Chapter 13 Solid and Hazardous Waste Chapter Overview Questions What is solid waste and how much do we produce? How can we produce less solid waste? What are the advantages and disadvantages of reusing recycled materials? What are the advantages and disadvantages of burning or burying solid waste? What is hazardous waste and how can we deal with it? Chapter Overview Questions (cont’d) What can we do to reduce exposure to lead and mercury? How can we make the transition to a more sustainable low-waste society? Updates Online The latest references for topics covered in this section can be found at the book companion website. Log in to the book’s e-resources page at www.thomsonedu.com to access InfoTrac articles. InfoTrac: Computer waste can be a toxic mess. St. Louis Post-Dispatch (St. Louis, MO), June 8, 2006. InfoTrac: The Greening of America. Newsweek International, August 14, 2006. InfoTrac: Unwanted electronics. Tam Harbert. Electronic Business, April 2006 v32 i4 pS-6(5). Department of Health and Human Services: ToxFaqs Electronics Recycling Science Daily: Ashes To Ashes, Dust To Dust: Litter Made To Degrade Video: The Throw-Away Society This video clip is available in CNN Today Videos for Environmental Science, 2004, Volume VII. Instructors, contact your local sales representative to order this volume, while supplies last. Core Case Study: Love Canal — There Is No “Away” Between 1842-1953, Hooker Chemical sealed multiple chemical wastes into steel drums and dumped them into an old canal excavation (Love Canal). In 1953, the canal was filled and sold to Niagara Falls school board for $1. The company inserted a disclaimer denying liability for the wastes. Core Case Study: Love Canal — There Is No “Away” In 1957, Hooker Chemical warned the school not to disturb the site because of the toxic waste. In 1959 an elementary school, playing fields and homes were built disrupting the clay cap covering the wastes. In 1976, residents complained of chemical smells and chemical burns from the site. Core Case Study: Love Canal — There Is No “Away” President Jimmy Carter declared Love Canal a federal disaster area. The area was abandoned in 1980 (left). Core Case Study: Love Canal — There Is No “Away” It still is a controversy as to how much the chemicals at Love Canal injured or caused disease to the residents. Love Canal sparked creation of the Superfund law, which forced polluters to pay for cleaning up abandoned toxic waste dumps. WASTING RESOURCES Solid waste: any unwanted or discarded material we produce that is not a liquid or gas. Municipal solid waste (MSW): produce directly from homes. Industrial solid waste: produced indirectly by industries that supply people with goods and services. Hazardous (toxic) waste: threatens human health or the environment because it is toxic, chemically active, corrosive or flammable. WASTING RESOURCES Solid wastes polluting a river in Jakarta, Indonesia. The man in the boat is looking for items to salvage or sell. WASTING RESOURCES The United States produces about a third of the world’s solid waste and buries more than half of it in landfills. About 98.5% is industrial solid waste. The remaining 1.5% is MSW. • About 55% of U.S. MSW is dumped into landfills, 30% is recycled or composted, and 15% is burned in incinerators. Electronic Waste: A Growing Problem E-waste consists of toxic and hazardous waste such as PVC, lead, mercury, and cadmium. The U.S. produces almost half of the world's e-waste but only recycles about 10% of it. INTEGRATED WASTE MANAGEMENT We can manage the solid wastes we produce and reduce or prevent their production. First Priority Primary Pollution and Waste Prevention • Change industrial process to eliminate use of harmful chemicals • Purchase different products • Use less of a harmful product • Reduce packaging and materials in products • Make products that last longer and are recyclable, reusable, or easy to repair Second Priority Last Priority Secondary Pollution and Waste Prevention Waste Management • Reuse products • Repair products • Recycle • Compost • Buy reusable recyclable products • Treat waste to reduce toxicity • Incinerate waste • Bury waste in landfills • Release waste into environment for dispersal or dilution Solutions: Reducing Solid Waste Refuse: to buy items that we really don’t need. Reduce: consume less and live a simpler and less stressful life by practicing simplicity. Reuse: rely more on items that can be used over and over. Repurpose: use something for another purpose instead of throwing it away. Recycle: paper, glass, cans, plastics…and buy items made from recycled materials. What Can You Do? Solid Waste • Follow the five Rs of resource use: Refuse, Reduce, Reuse, Repurpose, and Recycle. • Ask yourself whether you really need a particular item. • Rent, borrow, or barter goods and services when you can. • Buy things that are reusable, recyclable, or compostable, and be sure to reuse, recycle, and compost them. • Do not use throwaway paper and plastic plates, cups and eating utensils, and other disposable items when reusable or refillable versions are available. • Refill and reuse a bottled water container with tap water. • Use e-mail in place of conventional paper mail. • Read newspapers and magazines online. • Buy products in concentrated form whenever possible. REUSE Reusing products is an important way to reduce resource use, waste, and pollution in developed countries. Reusing can be hazardous in developing countries for poor who scavenge in open dumps. They can be exposed to toxins or infectious diseases. How People Reuse Materials Children looking for materials to sell in an open dump near Manila in the Philippines. Case Study: Using Refillable Containers Refilling and reusing containers uses fewer resources and less energy, produces less waste, saves money, and creates jobs. In Denmark and Canada’s Price Edward’s Island there is a ban on all beverage containers that cannot be reused. In Finland 95% of soft drink and alcoholic beverages are refillable (Germany 75%). REUSE Reducing resource waste: energy consumption for different types of 350-ml (12-oz) beverage containers. Aluminum can, used once Steel can, used once Recycled steel can Glass drink bottle, used once Recycled aluminum can Recycled glass drink bottle Refillable drink bottle, used 10 times Energy (thousands of kilocalories) How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Do you support banning all beverage containers that cannot be reused as Denmark has done? a. No. Reused containers may be unsanitary. b. Yes. A ban will save energy, money, and resources and result in a cleaner environment. Solutions: Other Ways to Reuse Things We can use reusable shopping bags, food containers, and shipping pallets, and borrow tools from tool libraries. Many countries in Europe and Asia charge shoppers for plastic bags. How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Should consumers have to pay for plastic or paper bags at grocery and other stores? a. No. Instead, give discounts to people who bring their own bags. b. Yes. Making consumers buy their bags will reduce waste. What Can You Do? Reuse • Buy beverages in refillable glass containers instead of cans or throwaway bottles. • Use reusable plastic or metal lunchboxes. • Carry sandwiches and store food in the refrigerator in reusable containers instead of wrapping them in aluminum foil or plastic wrap • Use rechargeable batteries and recycle them when their useful life is over. • Carry groceries and other items in a reusable basket, a canvas or string bag, or a small cart. • Use reusable sponges and washable cloth napkins, dishtowels, and handkerchiefs instead of throwaway paper ones. • Buy used furniture, computers, cars, and other items. • Give or sell items you no longer use to others. RECYCLING Primary (closed loop) recycling: materials are turned into new products of the same type. Secondary recycling: materials are converted into different products. Used tires shredded and converted into rubberized road surface. Newspapers transformed into cellulose insulation. RECYCLING There is a disagreement over whether to mix urban wastes and send them to centralized resource recovery plants or to sort recyclables for collection and sale to manufacturers as raw materials. To promote separation of wastes, 4,000 communities in the U.S. have implemented payas-you-throw or fee-per-bag waste collection systems. How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Should households and businesses be charged for the amount of mixed waste picked up but not charged for pickup of materials separated for recycling? a. No. It would encourage illegal dumping and burning of wastes. b. Yes. Consumer source separation saves money and makes consumers more conscientious. RECYCLING Composting biodegradable organic waste mimics nature by recycling plant nutrients to the soil. Recycling paper has a number of environmental (reduction in pollution and deforestation, less energy expenditure) and economic benefits and is easy to do. RECYCLING Recycling many plastics is chemically and economically difficult. Many plastics are hard to isolate from other wastes. Recovering individual plastic resins does not yield much material. The cost of virgin plastic resins in low than recycled resins due to low fossil fuel costs. There are new technologies that are making plastics biodegradable. How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Should we place much greater emphasis on recycling with the goal of recycling at least 60% of the municipal solid waste that we produce? a. No. Recycling programs should be market driven rather than setting unrealistically high goals that will either fail or require support from already overtaxed citizens. b. Yes. High recycling rates will reduce pollution and save energy. RECYCLING Reuse and recycling are hindered by prices of goods that do not reflect their harmful environmental impacts, too few government subsidies and tax breaks, and price fluctuations. How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Should governments pass laws requiring manufacturers to take back and reuse or recycle all packaging waste, appliances, electronic equipment, and motor vehicles at the end of their useful lives? a. No. These regulations would increase prices for consumers. b. Yes. The regulations would promote the manufacturing of more environmentally friendly products and further protect the environment. Trade-Offs Recycling Advantages Reduces air and water pollution Saves energy Reduces mineral demand Reduces greenhouse gas emissions Reduces solid waste production and disposal Disadvantages Does not save landfill space in areas with ample land May lose money for items such as glass and most plastic Helps protect biodiversity Reduces profits from landfills and incinerators Can save money for items such as paper, metals, and some plastics Source separation is inconvenient for some people Important part of economy BURNING AND BURYING SOLID WASTE Globally, MSW is burned in over 1,000 large waste-to-energy incinerators, which boil water to make steam for heating water, or space, or for production of electricity. Japan and a few European countries incinerate most of their MSW. Burning Solid Waste Waste-to-energy incinerator with pollution controls that burns mixed solid waste. Electricity Steam Smokestack Turbine Generator Conventional landfill Waste treatment Hazardous waste landfill Trade-Offs Incineration Advantages Reduces trash volume Less need for landfills Disadvantages Expensive to build Costs more than short-distance hauling to landfills Low water pollution Difficult to site because of citizen opposition Concentrates hazardous substances into ash for burial or use as landfill cover Some air pollution Older or poorly managed facilities can release large amounts of air pollution Sale of energy reduces cost Output approach that encourages waste production Modern controls reduce air pollution Can compete with recycling for burnable materials such as newspaper Some facilities recover and sell metals How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Do the advantages of incinerating solid waste outweigh the disadvantages? a. Yes. Incineration is a sanitary and effective method for eliminating infectious and organic wastes. b. No. Incineration can generate toxic air pollution and ashes. Burying Solid Waste Most of the world’s MSW is buried in landfills that eventually are expected to leak toxic liquids into the soil and underlying aquifers. Open dumps: are fields or holes in the ground where garbage is deposited and sometimes covered with soil. Mostly used in developing countries. Sanitary landfills: solid wastes are spread out in thin layers, compacted and covered daily with a fresh layer of clay or plastic foam. Topsoil Sand Clay Garbage Probes to detect methane leaks When landfill is full, layers of soil and clay seal in trash Electricity Methane storage and compressor building Methane gas recovery well Synthetic liner Sand Clay Subsoil Leachate treatment system Pipes collect explosive methane as used as fuel to generate electricity Leachate storage tank Compacted solid waste Garbage Sand generator building Leachate pipes Leachate pumped up to storage tank for safe disposal Clay and plastic lining to prevent leaks; pipes collect leachate from bottom of landfill Groundwater Groundwater monitoring well Leachate monitoring well Trade-Offs Sanitary Landfills Advantages No open burning Little odor Low groundwater pollution if sited properly Can be built quickly Low operating costs Disadvantages Noise and traffic Dust Air pollution from toxic gases and volatile organic compounds Releases greenhouse gases (methane and CO2) unless they are collected Groundwater contamination Can handle large amounts of waste Slow decomposition of wastes Filled land can be used for other purposes Discourages recycling, reuse, and waste reduction No shortage of landfill space in many areas Eventually leaks and can contaminate groundwater How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Do the advantages of burying solid waste in sanitary landfills outweigh the disadvantages? a. No. Ultimately, landfills leak and pollute the environment. b. Yes. They have relatively low operating costs, can store large amounts of waste, and are designed to prevent pollution. Case Study: What Should We Do with Used Tires? We face a dilemma in deciding what to so with hundreds of millions of discarded tires. HAZARDOUS WASTE Hazardous waste: is any discarded solid or liquid material that is toxic, ignitable, corrosive, or reactive enough to explode or release toxic fumes. The two largest classes of hazardous wastes are organic compounds (e.g. pesticides, PCBs, dioxins) and toxic heavy metals (e.g. lead, mercury, arsenic). What Harmful Chemicals Are in Your Home? Cleaning Gardening • Disinfectants • Drain, toilet, and window cleaners • Spot removers • Septic tank cleaners • Pesticides • Weed killers • Ant and rodent killers • Flea powders Paint • Latex and oil-based paints • Paint thinners, solvents, and strippers • Stains, varnishes, and lacquers • Wood preservatives • Artist paints and inks General • Dry-cell batteries (mercury and cadmium) • Glues and cements Automotive • Gasoline • Used motor oil • Antifreeze • Battery acid • Solvents • Brake and transmission fluid • Rust inhibitor and rust remover Hazardous Waste Regulations in the United States Two major federal laws regulate the management and disposal of hazardous waste in the U.S.: Resource Conservation and Recovery Act (RCRA) • Cradle-to-the-grave system to keep track waste. Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) • Commonly known as Superfund program. Hazardous Waste Regulations in the United States The Superfund law was designed to have polluters pay for cleaning up abandoned hazardous waste sites. Only 70% of the cleanup costs have come from the polluters, the rest comes from a trust fund financed until 1995 by taxes on chemical raw materials and oil. How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Should the U.S. Congress reinstate the polluterpays principle by using taxes from chemical, oil, mining, and smelting companies to reestablish a fund for cleaning up existing and new Superfund sites? a. No. All taxpayers, not certain industries, should pay for cleaning up sites polluted in the past. b. Yes. Funding for Superfund is needed and wastegenerating industries rather than ordinary citizens should fund it. DEALING WITH HAZARDOUS WASTE We can produce less hazardous waste and recycle, reuse, detoxify, burn, and bury what we continue to produce. Produce Less Waste Manipulate processes to eliminate or reduce production Recycle and reuse Convert to Less Hazardous or Nonhazardous Substances Land treatment Thermal treatment Incineration Chemical, physical, and biological treatment Ocean and atmospheric assimilation Put in Perpetual Storage Landfill Underground injection Waste piles Surface impoundments Salt formations Arid region unsaturated zone Conversion to Less Hazardous Substances Physical Methods: using charcoal or resins to separate out harmful chemicals. Chemical Methods: using chemical reactions that can convert hazardous chemicals to less harmful or harmless chemicals. Conversion to Less Hazardous Substances Biological Methods: Bioremediation: bacteria or enzymes help destroy toxic and hazardous waste or convert them to more benign substances. Phytoremediation: involves using natural or genetically engineered plants to absorb, filter and remove contaminants from polluted soil and water. Radioactive contaminants Organic contaminants Sunflower Inorganic metal contaminants Poplar tree Indian mustard Willow tree Brake fern Landfill Polluted groundwater in Decontaminated Soil water out Groundwater Rhizofiltration Roots of plants such as sunflowers with dangling roots on ponds or in greenhouses can absorb pollutants such as radioactive strontium90 and cesium-137 and various organic chemicals. Phytostabilization Plants such as willow trees and poplars can absorb chemicals and keep them from reaching groundwater or nearby surface water. Oil spill Polluted leachate Phytodegradation Plants such as poplars can absorb toxic organic chemicals and break them down into less harmful compounds which they store or release slowly into the air. Soil Groundwater Phytoextraction Roots of plants such as Indian mustard and brake ferns can absorb toxic metals such as lead, arsenic, and others and store them in their leaves. Plants can then be recycled or harvested and incinerated. Trade-Offs Phytoremediation Advantages Disadvantages Easy to establish Slow (can take several growing seasons) Inexpensive Can reduce material dumped into landfills Produces little air pollution compared to incineration Low energy use Effective only at depth plant roots can reach Some toxic organic chemicals may evaporate from plant leaves Some plants can become toxic to animals How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Do the advantages of using phytoremediation to detoxify hazardous waste outweigh the disadvantages? a. No. The process is often too slow and cannot remove contaminants below the root zones of the remediating plants. b. Yes. Plants can be effective in removing organics, radionuclides, and inorganic contaminants from soil and water. Conversion to Less Hazardous Substances Incineration: heating many types of hazardous waste to high temperatures – up to 2000 °C – in an incinerator can break them down and convert them to less harmful or harmless chemicals. Conversion to Less Hazardous Substances Plasma Torch: passing electrical current through gas to generate an electric arc and very high temperatures can create plasma. The plasma process can be carried out in a torch which can decompose liquid or solid hazardous organic material. Trade-Offs Plasma Arc Advantages Small Disadvantages High cost Produces CO2 and CO Mobile. Easy to move to different sites Produces no toxic ash Can release particulates and chlorine gas Can vaporize and release toxic metals and radioactive elements How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Do the advantages of using a plasma torch to detoxify hazardous waste outweigh the disadvantages? a. No. Plasma torches are expensive and the combustion byproducts may be harmful to the environment and humans. b. Yes. Plasma torches are convenient for disposing of hazardous wastes. Long-Term Storage of Hazardous Waste Hazardous waste can be disposed of on or underneath the earth’s surface, but without proper design and care this can pollute the air and water. Deep-well disposal: liquid hazardous wastes are pumped under pressure into dry porous rock far beneath aquifers. Surface impoundments: excavated depressions such as ponds, pits, or lagoons into which liners are placed and liquid hazardous wastes are stored. Trade-Offs Deep Underground Wells Advantages Disadvantages Safe method if sites are chosen carefully Leaks or spills at surface Wastes can be retrieved if problems develop Leaks from corrosion of well casing Easy to do Existing fractures or earthquakes can allow wastes to escape into groundwater Low cost Encourages waste production How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Do the advantages of deep-well disposal of hazardous waste outweigh the disadvantages? a. No. The systems may leak and contaminate valuable soils, sediments, and groundwaters. b. Yes. Deep injection wells can be designed to permanently remove hazardous wastes from surface and near-surface environments. Trade-Offs Surface Impoundments Advantages Low construction costs Low operating costs Can be built quickly Wastes can be retrieved if necessary Can store wastes indefinitely with secure double liners Disadvantages Groundwater contamination from leaking liners (or no lining) Air pollution from volatile organic compounds Overflow from flooding Disruption and leakage from earthquakes Promotes waste production How Would You Vote? To conduct an instant in-class survey using a classroom response system, access “JoinIn Clicker Content” from the PowerLecture main menu for Living in the Environment. Do the advantages of storing hazardous wastes in surface impoundments outweigh the disadvantages? a. No. The environment should not be openly exposed to liquid hazardous wastes. b. Yes. Surface impoundments are inexpensive solutions for at least the temporary storage of liquid wastes. Long-Term Storage of Hazardous Waste Long-Term Retrievable Storage: Some highly toxic materials cannot be detoxified or destroyed. Metal drums are used to stored them in areas that can be inspected and retrieved. Secure Landfills: Sometimes hazardous waste are put into drums and buried in carefully designed and monitored sites. Secure Hazardous Waste Landfill In the U.S. there are only 23 commercial hazardous waste landfills. Bulk Gas Topsoil waste vent Earth Impervious clay Plastic cover Sand Impervious Clay clay cap cap Water table Earth Groundwater Leak detection system Double leachate Plastic Reactive collection system double wastes liner in drums Groundwater monitoring well What Can You Do? Hazardous Waste • Use pesticides in the smallest amount possible. • Use less harmful substances instead of commercial chemicals for most household cleaners. For example use liquid ammonia to clean appliances and windows; vinegar to polish metals, clean surfaces, and remove stains and mildew; baking soda to clean household utensils, deodorize, and remove stains; borax to remove stains and mildew. • Do not dispose of pesticides, paints, solvents, oil, antifreeze, or other products containing hazardous chemicals by flushing them down the toilet, pouring them down the drain, burying them, throwing them into the garbage, or dumping them down storm drains. Case Study: Lead Lead is especially harmful to children and is still used in leaded gasoline and household paints in about 100 countries. Solutions Lead Poisoning Prevention Control Phase out leaded gasoline worldwide Sharply reduce lead emissions from old and new incinerators Phase out waste incineration Replace lead pipes and plumbing fixtures containing lead solder Test blood for lead by age 1 Remove leaded paint and lead dust from older houses and apartments Ban use of lead solder Ban use of lead in computer and TV monitors Remove lead from TV sets and computer monitors before incineration or land disposal Test for lead in existing ceramicware used to serve food Ban lead glazing for ceramicware used to serve food Ban candles with lead cores Test existing candles for lead Wash fresh fruits and vegetables Case Study: Mercury Mercury is released into the environment mostly by burning coal and incinerating wastes and can build to high levels in some types of fish. Solutions Mercury Pollution Prevention Control Phase out waste incineration Remove mercury from coal before it is burned Sharply reduce mercury emissions from coal-burning plants and incinerators Convert coal to liquid or gaseous fuel Tax each unit of mercury emitted by coal-burning plants and incinerators Switch from coal to natural gas and renewable energy resources such as wind, solar cells, and hydrogen Phase out use of mercury in all products unless they are recycled Collect and recycle mercurycontaining electric switches, relays, and dry-cell batteries Require labels on all products containing mercury AIR WINDS PRECIPITATION PhotoElemental chemical mercury vapor (Hg) Hg2+ and acids Inorganic mercury and acids (Hg2+) Inorganic mercury and acids (Hg2+) Deposition Incinerator Coalburning plant PRECIPITATION Hg2+ and acids Hg and SO2 Human sources WINDS Runoff of Hg2+ and acids WATER Large fish Deposition Vaporization Deposition Deposition Small fish BIOMAGNIFICATION IN FOOD CHAIN Phytoplankton Oxidation Elemental mercury liquid (Hg) Settles out Inorganic mercury (Hg2+) Bacteria and acids Bacteria Settles out SEDIMENT Zooplankton Organic mercury (CH3Hg+) Settles out ACHIEVING A LOW-WASTE SOCIETY In the U.S., citizens have kept large numbers of incinerators, landfills, and hazardous waste treatment plants from being built in their local areas. Environmental justice means that everyone is entitled to protection from environmental hazards without discrimination. Global Outlook: International Action to Reduce Hazardous Waste An international treaty calls for phasing out the use of harmful persistent organic pollutants (POPs). POPs are insoluble in water and soluble in fat. Nearly every person on earth has detectable levels of POPs in their blood. The U.S has not ratified this treaty. Making the Transition to a Low-Waste Society: A New Vision Everything is connected. There is no “away” for the wastes we produce. Dilution is not always the solution to pollution. The best and cheapest way to deal with wastes are reduction and pollution prevention.