Chapter 5 Igneous Rocks Section 5.1 What are Igneous Rocks? • Objectives: – Summarize igneous rock formation – Describe the composition of magma – Identify the factors that affect how rocks melt and crystallize – Define: • • • • • • Silicate Lava Igneous rock Partial melting Bowen’s reaction series Fractional crystallization I. Igneous Rock Formation • Magma – molten rock below Earth’s surface • Lava – magma that flows out onto Earth’s surface • Igneous rocks – form when magma cools and minerals crystallize • Rocks must be heated to temperatures of 800oC – 1200oC before they melt • Temperatures are present in nature in upper mantle and lower crust • Theory – heat came from remaining energy from Earth’s molten formation and head generated from the decay of radioactive elements A. Composition of Magma • Type of igneous rock that forms depends on the composition of the magma • Magma – often slushy mix of molten rock, dissolved gases, mineral crystals • Common elements present in magma are same major elements that are in Earth’s crust: • Oxygen, Silicon, Aluminum, Iron, Magnesium, Calcium, Potassium, Sodium • Silica is most abundant • Silica has greatest effect on magma characteristics • Magma classification: based on amount of silica it contains – Basaltic – – Andesitic – – Rhyolitic - • Silica content affects melting temperature and impacts how quickly magma flows • Once magma is free of overlying pressure of rock layers around it dissolved gases are able to escape into atmosphere – Chemical composition of lava is slightly different from chemical composition of magma from which it develops Mt. Etna, Sicily, Italy B. Magma Formation • Magma can be formed by melting Earth’s crust or by melting within the mantle • 4 main factors involved in formation of magma: temperature, pressure, water content, mineral content 1. Temperature – generally increases with depth (geothermal gradient) 2. Pressure – increases with depth • Result of weight of overlying rock • As pressure increases melting point increases 3. Water Content – changes melting point • As water content increases melting point decreases C. Mineral Content • Different minerals have different melting points – Basalt (olivine + calcium feldspar + pyroxene) melts at higher temperatures than granite (quartz + potassium feldspar) – Granite has lower melting point than basalt because granite contains more water and minerals that melt at lower temperatures • In general, rocks that are rich in iron and magnesium melt at higher temperatures than rocks that contain higher levels of silicon D. Partial Melting • Not all parts of a rock melt at the same temperature because they contain different minerals • This explains why magma is often a slushy mix of crystals and molten rock • Partial melting – process whereby some minerals melt at relatively low temperatures while other minerals remain solid – as each group of minerals melts, different elements are added to the magma mixture changing magma composition – If temperatures are not high enough to melt the entire rock the resulting magma will have a different composition than that of the original rock • This is one way different igneous rocks form II. Bowen’s Reaction Series • Bowen’s Reaction Serious – process that demonstrate as magma cools and crystallizes minerals form in predictable patterns • 2 main patterns / branches of crystallization: – Right – continuous, gradual change of mineral compositions in feldspar group – Left – abrupt change of mineral type in ironmagnesium groups A. Iron-Rich Minerals • Left branch • Undergo abrupt changes as magma cools and crystallizes – Olivine = 1st mineral to crystallize when magma that is rich in iron and magnesium begins to cool – When temp decreases enough for completely new mineral (pyroxene) to form olivine that previously formed reacts with magma and is converted to pyroxene – As temp decreases further similar reactions produce minerals amphibole and biotite mica B. Felspars • Right branch • Plagioclase feldspars – undergo continuous change of composition • As magma cools – 1st feldspars to form are calcium-rich • As cooling continues, feldspars react with magma, and their calcium-rich compositions change to sodium-rich compositions • In some cases, such as when magma cools rapidly, the calcium-rich cores are unable to react completely with magma – result in zoned crystal III. Fractional Crystallization • When magma cools it crystallizes in reverse order of partial melting • 1st minerals that crystallize from magma are last minerals that melted during partial melting • Fractional crystallization – similar to partial melting in that the composition of magma can change • Early formed crystals are removed from the magma and cannot react with it • As minerals form and their elements are removed from the remaining magma it becomes concentrated silica • Questions arose from discovery of Bowen’s reaction series: – If olivine converts to pyroxene during cooling, why is olivine found in rock? • Hypothesis: under certain conditions, newly formed crystals are separated from magma, and chemical reactions b/w magma and minerals stop. Can occur when crystals settle at bottom of magma body and when liquid magma is squeezed from crystal mush to form 2 distinct igneous bodies with different compositions. Olivine Peridotite = olivine + pyroxene • As fractional crystallization continues and more magma is separated from crystals, the magma becomes more concentrated in silica, aluminum, and potassium • Last 2 minerals to form are potassium feldspar and quartz – Potassium feldspar – one of most common feldspars in Earth’s crust – Quartz – often occurs in veins because it crystallizes while the last liquid portion of magma is squeezed into rock fractures Section 5.2 Classification of Igneous Rocks • Objectives: – Classify different types and textures of igneous rocks. – Recognize the effects of cooling rates on the grain sizes in igneous rocks. – Describe some uses of igneous rocks. – Define: • • • • • • • • • Intrusive rock Extrusive rock Basaltic rock Granitic rock Texture Porphyritic texture Vesicular texture Pegmatite kimberlite I. Mineral Composition of Igneous Rocks • Broad classification: intrusive or extrusive • Intrusive – when magma cools and crystallizes below Earth’s surface – If magma is injected into surrounding rock = igneous intrusion – Crystals = generally large enough to see without magnification • Extrusive – when magma cools and crystallizes on Earth’s surface – A.K.A. – lava flows or flood basalts – Crystals = small and difficult to see without magnification • Classified by mineral compositions, physical properties (grain size, texture) A. Classification of Igneous Rocks • According to mineral composition 1. Basaltic Rocks – dark-colored, lower silica content, contain mostly plagioclase and pyroxene (gabbro) 2. Granitic Rocks – light-colored, high silica contents, contain mostly quartz, potassium feldspar, plagioclase feldspar (granite) 3. Intermediate Rocks – mineral composition somewhere in between basaltic and granitic, consist mostly of plagioclase feldspar and hornblende (diorite) 4. Ultrabasic – only iron-rich minerals, such as olivine and pyroxene – always dark (peridotite) II. Texture • Rocks differ in sizes of grains or crystals • Texture – refers to size, shape, and distribution of crystals or grains that make up a rock – Rhyolite = fine-grained – Granite = coarse-grained • Difference in crystal size explained by fact that one rock is extrusive and other is intrusive A. Crystal Size and Cooling Rates • Lava flows on Earth’s surface – cools quickly and not enough time for large crystals to form = extrusive igneous rocks (rhyolite) – Sometimes cooling occurs so quickly that crystals do not form at all = volcanic glass (obsidian) • Magma cools slowly beneath Earth’s surface = sufficient time for large crystals to form • Intrusive igneous rocks can have crystals larger than 1 cm (granite, diorite, gabbro) B. Porphyritic Rocks • Porphyritic texture – characterized by large, wellformed crystals surrounded by finer-grained crystals of same mineral or different minerals • Indicate complex cooling history during which a slowly cooling magma (forming large crystals) suddenly began cooling rapidly (remaining magma forms small crystals) Rhyolite w/ white feldspar & dark gray quartz Basalt w/ olivine Andesite w/ amphibole (horneblend) C. Vesicular Rocks • Magma contains dissolved gases that escape when the pressure on magma lessens • If lava is thick enough to prevent gases bubbles from escaping holes (vesicles) are left behind – Rock that forms looks spongy – Vesicular texture – spongy appearance • Examples: pumice, vasicular basalt III. Thin Sections • Usually easier to observe sizes of mineral grains than it is to identify the mineral – to identify minerals geologists examine samples called thin sections – Thin section – slice of rock (2cm x 4cm x .033mm thick) • So thin light can pass through it • Petrographic microscope – observe mineral grains b/c they exhibit distinct properties – Properties allow geologists to identify minerals present in rock • Example: feldspar grains – show a distinct banding called twinning • Example: quartz grains – appear wavy as the microscope stage is rotated • Example: calcite crystals – become dark (extinguish) as stage is rotated IV. Igneous Rocks as Resources • Cooling and crystallization history of igneous rocks sometimes results in unusual but useful minerals • Can be used in many fields: construction, energy production, jewelry making A. Veins • Ores – minerals that contain useful mineral that can be mined for a profit • Often occur w/in igneous intrusions – Sometimes occur as veins – Fluid left during magma crystallization contains high levels of silica and water and any leftover elements that were not incorporated into the common igneous minerals • Some important metallic elements not included in common minerals = gold, silver, lead, copper • These + dissolved silica = released at end of magma crystallization in hot, mineral-rich fluid that fills cracks and voids in surrounding rock • Fluid solidifies to form metal-rich quartz veins B. Pegmatites • Pegmatites – veins of extremely large-grained minerals • Ores of rare elements (lithium) (beryllium) form in pegmatites • Can produce beautiful crystals – Minerals grow to voids and retain their shapes because these veins fill cavities and fractures in rock • Mount Rushmore C. Kimberlites • Variety of peridotite • Most likely form deep in crust or in mantle at depths of 150 – 300km – Because diamond and other minerals present in kimberlites can form only under very high pressure • Hypothesis: magma is intruded rapidly upward toward surface forms long, narrow, pipe-like structures – Extend many km into crust & only 100 – 300m diameter D. Igneous Rocks in Construction • Especially useful as building materials – Interlocking grain texture = strong – Many minerals resistant to weathering (granite)