Should we control a chemical that: Causes excessive sweating and vomiting. Is a major component in acid rain. Can cause severe burns in its gaseous state. Accidental inhalation can kill you. Contributes to erosion. Decreases the effectiveness of car brakes. Has been found in tumors of terminal cancer patients. What is the chemical? Dihydrogen Otherwise monoxide known as H2O Chapter 3 Water and the Fitness of the Environment Question? What molecule Is the most common In living Cells? Water - most cells are 70 - 95% water. The Water Planet Properties Of Water Be ready and able to discuss several of the following properties. Focus on definitions and examples. Review water structure and H-bonds from Chapter 2. Liquid Water Is Cohesive Water sticks to water. Why? Because the polarity of water results in hydrogen bonding. Liquid Water is Adhesive Water sticks to other molecules. Why? Hydrogen bonding. Water transport in trees uses Cohesion and Adhesion Water Has A High Surface Tension The surface of water is difficult to stretch or break. Why? Hydrogen bonding. Water Has A High Specific Heat Specific Heat - the amount of heat needed to raise 1 g of the substance 1 degree C. Why? Hydrogen bonding. Heat Total quantity of kinetic energy due to molecular motion. Temperature Measures the average speed of the molecules. Celsius Scale Will be used for most of our temperature measurements. O oC - water freezes 100 oC - water boils 37 oC - human body Water Stabilizes Temperature Water can absorb and store a huge amount of heat from the sun. Result - climate moderation Result - organisms are able to survive temperature changes. Fig. 3-5 Los Angeles (Airport) 75° 70s (°F) 80s San Bernardino 100° Riverside 96° Santa Ana Palm Springs 84° 106° Burbank 90° Santa Barbara 73° Pacific Ocean 90s 100s San Diego 72° 40 miles Water Has A High Heat Of Vaporization Heat of Vaporization: the quantity of heat a liquid must absorb for 1g of it to convert to a gaseous state. Evaporative Cooling Result: Water cools organisms from excessive heat buildup. Why? Hydrogen bonding Water Expands When It Freezes The distance between water molecules INCREASES from the liquid to the solid form. Why? Hydrogen bonding Solids and Liquids Water Benzene Floats Sinks States of Matter Solid Liquid Gas Result Aquatic life can live under ice. Water Is A Versatile Solvent Water will form a solution with many materials. Why? Hydrogen bonding Solution Homogeneous mixture of two or more substances. Solvent The dissolving agent. The material in the greater quantity. Solute The substance that is dissolved. The material in the lesser quantity. Hydrophilic Materials Materials that dissolve in water. Hydro - water philic - to like or love Have ionic or polar regions (polar covalent bonds) on their molecules for H+ bonds. Hydrophobic Materials that repel water. Hydro - water phobic - to fear Have non-polar covalent bonds. Ex - lipids. Solution Concentration Usually based on Molarity. Molarity - the number of moles of solute per liter of solution. Moles The molecular weight of a substance in grams. One Avogadro’s number of molecules. 6.02 X 1023 One Mole of each Sugar Copper Sulfate Sulfur Mercury Oxide Sodium Chloride Copper Comment AP Biology students should be able to calculate solutions in Molarity. Dissociation of Water Water can sometimes split into two ions. In pure water the concentration of each ion is 10-7 M Adding certain solutes disrupts the balance between the two ions. The two ions are very reactive and can drastically affect a cell. Acids that can release H+ Example: HCl HCl H+ + ClMaterials Acid Rain Acid Rain Bases that can absorb H+ Often reduce H+ by producing OHExample: NaOH NaOH Na+ + OHMaterials Neutrals Materials that are neither acids nor bases. Candice - IA Homework Read chapter 3, 4 Lab - Macromolecules Chapter 3 – Wed. 8/27 Chapter 4 – Fri. 8/29 pH Scale A logarithmic scale for showing H+ concentration pH = - log [H+] pH Scale Example: For a neutral solution: [H+] is 10-7 or - log 10-7 or - (-7) or 7 Acids: pH <7 etc. Bases: pH >7 etc. Each in H+ pH unit is a 10x change Comment [H+] + [OH-] = 14 Therefore, if you know the concentration of one ion, you can easily calculate the other. Fig. 3-9 pH Scale 0 1 Gastric juice, 2 lemon juice H+ H+ Battery acid + – H H+ OH + OH– H H+ H+ H+ 3 Vinegar, beer, wine, cola 4 Tomato juice Acidic solution 5 Black coffee Rainwater 6 Urine OH– H+ OH– H+ OH– OH– OH– + H+ H+ H Neutral solution Neutral [H+] = [OH–] Saliva 7 Pure water Human blood, tears 8 Seawater 9 10 OH– Milk of magnesia OH– OH– H+ OH– – OH– OH OH– + H Basic solution 11 Household ammonia 12 Household 13 bleach Oven cleaner 14 Buffers Materials that have both acid and base properties. Resist pH shifts. Cells and other biological solutions often contain buffers to prevent damage. Summary Be able to discuss the properties of water. Be able to measure solution concentrations in Molarity. Be able to work pH scale questions.