75 Points Chem I Name_________________________ Period_______ Stoichiometry Problem Set #1 PART A. Answer questions (1-3) given the following equation: Mg(s) + 2HCl (aq) → MgCl2(s) + H2(g) 1. How many grams of magnesium (Mg) is needed to produce 100. grams of hydrogen (H2)? 1.____________ 2. How many grams of hydrogen chloride (HCl) is needed to produce 200. g of hydrogen (H2)? 2.____________ 3. If 500. g of magnesium chloride (MgCl2) is produced in the above reaction, how many grams of hydrogen (H2) would be produced? 3.____________ PART B. Answer questions (4-5) given the following equation: P4(s) + 5O2 (g) → P4O10(g) 4. How many grams of tetraphosphorus decoxide (P4O10) is produced if you burn 50.0 grams of phosphorus with sufficient oxygen gas? 4.____________ 5. How many grams of oxygen would be needed in problem 4? 5.____________ 6. If 400. g of tetraphosphorus decoxide (P4O10) is needed for another experiment, how much phosphorus would have to be burned? 6.____________ 1 Chem I Stoichiometry Problem Set #2 Mass to Mass Relationships: Solve the following problems. If equations are provided, balance them first. If equation are not provided, write reactants in formula form, including reaction conditions, and balance the equation. PART A 7. If excess ammonium sulfate reacts with 20.0 grams of calcium hydroxide, how many grams of ammonia are produced? (NH4)2SO4(aq) + Ca(OH)2(cr) → CaSO4(cr) + NH3(g) + H2O(l) 8. How many grams of sodium hydroxide are needed to completely neutralize 25.0 grams of sulfuric acid? NaOH (aq) + H2SO4(aq) → Na2SO4(cr) + H2O(l) 9. If 20.0 grams of zinc react with excess hydrochloric acid to produce zinc chloride solution and hydrogen gas, how many grams of zinc chloride are produced? 1.____________ 2.____________ 3.____________ 10. How many grams of chlorine gas must be reacted with excess sodium iodide solution to produce 10.0 grams of sodium chloride and iodide gas? 4.____________ 11. Solid potassium chlorate decomposes to form potassium chlroide and oxygen gas. How many grams of oxygen are produced using 5.00 grams of solid potassium chlorate? 5.____________ 2 PART B 12. How many grams of copper are required to replace 4.00 grams of silver nitrate solution which forms silver metal and copper (II) nitrate solution? 13. If excess sulfuric acid reacts with 30.0 grams of sodium chloride solution to form sodium sulfate and hydrochloric acid, how many grams of hydrochloric acid are produced? 14. How much aqueous silver phosphate is produced if 10.0 grams of silver acetate solution is reacted with excess sodium phosphate solution to produce silver phosphate solid and sodium acetate solution? 15. How many grams of magnesium oxide can be produced when 50.0 grams of magnesium metal is combined with excess atmospheric oxygen in a synthesis reaction? 16. If propanol alcohol (C3H7OH) is combine with oxygen gas to form carbon dioxide gas and water, how many grams of propanol alcohol are needed to produce 750 grams of water? 3 6.____________ 7.____________ 8.____________ 9.____________ 10.___________ Chem I Stoichiometry Problem Set #3 Mass to Mass Relationships: Write formula equations with states of matter and rx condition, balance, and perform requested conversion. Answer should be express in correct sig figs and units. Write answer on line provided. Part A 17. How much (grams) hydrogen gas in a test tube would be combined with 44 grams of oxygen gas in the air to form water? 18. Solid lithium nitrate breaks down to form solid lithium nitrite and oxygen gas. How many grams of lithium nitrite are formed from 350 grams of lithium nitrate? 19. Aluminum chlorate reacts with sulfuric acid to form aluminum sulfate solution and chloric acid. How many grams of sulfuric acid are needed to form 100 grams of aluminum sulfate? 1.____________ 2.____________ 3.____________ 20. Chlorine gas and copper (I) iodide solution yield copper (I) chloride solution and iodine gas. If 350 grams of iodine gas are formed, how many grams of copper (I) chloride are also formed? 4.____________ 21. Solid tin (IV) hydroxide and hydrochloric acid react to produce water and tin (IV) chloride solution. If 450 grams of tin (IV) hydroxide are used, how many grams of water can be produced? 5.____________ 22. Ethanol alcohol (C2H5OH) in the presence of oxygen gas forms carbon dioxide gas and water. How many grams of carbon dioxide has can be produced from 4.50 grams of oxygen gas? 6.____________ 23. Aluminum metal and lead (II) acetate solution forms aluminum acetate solution and lead metal. Find the amount, in grams, of lead (II) acetate needed to form 125 grams of lead metal. 7.____________ 4 Part B 24. Copper metal and silver carbonate soltuion form copper (II) carbonate solution and silver metal. If you want to produce 400 grams of silver metal, how many grams of silver carbonate are required? 25. Solid strontium chlorate decomposes into solid strontium chloride and oxygen gas when heated. If you produce 210 grams of strontium chloride, how many grams of oxygen gas are also produced? 8.____________ 9.____________ 26. Methane gas (CH4) combines to produce water and carbon dioxide gas. If you have 110 grams of methane gas, how many grams of oxygen gas are needed to use up the methane? 10.___________ 27. Crystalline magnesium carbonate, when heated, produced magnesium oxide and carbon dioxide gas. If you produce 75.0 grams of magnesium oxide, how many grams of magnesium carbonate were used? 11.___________ 28. If 45.5 grams of sodium metal and exress chlorine gas combine to form crystalline sodium chloride, how many grams of sodium chloride are produced? 12.___________ 29. Solid diphosphorus pentoxide and solid barium oxide combine to form solid barium phosphate. How many grams of barium phosphate are produced if 10.0 grams of diphosphorus pentoxide are used? 13.___________ 30. 50.0 grams of solid cadmiun hydroxide breaks down when heated to form solid cadmium oxide and water. How many grams of cadmium oxide are formed? 14.___________ 31. If the temperature reaches 25°C, solid iron reacts with water to form iron (III) oxide and hydrogen gas. How much iron is needed to form 6.7 grams of hydrogen gas? 15.___________ 5 Chem I Stoichiometry Problem Set #4 Part A Limiting Reactants – If equations are provided, balance them and perform calculation. If there is not an equation, write reactants and products in formula form, balance equation, and perform calculation. Circle your answer! 32. For each of the following unbalanced equations, suppose 50.0 g of each reactant is taken. Show by calculation which reactant is the limiting reactant. a) MgCl2(aq) + O2(g) → b) Al(s) + Cl2(g) → Mg(ClO3)2(s) AlCl3(s) c) NaOH(s) + CO2(g) → Na2CO3(s) + H2O(l) 6 Part B 33. Suppose that you have exactly 50.0 g of each reactant taken. Determine which is the limiting and calculate what mass each product expected. a) NH3(g) + Na(s) → NaNH2(s) + b) SO2(g) + NaOH(s) → H2(g) Na2SO3(s) + 7 H2O(l) 34. For eachof the following unbalanced reactions, suppose exactly 150.00 g of each reactant is taken. Determine which reactant is limiting, and determine the mass of each product. a) NaCl(s) + H2SO4(aq) → HCl(aq) + Na2SO4(s) b) C3H8(g) + O2(g) → CO2(g) + H2O(l) 8 Part C 35. Lead (IV) chloride and sodium phosphate are mixed to form lead (IV) phosphate and sodium chloride. An experiment uses 125.0 grams of lead (IV) chloride mixed with 100.0 grams of sodium phosphate. Determine which reactant is limiting and calculate grams of each product produced. 36. Oxygen gas and zinc metal react to form zinc oxide ash. In an experiment, 75.0 grams of oxygen combines with 100.0 grams of zinc. Determine which reactant is limiting and calculate the grams of product produced. 9 Chem I Stoichiometry Problem Set #5 Excess Reactants – If equations are provided, balance them and perform calculation. If there is not an equation, write reactants and products in formula form, balance equation, and perform calculation. Circle your answer! Part A. Excess Reactants 1. For each of the following unbalanced equations, suppose 10.0 g of each reactant is taken. Show by calculation which reactant is the limiting reagent. Calculate the mass of excess reactant based on the limiting reactant. a. C2H6(g) + O2(g) CO2(g) + H2O(l) b. Ni(s) + Br2(g) NiBr3(s) c. KOH(s) + H2SO4(aq) K2SO4(aq) + H2O(l) 10 2. Suppose that you have exactly 50.0 g of ammonia gas (NH3) and 65.0 g of rubidium metal. Determine which is the limiting reactant and the mass of the reactant that will be in excess. a. NH3(g) + Rb(s) RbNH2(s) + H2(g) 3. You take 125 grams of each reactant. Determine which reactant is limiting, and also determine what mass of the two excess reactants will remain after the limiting reactant is consumed. Li2B4O7(s) + H2CO3(aq) + H2O(l) H3BO3(s) 11 + Li2CO3(aq) Part B 4. An experiment uses 25.0 grams of lead(II) nitrate mixed with 45 grams of potassium iodide to produce a yellow lead(II) iodide precipitate and clear potassium nitrate solution. Determine which reactant is limiting, calculate grams of each product produced, and determine the mass remaining of the excess reactant. 5. In an experiment 55.0 grams of oxygen gas combines with 45.0 grams of magnesium metal to form magnesium oxide ash. Determine which reactant is limiting, calculate grams of product produced, and determine the mass remaining of the excess reactant. 12 Chem I Stoichiometry Problem Set #6 Percent Yield– If equations are provided, balance them and perform calculation. If there is not an equation, write reactants and products in formula form, balance equation, and perform calculation. Circle your answer! Part A Percent Yield 1. Find the %yield of an experiment if a student obtained 38.6 grams of carbon monoxide after reacting 75.5 grams of solid iron(III) oxide with excess carbon in the following unbalanced reaction: Fe2O3(s) + C(s) Fe(s) + CO(g) 2. Find the %yield of an experiment if a student obtained 242 grams of aluminum oxide after reacting 135 grams of solid aluminum metal with excess sulfur monoxide gas in the following reaction: Al(s) + SO(g) Al2O3(s) + S(s) 13 3. Find the %yield of an experiment if a student obtained 231 grams of aspirin (C9H8O4) after reacting 200. grams of C7H6O3 with excess C7H6O3 in the following reaction: C7H6O3 + C4H6O3 C9H8O4 + C2H4O2 4. According to the following equation, calculate the percentage yield if 550.g of toluene is added to an excess of nitric acid and provides 305 g of the p-nitrotoluene product. C7H8 + HNO3 C7H7NO2 + H2O Part B 5. Quicklime, CaO, can be prepared by roasting limestone, CaCO3, according to the chemical equation below. When 200.g of CaCO3 are heated, the actual yield of CaO is 150.g. What is the percentage yield? CaCO3 CaO + CO2 14 6. Consider the following reaction unbalanced reaction: CaCO3 + FePO4 Ca3(PO4)2 + Fe2(CO3)3 Assuming we start with 100. grams of calcium carbonate and 45.0 grams of iron (III) phosphate, calculate the percent yield of calcium phosphate if 40.0 grams were collected in lab. Step 1: Find the Limiting Reactant Step 2: Calculate the Percent Yield 15