eu Gd Tb Dy Ho Er Tm Yb Lu Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium 140.908 144.24 144.24 150.36 151.966 157.25 158.925 162.50 164.930 167.26 168.934 173.04 174.967 91 92 93 94 95 96 97 98 99 100 101 102 103 Cf Es Ac Th Pa U Np Actinium 227.028 Thorium Protactinium Uranium Neptunium Plutonium Pu Am Cm Americium Curium Berkelium Bk 232.038 231.036 238.029 237.048 244.064 243.061 247.070 247.070 Californium Einsteinium 251.080 [254] Fm Md No Lr Fermium Mendelevium Nobelium Lawrencium 257.095 258.1 259.101 [262] 18 8A 1 1A Alkali Metals 1 H Alkaline Earth Metals Transition Lanthanides Actinides Metals Other Metals Metalloids Other Halogens Nonmetals Noble Gases 2 http://www.vincentsapone.com He Helium Hydrogen 1.0079 3 2 2A 13 3A 4 Li Be Lithium 6.941 Beryllium 11 12 9.0122 5 All column 8A elements have 8 valence electrons except helium (2ve) Na Mg Sodium 22.990 Magnesium 19 20 24.305 3 4 5 6 7 8 9 21 22 23 24 25 26 27 10 28 11 12 29 30 14 4A 6 15 5A 7 16 6A 8 17 7A 4.003 9 10 Ne B C N O F Boron Carbon Nitrogen Oxygen Fluorine Neon 10.811 12.011 14.007 15.999 18.998 20.180 13 14 15 16 17 18 Al Si P S Cl Ar Aluminum Silicon Phosphorus Sulfur Chlorine Argon 26.982 28.086 30.974 32.066 35.453 39.948 31 32 33 34 35 36 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Potassium 39.098 Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton 40.078 44.956 47.88 50.942 51.996 54.938 55.933 58.933 58.693 63.546 65.39 69.732 72.61 74.922 78.09 79.904 84.80 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 Xe Rb Sr Y Zr Rubidium 85.468 Strontium Yttrium Zirconium Niobium Nb Mo 87.62 88.906 91.224 92.906 95.94 55 56 72 73 74 Tc Ru Rh Pd Ag Cd In Sn Sb Te I Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon 98.907 101.07 102.906 106.42 107.868 112.411 114.818 118.71 121.760 127.6 126.904 131.29 75 76 77 78 79 80 81 82 83 84 85 86 Rn Molybdenum Technetium Cs Ba * Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Cesium 132.91 Barium 57-71 Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury Thallium Lead Bismuth Polonium Astatine Radon 137.33 178.49 180.948 183.85 186.207 190.23 192.22 195.08 196.967 200.59 204.383 207.2 208.980 [208.982] 209.987 222.018 87 88 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 Fr Ra ** Rf Db Sg Bh Hs Mt Ds Rg Francium [223] Radon 89-103 Rutherfordium Dubnium Seaborgium Bohrium Hassium [261] [262] [266] [264] [269] [268] [269] [272] [277] unknown [289] unknown [298] unknown unknown 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 La Ce [226] Atomic mass in [brackets] is for the most stable isotope . * Lanthanum Cerium 140.115 138.906 89 ** 90 Pr Nd Pm Sm Praseodymium Neodymium Promethium Cn Uut Meitnerium Darmstadtium Roentgenium Copernicium Ununtrium Fl Uup Lv Uus Uuo Flerovium Ununpentium Livermorium Ununseptium Ununoctium Eu Gd Tb Dy Ho Er Tm Yb Lu Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium 140.908 144.24 144.24 150.36 151.966 157.25 158.925 162.50 164.930 167.26 168.934 173.04 174.967 91 92 93 94 95 96 97 98 99 100 101 102 103 Cf Es Ac Th Pa U Np Actinium 227.028 Thorium Protactinium Uranium Neptunium Plutonium Pu Am Cm Americium Curium Berkelium Bk 232.038 231.036 238.029 237.048 244.064 243.061 247.070 247.070 Californium Einsteinium 251.080 [254] Fm Md No Lr Fermium Mendelevium Nobelium Lawrencium 257.095 258.1 259.101 [262] Lewis Dot Structures Column # 1 A-8A = #V.E.s Dot structures dots represent valence electrons. Six V.E.s Valence electrons are electrons in the outermost energy level of an atom. Important for Bonding!!! +8 The shell model on the right shows an oxygen atom with 8 total electrons. How many of them are valence electrons? O We draw it like this: The element symbol in the middle with dots drawn around it. Starting from the right, draw one dot on each side in a clockwise fashion and then double up the dots if necessary. Key Concept: • Shell diagrams show ALL electrons • Lewis Dot Structures show only the outermost ring (valence electrons) Lewis Dot Structures Column # 1 A-8A = #V.E.s Draw Dot Structures C Carbon is in Column 4A so it has four Valence electrons! Lewis Dot Structures 1VE 2VEs 3VEs 4VEs X X X X 5VEs 6VEs 7VEs 8VEs X X X X Period 2 Lewis Structures 1VE 2VEs 3VEs Li Be B 5VEs 6VEs N O 7VEs 4VEs C 8VEs F Ne Patterns in Electron Configuration * ** * ** 1s22s22p63s23p64s23d104p65s24d105p66s24f145d10 H 1s1 Li Be 2s1 2s2 S P D F Na Mg 3s1 3s2 He 1s2 B C N O F Ne 2p1 2p2 2p3 2p4 2p5 2p6 Al Si P S Cl Ar 3p1 3p2 3p3 3p4 3p5 3p6 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr 4s1 4s2 3d1 3d2 3d3 3d5 3d5 3d6 3d7 3d8 3d10 3d10 4p1 4p2 4p3 4p4 4p5 4p6 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe 5s1 5s2 4d1 4d2 4d4 4d5 4d5 4d7 4d8 4d10 4d10 4d10 5p1 5p2 5p3 5p4 5p5 5p6 Cs Ba 6s1 6s2 * Hf Ta W Re Os Ir Pt Au Hg Ti Pb Bi Po At Rn 5d2 5d3 5d4 5d5 5d6 5d7 5d9 5d10 5d10 6p1 6p2 6p3 6p4 6p5 6p6 Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn ** 7s1 7s2 6d2 6d3 6d4 6d5 6d6 6d7 6d8 6d10 6d10 http://www.vincentsapone.com * La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu 5d1 4f15d1 4f3 4f4 4f5 4f6 4f7 4f75d1 4f9 4f10 4f11 4f12 4f13 4f14 5s1 ** Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr 6d1 6d2 5f26d1 5f36d1 5f46d1 5f6 5f7 5f76d1 5f9 5f10 5f11 5f12 5f13 5f14 6d1 Why does each element have a unique set of spectral lines? 1. Each color of light has a specific size/wavelength/energy. 2. Each atom has a unique electron configuration resulting in different amounts of energy being given off when an electron jumps back down. 3. Also each atom has difference energy characteristics since the number of protons differs between atoms. Light is Electromagnetic Radiation • Visible Light is just a small part of the total spectrum of Light Full Electromagnetic Spectrum Some Infrared Photos Ultraviolet Radiation BLACK LIGHTS Flame Test Lab!!!!!