Honors Chemistry Final Exam Review 2011-12 Name ____________________________________________ Test Date: ____________ Time: ______________________ Room #: ______________ Proctor: ____________________ Unit 1: Measurement 1. A block of sodium with measurements 4.00 cm x 3.00 cm x 6.25 cm has a measured mass of 76.1 g. The accepted density for sodium if 0.971 g/cm3. Calculate the percent error. _____ 2. A 49.5 gram sample of tin at 95.0°C is placed into 145 grams of water. The water and tin reach thermal equilibrium at a temperature of 26.1°C. What was the initial temperature of the water? a. 22.4 °C b. 24.9 °C c. 27.3 °C d. 29.8 °C 3. If 145 J of heat are added to an unknown metal of mass 121 g, the temperature of the metal goes from 22.2°C to 24.3°C. Calculate the specific heat of the metal. Unit 2: Matter & Energy _____ 4. Benzene, C6H6, boils at 80.1˚C and has a density of 0.877 g/cm3. Determine the quantity of heat that is required to vaporize a 45.6 mL sample of benzene at 35.0˚C. a. 3140 J b. 4370 J c. 15800 J d. 18900 J _____ 5. If a gas’s temperature increases, what happens to the pressure and volume? a. Pressure increases and volume increases b. Pressure decreases and volume decreases c. Pressure decreases and volume increases d. Pressure increases and volume decreases _____ 6. A gas is collected over water in a eudiometer tube until the pressure is equilibrated with the atmospheric pressure. The volume of gas in the eudiometer is 28.5 mL. The temperature of the water is 36.0°C and the barometric pressure is 758 mm Hg. What is the volume of this gas at STP? a. 23.6 mL b. 25.1 mL c. 30.3 mL d. 32.2 mL 7. A balloon is filled to a volume of 745 mL with 158 grams of steam at 112°C. After a brief period of cooling, the balloon’s volume is measured to be 735 mL. How much heat energy did the steam lose? _____ 8. Which of the following occurs during a phase change? a. Temperature increases b. Kinetic energy increases c. Heat energy increases d. All of the above _____ 9. Which lettered region represents the phase with the highest intermolecular forces? A B C D E Increasing Temperature a. b. c. d. e. D E C B A Time Unit 3: Atomic Theory & Nuclear 10. Write the isotopic symbols for atoms with the following: a. 9 p+ and 10 no ________________ b. 25 p+ and 30 no________________ _____ 11. A chlorine atom has atomic number 17 and mass number 35. It has i. 17 protons, 17 electrons, and 18 neutrons ii. 35 protons, 35 electrons, and 17 neutrons iii. 17 protons, 17 electrons, and 52 neutrons iv. 18 protons, 18 electrons, and 17 neutrons 12. Complete the following chart: Isotopic Symbol a b Isotope Name Atomic Number Mass Number # protons # electrons # neutrons 16 8O manganese-56 2 13. Determine the average atomic mass of the following mixtures of isotopes. 126 128 a. 80.% 127 53 I , 17% 53 I , 3% 53 I _____ 14. If samples of two different elements each represent one mole, then a. they are equal in mass. b. they contain the same number of atoms c. their molar masses are equal d. they have the same atomic mass 15. Calculate the number of atoms in 10.0 g of aluminum. 16. Determine the mass in grams of 5.00 x 1023 mol of oxygen atoms. 17. Write balanced nuclear equations for the following: a. The alpha decay of neptunium-237 b. The beta decay of bismuth-210 c. Alpha-particle bombardment of plutonium-239 produces a neutron and another isotope. d. With what particle would you bombard sulfur-32 with to produce hydrogen-1 and phosphorus-32? 18. How much time will be required for a sample of radioactive tritium (t1/2 = 12.5 years) to lose 75 % of its radioactivity? _____ 19. A 900. mg sample of platinum-197 is found to have a mass of 56.3 mg after exactly 3 days. What is the halflife of platinum-197 in hours? a. 24 hrs b. 18 hrs c. 0.75 hrs d. 16 hrs 3 Unit 4: Chemical Compounds 20. Write the name if given the formula or the formula if given the name. a. HBr(aq) n. molybdous acid ___________________________________ b. Cu2C2O4 ___________________________________ o. calcium phosphate ___________________________________ c. Cl2O7 ___________________________________ p. arsenic triiodide ___________________________________ ___________________________________ d. Al(ClO4)3 q. magnesium sulfate heptahydrate ___________________________________ ___________________________________ e. Fe(NO3)3 • 9H2O r. ___________________________________ ___________________________________ f. SO3 ___________________________________ g. HNO2 (aq) ___________________________________ h. Pb(Cr2O7)2 ___________________________________ i. N2O5 ___________________________________ j. H3BO2 (aq) ___________________________________ k. SnBr4 ___________________________________ l. Ti(IO)3 ____________________________________ m. Ga2(WO3)3 iron(III) carbonate s. sodium acetate ___________________________________ t. manganese(IV) telluride ___________________________________ u. scandium arsenite ___________________________________ v. tetraphosphorous decoxide ___________________________________ w. phosphorous acid ___________________________________ x. hydroselenic acid ___________________________________ y. acetic acid ___________________________________ z. platinum(II) perbromate ___________________________________ ____________________________________ 4 21. Determine the molar mass of chromium(II) phosphite. 22. Determine the percent composition of manganese(VII) arsenate. 23. How many electrons are present in a 20.54 gram sample of calcium ions? 24. What mass of aluminum hypochlorite contain 1.574 x 1023 hypochlorite ions? 25. An unknown gas has an effusion rate that is 0.845 times that of dinitrogen pentoxide. What is the molar mass of the unknown gas? 26. Determine the relative effusion rate of carbon monoxide and carbon dioxide. Interpret your answer. 5 27. Organic – provide names or structures where applicable. a. f. CH3 Br CH3 CH3 CH2 CH CH C CH3 CH3 F CH CH2 CH3 CH3 C CH3 CH2 CH CH2 CH C CH3 CH3 Cl b. g. CH3 CH3 CH2 CH2 C CH3 CH2 CH CH3 CH3 c. h. Br CH3 CH3 CH2 CH3 CH3 CH CH CH CH CH CH3 Br CH3 CH2 C CH CH CH CH3 Br CH3 Cl d. 4-ethyl-2-methyl-1-heptene i. 3-ethyl-2,6-dimethylheptane e. 3-ethyl-2-methyl-1-octene j. 4,4-dimethyl-2-pentyne 6 Unit 5: Mole 28. The following pertains to the compound, potassium hypomolybdite. a. Calculate the mass of oxygen in potassium hypomolybdite if there are 3.91x1024 formula units. b. Calculate the total number of ions in 154.3 g of potassium hypomolybdite. c. Calculate the mass of potassium hypomolybdite needed to make 250. mL of a 0.500 M solution. 29. An unknown gas was collected over water. Determine the molar mass of the unknown gas if a 0.167 g sample occupies a volume of 69.8 mL at 60.0°C. The barometric pressure is 752.8 torr. 30. An unknown gas is determined to have an empirical formula of CH2. If a 0.176 g sample of this gas occupies a volume of 35.0 mL at 134 kPa and 175°C, determine its molecular formula. 31. 123g of sucrose is dissolved in 568g of water. The solution has a density of 1.34g/ mL. Determine the molarity and molality of the solution. 32. A compound is found to be 47.1% carbon, 6.54%H, and 46.4% chlorine. The rate of effusion of this compound in the gaseous state was measured relative to oxygen gas. Nitrogen was found to effuse at rate that was 2.34 times faster than this compound. Determine the molecular formula of the compound. 7 Unit 6: Chemical Equations 33. Calculate for the reaction 2Al (s) + 3Cl2 (g) 2AlCl3 (s) from the data. 2Al (s) + 6 HCl (aq) 2 AlCl3 (aq) + 3 H2 (g) H = -1049.0 kJ HCl (aq) HCl (g) H = +74.8 kJ 2 H2 (g) + 2 Cl2 (g) 4 HCl (g) H = -3690.0 kJ AlCl3 (s) AlCl3 (aq) H = -323.0 kJ 34. Using bond energies, calculate the enthalpy change for the following reactions: 35. Using bond energies, calculate molar heat of combustion for 1 mole of methane: 36. Based on the diagram to the right, determine: a. Endo or Exo? _______________________ b. ΔHforward = _______________________ c. Eaforward = _______________________ d. ΔHreverse = _______________________ e. Eareverse = _______________________ 8 37. Sketch a potential energy curve that is represented by the following values of ΔH and Ea. ΔHreverse = -10 kJ Eaforward = +40 kJ Activated Complex = 50 kJ Is this an endothermic or exothermic reaction? 38. Write complete balanced chemical equations. Indicate precipitate for double replacement reactions. a. Zinc carbonate decomposes. b. Strontium is mixed with chlorine gas. c. Combustion of octane. d. Iron is added to acetic acid. e. Potassium oxide is mixed with water. f. Lithium chlorate decomposes. g. Potassium hydroxide is added to sulfuric acid. h. Sulfur trioxide is bubbled through water. i. Zinc is dropped into hydrochloric acid. j. Decomposition of calcium oxide. k. Gold metal dropped into sulfurous acid. l. Silver nitrate is added to ammonium phosphate. m. Fluorine is added to sodium bromide. n. Carbonic acid is heated. 9 Unit 7: Stoichiometry ____ 39. Given the reaction of propane burning in air, how many grams of oxygen gas are required to burn 3.01 1023 propane molecules? a. b. c. d. e. 80.0 g 40.0 g 160 g 16.0 g 64.0 g ____ 40. A mixture of calcium oxide and calcium carbonate that had a mass of 3.454 g was heated until all the calcium carbonate was decomposed. After heating, the sample had a mass of 3.102 g. Calculate the mass of calcium carbonate present in the original sample. a. b. c. d. e. 0.400 g 0.800 g 1.00 g 1.60 g 0.200 g ____ 41. The following statements apply to the interpretation of chemical equations. Not all of the statements are true. Which response includes all of the true statements, and no others? I. II. III. IV. V. a. b. c. d. e. The sum of the number of moles of the reactants must equal the sum of the number of moles of products in a balanced equation. The sum of the number of grams of the reactants that react must equal the sum of the number of grams of the products produced by the reaction. The following equation for the reaction involving hypothetical substances, A, B, C, and D, implies that the products C and D are always produced in a three to one mole ratio. A + 2B 3C + D The equation shown in III implies that in any reaction involving A and B as reactants, A must be the limiting reactant. The total number of atoms in the reactants that react must always equal the total number of atoms in the products produced by the reaction. I and V I, II, and III II, IV, and V II, III, and V III, IV, and V ____ 42. The thermite reaction is performed using 8.6 g iron(III) oxide and 1.8 g powdered aluminum metal. Which reactant is in excess and by how much? a. b. c. d. e. Al, 0.3 g Fe2O3, 2.0 g Al, 2.1 g Al, 1.1 g Fe2O3, 3.3 g 10 ____ 43. The reaction of 5.0 g of fluorine gas with excess chlorine gas produced 5.6 g of chlorine trifluoride. What is the percent yield of the reaction? a. b. c. d. e. 58% 69% 76% 86% 92% ____ 44. Suppose 600. g of phosphorus reacts with 1300. g of sulfur in a synthesis reaction. How many grams of tetraphosphorus decasulfide can be produced, assuming an 80.0% yield for the reaction a. b. c. d. e. 4.62 102 g 1.44 103 g 2.16 103 g 4.92 103 g 6.50 102 g ____ 45. Sulfuric acid is probably the most important industrial chemical because it is used in so many industrial processes to produce or purify other chemicals. It can be produced by a three step process. First, sulfur is burned in air to give sulfur dioxide. Second, the sulfur dioxide is converted to sulfur trioxide by passing the sulfur dioxide over a catalyst in the presence of oxygen at a high temperature. Third, the sulfur trioxide is reacted with water to form sulfuric acid. What mass of sulfuric acid would be formed from 1.00 x 103 kg of sulfur, if the three steps gave yields as listed below? S + O2 SO2 2SO2 + O2 2SO3 SO3 + H2O H2SO4 92.5% 72.6% 98.2% a. b. c. d. e. ____ 46. a. b. c. d. e. ____ 47. 4.03 103 kg 2.02 103 kg 3.06 103 kg 2.84 103 kg 2.22 103 kg What mass of a 25.0% barium nitrate solution contains 40.0 grams of barium nitrate? 117 g 160 g 321 g 10.0 g 62.5 g If 45.0 mL of 0.250 M lead(IV) chloride solution reacts with 20.0 mL of ammonium sulfate, what is the molarity of the ammonium sulfate solution? a. b. c. d. e. ____ 48. 0.502 M 1.25 M 2.25 M 1.13 M 0.563 M What mass of calcium carbonate is required to react with 100. mL of a 2.00 M hydrochloric acid solution? a. 5.00 g b. 10.0 g c. 15.0 g 11 d. 20.0 g e. 23.0 g ____ 49. What volume of 0.150 M silver nitrate solution is required to react with 80.0 mL of 0.0660 M calcium chloride solution according to the following reaction? a. b. c. d. e. ____ 50. a. b. c. d. e. ____ 51. a. b. c. d. e. ____ 52. a. b. c. d. e. ____ 53. a. b. c. d. e. ____ 54. a. b. c. d. e. 70.4 mL 140 mL 26.8 mL 35.2 mL 60.2 mL How many grams of calcium hydroxide are contained in 1500. mL of a 0.0250 M calcium hydroxide solution? 3.17 g 2.78 g 1.85 g 2.34 g 3.47 g What volume of 0.0750 M barium hydroxide will completely react with 125 mL of 0.0350 M hydrochloric acid? 29.2 mL 42.0 mL 230. mL 536 mL 53.6 mL What is the molarity of a sulfurous acid solution if 23.7 mL of this solution requires 16.8 mL of 0.296 M sodium hydroxide for titration to its endpoint? 0.210 M 0.358 M 0.105 M 0.421 M 0.0525 M How much heat is released when 75 g of octane is burned completely? 7200 kJ 8360 kJ 4.1 105 kJ 3600 kJ 5500 kJ How much heat is evolved in the formation of 35.0 grams of iron(III) oxide from its elements at 25C and 1.00 atm pressure? 90.4 kJ 180.7 kJ 151 kJ 360.1 kJ 243. 9 kJ Unit 8: Electrons 55. Calculate and determine the type of EMR: 15 a. the energy of a photon with a frequency of 8.77x10 s−1 12 b. the frequency of a photon with an energy of 1.88x10−25 J. 56. Write the shortened configuration and orbital notation for: a. Silver 57. What is the total number of electrons that will be in p orbitals in 8.31 moles of ground state zinc atoms? 58. In the hydrogen atom, the energy associated with the fifth energy level is −8.72x10−20 J while the energy of the first energy level is −2.18x10−18 J. a. Calculate the energy change from n=5 to n=1? b. Calculate the wavelength of the emitted photon? _____ 59. Which of the following colors has the highest frequency? a. blue b. red c. violet d. yellow _____ 60. Which of the following has the longest wavelength? a. U.V. b. I.R. c. X-ray d. gamma Unit 9: Bonding 61. Draw the Lewis dot structure for strontium nitride. 62. By use of electronegativity, identify each of the following bonds as: nonpolar, polar covalent, or ionic. CH4 H2O RbI O2 13 63. How many coordinate covalent bonds are present in 6.93 x 1024 molecules of perchloric acid? 64. Show all possible resonance structures for the carbonate ion. 65. What is the electron geometry, molecular geometry and bond angle for the carbonate ion? 66. Complete the following table using your knowledge of Lewis Structures and VSEPR theory. Lewis Structure Structural Formula (indicate polarity) electron geometry bond angle molecular geometry CH2Cl2 H2S 14 BF3 NF3 Unit 10: Solutions ____ 67. Consider the three statements below. Which numbered response contains all the statements that are true and no false statements? I. II. III. a. b. c. d. e. ____ 68. a. b. c. d. e. ____ 69. a. b. c. d. e. ____ 70. Hydration is a special case of solvation in which the solvent is water. The oxygen end of water molecules is attracted toward Ca2+ ions. The hydrogen end of water molecules is attracted toward Cl- ions. I II III I and II I, II, and III Which of the following solutions would not be expected to exist? NaCl in CCl4 (carbon tetrachloride, a nonpolar solvent) NaCl in water Pentane, C5H12, in CCl4 Methyl alcohol, CH3OH, in water Vegetable oil in mineral oil The molality of a solution is the mass of solute divided by the kilograms of solvent. The moles of solute divided by the liters of solvent. the moles of solute divided by the kilograms of solvent. the mass of solute divided by the liters of solution. the moles of solute divided by the liters of solution. Calculate the molality of a solution that contains 25 g of H2SO4 dissolved in 80. g of H2O. 15 a. 1.6 m b. 2.2 m c. 3.2 m d. 6.3 m e. 7.0 m ____ 71 Calculate the molality of a 10.0% phosphoric acid solution in water. a. 0.380 m b. 0.760 m c. 1.13 m d. 1.51 m e. 1.89 m ____ 72. What mass of water must be used to dissolve 20.0 grams of ethanol, C2H5OH, to prepare a 0.0500 molal solution of ethanol? a. 3.76 kg b. 4.00 kg c. 8.70 kg d. 6.35 kg e. 7.18 kg ____ 73. Which aqueous solution would have the lowest vapor pressure at 25 C? a. 1 M NaCl b. 1 M Na3PO4 c. 1M sucrose, C12H10O11 d. 1 M MgCl2 e. 1 M glucose, C6H12O6 ____ 74. a. b. c. d. e. ____ 75. a. b. c. d. e. ____ 76. a. b. c. d. e. ____ 77. a. b. c. Which of these aqueous solutions would be expected to have the highest boiling point? 0.100 m calcium chloride 0.200 m sodium hydroxide 0.050 m potassium sulfate 0.050 m aluminum sulfate 0.200 m glucose If 4.27 grams of sucrose, C12H22O11, are dissolved in 15.2 grams of water, what will be the boiling point of the resulting solution? 101.64C 100.42C 99.626C 100.73C 101.42C Calculate the boiling point of a solution prepared by dissolving 70.0 g of naphthalene, C10H8 (a nonvolatile nonelectrolyte), in 220.0 g of benzene, C6H6. The Kb for benzene = 2.53C/m. The boiling point of pure benzene is 80.1C. 87.8C 73.8C 83.2C 86.4C 106.3C Calculate the freezing point of a solution that contains 68.4 g of sucrose in 300. g of water. - 0.186C - 0.372C - 0.558C 16 d. e. ____ 78. a. b. c. d. e. ____ 79. a. b. c. d. e. ____ 80. ____ ____ ____ ____ ____ a. b. c. d. e. 81. a. b. c. d. e. 82. a. b. c. d. e. 83. a. b. c. d. e. 84. a. b. c. d. e. 85. a. b. c. d. - 0.744C -1.24C Which of the following statements regarding a 1 M sucrose solution is not correct? The boiling point is greater than 100C. The freezing point is less than that of a 1 M NaCl solution. The freezing point is less than 0.0C. The boiling point is less than that of a 1 M NaCl solution. The vapor pressure at 100C is less than 760 torr. A 4.305-gram sample of a nonelectrolyte is dissolved in 105 grams of water. The solution freezes at -1.23C. Calculate the molecular weight of the solute. 39.7 g/mol 58.4 g/mol 46.2 g/mol 62.0 g/mol 74.2 g/mol When 35.0 g of an unknown nonelectrolyte is dissolved in 220.0 g of benzene, the solution boils at 83.2C. Calculate the molecular weight of the unknown nonelectrolyte. The Kb for benzene = 2.53C/m. The boiling point of pure benzene is 80.1C. 130 g/mol 20.3 g/mol 183 g/mol 156 g/mol 194 g/mol The following describe properties of substances. Which one is not a property of acids? They have a sour taste. They react with metal oxides to form salts and water. They react with other acids to form salts and water. Their aqueous solutions conduct an electric current. They react with active metals to liberate H2. Which of the following is not a common property of aqueous solutions of most bases? They have a bitter taste. They have a slippery feeling. They change the colors of many indicators. They react with protonic acids to form salts and stronger bases. Their aqueous solutions conduct an electric current. According to the Arrhenius theory, which of the following is an acid? NH3 CH4 HCl H2 NaOH According to the Brønsted-Lowry theory, a base is defined as __________. an electron pair acceptor a proton acceptor an electron pair donor a proton donor any species that can produce hydroxide ions in aqueous solution A Brønsted-Lowry acid is defined as a __________. species that donates a proton species that accepts a proton species that accepts a share in an electron pair species that makes available a share in an electron pair 17 e. ____ 86. a. b. c. d. e. ____ 87. a. b. c. d. e. ____ 88. species that produces hydroxide ions in aqueous solution Which of the following can be a Brønsted-Lowry acid? AlCl3 CH4 NaOH H2O H2 Which one of the following species could not react as a Brønsted-Lowry acid? HCl H2O CaO NH3 CH3COOH In the equation HF + H2O a. b. c. d. e. ____ 89. a. b. c. d. e. H3O+ + F- H2O is a base, and HF is its conjugate acid. H2O is an acid, and HF is the conjugate base. HF is an acid, and F- is its conjugate base. HF is a base, and H3O+ is its conjugate acid. HF is a base, and F- is its conjugate acid. Which of the following does not represent a conjugate acid-base pair? H2O/OHH3O+/OHHCl/ClHNO3/NO3NH4+/NH3 ____ 90. Write the net ionic equation for the complete neutralization of HBr by Ca(OH)2. Use H+ rather than H3O+. What is the sum of the coefficients? a. 6 b. 8 c. 3 d. 4 e. 5 ____ 91. Which of the following reactions is the net ionic equation for the acid-base reaction between H2CO3 and Sr(OH)2? a. H2CO3 + Sr2+ + 2 OH- SrCO3 + 2 H2O b. H3O+ + OH- 2 H2O c. 2 H3O+ + Sr2+ + 2 OH- Sr2++ 4 H2O d. H2CO3 + 2 OH- 2 H2O+ CO32e. H2CO3 + Sr(OH)2 2H2O+ Sr2+ + CO32____ 92. The molar concentration of the Ca2+ ion is __________ and the molar concentration of OH- ion is __________ in 0.015 M calcium hydroxide. a. 0.015 M; 0.015 M b. 0.015 M; 0.030 M c. 0.030 M; 0.015 M d. 0.030 M; 0.030 M e. not enough information to calculate 18 ____ 93. A solution having a pH of 1.4 would be described as __________. a. distinctly basic b. slightly basic c. neutral d. slightly acidic e. distinctly acidic ____ 94. Calculate the pH of a solution that has the H3O+ concentration of 0.50 M. a. - 0.30 b. 13.70 c. 0.30 d. 7.30 e. 0.50 ____ 95. Calculate the pH of a solution in which [OH-] = 2.50 10-4 M. a. 0.40 b. 3.60 c. -3.60 d. 10.40 e. 13.60 ____ 96. What is the concentration of H3O+ ions in a solution in which pH = 4.32? a. 4.8 10-5 M b. 6.2 10-4 M c. 5.1 10-4 M d. 8.6 10-5 M e. 3.5 10-4 M ____ 97. What is the pH of a 0.400 M nitric acid solution? a. 0.40 b. 2.05 c. 0.60 d. 4.12 e. 1.67 ____ 98. a. b. c. d. e. ____ 99. What is the pH of 500. mL of solution containing 0.0124 gram of calcium hydroxide? 2.96 3.17 9.68 10.83 11.04 Concentrated hydrochloric acid is about 12.1 M. What volume of concentrated HCl is required to produce 5500 mL of 0.250 M? a. 980 mL b. 0.114 L c. 98 mL d. 0.211 L e. 1114 mL ____ 100. A laboratory stock solution is 1.50 M sodium hydroxide. Calculate the volume of this stock solution that would be needed to prepare 300. mL of 0.200 M sodium hydroxide. a. 2.25 mL b. 10.0 mL c. 40.0 mL d. 1.00 mL e. 0.100 mL 19 ____ 101. When a solution is diluted, what is the relationship of the number of moles of solute in the more concentrated initial volume of solution to the number of moles of solute in the less concentrated final volume of solution? a. The ratio of the numbers is directly proportional to the two volumes. b. The ratio of the numbers is inversely proportional to the two volumes. c. The number of moles of solute in the more concentrated initial volume is always greater. d. The number of moles of solute in the less concentrated final volume is always greater. e. The number of moles of solute in both solutions is the same. ____ 102. Calculate the molarity of the resulting solution if 25.0 mL of 2.40 M sulfuric acid solution is diluted to 300. mL. a. 0.200 M b. 29.0 M c. 2.00 M d. 0.400 M e. 0.0400 M 20