J. J. Thomson (1856 – 1940) John Dalton (1766–1844) Ernest Rutherford (1871 – 1938) UEQ: How does the structure of matter influence its physical and chemical behavior? Atom Electron cloud Isotope Nucleus Proton Neutron Electron Mass number Atomic number Average atomic mass History of the Atom Democritus (400 BC) proposed idea that all matter is made up of atoms History of the Atom Aristotle disagreed and said that matter was uniform throughout and not composed of smaller particles. History of the Atom Dalton (1800’s) proveD atoms DiD exist BUT he thought the atom was a solid sphere History of the Atom Thomson (1904) proposed electrons were dispersed throughout a positively chargeD sphere (“plumpuDDing”) History of the Atom Rutherford (1911) disproved thomson’s moDel by using the golD foil method. This proved that there was a dense, positive center surrounded by electrons. History of the Atom Bohr (1913) hypothesized electron travel around fixed orbits around the nucleus Chadwick concluded the nucleus was made of protons and neutrons History of the Atom Electron Cloud model (current) Electrons do not follow fixed orbit; but, tend to be at certain areas around nucleus at any given time Structure of the atom 3 subatomic particles identify the element 1. protons Ernest Rutherford (1909) (+) charge Relative mass 1.007 276– or ~1 amu Mass of element Made of 3 quarks In nucleus, held by nuclear forces Identifies the element 2. Neutron (N) James Chadwick (1932) No charge; neutral Relative mass = 1.008 665 – or ~1 amu In nucleus and held by nuclear forces isotopes- atoms of same element with different #’s of neutrons Contributes to mass of atom Made of 3 quarks 3. Electron (e-) J.J. Thomson (1897) ( – ) charge Relative mass 0.000 5486 In orbitals, within the electron cloud Makes volume of atom (100,000 times larger than diameter of nucleus) Valence electrons - # in last energy level determines the chemical activity Atomic Number Number of protons Can also tell you number of electrons Atomic Mass Number of protons and neutrons of an atom Average Atomic Mass Weighted average mass of the mixture of an element’s isotopes Example: We have a box of 2 types of marbles (100 total). If 25% of these marbles have a mass of 2 g and 75% have a mass of 3 g, then what is the average mass of the marbles? Mathematical Formulas # of neutrons = mass # - atomic # Mass Number = neutrons + protons Atomic # = mass # - # of neutrons Nuclear Symbol superscript subscript Hyphen notation Element (name or symbol) hyphen mass # Isotope Elements of same atomic number with different number of neutrons Common Isotopes and Uses Hydrogen 1,2 Tracers for metabolic studies Oxygen 16 Metabolic studies and determining temperature of ancient seas Carbon 12 Metabolic studies and dating recent archeological artifacts Phosphorus 31 Metabolic and ecological tracers, studies of nucleotides and nucleic acids Sulfur 32, 33, 34 Labeling Proteins Cobalt 59 Cancer therapy, source of gamma rays