International Journal of Research In Science & Engineering Volume: 1 Issue: 1 e-ISSN: 2394-8299 p-ISSN: 2394-8280 ENERGY ANALYSIS OF DIESEL AND BIODIESEL FUELLED C.I.ENGINE USING FIRST LAW OF THERMODYANAMIC -A REVIEW Sagar P.Potdukhe 1 PG Student, Department of Mechanical Engineering, Govt. College of Engineering, Amravati. Sagar.potdukhe@gmail.com ABSTRACT Modeling has been used to investigate the combustion performance of a single cylinder direct injection diesel engine fuelled by biodiesel like cotton seed oil. The focus of the present study is to review the different available model used for modeling of CI engines. The modeling of CI engine is divided into single zone, multizone and multi-dimensional model. The model evaluation is made based on the time complexity, space complexity, and prediction accuracy using the developed computer program like MATLAB. Our focus is on single zone model which further subdivided in many submodel i.e. heat release rate, heat transfer, ignition delay period, droplet evaporation, intake and exhaust flow and combustion model. The numerical simulation was performed with the standard specification of a CI engine by using MATLAB software with least time. ,Keywords: Diesel engine modeling, IC Engine, Biodiesel, cotton seed oil methyl ester ----------------------------------------------------------------------------------------------------------------------------1. INTRODUCTION Engine simulation has been extensively used to improve the engine performance. Compression ignition direct injection (CIDI) diesel engines have been widely used in heavy-duty vehicle, marine transportation and now have been increasingly being used in light duty vehicles, particularly in Europe and Japan Experimental work which is aimed at fuel economy and low pollutants emission for IC engine requires change in input parameter which is highly demanding in terms of money and time. So, in order to overcome this drawback, an alternative simulation of engine performance with the help of mathematical model and powerful digital computers lowers the cost and time. [2] In these simulation models, the effect of various design structures like design of combustion chamber input parameters (intake pressure, injection timing, etc.) and operation changes (compression ratio, speed, etc.) can be estimated in fast and non-expensive way provided that main mechanism are recognized and modeled perfectly to meet the experimental results. [12] Depending upon the various possible applications different types of models for diesel engine combustion process have been in use. In the order of increased complexity and increased computer system requirements these can be classified as single zone model models, quasi dimensional phenomenological models and Multidimensional computational fluid dynamics models. These models can reduce the number of experiments. [5] In case of single zone model cylinder temperature, pressure and mass can be obtained from ordinary differential equations by using the first law of thermodynamics and equation of state in each process. Biodiesel (cotton seed oil) have become an alternate to petro diesel in the view of the faster depletion of petro diesel. Understanding the aspects of biodiesel combustion is now possible with the simulation models. The measured pressure rise in an engine is used to tune the model and helps in calculating the rate of heat release from the engine cylinder.[6] 2. Energy analysis In engineering, modeling a process has come to mean developing and using the appropriate combination of assumption and equation that permit critical feature of the process to be analyzed. The modeling of engine process IJRISE| www.ijrise.org|editor@ijrise.org International Journal of Research In Science & Engineering Volume: 1 Issue: 1 e-ISSN: 2394-8299 p-ISSN: 2394-8280 continues to develop as our understanding of the physical and chemistry of the phenomena of interest steadily expand and as the capability of computers to solve complex equation continues to increase.[1] 2.1 Types of models. These can be two categorized. 1) Thermodynamic model. ο· Zero-dimensional single zone. ο· Quasi-dimensional multi-zone. 2) Fluid dynamic model. ο· Multidimensional model. 1) Thermodynamic model. Thermodynamic energy conservation based model are zero-dimensional (since in the absence of any flow modeling, geometric feature of the fluid motion cannot be predicted), phenomenological (since additional detail beyond the energy conservation equation is added for each phenomenon in turn), and quasi-dimensional (where specific geometric feature, example, the spark-ignition engine flame or diesel fuel spray shapes, are added to basic thermodynamic approach). In single zone models, the working fluid in the engine is assumed to be a thermodynamic system, which undergoes energy and/or mass exchange with the surroundings and the energy released during the combustion process is obtained by applying the first law of thermodynamics to the system.[1] 2) Fluid dynamic model. Fluid-dynamic based model are often called multi-dimensional model due to in their inherent ability to provide detailed geometric information on the flow field based on solution of the governing flow equation. [1] 2.3 Governing Equations for Open Thermodynamic System It is often required the model a region of the engine as an open thermodynamic system. Example are the cylinder volume and the intake and exhaust manifolds (or portion of these volume). Such a model is appropriate when the gas inside the open system boundary can be assumed uniform in composition vary with time due to heat transfer, work transfer and mass flow across the boundary, and boundary displacement. Such an open system is illustrated in fig. 1.2.1. The important equations are mass and energy conservation. These equations for an open system, with time or crank angle as the independent variable, are the building blocks for thermodynamic-based model.[1] 2.3.1 Conservation of Mass The rate of change of the total mass m of an open system is equal to the sum of the mass flows into and out of the system[1]: Μ π πΜ π π= ∑ Mass flow into the system are taken as positive; mass flow out are taken as negative. Fig.1.1 Open thermodynamic system IJRISE| www.ijrise.org|editor@ijrise.org (1.1) International Journal of Research In Science & Engineering Volume: 1 Issue: 1 e-ISSN: 2394-8299 p-ISSN: 2394-8280 For conservation of the fuel chemical element, it is convenient to use the fuel fraction f, which is define as ππ /π, where ππ denotes the mass of fuel (or fuel elements in the combustion product) in open system π ππ = (ππ ) = ∑π πΜπ = ∑π πΜπΜ ππ (1.2) ππ‘ Differential of eq.(1.2) lead to an equation for the rate of change of fuel fraction: πΜ π πΜ = ∑π ( ) (ππ − π) (1.3) π The fuel/air equivalence ratio ∅ is related to f via ∅ = [(πΉ/π΄)π (1 − π)]. Hence the rate of change of equivalence ratio of the material in the open system is ∅Μ = πΜ 1 (1.4) (πΉ/π΄)π (1−π)2 2.3.2 Conservation of Energy The first law of thermodynamic for open system in fig. 1.1 can be written [ref 3]: πΈΜ = ππ€Μ − πΜ + ∑π πΜπΜ ππ (1.5) Μ ππ€ is the total heat transfer rate into the system, across the system boundary and equal the sum of the heat transfer rate out of the system across each part of the boundary. πΜ is the work transfer the rate out of the system across the boundary; where the piston is displaced, the work transfer rate equal to pV. Because all energies and enthalpies are expressed relative to the same datum, it is not necessary to include the heat released by combustion in Eq. (1.5); this is already accounted for in the energy and enthalpy terms. The goal is the define rate of change of state of the open system in terms of πΜ and πΜ . Two approaches are commonly used, depending on whether the thermodynamic property routine provide values for internal energy u or enthalpy h. thus πΈΜ in Eq. (1.5) can be expressed πΈΜ = π ππ‘ (ππ’) πΈΜ = (πβ) − or π ππ‘ (ππ) It is assumed that the system can be characterize by T, p, and ∅; thus u = u(T, p, ∅) β = β(π, π, ∅) π = π(π, π, ∅) And the rate of change of u, h, and π can be written in the form ππΌ ππΌ ππΌ πΌΜ = ( ) πΜ + ( ) πΜ + ( ) ∅Μ (1.6) Where πΌ is u, h, and π . Using the ideal gas law in its two ππ ππ π∅ forms, π = ππ π and ππ = ππ π, and Eq. (8) for πΜ , an equation for πΜ can be derived : πΜ = Μ π πΜ 1 ππ 1 ππΜ πΜ (− − πΜ − ∅+ ) ππ⁄ππ π π ππ π π∅ π (1.7) Returning now to the energy conservation equation, expressing πΈΜ in term of π’Μ ππ βΜ and π’Μ ππ βΜ in term of partial derivatives with respect to T, p, and∅, and substituting for πΜ with Eq. (1.7), one can obtain equations for: πΜ = [π΅ − π ππ’ πΜ πΜ π· ππ π VΜ 1 π ( − B = −RT + C= 1+ V m T ∂R + ππ π∅ ∅)]⁄( ππ’ ππ + (Q wΜ + ∑j mΜ j hj − mΜu) R ∂T IJRISE| www.ijrise.org|editor@ijrise.org πΆ π ππ’ π· π ππ ) (1.8) (1.9) (1.10) International Journal of Research In Science & Engineering Volume: 1 Issue: 1 e-ISSN: 2394-8299 p-ISSN: 2394-8280 and m is mass of gas in the cylinder, πΜ π and πΜ π are the mass flow rates through the inlet valve and the exhaust valve, and f is the fraction mf/m. The subscript i and e denotes the properties of the flow through the intake and the exhaust valves respectively.[1] Compression m = 0 Μ and fΜ = 0 Μ Μ v Bm B V Q TΜ = (− − w ) A (1.11) Exhaust: mΜ fΜ = − e (fe − f) mΜ = −mΜ e B mΜ e A m T = [− h VΜ m C B V B (1 − ) − − φ + 1 Bm (1.12) (−mΜ e he − Q wΜ )] (1.13) Where, he is the enthalpy of flow through the exhaust valve. Above modelling technique have been traditionally used in two different directions [1] ο· In one way, both these models have been used to predict the in-cylinder pressure as a function of crank angle from an assumed energy release or mass burned profile (as a function of crank angle). ο· Another use of these models lies in determining the energy release/mass burning rate as a function of crank angle from experimentally obtained in-cylinder pressure data. 2.3.3 Engine modeling general equations for first-law of thermodynamics The first-law of thermodynamics applied to the engine cylinder reads [4]. dQ πΏ dφ −π dV dφ = dU dφ − ∑π πππ dφ βπ (1.14) where dQL/dφ is the rate of heat loss to the cylinder walls, as described by the semi-empirical Annand or Woschni correlations, p is the pressure of cylinder contents, dmj is the mass exchanged (positive when entering) in the step dφ and hj is the specific enthalpy of it. Subscript j denotes fuel injection, and exchange with the exhaust manifold, inlet manifold and crankcase . Ideal gas relation is given by ππ = ππ π π (1.15) The ideal gas relation can be expressed in differential form as: π dV dp dT dT +π = ππ π + π π π dφ dφ dφ dφ (1.16) The application of the first-law of thermodynamics to the engine cylinder (open cycle). ∑ ππ πvi π πππ dT dQ πΏ ππ π π dV πππ = − +∑ βπ − ∑ π’π dφ dφ π dφ dφ dφ π π The volume V of the engine cylinder, needed in the previous equations, π·2 π = πππ + π ( ) π₯ 4 With Vcl the clearance volume and x the piston displacement from its TDC position IJRISE| www.ijrise.org|editor@ijrise.org (1.17) (1.18) International Journal of Research In Science & Engineering Volume: 1 Issue: 1 e-ISSN: 2394-8299 p-ISSN: 2394-8280 π₯ = π(1 − πππ π) + πΏ[1 − √1 − π 2 π ππ2 π ] (1.19) Where L is the connecting rod length, r the crank radius, f = r/L and the crank angle 4 is measured from the bottom dead centre position (BDC). Consequently[4] dV π΄ππ·2 π cos π = [π sin π (1 + )] dφ 4 √1 − π 2 π ππ2 π (1.20) dφ = 6N dt With N the engine speed expressed in rpm, for transforming the various terms from time to degree crank angle basis. 3. Engine Submodels Submodels included in the study of the smallest region inside the engine cylinder which helps in proper understanding of the actual phenomena of the engine. It includes the different engine submodels which also help to study complex behaviour of the combustion.[12] 3.1 Intake and Exhaust Manifold Submodel Intake and exhaust manifold Submodel deals with the mass flow rate inside the cylinder either the air entering during the intake stroke, mass of fuel during the compression stroke and the amount of gases flow through the exhaust stroke. The timing and rate of fuel injection into the chamber affects the spray dynamics and combustion characteristics. If the upstream pressure of the injector nozzle is known and assumed that flow through the nozzle is incompressible, one dimensional and quasi-steady, then the mass flow rate of fuel injected inside the cylinder through the nozzle is given by [2]. π = πΆπ π΄π √2ππ βπ (1.21) In this type of mass flow rate, the intake and exhaust tanks (submodel) are treated as plenums with known temperatures and pressures. Earlier these models do not provide any information whether the flow is subcritical or supercritical at the inlet or outlet. They can be solved with the help of conservation of mass equation: in order to calculate the mass flow rate the equation is given by [2] π1 π = π΄π π1 √ π 1 π1 π1 = 2πΎ πΎ−1 2⁄πΎ π2 [( 2⁄πΎ π1 (πΎ+1)⁄πΎ π2 )−( (πΎ+1)⁄πΎ π1 )] (1.22) These equations are further modified by taking into account the critical behavior of the fluid at intake manifold and exhaust manifold. The intake process is assumed as a subcritical flow and the intake flow rate is given as [2] πππ π∅ = 1 6π ππ πΉπ √ 2ππ ππ −1 2⁄ππ π2 [( 2⁄π π1 π )−( (π +1)⁄ππ π2 π (π +1)⁄ππ π1 π )] (1.23) During the exhaust process, the flow at outlet valve is considered as a supercritical flow due to higher pressure difference between cylinder and exhaust port. When the pressure at the outlet valve decreases, then the behavior of flow changes to subcritical flow. 3.2 Modeling of heat release rate For empirical zero-dimensional modeling, the heat release approach is commonly used. In this, the thermal effects of combustion, rather than the process itself are modeled. Expressions are developed which correlate the IJRISE| www.ijrise.org|editor@ijrise.org International Journal of Research In Science & Engineering Volume: 1 Issue: 1 e-ISSN: 2394-8299 p-ISSN: 2394-8280 gross heat release rate to the cylinder pressure trace using first law of thermodynamics. The generated heat release data can be presented using mathematical tools such as Wiebe functions. These models consist of coefficients whose values need to be determined experimentally. The models can be verified by comparing the predicted cylinder pressure with the experimentally obtained cylinder pressure. The heat-release model should include[1]: a) An empirical or analytical description of ignition delay, b) An expression for the heat released during the pre-mixed phase, c) An expression for the heat released during the diffusion phase. 3.3 Ignition delay modeling:Ignition delay can be defined as the time interval between the start of fuel injection and the start of combustion. Many researchers have given correlations for predicting ignition delay in which the earliest was Wolfer (1938). The empirical formula used in the present model is shown in equation which was given by Hardenberg. This equation gives the value of ignition delay in terms of values of degrees of crank angle using temperatures (T) in Kelvin and pressure (P) in bar. The equation (33) has been used to predict the ignition delay. The ignition delay is modelled with an Arrhenius type of correlation. [1] π = 3.45. π −0.2 exp(2100⁄π) (1.24) The three important variables to be taken into account for ignition delay modeling are mean temperature, mean pressure and load. Engine load is given in terms of the percentage of maximum torque output. So modified equation is given by π = π. ∅−π π−π exp(2100⁄π) (1.25) Ø = load in percent 3.4 Mass Flow Model Thermodynamic model based on the step-by-step ‘emptying and filling method described by Watson and Janota. The conservation equations are used to evaluate the work, heat and mass transfer taking place across the boundaries of the control volume. The equations are solved at each crank & angle interval over an engine cycle of 360 degrees for a two-stroke engine or 720 degrees for a four-stroke engine. A comparison is made between the calculations for the previous cycle and the present cycle. If the convergence criteria have been met, the results will be recorded and the calculations stopped; otherwise a new cycle is commenced. Convergence usually takes between five to eight cycles.[13] A constant manifold pressure is assumed, and the mass transfer rate across valves and ports is calculated using the orifice analogy. For subsonic flow, this is described by √ Μ πΜ = πΆππ΄π π’ ( 2πΎ πΎ−1 )( 1 π π’ ππ’ π ) [( π) ππ’ 2⁄πΎ π − ( π) ππ’ (πΎ+1)⁄πΎ (πΎ+1)⁄πΎ ] (1.26) For chocked flow πΜ = πΆππ΄ππ’ √( 1 π π’ ππ’ )( 2 πΎ+1 ) (πΎ+1)⁄(πΎ−1) (1.27) Where πΜ is the mass flow rate through the valve or port, Cd is the discharge coefficient, A is the area, and γ, R, T, and P refer to the specific heat ratios, the specific perfect gas constant, absolute temperature, and pressure, respectively, for the fluid. The subscripts d and u denote downstream and upstream, respectively. The product Cd A represents an effective flow area, and it is calculated at each crank angle step corresponding to the valve or port timing input by the user. The value for Cd may be either a fixed average value, or it may be based on a set of nondimensional flow coefficients which are stored in simulation model as functions of valve lift. In the latter case, the user has a choice of either a high-swirl or zero-swirl inlet port and either a good or poor exhaust port. As a means of simplifying the input data, the program contains a typical valve lift polynomial to calculate the lift at each crank angle. The same polynomial is used for both inlet and exhaust valves.[13]. 3.5 Heat Transfer Model One-dimensional heat flux model to describe the heat transfer through the wall into the coolant at each crank angle step. Heat fluxes through the piston, cylinder liner, and cylinder head are calculated separately based on a IJRISE| www.ijrise.org|editor@ijrise.org International Journal of Research In Science & Engineering Volume: 1 Issue: 1 e-ISSN: 2394-8299 p-ISSN: 2394-8280 resistance network analogy approach. The heat flow path between the cylinder gases and the engine coolant can be considered to consist of three parts: gas to wall, conduction through wall, and wall to coolant. In the model, a composite wall is used with the option of using up to three layers with different thickness and material properties. Wall to coolant convection heat transfer is modelled using empirical bulk surface heat transfer coefficients.[12] πππ€ = βπ. π΄π(ππ€, π − ππππ ) (1.28) ππ‘ 4. LITERATURE SURVEY The following references were studied for analysis of experimental results by using different model and biodiesel in different working conditions on First law of Thermodynamic Vivek Kumar Gaba, Prerana Nashine and Shubhankar Bhowmick(2012): developed a combustion model for a diesel compression ignition (CI) engine for constant pressure combustion process. The work analytically examines the performance of a CI engine with the minimum use of diesel fuel as pilot fuel, and bio-diesel as secondary fuel. The combustion model has been developed for an ideal diesel engine using blends of biodiesel ranging from 20% to 100%. Using the first law of thermodynamics and equation of state in each process, the cycle was critically analyzed. The specification of a standard CI engine was used for numerical calculations. The variation of temperature with different equivalence ratio were studied and reported. The thermal efficiency of a pure diesel engine was observed to decrease exponentially from 67% to 47% as the equivalence ratio increases from 0.7 to 1.3. It was also observed that B- 20 and B-40 formed a good mixture among all other blends and the efficiency of pure bio-diesel was comparatively less than diesel as well as for other blends. A sharp increase in work output was observed as the equivalence ratio increases due to more fuel injection. It was also observed that efficiency of pure bio-diesel is comparatively lesser than all other blends, but the maximum cycle temperature for this blend is least. This indicates that NOx emission was not present in case of pure diesel; hence pure biodiesel can be used resulting in less pollution despite of less efficiency & work output. Work aims to develop a combustion model for a diesel compression ignition (CI) engine for constant pressure combustion process. The work analytically examines the performance of a CI engine with the minimum used of diesel fuel as pilot fuel, and bio-diesel as secondary fuel. The combustion model had been developed for an ideal diesel engine using blends of biodiesel ranging from 20% to 100%. Using the first law of thermodynamics and equation of state in each process, the cycle had been critically analyzed. The specification of a standard CI engine had been used for numerical calculations. The variation of temperature with different equivalence ratio is studied and reported. The thermal efficiency of a pure diesel engine is observed to decrease exponentially from 67% to 47% as the equivalence ratio increases from 0.7 to 1.3. It is also observed that B- 20 and B-40 formed a good mixture among all other blends. The work in a one-dimensional combustion model, employing constant eddy diffusivity and a one-step chemical reaction had been developed and applied to study the flame propagation in a Spark Ignition (SI) engine at 1600 and 4200 rpm under fuel rich conditions using one and two zone thermodynamic models. The thermodynamic models had been compared with 1-D model for average mixture temperature, the temperatures of the burned and unburned gases and the flame surface area and indicate that the one-dimensional model predictions are very sensitive to the eddy diffusivity and reaction rate data where as the two-zone thermodynamic model predicts, first, a monotonically increasing flame surface area with time and, then, a monotonically decreasing surface area. BORDET Nicolas, CAILLOL Christian, HIGELIN Pascal (2010). This paper presented a new 0D phenomenological approach to predict the combustion process in Diesel engines operated under various running conditions. The aim of this work was to develop a physical approach in order to improve the prediction of incylinder pressure and heat release for developing a tool for engine pre-mapping. The main contribution of this study was the modeling of the premixed part of the Diesel combustion. IJRISE| www.ijrise.org|editor@ijrise.org International Journal of Research In Science & Engineering Volume: 1 Issue: 1 e-ISSN: 2394-8299 p-ISSN: 2394-8280 In phenomenological Diesel combustion models, the premixed combustion phase was sometimes modeled as the propagation of a turbulent flame front. However, experimental studies had shown that this phase of Diesel combustion was actually a rapid combustion of part of the fuel injected and mixed with the surrounding gas. This mixture ignites quasi instantaneously when favourable thermodynamic conditions are locally reached. A chemical process then controls this combustion. they were worked on Spray and entrained surrounding gas model, two states turbulence model: K-k modified model, Vaporization model, Premixed Combustion Model, Diffusion Combustion Model, Extended Model for Multi Injection. Results were measured engine data are compared with computed results using the developed combustion model. Injection rates were modeled with Hermits polynomials optimized for each injection. The determined model parameters were then kept constant for the whole range of engine operating parameters. This experimental apparent energy rate was compared with the apparent energy rate calculated from the simulated pressure traces. Future work should improve the model to take into account large EGR rates as well as in-cylinder temperature distribution. To improve the existing model, interaction between sprays must be taken into account in multi-injection cases. Furthermore, a more detailed spray model can improve general results especially in cases with multiinjection. Zehra Sahin, Orhan Durgun (2008). In the presented study, the aim was to develop a complete cycle model and to prepare a computer code for determining complete cycle, performance characteristics, and exhaust emissions of diesel engines. For this purpose, a computer program had been developed. To compute diesel engine cycles, zerodimensional intake and exhaust model developed by Durgun,. Details of fuel spray formation, fuel–air mixing, swirl and heat transfer had been taken into account in this model. Also, an emission model based on the chemical equilibrium and kinetics of NO had been developed to calculate the pollutant concentrations within each zone and the whole of the cylinder. Using the developed computer program, complete engine cycle, engine performance parameters and exhaust emissions could be determined easily. The values of the cylinder pressure and engine performance parameters predicted by the presented model matched closely with the other theoretical models and experimental data the accuracy of a newly developed model, like the presented one, must be controlled comparing with the experimental and theoretical values given in the relevant literature. Numerical results obtained from the presented model were compared with the experimental results and with the theoretical models, the results of which were accepted to be at sufficient accuracy. These indicate that cylinder pressure values obtained from the presented model are lower than Bazari’s results. However, formation and vaporization of fuel droplets were modeled, and spray wall impingement was also taken into account in detail in Bazari’s model, and in the presented model and in Bazari’s models, Annand’s correlation has been used for the calculation of heat transfer. In future studies, it is planned to take into account a detailed wall impingement model and evaporation model. The effects of the residual gases in the cylinder could be used and a more detailed heat transfer model would also be included in the calculations. C.D. Rakopoulos and E.G. Giakoumis (2006). This paper surveys the publications available in the open literature concerning diesel engine simulations under transient operating conditions. Only those models that include both full engine thermodynamic calculations and dynamic power train modeling are taken into account, excluding those that focus on control design and optimization. Most of the attention is concentrated to the simulations that follow the filling and emptying modeling approach. One of the main purposes of this paper is to summarize basic equations and modeling aspects concerning in-cylinder calculations, friction, turbocharger, engine dynamics, governor, fuel pump operation, and exhaust emissions during transients. The various limitations of the models are discussed together with the main aspects of transient operation (e.g. turbocharger lag, combustion and friction deterioration), which diversify it from the steady-state. The stringent regulations concerning engine exhaust emissions dominate the automotive industry, forcing manufacturers to new developments. Sophisticated, high pressure common rail injection systems, exhaust gas recirculation and variable geometry turbochargers are applied for reduction of fuel consumption, pollutant emissions and noise. In this work the publications concerning transient diesel engine simulation will be surveyed, provided they include both engine thermodynamic and powertrain dynamic submodels. To maintain the paper size at an IJRISE| www.ijrise.org|editor@ijrise.org International Journal of Research In Science & Engineering Volume: 1 Issue: 1 e-ISSN: 2394-8299 p-ISSN: 2394-8280 acceptable level, it was decided that works which put emphasis on controllers design rather than thermodynamics, i.e. applying optimization algorithms, or Bode diagrams, will not be covered. Most of the attention will be paid to the simulations that follow the filling and emptying modeling technique. This, to the opinion of the authors, had proven so far to be the best approach to adequately shed light into the engine processes during transients. Moreover, taking into account its computational requirements, it was the most promising one for successful transient exhaust emissions predictions. The transient response of compression ignition engines forms a significant part of their operation and it was of critical importance, owing to the often non-optimum performance involved as regards turbocharged engines. Moreover, the launch of emission directives, in the form of Transient Cycles, have directed engine manufacturers to deal with overall (vehicles’) transient performance, since it was well established that the transient operation contributes much more to the total amount of emissions than the corresponding steady-state one. The majority of transient diesel engine simulations are based on the filling and emptying approach, which combines adequate insight into the relevant phenomena and requires limited computational time. Quasi-linear models are met often, owing to the low computational time required that makes them ideal for real time simulations. Reliable study of pollutants emissions during transient operation via the use of suitable models is the most important objective for the future. Its accomplishment is, for the moment, limited, due to the high computational time required for the analysis of hundreds of cycles. Fortunately, experimental investigations of transient operation and computational power of personal computers both flourish during the last years, forming a sound basis for an even more successful investigation of dynamic engine operation in the near future. Donepudi Jagadish, Ravi Kumar Puli and K. Madhu Murthy (2011): A zero dimensional model had been used to investigate the combustion performance of a single cylinder direct injection diesel engine fuelled by biofuels with options like supercharging and exhaust gas recirculation. The numerical simulation was performed at constant speed. The indicated pressure, temperature diagrams are plotted and compared for different fuels. The emissions of soot and nitrous oxide are computed with phenomenological models. Content was prediction of heat release and gas properties, Calculation of ignition delay, Nitric Oxide Formation, Frictional Power Calculations, Indicated Power and Brake Power calculations, Combustion duration, Prediction of soot formation, Frictional Power Calculations. The peak pressures was lowered with ethanol blending with diesel. And supercharging operation resulted in little lowering the maximum combustion pressure, temperatures in comparison to no supercharging case. The peak cylinder pressures are low with biodiesel blends in comparison to diesel since the heating value of biodiesel is lower than that of diesel resulting in lower heat release. Poor atomization and slow heat release rate also the reason for lower peak pressure for pure biodiesel. In future the experimental work is also carried out with biodiesel (palm stearin methyl ester) diesel blends, ethanol diesel blends P.A. Lakshminarayanan and Y.V. Aghav. The phenomenological combustion models are practical to describe diesel engine combustion and to carry out parametric studies. This is because the injection process, which can be relatively well predicted with the phenomenological approach, has the dominant effect on mixture formation and subsequent course of combustion. The need for improving these models was also established by incorporating developments happening in engine designs. A phenomenological model consisting of sub-models for combustion and emissions are proposed in detail in this chapter. With more and more “model based control programs” used in the ECU controlling the engines, phenomenological models are assuming importance now. The full CFD based models though give detailed insight into the combustion phenomena and guide the design engineer, they are too slow to be handled by the ECU’s or for laying out the engine design. Md. Moinul Islam, Mohammad Anisur Rahman, Mohammad Zoynal Abedin.. An experimental investigation had carried out for the first law analysis of a DI (direct-ignition) diesel engine running on straight soybean oil (SVO) preheated at 50, 75, 100oC with different loads at varying speeds of 1750, 2000, 2250 rpm. The results show that preheated straight soybean oil may be a practical replacement of the conventional diesel fuel with a small power and efficiency drop. The brake thermal efficiency of the engine apparently increases with increased preheats temperature of the soybean oil fuel and at 100oC it becomes very much comparable with the performance trends obtained using diesel fuel. IJRISE| www.ijrise.org|editor@ijrise.org International Journal of Research In Science & Engineering Volume: 1 Issue: 1 e-ISSN: 2394-8299 p-ISSN: 2394-8280 3. CONCLUSION A comprehensive survey on First Law of Thermodynamics using diesel and biodiesel fuels is presented in this literature. Extensive theory on the energy balance is given including the application of the first law of thermodynamics, variation in heat transfer correlation for wall heat loss evaluation, thermodynamic models etc Modelling and energy analysis, zero dimensional single zone combustion model simulation has been carried out to predict the single cylinder constant speed diesel engine performance. ο ο ο ο The single-zone thermodynamic models are comparatively easier to apply and exhibit reasonable accuracy but for better accuracy multi-zone models are preferable. The engine performance improved with low quantity blends of biodiesel to diesel, this indicated by the higher maximum combustion temperature and pressure. Biodiesels have lower thermal efficiency than diesel fuel .For same amount of output power, the BSFC of biodiesels is much higher than diesel fuel. The heat losses except the exhaust loss are higher while using biodiesels due to the presence of excessive oxygen molecules. Thermal insulation can be a good solution in this regard; mean while it will increase the exhaust heat loss. The brake power decreases with the increase of cetane number. The cooling water loss is comparatively higher than the exhaust heat loss for biodiesels. Modifying the equations if necessary so that it could be applied over a much wider range of speed and load. REFERENCES [1] John B. Heywood, “Internal Combustion Engine Fundamental” publication Tata McGraw Hill Education Private Limited, New delhi, Edition 2011. [2] Suneel Kumar,Manish Kumar Chauhan, Varun, “Numerical modeling of compression ignition engine, Renewable and Sustainable Energy Reviews 19 (2013) 517–530. [3]Kyung Tae Yun, Heejin Cho, Rogelio Luck, Pedro J. Mago, “Modeling of reciprocating internal combustion engines for power generation and heat recovery, Applied Energy 102 (2013) 327–335. [4]C.D. Rakopolus, E.G.Gakoms, “Second-law analyses applied to internal combustion engines operation”,science direct Progress in Energy and Combustion Science 32 (2006) 2–47. [5] Zehra S_ahin, Orhan Durgun,” Multi-zone combustion modeling for the prediction of diesel engine cycles and engine performance parameters, Applied Thermal Engineering 28 (2008) 2245–2256. [6] Donepudi Jagadish, Ravi Kumar Puli and K. Madhu Murthy, “Zero Dimensional Simulation of Combustion Process of a DI Diesel Engine Fuelled With Biofuels, World Academy of Science, Engineering and Technology 56 2011. [7] BORDET Nicolas, CAILLOL Christian, HIGELIN Pascal, “A Physical 0D Diesel Combustion Model Using Tabulated Chemistry with Presumed Probability Density Function Approach:For engine pre-Mapping, Institut PRISME - University of Orleans, France, FISITA2010-SC-O-26. [8] Md. Moinul Islam, Mohammad Anisur Rahman, Mohammad Zoynal Abedin, “First Law Analysis of a DI Diesel Engine Running on Straight Vegetable oil, nternational Journal of Mechanical & Mechatronics Engineering IJMME-IJENS Vol: 11 No: 03 [9] Vivek Kumar Gaba, Prerana Nashine and Shubhankar.Bhowmick,” Combustion Modeling of Diesel Engine Using Bio-Diesel as Secondary Fuel, International Conference on Mechanical and Robotics Engineering (ICMRE'2012) May 26-27, 2012 Phuket. [10] Fredrik Karlsson, “Modelling the Intake Manifold Dynamics in a Diesel Engine, LiTH-ISY EX-3084,April 2, 2001. [11] C. Borgnakke, P.Puzinauskas, Y. Xiao, “spark ignition engine simulation models, project no. 2000511,Feb 1986. [12] Geboren te Helmond, “ Development and validation of a phenomenological diesel engine combustion model, Paul Verspaget Grafische Vormgeving-Communicatie Printed by the Eindhoven University Press, 2009. [13] N. LAWRENCE, “Diesel Engine Cycle and Cooling System Simulation Program, Australian Maritime College, P.O. Box 986 Launceston, ‘Tasmania 7250, Australia, Mathematical and Computer ModeUing 33 (2001) 565-575. [14] Y. Gao, W.K. Chow, “A Brief Review on Combustion Modeling, International Journal on Architectural Science, Volume 6, Number 2, p.38-69, 2005. IJRISE| www.ijrise.org|editor@ijrise.org International Journal of Research In Science & Engineering Volume: 1 Issue: 1 e-ISSN: 2394-8299 p-ISSN: 2394-8280 [15] Tapan K. Gogoi, N.K Sarma, A Ahmed Choudhury and T. Talukdar, “First Law Analysis of Diesel Engine Performance Using Diesel and Bio-Diesel Fuel, International Journal of Emerging Technology and Advanced Engineering Volume 3, Special Issue 3: ICERTSD 2013, Feb 2013, pages 421-426. [16] Yunus A. Cengel, Michael A. Boles, “Thermodynamics An Engineering Approach,” Tata McGraw Hill Edition, 2006 IJRISE| www.ijrise.org|editor@ijrise.org