A chemical reaction is a change in composition. • Is represented by a chemical equation which uses symbols and formulas. • Reactant(s)-the original substance(s) undergoing change • Product(s)- the new substance(s) produced A silver spoon tarnishes. The silver reacts with sulfur in the air to make silver sulfide, the black material we call tarnish. 2 Ag + S Ag2S Reactants Product 2 H2 (g) + O2 (g) --> 2 H2O (l) Symbols Meaning Reactants what is written on the left-hand-side of the arrow. ex. H2 and O2 Products what is written on the right-hand-side of the arrow. ex. H2O --> separates the reactants from the products (s),(l), (g) indicates the physical states of each species in the chemical reaction. For example, • (s) a solid substance , • (l) a liquid substance, • (g) a gaseous substance, • (aq) an aqueous solution (substance dissolved in water) Types of Reactions • • • • • Synthesis Decomposition Single Displacement Double Displacement Combustion SYNTHESIS REACTIONS A + B AB Two materials, elements or compounds, come together to make a single product. Some examples of synthesis reactions are: • Hydrogen gas and oxygen gas burn to produce water. 2 H 2 + O2 2 H 2 O • sulfur trioxide reacts with water to make sulfuric acid. H2O + SO3 H2SO4 DECOMPOSITION REACTIONS XZ X + Z One reactant only Some examples of decomposition reactions are: potassium chlorate when heated comes apart into oxygen gas and potassium chloride • 2 KClO3 2 KCl + 3 O2 and heating sodium bicarbonate releases water and carbon dioxide and sodium carbonate. • 6 NaHCO3 3 Na2CO3 + 3 H2O + 3 CO2 SINGLE REPLACEMENT REACTIONS ALSO CALLED SINGLE DISPLACEMENT • 2 KI + Cl2 2 KCl + I2 • Positive ions will replace positive ionsnegative ions will replace negative ions DOUBLE REPLACEMENT REACTIONS ALSO CALLED DOUBLE DISPLACEMENT • AgNO3 + KCl AgCl(s) + KNO3 • Positive and negative ions in an equation switch partners. • Remember…the positive ion is always written 1st Combustion Reactions • Occurs between a hydrocarbon and oxygen • Products are always carbon dioxide and water • CH4 +2 O2 CO2 + 2H2O Balancing Chemical Equations • An equation is balanced by adding whole number COEFFICIENTS in front of a compound’s formula or element’s symbol. Tips!!!! • Delay the balancing of hydrogen and oxygen • If a polyatomic appears on both sides of an equation, treat them as a single unit • Remember… balancing one element may unbalance another!!! Predicting Products of Reactions For many reactions, the products can be predicted by classifying the reaction and looking at the reactants. Double Replacement • Check solubility rules! • A basic knowledge of which compounds are soluble in aqueous solutions (dissolved in water) is essential for predicting whether a given reaction might involve formation of a precipitate (an insoluble solid that comes from a liquid solution). Single Replacement • Activity Series- the ability to react - a list of elements organized according to the ease with which they undergo single replacement reactions. • The most active elements are at the top-the least reactive at the bottom • Elements can replace those that are below them (i.e. those that are less reactive) but NOT those above them (i.e. those that are more reactive) • Elements can also do everything in it’s group and everything below it but NOT above. Diatomics F2 Cl2 Br2 H2 I2 N2 O2 Examples: • Al + ZnCl2 This reaction would go to completion because aluminum is above zinc in the series and can therefore replace it. • Co + NaCl NR Cobalt can not replace Na because Na is above it in the series and is therefore the more reactive element. More Examples: • NaCl + I2 NR Iodine is below Cl in the halogen activity series and therefore can’t replace it. • Pt + O2 NR Pt forms oxides only indirectly. More Examples: • Al + H2O (l) NR Al can only react with water that is steam (a.k.a. gas) • Li + HCl This reaction would go to completion because Li can react with acids (remember.. they can do anything in their group and the groups below them) Synthesis and Decomposition: • Use “cheat sheet” to know how the elements or compounds combine or decompose. • Use gas ion chart Combustion: • Products should always be CO2 and H2O