Benchmark Mid-Term Study Guide Chapter 1: Introduction to Chemistry A systematic approach that scientists use: • Scientific method 1. Observation 2. hypothesis 3. experiment 4. results/Data 5. Conclusions 6. theory 7. law Matching B 6. refers to physical characteristics such as color, odor, or shape ___ C 7. refers to mass, volume, and temperature measurements ___ D 8. a variable controlled by the experimenter ___ ___ A 9. the act of gathering information E 10. changes in value based on the value of the controlled variable ___ a. b. c. d. e. Observation Qualitative data Quantitative data Independent variable Dependent variable Multiple Choice 11. A constant is a factor that a. b. c. d. Changes during an experiment Changes from one lab group to another Is affected by the dependent variable Is not allowed to change during an experiment Matching 12. A control is a. Variable that changes during an experiment b. Standard for comparison c. Type of dependent variable d. Type of experiment Matching 13. A hypothesis is a(n) a. Educated Guess b. Explanation supported by many experiments c. Tentative explanation of observations d. Law describing a relationship in time Matching 14. A theory is a(n) a. Set of controlled observations b. Explanation supported by many experiments c. Tentative explanation of observations d. Law describing a relationship in time Matching 15. A law is a(n) a. Set of controlled observations b. Explanation supported by many experiments c. Tentative explanation of observations d. Law describing a relationship in time Matching 16. A model is a(n) A visual, verbal, or mathematical. GRAPH, Pie Chart Completion 17. What piece of lab equipment should be used to accurately measure volume? Graduated cylinder 18. What piece of lab equipment should be used to Balance accurately measure mass? 19. What is the proper technique for smelling a chemical in the laboratory? Wafting 20. What is the proper technique for holding a test tube Test tube holder while heating? Chapter 2: Data Analysis 1. Change the following data into scientific notation. a. 5,000,000 km 5 x 106 km -4 g 4.21 x 10 b. 0.000421 g -2 cm 3 x 10 c. 0.03 cm 2. Change the following data into ordinary notation. a. 5.3 x 1012 b. 4.0 x 105 c. 6.1 x 10-5 5,300,000,000,000 400,000 0.000061 3.Use the terms precise and accurate to describe the following figures. You may use both terms for some figures. If a term does not apply to a figure, leave the space blank. neither Precise but Not accurate Accurate & precise 4. Students were asked to find the density of an unknown white powder. Each student measured the volume and mass of three separate samples. They reported calculated densities for each trial and an average of the three calculations in the following data table. The power was sucrose, also called table sugar, which has a density of 1.59 g/cm3. a. Which student’s measurements were most accurate? A – because all of their values are close to the accepted value of sugar, 1.59% b. Which student’s measurement were most precise? C – because all of their values are close together but not close to the accepted value Density Data Collected by Three Different Students Student A Student B Student C Trial 1 1.54 g/cm3 1.40 g/cm3 1.70 g/cm3 Trial 2 1.60 g/cm3 1.68 g/cm3 1.69 g/cm3 Trial 3 1.57 g/cm3 1.51 g/cm3 1.71 g/cm3 Average 1.57 g/cm3 1.51 g/cm3 1.70 g/cm3 5. A sample of aluminum is placed in a 25 mL graduated cylinder containing 10.0 mL of water. The level of water rises to 18.0 mL. Aluminum has a density of 2.7 g/mL. Calculate the mass of the sample. (Use appropriate significant figures.) 18.0 mL - 10.0 mL 8.0 mL m = d(v) = 2.7 g/mL(8.0mL) = 21.6g = 22g 6. You have a 230g sample of ethanol with a density of 0.7893 g/mL. What volume of ethanol do you have? (use appropriate significant figures) v = m/d = 230g 0.7893g/mL = 291.4 = 290 mL 7. An object with a mass of 7.5g raises the level of water in a graduated cylinder from 25.1 mL to 30.1 mL. What is the density of the object? 30.1 mL -25.1 mL 5.0 mL d = m/v 7.5g 5.0mL = 1.5 g/mL 8. Determine the volume indicated in Figure 1. 64.0 mL 9. Determine the length indicated by Letter H in Figure 2. 12.94 cm 10. Determine the volume indicated in Figure 3. 34.7 °C Figure 3 Figure 1 Figure 2 Chapter 3 – Matter: Properties & Changes mass Matter is anything with (1) ____________________ and volume. A (2) substance ____________________ is a form of matter with a uniform and unchanging composition. Substances have specific, unchanging (3) properties ____________________ that can be observed. Substances have both physical physical and chemical properties. (4) ____________________ properties can be observed without changing a substance’s chemical density composition. Color, hardness, and (5) ____________________ are examples. Other properties cannot be observed without changing the chemical composition of a substance. These are called (6) __________________ properties. An example is the tendency of iron to form rust when exposed to air. chemical mass physical density properties substance • Label each property as either physical intensive, physical extensive, or chemical. Physicalintensive Chemical Physicalintensive Physicalextensive 7. Bitter taste Physicalextensive 8. length 9. Corrosion Physicalintensive 10. Malleability 11. Magnetic 12. Flammability 13. Volume 14. Reacts with an acid to form a gas Chemical Chemical Intensive – doesn’t matter how much you have Extensive – does matter how much you have _____ True 15. A solid has definite shape and volume. _____ False 16. A liquid has a definite shape and takes on the volume of its container. True 17. A gas has both the shape and the volume of its _____ container. False 18. The particles in a solid are spaced far apart. _____ gas 19. ____________ solid 20. ____________ liquid 21. ____________ 22.What are the four indicators that a chemical change has taken place? a. Temperature change b. Color change c. Gas (bubbles) produced d. Precipitate (solid) formed Identify the following as physical or chemical changes C 23. Log burning P 24. Making kool-aid 25. Iron rusts in air C 26. Fermentation of apple juice 27. Milk sours P 28. Slicing bread 29. Water boiling P 30. Dissolving NaCl into H2O C C P Solution Size of particles Too small to see Composition Tyndall effect Settle Out Clarity Colloid intermediate homogeneous Heterogeneous Suspension visible/large heterogeneous Negative positive negative No No Yes Clear Cloudy Cloudy Type of Matter 32. Water Substance compound heterogeneous 33. Soil homogeneous 34. Sugar water 35. Oxygen 36. Carbon dioxide 37. Rocky road ice cream Mixture element compound heterogeneous 38. List four techniques that can be used to separate a mixture. a. Filtration b. Distillation c. Chromatography d. crystallization Chapter 4 – The Structure of the Atom Subatomic particle Location Charge Relative Mass Proton Inside nucleus + 1 Electron Outside nucleus - 0 Neutron Inside nucleus 0 1 2. Most of an atom’s mass can be found in the nucleus ______________. 3. The number of protons in an atom is its atomic # ________________. 4. The number of protons + neutrons in an atom is its mass # ______________. protons always 5. In a neutral atom, the number of ______ electrons equals the number of __________. 6. Isotopes are atoms of an element with a different mass # ________. They have the same number of protons but a different number of ____________. neutrons ________ 7. Use a periodic table to identify the following elements. a. b. c. d. 47 protons Ag - silver 95 electrons Am - americium Atomic number = 28 Ni - nickel 6 protons and 8 neutrons Carbon – 14 or 14 6 C 16 7 Isotope Name Oxygen–16 Symbolic Notation 16 8 Nitrogen - 16 Bromine - 80 80 35 Number of Number of Number of Protons Electrons Neutrons O 8 N 7 Br 35 8 7 35 8 9 45 9. Three isotopes of argon occur in nature 36 – 18 Ar, 38 40 Ar, and Ar. Calculate the average atomic mass 18 18 of argon to two decimal places, given the following relative atomic masses and abundances of each of the isotopes: argon–36 (35.97 amu; 0.337%), argon–38 (37.96 amu; 0.063%), and argon–40 (39.96 amu; 99.600%). 35.97 (0.00337) = 37.96 (0.00063) = 39.96 (0.996) = 0.1212 0.0239 39.800 39.945 amu Chapter 25: Nuclear Chemistry Radioactivity Process where substances emit radiation Radioisotopes Unstable isotopes that are radioactive Half-life Time required for one-half of a radioisotope’s nuclei to decay into its products Nuclear fission Splitting of a heavy nucleus into two smaller nuclei (nuclear power plants) Nuclear fusion Combining two nuclei to form a heavier, more stable nucleus – occurs in the sun 2. Nuclear reactions involve changes in an atom’s nucleus, whereas chemical reactions do not. Type of radiation Alpha, α Symbol What is it? Can be stopped by α Particle Paper Beta, β β Particle Wood/ aluminum foil Gamma, γ Γ wave Lead/ concrete Penetrating Power 4 2 He 0 e -1 energy