Solving a Stoichiometry Problem 1. 2. 3. 4. Balance the equation. Convert given to moles. Determine which reactant is limiting. Use moles of limiting reactant and mole ratios to find moles of desired product. 5. Convert from moles to grams, molecules or Liters. Practice Test (Ch. 9) 2 Al + 6 HCl 2 AlCl3 + 3 H2 1. How many moles mol of aluminum chloride (AlCl AlCl33) would be produced from 0.12 moles mol of hydrochloric acid (HCl)? Use Mole Ratio (Balanced Equation) 0.12 mol HCl X mol AlCl3 mol HCl = 0.040 mol AlCl3 Practice Test (Ch. 9) 2 Al 6 HCl 2 AlCl3 + + 3 H2 2. If you wanted to completely react 5.0 moles mol of Al HCl Aluminum, how many moles mol of hydrochloric acid (HCl) would be needed? Use Mole Ratio (Balanced Equation) 5.0 mol Al X mol HCl mol Al = 15 mol HCl Practice Test (Ch. 9) 2 Al + 6 HCl 2 AlCl3 + 3 H2 3. How many grams g of hydrochloric HCl acid would be needed to completely react 35.8 g ofAlaluminum foil? Set up Units don’t match Convert Use Periodic givenTable to moles 35.8 g Al X Mole Ratio 1 mol Al 26.98 g Al Use Periodic Table g HCl 36.46 Units still X don’t match 1 mol HCl mol HCl g HCl mol Al x = Units Match = 145 _________ g HCl Practice Test (Ch. 9) 2 Al + 6 HCl 2 AlCl3 3 H2 + 4. How many grams g of aluminum Al would be needed to produce 67.2 dm33 H of2 hydrogen gas? Set up Units don’t match 3 Convert 1 mole =given 22.4to dmmoles 67.2 dm3 H2 x 1 Mole Ratio mol H2 22.4 dm3 H2 Use Periodic Table g Al 26.98 Units still x don’t match 1 mol Al mol Al g Al mol H2 x = Units Match = 53.96 _________ g Al Practice Test (Ch. 9) 2 CO(g) + 1 O2 (g) 2 CO2 (g) 5. How many molecules molec. of carbon CO2 dioxide (CO2) would be produced by completely reacting 8.00 8.00 grams g O2 of oxygen gas (O2) with carbon monoxide (CO)? Set up Units don’t match Convert Use Periodic givenTable to moles Mole Ratio 8.00 g O2 x 1 mol O2 32.00 g O2 x= mol CO2 molec.CO2 mol O2 1 mol = 6.02 x 1023 molecules 23 molec. still CO2 Units Match 6.02 x 10Units 23 x 3.01 x 10 don’t match ________ molec.CO2 1 mol CO2 = Practice Test (Ch. 9) 2 CO(g) + 1 O2 (g) 2 CO2 (g) 6. What volume in LL ofOoxygen gas (O2) would react with 2 6.0 LL CO of carbon monoxide gas (CO)? 6.0 Set up Units don’t match Convert 1 mole =given 22.4to L moles 6.0 L CO x 1 mol CO 22.4 L CO 1 mol = 22.4 L x Mole Ratio L O2 22.4 Units still don’t match 1 mol O2 mol O2 x= __________ L O2 mol CO Units Match = 3.0 ________ L O2 Practice Test (Ch. 9) 1 N2(g) + 3 H2 (g) 2 NH3 (g) 7. What volume in LL ofNH ammonia gas (NH3) would be 3 produced from 14.0 g of N2 nitrogen (N2) at STP? Set up Units don’t match Convert 1 mole =given Molartomass moles(periodic table) Mole Ratio 14.0 g N2 x 1 mol N2 28.0 g N2 1 mol = 22.4 L x L NH3 22.4 Units still don’t match 1 mol NH3 mol NH3 x= ________ L NH3 mol N2 Units Match = 22.4 ________ L NH3 Solving a Stoichiometry Problem Reactants 1 CH4 (g) + O22 (g) CO2 (g) + 2 O 2 H2O (l) Compare balance 8.0 moles mol to O2 8. If 6.0 the moles mol two CHof methane from is mixed with equation 8.0 4reactants moles forthe each reactant in the problem. of Ogiven mixture is ignited, determine: 2, and a. The limiting reactant Ideal situation (From Bal.Eqn.) = Moles given in Problem O2 CH4 = = 1.33 1 1.33 is less than 2 so… moles O2 in given problem is the limiting reagent. Solving a Stoichiometry Problem Reactants 1 CH4 (g) + O22 (g) CO2 (g) + 2 O 2 H2O (l) Compare balance 8.0 moles mol to O2 8. If 6.0 the moles mol two CHof methane from is mixed with equation 8.0 4reactants moles forthe each reactant in the problem. of Ogiven mixture is ignited, determine: 2, and b. The reactant in excess Ideal situation (From Bal.Eqn.) = Moles given in Problem = 0.50 CH4 O2 = = 0.75 0.75 is greater than 0.50 so… moles CH4 in given problem is the excess reagent. Solving a Stoichiometry Problem Excess CH4 (g) + Limiting 2 O2 (g) 1 CO2 (g) + 2 H2O (l) 8. If 6.0 moles of methane is mixed with 8.0 moles of O2, and the mixture is ignited, determine: c. The moles of carbon dioxide (CO2) produced. Identify whatlimiting you wantreagent to find Start with the 8.0 mol O2 x mol CO2 mol O2 Use Mole Ratio (Bal. Equation) 4.0 = ________ mol CO2 Solving a Stoichiometry Problem Excess 1 CH4 (g) + Limiting 2 O2 (g) CO2 (g) + 2 H2O (l) 8. If 6.0 moles of methane is mixed with 8.0 moles of O2, and the mixture is ignited, determine: d. How many grams of excess reactant left over over?? 1stStart find out howthe muchlimiting excess gets Identify what you want toused findup. with reagent 8.0 mol O2 x mol CH4 mol O2 Use Mole Ratio (Bal. Equation) 4.0 = ________ mol CH4 Amount Used up Solving a Stoichiometry Problem Excess CH4 (g) + Limiting 2 O2 (g) CO2 (g) + 2 H2O (l) 6.0 moles mol CH 8. If 6.0 of4 methane is mixed with 8.0 moles of O2, and the mixture is ignited, determine: d. How many grams of excess reactant left over ? Excess Reagent (original amount) = 4.0 mol CH4 2.0 mol CH4 Amount Used up Excess moles Left over Solving a Stoichiometry Problem Excess CH4 (g) + Limiting 2 O2 (g) CO2 (g) + 2 H2O (l) 8. If 6.0 moles of methane is mixed with 8.0 moles of O2, and the mixture is ignited, determine: d. How many grams of excess reactant left over over?? 1 mole = Molar mass (Periodic table) 2.0 mol CH4 x 16.05 g CH4 1 mol CH4 Use molar mass (Periodic table) 2 sig.figs. 32.10 32 = ________ g CH4 grams of excess reactant. Solving a Stoichiometry Problem Excess CH4 (g) + Limiting 2 O2 (g) CO2 (g) + 2 H2O (l) 8. If 6.0 moles of methane is mixed with 8.0 moles of O2, and the mixture is ignited, determine: e. How many grams of water will theoretically be produced fro this reaction? 1 mole =to molar mass Identify what you want find (Periodic Table) Start with the limiting reagent 8.0 mol O2 x mol H2O mol O2 Use Mole Ratio (Bal. Equation) 18.02 g H2O x = ________ g H2O 1 mol H2O Theoretical Yield 144.16 144.2 Solving a Stoichiometry Problem Excess CH4 (g) + Limiting 2 O2 (g) CO2 (g) + 2 H2O (l) 8. If 6.0 moles of methane is mixed with 8.0 moles of O2, and the mixture is ignited, determine: f. Determine the % yield if the actual amount of g water produced during this reaction is 130.0 g. % Yield = Actual Yield Theoretical Yield X 100 = 144.2 g from previous Problem = 90.15% X 100