Indicators and pH meters Materials 1. 2. 3. 4. 5. 6. pH meter or paper 2 Buret 2 Buret clamp Two 100 mL beakers Two 50 mL beakers HCl solution of the following concentrations: 1.0 M, 0.1 M (1-2 L), 0.01 M, 0.001 M (Don’t need as much) 7. NaOH solution of the following concentrations: 1,0 M, 0.1 M, (500 ml) 0.01 M, 0.001 M (Don’t need as much) 8. Acid-base indicators: phenolphthalein, methyl orange, bromothymol blue, bromocresol green, phenol red 9. Vinegar Coca-cola Windex Procedure: Part A - pH of Common Substances 1. Measure the pH of the basic solutions provided as on the data sheet. Use litmus pH paper. Observations: Acidic Solution pH 1.0 mol/L HCl 0.1 mol/L HCl 0.01 mol/L HDl 0.001 mol/L HCl Basic Solution pH 1.0 mol/L NaOH 0.1 mol/L NaOH 0.01 mol/L NaOH 0.001 mol/L NaOH Household solution pH Vinegar Pop Windex Part B - Acid-Base Indicators 1. Fill one buret with 0.1 M NaOH solution. 2. Transfer about 25 mL of 0.1 M HCl solution into a 100 ml beaker and add 3-4 drops of indicator. 3. Add the base solution to the acid solution and observe the full range of colour change of the indicator. Record the full range of change in the colour in the data sheet. ( Example: red to orange.) 4. In order to measure the pH of the solution at the onset of colour change, you need to add some acid solution to the Erlenmeyer flask so that the colour of the solution reaches the in-between colour of the colour change. (Example: the in-between colour of red to orange is yellow.) This is the end point of the titration for this particular indicator. 5. Transfer a portion of the solution from the Erlenmeyer flask into a small beaker and measure the pH. Record the pH. 6. Repeat steps 2 to 5 for each of the indicators provided. Indicator bromothymol blue Methyl orange Phenol red Phenolphthalein Methyl violet Initial colour Intermediate colour Final colour pH at endpoint