Science 10 Chemistry Unit- Chapter 4, Lesson 1 Atomic Theory John Dalton (1766-1844) hypothesized that all mater could be broken up into smaller pieces and that the smallest possible piece was the atom. He was right, all matter can be broken down into smaller pieces and one of those is the atom, but atoms can also be broken down into smaller pieces. These smaller pieces are called subatomic particles. Subatomic particles are the particles that make up an atom. A subatomic particle is a part of an atom much the same as a wheel is part of a car. The three main subatomic particles are protons, neutrons, and electrons. Today, scientists know subatomic particles in turn can be broken down into still smaller particles. The modern atomic theory states that an atom consists of: Protons are subatomic particles that have an electrical charge of 1+ (positive) and a mass of 1u (atomic mass unit). They are at the center of an atom. Neutrons are subatomic particles that have no electrical charge. They are neutral, and have a mass of 1u (atomic mass unit). They are also at the center of an atom. Electrons are subatomic particles that have an electrical charge of 1(negative) and effective mass of 0u (atomic mass unit). They are outside the center of the atom. An atom consists of a dense nucleus, made up of protons and neutrons, surrounded by electrons moving in space. Neils Bohr was a scientist who suggested that electrons travel in a circular orbit or energy level in well-defined path around the center of an atom. Nucleus At the center of an atom is a nucleus. The nucleus is tiny in comparison to the whole atom. A nucleus is made of protons and neutrons. Protons and neutrons both have a mass of 1u. If an atom were the size of a football stadium, the nucleus would be the size of a football. Different elements are made up of different atoms. Each atom is made of the same three subatomic particles, but different because of the number of each particle present. The simplest nucleus is just one proton. This is in the atom Hydrogen. Hydrogen can also have neutrons present in the nucleus but it is possible for it to have just one proton. Atoms with nuclei that have less than 30 protons usually have the same number of protons and neutrons. As the protons in the nucleus increase you need extra neutrons to help make it stable. The nucleus always has a positive charge because it contains positively charged protons and neutral neutrons. Electrons Electrons are so light they are considered to have zero mass and they have a negative electric charge (-1). Electrons move around the nucleus in specific paths called energy levels. Energy levels exist whether there is an electron in them or not. Electrons occupy certain energy levels depending on the atom. For example, hydrogen has a single electron in the first energy level. Sodium has two electrons in the first energy level, eight electrons in the second energy level and one electron in the third energy level. An atom can have a maximum of two electrons occupying the first energy level, eight in the second energy level and eight in the third energy level. Each energy level must be filled before electrons occupy the next one. Exercise 1 Charge Protons Location Mass symbol Electrons Neutrons Atomic Number The atomic number is equal to the number of protons in the nucleus. The atomic number is special because it can be used to identify any known element. It is easy to identify copper because it has an atomic number of 29. Carbon has an atomic number of 6, oxygen has an atomic number of 8, and so on. The atomic number of any element is found in the periodic table. Mass Number All atoms have a mass number. The mass number is equal to the number of protons plus the number of neutrons (e.g., carbon has six protons and six neutrons). The mass number for carbon would be 6 (protons) + 6 (neutrons) = 12. Mass number = atomic number (number of protons) + number of neutrons The atomic mass of an atom is expressed in atomic mass units (u). This means the atomic mass of carbon is expressed as 12 u. You can solve for atomic number and number of neutrons by modifying the formula shown above. Atomic number = mass number - number neutrons Number of neutrons = mass number - atomic number Exercise 2 Use your understanding of mass number to calculate the values for the blank spaces in the table below. Place the proper symbol for the elements in the brackets. Refer to the periodic table. Place the atomic symbol in the brackets following the names in the table below. Fill in the blanks with the values for the atomic number and number of protons. Iron (_____) Krypton (_____) Uranium (_____) Sodium (_____) Atomic Number Number of Protons Lithium (_____) Chlorine (_____) Number of Protons 3 17 Number of Neutrons 4 Mass number Copper (_____) 47 34 35 Silver (_____) 63 61