1 Spill Prevention, Control, and Countermeasures: Hazardous Liquids Center for Toxicology and Environmental Health, LLC Environmental Perspective 2 Presentation Agenda Reactive Measures BTEX – Full Shift Proactive Measures Reactive Measures BTEX – Short Term Exposure & Real-time Monitoring Two basic approaches used to deal with incidents involving the transportation of hazardous Other chemicals of interest… liquids: proactive and reactive measures. This presentation discusses each. Center for Toxicology and Environmental Health, LLC 3 Presentation Goal – Provide 40,000 ft overview This… Center for Toxicology and Environmental Health, LLC Not This. 4 Definition Proactive Measures “Creating or controlling a situation by causing something to happen rather than responding to it after it has happened.” The steps you undertake before an incident occurs which allows you to better mitigate its effects. Center for Toxicology and Environmental Health, LLC 5 Proactive Measures = Spill Prevention and Control Center for Toxicology and Environmental Health, LLC 6 Spill Prevention and Control Center for Toxicology and Environmental Health, LLC 7 Spill Prevention and Control 49 CFR 195 – Transportation of Hazardous Liquids by Pipeline Testing Maintenance Procedures Other Training Maps Monitoring & Inspections Center for Toxicology and Environmental Health, LLC 8 Pro-Active Measures Testing Pressure Testing (or Risk-based alternative) of pipeline and all components -4 continuous hrs at 125% of max. operating pressure plus: -Visual inspection for leak or additional 4 hrs continuous testing at 110% of max operating pressure -Using H2O or inert gas (low stress pipe) Cathodic Protection & External Corrosion Control -Must be tested just prior to lowering the pipe into the ditch or submerging the pipe Non-destructive Weld Tests Recordkeeping -Test records must be maintained the entire time that the tested facility is in use Center for Toxicology and Environmental Health, LLC 9 Pro-Active Measures Standard Operating Procedures Operations, Maintenance, and Emergencies Manual of Written Procedures -Normal Operations -Abnormal Operations -Emergencies Reviewed once per calendar year and at least every 15 months Abnormal Operations -Responding to, investigating, and correcting the cause of: -Unintended closure of valves or shutdown -Increase or decrease in pressure or flow -Loss of communication -Operation of any safety device Emergencies -Discovery, Notifications, Lists of Response Resources, Control/Minimize Hazards Center for Toxicology and Environmental Health, LLC 10 Pro-Active Measures Training Establish and Conduct Continuous Training Program -Understand roles & responsibilities -Know characteristics & hazards of commodities transported -Recognize conditions likely to cause emergencies/predict consequences and take appropriate actions -Steps to minimize potential fire, explosion, toxicity or environmental damages -Know characteristics and causes of fires and appropriate use of extinguishers *Once per calendar year and at least every15 months ** Additional training required for “Qualified Personnel” Center for Toxicology and Environmental Health, LLC 11 Pro-Active Measures Maps Maps of Pipeline Systems -Breakout tanks -Scrapers and spheres -Valves -ROWs -Safety devices -Crossings (roads, railroads, rivers, pipelines, and utilities) -Pressures -Diameters, grade, type, and wall thickness Center for Toxicology and Environmental Health, LLC 12 Pro-Active Measures Monitoring & Inspections Right-of-Ways (ROWs) -26 times/calendar year at interval not exceeding 3 weeks -Surface conditions on and adjacent to ROWs (typically walking, driving, or flying) Crossings under Navigable Waters -Every 5 years for each crossing under navigable waterways Gulf of Mexico - If pipeline is >4 ½ inches (14mm) in diameter and located in water < 15 feet deep, must rebury line to a depth of at least 3 feet below grade surface Center for Toxicology and Environmental Health, LLC 13 Pro-Active Measures Other Pro-Active Measures • • • • • • • • Maintenance Communication System Line Markers Signs Security Written Damage Prevention Program Public Awareness Leak Detection Center for Toxicology and Environmental Health, LLC 14 Pro-Active Measures Special Considerations High Consequence Areas -Commercially navigable waterways -Concentrated populations centers (>50,000 people as of last U.S. Census) and has a population density of at least 1,000 people/mi2 -“Other” populated area, which means a place, as defined and delineated by the Census Bureau, that contains a concentrated population, such as an incorporated or unincorporated city, town, village, or other designated residential or commercial area -“Unusually sensitive” areas (drinking water or ecological resource area that is unusually sensitive to environmental damage from a hazardous liquid pipeline release) -Drinking water intake; -Source Water Protection Area (SWPA); -Location containing imperiled, T&E, or depleted marine mammal species, or an imperiled ecological community where the species or community is aquatic, aquatic dependent, or terrestrial with a limited range Center for Toxicology and Environmental Health, LLC 15 Special Considerations High Consequence Areas (HCA) Requires Pipeline Integrity Management Program - Elements of written program include: - A process for identifying which pipeline segments could affect a HCA; - A baseline assessment plan; - An analysis that integrates all available information about the integrity of the entire pipeline and the consequences of a failure; - Criteria for remedial actions to address integrity issues raised by assessment & analysis; - A continual process of assessment and evaluation to maintain a pipeline's integrity - Identification of preventive and mitigative measures to protect the HCA - Methods to measure the program's effectiveness - A process for review of integrity assessment results and information analysis by a person qualified to evaluate the results and information Center for Toxicology and Environmental Health, LLC 16 Pro-Active Measures 40 CFR 112 – Oil Pollution Prevention Differs from requirements found in 49 CFR 195 in that 40 CFR 112 deals with bulk storage and internal handling of oil (i.e., facilities) not oil in transportation (e.g., railcars, trucks, and pipelines). Require facilities to prepare and implement site-specific plans* to address three areas: • Secondary containment and other engineered and procedural control measures • Operating procedures, inspections and other administrative measures • Countermeasures and clean up measures *Type and complexity of plans determined by overall storage capacity of the facility (e.g., Spill Prevention Control and Countermeasures Plan versus Facility Response Plan) Center for Toxicology and Environmental Health, LLC 17 Pro-Active Measures 40 CFR 112 – Oil Pollution Prevention Highlights of SPCC Rule: Facilities must utilize secondary containment or environmental equivalent” for all bulk oil storage containers which are defined as > to 55 gallons and must account for containment of 100% of single largest container in dike plus “adequate freeboard for precipitation”. Security at facility must be sufficient to deter vandalism and acts of terrorism (e.g., fences, lights, cameras, locks, 24-hour staffing, etc) Inspections must be conducted routinely (typically monthly) and include all tanks and appurtenances including , supports, pipes, dikes, handling areas, etc. Center for Toxicology and Environmental Health, LLC 18 Pro-Active Measures 40 CFR 112 – Oil Pollution Prevention Highlights of SPCC Rule Cont’d: Training must be given annually to all “oil handling personnel”. If facility oil storage capacity exceeds 1,000,000 gallons than Facility Response Plan (FRP) must additionally be prepared which incorporates all SPCC rules plus requires hazard analysis of worst case discharge and triannual drills and exercises to demonstrate efficacy of the plan. Center for Toxicology and Environmental Health, LLC 19 Reactive Measures When bad things happen despite pro-active measures Center for Toxicology and Environmental Health, LLC 20 Definition Reactive Measures “Actions done in response to a problem or situation. Reacting to problems when they occur instead of doing something to prevent them.” The steps taken after a release has occurred to minimize environmental exposure and liabilities. Center for Toxicology and Environmental Health, LLC 21 Reactive Measures Responding to An Incident Work the Plan - You’ve spent time, money and resources engaging in pro-active measures. You’ve previously planned the work, now work the plan. - Internal notifications - External agency notifications - Corrective measures and stopping the source of the release - Mobilization of contractors and resources - Deployment of control and recovery assets - Organization, structure, and location of incident command - Coordination of response activities - System restoration/business continuity Center for Toxicology and Environmental Health, LLC 22 Reactive Measures Responding to An Incident Response Priorities: P-E-A-R People Environment Assets Reputation Center for Toxicology and Environmental Health, LLC 23 Response Priorities People Responsibility for Community st 1 Responders, Employees & Contractors, and - Constituent-specific OSHA established “Permissible Exposure Limit” (PEL) Time Weighted Average (TWA) which is the permissible concentration in air of a substance that shall not be exceeded in an 8-hour work shift or a 40-hour work week - Constituent-specific ACGIH derived “Threshold Limit Values” (TLV) TWA which is the concentration for a normal 8-hour workday and a 40-hour workweek, to which nearly all workers may be repeatedly exposed, day after day, without adverse effect. - Typically the primary concern when dealing with people is the route of exposure through inhalation. Exacerbated by fires, blow-outs and activities like vacuum truck recovery, transferring, lightering, etc which aerosolize particulates into the air. - Other routes of exposure include: ingestion (drinking water, fish consumption) and contact dermatitis (exposure to surface water, sediment, and/or soils). Center for Toxicology and Environmental Health, LLC 24 Response Priorities People – Air Monitoring Strategy - Incident details – Location (i.e. urban versus remote), type and amount of product released and/or on fire, SDSs, description of the environmental impacts (i.e. soil, water), site air monitoring results. - Receptors – Location in relation to unplanned release and/or fire (i.e. distance, downwind/stream, up wind/stream), type of receptors (i.e. intermediate, commercial, industrial, farmland, residential, schools, daycares, hospitals, immune compromised individuals). - Location Details – Urban versus remote, accessibility, weather conditions, flooding, run-off, inversions, exclusion zone boundary, private versus public land, aerial maps. - Sample Methodologies – Equipment/Sample Media capability (i.e. range, resolution, specificity), availability, chemical interferences, previous results, data extrapolation, laboratory capabilities. Center for Toxicology and Environmental Health, LLC 25 Response Priorities People – Air Monitoring Sampling & Monitoring - Real-time instrumentation vs. analytical - Rapidity vs. quality - If not done and documented properly can yield results quickly but not provide you with the level of detail needed to support subsequent litigation. Public Health Unit - Review data: issue advisories for beach closures, fish consumption, evacuations, etc. Typically work with Federal, State, County Health Departments. - Not stood up in every incident; depends on UC/IC whether it is warranted. Center for Toxicology and Environmental Health, LLC 26 Response Priorities Environment Monitoring & Sampling Shoreline Assessment Resources At Risk (RAR) Wildlife Natural Resource Damage Assessment Waste Coordination Center for Toxicology and Environmental Health, LLC 27 Environment Monitoring & Sampling Purpose is to produce rapid, reproducible, actionable, and defensible data. Examples include: - Work Zone Exposure Monitoring Community Exposure Monitoring Drinking Water Intake Sampling Source Oil Sampling for Comparative Fingerprinting Background Sampling of River, Material and Waste Staging Areas Ephemeral Environmental Sampling (surface water, water column, sediment, soil, biota) Center for Toxicology and Environmental Health, LLC 28 Environment Shoreline Assessment Shoreline Cleanup Assessment Technique (SCAT) - Evaluates oiling conditions; Factors in shoreline types ; Identifies sensitive resources; Determines need for cleanup; Recommends cleanup methods and endpoints; and, Places constraints on cleanup if necessary, due to ecological, economic, or cultural concerns Rapid Assessment Technique (RAT) - Rapidly documents gross delineation of shoreline impacts and documents unimpacted shorelines Center for Toxicology and Environmental Health, LLC 29 Environment Resources At Risk (RAR) Evaluate impacts to threatened & endangered plants and animals; culturally sensitive areas such Native-American artifacts, shipwrecks, etc); and/or, historically sensitive areas such as parks, monuments, and cemeteries. Center for Toxicology and Environmental Health, LLC 30 Response Priorities Wildlife Hotline Number Set-up - Report & Documentation of sightings - Advise Operations Section Establish Animal Recovery and Rehabilitation Center(s) - Requires permits - Knowledge of Proper Chain of Custody Records Center for Toxicology and Environmental Health, LLC 31 Response Priorities Natural Resource Damage Assessment Separate Activity from “Response” Purpose is to compensate the public for injured natural resources Natural Resources Have Value The Government Holds Natural Resources in Trust for the Public- Trustees Focus is on restoration of natural resources Not punitive Center for Toxicology and Environmental Health, LLC 32 Response Priorities Waste Coordination Properly manage waste generation, handling, transportation, final disposition (e.g., recycling, disposal, beneficial re-use, etc) Provide necessary documentation for “mass-balance” accounting - Penalties and fines are determined in part by the amount of material released into the environment. Accounting for the amount of material recovered as part of the waste stream can potentially save you millions in fines. Center for Toxicology and Environmental Health, LLC 33 Response Priorities Asset System Restoration and Business Continuity; resumption of “normal” operations - Typically slowed by causation and/or criminal investigations (e.g., CSB, PHMSA, FRA) - Know your rotation schedule and personnel. If you are working on the response, who is running the business and doing your “day job”? Center for Toxicology and Environmental Health, LLC 34 Response Priorities Reputation How credible is your response to the incident? How effectively are you communicating? Did you take responsibility for the incident or pass blame onto others? What do your public statements say about your organization? Increased Regulatory Oversight DECREASED PUBLIC TRUST Increased negative media coverage Decreased Stock Price Center for Toxicology and Environmental Health, LLC 35 The The “True” “True” Cost Cost of of aa Response Response… Center for Toxicology and Environmental Health, LLC 36 Center for Toxicology and Environmental Health, LLC 37 Now what? The Emergency Is Over….. Did you do enough to address potential lingering issues? • • • • • • • • • Health Effects of Chemicals Safety of Food Indoor Air Quality Water/soil Quality Medical Surveillance Water wells, supply Property Claims Litigation Center for Toxicology and Environmental Health, LLC Is this chemical toxic? Is my water safe to drink? Is my home safe to reoccupy? Are my pets safe? 38 Wrap Up Conclusions Proactive measures are generally better than reactive measures –demonstrates to regulators, employees, and shareholders: we are ahead of this, our approach is solid, and we know how to move forward. Reactive measures involve protecting people, the environment, and assets, but also protecting your liabilities! Center for Toxicology and Environmental Health, LLC 39 Questions? April Steger, B.S. CTEH, L.L.C. Manager, Gulf Coast Operations asteger@cteh.com 501-960-5723 Center for Toxicology and Environmental Health, LLC