Not long ago, in a chemistry Mayso the FORCE/area be with you lab far far away… 1. Describe Gay-Lussac’s Law with a formula 2. Use Gay-Lussac’s Law to determine either a temperature or volume 3. Combine all three laws into the Combined Gas Law 4. Use the Combined Gas Law to determine either temperature, volume or pressure If n and V are constant, then P α T P and T are directly proportional. P1 P2 T1 T2 If one temperature goes up, the pressure goes up! Joseph Louis GayLussac (1778-1850) Gay Lussac’s Law Summary The pressure and temperature of a gas are directly related, provided that the volume remains constant. P1 P2 T1 T2 P1 P2 T1 T2 3.00 atm 298 K P2 325 K 3.3 atm P1 P2 T1 T2 1.8 atm 1.9 atm 293 K T2 310 K or 36 oC Now let’s put all 3 laws together into one big law……. The good news is that you don’t have to remember all three gas laws! Since they are all related to each other, we can combine them into a single equation. BE SURE YOU KNOW THIS EQUATION! PV PV 1 1 2 2 T1 T2 No, it’s not related to R2D2 The Combined Gas Law The combined gas law expresses the relationship between pressure, volume and temperature of a fixed amount of gas. PV PV 1 1 2 2 T1 T2 Boyle’s law, Gay-Lussac’s law, and Charles’ law are all derived from this by holding a variable constant. If you should only need one of the other gas laws, you can cover up the item that is constant and you will get that gas law! P1 V1 T1 = P2 V2 T2 Boyle’s Law Charles’ Law Gay-Lussac’s Law Greatest Reasons for Termination from a Job 1. The inability to get along with co-workers and supervisors. 2. Absenteeism 3. Lack of interest 4. Continuously making costly mistakes 5. Does not follow directions 6. Shows an unwillingness to learn A sample of helium gas has a volume of 0.180 L, a pressure of 0.800 atm and a temperature of 29°C. What is the new temperature(°C) of the gas at a volume of 90.0 mL and a pressure of 3.20 atm? Set up Data Table P1 = 0.800 atm V1 = 180 mL T1 = 302 K P2 = 3.20 atm V2 = 90 mL T2 = ?? P1 = 0.800 atm V1 = 180 mL T1 = 302 K P2 = 3.20 atm V2 = 90 mL T2 = ?? P1 V 1 T1 = P2 V 2 T2 P1 V1 T2 = P2 V2 T1 T2 = 3.20 atm x 90.0 mL x 302 K 0.800 atm x 180.0 mL = 604 K T2 = 604 K - 273 = 331 °C Hint #5. A record of data is essential. It fools the instructor into thinking that you were working. 1. Describe Gay-Lussac’s Law with a formula. 2. Use Gay-Lussac’s Law to determine either a temperature or volume 3. Combine all three laws into the Combined Gas Law 4. Use the Combined Gas Law to determine either temperature, volume or pressure A gas has a volume of 675 mL at 35°C and 0.850 atm pressure. What is the temperature in °C when the gas has a volume of 0.315 L and a pressure of 802 mm Hg? P1 = 0.850 atm V1 = 675 mL T1 = 308 K P2 = 1.06 atm V2 = 315 mL T2 = ?? P1 V 1 T1 = P2 V 2 T2 P1 V1 T2 = P2 V2 T1 T2 = 1.06 atm x 315 mL x 308 K = 179 K 0.850 atm x 675 mL T2 = 179 K - 273 = -94 °C P1 V1 (34,470 Pa) (473.18 mL) P2 P2 V2 (13.13 mL) 1,242,000 Pa V1 V2 T1 T2 31.4 L 25.0 L 296.6 K T2 236 K or -37 oC P1 = 12.0 atm V1 = 23.0 L T1 = 200. K P2 = 14.0 atm V2 = ? L T2 = 300. K P1 V 1 T1 = P2 V 2 T2 P1 V1 T2 = P2 V2 T1 V2 = 12.0 atm x 23.0 L x 300 K 14.0 atm x 200 K = 29.6 L Pass the Clicker!!! 1. 2. 3. 4. 5. 2.00 atm 0.500 atm 1.08 atm 0.923 atm Not listed 1. 2. 3. 4. 5. -124oC 149oC 119oC -154oC Not listed 1. 2. 3. 4. 5. .00687 mL 44.4 mL 6.87 mL 5220 mL Not listed The End!!!